US3464932A - X-ray absorbing glass compositions - Google Patents

X-ray absorbing glass compositions Download PDF

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Publication number
US3464932A
US3464932A US758027A US3464932DA US3464932A US 3464932 A US3464932 A US 3464932A US 758027 A US758027 A US 758027A US 3464932D A US3464932D A US 3464932DA US 3464932 A US3464932 A US 3464932A
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US
United States
Prior art keywords
glass
absorption
radiation
weight
ray
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US758027A
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English (en)
Inventor
John H Connelly
George B Hares
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Corning Glass Works
Original Assignee
Corning Glass Works
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Corning Glass Works filed Critical Corning Glass Works
Application granted granted Critical
Publication of US3464932A publication Critical patent/US3464932A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J35/00X-ray tubes
    • H01J35/02Details
    • H01J35/16Vessels; Containers; Shields associated therewith
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/078Glass compositions containing silica with 40% to 90% silica, by weight containing an oxide of a divalent metal, e.g. an oxide of zinc
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00Compositions for glass with special properties
    • C03C4/08Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths
    • C03C4/087Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths for X-rays absorbing glass

Definitions

  • Various fluxes such as B 0 and P 0 may be present but, preferably, in amounts less than about 5% by weight each.
  • PbO while desirably absent, may be included in amounts up to about 3% by weight.
  • various coloring agents e.g., C0 0 Cr O V 0 CuO, and NiO, may be present in very small amounts to impart a neutral shade to the glass.
  • conventional fining agents such as AS203 and Sb O may be added, where desired.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)
  • Vessels, Lead-In Wires, Accessory Apparatuses For Cathode-Ray Tubes (AREA)
US758027A 1968-09-06 1968-09-06 X-ray absorbing glass compositions Expired - Lifetime US3464932A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US75802768A 1968-09-06 1968-09-06

Publications (1)

Publication Number Publication Date
US3464932A true US3464932A (en) 1969-09-02

Family

ID=25050179

Family Applications (1)

Application Number Title Priority Date Filing Date
US758027A Expired - Lifetime US3464932A (en) 1968-09-06 1968-09-06 X-ray absorbing glass compositions

Country Status (8)

Country Link
US (1) US3464932A (de)
JP (1) JPS548684B1 (de)
BE (1) BE734274A (de)
DE (1) DE1925406B2 (de)
ES (1) ES369365A1 (de)
FR (1) FR2017469B1 (de)
GB (1) GB1250425A (de)
NL (1) NL6911535A (de)

Cited By (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3805107A (en) * 1972-02-17 1974-04-16 Corning Glass Works Faceplate for television picture tube
US3854964A (en) * 1972-03-13 1974-12-17 Gen Electric Lead silicate high voltage vacuum tube glass envelope
US3907584A (en) * 1971-12-20 1975-09-23 Nippon Electric Glass Co Glass composition
US3987330A (en) * 1975-04-25 1976-10-19 Owens-Illinois, Inc. Zirconia containing glass compositions for cathode ray tubes
US4065697A (en) * 1969-02-17 1977-12-27 Owens-Illinois, Inc. Cathode-ray tube
US4065317A (en) * 1971-10-28 1977-12-27 Nippon Electric Glass Company, Ltd. Novel glass compositions
US4089693A (en) * 1969-10-03 1978-05-16 U.S. Philips Corporation Glass for television display cathode-ray tubes
US4174490A (en) * 1977-05-25 1979-11-13 U.S. Philips Corporation Cathode-ray tube
US4215033A (en) * 1978-09-08 1980-07-29 American Dental Association Health Foundation Composite dental material
DE3032771A1 (de) * 1979-09-03 1981-03-19 Naamloze Vennootschap Philips' Gloeilampenfabrieken, Eindhoven Glas, insbesondere fuer den schirm von kathodenstrahlroehren
US4277286A (en) * 1980-02-19 1981-07-07 Corning Glass Works Lead-free glasses of high x-ray absorption for cathode ray tubes
US4331770A (en) * 1980-04-21 1982-05-25 Corning Glass Works Low liquidus glasses for television tube faceplates
US4366252A (en) * 1980-03-13 1982-12-28 Owens-Illinois, Inc. Fluorine-free, zirconia-free, X-ray absorbing silica based glass, containing oxides of lead, barium and strontium plus oxides of calcium, magnesium, sodium, potassium, cerium, titanium, arsenic and antimony
US4390637A (en) * 1980-09-10 1983-06-28 Nippon Electric Glass Company, Limited X-Ray absorbing glass for a color cathode ray tube having a controlled chromaticity value and a selective light absorption
US4520115A (en) * 1982-08-02 1985-05-28 Schott Glaswerke High absorbance Pb-containing glass for cathode ray tube picture screen
US4599319A (en) * 1982-12-04 1986-07-08 Schott-Glasswerke PbO-free glasses for cathode ray tubes having a high protective effect against X-rays while simultaneously having good resistance to acid and stability to radiation
US4725383A (en) * 1983-08-09 1988-02-16 Ebara Corporation Process for volume reduction and solidification of a radioactive sodium borate waste solution
US4737475A (en) * 1985-10-07 1988-04-12 General Electric Company Arsenic-free lead silicate vacuum tube glass
US4804885A (en) * 1982-02-04 1989-02-14 Tektronix, Inc. X-ray attenuating ceramic materials
US4949010A (en) * 1982-02-04 1990-08-14 Tektronix, Inc. X-ray attenuating ceramic materials
US5192718A (en) * 1991-10-24 1993-03-09 Corning Incorporated Lead silicate glasses
US5215944A (en) * 1991-07-29 1993-06-01 Ppg Industries, Inc. X-ray absorbing glass compositions
US5270269A (en) * 1992-06-08 1993-12-14 Corning Incorporated Lead-free fine crystal glassware
US5468693A (en) * 1993-12-10 1995-11-21 Corning Incorporated Lead-free glasses exhibiting characteristics of crystal
US5468692A (en) * 1994-12-19 1995-11-21 Corning Incorporated Non-browning cathode ray tube glasses
US5599752A (en) * 1993-12-08 1997-02-04 U.S. Philips Corporation Glass for a cone of a display tube, display tube envelope comprising a cone of such a glass and method of manufacturing a cone from such a glass
US5599754A (en) * 1994-10-14 1997-02-04 Asahi Glass Company Ltd. Glass composition for a substrate, and substrate for plasma display made thereof
US5631195A (en) * 1994-09-14 1997-05-20 Asahi Glass Company Ltd. Glass composition and substrate for plasma display
EP1153410A1 (de) * 1998-10-28 2001-11-14 International Lead Zinc Research Organization Kathodenstrahlröhre mit vermindeten bräurungseigenschafter
US20030032544A1 (en) * 2001-07-27 2003-02-13 Nippon Electric Glass Co., Ltd CRT funnel glass capable of effectively recycling another glass member
US20050209086A1 (en) * 2003-12-10 2005-09-22 Asahi Glass Company, Limited Panel glass for cathode ray tube
US20140011035A1 (en) * 2011-03-31 2014-01-09 Nippon Sheet Glass Company, Limited Glass composition suitable for chemical strengthening and chemically strengthened glass article

