US3537923A - Booster ignition compositions for small arms weapon containing boron and boron compositions - Google Patents
Booster ignition compositions for small arms weapon containing boron and boron compositions Download PDFInfo
- Publication number
- US3537923A US3537923A US515512A US3537923DA US3537923A US 3537923 A US3537923 A US 3537923A US 515512 A US515512 A US 515512A US 3537923D A US3537923D A US 3537923DA US 3537923 A US3537923 A US 3537923A
- Authority
- US
- United States
- Prior art keywords
- rockets
- rocket
- casing
- propellant
- grain
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 15
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title description 5
- 229910052796 boron Inorganic materials 0.000 title description 5
- 235000015842 Hesperis Nutrition 0.000 description 86
- 235000012633 Iberis amara Nutrition 0.000 description 86
- 239000003380 propellant Substances 0.000 description 55
- 229910052751 metal Inorganic materials 0.000 description 26
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- 238000000034 method Methods 0.000 description 16
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- 239000000463 material Substances 0.000 description 13
- 238000010304 firing Methods 0.000 description 12
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- 238000004519 manufacturing process Methods 0.000 description 11
- 239000004033 plastic Substances 0.000 description 11
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- 229910000831 Steel Inorganic materials 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000010276 construction Methods 0.000 description 5
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- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 208000027418 Wounds and injury Diseases 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
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- 239000000843 powder Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical group CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- UOJVPTSUKIRXSU-UHFFFAOYSA-K Cl(=O)(=O)[O-].[B+3].Cl(=O)(=O)[O-].Cl(=O)(=O)[O-] Chemical compound Cl(=O)(=O)[O-].[B+3].Cl(=O)(=O)[O-].Cl(=O)(=O)[O-] UOJVPTSUKIRXSU-UHFFFAOYSA-K 0.000 description 3
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- 239000000126 substance Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- OLRXHZHVFRYMHO-UHFFFAOYSA-N [N+](=O)([O-])[O-].[K+].[B+3].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-] Chemical compound [N+](=O)([O-])[O-].[K+].[B+3].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[N+](=O)([O-])[O-] OLRXHZHVFRYMHO-UHFFFAOYSA-N 0.000 description 2
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- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 238000004080 punching Methods 0.000 description 2
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000272517 Anseriformes Species 0.000 description 1
- 208000010392 Bone Fractures Diseases 0.000 description 1
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- 241001463014 Chazara briseis Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
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- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910000711 U alloy Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
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- CNKHSLKYRMDDNQ-UHFFFAOYSA-N halofenozide Chemical compound C=1C=CC=CC=1C(=O)N(C(C)(C)C)NC(=O)C1=CC=C(Cl)C=C1 CNKHSLKYRMDDNQ-UHFFFAOYSA-N 0.000 description 1
- 210000003128 head Anatomy 0.000 description 1
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- 230000000977 initiatory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- VRNINGUKUJWZTH-UHFFFAOYSA-L lead(2+);dithiocyanate Chemical compound [Pb+2].[S-]C#N.[S-]C#N VRNINGUKUJWZTH-UHFFFAOYSA-L 0.000 description 1
- 231100000518 lethal Toxicity 0.000 description 1
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- 238000003754 machining Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
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- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
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- 229910052719 titanium Inorganic materials 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
- C06C9/00—Chemical contact igniters; Chemical lighters
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B33/00—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
- C06B33/12—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide the material being two or more oxygen-yielding compounds
- C06B33/14—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide the material being two or more oxygen-yielding compounds at least one being an inorganic nitrogen-oxygen salt
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02K—JET-PROPULSION PLANTS
- F02K9/00—Rocket-engine plants, i.e. plants carrying both fuel and oxidant therefor; Control thereof
- F02K9/95—Rocket-engine plants, i.e. plants carrying both fuel and oxidant therefor; Control thereof characterised by starting or ignition means or arrangements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F42—AMMUNITION; BLASTING
- F42B—EXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
- F42B1/00—Explosive charges characterised by form or shape but not dependent on shape of container
Definitions
- the invention relates to improvements in a booster material for igniting substantially instantaneously the full length of a perforated rocket propellant.
- the booster comprises a mixture of 36% potassium nitrate and 64% of a mixture of aluminum in fine grains with an oxide of a chemically weaker metal as approximately 53% of the formula plus about 40% boron chlorate, 2% boron (90-92% pure), and 5% nitrocellulose binder.
- This invention relates to miniature rockets suitable for anti-personnel use and other uses and it relates more particularly to a low cost, light weight self-propelled rocket of small dimension capable of attaining such high velocity as to enable it to be used as an extremely eflicient kinetic energy kill mechanism or for use as other weaponry.
- This invention relates to a novel ordnance weapon and methods for constructing the same.
- a small rocket is provided for use as an antipersonnel kinetic energy kill mechanism.
- a plurality of such miniature rockets may be packaged together in a firing tube so that many may be fired simultaneously, or a number of such rockets may be dispersed and fire from a carrier such as a shell, bomb, or missile.
- the rifle has been used as the standard small arms weapon. However, it suffers from a number of disadvantages. It is expensive to manufacture. The accuracy required in machining the barrel, and the precision required in the parts for feeding and aligning the bullet and cartridge, are costly such that providing a means for firing a bullet is considered to be relatively expensive. A rifle is heavy both in itself and with respect to its ammunition, and it requires considerable skill to manipulate with any degree of effectiveness. The length of the barrel and the precision and rifling embodied in the barrel lining obviously require the rifle to be of a size which makes concealment difficult, and calls for a rifle of substantial weight, thereby imposing burdens on personnel using it.
- the bullet has the undesirable characteristic of having its maximum velocity at the muzzle of the gun with continual deceleration thereafter, whereas one would prefer to have the maximum velocity in the probable target zone. Since it is necessary that a bullet must acquire its velocity from the expansion of gases while in the barrel of the rifle, and prior to ejection from the gun, it is essential for the proper design of a rifle to provide a barrel of suflicient length to enable full acceleration of the bullet before it emerges from the barrel. The barrel must be formed with suitable rifling to direct the bullet accurately at the time it is ejected from the barrel toward the target. The velocity of the rifle bullet from the very start is too low for maximum effectiveness since, using ordinary techniques, the velocity is about 2,800 feet per second.
- the rate of acceleration required to be effected within the length of the rifle barrel introduces a considerable amount of recoil in the rifle. The user is thereby exposed to a rather large kick-back which makes it diflicult to control the barrel and its effective use is limited to persons capable of absorbing the shock.
- CBR chemi cal, biological or radiological
- the rifle is subject to the deficiency that once the bullet is free of the barrel, it thereafter loses velocity such that maximum elfectiveness, from the standpoint of speed or velocity, occurs closest to the rifle, whereas at distances 200 to 300 yards from the rifle, the velocity of the bullet has decreased to such extent as to no longer have ultimate effectiveness.
- the launching device need not be fabricated of high strength, relatively heavy, accurately machined elements.
- the miniature rocket of this invention can be launched from any inexpensive and readily available device such as a soda straw, a cigarette, or any elongated tube suitable for imparting direction to the rocket. Because of the nonlimiting character of the launching device, as will hereinafter be described, full and complete concealment of the rocket and launcher becomes possible thereby to render rockets more effective as a protective device, or as an offensive/ defensive, or clandestine weapon of war.
- rockets are of such small dimension and weight, a series of rockets or a plurality of rockets can be housed within a single launching device for sequential firing, or for substantially simultaneous firing, for coverage over troop concentration area.
- the entire assembly weighs less than a fraction of a pound and occupies very little space.
- the rocket gathers speed by acceleration in flight, as distinguished from acceleration within the confined length of a rifle barrel, there is no resulting recoil or kick-back such that the rocket can be easily controlled and fired with very little, if any, previous training. It is only necessary for the operator to learn to aim the rocket weapon in the general direction of the target.
- the rockets continue to accelerate during flight, the maximum velocity will be achieved in the probable target area at a distance from the point of launch. It becomes possible, with the miniature rockets of this invention, to develop velocities which exceed 3500 and even 5000 feet per second with speeds of better than 3000 feet per second obtainable 200 to 300 feet from the point of launch. It is known that above certain projectile velocities that the kinetic energy of the projectile is a more important wound ballistic parameter than momentum. Because of the extremely high velocities of these miniature rockets, obtainable in the probable target area, they are very effective kinetic energy kill mechanisms.
- Rockets have never before been used as a purely anti-personnel weapon, mainly because they have been too large for such a use; but also because they have not been accurate enough, they could not be made small enough, and they did not fly fast enough. They have therefore only been used to deliver payloads.
