US3607394A - Novel pregelatinized starches and process for preparing same - Google Patents

Novel pregelatinized starches and process for preparing same Download PDF

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US3607394A
US3607394A US829083A US3607394DA US3607394A US 3607394 A US3607394 A US 3607394A US 829083 A US829083 A US 829083A US 3607394D A US3607394D A US 3607394DA US 3607394 A US3607394 A US 3607394A
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starches
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pastes
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Felix Joseph Germino
Gerald Donald Miller
Jerry Adam Moskaluk
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
    • C08B30/12—Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
    • C08B30/14—Cold water dispersible or pregelatinised starch

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  • Pregelatinized starches are prepared by pasting an aqueous slurry of a starch which contains at least 50 percent amylopectin at a temperature of at least 300 F, and then rapidly, preferably instantaneously, removing the water therefrom as by roll or spray drying.
  • the resultant products rapidly disperse in water to form smooth pastes which are characterized by low initial viscosity and minimal setback.
  • pregelatinized starches i.e. starches which have been gelatinized and dried and which will disperse when added to cold water to form pastes. They are generally prepared either by first gelatinizing an aqueous slurry of starch, as by heating it to its gelatinization temperature, and then instantaneously removing the moisture, as by means of a roll or spray drier, or, alternatively, by passing an aqueous slurry of granular (i.e. ungelatinized) starch through a suitable apparatus, e.g. a roll or spray drier, wherein the starch is simultaneously gelatinized and dried.
  • a suitable apparatus e.g. a roll or spray drier
  • pregelatinized starches which will form pastes of low viscosity are desirable; such products are customarily prepared by hydrolyzing the starch, as with acid or enzyme, prior to or simultaneously with the pregelatinizing treatment. Hydrolysis causes molecular degradation of the starch, that is to say, it breaks down the starch molecules; because of this the resultant pastes are not only low in viscosity but low in molecular weight as well.
  • setback Another feature of pastes prepared from ordinary pregelatinized starch is their tendency to increase in viscosity upon standing; this characteristic is generally referred to as setback.” conventionally, setback is minimized by derivatizing the starch, i.e. adding substituent groups to the molecule.
  • pregelatinized starches having the ability to disperse rapidly in cold water to form exceptionally smooth pastes, which pastes are characterized by low initial viscosity and exceptionally good viscosity stability (i.e. minimal setback). Furthermore, unlike conventional pregelatinized starches which have been subjected to hydrolysis to lower their paste viscosity, the starches of our invention are characterized by substantially no, or at most very slight, molecular degradation.
  • Another object is to prepare pregelatinized starches which will rapidly disperse in cold or warm water to form exceptionally smooth pastes of low viscosity.
  • An additional object is to treat starch in such a way that the molecules of same will be substantially undegraded, but pastes of the starch will nevertheless exhibit low viscosity and exceptionally good viscosity stability.
  • a granular starch which contains at least 50 percent amylopectin is slurried in water and pasted at a temperature of at least about 300 F., after which the water is instantaneously removed.
  • the starch can be any starch provided it contains at least about 50 percent amylopectin.
  • Cereal starches such as those derived from corn, wheat, barley, etc.; tuber starches, such as those obtained from potatoes, tapioca, or the like; and the waxy starches," e.g. waxy maize, waxy rice, and waxy sorghum, which consist entirely or substantially entirely of amylopectin, and are all suitable for the practice of the invention.
  • the high amylose" starches i.e.
  • starches which contain 60 percent amylose or more, as well as amylose itself, are not suitable, in that these starches produce products which form gels upon reconstitution with water, and gel formation is an undesirable characteristic in the applications for which the products of the invention find their greatest utility.
  • the starches can be modified and/or derivatized prior to the pasting treatment.
  • the only critical requirements for starches to be treated in accordance with the invention are (1) they must be granular, i.e. ungelatinized, (2) they must be capable of being gelatinized in water (for example, a starch which is so highly cross-linked that it will not undergo gelatinization could not be used), and (3) they must contain at least 50 percent amylopectin.
