US358817A - Jacobs - Google Patents
Jacobs Download PDFInfo
- Publication number
- US358817A US358817A US358817DA US358817A US 358817 A US358817 A US 358817A US 358817D A US358817D A US 358817DA US 358817 A US358817 A US 358817A
- Authority
- US
- United States
- Prior art keywords
- light
- action
- exposed
- resinate
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920001195 polyisoprene Polymers 0.000 description 18
- WQYVRQLZKVEZGA-UHFFFAOYSA-N Hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 16
- 239000011248 coating agent Substances 0.000 description 16
- 238000000576 coating method Methods 0.000 description 16
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 14
- 238000005530 etching Methods 0.000 description 14
- 239000000126 substance Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 12
- 239000002904 solvent Substances 0.000 description 10
- 239000002253 acid Substances 0.000 description 8
- HEDRZPFGACZZDS-UHFFFAOYSA-N chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 8
- 150000007513 acids Chemical class 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 229910052573 porcelain Inorganic materials 0.000 description 6
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 239000004575 stone Substances 0.000 description 6
- 239000000899 Gutta-Percha Substances 0.000 description 4
- 229920000588 Gutta-percha Polymers 0.000 description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-N HF Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 4
- 240000000342 Palaquium gutta Species 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 239000000395 magnesium oxide Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 239000007800 oxidant agent Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000000976 ink Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/20—Exposure; Apparatus therefor
- G03F7/2022—Multi-step exposure, e.g. hybrid; backside exposure; blanket exposure, e.g. for image reversal; edge exposure, e.g. for edge bead removal; corrective exposure
Definitions
- This invention relates to reproduction by photography.
- the object is in'a novel, expeditious, and effective manner to produce upon a hard surface snch as that of glass, porcelain, metal, a lithographic stone, or the like-a represen tation, view, picture, image, or ornament, so that the surface will itself present a representation, view, picture, image, or ornament, or that impressions of such can be taken therefrom by known printing methods.
- the invention consists in preparing glass, porcelain, metals, lithographic stones, orother appropriate surfaces for production or reproduction by the application thereto of a solution of a resin-ate suitably strengthened, which after drying, after having portions of it exposed to light, and after being treated with a substance or with substances that will attack the portions which have been exposed to light, or will affect them, without attacking or affecting' the portions which have not been exposed to light, or with attack or action upon these in a less degree, or after being treated with a substance or with substances which will affect, attack, or remove the portions which have not been exposed to light, without affecting, attacking, or removing the portions which have been exposed to light, or with influence upon these in less degree, will present a representation, view, picture, image, or ornament, or a printingsurface thereof.
- the invention also consists in an object having its surfaces so prepared.
- the coating can be made more durable by the addition of caoutchouc, guitapercha, india-ruhber, or the solution in benzole of other suitable bodies to the resinate before the same is applied to the surface.
- I have also stated that when I Wish to produce the negative of an object I subject the prepared surface, alter suitable exposure, to the action of benzole, ether, bisulphide of carbon, chloroform, or other solvent, whereby those parts which have not been exposed to the action of light will be affected or removed without materially affecting the parts which have been exposed to light.
- I may prepare a printing surface without etching.
- I apply the coating of resinate and caoutchouc or the like and expose to light, as already described, and then subject the surface to the action of a solvent, by preference a mixture of benzole and ben zine. The photograph obtained may then be reproduced upon the application of fatty inks.
- a solvent by preference a mixture of benzole and ben zine.
- the photograph obtained may then be reproduced upon the application of fatty inks.
- all the surfaces so produced, be they in intaglio or in relief, are susceptible of reproduction for multiplication by galvano-plastic or other well-known processes.
Description
UNITED STATES PATENT OEEIcE,
ARMAND MULLER-JACOBS, OF NEW YORK, N. Y., ASSIGNOR TO THE UNIVERSAL COLOR COMPANY, OF NEW YORK.
PHOTOGRAPHlC REPRODUCTION.
SPECIFICATION forming part of Letters Patent No, 358.817, dated March 1, 1867.
Application filed November 27, 1886. Serial No. 220,095.
To all 1071 0112, it may concern.-
Be it known that I, ARMAND MULLER- JACOBS, a citizen of Switzerland, residing at New York, in the county of New York and State of New York, have invented certain new and useful Improvements in Photographic Reproduction; and I do hereby declare the following to be a full, clear, and exact descrip tion ofthe invention, such as will enable others skilled in the art to which it appertains to make and use the same. v
This invention relates to reproduction by photography.
The object is in'a novel, expeditious, and effective manner to produce upon a hard surface snch as that of glass, porcelain, metal, a lithographic stone, or the like-a represen tation, view, picture, image, or ornament, so that the surface will itself present a representation, view, picture, image, or ornament, or that impressions of such can be taken therefrom by known printing methods.
The invention consists in preparing glass, porcelain, metals, lithographic stones, orother appropriate surfaces for production or reproduction by the application thereto of a solution of a resin-ate suitably strengthened, which after drying, after having portions of it exposed to light, and after being treated with a substance or with substances that will attack the portions which have been exposed to light, or will affect them, without attacking or affecting' the portions which have not been exposed to light, or with attack or action upon these in a less degree, or after being treated with a substance or with substances which will affect, attack, or remove the portions which have not been exposed to light, without affecting, attacking, or removing the portions which have been exposed to light, or with influence upon these in less degree, will present a representation, view, picture, image, or ornament, or a printingsurface thereof.