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3819972A (en) * 1972-02-28 1974-06-25 Owens Illinois Inc Novel glass compositions and cathode-ray tubes made therefrom

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1633534A (en) * 1926-01-12 1927-06-21 Saint Gobain Glass and process of making the same
US2025099A (en) * 1934-10-13 1935-12-24 Pittsburgh Plate Glass Co X-ray absorption glass
US2747105A (en) * 1951-11-29 1956-05-22 Pittsburgh Plate Glass Co Transparent nuclear radiation shield
US3138561A (en) * 1953-11-23 1964-06-23 Johns Manville Fiber Glass Inc Radiation resisting glass composition
US3356579A (en) * 1964-01-29 1967-12-05 Corning Glass Works Radiation window glass
US3369961A (en) * 1964-01-30 1968-02-20 Corning Glass Works Radiation-resistant metal sealing glass

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1633534A (en) * 1926-01-12 1927-06-21 Saint Gobain Glass and process of making the same
US2025099A (en) * 1934-10-13 1935-12-24 Pittsburgh Plate Glass Co X-ray absorption glass
US2747105A (en) * 1951-11-29 1956-05-22 Pittsburgh Plate Glass Co Transparent nuclear radiation shield
US3138561A (en) * 1953-11-23 1964-06-23 Johns Manville Fiber Glass Inc Radiation resisting glass composition
US3356579A (en) * 1964-01-29 1967-12-05 Corning Glass Works Radiation window glass
US3369961A (en) * 1964-01-30 1968-02-20 Corning Glass Works Radiation-resistant metal sealing glass