  • the instantaneous removal of the water after the high temperature pasting can be performed in any suitable apparatus, e.g. a drum drier, a spray drier, a belt drier, a foam mat drier, or the like, the only requirement being that the apparatus be capable of drying the starch paste very rapidly.
  • a drum drier e.g. a drum drier, a spray drier, a belt drier, a foam mat drier, or the like, the only requirement being that the apparatus be capable of drying the starch paste very rapidly.
  • the original slurry can contain up to about 35 percent starch solids (by weight, based on the weight of the total slurry).
  • the starch must be pasted at a temperature of at least about 300 F.
  • the only upper temperature limit is that at which substantial molecular degradation of the starch will take place, e.g. over about 450 F.
  • Temperatures of from about 315 F. to about 360 F. are preferred.
  • the paste It is very important that the paste not be permitted to cool to a point at which the starch begins to retrograde or becomes aggregated prior to removal of the water.
  • the temperature at which retrogradation or aggregation begins depends upon the solids content of the paste. For example, a 35 percent solids paste will begin to retrograde at about 190 F., while one of 12 percent solids will begin to retrograde at about -l50 F.
  • the paste be fed to the drier very quickly after the completion of the pasting step, because the longer it is held at a high temperature the greater is the likelihood of molecular degradation an-d/or crystallization.
  • the products because of their ability to reconstitute in cold water to form smooth pastes of relatively low viscosity, high molecular weight and minimal setback, are extremely useful as adhesives and as coatings and sizings for paper and textiles. It has also been observed that the reconstituted pastes have excellent film-forming properties, i.e., they will readily form films which exhibit excellent oil holdout and water holdout properties.
  • the products are also excellent iron oxide depressants in the calcium soap flotation process for concentrating iron ores.
  • the products of the invention are characterized by complete granular fragmentation, as contrasted with the conventional pregelatinized starches which contain a certain amount, usually about 10-15 percent, of intact granules.
  • pastes of starches prepared in accordance with the invention were substantially lower than those cooked at 212 F. and 250 F.
  • Blender at 4,000 r.p.m. prior to addition to the pulp. ln run 5 the alkaline starch dispersion was cooked at 100 C. for minutes prior to addition to the pulp.
  • Table ll sets forth the amounts of starch used in each run As can also be seen from the table, pastes of starches 5 (calculated on the basis of pounds of starch per ton of ore), prepared in accordance with the invention which were held and the analyses of the froth and concentrate portions of each for 24 hours increased only slightly in viscosity. r
  • EXAMPLE II An aqueous slurry at 25 percent solids of white milo starch 25 was pasted at 3350 F in a Steam injection cooker and from the percent iron recovery in the concentrates, ll. 18 mediately roll dried as in Example 1. The product was added to f P at 3 SFarch per ton of ore the starch of the at a of 26 percent sohds; the starfzh re.adlly dlspflsed to form a smooth 30 $112! has been subjected to extensive shearing in a blender or as paste The Brookfield vlscosny (at 20 'h 7200 regular starch used at the increased rate of 4 lbs. per ton. Ad-
  • Run 01 used a corn starch treated in accordance with further characterized by complete granular fragmentation and Example I, pasted at 340 F.
  • Runs 2 and 3 employed regular, substantially no molecular degradation, said starch having unmodified corn starch in two different amounts.
  • ln run 4 been prepared in accordance with the process of claim 1. regular unmodified corn starch was used, and the alkaline starch dispersion was homogenized for 5 minutes in a Waring

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  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
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Abstract

Pregelatinized starches are prepared by pasting an aqueous slurry of a starch which contains at least 50 percent amylopectin at a temperature of at least 300* F, and then rapidly, preferably instantaneously, removing the water therefrom as by roll or spray drying. The resultant products rapidly disperse in water to form smooth pastes which are characterized by low initial viscosity and minimal setback.