The invention also consists in an object having its surfaces so prepared.
In an application for patent upon a new process of photography,filed October 23, 1886,
I have announcedthat certain resinates not soluble in water by exposure to light change their properties as to solubility and as to re (No specimens.)
sistance to bleaching and oxidizing agents and acids. different resin-ates differing in degree of change. I have also stated that the resinates not readily soluble in water are soluble in benzole and various other hydrocarbons, in ether, chloroform, and bisulphide of carbon, and are almost indifferent to the action of bleaching agentssuch as hypochlorite of sodium; but that after exposure to light they become more or less insoluble in the abovenamed solvents, and are effected by the bleaching agents. I have also stated that the resinates are applied to the surfaces for use in solution in the solvents above named. I have also stated that the coating can be made more durable by the addition of caoutchouc, guitapercha, india-ruhber, or the solution in benzole of other suitable bodies to the resinate before the same is applied to the surface. I have also stated that when I Wish to produce the negative of an object I subject the prepared surface, alter suitable exposure, to the action of benzole, ether, bisulphide of carbon, chloroform, or other solvent, whereby those parts which have not been exposed to the action of light will be affected or removed without materially affecting the parts which have been exposed to light. I have also stated that when I wish to produce the positive of an object I subject the prepared surface, after exposure to light, to the action of hypochlorite of sodium, oxidizing agents, alkalies, or acids, which will affect those parts of the surface which have been exposed to light without materially affecting the parts which have not been so exposed.
By the present invention, when a surface suitable for etching, coated by a resinate dissolved in benzole, bisulphide of carbon, &c., to which has been added a solution of guttapercha, caoutchouc, rubber, or gums, &c., has been exposed in parts to light, either the portions which have not been exposed to light or those which have been exposed to light may be etched without materially affecting the others.
I find when, with the addition of caoutchouc or the like, I apply the method described in my application filed October 23, 1886, to produce a negative that the parts which have not a suitable resinate, by preference the resinate of magnesia, add to it a solution of gutta-percha or rubber, then coat the surface of the substance employed with the mixture, expose it in parts to light, as desired, then subject it to the action of hypochlorite ofsodium which affects-or removes the resinate where exposed to light, and then to the action of hydrofluoric acid, which thus more readily etches the parts which have been exposed to light than the others. I can also etch on glass, porcelain, or thelikeby followingthe methodjustdescribed, omitting the use of hypochlorite of sodium; but the former procedure is preferable, as by the latter the etching may not be so perfect.
By another method I coat and expose the surface as above, then subject it to the action of any solvent of the resinate and rubbersuch as a mixture of benzine and benzole-- which affects or removes the portion of the coat which has not been exposed to light, and then to the action of the acid, which thus more readily etches those parts which have not been exposed to light than the others.
Of course other surfaces such as metals, lithographic stones, &c.can be etched in the same manner by using the appropriate acids.
The solution which I have found best adapted for coating the surfaces is as follows: one per cent. 0 caoutchouc, fifteen per cent. of resinate of magnesia, and eighty-four per cent. of henzole.
In some instances I may prepare a printing surface without etching. To do this Ifind the following method preferable: I apply the coating of resinate and caoutchouc or the like and expose to light, as already described, and then subject the surface to the action of a solvent, by preference a mixture of benzole and ben zine. The photograph obtained may then be reproduced upon the application of fatty inks. Of course all the surfaces so produced, be they in intaglio or in relief, are susceptible of reproduction for multiplication by galvano-plastic or other well-known processes.
Having thus fully described my invention, what I claim as new, and desire to'secure by Letters Patent, is-
l. The process of preparing a hard surface in suitable condition to be etched or for use to yield an impression without being etched, which consists in coating the surface with a solution of a suitable resinate strengthened by caoutchouc or the like, subjecting it in parts then to the action of light, and then to the action of an agent which will affect some parts of the coating more than others, substantially as described.
2. The new process of etching, which consists i-n coating an appropriate surface with a suitable resinate strengthened by caoutchouc or the like, subjecting it then in parts to the action of light, then to the action of an agent which will affect some parts ofthe coating more than others, and then to the action of an etching substance, substantially as described.
3. The new process of etching, which consists in coating an appropriate surface with a suitable resinate strengthened by caoutchouc orthe like, subjecting it in parts to the action of light, and then directly to the action of an etching substance, substantially as described.
4. Areproducing surface composed ofasuitable resinate and caoutchouc or the like, substantially as set forth.
In testimony whereof Iaffix my signature in presence of two witnesses.
ARMAND M I ILLER JACO BS.
Witnesses:
It. G. DYRENFORTH, J AS. M. LEHMAIER.
Publications (1)
Publication Number | Publication Date |
---|---|
US358817A true US358817A (en) | 1887-03-01 |
Family
ID=2427858
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US358817D Expired - Lifetime US358817A (en) | Jacobs |
Country Status (1)
Country | Link |
---|---|
US (1) | US358817A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3175908A (en) * | 1959-07-29 | 1965-03-30 | Kalle Ag | Production of relief printing plates |
-
0
- US US358817D patent/US358817A/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3175908A (en) * | 1959-07-29 | 1965-03-30 | Kalle Ag | Production of relief printing plates |
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