US3747527A

US3747527A - Process and product

Info

Publication number: US3747527A
Application number: US00160435A
Authority: US
Inventors: G Griffith
Original assignee: Commercial Solvents Corp
Current assignee: BARCLAYS/AMERICAN/BUSINESS CREDIT Inc A CORP OF CT; IMC Chemical Group Inc; Commercial Solvents Corp
Priority date: 1971-07-07
Filing date: 1971-07-07
Publication date: 1973-07-24
Anticipated expiration: 1990-07-24
Also published as: CA973756A

Abstract

A booster for initiating relatively insensitive explosive compositions, and a process for manufacturing such boosters. In accordance with the process, a base is provided with at least one upstanding rod in the location at which an opening is desired in the booster for a fuse. A layer of relatively sensitive explosive material is placed around this rod, and an outer form having the cross-section desired of the finished booster is placed around the rod and explosive layer. A somewhat insensitive explosive material of high brisance is placed within the outer form and surrounding the relatively sensitive explosive material and allowed to harden to form the finished booster which thus comprises an outer layer of the somewhat insensitive explosive material and an inner layer of the more sensitive explosive material surrounding the fuse opening. A second rod can be provided to cause a second opening into the booster also contacting relatively sensitive explosive material. This second opening, for example, might accommodate a detonating cap. The layer of relatively sensitive explosive material can be provided in two or more lengths, if desired.

Description

United States Patent [191 Griffith 1 July 24, 1973 I PROCESS AND PRODUCT George L. Gritllth, Coopersburgh, Pa.

[73] Assignee: Commercial Solvents Corporation,

Terre Haute, Ind.

[22] Filed: July 7, 1971 [2|] Appl. No.: 160,435

[75] Inventor:

Primary Examiner-Verlin R. Pendegrass Altomey.l0hn W. BehringerJames N. Dresser et al.

[57] ABSTRACT A booster for initiating relatively insensitive explosive compositions, and a process for manufacturing such boosters. In accordance with the process, a base is provided with at least one upstanding rod in the location at which an opening is desired in the booster for a fuse. A layer of relatively sensitive explosive material is placed around this rod, and an outer form having the cross-section desired of the finished booster is placed around the rod and explosive layer. A somewhat insensitive explosive material of high brisance is placed within the outer form and surrounding the relatively sensitive explosive material and allowed to harden to form the finished booster which thus comprises an outer layer of the somewhat insensitive explosive mate rial and an inner layer of the more sensitive explosive material surrounding the fuse opening. A second rod can be provided to cause a second opening into the booster also contacting relatively sensitive explosive material. This second opening, for example, might accommodate a detonating cap. The layer of relatively sensitive explosive material can be provided in two or more lengths, if desired.

9 Claims, 13 Drawing Figures PATENIELJIII PdlHH 3.747. 527

SHEET 1 BF 2 INVENTOR GEORGE L. GRIFFITH ATTORNEYS PROCESS AND PRODUCT The present invention pertains to a detonator for explosives. More particularly, the present invention pertains to a detonating booster for initiating relatively insensitive explosive compositions and to a process for manufacturing such boosters.

Insensitive explosives, such as those containing a high percentate of ammonium nitrate and nonexplosive organic sensitizers, are not generally detonatable by such conventional means as blasting caps and fuses. These insensitive explosives have been detonated in the past by the use of a primer such as dynamite or TNT which, in turn, is detonated by a blasting cap or a fuse of such material as pentaerythritol tetranitrate (PETN), commercially available as an elongated cord type fuse under the tradename Primacord. Not only are such primers expensive, but also dynamite, fine grained TNT and blasting caps are very sensitive to heat and shock, thus presenting a potential safety hazard. Use of a Primacord fuse is highly desirable because of the ease and safety with which it can be utilized. The most desirable boosters are thus materials which are reliably detonated by Primacord.

There have recently been developed boosters including an inner layer of Primacord sensitive material completely or partially surrounded by an outer layer of Primacord insensitive material of high brisance. These boosters initiate high ammonium nitrate explosives in a generally satisfactory manner; however, heretofore they have presented certain shortcomings, in particular difficulty of manufacture. Manufacture of one type of such booster requires two casting processes a first to form the inner Primacord sensitive core, and a second to form the outer Primacord insensitive sheath. A sec ond type of such booster has the inner Primacord sensitive material disposed in a multi-layer figure eight configuration. Placement of this within the sheath mold is a laborious and time-consuming task.