- the rockets of the present invention are new and novel in that eminent scientists were very doubtful that the rockets could be made to fly reliably, nor that they could be made to fly fast enough for the intended use as an anti-personnel kinetic energy kill mechanism. These rockets produce new and unexpected results in that they have been made to fly fast enough for the intended use, and they are employed in an entirely new concept as a strictly anti-personnel weapon.
- This invention is thus limited to the important field of miniature rockets having a diameter within the range of to 1 inch and a length within the range of 1 to 24 inches and preferably to miniature rockets having a diameter of less than 4 inch and a length less than 6 inches.
- the invention is to be distinguished from such self-propelled rocketry as represented by rockets of considerably larger dimensions which are not designed for, and are impracticable and incapable of being used as antipersonnel kinetic energy kill mechanism.
- Miniature rockets of the type described have not been produced merely by sealing down rockets of substantially larger dimensions which are designed for non-equivalent use. There are a number of reasons advanced, by those skilled in the art, for the inability heretofore to produce small diameter finned rockets of high performance as antipersonnel kinetic energy kill mechanisms.
- Rockets of small diameter were believed subject to very low efiiciencies and very low specific impulse. This may have been the result of the inability to achieve uniform radial burning of the propellant whereby imbalances would develop in the thrust to introduce error in the direction of flight. Such non-uniform burning would also cause exposure of some portions of the motor casing to higher temperatures than other portions whereby it was necessary to make use of casings of greater wall thickness and weight to prevent case bursting. This results in inefiicient low performance rockets due to the added weight.
- Rocket cases of the small dimensions, stability, and tolerances contemplated by this invention were not available and were believed to be incapable of manufacture.
- the requirement is for uniform, balanced, thin walled casings capable of withstanding thermal load and shock, high aerodynamic heating, and high internal pressures and aerodynamic stresses, for high performance.
- a miniature rocket which is particularly effective against personnel as a kinetic energy kill mechanism.
- the miniature rockets of the present invention are extremely small by comparison with other rockets heretofore produced.
- the rockets are dimensioned to have a length within the range of 8 to .35 mm. and a diameter of 1 /2 to 3 mm. and weigh from 40 to 300 mg.
- Large numbers of rockets can be packaged in a launcher to form an assembly of low weight and small size. By firing a large number of such miniature rockets simultaneously from a launching tube, a shotgun effect can be achieved making it only necessary to point the launching tube in the general direction of the target.
- the weapon is particularly adaptable to use in guerrilla warfare and by unskilled military personnel.
- the maximum velocity can exceed 5000 feet per second and can be achieved within 50 yards of the firing point.
- a velocity of 3000 feet per second can be maintained as far as 200 yards from the firing point.
- the rockets of the present invention comprise an effective, inexpensive weapon of lightweight and small dimension which can be employed by unskilled personnel.
- a large num ber of such rockets can be carried by a bomb, missile, or shell for subsequent dispersion and firing to cover a large area.
- the overall length of the rocket is approximately 1.4" and the body is A in diameter.
- the nose of the rocket can be adapted to carry a payload such as a high explosive, or CBR (chemical, biological, or radiological) agent.
- CBR chemical, biological, or radiological
- the rocket can penetrate several layers of plasterboard, steel sheet, or wood of substantial thickness, and it is capable of bone fracture.
- the tubular casing can be formed by continuous extrusion of metal tubing of the desired small diameter and thin wall section. Conventional techniques of cutting to size, for the length desired, and shaping the leading end portion to the ogive desired, form a basic rocket case.
- the tubing can be closed at the forward end by any one of the typical metallurgical forming processes of impacting, spinning, swaging, or coining to form the nose.
- a unique and novel concept of this invention resides in the fabrication of the rocket casing of thin metal foil or sheet stock.
- a tubular rocket casing having an internal diameter of A; inch and a length of 1 /2 inches and a wall thickness of 0.002 inch can be fabricated of metal foil, having a width of 1 /2 inches and a thickness of 0.0003 inch, by winding the foil about a diameter core or mandrel to form six to seven layers which may be secured one to the other to provide a laminated structure.
- Such laminations may be joined into an integral casing by precoating the foil with a pressure-sensitive adhesive, a quick setting adhesive, or a heat setting adhesive, or by metal brazing, or gas welding, or by mechanical working for interfacial bonding.
- the multiple layers can be joined by electric or ultrasonic welding to produce a body having strength which exceeds the strength produced from a solid tube of the same metal.
- ultrasonic welding techniques which are fast and relatively inexpensive, a high strength tubular casing having an internal diameter of A3 inch, and a wall thickness of 0.002 inch, can be fabricated of 0.001 inch metal foil wound for two complete revolutions about a A; inch diameter mandrel.
- Tubular casings, with or without fins can also be formed by conventional techniques into tubular members of thicker wall section whereafter the wall sections can be scaled down to the desired dimension by conventional mechanical processes such as milling, chemical milling processes, or by electro-forming with the metal casing constituting one of the electrodes from which metal is taken into the electrolyte.
- a tubular casing of the desired dimension and mass can also be fabricated by electro-forming techniques, using such metals as nickel, to produce a casing of exceptionally high strength.
- a tubular casing of the desired dimension and mass can also be produced by impact extrusion. Use is made of a small billet of the desired metal and it is impacted with a male member while at ambient low or high temperature to effect extrusion of a cavity of the desired dimension followed by heat treatment and/or coining, if desired.
- tubular casing When formed of a plastic or resinous material, with or without fiberous or filler materials, the tubular casing can be fabricated, with or without fins, by injection, impact, pressure, or by transfer molding techniques.
- Tubular metal combustion chambers can be inserted inside the plastic body to contain the pressure rise of fast burning propellants, although they have not proven necessary in many designs.
- Deep drawing of metal casings in the order of 0.0015 inch in thickness or greater has been successfully practiced with a length to diameter ratio in excess of 9 to 1, particularly when use is made of special high production deep drawing machines, such as an eyelet machine.
- tubular rocket casings of the described dimensions can be fabricated of such materials as carbon steels, stainless steels, titanium, magnesium, aluminum and alloys of aluminum, brass, nickel, uranium alloys, plastics and filled, or loaded resinous or plastic materials.
- the nose of the rocket can be formed in various ways and the choice depends somewhat on the particular nozzle and fin configuration and/or structure to be used. If a nozzle is lightweight, e.g., formed directly as part of the casing, or is a lightweight insert, then a heavy nose is not required for proper balance and the nose can be formed simply as part of the casing by deep drawing, rolling, etc. But, if a heavy 'nozzle is formed or locked into the aft end of a rocket case or heavier than normal fins are used, then in order to counter-balance the weight, a heavy nose is required.
- a nose can be formed as a separate portion and locked into the tubular casing by metal forming techniques or the nose can be integral to the casing and weight added through the nozzle end. In the case of plastic rockets the weighted nose can be a needle pointed metal insert.
- the rockets of the present invention may be stabilized in flight in various ways, preferably by the use of fins. It is desirable to provide a rocket in which a plurality, suitably three or four, fins extend radially outward from the tail end portion of the casing to guide the rocket in flight. Three fins are easier to effect for mass production, and three finned rockets are more easily packed in clusters, but four finned rockets are more stable in flight.
- the rockets can be flown successfully without inhibitor if uniform longitudinal ignition of the propellant grain is achieved whereby the propellant grain burns uniformly and does not expose one portion of the interior of the rocket case to the heat of combustion or flame front before nearly all of the propellant is burned.
- Some inhibitors which were tried for the rockets of the present invention have been epoxys and polyester resins. These worked but had relatively poor bonding characteristics. Plain rubber cement was tried, but the solvent was objectionable due to its inflammability. Titanium dioxide in a latex soluble base paint worked relatively well and it is believed a magnesium oxide soluble base paint would also work.
- the best inhibitors have been cellulose acetate, in the form of a spray, dip, or tape, ethyl cellulose, and polyvinyl acetate, polyvinyl alcohol, or polyvinyl chloride. A very thin layer is all that is necessary and if it is in the form of a tape which will bond to the propellant it is perfectly acceptable providing it is thin enough. It is possible that many types of tapes having a pressure sensitive surface which will bind to a high explosive surface may prove adequate and a simple solution to the problems.
- the propellant grain is generally of a center burning configuration and is positioned inside the casing adjacent the outer wall extending radially inward terminating short of the central axis thereby providing a central bore through which the combustion gases issue during outward radial burning of the propellant from the inner surfaces of the case substantially simultaneously throughout the length.
- E-nd burning propellants have not proven very successful due to the localized heat concentrations on the case which causes burn through.
