US3545442A - Bandaging and dressing material - Google Patents

Bandaging and dressing material Download PDF

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US3545442A
US3545442A US3545442DA US3545442A US 3545442 A US3545442 A US 3545442A US 3545442D A US3545442D A US 3545442DA US 3545442 A US3545442 A US 3545442A
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layer
fibers
material
surface
layers
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Dan B Wicker
James G Bennett Jr
Lowell G Ward
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HUYCK Corp A CORP OF NY
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Huyck Corp
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/48Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, E.G. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/00004Non-adhesive dressings
    • A61F13/00021Non-adhesive dressings characterized by the structure of the dressing
    • A61F13/00029Non-adhesive dressings characterized by the structure of the dressing made of multiple layers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, E.G. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F2013/00089Wound bandages
    • A61F2013/00217Wound bandages not adhering to the wound
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, E.G. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F2013/51002Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers with special fibres
    • A61F2013/51038Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers with special fibres being a mixture of fibres
    • A61F2013/51042Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers with special fibres being a mixture of fibres with hydrophobic and hydrophilic fibres
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, E.G. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F2013/51078Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers being embossed
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, E.G. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • A61F13/534Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad
    • A61F2013/53445Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad from several sheets
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, E.G. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • A61F13/534Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad
    • A61F13/537Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer
    • A61F13/53708Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer the layer having a promotional function on liquid propagation in at least one direction
    • A61F2013/53721Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium having an inhomogeneous composition through the thickness of the pad characterised by a layer facilitating or inhibiting flow in one direction or plane, e.g. a wicking layer the layer having a promotional function on liquid propagation in at least one direction with capillary means
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, E.G. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/53Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium
    • A61F13/539Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium characterised by the connection of the absorbent layers with each other or with the outer layers
    • A61F2013/53966Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the absorbing medium characterised by the connection of the absorbent layers with each other or with the outer layers by needling, sewing, blow-needling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/659Including an additional nonwoven fabric
    • Y10T442/664Including a wood fiber containing layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/659Including an additional nonwoven fabric
    • Y10T442/666Mechanically interengaged by needling or impingement of fluid [e.g., gas or liquid stream, etc.]
    • Y10T442/667Needled

Description

o United States. Patent [1113,545,442

[72] Inventors Dan B. Wicker [501 Field olSearch 128/155, Loudonvllle, New York; 156, 296; 28172.2; 156/148; 161/ 150, 157 James G. BennetgJr. Plttsfleld Massachusetts; Lowell G. Ward: East I 56] References cited Greenbush, New York UNITED STATES PATENTS U PP 398,593 3,285,245 11/1966 Eldredge etal 128/ 156 f d Kn 2 3,336,923 8/1967 Devaud l28/296X atente [73] Assignee Huyck Corporation Pnmary Exanzzner-Charles F. Rosenbaum Reamer, New Yak Attorney-W1 11am A. Rhmes a corporation of New York [54] BANDAGING AND DRESSING MATERIAL ABSTRACT This invention relates to medical dressin 8 10 Claims gnmwing Figs which are absorbent of body exudates, yet are made nonad- [52] US. 128/296, herent to bodyportions with which they are placed in contact 161/67, 161/150, 128/156, 156/148 by means of a foraminous contact layer having hydrophobic [51] Int. (1 A611 13/00 thermoplastic fibers.

PATENTEU DEC 8 I970 sum 10F 2 FIG.6.

FIE.

PATENTEIIUEC 8IIIIII I I 31543442 SHEET 2 OF 2 DELIVERY OF I CELLULOSE WADDING CARDING MACHINE I I I l I I RAYON WEB i I i I0 I I I3 WINDING RoLLER CARDING MACHINE IEI I FIGS. NEEDLING :I;.},I.. MACHINE II I II; he

I I I I II":'::: l3 i I i i I i I I I I IIII I ||l I II 1 HIUEIIHEIIIIEI'I' /8 I III :I 1}! :I {I -l I 11'!!! I I LAPPING I ROLLER CARRYING MACH'NE RAYON AND cELLuLosIc I LAMINATES EMBOSSING ROLLER 9 HOT ROLLER FILLED ROLLER BANDAGING AND DRESSING MATERIAL This invention relates to materials especially adapted for use as bandages or medical dressings and for sponges to be applied to open cuts or wounds of the human body. It involves a combination of layers of fibrous materials adapted to receive and absorb body fluids from an open cut or wound and so retain the same in relation to the cut or. wound as to enable ready removal of the bandage or dressing without injury to the cut or wound and to expedite the healing action of the same.

Various typesof bandaging' and dressing materials have been proposed heretofore, but none of these have involved the combination of features contemplated by the present invention for enabling the removal of such materials from the wound, with the exuded fluids effectively retained by the material without the danger of removing any part of the healing scab from the injured surface for replacement by a new section or strip of such material. I

For achieving the foregoing purposes the present invention envisions the provision in a relatively thin, flexible and soft, flat or contoured bandaging or dressing material of at least two, and preferably three, or possibly more, layers of different types of materials. All of these layers are preferably formed of fibers which may be interlocked by techniques other than weaving or knitting thereof into a continuous fabric. This greatly facilitates and renders more economical, the production of the final product. However, certain of the advantages of the invention can be achieved by the use of a woven or knitted gauze as one or more of the layers of the composite material adjacent one surface thereof.