The present invention is a booster for initiating relatively insensitive explosive compositions and comprising an outer layer of somewhat insensitive explosive material of high brisance and one or more inner layers of a more sensitive explosive material adjacent one or more openings adapted for receipt of a fuse or a blasting cap. Relatively insensitive explosive materials of high brisance suitable as the outer layer include TNT, pentolite, cyclonite (RDX), and composition B (RDX, TNT, and wax), and mixtures thereof. More sensitive explosive materials suitable for the inner layers include pentaerythritol tetranitrate (PBTN) and finely-divided pentolite (PETN and TNT). In another aspect, the present invention pertains to a method of manufacturing such boosters. In accordance with this method, a layer of the more sensitive explosive material is placed in contact with one or more rods within a molding form, and the molding form is then filled with the somewhat insensitive booster material which is subsequently allowed to compact or harden. In one embodiment, the more sensitive explosive material is provided in a sheet material wrapped around the rods. In another embodiment, the more sensitive explosive material is provided as an extrusion which contacts only a portion of the surface'of the rods and which is primarily surrounded by the less sensitive booster material. In a preferred embodiment, the more sensitive explosive material is provided as one or more hollow cylinders, and the rods are passed through the central openings thereof.

These and other aspects and advantages of the present invention are more apparent in the following detailed description and claims, particularly when considered in conjunction with the accompanying drawings in which like parts bear like reference numerals.

In the drawings:

FIG. 1 is a perspective illustration of one embodiment ofa booster in accordance with the present invention;

FIG. 2 is a horizontal sectional view taken along line 2-2 of FIG. 1;

FIG. 3 is a vertical sectional view taken along line 3-3 of FIG. 2;

FIG. 4 is a view similar to FIG. 2 and depicting a modified embodiment of a booster in accordance with the present invention;

FIGS. 5 through 8 are views similar to FIG. 2 and depicting other modified embodiments of boosters in accordance with the present invention;

FIG. 9 is a view, partially broken, illustrating a preferred process for manufacturing a booster in accordance with the present invention;

FIG. 10 illustrates an alternative step in a process for manufacturing a booster in accordance with the present invention;

FIG. 11 is a vertical sectional view depicting a further embodiment ofa booster in accordance with the present invention;

FIG. 12 is a view, partially broken, illustrating a process for manufacturing the booster of FIG. 11 in accordance with the present invention; and

FIG. 13 is a vertical sectional view depicting yet another embodiment of a booster in accordance with the present invention.

As depicted in FIGS. 1, 2, and 3, booster 10 includes an outer material 12 of a somewhat insensitive explo sive of high brisance and surrounding a first inner material core 14 and a second inner material core 15, each of an explosive more sensitive than is material 12. Booster 10 is formed with a first longitudinal perforation or opening 16 passing completely through the booster, through both outer material 12 and inner material 14, to receive a fuse of, for example, Primacord, and a second longitudinal opening 18 passing from one outer surface of the booster a substantial distance into the booster, for example, two-thirds the length of the booster, to receive a blasting cap. In the embodiment depicted in FIGS. 1-3, inner material 14 is thus in the shape of an elongated cylinder having an axial opening therethrough to define opening 16 over a portion of the length of opening 16.

The inner more sensitive material I4 is thus adjacent opening 16 so that a fuse within opening 16 will contact the more sensitive material 14. Likewise, the inner more sensitive material 15 is adjacent opening 18 to permit intimate contact with a blasting cap. As depicted in FIG. 4 material 14 can be adjacent the edge of opening 18 if desired so that a blasting cap in opening 18 likewise contacts material 14, thereby eliminating inner material layer 15. Booster 10, by way of example, might have a diameter in the order of about 2-54 inches and a length in the range of from about 2-h inches to about 6 inches and preferably a length in the order of about 4-% inches. These dimensions, of course, vary, depending upon the particular application for which the booster is intended. The inner material l4 has a length of at least 9% inch aand preferably 2% inches and a diameter in the order of, for example, b inch. Inner material 14 can extend the entire length of booster I0, if desired. Inner material 15 has a length in the order of 1 inch and a diameter in the order of inch.

FIGS. 5, 6, 7, and 8 depict modified embodiments of boosters in accordance with the present invention hav ing elongated cores of inner material I4 of various shapes. In the embodiment of FIG. 5, the inner material 14 is provided with a first curved edge 20 defining a portion of the circumferential surface of opening 16 and thus adjacent opening 16 and a second curved edge 22 defining a portion of the circumferential surface of opening 18 and thus adjacent opening I8. This shape of material 14 can be readily formed as an extrusion. The embodiment of FIG. 6, has the inner material 14 defining approximately one-half of the circumferential surface of opening 16 and approximately one-half of the circumferential surface of opening 18. In the embodiment of FIG. 7, inner material 14 completely encircles

openings

16 and 18, defining the entire circumferential surface thereof over the length of inner material I4. The embodiment depicted in FIG. 8 has the entire circumferential surface of opening 16 and approxi mately one-half the circumferential surface of opening I8 defined by inner material I4. While FIGS. 2-8 depict several embodiments of the present invention, numerous others could be made within the scope of the invention.

