US3464932A - X-ray absorbing glass compositions - Google Patents
X-ray absorbing glass compositions Download PDFInfo
- Publication number
- US3464932A US3464932A US758027A US3464932DA US3464932A US 3464932 A US3464932 A US 3464932A US 758027 A US758027 A US 758027A US 3464932D A US3464932D A US 3464932DA US 3464932 A US3464932 A US 3464932A
- Authority
- US
- United States
- Prior art keywords
- glass
- absorption
- radiation
- weight
- ray
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011521 glass Substances 0.000 title description 54
- 239000000203 mixture Substances 0.000 title description 19
- 230000009102 absorption Effects 0.000 description 40
- 238000010521 absorption reaction Methods 0.000 description 40
- 229910052788 barium Inorganic materials 0.000 description 9
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 9
- 230000005540 biological transmission Effects 0.000 description 9
- 239000000463 material Substances 0.000 description 7
- 230000005855 radiation Effects 0.000 description 6
- 229910052712 strontium Inorganic materials 0.000 description 6
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 6
- 238000002845 discoloration Methods 0.000 description 5
- 230000001965 increasing effect Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000006096 absorbing agent Substances 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 239000006105 batch ingredient Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000006025 fining agent Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- -1 glass Chemical class 0.000 description 1
- 229910003439 heavy metal oxide Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000005368 silicate glass Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000004846 x-ray emission Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J35/00—X-ray tubes
- H01J35/02—Details
- H01J35/16—Vessels; Containers; Shields associated therewith
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C3/00—Glass compositions
- C03C3/04—Glass compositions containing silica
- C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
- C03C3/078—Glass compositions containing silica with 40% to 90% silica, by weight containing an oxide of a divalent metal, e.g. an oxide of zinc
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/08—Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths
- C03C4/087—Compositions for glass with special properties for glass selectively absorbing radiation of specified wave lengths for X-rays absorbing glass
Definitions
- Various fluxes such as B 0 and P 0 may be present but, preferably, in amounts less than about 5% by weight each.
- PbO while desirably absent, may be included in amounts up to about 3% by weight.
- various coloring agents e.g., C0 0 Cr O V 0 CuO, and NiO, may be present in very small amounts to impart a neutral shade to the glass.
- conventional fining agents such as AS203 and Sb O may be added, where desired.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
- Vessels, Lead-In Wires, Accessory Apparatuses For Cathode-Ray Tubes (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US75802768A | 1968-09-06 | 1968-09-06 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3464932A true US3464932A (en) | 1969-09-02 |
Family
ID=25050179
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US758027A Expired - Lifetime US3464932A (en) | 1968-09-06 | 1968-09-06 | X-ray absorbing glass compositions |
Country Status (8)
Country | Link |
---|---|
US (1) | US3464932A (de) |
JP (1) | JPS548684B1 (de) |
BE (1) | BE734274A (de) |
DE (1) | DE1925406B2 (de) |
ES (1) | ES369365A1 (de) |
FR (1) | FR2017469B1 (de) |
GB (1) | GB1250425A (de) |
NL (1) | NL6911535A (de) |
Cited By (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3805107A (en) * | 1972-02-17 | 1974-04-16 | Corning Glass Works | Faceplate for television picture tube |
