US3694995A - Corrugate-film laminate package material and package - Google Patents

Corrugate-film laminate package material and package Download PDF

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Publication number
US3694995A
US3694995A US71063A US3694995DA US3694995A US 3694995 A US3694995 A US 3694995A US 71063 A US71063 A US 71063A US 3694995D A US3694995D A US 3694995DA US 3694995 A US3694995 A US 3694995A
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Prior art keywords
film
corrugated
fluting
package
carton
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Expired - Lifetime
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US71063A
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James C Mckinney
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WR Grace and Co
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WR Grace and Co
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/08Corrugated paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/40Applications of laminates for particular packaging purposes
    • B65D65/403Applications of laminates for particular packaging purposes with at least one corrugated layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D71/00Bundles of articles held together by packaging elements for convenience of storage or transport, e.g. portable segregating carrier for plural receptacles such as beer cans or pop bottles; Bales of material
    • B65D71/06Packaging elements holding or encircling completely or almost completely the bundle of articles, e.g. wrappers
    • B65D71/08Wrappers shrunk by heat or under tension, e.g. stretch films or films tensioned by compressed articles
    • B65D71/10Wrappers shrunk by heat or under tension, e.g. stretch films or films tensioned by compressed articles and provided with inserts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/40Closed containers
    • B32B2439/62Boxes, cartons, cases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2571/00Bundles of articles held together by packaging elements for convenience of storage or transport, e.g. portable segregating carrier for plural receptacles such as beer cans, pop bottles; Bales of material
    • B65D2571/00006Palletisable loads, i.e. loads intended to be transported by means of a fork-lift truck
    • B65D2571/00012Bundles surrounded by a film
    • B65D2571/00018Bundles surrounded by a film under tension
    • B65D2571/00024Mechanical characteristics of the shrink film
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2571/00Bundles of articles held together by packaging elements for convenience of storage or transport, e.g. portable segregating carrier for plural receptacles such as beer cans, pop bottles; Bales of material
    • B65D2571/00006Palletisable loads, i.e. loads intended to be transported by means of a fork-lift truck
    • B65D2571/00037Bundles surrounded by carton blanks

Abstract

This invention comprises a corrugated package material wherein the corrugated fluting is attached to one or more sheets of heat shrinkable polymeric film. The heat shrinkable film is preferably on only one side of the corrugated fluting, but may be on both sides of the corrugated fluting. This packaging material is then formed into a carton and this carton filled; or is used to bundle a series of containers, and the final assembly, whether a carton or bundle, heat shrunk, whereby the strength of the corrugate is increased.