Description

United States Patent [72] Inventors Felix Joseph Germino 12414 83 rd Ave., Palos Park, 111. 60464; Gerald Donald Miller, 3621 Douglas Road, Downers Grove, Ill. 60515; Jerry Adam Moskaluk, 14500 Sawyer Ave., Midlothian,
in. 60445 Appl. No. 829,083 Filed May 29, 1969 Patented Sept. 21, 1971 NOVEL PREGELATINIZED STARCHES AND PROCESS FOR PREPARING SAME 5 Claims, No Drawings [1.8. CI 127/32, 75/2, 127/69 Int. Cl C131 1/08 Field of Search 127/28, 32, 69, 70, 71
OTHER REFERENCES Ward Pigman, ed., The Carbohydrates," 676, Academic Press, New York, 1957.
Primary ExaminerMorris O. Wolk Assistant Examiner-Sidney Marantz Attorneys Frank E. Robbins, Janet E. Price, Robert D.
Weist, Martha A. Michaels and Dorothy R. Thumler ABSTRACT: Pregelatinized starches are prepared by pasting an aqueous slurry of a starch which contains at least 50 percent amylopectin at a temperature of at least 300 F, and then rapidly, preferably instantaneously, removing the water therefrom as by roll or spray drying. The resultant products rapidly disperse in water to form smooth pastes which are characterized by low initial viscosity and minimal setback.
NOVEL PREGELATINIZED STARCHES AND PROCESS FOR PREPARING SAME This invention relates to cold water dispersible starch products and to a method for preparing same.
So-called pregelatinized starches, i.e. starches which have been gelatinized and dried and which will disperse when added to cold water to form pastes, have long been known to the art. They are generally prepared either by first gelatinizing an aqueous slurry of starch, as by heating it to its gelatinization temperature, and then instantaneously removing the moisture, as by means of a roll or spray drier, or, alternatively, by passing an aqueous slurry of granular (i.e. ungelatinized) starch through a suitable apparatus, e.g. a roll or spray drier, wherein the starch is simultaneously gelatinized and dried.
When an ordinary (i.e. unmodified and underivatized) starch is subjected to a conventional pregelatinizing treatment the product will, upon addition to cold (i.e. room temperature) water, form a smooth, relatively viscous paste. For certain applications, pregelatinized starches which will form pastes of low viscosity are desirable; such products are customarily prepared by hydrolyzing the starch, as with acid or enzyme, prior to or simultaneously with the pregelatinizing treatment. Hydrolysis causes molecular degradation of the starch, that is to say, it breaks down the starch molecules; because of this the resultant pastes are not only low in viscosity but low in molecular weight as well.
Another feature of pastes prepared from ordinary pregelatinized starch is their tendency to increase in viscosity upon standing; this characteristic is generally referred to as setback." conventionally, setback is minimized by derivatizing the starch, i.e. adding substituent groups to the molecule.
We have discovered a simple, rapid, and inexpensive method for preparing pregelatinized starches having the ability to disperse rapidly in cold water to form exceptionally smooth pastes, which pastes are characterized by low initial viscosity and exceptionally good viscosity stability (i.e. minimal setback). Furthermore, unlike conventional pregelatinized starches which have been subjected to hydrolysis to lower their paste viscosity, the starches of our invention are characterized by substantially no, or at most very slight, molecular degradation.
It is an object of the present invention to prepare cold water dispersible starches which will reconstitute to form pastes having low initial viscosity and minimal setback.
Another object is to prepare pregelatinized starches which will rapidly disperse in cold or warm water to form exceptionally smooth pastes of low viscosity.
An additional object is to treat starch in such a way that the molecules of same will be substantially undegraded, but pastes of the starch will nevertheless exhibit low viscosity and exceptionally good viscosity stability.
Other objects and advantages will be apparent from the specification and the appended claims.
Briefly, the process is as follows. A granular starch which contains at least 50 percent amylopectin is slurried in water and pasted at a temperature of at least about 300 F., after which the water is instantaneously removed.