US3854964A (en) * | 1972-03-13 | 1974-12-17 | Gen Electric | Lead silicate high voltage vacuum tube glass envelope |
US3907584A (en) * | 1971-12-20 | 1975-09-23 | Nippon Electric Glass Co | Glass composition |
US3987330A (en) * | 1975-04-25 | 1976-10-19 | Owens-Illinois, Inc. | Zirconia containing glass compositions for cathode ray tubes |
US4065697A (en) * | 1969-02-17 | 1977-12-27 | Owens-Illinois, Inc. | Cathode-ray tube |
US4065317A (en) * | 1971-10-28 | 1977-12-27 | Nippon Electric Glass Company, Ltd. | Novel glass compositions |
US4089693A (en) * | 1969-10-03 | 1978-05-16 | U.S. Philips Corporation | Glass for television display cathode-ray tubes |
US4174490A (en) * | 1977-05-25 | 1979-11-13 | U.S. Philips Corporation | Cathode-ray tube |
US4215033A (en) * | 1978-09-08 | 1980-07-29 | American Dental Association Health Foundation | Composite dental material |
DE3032771A1 (de) * | 1979-09-03 | 1981-03-19 | Naamloze Vennootschap Philips' Gloeilampenfabrieken, Eindhoven | Glas, insbesondere fuer den schirm von kathodenstrahlroehren |
US4277286A (en) * | 1980-02-19 | 1981-07-07 | Corning Glass Works | Lead-free glasses of high x-ray absorption for cathode ray tubes |
US4331770A (en) * | 1980-04-21 | 1982-05-25 | Corning Glass Works | Low liquidus glasses for television tube faceplates |
US4366252A (en) * | 1980-03-13 | 1982-12-28 | Owens-Illinois, Inc. | Fluorine-free, zirconia-free, X-ray absorbing silica based glass, containing oxides of lead, barium and strontium plus oxides of calcium, magnesium, sodium, potassium, cerium, titanium, arsenic and antimony |
US4390637A (en) * | 1980-09-10 | 1983-06-28 | Nippon Electric Glass Company, Limited | X-Ray absorbing glass for a color cathode ray tube having a controlled chromaticity value and a selective light absorption |
US4520115A (en) * | 1982-08-02 | 1985-05-28 | Schott Glaswerke | High absorbance Pb-containing glass for cathode ray tube picture screen |
US4599319A (en) * | 1982-12-04 | 1986-07-08 | Schott-Glasswerke | PbO-free glasses for cathode ray tubes having a high protective effect against X-rays while simultaneously having good resistance to acid and stability to radiation |
US4725383A (en) * | 1983-08-09 | 1988-02-16 | Ebara Corporation | Process for volume reduction and solidification of a radioactive sodium borate waste solution |
US4737475A (en) * | 1985-10-07 | 1988-04-12 | General Electric Company | Arsenic-free lead silicate vacuum tube glass |
US4804885A (en) * | 1982-02-04 | 1989-02-14 | Tektronix, Inc. | X-ray attenuating ceramic materials |
US4949010A (en) * | 1982-02-04 | 1990-08-14 | Tektronix, Inc. | X-ray attenuating ceramic materials |
US5192718A (en) * | 1991-10-24 | 1993-03-09 | Corning Incorporated | Lead silicate glasses |
US5215944A (en) * | 1991-07-29 | 1993-06-01 | Ppg Industries, Inc. | X-ray absorbing glass compositions |
US5270269A (en) * | 1992-06-08 | 1993-12-14 | Corning Incorporated | Lead-free fine crystal glassware |
US5468693A (en) * | 1993-12-10 | 1995-11-21 | Corning Incorporated | Lead-free glasses exhibiting characteristics of crystal |
US5468692A (en) * | 1994-12-19 | 1995-11-21 | Corning Incorporated | Non-browning cathode ray tube glasses |
US5599752A (en) * | 1993-12-08 | 1997-02-04 | U.S. Philips Corporation | Glass for a cone of a display tube, display tube envelope comprising a cone of such a glass and method of manufacturing a cone from such a glass |
US5599754A (en) * | 1994-10-14 | 1997-02-04 | Asahi Glass Company Ltd. | Glass composition for a substrate, and substrate for plasma display made thereof |
US5631195A (en) * | 1994-09-14 | 1997-05-20 | Asahi Glass Company Ltd. | Glass composition and substrate for plasma display |