- the inside radial burners provide a layer of propellant which insulates the case from the flame front until the propellant is nearly expended. Inhibitor between the propellant and case also p ovides insulation. b t lowers the effective propellant 8 mass to total mass ratio.
- propellant which is of the double base type and which is quite similar in composition to powders identified commercially by such names as Bullseye, Red Dot, etc., with or without additives, although other homogeneous propellants can be used.
- the propellant is preferably employed as a single monolithic tubular grain of relatively thick walled cylindrical configuration dimensioned to have an outer diameter corresponding to the inner diameter of the bore of the casing so as to be received in close fitting coaxial relationship therein.
- the cylindrical section is formed into a tubular membar to provide a central bore for burning the grain radially outward while the combustion gases are exhausted in their entirety through the bore for passage rearwardly from the rocket through the nozzle whereby the rocket is driven in flight at an accelerating speed.
- the monolithic grain can be machined from a solid rod or it can be cast or extruded to the desired inside and outside diameters from a liquid or paste containing the powder particles in a suitable vehicle. It can be formed by hot pressing directly into the rocket casing whereby a preferred intimate mating relationship is made between the outer periphery of the propellant grain and the inner surfaces of the casing to minimize the necessity for having to utilize an inhibitor and adhesive at the interface. Micro extrusion techniques have been employed successfully in the preparation of propellants for high performance miniature rockets.
- the intimate compressive contact between the grain and easing enables the grain to rely on the casing for support substantially uniformly throughout its surface thereby to minimize breakdown of the grain under the extremely high pressures and temperatures and acceleration forces existing in flight,
- the grain is limited to progressive radial burning from the inside out for generation of uniform gaseous pressures in flight.
- the monolithic grain can be bonded to the casing by the use of a suitable adhesive which will adequately tie in the grain to the casing for support and which will also serve as a retardant or inhibitor to prevent burning of the grain at the outer wall.
- Nozzles can be formed in the rearward end portion of the casing by the metallurgical processes of impacting, rolling, spinning, swaging, or coining to provide a rocket casing which includes one end adapted to receive a nose piece, the tubular casing forming the combustion chamher, and the integrally formed nozzle. If nozzles are made in this way then it is possible to have a front loading rocket. Rockets can then be manufactured less noses and stockpiled with an assortment of desired noses such as steel needle points, CBR carrier, or high explosives, etc.,
- the nozzle can be separately formed of such materials as solid or powdered metals, plastics, ceramics, and/or synthetic resinous materials which are filled with such materials as asbestos, glass, metal, or other fibrous elements or fillers, depending upon the end use of the rocket, the rates of nozzle ablation desired, and the overall design specifications.
- Separately formed nozzles can be secured in position in the tail end portion of the tubular casing by means of cements, brazing, welding, such as ultrasonic welding, or by mechanical forming, such as crimping, rolling, or swaging.
- Rocket nozzles of the types described can also be formed very simply and inexpensively by the metallurgical process of punching flat sheets of metal, plastics, or other sheet material, to the desired outside diameter.
- the part or parts can be punched, with or without coining, to form a conical cavity as well as the port.
- Punch ing or piercing operations of the type described yield a divergent or expansion cone to give an economically formed and efiicient nozzle.
- the rocket can be fuzed by means which are only a few thousandths of an inch in diameter and are located within the cavity of the propellant grain, preferably extending to the forward end portion thereof. They ignite the grain uniformly longitudinally to enable the grain to burn efficiently and progressively radially outward.
- the fuzing of the rocket is extremely more difficult in miniature fin stabilized rockets of the type represented by the practice of this invention where it may be desirable for a finite amount of time to lapse between ignition of the fuze and burning of the propellant.
- Such delays in fusing are desirable when the rockets are clustered in bomblets, or other delivery vehicles, to enable the rockets to be dispersed from the carrier and aerodynamically stabilized before ignition. Delay times of several seconds or even minutes are sometimes desired for some miniature rocket weapon delivery and employment systems.
- a typical fuze can be made from a copper wire with a pyrotechnic coating, generally of a low ash material such as can be fabricated of propellant wool, granules, flakes, or powder. See copending applications SN. 92,963, Rocket Fuse, filed Mar. 2, 1961, and SN. 95,391, Ignition Method, filed Mar. 13, 1961.
- This type fuze has a time delay value which is controlled by the dimension, composition, and configuration of the fuze.
- the ignition of the rocket motor is effected by a booster which is located at the forward end of the grain and is the internal terminal of the fuze.
- Use can also be made of ignition means and an ignition train fuze system which burns at a predetermined rate through the bore of the grain from the nozzle end with the burning being maintained sufficiently cool or insulated from the propellant so as not to ignite the grain.
- electrical ignition can be used by employing small diameter enamel coated wires having the ends bared, twisted together, and embedded in a glob of booster.
- the booster is provided at the forward end of the grain as a part of the fuzing system. While being minute in size it is capable of quickly liberating a large amount of heat sufficient to uniformly and longitudinally ignite the grain.
- a special booster is used and is very important and a novel portion of the invention. It consists of a mixture of 36% boron potassium nitrate and 64% T hermit as approximately 53% of the formula plus about 40% boron chlorate, 2% boron (-92% pure), and 5% nitrocellulose binder. Thermit is the trademark name of a product known in the trade to be a mixture of aluminum in fine grains with an oxide of a chemically weaker metal, usually iron.
- the booster can be formed of small granules, flakes, or powder.
- a rocket can be lighted by a defiagrating fuze alone if it is hot and fast enough, but it must be very fast in order to light the propellant relatively simultaneously along its length to prevent subsequent case burn through and/or end burning from uneven ignition.
- the booster must be secured at the forward end of the grain within the combustion chamber. This prevents gases from the fuze from prematurely ejecting the booster out of the rocket and retains the booster in the combustion chamber for a time long enough for the propellant grain to start burning properly. Sometimes the fuze and/or booster Will eject or become ejected from the exhaust end of the rocket before full ignition has been achieved to cause the rocket to abort. Such losses may occur as the result of high acceleration during launch and burning. In order to prevent this from occurring the booster can be secured in the forward end of the combustion chamber by hooking the fuze over the grain to wedge it between the booster and the grain. Any other form of secure attachment will also serve the purpose.
- Inhibitor or insulation prevents the fuze running to the booster from prematurely igniting the propellant in a cone or end burning configuration. It is an important parameter that the rocket be ignited with pure uniform radial burning. With delay fuzes, the interior portion may be inhibited for only a part of the length of the interior surface.
- the booster generates a hot fire which sweeps back through the perforation along the grain penetrating the inhibitor layer and causing uniform ignition.
- the booster is in globular form, not necessarily in contact with the propellant grain. It must be of enough quantity to ignite the propellant through the inhibitor but not enough to detonate the propellant and thereby blow the case.
- the miniature rockets of this invention may be used for various purposes.
- the rocket is basically adapted for use as an antipersonnel kinetic energy kill mechanism in the light of the high velocities which are reached shortly after launch and which can be maintained at ranges of hundreds of yards.
- the head of the rocket can be provided with a high explosive charge to impart tremendous physiological shock to the victim. Only very small amounts are necessary to effect this.
- the payload can be formulated to include CBR agents, incendiary materials, smoke generating materials, chaff for radar detection and jamming, or the like.
- a plurality of such rockets can be packed in a bomblet preferably while the fins are folded circumferentially about the casing to conserve space.
- the rockets can also be packaged into containers or bomblets equipped with a flash or heat-generating mechanism which will ignite a flash or heat sensitive portion of the rockets.
- the flash sensitive compound is usually applied to the nozzle dis charge portion and has the fuze embedded therein. The compound receives the fire and ignites the fuze initiating the fire train which may have a delay element incorporated therein.
- This fiash sensitive compound a new and novel composition, is formed of a mixture of approximately 66% Potassium Chlorate and 34% Lead Thiocyanate as 7580% of the mix plus approximately 20% Zirconium powder and about 5% nitrocellulose binder. The proportions can be varied slightly without effecting the sensitiveness of the compound.
- the rocket casing is dimensioned to have a thickness of 0.005 inch.
- Such rockets can readily be accelerated to speeds of over 3300 feet per second in flight.
- the rocket can penetrate over twenty layers of A2 inch Cellotex with few, if any, distortions to the rocket body.
- penetration of the same thickness of Cellotex cannot be effected as the rocket body becomes crimped and bent on impact and sometimes tumbles. This causes a larger wound and increases antipersonnel effectiveness.
- a sharply pointed metal nose can be inserted onto the front end of the casing and fastened by crimp forming.
- the nozzle can be formed by the conventional process of swaging or coining the rearward end of the formed casing.