The starch can be any starch provided it contains at least about 50 percent amylopectin. Cereal starches, such as those derived from corn, wheat, barley, etc.; tuber starches, such as those obtained from potatoes, tapioca, or the like; and the waxy starches," e.g. waxy maize, waxy rice, and waxy sorghum, which consist entirely or substantially entirely of amylopectin, and are all suitable for the practice of the invention. The high amylose" starches, i.e. those which contain 60 percent amylose or more, as well as amylose itself, are not suitable, in that these starches produce products which form gels upon reconstitution with water, and gel formation is an undesirable characteristic in the applications for which the products of the invention find their greatest utility. The starches can be modified and/or derivatized prior to the pasting treatment. The only critical requirements for starches to be treated in accordance with the invention are (1) they must be granular, i.e. ungelatinized, (2) they must be capable of being gelatinized in water (for example, a starch which is so highly cross-linked that it will not undergo gelatinization could not be used), and (3) they must contain at least 50 percent amylopectin.
The instantaneous removal of the water after the high temperature pasting can be performed in any suitable apparatus, e.g. a drum drier, a spray drier, a belt drier, a foam mat drier, or the like, the only requirement being that the apparatus be capable of drying the starch paste very rapidly.
The original slurry can contain up to about 35 percent starch solids (by weight, based on the weight of the total slurry). As stated before, the starch must be pasted at a temperature of at least about 300 F. The only upper temperature limit is that at which substantial molecular degradation of the starch will take place, e.g. over about 450 F. Temperatures of from about 315 F. to about 360 F. are preferred.
It is very important that the paste not be permitted to cool to a point at which the starch begins to retrograde or becomes aggregated prior to removal of the water. The temperature at which retrogradation or aggregation begins depends upon the solids content of the paste. For example, a 35 percent solids paste will begin to retrograde at about 190 F., while one of 12 percent solids will begin to retrograde at about -l50 F. Also, it is preferred that the paste be fed to the drier very quickly after the completion of the pasting step, because the longer it is held at a high temperature the greater is the likelihood of molecular degradation an-d/or crystallization.
The products, because of their ability to reconstitute in cold water to form smooth pastes of relatively low viscosity, high molecular weight and minimal setback, are extremely useful as adhesives and as coatings and sizings for paper and textiles. It has also been observed that the reconstituted pastes have excellent film-forming properties, i.e., they will readily form films which exhibit excellent oil holdout and water holdout properties. The products are also excellent iron oxide depressants in the calcium soap flotation process for concentrating iron ores.
Structurally, the products of the invention are characterized by complete granular fragmentation, as contrasted with the conventional pregelatinized starches which contain a certain amount, usually about 10-15 percent, of intact granules.
The following examples will illustrate the practice of the invention. They are intended for illustrative purposes only, and should not be construed as limiting the scope of the invention in any way.
EXAMPLE I A series of runs was made in which aqueous slurries, at 25 percent solids concentration by weight, of regular, unmodified corn starch were heated in a steam injection cooker to temperatures of from 212 F. to 355 F. until they were completely pasted. Immediately after pasting the products were passed over a 24 inch roll drier, operated at 2.6 rpm. and 100 lbs.
steam, the skin temperature of the rolls being 284 F. The
TABLE 1 Brooktield vis- Concentration Brookfield viscosity of reconol reconstituted cosity of reconstitutod pastes Pasting temp., pastes, weight stituted pastes after 24 hours at F. percent atF., cps. 150 F., cps.
Approximately.
As can be seen from Table l, pastes of starches prepared in accordance with the invention (cooked at temperatures of 300 F. and 355 F.) were substantially lower than those cooked at 212 F. and 250 F.
Blender at 4,000 r.p.m. prior to addition to the pulp. ln run 5 the alkaline starch dispersion was cooked at 100 C. for minutes prior to addition to the pulp.