Cited By (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4065697A (en) * 1969-02-17 1977-12-27 Owens-Illinois, Inc. Cathode-ray tube
US4089693A (en) * 1969-10-03 1978-05-16 U.S. Philips Corporation Glass for television display cathode-ray tubes
US4065317A (en) * 1971-10-28 1977-12-27 Nippon Electric Glass Company, Ltd. Novel glass compositions
US3907584A (en) * 1971-12-20 1975-09-23 Nippon Electric Glass Co Glass composition
US3805107A (en) * 1972-02-17 1974-04-16 Corning Glass Works Faceplate for television picture tube
US3854964A (en) * 1972-03-13 1974-12-17 Gen Electric Lead silicate high voltage vacuum tube glass envelope
US3987330A (en) * 1975-04-25 1976-10-19 Owens-Illinois, Inc. Zirconia containing glass compositions for cathode ray tubes
US4174490A (en) * 1977-05-25 1979-11-13 U.S. Philips Corporation Cathode-ray tube
US4215033A (en) * 1978-09-08 1980-07-29 American Dental Association Health Foundation Composite dental material
DE3032771A1 (de) * 1979-09-03 1981-03-19 Naamloze Vennootschap Philips' Gloeilampenfabrieken, Eindhoven Glas, insbesondere fuer den schirm von kathodenstrahlroehren
US4277286A (en) * 1980-02-19 1981-07-07 Corning Glass Works Lead-free glasses of high x-ray absorption for cathode ray tubes
US4366252A (en) * 1980-03-13 1982-12-28 Owens-Illinois, Inc. Fluorine-free, zirconia-free, X-ray absorbing silica based glass, containing oxides of lead, barium and strontium plus oxides of calcium, magnesium, sodium, potassium, cerium, titanium, arsenic and antimony
US4331770A (en) * 1980-04-21 1982-05-25 Corning Glass Works Low liquidus glasses for television tube faceplates
US4390637A (en) * 1980-09-10 1983-06-28 Nippon Electric Glass Company, Limited X-Ray absorbing glass for a color cathode ray tube having a controlled chromaticity value and a selective light absorption
US4804885A (en) * 1982-02-04 1989-02-14 Tektronix, Inc. X-ray attenuating ceramic materials
US4949010A (en) * 1982-02-04 1990-08-14 Tektronix, Inc. X-ray attenuating ceramic materials
US4520115A (en) * 1982-08-02 1985-05-28 Schott Glaswerke High absorbance Pb-containing glass for cathode ray tube picture screen
US4599319A (en) * 1982-12-04 1986-07-08 Schott-Glasswerke PbO-free glasses for cathode ray tubes having a high protective effect against X-rays while simultaneously having good resistance to acid and stability to radiation
US4725383A (en) * 1983-08-09 1988-02-16 Ebara Corporation Process for volume reduction and solidification of a radioactive sodium borate waste solution
US4737475A (en) * 1985-10-07 1988-04-12 General Electric Company Arsenic-free lead silicate vacuum tube glass
US5215944A (en) * 1991-07-29 1993-06-01 Ppg Industries, Inc. X-ray absorbing glass compositions
US5192718A (en) * 1991-10-24 1993-03-09 Corning Incorporated Lead silicate glasses
EP0538568A1 (de) * 1991-10-24 1993-04-28 Corning Incorporated Bleisilicatgläser
US5270269A (en) * 1992-06-08 1993-12-14 Corning Incorporated Lead-free fine crystal glassware
EP0575758A1 (de) * 1992-06-08 1993-12-29 Corning Incorporated Bleifreie feine Kristallglaswaren
US5725627A (en) * 1993-12-08 1998-03-10 U. S. Philips Corporation Glass for a cone of a display tube, display tube envelope comprising a cone of such a glass and method of manufacturing a cone from such a glass
US5599752A (en) * 1993-12-08 1997-02-04 U.S. Philips Corporation Glass for a cone of a display tube, display tube envelope comprising a cone of such a glass and method of manufacturing a cone from such a glass
US5468693A (en) * 1993-12-10 1995-11-21 Corning Incorporated Lead-free glasses exhibiting characteristics of crystal
US5780373A (en) * 1994-09-14 1998-07-14 Asahi Glass Company Ltd. Glass composition and substrate for plasma display
US5631195A (en) * 1994-09-14 1997-05-20 Asahi Glass Company Ltd. Glass composition and substrate for plasma display
US5599754A (en) * 1994-10-14 1997-02-04 Asahi Glass Company Ltd. Glass composition for a substrate, and substrate for plasma display made thereof
US5468692A (en) * 1994-12-19 1995-11-21 Corning Incorporated Non-browning cathode ray tube glasses
EP0719739A2 (de) 1994-12-19 1996-07-03 Corning Incorporated Nicht-bräunende Gläser für Kathodenstrahlrohren
EP1153410A1 (de) * 1998-10-28 2001-11-14 International Lead Zinc Research Organization Kathodenstrahlröhre mit vermindeten bräurungseigenschafter
EP1153410A4 (de) * 1998-10-28 2003-01-22 Int Lead Zinc Res Kathodenstrahlröhre mit vermindeten bräurungseigenschafter
US20030032544A1 (en) * 2001-07-27 2003-02-13 Nippon Electric Glass Co., Ltd CRT funnel glass capable of effectively recycling another glass member
US20040259715A1 (en) * 2001-07-27 2004-12-23 Nippon Electric Glass Co., Ltd. Method of preparing CRT funnel glass capable of effectively recycling another glass member
US6865909B2 (en) 2001-07-27 2005-03-15 Nippon Electric Glass Co., Ltd Method of preparing CRT funnel glass capable of effectively recycling another glass member
US20050209086A1 (en) * 2003-12-10 2005-09-22 Asahi Glass Company, Limited Panel glass for cathode ray tube
US20140011035A1 (en) * 2011-03-31 2014-01-09 Nippon Sheet Glass Company, Limited Glass composition suitable for chemical strengthening and chemically strengthened glass article

Also Published As

Publication number Publication date
NL6911535A (de) 1970-03-10
JPS548684B1 (de) 1979-04-18
FR2017469B1 (de) 1974-06-14
GB1250425A (de) 1971-10-20
FR2017469A1 (de) 1970-05-22
BE734274A (de) 1969-12-09
ES369365A1 (es) 1971-06-01
DE1925406A1 (de) 1970-08-13
DE1925406B2 (de) 1971-03-25

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