More particularly, considering the invention as applied to a three-layered fibrous material, one of the layers is formed from fibers produced from a synthetic resinof a character capable of withstanding sterilizing treatments at temperatures required for this purpose, but capable of softening to a semifluid extent upon subjection to a temperature higher than that required for sterilization but lower than that which will deleteriously affect the other layers, as by scorching or the like. An excellent type of fiber for this purpose is formed of polypropylene, but other synthetic fibers may achieve the same purpose to a certain extent, as for example, polyvinylidene chloride which softens at. 240 F. to 280 F., and polyvinylidene dinitrile which softensand becomes sticky at about 340 F. It is important, however, that the fibers em,- ployed have properties of the character herein specified. The said higher temperature treatment of this synthetic fiber material, together with some pressure applied thereto, causes the synthetic fibers to bond and also serves to eliminate the projection of free fibers from, and to provide a smooth feel to its exposed surface, which is the intended to be applied to the wound, but without forming a continuous film surface that will eliminate, or objectionably reduce the number of capillary passages extending through such layer. In fact the heat treatment referred to serves toreduce the cross-sectional area of such passages and thus increases their ability to transmit fluid by capillary action.

t In accordance with the invention the layer referred to just above is formed of a synthetic resin which is hydrophobic and will therefore not absorb the moisture removed from the wound but will simply transfer it by capillary action and by the low hydrostatic pressure developed in the wound to the next layer of the material. Said next layer is highly desirably in the nature of a wadding formed of fibers highly capable of absorbing the exuded fluid from the wound and also capable of transmitting the fluid laterally to'cause it to be absorbed in all regions thereof. For this purpose, said layer may highly desirably be formed of cellulose fibers, derived from either soft or hard wood, preferably with the fibers disposed in relation to each other in the same manner as in a sheet of paper, but it may be formed from carded cotton fibers or other similar materials or by curlating or gametting or otherwise forming the fibers into wadding. It has good fluid absorption properties and tends to retain the majority of the fluid exuded from the wound and to distribute said fluid throughout the area of said layer.

If the amount of body fluid is such that it cannot be retained by the cellulosic wadding, during the interval between changing of the bandaging or dressing material, it may be delivered to a third layer, preferably formed of rayon. For best results, this is a carded web that is applied to the intermediate cellulosic layer by pressure, prior to the application of the firstmentioned synthetic resin layer. It is: preferably formed of rayon fibers having a length of between about 1 inch and 2 inches and a relatively small denier, i.e. around 3 denier. It can however, with some loss of advantage from its desirable properties, be replaced by a gauze formed of cotton or the like.

Where a three-layer structure such as that heretofore described is employed, the second layer may be used primarily for the purpose of holding thehighly absorbent fibers of the third layer in place so that they may be easily handled throughout the various steps of processing, such as those hereinafter described. In such a case, it is desirable that the material from which the second layer is formed should have the properties heretofore set forth with reference to it, in addition to that of providing a good carrier medium for the absorbent material. Thus, it is possible to practice this invention without the presence of what has heretofore been described as the material forming the second layer, by utilizing materials having the high absorbency and other characteristics herein described as characterizing the materials of the third layer, in combination with the first layer alone or in concert with other layers and the first layer. 7

It should also be pointed out that the most important characteristic of the material herein described for use in the third layer is absorbency, without limitation as to the physical form which it takes. Thus fibers of rayon or other synthetic material might be used, or a foamed or spongelike layer or any other material capable of absorbing body fluids in quantity.

It will be noted from the foregoing that the invention contemplates the highly preferred production of the final product without the necessity of forming any of the various components by weaving or knitting them into the formof a fabric or gauze, or the like. However as indicated above, certain advantages of the invention can be achieved through the use of a woven or knitted gauze as one layer of the composite fabric.

In the case of a three-layered construction, the second layer, madefrom material such as cellulose or cotton wadding, and the rayon or the like forming the third layer of the final product, may be overlapped and united to each other by the application of suitable pressure to produce a continuous web of the two layers. The synthetic resin lfiber layer may then be applied to the exposed surface of the cellulose layer by lapping a suitable number of layers of 'cardfed fibers of the same through the use of apparatus well known in the art of producing multiple-layer webs. Preferably six to ten thin layers of such carded synthetic fibers may be a lapped to the exposed surface of the cellulosic layer, as the latter with its united rayon layer or gauze is continuously advanced along a predetermined path, by passing and folding a continuous length of said carded, synthetic fibers back and forth across the path of advance of the cellulosic layer and the layer of rayon or the like.