Table ll sets forth the amounts of starch used in each run As can also be seen from the table, pastes of starches 5 (calculated on the basis of pounds of starch per ton of ore), prepared in accordance with the invention which were held and the analyses of the froth and concentrate portions of each for 24 hours increased only slightly in viscosity. r
IABLE 11 Percent Lb. starch Percent Percent Fe re- Run No. Corn starch used per ton ore Product weight Fe covery 1 Prepared according to lnvention- 3 Froth 25. 94 33. 65 15.93 Concentrate 74. ()6 62. 21 84. U7
2 Regular. 3 Frotli 51. 00 47. 75 44. 21 Concentrate. 4U. 00 62.71 55. 79
3 Regular 4 Froth 23. 90 30. 40 13. 23 Concentrate. 76. 10 62. 64 86. 77
4 Homogenlzed regular 3 Froth 21. 7O 28. 19 11. 24 Concentrate. 78. 30 6'2. 31 88. 76
5 Cooked regular 3 Froth 48. 72 46.73 41. 39 Concentrate- 51. 28 62. 88 58. 61
EXAMPLE II An aqueous slurry at 25 percent solids of white milo starch 25 was pasted at 3350 F in a Steam injection cooker and from the percent iron recovery in the concentrates, ll. 18 mediately roll dried as in Example 1. The product was added to f P at 3 SFarch per ton of ore the starch of the at a of 26 percent sohds; the starfzh re.adlly dlspflsed to form a smooth 30 $112! has been subjected to extensive shearing in a blender or as paste The Brookfield vlscosny (at 20 'h 7200 regular starch used at the increased rate of 4 lbs. per ton. Ad-
EXAMPLE I" vantages in the use of starch prepared in accordance with the invention are that less of it needs to be used as a depressant A 16 percent aqueous slurry of regular unmodified corn and that its dispersions do not need to be sheared extensively starch was pasted at 360 F. in a Votator indirect heat to be obtained in a useful form. exchanger. Immediately after pasting the product was dried in While the invention has been described in connection with a spray drier. A 25 percent solids paste was prepared in water specific embodiments thereof, it will be understood that it is at 110 F. The Brookfield viscosity of the paste was l26,000 capable of further modification, and this application is inc.p.s. tended to cover any variations, uses, or adaptations of the in- Th example was repeated using wheat h, waxy i 40 vention following, in general, the principles of the invention starch and potato starch with comparable results. In all cases and ing such departures from the present disclosure as the products rapidly dispersed in water to form smooth pastes come within known customal'y Practice in the to which which were characterized by low initial viscosity and minimal the invention pertains and as y be pp the essemial Setback features hereinbefore set forth, and as fall within the scope of the invention. EXAMPLE lV What is claimed is: This example illustrates the use of starch prepared in ac- Process for preparmga-prefgelanmzed Cvold water dlsper' slble starch product comprising. cordance with the invention in the concentration of lron ores. L heating an aqueous slurry f a granular r h, said granu- S tandard procedure for ore flotanon a lar starch containing at least 50 percent amylopectin, at a descnpilon ofwhlch was emPloyed temperature of at least about 300 F. for a time sufficient A 500-gram sample of iron ore lS pulped to 30 percent to paste completely Said Starchand solids in a batch laboratory conditioner. To this ls added a 2 thereafter rapidly removing substantially all of the percent starch dispersion prepared by stirring the starch in 0.5 moisture from the pasted starch N sodium hydroxide solution for 30 mlnutesat room tempera- 2. process of claim {wherein the moisture is removed by ture. The pH of the pulp and starch mixture is ad usted to 1 1.8 roll-drying the pasted starch. and the pulp is conditioned for 2 minutes. This is followed by process f claim 1 wherein the moisture is removed by 1-minute conditioning with calcium chloride (2 lbs. per ton Spray drying the pasted starch.