FIG. 9 depicts a preferred process of manufacturing the embodiment of booster which is depicted in FIGS. I, 2, and 3. Base 24 is provided with a pair of upwardly extending

rods

26 and 28 in the locations at which

openings

16 and 18 are to be provided. Preferably,

rods

26 and 28 have a slight taper over their lengths. A layer of more sensitive explosive material 14 is affixed about rod 26, and a layer of more sensitive material I5 is affixed about rod 28 in the desired location. These layers I4 and can be affixed to

rods

26 and 28 in any of several manners. In a preferred process, hollow cylinders of the more sensitive explosive material are positioned over

rods

26 and 28. Preferably, these hollow cylinders have inner diameters such that the

cylinders

14 and 15 position themselves on

tapered rods

26 and 28 at the desired locations, keeping in mind that the finished booster is inverted during the manufacturing process of FIG. 9, relative to the finished booster depicted in FIGS. I-3. Alternatively, if material 14 is to extend the length of booster 10, then the cylinder of material 14 can rest upon base 24. FIG. l0 illustrates an alternative step in the manufacturing process in which a section of more sensitive explosive material 34 is cut from a flexible sheet of such material, wrapped about a hollow cylindrical sleeve 36 of, for example, paper, and affixed thereto by an adhesivev The resulting compacted cylindrical layer of the more sensi tive explosive material is then placed on rod 26 or on rod 28, as desired. Alternatively, sleeve 36 can be placed on rod 26 or on rod 28 before the section of more sensitive explosive material 34 is wrapped about and affixed to the sleeve.

After material I4 aand material IS are affixed on

rods

26 and 28, a mold form 30 of metal or cardboard aand having a cross-section of that desired for the finished booster is positioned around

rods

26 and 28 and material I4 and I5, as depicted in FIG. 6, and noncompacted, e.g. molten, explosive material I2 is poured into the mold form from a spout 32. After the material I2 has compacted or hardened, booster I0 is removed from base 24. If form 30 is cardboard or paper, then it need not be removed from the finished booster.

In a preferred implementation of the manufacturing process depicted in FIG. 9, pin 26 has a length in the order of 4 inches and tapers from a diameter in the order of 0.295 inches near the top of the pin to a diameter in the order of 0.312 inches at the base of the pin; pin 28 has a length in the order of three inches, a diameter at its top in the order of 0.305 inches and a diameter at its base in the order of0.3 l 2 inches. The material I4 is applied in the form of a hollow cylindrical sleeve or tube of PETN placed over rod 26 and having a length in the order of Z-A inches, an inside diameter in the order of 0.308 inches, and an outside diameter in the order of 0.480 inches. The material 15 is applied in the form of a hollow cylindrical sleeve or tube of PETN placed over rod 28 and having a length in the order of one inch, an inside diameter in the order of 0.307 inches, and an outside diameter in the order of 0.480 inches. A relatively sensitive explosive made up of PETN and an elastomeric binder and suitable for use as material I4 and as material 15 is commercially available in both sheet form and hollow cylindrical sleeve form from E. I. duPont de Nemours & Co., under the trademark Detasheet, and can likewise be obtained in extruded shapes from that source.

FIG. II depicts an alternate embodiment of explosive booster 40 in accordance with the present inven tion.

Longitudinal openings

42 and 44 pass completely through the booster. Opening 44 is surrounded over a first short portion of its length by a first core 46 and over a second short portion of its length, preferably contiguous with the first short portion, by a second core 48.

Cores

46 and 48 and

longitudinal openings

42 and 44 are surrounded by an outer layer 50 of a somewhat insensitive explosive of high brisance.

Cores

46 and 48 are of an explosive more sensitive than outer layer 50. Opening 42, which

contacts cores

46 and 48, is adapted to receive a fuse of, for example, Primacord. The interior of core 48 forms a capwell for blasting caps, while the smaller diameter interior of core 46 provides close contact with small diameter, low coreload detonating cords, should that be desired.

The booster 40 can be enclosed by a canister 52 with a bottom lid 54 and a top wax seal 56, if desired. By way of illustration, a satisfactory explosive booster in accordance with this embodiment of tthe present invention can be made with outer material 50 being, for example composition B, and having a length in the order of 3 1; inches and a diameter in the order of 2-& inches, with first core 46 being a piece of duPont Deta flex No. 72P-O50 having a length in the order of I78 inch, an outside diameter in the order of A inch, and an inside diameter in the order of 7/32nds inch, and with second core 48 being a piece of duPont Detaflex No. 72P-l75 having a length in the order of l-% inches, an outside diameter in the order of /4 inch and an inside diameter in the order of 5/l6ths inch. The booster of FIG. II can readily be manufactured by the process described above as depicted in FIG. 12.