The continuously advancing web of the three layers of different types of fibers is then passed through a needling mechanism, provided with reciprocating barbed needles which carry fibers of the synthetic layer down through the cellulose wadding and rayon or other selected types of layers. As a result of this some of the fibers of the resin layer are carried down through the other layers, to firmly unite the three layers together and improve the overall properties of the bandaging adapted to impart heat to the exposed surface of the synthetic resin fiber layer to raise its temperature to its softening point. When the synthetic resin fibers are formed of polypropylene the heated wher of the calendering apparatus may be maintained at a temperature of about 330 F. If other synthetic resin fibers are used, the temperature of the heated roller at this stage of the process may'be varied to impart sufficient heat to the fibers to soften them, without completely melting the same. This brings about a slight fusion of the resin fibers to such an extent a's'to produce a relatively smooth feel to its outer surface, with the elimination of any free projecting fibers and without closing off the capillary passages through said resin 'fiber layer provided by the disposition of the fibers thereof and by the action of. the barbed needles, and without damaging any of the other layers ofthe material.

' In the use of the foregoing web as a bandaging material the synthetic resin fiber layer, with its relatively smooth and comfortable-feeling exposed, surface, with no free projecting fibers, will be applied to the open cut or wound on the body of a person, with the other. layer 'o'r layers disposed outwardly thereof, while in the use of the material as a dressing it will preferably, but not necessarily, be folded over to apply the synthetic resin fiber layer against the body and also exposed on the outer face of the dressing, with the rayon or similar layer having surfaces in directly opposed relation and the cellulosic or like layer intermediate the two other, layers mentioned. In either case the hydrophobic synthetic fiber layer, with smooth exposed surface free from projecting fibers, will pass the body fluids, by capillary action and hydrostatic pressure, to the other layers and will thus guard against the removal of a portion of scab, that may be formed at the'surface of thewound, as the dressing is removed. The calendering of the material, with the polypropylene layer arranged-to engage the hot surface of one of the rolls, will serve to eliminate any free'fibers extending from the surfacethat will be applied to and become embedded in the wound. This will greatly minimize the entanglement with blood fibrils and the danger of removing any portion of the scab that has formed, or is in the process of formation, upon removal of the bandaging or dressing material.

Certain of the advantages of this invention may be obtained by subjecting the fibrous resin layer alone to a forming and heattreating operation such as that heretofore described, using a heat treatment technique whereby only one surface of the layer is elevated to the fusing temperature while under pressure. This may be accomplished by use of a pair of press rollers only one of which is heated to the fusing temperature or by use of a cloth carrier medium in contact with the side of the layer which faces away from the heated roller, or by other similar techniques which are known in the art for achieving the indicated purpose. By this means, the fibrous resin sheet will have one smooth surface of the quality and having the properties heretofore described as being desirable for nonadherent body contact and the other surface will still be fuzzy. In this formthe fibrous resin layer may later be combined with any of a wide variety of commonly used absorptive materials, such as cotton or rayon, with the smooth side of said layer toward the source of the body fluids and the absorptive material placed against the fuzzy side of the fibrous resin layer. The fibers extending'from the fuzzy side of thefibrous resin layer will then be intermingled with the absorptive material, thereby permitting the combination of components .to freely absorb large quantities of body fluid and at the same time the nonadherent features heretofore described will be obtained. I

' A further feature of the invention involves embossing of the exposed surface of the synthetic resin fiber layer to impart a smooth feel and a more attractive appearance to the latter. This is of particular importance in the use of the materials as a folded dressing for wounds, as will be apparent from the following further description of the invention.

I With the foregoing features and advantages of the invention ,in mind, a preferred embodimentof the invention will now be described in somewhat greater detail in connection with the accompanying drawings, in which:

FIG. 1 is a schematic view, on an enlarged scale, showing a barbed needle in relation to the three layers forming the bandaging material at the needling step of the process;

FIG. 2 is a cross-sectional view through the several layers of the material, on an enlarged scale, in the region of the opening provided by a barbed needle, this being taken along the line 2-2 of FIG. 3;

FIG. 3 is a plan view, on an enlarged scale, of a small section of the bandaging or dressing material; 7

FIG. 4 is an enlarged cross-sectional view through a portion of the material prior to theneedling operation thereon;

FIG. 5 is an enlarged cross-sectional view through a portion of the bandaging or dressing material folded over upon itself, as used for dressing material purposes;

FIG. 6 is a plan view, on an enlarged scale, of a small portion of the material, showing its appearance after it has been embossed in accordance with one possible aspect of the invention;

FIG. 7 is a schematic view illustrating the arrangement of apparatus employed in carrying out the initial portions of the process;

FIG. 8 is a similar schematic view showing the arrangemen of apparatus for carrying out further steps involved in the process, and

FIG. 9 is a schematic view, in elevation, of apparatus for carrying out still further steps of the process.