- the fins can be formed in advance of the nozzle by splitting or cutting the outer foil layer and turning the split portions outwardly to extend radially from the casing.
- a monolithic tubular shaped grain of a double base type propellant is extruded to proper form, dried, and inserted into the casing with the micro-pyrotechnic fuze and booster positioned inside the grain.
- the fuze can be insulated with plastic spaghetti or the grain inhibited on the interior surfaces for part of its length.
- the fuze is bared at the forward end and wrapped about the booster to anchor the fuze and booster within the propellant grain cavity during the unstable conditions of ignition and high acceleration.
- the fins can be collapsed circumferentially about the peripheral surface of the rocket casing so as to occupy less space in loading or packaging. Any curl that remains after launch will cause the rocket to roll during flight for less dispersion.
- a rocket of the type described can achieve a velocity at burnout exceeding 3500 feet per second.
- the front end of the casing can be processed by impacting or coning to increase the mass density and to form a very sharp pointed nose.
- the fins are preferably separately formed of steel and ultrasonically welded in place onto the outside of the casing at the rearward end portion thereof.
- the casing is heated to elevated temperature of about l00200 C. while the propellant grain is chilled to a temperature within the range of 0 to 80 C. and the propellant, dimensioned to be received in fitting relationship within the casing, is inserted in the casing without any inhibitor or adhesive.
- the present invention offers a large number of advantages over the prior art of small arms weapons, such as the rifle and bullets, in addition to those noted earlier.
- the jets maybe fired in various fashions.
- the igniter leads to a deflagrating fuse, which has a plurality of branches. Each of the deflagrating fuse branches leads into the central cavity of one of the rockets.
- the button When the button is depressed, the igniter is set off, in turn firing all of the rockets simultaneously.
- Other ignition devices can be used such as electrical bridge wires or heater wires.
- honeycomb sections for storage of a multiplicity of miniature rockets, for support of the rockets in separated relation in the honeycomb sections, or for sequential or simultaneous firing.
- the honeycomb formed of paper, metal foil, or the like, thus functions either as a carrier and/or a launcher in which the rockets are each separately housed in separated compartments within a minimum of space.
- the cases of the rockets can be made in a number of ways. For instance, they can be deep drawn, electro-formed or extruded. Further, they can be made in more than one piece.
- the tube portions can be made individually, and the nose portion separately formed and fastened thereto. Further, the fins may be either formed in place or may be made separately and attached to the case, or they may be extruded with the case.
- the cases are preferably made of a thin strong metal, such as stainless steel, they can be made of plastic or combinations of metals, plastics, and resins, e.g., a plastic case can be combined with a metal combustion chamber.
- the rockets of the present invention may be stabilized in flight in various ways including the use of the fins heretobefore described.
- One method of stabilization is to make the nose heavy as by filling it with metal.
- Another method is to use skewed or canted fins or vaned combustion chamber nozzles so that a rotational movement or spin will be imparted to the rocket in flight.
- various combinations of the stabilizing means can be employed.
- the rocket in the lancher is provided with short forward canard fins as well as rear fins.
- the launching tubes can be provided with packing material which serves the same purpose.
- compositions normally thought of as detonators can be employed as propellants and have the advantages of high density, high specific impulse, and high burning rates.
- the rockets of the present invention are well adapted for use by unskilled troops.
- the pattern formed by the rockets on leaving the launcher is such that accurate aiming is not necessary.
- the instructions for use are so simple that they can be given merely by cartoons printed on the launcher.
- a carrier for the rockets together with dispersal and firing means, they form excellent weapons for covering a target of large area, such as dispersed troops.
- they can be used as antiaircraft or underwater weapons and may be used to carry small payloads of CBR agents or high explosives.
- the rockets emit light for about the first 50 yards of their trajectory, they act as tracers aiding in aiming. Additional tracer material can be added to trace over the full range. From the foregoing it is obvious that there has been provided a unique small arms weapon, which can be manufactured in large quantities at low cost, which can be used by unskilled personnel, and which is highly lethal.
- the rockets of the present invention are of very small size and are of a different order of magnitude than the rockets heretofore proposed.
- Conventional rocket formulas do not apply to their performance so that they do not represent a mere scale down of existing rockets.
- the chamber pressure and burning rate formulas of conventional size rockets do not directly apply to them.
- the chamber pressure far exceeds the bursting strength of the case.
- a booster mixture for effecting uniform ignition of miniature rockets comprising a mixture of approximately 36% boron potassium nitrate and 64% of a mixture of aluminum in fine grains with an oxide of a chemically Weaker metal as approximately 53% of the formula plus 14 approximately 40% boron chlorate, 2% boron (90-92% 2,990,683 7/1961 Walden 149-38 X BENJAMIN R. PADGETT, Primary Examiner US. Cl. X.R.
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Description
fid States Patent Int. Cl. C06c 1/00 US. Cl. 149-22 1 Claim ABSTRACT OF THE DISCLOSURE The invention relates to improvements in a booster material for igniting substantially instantaneously the full length of a perforated rocket propellant. The booster comprises a mixture of 36% potassium nitrate and 64% of a mixture of aluminum in fine grains with an oxide of a chemically weaker metal as approximately 53% of the formula plus about 40% boron chlorate, 2% boron (90-92% pure), and 5% nitrocellulose binder.
This invention relates to miniature rockets suitable for anti-personnel use and other uses and it relates more particularly to a low cost, light weight self-propelled rocket of small dimension capable of attaining such high velocity as to enable it to be used as an extremely eflicient kinetic energy kill mechanism or for use as other weaponry.
This application is a divisional application of my copending application Ser. No. 435,780, filed Feb. 11, 1965, entitled Small Arms Weapon, which is a continuationin-part of application Ser. No. 141,237, filed Sept. 20, 1961, which was a continuation-in-part of application Ser. No. 61,017, filed Oct. 6, 1960, the latter two applications now abandoned.
This invention relates to a novel ordnance weapon and methods for constructing the same. According to the basic concept of the weapon, a small rocket is provided for use as an antipersonnel kinetic energy kill mechanism. In accordance with various embodiments of the invention a plurality of such miniature rockets may be packaged together in a firing tube so that many may be fired simultaneously, or a number of such rockets may be dispersed and fire from a carrier such as a shell, bomb, or missile.
Traditionally, the rifle has been used as the standard small arms weapon. However, it suffers from a number of disadvantages. It is expensive to manufacture. The accuracy required in machining the barrel, and the precision required in the parts for feeding and aligning the bullet and cartridge, are costly such that providing a means for firing a bullet is considered to be relatively expensive. A rifle is heavy both in itself and with respect to its ammunition, and it requires considerable skill to manipulate with any degree of effectiveness. The length of the barrel and the precision and rifling embodied in the barrel lining obviously require the rifle to be of a size which makes concealment difficult, and calls for a rifle of substantial weight, thereby imposing burdens on personnel using it. Further, the bullet has the undesirable characteristic of having its maximum velocity at the muzzle of the gun with continual deceleration thereafter, whereas one would prefer to have the maximum velocity in the probable target zone. Since it is necessary that a bullet must acquire its velocity from the expansion of gases while in the barrel of the rifle, and prior to ejection from the gun, it is essential for the proper design of a rifle to provide a barrel of suflicient length to enable full acceleration of the bullet before it emerges from the barrel. The barrel must be formed with suitable rifling to direct the bullet accurately at the time it is ejected from the barrel toward the target. The velocity of the rifle bullet from the very start is too low for maximum effectiveness since, using ordinary techniques, the velocity is about 2,800 feet per second. If velocities of 3,000 feet per second and higher can be achieved, the victim suffers severe shock and tissue damage as contrasted to mere penetration achieved by an ordinary rifle. Even less effectiveness is experienced in proportion to the distance the bullet travels from the rifle before striking a target. Although attempts have been made to obtain higher muzzle velocities for rifles, such attempts have invariably resulted in increased weapon weight and rapid erosion of the gun barrel.
Further, the rate of acceleration required to be effected within the length of the rifle barrel introduces a considerable amount of recoil in the rifle. The user is thereby exposed to a rather large kick-back which makes it diflicult to control the barrel and its effective use is limited to persons capable of absorbing the shock. Further, because of the high rate of acceleration and rotation of the bullet projected from the rifle, it is difficult to bond or join other elements with the bullet, such as CBR (chemi cal, biological or radiological) agents, which also must be easily disseminated in the target, for delivery with the bullet to a distant target. This factor therefore limits the rifle to uses for delivery of bullets and like payloads.