Description

United States Patent McKinney I541 CORRUGATE-FILM LAMINATE Primary Examiner-Theron E. Condon l t [72] men or C McKmney Greenvlne Assistant Examiner-Eugene F. Desmond Attomey--John .l. Toney, William D. Lee, Jr. and Ed- [7 3] Assigneez W. R. Grace & Co., Duncan, SC. d J, Han n, Jr, [22] Filed:
[57] ABSTRACT This invention comprises a corrugated package Sept. 10, 1970 211 Appl. No.: 71,063
material wherein the corrugated fluting is attached to one or more sheets of heat shrinkable polymeric film. The heat shrinkable film is preferably on only one side [51] Int. Cl. 53/02 Fleld 0f of the corrugated fluting, but y be on b h Sides of the corrugated fluting. This packaging material is then References cued formed into a carton and this carton filled; or is used UNITED STATES PATENTS to bundle a series of containers, and the final ask n a $6 a m 0 e/m r de H. nm E Om g mo c a ne oh m t m 5 c 9 am .m n I t 4 S .me w. V. m Mr mm sw 0W0 3 3 N N 5%5 "/N 5m ".a l nmfl m mum mfim ell Ufa BDK 20 767 999 1.11 l// 288 PATENT'ED nm 3 I972 INVENTOR James 6. McK/hney CORRUGATE-FILM LAMINATE PACKAGE MATERIAL AND PACKAGE BACKGROUND OF THE INVENTION This invention relates to a corrugated material attached to a heat shrinkable polymeric film, forming a corrugated composite for packaging. The invention further relates to a package wherein containers are within a carton formed from this corrugated composite; or containers are bundled in this material, and the polymeric film is then shrunk to increase the strength of the fluting and the final package.
Corrugated cartons are a standard item in commerce for transporting a series of smaller containers. These cartons maintain the containers in a set orientation, protect the container surfaces from damage, and give strength to allow stacking for more efficient storage and transport. Further, corrugated cartons to a degree protect these containers against moisture and weather, preserving the more decorative containers within the carton. There is a nonending search for cartons which are light-weight, strong, of low bulk, weatherproof, can still maintain the packaged containers in a set orientation, and are stackable without carton or bundle distortion. The present invention is directed to such a packaging material and package. In the present invention, corrugated fluting is attached to a heat shrinkable polymeric film. This is then either formed into a carton or used to bundle a series of containers. When in the form of a carton, it is filled with containers and sealed. In either form, carton or bundle, the package is then heat-treated to shrink the polymeric film and tighten the corrugated fluting core. This operation of heatshrinking serves both to tighten the fluting and to place the package in a state of compression. When stacked, the sides of the carton or bundle are not readily placed in a bulging tension condition without exerting forces greater than those experienced in normal warehousing.
The prior art is illustrated by any of U.S. Pat. Nos. 3,407,987, 3,406,052 and 3,411,689. U.S. Pat. No. 3,407,987 sets out a corrugated packaging material suitable for bundling. U.S. Pat. No. 3,406,052 discloses plastic coated corrugated fiberboards and methods for making this material. The corrugated flute is here coated on one or two sides with the plastic. However, this plastic is not of a shrinkable variety, and thus is not a similar material, and will not produce stackable, nonbulging cartons and bundles. U.S. Pat. No. 3,411,689 sets out a reinforced corrugated paperboard carton material and carton. In this instance, a strong non-bulging carton is formed, but it entails the use of a thermoplastic material for strengthening. Further, for
strength, the container is quite massive. Thick layers of compressive force which resists sidewall distortion on' stacking.
It is an object of this invention to set out a packaging material capable of being formed into a sidewall bulgeresistant carton or bundle.
It is also an object of this invention to disclose a packaging material wherein corrugated flutes are attached to polymeric heat-shrinkable -film which is then formed into acarton or used as a bundling material.
It is further an object of this invention to provide a corrugated container of high strength, but of a low weight and bulk, and stackable for storage.
BRIEF SUMMARY OF THE INVENTION Briefly, this invention comprises anew corrugated packaging material and new cartons and bundled packages produced from this material. The corrugated packaging material is constructed of a corrugated fluting attached to a heat-shrinkable polymeric film. The polymeric film can be attached to one or both sides of the corrugated fluting. In use, this material is either formed into a carton or used to bundle a plurality of containers. This package is then heated to shrink the polymeric film which tightens the corrugated fluting, keeping the fluting in a tightened condition and the package in a compressed state. In this condition, forces due to stacking fail to bulge or distort the package, facilitating warehouse storage.
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a plan view of the corrugated packaging material.
FIG. 2 is an elevation of a single face corrugated packaging material.
FIG. 3 is an elevation of the double face embodiment of the packaging material.
FIG. 4 is an elevation of the corrugated packaging material with the backing sheet in a shrunken condition.
FIG. 5 is a perspective view of bundled containers.
DETAILED DESCRIPTION OF THE INVENTION More specifically, the preferred embodiments are set out in the accompanying drawings which will now be more fully discussed. FIG. 1 is a plan view of the packaging material 10. This material comprises a heatshrinkable polymeric film layer 11 adhesively attached to a paper or paper board corrugate 12. The polymeric film 'in this invention must be of a heat-shrinkable variety. By heat-shrinkable polymeric film is meant any of the conventional uniaxially oriented polymeric films which on the application of heat are shrunk to a decreased surface area. Such films comprise oriented polyolefinic films such as polypropylene, polyethylene, polyisopropylethylene and polyisobutylethylene. Other exemplary films are polystyrene, polyethylene terephthalate, polyethylene-2,6-naphthalate,
' polyethylene-1,5-naphthalate, polytetramethylene-l,2-
dioxybenzoate, polyhexamethylene adipamide, polyhexamethylenev sebacamide, polycaprolactam, polyvinylchloride anpolymethyl-methacrylate. Also included are polymers of alpha mono-olefinically unsaturated hydrocarbons with organic compounds having polymer producing unsaturation such as is present in butene, vinyl acetate, vinyl stearate, vinyl formate, methyl acrylate, Z-ethyl hexyl acrylate, acrylic acid, isoprene, butadiene acrylamide, methacrylic acid, ethyl acrylate N-methyl-n-vinyl acetamide and the like. This list is illustrative of the types of polymeric films known in the art and is not an exhaustive citation of heatshrinkable polymeric films. Others are known to the art and exhibit varying degrees of shrink on heating, and are useful in and a part of this invention.
The film in a preferred embodiment is a polyolefin, and preferably polypropylene. Polypropylene is readily uniaxially oriented, is dimensionally stable on storage, readily workable for bonding corrugated fluting, and can be heat-shrunk at moderate temperatures. The thickness of the film is not critical to the invention, and may range from I mils to 30 mils.