Referring now particularly to FIGS. 7-9 inclusive, the apparatus employed for carrying out the process of producing a preferred embodiment of the improved dressing or bandaging material will first be described. At 10 (FIG. 7) there is indicated a carding machine which receives the rayon fibers to be used in making one layer of the material, in accordance with the preferred embodiment of the invention. The fibers so employed are preferable about 1% inches in length and have a denier of about 3, but the length and denier of the fibers may be varied to a certain extent within the capabilities of the selected carding machine. These fibers, as indicated, may be formed into a web by a carding machine and are preferably 183 deposited in web form on an endless conveyor belt (not shown). As the rayon web is advanced in the direction indicated by the arrow in FIG. 7, it passes through a zone 11 in which the layer of cellulosic wadding or the like is applied to its upper surface. This layer is preferably formed of eithersoft or hard wood fibers having a length of between 1 and 5 millimeters formed into a continuous sheet on a paper making machine. It is preferably a rather denselayer, considerably more so than the rayon fiber layer. At the delivery station 11, such continuous web or sheet of the cellulosic wadding may be directed downwardly from a large supply roller to the upper surface of the rayon web, with the two layers being a'dvanced at the same speed. If the cellulose wadding is replaced by, or in the nature of, a cotton wadding, this may be produced on a carding machine similar to that used for therayoh .web, needled or otherwise compacted by pressure and delivered from such carding machine to the upper surface of the rayon web in the region 11. With respect to all of the various layers of the composite material, the preferred fiber lengths will depend somewhat upon the nature of the processing equipment used.

From the region 11 the 'two layers, namely the rayon web and the cellulosic wadding are delivered to a pair of rollers 12, only the upper one of which is shown in FIG. 7. A correspond ing roller is provided directly beneath the one indicated a'tl2 and the two rollers thus serve to compress the rayon weban d cellulosic wadding together to a certain extent, thus causing them to become laminated, with or without adhesive means for bonding them together. The lower roller cooperating with roller 12 may carry the conveyor belt on which the web and wadding are deposited, and this belt may then be retumed to the left end of the apparatus, at which a similar roller, maybe provided for supporting the endless belt; Any suitablemeans may be provided for driving the belt at the desired spee d. The

laminated layers of rayon web and cellulosic wadding are delivered to, a winding roller 13 which is rotated, in the direction indicated by the arrow, to wind a suitable length of this laminated material into a roll. In the course of such winding the fibers of the two layers will be pressed together further to insure interlocking of certain of their fibers.

Referring now to FIG. 8, the roll of the two layers wrapped about the winding roller l3 is suitably mounted in the frame structure of a machine for delivery of the rayon and cellulosic laminates in the direction indicated by the arrow 14. As the two layers are thus advanced, with the cellulosic wadding layer at the upper surface, there is deposited on the exposed face of the latter a batt of polypropylene fibers. This batt is produced by a carding machine 15 which delivers the not be closed off, but in fact are insured of and will be im proved in their capillarity and ability to transmit body fluid by hydrostatic pressure. In producing the desired form of the end product, it has been found desirable to urge the rollers 26 and 27 toward each other under a force of 100 pounds per linear inch of that portion of the rollers which are in contact with the material. V

The material leaving the calendering rollers may be delivered to a winding roller and thus constitute the final form of the dressing or bandaging material. Before such winding, however, the polypropylene layer should be cooled sufficiently to avoid any tendency of it to adhere to the next wrap of the material around the winding roller.

It has been found desirable, in some instances, to improve the appearance and feel. of the dressing or bandaging material by embossing the exposed surface of the polypropylene batt.

a length between 2 inches and 4% inches have been found particularly desirable, and a nominal denier between 1.5and 6, it

heated to a suitable temperature, preferably about 300 F.,

being recognized that in making synthetic fibers of a desired denier, the actual denier may vary somewhat. These carded fibers, as delivered along the path indicated by arrow 16, are lapped back and forth across the upper surface of the cellulosic layer of the laminate delivered from the roller 13. For this purpose a lapping machine, of known character, may be used to provide about six to eight layers of the carded polypropylene fibers to the surface of the cellulosic wadding in the region indicated at 18. From this point the three layers, with the polypropylene batt uppermost, are passed through the needling machine indicated at 19. This needling machine is provided with a plurality of barbed needles 20, of the character shownin FIG. I, the number of these needles employed and the frequency with which they are reciprocated in a vertical direction in relation to the rate of advance of the three layers of the material formed in the manner described above, should be such as to impart between about 100 and 200 needle penetrations per square inch of the material. In a highly satisfactory form of the desired product, about 140 needlings per square inch have been provided. The needling will produce the effect id indicated on an enlarged scale in FIG. 2; namely, it will carry portions of the polypropylene fibers 21 downwardly through the cellulosic fibers 22 and rayon fibers 23. This results in bonding the various layers more firmly together and also in providing further capillary passages through the material. Furthermore, by effecting the needling action in the direction indicated there is no danger of having fibers of the cellulose wadding or the rayon layers carried to the exposed surface of the synthetic resin layer. The needle openings thus formed are indicated at 24 in FIG. 3.