Still further, the rifle is subject to the deficiency that once the bullet is free of the barrel, it thereafter loses velocity such that maximum elfectiveness, from the standpoint of speed or velocity, occurs closest to the rifle, whereas at distances 200 to 300 yards from the rifle, the velocity of the bullet has decreased to such extent as to no longer have ultimate effectiveness.
In contrast to the rifle and bullet, self-propelled miniature rockets, to which this application is addressed, can he launched by the user with only a small initial velocity and unlike a rifle the launching device need not be fabricated of high strength, relatively heavy, accurately machined elements. Instead, the miniature rocket of this invention can be launched from any inexpensive and readily available device such as a soda straw, a cigarette, or any elongated tube suitable for imparting direction to the rocket. Because of the nonlimiting character of the launching device, as will hereinafter be described, full and complete concealment of the rocket and launcher becomes possible thereby to render rockets more effective as a protective device, or as an offensive/ defensive, or clandestine weapon of war.
Since the rockets are of such small dimension and weight, a series of rockets or a plurality of rockets can be housed within a single launching device for sequential firing, or for substantially simultaneous firing, for coverage over troop concentration area. The entire assembly weighs less than a fraction of a pound and occupies very little space.
Because the rocket gathers speed by acceleration in flight, as distinguished from acceleration within the confined length of a rifle barrel, there is no resulting recoil or kick-back such that the rocket can be easily controlled and fired with very little, if any, previous training. It is only necessary for the operator to learn to aim the rocket weapon in the general direction of the target.
Since the rockets continue to accelerate during flight, the maximum velocity will be achieved in the probable target area at a distance from the point of launch. It becomes possible, with the miniature rockets of this invention, to develop velocities which exceed 3500 and even 5000 feet per second with speeds of better than 3000 feet per second obtainable 200 to 300 feet from the point of launch. It is known that above certain projectile velocities that the kinetic energy of the projectile is a more important wound ballistic parameter than momentum. Because of the extremely high velocities of these miniature rockets, obtainable in the probable target area, they are very effective kinetic energy kill mechanisms. Rockets have never before been used as a purely anti-personnel weapon, mainly because they have been too large for such a use; but also because they have not been accurate enough, they could not be made small enough, and they did not fly fast enough. They have therefore only been used to deliver payloads.
The rockets of the present invention are new and novel in that eminent scientists were very doubtful that the rockets could be made to fly reliably, nor that they could be made to fly fast enough for the intended use as an anti-personnel kinetic energy kill mechanism. These rockets produce new and unexpected results in that they have been made to fly fast enough for the intended use, and they are employed in an entirely new concept as a strictly anti-personnel weapon.
These are but a few of the advantages capable of being derived by miniature self-propelled finned rockets which form the subject matter of this invention. Other advantages will become apparent hereinafter from the description of the invention.
This invention is thus limited to the important field of miniature rockets having a diameter within the range of to 1 inch and a length within the range of 1 to 24 inches and preferably to miniature rockets having a diameter of less than 4 inch and a length less than 6 inches. The invention is to be distinguished from such self-propelled rocketry as represented by rockets of considerably larger dimensions which are not designed for, and are impracticable and incapable of being used as antipersonnel kinetic energy kill mechanism.
Miniature rockets of the type described have not been produced merely by sealing down rockets of substantially larger dimensions which are designed for non-equivalent use. There are a number of reasons advanced, by those skilled in the art, for the inability heretofore to produce small diameter finned rockets of high performance as antipersonnel kinetic energy kill mechanisms.
Rockets of small diameter were believed subject to very low efiiciencies and very low specific impulse. This may have been the result of the inability to achieve uniform radial burning of the propellant whereby imbalances would develop in the thrust to introduce error in the direction of flight. Such non-uniform burning would also cause exposure of some portions of the motor casing to higher temperatures than other portions whereby it was necessary to make use of casings of greater wall thickness and weight to prevent case bursting. This results in inefiicient low performance rockets due to the added weight.
The forces existing, by reason of the rates of acceleration, were believed by others to tend to collapse the propellant and cause malfunctions, and the erosive burning of the propellant and expected to cause additional m lf nctions.
Since the burning gases are at temperatures in excess as the casing, nozzle, and the like parts might suffer from relatively instantaneous thermal loads thereby causing shock disintegration of the rocket components before burnout of the propellant.
Since larger finned rockets traveling at speeds of over 2000 feet per second suffer from aerodynamic heating, it was believed that a similar condition would occur in small rockets and that the amount of aerodynamic heating would be suflicient to introduce serious malfunctions due to the thin lightweight casing which is necessary if the rockets are to fly at high velocity.
It was also believed that miniaturization would increase the inconsistencies of ignition and burning which would cause still greater undesirable elfects on small rockets thereby to render them inconsistent and unreliable in use.
Experiences with inhibitors used in propellants for rockets of large dimension indicated an undesirable tendency by the inhibitors to inactivate a large proportion of the surface of the propellant so treated. In miniaturized rockets, it was thought that low performances and ineflicient utilization of propellant would occur by leaving large amounts of unburned propellant in the rocket combustion chamber.
Further, those skilled in the art were of the opinion that small accurately dimensioned propellant grains, and other components, could not be produced for eflicient use in miniature rockets.
It was believed that the small nozzles required for rockets of such small dimensions would be subject to a rate of ablation such as would cause loss of pressure and cesation of burning whereby the esential high acceleration rates could not be achieved or maintained. When the nozzle a'blates severely, or erodes erratically, the rocket is incapable of maintaining direction thereby creating a very erratic rocket with a resulting large course deviation.
It was also believed impractical to make use of a finned rocket since such thin fins would be required as would be unable to withstand the high stresses incurred during flight at speeds in excess of Mach 2.
Reliable pyrotechnic fuses and igniters of the small dimensions and operational certainty required for small rockets of the dimension to which this invention is addressed were not available and were believed to be technically beyond the skill of the art.
Rocket cases of the small dimensions, stability, and tolerances contemplated by this invention were not available and were believed to be incapable of manufacture. The requirement is for uniform, balanced, thin walled casings capable of withstanding thermal load and shock, high aerodynamic heating, and high internal pressures and aerodynamic stresses, for high performance.
It is an object of this invention to produce and to provide a method for producing miniature rockets having a length less than 24 inches, and more specifically in the order of 35 mm., and a diameter less than 1 inch and more specifically in the order of 3 mm, which are capable of construction in a simple and eflicient manner to overcome the many difliculties and problems confronting the manufacture and use thereof as previously described, and it is a related object to produce, and to provide for producing, miniature size rockets of the type described which are formed with an internal grain which is an inside-outside burner or burns uniformly radially from the inner surfaces radially outward to the casing for substantially complete combustion of the propellant, and which generates gaseous pressures at a rate for controlled acceleration of the rocket with little deviation in direction; and which can make use of a nozzle that ablates at a known and controllable rate for pressure control during burning of the propellant to achieve proper speed and direction in flight; which embodies suflicient strength to maintain the elements in the desired relationship in the assembly notwithstanding the large forces brought into play by the high rates of acceleration, the high temperatures and thermal shock to which the elements are exposed in use, and the high pressures and aerodynamic forces that exist during flight; which is capable of acceleration to velocities in excess of 5000 feet per second, and which is capable of impact speeds in excess of 2000 feet per second at ranges of 200 yards or more; which can be launched singly or in numbers from very simple and inexpensive launching devices; which can be concealed in use thereby to constitute an offensive, defensive, clandestine weapon; which is capable of use in the atmosphere or under water without loss of efiiciency or reliability; which can be launched in series or in clusters to achieve a shotgun effect for more effective coverage; which can be manufactured in a simple and inexpensive manner from a large variety of materials; which can be adapted for use with various types of payloads, and which has acceptable shelf life and can be packaged for shipment to distant locations in convenient and inexpensive packages for wider dissemination and application of use; and it is a still further object of this invention to produce and to provide new and improved means and devices for launching miniature rockets of the type described.
In accordance with the present invention, a miniature rocket is provided which is particularly effective against personnel as a kinetic energy kill mechanism. The miniature rockets of the present invention are extremely small by comparison with other rockets heretofore produced. Typically, the rockets are dimensioned to have a length within the range of 8 to .35 mm. and a diameter of 1 /2 to 3 mm. and weigh from 40 to 300 mg. Large numbers of rockets can be packaged in a launcher to form an assembly of low weight and small size. By firing a large number of such miniature rockets simultaneously from a launching tube, a shotgun effect can be achieved making it only necessary to point the launching tube in the general direction of the target. Since no particular skill is required, the weapon is particularly adaptable to use in guerrilla warfare and by unskilled military personnel. The maximum velocity can exceed 5000 feet per second and can be achieved within 50 yards of the firing point. A velocity of 3000 feet per second can be maintained as far as 200 yards from the firing point. Thus the rockets of the present invention comprise an effective, inexpensive weapon of lightweight and small dimension which can be employed by unskilled personnel. Similarly, a large num ber of such rockets can be carried by a bomb, missile, or shell for subsequent dispersion and firing to cover a large area.