The corrugated fluting 12 may be of. any type and will depend on the substance to be packaged and the protection required. The fluting material may be of paper, paperboard, plastic or a combination of paper and plastic or paperboard and plastic. In a preferred and most useful embodiment, the corrugation is a standard paperboard of A, B or C designation. A-corrugation has approximately 36 flutes per foot, B-corrugation has approximately 52 flutes per foot, and C-corrugation has approximately 42 flutes per foot. The fluting material may range in thickness from 0.005 inch to 0.02 inch, depending on the package requirements. A preferred thickness is 0.009 inch. The flutes are either adhesively bonded-to the film l 1 using a standard adhesive such as starch or some other special purpose adhesive, orheat sealed, since in many instances the film at elevated temperatures has adhesive properties.
FIG. 2 sets out in cross-section a single face corrugated'medium. In this embodiment, the fluting 12 is bonded to a single sheet of film. In'this instance, the film is preferably polypropylene. The film thickness is 15 mil and the corrugate fluting is 0.009 inch thick and contains 36 flutes per foot. FIG. 3 sets out in cross-section a double face board. The fluting 12 and film l l are the same as in FIG. 2. Film l3 is also of a heat-shrinkable variety, and may have the same. or differing shrink properties as film ll.
FIG. 4 sets out incross-section an exploded view of the corrugate fluting and film of FIG. 2 after heatshrinkage of the film. The film 11, in this instance polypropylene, is heat-shrunk by heating the corrugatefilm to 250 to 330 F. For other heat-shrinkable polymer films, the temperature ranges from about 150 F to about 350 F. These temperatures are those generally encountered; and'this invention is operable at other temperatures depending on conditions. For example, shrink tunnel temperatures may be as high as 400 F, depending on thethickness of the wrapping, rate of passage through the tunnel and other factors. The corrugate core is in this instance in a tightened condition having greater than the original 36 flutes per foot.
FIG. 5 is a perspective view of a plurality of containers bundled within the present packaging material, and the polymeric film shrunk, putting the corrugate core in' a tightened condition and the bundle in a compressed state. The bundle in this embodiment contains tightened corrugated fluting on foursides and clear plastic film on the ends. This packaging material may be essentially that of FIG. 1, but with the film 11 extending beyond the fluting 12 on each side in the direction longitudinal with the flutes. This film may be tends beyond the fluting it should be of a biaxially oriented type. By using a biaxially orientedtype, not only will the corrugations be strengthened, but the entire package will be strengthened. The corrugatedfluting may be of the single or double face type, however, for bundling it is preferably of a single face type. The
width of the extension beyond the flutes depends on he a package to be formed and may operably be from about 6 inches to about 18 inches or more. In a further embodiment, in forming a bundle the material of FIG. 1 can be used directly where the corrugate composite is cutand folded and sealed to form a corrugated top and bottom section, or the top and bottom may be-left entirely open. The packaging material is useful in any of these embodiments, but packages wherein the top and bottom are sealed are preferred. J
The packaging material of FIG. 1 may also be formed into corrugated carton blanks which can then be assembled into cartons. The material in this instance may be of a single or double face type. The carton when formed, by heat sealingor adhesives, can be heated to shrink the polymeric film prior to filling and sealing or after filling and sealing. When in a form to be heated, and the polymeric film shrunk prior to filling and sealing, the material is preferably of the double face type.
In a further embodiment of this invention, flat noncorrugated blanks can be formed at one place and these blanks shipped to theuser who, by heat shrinking, forms these blanks into corrugatedblanks. In this enibodiment, a uniaxially oriented film is preferably adhesively attached at set points to a flat fluting type material. The film is preferably attached to both sides to form a double face material on heat shrinking, although a single sheet of film on one side maybe used to form a single face material. It is usually desirable to precorrugate the fluting material and then flatten it out prior-to attaching it to the film to assure aneven corrugating without any irregular crinkling during subsequent heat shrinking corrugation. Further, in forming the double face material, each film is attached at alternating intervals along the flat fluting material so that when the films are heat shrunk, the decrease in dimension of the film corrugates the flat fluting material. The prime benefit of such a material is in the volume which must I be transported to the user. There is greater efficiency in of a uniaxially or biaxially oriented type, however, in a preferred embodiment when the shrinkable film ex-v transporting a flat blank which is then treated to form corrugations, over transporting a corrugated sheet.
The process of heat-shrinkage the face film or films is' essentially that of subjecting the film to a temperature wherein by elastic memory the film loses its stretched orientation. The heat in this instance can be supplied by radiation, conduction or convection or any combination. In one technique, the bundles or cartons are conveyed through a tunnel containing lamps'with a high infrared emission; In another method, warmed air is blown on, and if an unfilled and sealed carton, also in, the .carton, shrinking the face films. In general, techniques and equipment for heat shrinking are well known and any of thesecan be adapted for usewith this invention. i
As is apparent from FIG. 5, both the corrugate and the bundle are here in a tightened condition. The shrunken film maintains the fluting in a tight and defined state, and the entirepackage ina compressed condition. Therefore, when stacked and a force is applied to the fluting, the fluting is not deformed in directions parallel or transverse to the fluting. The shrunken film maintains its tightening and compressive force on the fluting and package, preventing any sidewall bulging on stacking.
lclaim: l. The method of packaging comprising a. attaching a heat shrinkable polymeric film to a substrate in a plurality of regular spaced apart areas to form a film/substrate, b. wrapping the film/substrate around an object, c. heating said film/substrate to a temperature sufficient to shrink said film and causing the regular spaced apart attached surfaces of the substrate to move closer together, thereby forming corrugations in the substrate with the peaks of the flutes thereof closer than the said spaced apart attachment areas.
2. The method of claim 1 wherein said film is attached to the peaks of the flutes of a corrugated board.
3. The method of claim 1 wherein said film is attached to an uncorrugated sheet with the attachment being in regular spaced apart rows.
4. The method of claim 3 wherein said uncorrugated sheet is first corrugated and then flattened prior to attaching the film at the locations where the peaks of the flutes existed prior to flattening.