After passage of the three layers of the material through the needling machine they are advanced in the direction indicated by the arrow 25 (FIG. 9) to a calender-ing apparatus. This comprises a hot roller 26, which is in contact with the synthetic resin (polypropylene) layer 21 of the material while the rayon layer 23 cooperates with a lower roller 27 which is not heated and is preferably in the form of a filled roller, i.e. a solid nonmetallic roller formed of materials having low heat transfer properties.

In passing through the nip of the rollers 26 and 27 the three layers are pressed together, simultaneously with the heating of the outer surface of the polypropylene batt. It has been found desirable to employ a heated roller having a diameter of about 7 inches and a lower filled roller having a diameter of about 12 inches. These rollers are preferably rotated at such a speed as to cause the laminated material to travel at a rate of about 28 feet per minute. Roller 26 is preferably heated to a temperature of about 330 F which is sufficient to soften the engaged fibers of polypropylene and thus eliminate the projection of such fibers outwardly from the upper surface of the material, and in fact provide a quite smooth feel to such exposed surface. The temperature of roller 26, and the time during which the polypropylene fibers are in contact therewith, are such that the capillary passages through the polypropylene batt will For this purpose, as shown in FIG. 9, the laminated material after passing through the calendering zone may be passed between a pair of rollers 28 and 29. The upper roller 28 will be and will have its outer surface provided with any desired form of design to be embossed upon the upper surface of the polypropylene batt. As indicated in FIG. 6, such design may, for example, produce slight ridges 30 and 31 arranged in rectangular relation to each other and slightly depressed surfaces 32. r

When the material produced in accordance with this invention is to be used for bandaging purposes, a suitable length of the same will, after being sterilized by recognized procedures, be wrapped around the armor leg or the like in the region in which the wound exists. Insuch use of the material, the exposed surface of the polypropylene batt will be applied to the surface of the body.

If desired, a small section of the material of the present invention may have applied to its outer surface, i.e. the opposite side from the smooth synthetic fiber layer surface which contacts the body, an adhesive tape of conventional character adapted to retain the bandage in the desired location. The

resulting product would then be in the category of what is generally designated an adhesive dressing.

When the material is to be used for dressing purposes, it may also be used in such single layer form or it may be folded over, as indicated in FIG. 5, with the polypropylene batt hav ing its outer face exposed at both surfaces of the folded material. Thus this exposed face of the batt will be placed in contact with the wound being dressed and will also be exposed at the outer surface of the dressing. This provides a dressing having a smooth, comfortable feeling exposed surface, which is particularly attractive in appearance, and especially so if the polypropylene layer has been subjected to the embossing step described above. 7

While polypropylene fibers of the character above described have been found exceptionally well suited for the purposes of the invention, other synthetic resin fibers, such as those mentioned above, having the properties mentioned, may be used advantageously. The resin fibers should be of a hydrophobic character, should becapable of sterilization in ambient low-pressure steam without softening or unduly shrinking or deteriorating the fibers, and capable of being readily softened at a temperature below 400 F. by the calendering of the same as it is passed in. contact with a heated calendering roller.

We claim:

l. A multilayered structure for absorbing body fluids comprising a first layer forming one surface of said structure and being formed from fibers of a thermoplastic resin which is hydrophobic and fusible only at a temperature higher than that necessary to sterilize said structure, and a second layer formed from material which is absorptive, at least some of the fibers from saidfirst layer extending into the material of said second layer, substantially none of the component material of said second layer extending all the way through said first layer, the exposed surface of said first layer which faces away from said second layer having substantially no fibers projecting therefrom.

2. A bandaging or dressing material of the character set forth in clainil in which said first-mentioned layer is a batt of polypropylene fibers.

3. A bandaging or dressing material of the character set forth in claim 1 in which said, second-mentioned layer is formed of fibers selected from the group consisting of cellulosic, cotton and rayon fibers.

4. Abandaging or dressing material of the character set forth in claim 3 in which said second layer is formed of rayon fibers approximately I to 2 inches in length.

5. A bandaging or dressing material of the character set forth in claim 1 in which said first layer is formed of fibers of a denier between 1.5 and 6 and of a length between 1 and 8 inches.

6. A bandaging or dressing material of the character set forth in claim 1 in which said first layer has its fibers carded and lapped to provide6 to Slayers of the fibers in each region of the material.

7. -A bandaging or dressing material as set forth in claim 1, the exposed surface of said'first-mentioned layer being embossed.

8. A multilayered structure for absorbing body fluids comprising a first layer forming one surface of said structure and being formed from fibers of a thermoplastic resin which is hydrophobic and fusible only at a temperature higher than that necessary to sterilize said structure but lower than that at which any of the constituents of said structure will degrade, and a second layer formed from material which is absorptive and capable of being penetrated by fibers from said first layer, at least some of the fibers from said first layer being imbedded in said second layer, none of the component material of said second layer extending all the way through said first layer, the exposed surface of said first layer which faces away from said second layer having substantially no fibers projecting therefrom.