In the embodiment described, the overall length of the rocket is approximately 1.4" and the body is A in diameter. If desired, the nose of the rocket can be adapted to carry a payload such as a high explosive, or CBR (chemical, biological, or radiological) agent.
With this type of rocket, velocities up to Mach 3 have been achieved at burnout. The rocket can penetrate several layers of plasterboard, steel sheet, or wood of substantial thickness, and it is capable of bone fracture.
In the preferred practice of this invention, novelty exists not only in the rocket per se having dimensions of the type previously described, but also in the means for construction of the rocket elements including the easing, the inhibitor and case bonding agent, the propellant grain, the ignition means, the nozzle, the nose piece and fins, and their method of assembly to form a rocket; also in the means for packaging the rocket for storage, shipment, and use, and the means for launching the rocket or a plurality of rockets, as the case may be, all as will hereinafter be described.
The tubular casing can be formed by continuous extrusion of metal tubing of the desired small diameter and thin wall section. Conventional techniques of cutting to size, for the length desired, and shaping the leading end portion to the ogive desired, form a basic rocket case.
The tubing can be closed at the forward end by any one of the typical metallurgical forming processes of impacting, spinning, swaging, or coining to form the nose.
A unique and novel concept of this invention resides in the fabrication of the rocket casing of thin metal foil or sheet stock. For example, a tubular rocket casing having an internal diameter of A; inch and a length of 1 /2 inches and a wall thickness of 0.002 inch can be fabricated of metal foil, having a width of 1 /2 inches and a thickness of 0.0003 inch, by winding the foil about a diameter core or mandrel to form six to seven layers which may be secured one to the other to provide a laminated structure. Such laminations may be joined into an integral casing by precoating the foil with a pressure-sensitive adhesive, a quick setting adhesive, or a heat setting adhesive, or by metal brazing, or gas welding, or by mechanical working for interfacial bonding. In the alternative, the multiple layers can be joined by electric or ultrasonic welding to produce a body having strength which exceeds the strength produced from a solid tube of the same metal. By the use of ultrasonic welding techniques, which are fast and relatively inexpensive, a high strength tubular casing having an internal diameter of A3 inch, and a wall thickness of 0.002 inch, can be fabricated of 0.001 inch metal foil wound for two complete revolutions about a A; inch diameter mandrel.
In the fabrication of the tubular casing by the described process of lamination of thin metallic foils, it is possible to incorporate thermal barriers in the casing between the foil layers, which, at the same time, increase the strength of the casing and the interbonding of the lamina. Such modifications may be achieved by interleaving with thin non-metallic films of low heat conductivity. Such construction not only increases the strength of the casing but it minimizes the effects of thermal shock and enables the rocket to run cool for its short burn time thereby enhancing its resistance to bursting from the internally generated high temperatures and pressures.
Tubular casings, with or without fins, can also be formed by conventional techniques into tubular members of thicker wall section whereafter the wall sections can be scaled down to the desired dimension by conventional mechanical processes such as milling, chemical milling processes, or by electro-forming with the metal casing constituting one of the electrodes from which metal is taken into the electrolyte.
A tubular casing of the desired dimension and mass can also be fabricated by electro-forming techniques, using such metals as nickel, to produce a casing of exceptionally high strength.
A tubular casing of the desired dimension and mass can also be produced by impact extrusion. Use is made of a small billet of the desired metal and it is impacted with a male member while at ambient low or high temperature to effect extrusion of a cavity of the desired dimension followed by heat treatment and/or coining, if desired.
When formed of a plastic or resinous material, with or without fiberous or filler materials, the tubular casing can be fabricated, with or without fins, by injection, impact, pressure, or by transfer molding techniques. Tubular metal combustion chambers can be inserted inside the plastic body to contain the pressure rise of fast burning propellants, although they have not proven necessary in many designs.
Deep drawing of metal casings in the order of 0.0015 inch in thickness or greater has been successfully practiced with a length to diameter ratio in excess of 9 to 1, particularly when use is made of special high production deep drawing machines, such as an eyelet machine.
The tubular rocket casings of the described dimensions can be fabricated of such materials as carbon steels, stainless steels, titanium, magnesium, aluminum and alloys of aluminum, brass, nickel, uranium alloys, plastics and filled, or loaded resinous or plastic materials.
The nose of the rocket can be formed in various ways and the choice depends somewhat on the particular nozzle and fin configuration and/or structure to be used. If a nozzle is lightweight, e.g., formed directly as part of the casing, or is a lightweight insert, then a heavy nose is not required for proper balance and the nose can be formed simply as part of the casing by deep drawing, rolling, etc. But, if a heavy 'nozzle is formed or locked into the aft end of a rocket case or heavier than normal fins are used, then in order to counter-balance the weight, a heavy nose is required. A nose can be formed as a separate portion and locked into the tubular casing by metal forming techniques or the nose can be integral to the casing and weight added through the nozzle end. In the case of plastic rockets the weighted nose can be a needle pointed metal insert.
The rockets of the present invention may be stabilized in flight in various ways, preferably by the use of fins. It is desirable to provide a rocket in which a plurality, suitably three or four, fins extend radially outward from the tail end portion of the casing to guide the rocket in flight. Three fins are easier to effect for mass production, and three finned rockets are more easily packed in clusters, but four finned rockets are more stable in flight.
The rockets can be flown successfully without inhibitor if uniform longitudinal ignition of the propellant grain is achieved whereby the propellant grain burns uniformly and does not expose one portion of the interior of the rocket case to the heat of combustion or flame front before nearly all of the propellant is burned.
Achieving uniform ignition with consistant regularity is difficult and therefor a very thin layer of inhibitor is generally employed to keep the heat from reaching the case. It was quickly determined that the standard inhibitors used for large rockets are unsatisfactory for miniature rockets in that they penetrate into the propellant and render a portion or layer of it useless. This unburned propellant is dead weight in small rockets, lowering the rockets efliciency, in addition to taking up valuable combustion chamber space which is at a premium when working with rockets of such small size. The standard inhibitors which are believed to have the effect of killing part of the propellant are those which use solvents of acetone, ether, ketone, methyl ethyl ketone, or other highly volatile solvents. Some inhibitors which were tried for the rockets of the present invention have been epoxys and polyester resins. These worked but had relatively poor bonding characteristics. Plain rubber cement was tried, but the solvent was objectionable due to its inflammability. Titanium dioxide in a latex soluble base paint worked relatively well and it is believed a magnesium oxide soluble base paint would also work. The best inhibitors have been cellulose acetate, in the form of a spray, dip, or tape, ethyl cellulose, and polyvinyl acetate, polyvinyl alcohol, or polyvinyl chloride. A very thin layer is all that is necessary and if it is in the form of a tape which will bond to the propellant it is perfectly acceptable providing it is thin enough. It is possible that many types of tapes having a pressure sensitive surface which will bind to a high explosive surface may prove adequate and a simple solution to the problems.
The propellant grain is generally of a center burning configuration and is positioned inside the casing adjacent the outer wall extending radially inward terminating short of the central axis thereby providing a central bore through which the combustion gases issue during outward radial burning of the propellant from the inner surfaces of the case substantially simultaneously throughout the length. E-nd burning propellants have not proven very successful due to the localized heat concentrations on the case which causes burn through. The inside radial burners provide a layer of propellant which insulates the case from the flame front until the propellant is nearly expended. Inhibitor between the propellant and case also p ovides insulation. b t lowers the effective propellant 8 mass to total mass ratio. Inside outside burning propellants have been tried and have been fairly successful because they burn so fast that the burn period is over and the pressure expended before the case is significantly effected by thermal shock and pressure load. These propellants are effective for short range rockets, but are not completely consistent due to case burn through problems.
In the practice of this invention, it is preferred to make use of a propellant which is of the double base type and which is quite similar in composition to powders identified commercially by such names as Bullseye, Red Dot, etc., with or without additives, although other homogeneous propellants can be used.
The propellant is preferably employed as a single monolithic tubular grain of relatively thick walled cylindrical configuration dimensioned to have an outer diameter corresponding to the inner diameter of the bore of the casing so as to be received in close fitting coaxial relationship therein.
The cylindrical section is formed into a tubular membar to provide a central bore for burning the grain radially outward while the combustion gases are exhausted in their entirety through the bore for passage rearwardly from the rocket through the nozzle whereby the rocket is driven in flight at an accelerating speed.