EP1153410A1 (de) * | 1998-10-28 | 2001-11-14 | International Lead Zinc Research Organization | Kathodenstrahlröhre mit vermindeten bräurungseigenschafter |
US20030032544A1 (en) * | 2001-07-27 | 2003-02-13 | Nippon Electric Glass Co., Ltd | CRT funnel glass capable of effectively recycling another glass member |
US20050209086A1 (en) * | 2003-12-10 | 2005-09-22 | Asahi Glass Company, Limited | Panel glass for cathode ray tube |
US20140011035A1 (en) * | 2011-03-31 | 2014-01-09 | Nippon Sheet Glass Company, Limited | Glass composition suitable for chemical strengthening and chemically strengthened glass article |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3819972A (en) * | 1972-02-28 | 1974-06-25 | Owens Illinois Inc | Novel glass compositions and cathode-ray tubes made therefrom |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1633534A (en) * | 1926-01-12 | 1927-06-21 | Saint Gobain | Glass and process of making the same |
US2025099A (en) * | 1934-10-13 | 1935-12-24 | Pittsburgh Plate Glass Co | X-ray absorption glass |
US2747105A (en) * | 1951-11-29 | 1956-05-22 | Pittsburgh Plate Glass Co | Transparent nuclear radiation shield |
US3138561A (en) * | 1953-11-23 | 1964-06-23 | Johns Manville Fiber Glass Inc | Radiation resisting glass composition |
US3356579A (en) * | 1964-01-29 | 1967-12-05 | Corning Glass Works | Radiation window glass |
US3369961A (en) * | 1964-01-30 | 1968-02-20 | Corning Glass Works | Radiation-resistant metal sealing glass |
-
1968
- 1968-09-06 US US758027A patent/US3464932A/en not_active Expired - Lifetime
-
1969
- 1969-05-14 GB GB1250425D patent/GB1250425A/en not_active Expired
- 1969-05-19 DE DE19691925406 patent/DE1925406B2/de active Pending
- 1969-05-23 FR FR696916846A patent/FR2017469B1/fr not_active Expired
- 1969-06-09 BE BE734274D patent/BE734274A/xx unknown
- 1969-06-14 JP JP4653069A patent/JPS548684B1/ja active Pending
- 1969-07-10 ES ES369365A patent/ES369365A1/es not_active Expired
- 1969-07-28 NL NL6911535A patent/NL6911535A/xx unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1633534A (en) * | 1926-01-12 | 1927-06-21 | Saint Gobain | Glass and process of making the same |
US2025099A (en) * | 1934-10-13 | 1935-12-24 | Pittsburgh Plate Glass Co | X-ray absorption glass |
US2747105A (en) * | 1951-11-29 | 1956-05-22 | Pittsburgh Plate Glass Co | Transparent nuclear radiation shield |
US3138561A (en) * | 1953-11-23 | 1964-06-23 | Johns Manville Fiber Glass Inc | Radiation resisting glass composition |
US3356579A (en) * | 1964-01-29 | 1967-12-05 | Corning Glass Works | Radiation window glass |
US3369961A (en) * | 1964-01-30 | 1968-02-20 | Corning Glass Works | Radiation-resistant metal sealing glass |
Cited By (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4065697A (en) * | 1969-02-17 | 1977-12-27 | Owens-Illinois, Inc. | Cathode-ray tube |
US4089693A (en) * | 1969-10-03 | 1978-05-16 | U.S. Philips Corporation | Glass for television display cathode-ray tubes |
US4065317A (en) * | 1971-10-28 | 1977-12-27 | Nippon Electric Glass Company, Ltd. | Novel glass compositions |
US3907584A (en) * | 1971-12-20 | 1975-09-23 | Nippon Electric Glass Co | Glass composition |
US3805107A (en) * | 1972-02-17 | 1974-04-16 | Corning Glass Works | Faceplate for television picture tube |
US3854964A (en) * | 1972-03-13 | 1974-12-17 | Gen Electric | Lead silicate high voltage vacuum tube glass envelope |
US3987330A (en) * | 1975-04-25 | 1976-10-19 | Owens-Illinois, Inc. | Zirconia containing glass compositions for cathode ray tubes |
US4174490A (en) * | 1977-05-25 | 1979-11-13 | U.S. Philips Corporation | Cathode-ray tube |
US4215033A (en) * | 1978-09-08 | 1980-07-29 | American Dental Association Health Foundation | Composite dental material |