Ore) h 2 minutes Conditioning with Actihol FAQ 4. Process of claim 1 wherein said starch slurry is heated at a P The Conditioned P p is transferred to Fager- 6o temperaturewithin the range of between about 315 F. and gren laboratory flotation machine, diluted to 20 percent about 360 F solids, and floated for 5 minutes. The froth and the concen- 5, A l i i d Starch product hi h ill idl Irate are Weighed and yz fOrifOn Content disperse in water to form a smooth paste having low initial Five runs were made, employing different starches as folviscosity and excellent viscosity stability, said starch being lows. Run 01 used a corn starch treated in accordance with further characterized by complete granular fragmentation and Example I, pasted at 340 F. Runs 2 and 3 employed regular, substantially no molecular degradation, said starch having unmodified corn starch in two different amounts. ln run 4 been prepared in accordance with the process of claim 1. regular unmodified corn starch was used, and the alkaline starch dispersion was homogenized for 5 minutes in a Waring

Claims (5)

  1. 2. thereafter rapidly removing substantially all of the moisture from the pasted starch.
  2. 2. Process of claim 1 wherein the moisture is removed by roll-drying the pasted starch.
  3. 3. Process of claim 1 wherein the moisture is removed by spray drying the pasted starch.
  4. 4. Process of claim 1 wherein said starch slurry is heated at a temperature within the range of between about 315* F. and about 360* F.
  5. 5. A pregelatinized starch product which will rapidly disperse in water to form a smooth paste having low initial viscosity and excellent viscosity stability, said starch being further characterized by complete granular fragmentation and substantially no molecular degradation, said starch having been prepared in accordance with the process of claim 1.
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US4667654A (en) * 1985-07-10 1987-05-26 National Starch And Chemical Corporation Pulse combustion process for the preparation of pregelatinized starches
US4853114A (en) * 1988-04-05 1989-08-01 American Cyanamid Copany Method for the depressing of hydrous, layered silicates
EP0366898A1 (en) * 1988-09-12 1990-05-09 National Starch and Chemical Investment Holding Corporation Continuous coupled jet-cooking/spray-drying process and novel pegelatinized high amylose starches prepared thereby
US5188674A (en) * 1988-09-12 1993-02-23 National Starch And Chemical Investment Holding Corporation Continuous coupled jet-cooking/spray-drying process and novel pregelatinized high amylose starches prepared thereby
US5307938A (en) * 1992-03-16 1994-05-03 Glenn Lillmars Treatment of iron ore to increase recovery through the use of low molecular weight polyacrylate dispersants
US5435851A (en) * 1988-09-12 1995-07-25 National Starch And Chemical Investment Holding Corporation Continuous coupled jet-cooking/spray-drying process and novel pregelatinized high amylose starches and gums prepared thereby
US5641349A (en) * 1995-01-24 1997-06-24 National Starch And Chemical Investment Holding Corporation Water-based adhesives containing thermally-inhibited starches
US5718770A (en) * 1994-08-25 1998-02-17 National Starch And Chemical Investment Holding Corporation Thermally-inhibited pregelatinized granular starches and flours and process for their production
US5720822A (en) * 1995-06-07 1998-02-24 National Starch And Chemical Investment Holding Corporation Thermally-inhibited pregelatinized non-granular starches and flours and process for their production
US5830884A (en) * 1995-01-18 1998-11-03 National Starch And Chemical Investment Holding Corporation Pharmaceutical products containing thermally-inhibited starches
US5863341A (en) * 1994-06-21 1999-01-26 Miller; Ray Ramsay Method of preparing a starch adhesive and products of the method