Claims (3)

  1. 2. The method of claim 1 wherein said film is attached to the peaks of the flutes of a corrugated board.
  2. 3. The method of claim 1 wherein said film is attached to an uncorrugated sheet with the attachment being in regular spaced apart rows.
  3. 4. The method of claim 3 wherein said uncorrugated sheet is first corrugated and then flattened prior to attaching the film at the locations where the peaks of the flutes existed prior to flattening.
US71063A 1970-09-10 1970-09-10 Corrugate-film laminate package material and package Expired - Lifetime US3694995A (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3805473A (en) * 1971-03-25 1974-04-23 E Lidgard Packaging methods and structures
US4666749A (en) * 1986-01-17 1987-05-19 Mccurry Thomas M Covering for roll end-support panel
WO1994016955A1 (en) * 1993-01-20 1994-08-04 The Procter & Gamble Company Packaging assembly with improved stackability
US5566824A (en) * 1993-01-20 1996-10-22 The Procter & Gamble Company Packaging assembly with improved stackability
US5623812A (en) * 1994-10-14 1997-04-29 Transhield Technology Co., Llc Shrink wrap material and method for protecting articles
US20020077015A1 (en) * 2000-09-19 2002-06-20 Todt Gregory L. Material for protecting articles having a nonwoven fabric bonded to a shrink film by an adhesive applied in a pre-determined pattern
US6562740B1 (en) 2000-09-19 2003-05-13 Transhield Technology As Material for protecting articles having a nonwoven fabric bonded to a shrink film by an adhesive applied to the film in a pre-determined pattern
US6696120B1 (en) 2000-10-12 2004-02-24 Transhield Technology As Shrink wrap material having reinforcing scrim and method for its manufacture
US20050121348A1 (en) * 2003-12-09 2005-06-09 Clare Timothy P. Package insert and stackable package for articles
US20050205652A1 (en) * 2004-03-19 2005-09-22 Georgia-Pacific Corporation Reinforced fiberboard bulk container
US20090258191A1 (en) * 2008-04-15 2009-10-15 Tredegar Film Products Corporation Shrink film laminates
US7740149B2 (en) 2002-09-27 2010-06-22 Ropak Corporation Container sidewall strengthening apparatus and methods
WO2014176084A1 (en) * 2013-04-26 2014-10-30 Eastman Chemical Company Self-corrugating laminates useful in the manufacture of thermoelectric devices and corrugated structures therefrom
US10439124B2 (en) * 2015-12-25 2019-10-08 Fujifilm Corporation Thermoelectric conversion module, heat conductive laminate, and method of producing thermoelectric conversion module

