US361641A - Apparatus for manufacturing heating and illuminating gas - Google Patents

Apparatus for manufacturing heating and illuminating gas Download PDF

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US361641A
US361641A US361641DA US361641A US 361641 A US361641 A US 361641A US 361641D A US361641D A US 361641DA US 361641 A US361641 A US 361641A
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gas
pipe
retort
steam
air
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/384Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts the catalyst being continuously externally heated

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  • the invention also contemplates the production of a superior article of carbureted hydrogen gas by subjecting the crude petroleum to successive generation, in the manner fully set forth hereinafter.
  • Figure 1 is a sectional view illustrating our apparatus.
  • Fig. 2 is a sectional view showing the manner of applying the gas-retorts to an ordinary heater.
  • the reference-numeral 1 denotes a pipe communicating with any suit- Serial No. 228,375. (No model.)
  • This pipe has a cock, 2, by which the inflow of air or steam may be regulated or wholly cut off.
  • a pipe, 3, entering the pipe 1, and communicating at its other end with a reservoir, 4, containing crude petroleum, said reservoir being elevated above the point of union of the two pipes, and the pipe 3 being preferably constructed with an elbow or return-bend, 5.
  • a second cock, 6, serves to regulate or shut off the flow of the mingled oil and air or steam through the pipe 1.
  • a retort, 7, is placed, having any suitable heating apparatus surrounding or partly surrounding the same.
  • the pipe 1 enters the top of said retort through a standpipe, 8.
  • the pipe 1 passes downward to the bottom of the retort, which is heated to a temperature that may range from 1,500 to 2,3.00 Fahrenheit, and never be less than the firstmentioned degree, discharging the oil and air or steam upon the heated bottom,heated to 1,000
  • Openingfrom the lid of the retort is a pipe,9 with which a horizontal section of piping, 10, communicates.
  • This section has a joint, :11, from which depends a siphon, 12, communicating with the said section.
  • the siphon-pipe discharges at the point 13, and may empty into any suitable receptacle adapted to receive Elie tar and other heavy products of distillaion.
  • the section 10 communicates with a stand-pipe, 14, which enters the lid of a second retort or superheater, 15, and, passing downward, opens a little above the bottom of said retort, to which the volatile products of generation yielded by the first retort are delivered.
  • a pipe, 16 Entering the top of the standpipe 14 is a pipe, 16, which passes down en-. tirely through the stand-pipe, then returns upon itself after traversing the second retort, passes up through a second stand-pipe, 17, and empties into a main, 18.
  • the pipe 16 is concentric with the two stand-pipes '14 and 17,and. communicates with any suitable reservoir by may be placed in the main 18; but ordinarily this will not be required.
  • the service-pipes are tapped into the main 18, and from the latter, also, may be led one or moreIpipes for supplying gas, by the combustion of which the retorts 7 and 15 are heated.
  • the vessel 4 being supplied with a liquid hydrocarbon, and the cocks being adjusted, the mingled oil and air or steam flows through the pipe'l and are discharged into the heated retort 7, where the oil is at once volatilized and aportion thereof completely decomposed, so as to produce at once carbureted hydrogen, which is already a fixed gas, requiring no subsequent treatment, except to improve it by additional heating.
  • the remaining product of volatilization is a hydrocarbon gas, which, together with the carbureted hydrogen and the heated air or steam, passes over into the section 10. Here a sufficient condensation takes place to eliminate the tar, em-
  • the gas enters the main 18, at or near the entrance of which it is mingled, when a fuel-gas is to be produced, with the'air, steam, or air and steam from the second pipe, 16, which is carried entirely through the retort 15, where the contents of said pipe are raisedto the proper temperature.
  • the retorts may be connected with any ordinary heater, 19, as in Fig. 2, the arrangement for the second retort or superheater being the same as that shown in Fig. 2.
  • the superheating of the volatilized gas in the manner described produces a gas of a high degree of purity and of increased illuminating power.
  • An apparatus for manufacturing carbureted hydrogen gas from oils consisting, essentially, of a vertical retort, a pipe for admitting a mixture of oil and steam or air into said retort, terminating in proximity to the bottom of the retort, a gas-discharge pipe, a second retort or superheater, a gas-inlet pipe terminating in proximity'to the bottom of said second retort, a gas-main at the top of the latter,