9. A bandaging or dressing material comprising a mu]- tilayered strip, the layer at one surface of said strip being formed of carded fibers of a synthetic resin which is hydrophobic and has a softening temperature well above 200 F. but below 400 F., the layer at the opposite surface of said strip being formed of fibers selected from at least one of the group consisting of rayon and cotton, and an intermediate layer being formed of a wadding of fibers of highly absorbent character, all of the layers of said strip being held together merely by the interlocking of the free fibers thereof and by needled fibers from the first mentioned layer extending through the others, the exposed surface of said synthetic resin fiber layer being smooth and free from projecting fibers.

10. A bandaging or dressing material of the character set forth in claim 9 in which said absorbent wadding layer is formed of wood fibers having a length of between about I and 5 mm.

US3545442A 1964-09-23 1964-09-23 Bandaging and dressing material Expired - Lifetime US3545442A (en)

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US3683912A (en) * 1970-04-28 1972-08-15 Kimberly Clark Co Absorbent tampon
US3695270A (en) * 1970-01-22 1972-10-03 Int Playtex Corp Sanitary tampon
US3703897A (en) * 1969-10-09 1972-11-28 Kendall & Co Hydrophobic non-adherent wound dressing
US3811445A (en) * 1970-01-22 1974-05-21 Int Playtex Corp Absorbent material and methods of making the same
US3824996A (en) * 1969-11-18 1974-07-23 R Carlisle Highly absorbent pressure dressing for wounds
US3834390A (en) * 1972-11-20 1974-09-10 Weck & Co Edward Combination neurosurgical sponge
US3886942A (en) * 1970-02-27 1975-06-03 Kimberly Clark Co Sanitary napkin
US3937223A (en) * 1974-04-19 1976-02-10 American Cyanamid Company Compacted surgical hemostatic felt
US4051848A (en) * 1976-03-01 1977-10-04 Levine Norman S Synthetic skin wound dressing
US4059114A (en) * 1976-05-12 1977-11-22 Minnesota Mining And Manufacturing Company Garment shield
USRE29766E (en) * 1975-05-07 1978-09-19 Poly-Wide, Inc. Method of and means for treating burn victims
US4128686A (en) * 1976-02-03 1978-12-05 William Kyle Management of incontinence
US4154889A (en) * 1974-08-19 1979-05-15 Phillips Petroleum Company Nonwoven fabric, method and apparatus for it's manufacture
US4162190A (en) * 1974-04-29 1979-07-24 Scapa-Porritt Limited Paper makers wet felts
US4193404A (en) * 1976-09-23 1980-03-18 Johnson & Johnson Stretchable and conformable pad
US4203435A (en) * 1977-02-10 1980-05-20 Firma Carl Freudenberg Wound dressing
US4214582A (en) * 1979-02-07 1980-07-29 The Kendall Company Surgical dressing
US4219019A (en) * 1979-02-07 1980-08-26 The Kendall Company Bandage
US4381611A (en) * 1977-10-21 1983-05-03 Phillips Petroleum Company Method and apparatus for absorbing moisture
US4469740A (en) * 1983-02-28 1984-09-04 Bailly Richard Louis Foam plastic material with moisture removing properties
US4480000A (en) * 1981-06-18 1984-10-30 Lion Corporation Absorbent article
US4502156A (en) * 1977-10-21 1985-03-05 Phillips Petroleum Company Apparatus for absorbing moisture
EP0151018A2 (en) * 1984-01-26 1985-08-07 JOHNSON & JOHNSON Absorbent laminates
US4537822A (en) * 1983-02-08 1985-08-27 Toyo Boseki Kabushiki Kaisha Three-layered fabric material
US4562110A (en) * 1981-08-18 1985-12-31 Tong David Philip Process for the production of alginate fibre material and products made therefrom
US4568341A (en) * 1982-03-10 1986-02-04 James G. Mitchell Absorbent pads, incontinence care products and methods of production
US4617326A (en) * 1984-03-14 1986-10-14 Landstingens Inkopscentral Lic Ekonomisk Forening Bacteria adsorbing composition
US4645757A (en) * 1979-06-21 1987-02-24 Landstingens Inkopscentral Lic Ekonomisk Forening Agent for preventing or treating infections in human beings and animals
US4655209A (en) * 1986-05-05 1987-04-07 Scott Douglas G Surgical dressing and packaging
US4667665A (en) * 1984-08-16 1987-05-26 Colin O'D. Offenhartz Non-occlusive burn and trauma dressing
US4699618A (en) * 1983-05-05 1987-10-13 Vereinigte Papierwerke, Schickedanz & Co. Fluff free tampon and method for making
WO1990013695A1 (en) * 1989-04-28 1990-11-15 Unilever Plc Absorbent cloth
US5171238A (en) * 1989-03-16 1992-12-15 The Transzonic Companies Absorbent pad with fibrous facing sheet
US5296290A (en) * 1984-01-26 1994-03-22 Johnson & Johnson Absorbent laminates
US5401267A (en) * 1993-05-12 1995-03-28 Kimberly-Clark Corporation Absorbent article having enhanced wicking capacity
US5437653A (en) * 1993-05-12 1995-08-01 Kimberly-Clark Corporation Absorbent article having two coapertured layers and a method of making the article
US5454800A (en) * 1993-05-12 1995-10-03 Kimberly-Clark Corporation Absorbent article
US5470326A (en) * 1991-07-26 1995-11-28 Mcneil-Ppc, Inc. Clean dry facing needled composite
US5556392A (en) * 1992-11-20 1996-09-17 Peaudouce Composite nonwoven material and application to any absorbent article of hygiene
US5810798A (en) * 1995-06-30 1998-09-22 Kimberly-Clark Worldwide, Inc. Absorbent article having a thin, efficient absorbent core
US5834385A (en) * 1996-04-05 1998-11-10 Kimberly-Clark Worldwide, Inc. Oil-sorbing article and methods for making and using same
US5879487A (en) * 1996-04-09 1999-03-09 Wearco Llc Absorbent material and method for making same
US6174594B1 (en) * 1986-01-28 2001-01-16 Aerospace Preforms Limited Shaped filamentary structures
US6206865B1 (en) 1995-11-13 2001-03-27 Kimberly-Clark Worldwide, Inc. Absorbent article having a cellulosic transfer layer
US6452062B1 (en) 1993-05-26 2002-09-17 Sca Hygiene Products Ab Composite nonwoven material and its application to any absorbent article of hygiene
DE202010003153U1 (en) 2010-03-04 2010-05-20 Neubauer, Norbert Incontinence pad
US20130067706A1 (en) * 2011-09-20 2013-03-21 Paul Y. Fung Method for making a fibrous absorbent material
CN103556399A (en) * 2013-11-08 2014-02-05 江苏丹毛纺织股份有限公司 Preparation method of special-shaped-surface acupuncture cotton
DE102012022756A1 (en) * 2012-11-22 2014-05-22 Karl Werner Wilke A surface antimicrobial patient support
US9402770B2 (en) 2011-12-09 2016-08-02 Covidien Antimicrobial non-adherent dressings and related methods therefor