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3050402A (en) * 1959-07-22 1962-08-21 Grace W R & Co Method of packaging a foodstuff
US3497059A (en) * 1966-11-02 1970-02-24 American Packaging Corp Package and method for making same
US3522688A (en) * 1966-10-19 1970-08-04 Alkor Oberlikon Plastic Gmbh Method of enveloping a loaded pallet in a conforming plastic film
US3562999A (en) * 1969-05-28 1971-02-16 Scal Gp Condit Aluminium Method and container for packing flexible tubes

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3050402A (en) * 1959-07-22 1962-08-21 Grace W R & Co Method of packaging a foodstuff
US3522688A (en) * 1966-10-19 1970-08-04 Alkor Oberlikon Plastic Gmbh Method of enveloping a loaded pallet in a conforming plastic film
US3497059A (en) * 1966-11-02 1970-02-24 American Packaging Corp Package and method for making same
US3562999A (en) * 1969-05-28 1971-02-16 Scal Gp Condit Aluminium Method and container for packing flexible tubes

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3805473A (en) * 1971-03-25 1974-04-23 E Lidgard Packaging methods and structures
US4666749A (en) * 1986-01-17 1987-05-19 Mccurry Thomas M Covering for roll end-support panel
WO1994016955A1 (en) * 1993-01-20 1994-08-04 The Procter & Gamble Company Packaging assembly with improved stackability
US5566824A (en) * 1993-01-20 1996-10-22 The Procter & Gamble Company Packaging assembly with improved stackability
US5623812A (en) * 1994-10-14 1997-04-29 Transhield Technology Co., Llc Shrink wrap material and method for protecting articles
US6875712B2 (en) 2000-09-19 2005-04-05 Transhield Technology As Material for protecting articles having a nonwoven fabric bonded to a shrink film by an adhesive applied in a pre-determined pattern
US20020077015A1 (en) * 2000-09-19 2002-06-20 Todt Gregory L. Material for protecting articles having a nonwoven fabric bonded to a shrink film by an adhesive applied in a pre-determined pattern
US6562740B1 (en) 2000-09-19 2003-05-13 Transhield Technology As Material for protecting articles having a nonwoven fabric bonded to a shrink film by an adhesive applied to the film in a pre-determined pattern
US6696120B1 (en) 2000-10-12 2004-02-24 Transhield Technology As Shrink wrap material having reinforcing scrim and method for its manufacture
US7740149B2 (en) 2002-09-27 2010-06-22 Ropak Corporation Container sidewall strengthening apparatus and methods
US20050121348A1 (en) * 2003-12-09 2005-06-09 Clare Timothy P. Package insert and stackable package for articles
US8056798B2 (en) 2004-03-19 2011-11-15 Georgia-Pacific Corrugated Llc Reinforced fiberboard bulk container
US7604156B2 (en) 2004-03-19 2009-10-20 Georgia-Pacific Corrugated Llc Reinforced fiberboard bulk container
US20090001147A1 (en) * 2004-03-19 2009-01-01 Georgia-Pacific Corrugated Llc Reinforced fiberboard bulk container
US20050205652A1 (en) * 2004-03-19 2005-09-22 Georgia-Pacific Corporation Reinforced fiberboard bulk container
US20090258191A1 (en) * 2008-04-15 2009-10-15 Tredegar Film Products Corporation Shrink film laminates
WO2014176084A1 (en) * 2013-04-26 2014-10-30 Eastman Chemical Company Self-corrugating laminates useful in the manufacture of thermoelectric devices and corrugated structures therefrom
US9064994B2 (en) 2013-04-26 2015-06-23 Eastman Chemical Company Self-corrugating laminates useful in the manufacture of thermoelectric devices and corrugated structures therefrom
US10439124B2 (en) * 2015-12-25 2019-10-08 Fujifilm Corporation Thermoelectric conversion module, heat conductive laminate, and method of producing thermoelectric conversion module

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AU2856971A (en) 1972-11-09

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