The monolithic grain can be machined from a solid rod or it can be cast or extruded to the desired inside and outside diameters from a liquid or paste containing the powder particles in a suitable vehicle. It can be formed by hot pressing directly into the rocket casing whereby a preferred intimate mating relationship is made between the outer periphery of the propellant grain and the inner surfaces of the casing to minimize the necessity for having to utilize an inhibitor and adhesive at the interface. Micro extrusion techniques have been employed successfully in the preparation of propellants for high performance miniature rockets.
In the assembly of the grain into the tubular rocket casing, use can be made of a special technique wherein the rocket casing is heated to an elevated temperature in the order of 100200 C. and the propellant grain is cooled to a lower temperature in the order of 0 to 80 C. at the time of insertion to take advantage of the high thermal coefficient of expansion of the grain whereby as the elements return to normal temperatures, the propellant grain becomes stressed in radial compression by the embracing rocket casing. This provides for a sealed relationship between the grain and the casing thereby preventing cracks, defects and passages in the grain for the flame front to proceed along to reach the case. This obviates some of the problems heretofore encountered in case burn through. In addition, the intimate compressive contact between the grain and easing enables the grain to rely on the casing for support substantially uniformly throughout its surface thereby to minimize breakdown of the grain under the extremely high pressures and temperatures and acceleration forces existing in flight, Thus the grain is limited to progressive radial burning from the inside out for generation of uniform gaseous pressures in flight.
Alternatively, the monolithic grain can be bonded to the casing by the use of a suitable adhesive which will adequately tie in the grain to the casing for support and which will also serve as a retardant or inhibitor to prevent burning of the grain at the outer wall.
Nozzles can be formed in the rearward end portion of the casing by the metallurgical processes of impacting, rolling, spinning, swaging, or coining to provide a rocket casing which includes one end adapted to receive a nose piece, the tubular casing forming the combustion chamher, and the integrally formed nozzle. If nozzles are made in this way then it is possible to have a front loading rocket. Rockets can then be manufactured less noses and stockpiled with an assortment of desired noses such as steel needle points, CBR carrier, or high explosives, etc.,
and the proper nose can be selected and inserted when the need is determined.
Unless the nozzle is integrally formed with and during manufacturing of the casing, as previously described, the nozzle can be separately formed of such materials as solid or powdered metals, plastics, ceramics, and/or synthetic resinous materials which are filled with such materials as asbestos, glass, metal, or other fibrous elements or fillers, depending upon the end use of the rocket, the rates of nozzle ablation desired, and the overall design specifications.
Separately formed nozzles can be secured in position in the tail end portion of the tubular casing by means of cements, brazing, welding, such as ultrasonic welding, or by mechanical forming, such as crimping, rolling, or swaging.
Rocket nozzles of the types described can also be formed very simply and inexpensively by the metallurgical process of punching flat sheets of metal, plastics, or other sheet material, to the desired outside diameter. The part or parts can be punched, with or without coining, to form a conical cavity as well as the port. Punch ing or piercing operations of the type described yield a divergent or expansion cone to give an economically formed and efiicient nozzle.
The rocket can be fuzed by means which are only a few thousandths of an inch in diameter and are located within the cavity of the propellant grain, preferably extending to the forward end portion thereof. They ignite the grain uniformly longitudinally to enable the grain to burn efficiently and progressively radially outward. The fuzing of the rocket is extremely more difficult in miniature fin stabilized rockets of the type represented by the practice of this invention where it may be desirable for a finite amount of time to lapse between ignition of the fuze and burning of the propellant. Such delays in fusing are desirable when the rockets are clustered in bomblets, or other delivery vehicles, to enable the rockets to be dispersed from the carrier and aerodynamically stabilized before ignition. Delay times of several seconds or even minutes are sometimes desired for some miniature rocket weapon delivery and employment systems.
A typical fuze can be made from a copper wire with a pyrotechnic coating, generally of a low ash material such as can be fabricated of propellant wool, granules, flakes, or powder. See copending applications SN. 92,963, Rocket Fuse, filed Mar. 2, 1961, and SN. 95,391, Ignition Method, filed Mar. 13, 1961. This type fuze has a time delay value which is controlled by the dimension, composition, and configuration of the fuze. The ignition of the rocket motor is effected by a booster which is located at the forward end of the grain and is the internal terminal of the fuze.
Use can also be made of ignition means and an ignition train fuze system which burns at a predetermined rate through the bore of the grain from the nozzle end with the burning being maintained sufficiently cool or insulated from the propellant so as not to ignite the grain. If a time delay is not necessary, electrical ignition can be used by employing small diameter enamel coated wires having the ends bared, twisted together, and embedded in a glob of booster. A layer of inhibitor /2 to 1 mil thick, which can be provided on the internal surface of the grain (inside the perforation), prevents the pyrotechnic fuse from prematurely igniting the propellant before the booster effects uniform ignition of the grain. Inhibitor is particularly necessary in the case of time delay fuzes to prevent premature ignition.
The boosteris provided at the forward end of the grain as a part of the fuzing system. While being minute in size it is capable of quickly liberating a large amount of heat sufficient to uniformly and longitudinally ignite the grain. A special booster is used and is very important and a novel portion of the invention. It consists of a mixture of 36% boron potassium nitrate and 64% T hermit as approximately 53% of the formula plus about 40% boron chlorate, 2% boron (-92% pure), and 5% nitrocellulose binder. Thermit is the trademark name of a product known in the trade to be a mixture of aluminum in fine grains with an oxide of a chemically weaker metal, usually iron. The booster can be formed of small granules, flakes, or powder. A rocket can be lighted by a defiagrating fuze alone if it is hot and fast enough, but it must be very fast in order to light the propellant relatively simultaneously along its length to prevent subsequent case burn through and/or end burning from uneven ignition.
The booster must be secured at the forward end of the grain within the combustion chamber. This prevents gases from the fuze from prematurely ejecting the booster out of the rocket and retains the booster in the combustion chamber for a time long enough for the propellant grain to start burning properly. Sometimes the fuze and/or booster Will eject or become ejected from the exhaust end of the rocket before full ignition has been achieved to cause the rocket to abort. Such losses may occur as the result of high acceleration during launch and burning. In order to prevent this from occurring the booster can be secured in the forward end of the combustion chamber by hooking the fuze over the grain to wedge it between the booster and the grain. Any other form of secure attachment will also serve the purpose.
Inhibitor or insulation prevents the fuze running to the booster from prematurely igniting the propellant in a cone or end burning configuration. It is an important parameter that the rocket be ignited with pure uniform radial burning. With delay fuzes, the interior portion may be inhibited for only a part of the length of the interior surface. The booster generates a hot fire which sweeps back through the perforation along the grain penetrating the inhibitor layer and causing uniform ignition. The booster is in globular form, not necessarily in contact with the propellant grain. It must be of enough quantity to ignite the propellant through the inhibitor but not enough to detonate the propellant and thereby blow the case.
The miniature rockets of this invention may be used for various purposes. The rocket is basically adapted for use as an antipersonnel kinetic energy kill mechanism in the light of the high velocities which are reached shortly after launch and which can be maintained at ranges of hundreds of yards. The head of the rocket can be provided with a high explosive charge to impart tremendous physiological shock to the victim. Only very small amounts are necessary to effect this. The payload can be formulated to include CBR agents, incendiary materials, smoke generating materials, chaff for radar detection and jamming, or the like.
A plurality of such rockets can be packed in a bomblet preferably while the fins are folded circumferentially about the casing to conserve space. The rockets can also be packaged into containers or bomblets equipped with a flash or heat-generating mechanism which will ignite a flash or heat sensitive portion of the rockets. The flash sensitive compound is usually applied to the nozzle dis charge portion and has the fuze embedded therein. The compound receives the fire and ignites the fuze initiating the fire train which may have a delay element incorporated therein. This fiash sensitive compound, a new and novel composition, is formed of a mixture of approximately 66% Potassium Chlorate and 34% Lead Thiocyanate as 7580% of the mix plus approximately 20% Zirconium powder and about 5% nitrocellulose binder. The proportions can be varied slightly without effecting the sensitiveness of the compound.
In the above described example, the rocket casing is dimensioned to have a thickness of 0.005 inch. Such rockets can readily be accelerated to speeds of over 3300 feet per second in flight. When traveling at a speed of 2300 to 2700 feet per second, the rocket can penetrate over twenty layers of A2 inch Cellotex with few, if any, distortions to the rocket body. When traveling at a speed greater than 2700 feet per second, penetration of the same thickness of Cellotex cannot be effected as the rocket body becomes crimped and bent on impact and sometimes tumbles. This causes a larger wound and increases antipersonnel effectiveness.