Description

(No Model.)
W. A. MYERS & S. H. ALTIGE.
APPARATUS FOR MANUFACTURING HEATING AND ILLUMINATING GAS. No. 361,641. Patented Apr. 19,1887.
I nu /7920219. WiZZz'wwt Q1. e lily6ii9 1 Manuela] hi6.
N. PETERS. Photn-Ulhognpher, Wmhmghm. u. c.
provide an apparatus adapted for use with an lowing is a specification.
UNITED STATES PATENT QFFICEO WILLIAM A. MYERS AND SAMUEL H. ALIICE, OF BOLIVAR, NEYV YORK.
APPARATUS FOR MANUFACTURING SPECIFICATION forming part of Letters Patent No. 361,641, dated April 19, 1887.
Application filed February 21, 1887.
To all whom it may concern:
Be it known that we, WILLIAM A. MYERs and SAMUEL H. ALTIon, citizens of the United States, residing at Bolivar, in the county of Allegany and State of New York, have invented new and useful Improvements in Apparatus for Manufacturing Illuminating-Gas and Heating and Fuel Gas, of which the fol- Our invention relates to an apparatus for manufacturing heating and illuminating gas from all kinds of oils, but more particularly from liquid hydrocarbons, such as crude petroleum; and the purpose thereof is to provide a simple mechanism whereby gas may be generated on any required scale, and wherein the hydrocarbon employed is not only fully utilized, and a larger percentage of gas produced, but the quality thereof is improved and the heavy products-such as tar, sulphur,and empyreumatic oils-are completely removed by gravity.
It is a further purpose of our invention to ordinary boiler or furnace, whereby the heat required to operate the same can be obtained from the gas produced by the apparatus,making the running of the boilers nearly automatic as long as the petroleum is supplied to the generator, the only heat from an extraneous source being that required to initiate the generation of gas in the retort.
The invention also contemplates the production of a superior article of carbureted hydrogen gas by subjecting the crude petroleum to successive generation, in the manner fully set forth hereinafter.
The invention consists in the process and apparatus hereinafter fully set forth,and definitely pointed out in the claims following this description. 7 v
In the accompanying drawings, Figure 1 is a sectional view illustrating our apparatus. Fig. 2 is a sectional view showing the manner of applying the gas-retorts to an ordinary heater.
In the said drawings, the reference-numeral 1 denotes a pipe communicating with any suit- Serial No. 228,375. (No model.)
able reservoir, from which air or steam, or
both mingled together, may be taken. This pipe has a cock, 2, by which the inflow of air or steam may be regulated or wholly cut off.
Situated at a point beyond the cock 2 is a pipe, 3, entering the pipe 1, and communicating at its other end with a reservoir, 4, containing crude petroleum, said reservoir being elevated above the point of union of the two pipes, and the pipe 3 being preferably constructed with an elbow or return-bend, 5. A second cock, 6, serves to regulate or shut off the flow of the mingled oil and air or steam through the pipe 1.
Beyond the cock 6 a retort, 7, is placed, having any suitable heating apparatus surrounding or partly surrounding the same. The pipe 1 enters the top of said retort through a standpipe, 8. The pipe 1 passes downward to the bottom of the retort, which is heated to a temperature that may range from 1,500 to 2,3.00 Fahrenheit, and never be less than the firstmentioned degree, discharging the oil and air or steam upon the heated bottom,heated to 1,000
Fahrenheit, or more.
Openingfrom the lid of the retort is a pipe,9 with which a horizontal section of piping, 10, communicates. This section has a joint, :11, from which depends a siphon, 12, communicating with the said section. The siphon-pipe discharges at the point 13, and may empty into any suitable receptacle adapted to receive Elie tar and other heavy products of distillaion.
Beyond the siphon the section 10 communicates with a stand-pipe, 14, which enters the lid of a second retort or superheater, 15, and, passing downward, opens a little above the bottom of said retort, to which the volatile products of generation yielded by the first retort are delivered. Entering the top of the standpipe 14 is a pipe, 16, which passes down en-. tirely through the stand-pipe, then returns upon itself after traversing the second retort, passes up through a second stand-pipe, 17, and empties into a main, 18. The pipe 16 is concentric with the two stand-pipes '14 and 17,and. communicates with any suitable reservoir by may be placed in the main 18; but ordinarily this will not be required.