US5871756A (en) * 1995-01-18 1999-02-16 National Starch And Chemical Investment Holding Corporation Cosmetics containing thermally-inhibited starches
US5932017A (en) * 1993-07-30 1999-08-03 National Starch And Chemical Investment Holding Corporation Thermally-inhibited non-pregelatinized granular starches and flours and process for their preparation
JP3079251B2 (en) 1997-03-12 2000-08-21 農林水産省農業研究センター所長 Wheat starch with new properties
US6221420B1 (en) 1993-07-30 2001-04-24 National Starch And Chemical Investment Holding Corporation Foods containing thermally-inhibited starches and flours
WO2001092401A3 (en) * 2000-06-01 2002-05-02 Staley Mfg Co A E Highly flexible starch-based films
US6451121B2 (en) 1993-07-30 2002-09-17 National Starch And Chemical Investment Holding Corporation Thermally-inhibited non-pregelatinized granular starches and flours and process for their preparation
US20020189607A1 (en) * 2001-03-27 2002-12-19 Opta Food Ingredients,Inc. Potato starch compositions and methods of making same
US20030029444A1 (en) * 2001-03-26 2003-02-13 Domenico Carbone Process for cooking/drying high-amylose starches
US6528088B1 (en) 2000-06-01 2003-03-04 A. E. Staley Manufacturing Co. Highly flexible starch-based films
US20050005928A1 (en) * 2001-12-21 2005-01-13 Rudolf Klingler Pregelatinized starches and processes for their production
US20050008677A1 (en) * 2003-04-14 2005-01-13 Fmc Corporation Delivery system of homogeneous, thermoreversible gel film containing kappa-2 carrageenan
US20050014852A1 (en) * 2003-04-14 2005-01-20 Fmc Corporation Homogeneous, thermoreversible gel containing reduced viscosity carrageenan and products made therefrom
US20050013847A1 (en) * 2003-04-14 2005-01-20 Fmc Corporation Delivery systems of homogeneous, thermoreversible alginate films
US20050019294A1 (en) * 2003-04-14 2005-01-27 Fmc Corporation Homogeneous, thermoreversible alginate films and soft capsules made therefrom
US20050019295A1 (en) * 2003-04-14 2005-01-27 Fmc Corporation Homogeneous, thermoreversible low viscosity polymannan gum films and soft capsules made therefrom
US20050019374A1 (en) * 2003-04-14 2005-01-27 Fmc Corporation Homogeneous, thermoreversible gel film containing kappa-2 carragenan and soft capsules made therefrom
US20050048185A1 (en) * 2003-04-14 2005-03-03 Fmc Corporation Delivery systems of homogeneous, thermoreversible low viscosity polymannan gum films
US6949256B2 (en) 2002-01-18 2005-09-27 Banner Pharmacaps, Inc. Non-gelatin capsule shell formulation
US20100330369A1 (en) * 2008-02-22 2010-12-30 Cargill Incorporated Pregelatinized starches as carrier materials for liquid components
WO2011000524A1 (en) 2009-07-03 2011-01-06 Cargill, Incorporated A particulate flavor delivery system, a method of making it and use thereof
US7887838B2 (en) 2002-01-18 2011-02-15 Banner Pharmacaps, Inc. Non-gelatin film and method and apparatus for producing same
WO2012119765A1 (en) 2011-03-09 2012-09-13 Cargill, Incorporated A powdered acid-loaded carrier material
WO2019115944A1 (en) 2017-12-13 2019-06-20 Roquette Freres Thickening and stabilising system of natural origin suitable, in particular, for preparing cosmetic products
WO2019202264A1 (en) 2018-04-17 2019-10-24 Roquette Freres Film-forming system with barrier effect, in particular against air pollution, of natural origin and for use in cosmetics
US10786819B2 (en) 2016-01-21 2020-09-29 Regents Of The University Of Minnesota Cationic flotation of silica and apatite from oxidized iron ores at natural pH
EP3797601A1 (en) * 2019-09-24 2021-03-31 Beneo, Remy Process for the preparation of pregelatinized starch and/or pregelatinized flour and pregelatinized starch and/or pregelatinized flour obtainable from said process
WO2021219967A1 (en) 2020-04-30 2021-11-04 Roquette Freres Plant-based egg alternative
US12133918B2 (en) 2021-10-01 2024-11-05 Griffin Gamma, Llc Partially pre-gelatinized cassava starch as pharmaceutical excipient

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