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US4600620A (en) * 1982-08-13 1986-07-15 Lever Brothers Company Article suitable for wiping surfaces
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US7112712B1 (en) * 1999-11-10 2006-09-26 Protex Healthcare (Uk) Limited Dressing
GB201507134D0 (en) * 2015-04-27 2015-06-10 Medtrade Products Ltd Wound dressing

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Publication number Priority date Publication date Assignee Title
US3703897A (en) * 1969-10-09 1972-11-28 Kendall & Co Hydrophobic non-adherent wound dressing
US3824996A (en) * 1969-11-18 1974-07-23 R Carlisle Highly absorbent pressure dressing for wounds
US3695270A (en) * 1970-01-22 1972-10-03 Int Playtex Corp Sanitary tampon
US3811445A (en) * 1970-01-22 1974-05-21 Int Playtex Corp Absorbent material and methods of making the same
US3886942A (en) * 1970-02-27 1975-06-03 Kimberly Clark Co Sanitary napkin
US3683912A (en) * 1970-04-28 1972-08-15 Kimberly Clark Co Absorbent tampon
US3834390A (en) * 1972-11-20 1974-09-10 Weck & Co Edward Combination neurosurgical sponge
US4128612A (en) * 1974-04-19 1978-12-05 American Cyanamid Company Making absorbable surgical felt
US3937223A (en) * 1974-04-19 1976-02-10 American Cyanamid Company Compacted surgical hemostatic felt
US4162190A (en) * 1974-04-29 1979-07-24 Scapa-Porritt Limited Paper makers wet felts
US4154889A (en) * 1974-08-19 1979-05-15 Phillips Petroleum Company Nonwoven fabric, method and apparatus for it's manufacture
USRE29766E (en) * 1975-05-07 1978-09-19 Poly-Wide, Inc. Method of and means for treating burn victims
US4128686A (en) * 1976-02-03 1978-12-05 William Kyle Management of incontinence
USRE30972E (en) * 1976-02-03 1982-06-15 Nicholas Proprietary Limited Management of incontinence
US4051848A (en) * 1976-03-01 1977-10-04 Levine Norman S Synthetic skin wound dressing
US4059114A (en) * 1976-05-12 1977-11-22 Minnesota Mining And Manufacturing Company Garment shield
US4193404A (en) * 1976-09-23 1980-03-18 Johnson & Johnson Stretchable and conformable pad
US4203435A (en) * 1977-02-10 1980-05-20 Firma Carl Freudenberg Wound dressing
US4381611A (en) * 1977-10-21 1983-05-03 Phillips Petroleum Company Method and apparatus for absorbing moisture
US4502156A (en) * 1977-10-21 1985-03-05 Phillips Petroleum Company Apparatus for absorbing moisture
US4219019A (en) * 1979-02-07 1980-08-26 The Kendall Company Bandage
US4214582A (en) * 1979-02-07 1980-07-29 The Kendall Company Surgical dressing
US4645757A (en) * 1979-06-21 1987-02-24 Landstingens Inkopscentral Lic Ekonomisk Forening Agent for preventing or treating infections in human beings and animals
US4480000A (en) * 1981-06-18 1984-10-30 Lion Corporation Absorbent article
US4562110A (en) * 1981-08-18 1985-12-31 Tong David Philip Process for the production of alginate fibre material and products made therefrom
US4568341A (en) * 1982-03-10 1986-02-04 James G. Mitchell Absorbent pads, incontinence care products and methods of production
US4537822A (en) * 1983-02-08 1985-08-27 Toyo Boseki Kabushiki Kaisha Three-layered fabric material
US4469740A (en) * 1983-02-28 1984-09-04 Bailly Richard Louis Foam plastic material with moisture removing properties
US4699618A (en) * 1983-05-05 1987-10-13 Vereinigte Papierwerke, Schickedanz & Co. Fluff free tampon and method for making
EP0151018A2 (en) * 1984-01-26 1985-08-07 JOHNSON & JOHNSON Absorbent laminates