The service-pipes are tapped into the main 18, and from the latter, also, may be led one or moreIpipes for supplying gas, by the combustion of which the retorts 7 and 15 are heated. The vessel 4 being supplied with a liquid hydrocarbon, and the cocks being adjusted, the mingled oil and air or steam flows through the pipe'l and are discharged into the heated retort 7, where the oil is at once volatilized and aportion thereof completely decomposed, so as to produce at once carbureted hydrogen, which is already a fixed gas, requiring no subsequent treatment, except to improve it by additional heating. The remaining product of volatilization is a hydrocarbon gas, which, together with the carbureted hydrogen and the heated air or steam, passes over into the section 10. Here a sufficient condensation takes place to eliminate the tar, em-
pyreumatic oils, and other residual products,
which are carried off by the siphon 12; hence the heated gas and air pass to the stand-pipe 14, by which they are delivered to the superheater or second retort, 15. In this retort the hydrocarbon gas and the air or steam passing over from the first retort, together with the carbureted hydrogen generated therein, are brought in contactwith the intensely-heated bottom of the superheater. This bottom is heated, like that of the first retort, to a degree of heat ranging from 1,500 Fahrenheit upward, whereby the hydrocarbon gas carried over from the first retort is decomposed again and converted into carbureted hydrogen. Leaving the latter, the gas enters the main 18, at or near the entrance of which it is mingled, when a fuel-gas is to be produced, with the'air, steam, or air and steam from the second pipe, 16, which is carried entirely through the retort 15, where the contents of said pipe are raisedto the proper temperature.
For the illumination ofdwellings the retorts may be connected with any ordinary heater, 19, as in Fig. 2, the arrangement for the second retort or superheater being the same as that shown in Fig. 2.
The superheating of the volatilized gas in the manner described produces a gas of a high degree of purity and of increased illuminating power. The air or steam or air and steam, as the case may be, entering through the pipe 1 into the retort 7, becomes decomposed, and is intimately mingled with the gaseous proretort, which at once causes a conversion, of
the mixture into a fixed carbureted hydrogen gas and into hydrocarbon gas, after which the products of generation are carried through a pipe in which the condensable or residual matters are collected, and the gases are delivered into a second retort or superheater, in order to be completely converted into carbureted hydrogen. In this superheater an additional supply of steam or air is also intensely heated by its passage through a pipe which runs through the superheater and discharges into a main or pipe leading directly to a gasometer; or said main may have the pipes of the consumption devices directly connected with the same.
In prior processes it has been found impossible to produce a fixed illuminating or heating gas from hydrocarbon oils by retort action alone, and it"has been found necessary to use scrubbers or washers for purifying the gas passing from the retorts. Our gas, after generation in the retorts and after having been charged with decomposed air or steam heated by passage through the superheater, is at once ready for consumption, and it no longer contains condensable matters.
It will be understood that when an illuminating-gas is to be the resultant product of our process the same must be fixed and not contain condensable matters, and this is accomplished by omitting the step of admitting air or steam into the gas-main, such admixture of steam or air with the fixed gas passing .from the last retort only taking place when the gas is to be used for supplying the furnace which heats the retorts, or any other furnace in which a gas is employed as fuel.
Having thus described our invention, what we claim is 1. An apparatus for manufacturing carbureted hydrogen gas from oils, consisting, essentially, of a vertical retort, a pipe for admitting a mixture of oil and steam or air into said retort, terminating in proximity to the bottom of the retort, a gas-discharge pipe, a second retort or superheater, a gas-inlet pipe terminating in proximity'to the bottom of said second retort, a gas-main at the top of the latter,
anda steam or air heating pipe'passing through the second retort and discharging into the gasmain at the top of said second retort, substantially as described.
2. The combination, with the retort, of the air or steam pipe having a communicating pipe leading from an oil-reservoir, a super heater connected to the retort by a horizontal In testimony whereof we affix our signatures .section of pipe, a siphon-pipe communicatinpresence of two witnesses.
ing with said section to receive the tar, and a second pipe conveying air or steam and trav- WILLIAM MYERS ersing the superheater and delivering its SAMUEL H; ALTIOE heated contents to be mingled with the super- Witnesses: heated gas at or near the entrance to the main, W. O. MCBRIDE,
substantially as described. CHAS. H. BROWN.
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