The following description will be with reference to the construction of a miniature rocket of metal foil in accordance with the practice of this invention. For this purpose, use is made of steel or stainless steel foil of about 00003 inch in thickness. In the production of a rocket casing designated to have a wall thickness of about 0.002 inch, six to seven layers of the metal foil are wrapped about a mandrel, the outer diameter of which is dimensioned to correspond to the inner diameter of the rocket casing. When fully wound about the mandrel, the layers can be secured by a heat sensitive adhesive thinly applied to the foil.
A sharply pointed metal nose can be inserted onto the front end of the casing and fastened by crimp forming. The nozzle can be formed by the conventional process of swaging or coining the rearward end of the formed casing. The fins can be formed in advance of the nozzle by splitting or cutting the outer foil layer and turning the split portions outwardly to extend radially from the casing.
Before forming the nozzle, a monolithic tubular shaped grain of a double base type propellant, inhibited with latex or water soluable resin, is extruded to proper form, dried, and inserted into the casing with the micro-pyrotechnic fuze and booster positioned inside the grain. The fuze can be insulated with plastic spaghetti or the grain inhibited on the interior surfaces for part of its length. The fuze is bared at the forward end and wrapped about the booster to anchor the fuze and booster within the propellant grain cavity during the unstable conditions of ignition and high acceleration.
Since the steel foil of which the casing is formed is resilient in character, the fins can be collapsed circumferentially about the peripheral surface of the rocket casing so as to occupy less space in loading or packaging. Any curl that remains after launch will cause the rocket to roll during flight for less dispersion. A rocket of the type described can achieve a velocity at burnout exceeding 3500 feet per second.
When foil of greater thickness is employed to form the rocket casing, the front end of the casing can be processed by impacting or coning to increase the mass density and to form a very sharp pointed nose. In this modification, I
the fins are preferably separately formed of steel and ultrasonically welded in place onto the outside of the casing at the rearward end portion thereof. In the assembly of the rocket, the casing is heated to elevated temperature of about l00200 C. while the propellant grain is chilled to a temperature within the range of 0 to 80 C. and the propellant, dimensioned to be received in fitting relationship within the casing, is inserted in the casing without any inhibitor or adhesive.
The present invention offers a large number of advantages over the prior art of small arms weapons, such as the rifle and bullets, in addition to those noted earlier.
The jets maybe fired in various fashions. One may use an igniter and a firing button. The igniter leads to a deflagrating fuse, which has a plurality of branches. Each of the deflagrating fuse branches leads into the central cavity of one of the rockets. When the button is depressed, the igniter is set off, in turn firing all of the rockets simultaneously. Other ignition devices can be used such as electrical bridge wires or heater wires.
Due to the absence of any kick-back with rockets, use can be made of simple and inexpensive tubular members as launchers, for example, soda straws, bean shooters, cigarette wrapper sand the like, with the ability to aim the rocket for a relatively high degree of accuracy at short ranges. This too permits substantially full concealment of the weapon for use as a defensive or clandestine weapon.
Use can also be made of honeycomb sections for storage of a multiplicity of miniature rockets, for support of the rockets in separated relation in the honeycomb sections, or for sequential or simultaneous firing. The honeycomb, formed of paper, metal foil, or the like, thus functions either as a carrier and/or a launcher in which the rockets are each separately housed in separated compartments within a minimum of space.
The cases of the rockets can be made in a number of ways. For instance, they can be deep drawn, electro-formed or extruded. Further, they can be made in more than one piece. The tube portions can be made individually, and the nose portion separately formed and fastened thereto. Further, the fins may be either formed in place or may be made separately and attached to the case, or they may be extruded with the case. Although the cases are preferably made of a thin strong metal, such as stainless steel, they can be made of plastic or combinations of metals, plastics, and resins, e.g., a plastic case can be combined with a metal combustion chamber.
The rockets of the present invention may be stabilized in flight in various ways including the use of the fins heretobefore described. One method of stabilization is to make the nose heavy as by filling it with metal. Another method is to use skewed or canted fins or vaned combustion chamber nozzles so that a rotational movement or spin will be imparted to the rocket in flight. Of course, various combinations of the stabilizing means can be employed.
Various guide means may be used to hold the rockets concentric until they leave the launcher tube. Thus, the rocket in the lancher is provided with short forward canard fins as well as rear fins. The launching tubes can be provided with packing material which serves the same purpose.
Although it is generally preferred to use standard rocket propellants, other propellants can be used, including high explosives. Thus, compounds such as HMX, which would normally detonate, merely burn when employed in small diameter rockets. Thus, compositions normally thought of as detonators can be employed as propellants and have the advantages of high density, high specific impulse, and high burning rates.
As has been pointed out above, the rockets of the present invention are well adapted for use by unskilled troops. The pattern formed by the rockets on leaving the launcher is such that accurate aiming is not necessary. The instructions for use are so simple that they can be given merely by cartoons printed on the launcher. By employing a carrier for the rockets together with dispersal and firing means, they form excellent weapons for covering a target of large area, such as dispersed troops. In addition to defense against personnel they can be used as antiaircraft or underwater weapons and may be used to carry small payloads of CBR agents or high explosives. Since the rockets emit light for about the first 50 yards of their trajectory, they act as tracers aiding in aiming. Additional tracer material can be added to trace over the full range. From the foregoing it is obvious that there has been provided a unique small arms weapon, which can be manufactured in large quantities at low cost, which can be used by unskilled personnel, and which is highly lethal.
As has been previously pointed out, the rockets of the present invention are of very small size and are of a different order of magnitude than the rockets heretofore proposed. Conventional rocket formulas do not apply to their performance so that they do not represent a mere scale down of existing rockets. For instance, the chamber pressure and burning rate formulas of conventional size rockets do not directly apply to them. For instance, according to conventional rocket formulas, the chamber pressure far exceeds the bursting strength of the case.
It will be understood that changes can be made in the details of construction and methods of fabrication of the miniature rockets without departing from the spirit of the invention. The invention is not to be limited, therefore, except as defined in the following claim.
We claim:
1. A booster mixture for effecting uniform ignition of miniature rockets comprising a mixture of approximately 36% boron potassium nitrate and 64% of a mixture of aluminum in fine grains with an oxide of a chemically Weaker metal as approximately 53% of the formula plus 14 approximately 40% boron chlorate, 2% boron (90-92% 2,990,683 7/1961 Walden 149-38 X BENJAMIN R. PADGETT, Primary Examiner US. Cl. X.R.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US51551265A | 1965-10-22 | 1965-10-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3537923A true US3537923A (en) | 1970-11-03 |
Family
ID=24051668
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US515512A Expired - Lifetime US3537923A (en) | 1965-10-22 | 1965-10-22 | Booster ignition compositions for small arms weapon containing boron and boron compositions |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US3537923A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5639984A (en) * | 1995-03-14 | 1997-06-17 | Thiokol Corporation | Infrared tracer compositions |
| FR2776656A1 (en) * | 1998-03-30 | 1999-10-01 | Giat Ind Sa | METHOD FOR MANUFACTURING AN OBJECT FROM A GRANULAR MATERIAL, IGNITION TUBE AND PROPULSIVE CHARGE OBTAINED WITH SUCH A PROCESS |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2990683A (en) * | 1957-12-30 | 1961-07-04 | Phillips Petroleum Co | Ignition of solid rocket propellants |
-
1965
- 1965-10-22 US US515512A patent/US3537923A/en not_active Expired - Lifetime
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2990683A (en) * | 1957-12-30 | 1961-07-04 | Phillips Petroleum Co | Ignition of solid rocket propellants |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5639984A (en) * | 1995-03-14 | 1997-06-17 | Thiokol Corporation | Infrared tracer compositions |
| FR2776656A1 (en) * | 1998-03-30 | 1999-10-01 | Giat Ind Sa | METHOD FOR MANUFACTURING AN OBJECT FROM A GRANULAR MATERIAL, IGNITION TUBE AND PROPULSIVE CHARGE OBTAINED WITH SUCH A PROCESS |
| EP0949224A1 (en) * | 1998-03-30 | 1999-10-13 | Giat Industries | Process for making an object from granular material and an igniter tube and propellant charge obtained by such a process |
| US6336981B2 (en) | 1998-03-30 | 2002-01-08 | Giat Industries | Process to manufacture an object using a granular material igniter tube and propellant charge obtained using such a process |
| US6368434B1 (en) * | 1998-03-30 | 2002-04-09 | Giat Industrie | Igniter tube and propellant charge made of granular material in a binder |
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