US5296290A (en) * 1984-01-26 1994-03-22 Johnson & Johnson Absorbent laminates
EP0151018B1 (en) * 1984-01-26 1989-03-22 JOHNSON & JOHNSON Absorbent laminates
US4617326A (en) * 1984-03-14 1986-10-14 Landstingens Inkopscentral Lic Ekonomisk Forening Bacteria adsorbing composition
US4667665A (en) * 1984-08-16 1987-05-26 Colin O'D. Offenhartz Non-occlusive burn and trauma dressing
US6174594B1 (en) * 1986-01-28 2001-01-16 Aerospace Preforms Limited Shaped filamentary structures
US4655209A (en) * 1986-05-05 1987-04-07 Scott Douglas G Surgical dressing and packaging
US5171238A (en) * 1989-03-16 1992-12-15 The Transzonic Companies Absorbent pad with fibrous facing sheet
WO1990013695A1 (en) * 1989-04-28 1990-11-15 Unilever Plc Absorbent cloth
US5470326A (en) * 1991-07-26 1995-11-28 Mcneil-Ppc, Inc. Clean dry facing needled composite
US5879344A (en) * 1992-11-20 1999-03-09 Peadouce Composite nonwoven material and its application to any absorbent article of hygiene
US5556392A (en) * 1992-11-20 1996-09-17 Peaudouce Composite nonwoven material and application to any absorbent article of hygiene
US5437653A (en) * 1993-05-12 1995-08-01 Kimberly-Clark Corporation Absorbent article having two coapertured layers and a method of making the article
US5454800A (en) * 1993-05-12 1995-10-03 Kimberly-Clark Corporation Absorbent article
US5401267A (en) * 1993-05-12 1995-03-28 Kimberly-Clark Corporation Absorbent article having enhanced wicking capacity
US6452062B1 (en) 1993-05-26 2002-09-17 Sca Hygiene Products Ab Composite nonwoven material and its application to any absorbent article of hygiene
US5810798A (en) * 1995-06-30 1998-09-22 Kimberly-Clark Worldwide, Inc. Absorbent article having a thin, efficient absorbent core
US6206865B1 (en) 1995-11-13 2001-03-27 Kimberly-Clark Worldwide, Inc. Absorbent article having a cellulosic transfer layer
US5834385A (en) * 1996-04-05 1998-11-10 Kimberly-Clark Worldwide, Inc. Oil-sorbing article and methods for making and using same
US5879487A (en) * 1996-04-09 1999-03-09 Wearco Llc Absorbent material and method for making same
DE202010003153U1 (en) 2010-03-04 2010-05-20 Neubauer, Norbert Incontinence pad
US8695185B2 (en) * 2011-09-20 2014-04-15 Mcneil-Ppc, Inc. Method for making a fibrous absorbent material
US9150988B2 (en) 2011-09-20 2015-10-06 Johnson & Johnson Consumer Inc. Method for making a fibrous absorbent material
US20130067706A1 (en) * 2011-09-20 2013-03-21 Paul Y. Fung Method for making a fibrous absorbent material
US9402770B2 (en) 2011-12-09 2016-08-02 Covidien Antimicrobial non-adherent dressings and related methods therefor
DE102012022756A1 (en) * 2012-11-22 2014-05-22 Karl Werner Wilke A surface antimicrobial patient support
DE102012022756B4 (en) * 2012-11-22 2016-11-03 Karl Werner Wilke A surface antimicrobial patient support and their use
CN103556399A (en) * 2013-11-08 2014-02-05 江苏丹毛纺织股份有限公司 Preparation method of special-shaped-surface acupuncture cotton

Also Published As

Publication number Publication date Type
DE1492362A1 (en) 1970-01-29 application
JPS4924432B1 (en) 1974-06-22 grant
DE1492362B2 (en) 1973-07-26 application
GB1130857A (en) 1968-10-16 application

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Owner name: HUYCK CORPORATION A CORP. OF NY.

Free format text: MERGER;ASSIGNOR:HUYCK CORPORATION (MERGED INTO) BTR FABRICS (USA) AND CHANGED INTO;REEL/FRAME:003927/0115

Effective date: 19810630