FIG. I3 depicts an explosive booster in accordance with the present invention and suitable for use as a primer or booster in a train of seismic explosive cans, for example, within a bore hole during land seismic work as described in U.S. Pat. No. 3,097,601, issued July l6, 1963 to George L. Griffith and George A. Lyte. Booster 58 includes an outer material sheath 60 of a somewhat insensitive explosive material of high brisance and surrounding an inner material core 62 of an explosive more sensitive than is material 60. Spacer 64 can be provided above core 62 if desired. Capwell 66 extends through spacer 64 and into core 62 and is adpated to receive an explosive device such as a blasting cap to initiate booster 58. Booster 58 is enclosed by casing 68 which includes a threaded lower extension 70. The upper surface of booster 58 is closed by lid 72 which includes threaded recess 74 and a capwell opening 75. Threaded extension 70 and threaded recess 74 permit booster 58 to be included in a train of seismic explosive cans, as set out in U.S. Pat. No. 3,897,601. Booster 58 might have a diameter in the order of 2 inches and a length in the order of 6 inches, with core 62 having an outside diameter in the order of '16 inch, an internal diameter in the order of 5/l6ths inch, and a length in the order of 2-5 4 inches and being formed of duPont Detaflex No. 72P-225.

Although the present invention has been described with reference to preferred embodiments, numerous modifications and alterations could be made and still the result would come within the scope of this invention.

What is claimed is:

1. An explosive booster for initiating relatively insensitive explosives comprising a cylindrical sheath of somewhat insensitive explosive material of high brisance having a perforation extending longitudinally thereinto and adapted to receive an explosive device; and

a cylindrical core of more sensitive explosive material encircled by the sheath and encircling the perforation over at least a portion of the length thereof, said cylindrical core having a longitudinal axis substantially parallel with the longitudinal axis of the sheath, said cylindrical core including a first core portion of a first internal diameter and a second core portion of a second internal diameter.

2. An explosive booster as claimed in claim 1 in which the cylindrical core is pentaerythritol tetranitrate.

3. An explosive booster as claimed in claim 2 in which the cylindrical sheath is TNT.

4. An explosive booster as claimed in claim 2 in which the cylindrical sheath is pentolite.

5. An explosive booster as claimed in claim 2 in which the cylindrical sheath is composition B.

6. An explosive booster as claimed in claim I in which the cylindrical sheath has a second perforation extending longitudinally thereinto.

7. An explosive booster as claimed in claim 1 in which the cylindrical core includes a second surface defining at least a portion of the circumference of the second perforation over at least a portion of the length thereof.

8. An explosive booster as claimed in claim 1 in which the first core portion has a length in the order of 56 inch, an outside diameter in the order of '16 inch, and an inside diameter in the order of 7/32nds inch, the sec ond core portion has a length in the order of 1 inches, an outside diameter in the order of b inch and an inside diameter in the order of 5/l 6ths inch, and the cylindrical sheath has a length in the order of 3-56 inches and a diameter in the order of 2-56 inches.

9. An explosive booster as claimed in claim 1 in which the cylindrical sheath is enclosed within a casing having a threaded lower portion and an upper cap with a threaded internal recess.

i t i

Claims

2. An explosive booster as claimed in claim 1 in which the cylindrical core is pentaerythritol tetranitrate.
3. An explosive booster as claimed in claim 2 in which the cylindrical sheath is TNT.
4. An explosive booster as claimed in claim 2 in which the cylindrical sheath is pentolite.
5. An explosive booster as claimed in claim 2 in which the cylindrical sheath is composition B.
6. An explosive booster as claimed in claim 1 in which the cylindrical sheath has a second perforation extending longitudinally thereinto.
7. An explosive booster as claimed in claim 1 in which the cylindrical core includes a second surface defining at least a portion of the circumference of the second perforation over at least a portion of the length thereof.
8. An explosive booster as claimed in claim 1 in which the first core portion has a length in the order of 1/2 inch, an outside diameter in the order of 1/2 inch, and an inside diameter in the order of 7/32nds inch, the second core portion has a length in the order of 1- 3/4 inches, an outside diameter in the order of 1/2 inch and an inside diameter in the order of 5/16ths inch, and the cylindrical sheath has a length in the order of 3-1/2 inches and a diameter in the order of 2- 1/2 inches.
9. An explosive booster as claimed in claim 1 in which the cylindrical sheath is enclosed within a casing having a threaded lower portion and an upper cap with a threaded internal recess.