DE3032771A1 (de) * | 1979-09-03 | 1981-03-19 | Naamloze Vennootschap Philips' Gloeilampenfabrieken, Eindhoven | Glas, insbesondere fuer den schirm von kathodenstrahlroehren |
US4277286A (en) * | 1980-02-19 | 1981-07-07 | Corning Glass Works | Lead-free glasses of high x-ray absorption for cathode ray tubes |
US4366252A (en) * | 1980-03-13 | 1982-12-28 | Owens-Illinois, Inc. | Fluorine-free, zirconia-free, X-ray absorbing silica based glass, containing oxides of lead, barium and strontium plus oxides of calcium, magnesium, sodium, potassium, cerium, titanium, arsenic and antimony |
US4331770A (en) * | 1980-04-21 | 1982-05-25 | Corning Glass Works | Low liquidus glasses for television tube faceplates |
US4390637A (en) * | 1980-09-10 | 1983-06-28 | Nippon Electric Glass Company, Limited | X-Ray absorbing glass for a color cathode ray tube having a controlled chromaticity value and a selective light absorption |
US4804885A (en) * | 1982-02-04 | 1989-02-14 | Tektronix, Inc. | X-ray attenuating ceramic materials |
US4949010A (en) * | 1982-02-04 | 1990-08-14 | Tektronix, Inc. | X-ray attenuating ceramic materials |
US4520115A (en) * | 1982-08-02 | 1985-05-28 | Schott Glaswerke | High absorbance Pb-containing glass for cathode ray tube picture screen |
US4599319A (en) * | 1982-12-04 | 1986-07-08 | Schott-Glasswerke | PbO-free glasses for cathode ray tubes having a high protective effect against X-rays while simultaneously having good resistance to acid and stability to radiation |
US4725383A (en) * | 1983-08-09 | 1988-02-16 | Ebara Corporation | Process for volume reduction and solidification of a radioactive sodium borate waste solution |
US4737475A (en) * | 1985-10-07 | 1988-04-12 | General Electric Company | Arsenic-free lead silicate vacuum tube glass |
US5215944A (en) * | 1991-07-29 | 1993-06-01 | Ppg Industries, Inc. | X-ray absorbing glass compositions |
US5192718A (en) * | 1991-10-24 | 1993-03-09 | Corning Incorporated | Lead silicate glasses |
EP0538568A1 (de) * | 1991-10-24 | 1993-04-28 | Corning Incorporated | Bleisilicatgläser |
US5270269A (en) * | 1992-06-08 | 1993-12-14 | Corning Incorporated | Lead-free fine crystal glassware |
EP0575758A1 (de) * | 1992-06-08 | 1993-12-29 | Corning Incorporated | Bleifreie feine Kristallglaswaren |
US5725627A (en) * | 1993-12-08 | 1998-03-10 | U. S. Philips Corporation | Glass for a cone of a display tube, display tube envelope comprising a cone of such a glass and method of manufacturing a cone from such a glass |
US5599752A (en) * | 1993-12-08 | 1997-02-04 | U.S. Philips Corporation | Glass for a cone of a display tube, display tube envelope comprising a cone of such a glass and method of manufacturing a cone from such a glass |
US5468693A (en) * | 1993-12-10 | 1995-11-21 | Corning Incorporated | Lead-free glasses exhibiting characteristics of crystal |
US5780373A (en) * | 1994-09-14 | 1998-07-14 | Asahi Glass Company Ltd. | Glass composition and substrate for plasma display |
US5631195A (en) * | 1994-09-14 | 1997-05-20 | Asahi Glass Company Ltd. | Glass composition and substrate for plasma display |
US5599754A (en) * | 1994-10-14 | 1997-02-04 | Asahi Glass Company Ltd. | Glass composition for a substrate, and substrate for plasma display made thereof |
US5468692A (en) * | 1994-12-19 | 1995-11-21 | Corning Incorporated | Non-browning cathode ray tube glasses |
EP0719739A2 (de) | 1994-12-19 | 1996-07-03 | Corning Incorporated | Nicht-bräunende Gläser für Kathodenstrahlrohren |
EP1153410A1 (de) * | 1998-10-28 | 2001-11-14 | International Lead Zinc Research Organization | Kathodenstrahlröhre mit vermindeten bräurungseigenschafter |
EP1153410A4 (de) * | 1998-10-28 | 2003-01-22 | Int Lead Zinc Res | Kathodenstrahlröhre mit vermindeten bräurungseigenschafter |
US20030032544A1 (en) * | 2001-07-27 | 2003-02-13 | Nippon Electric Glass Co., Ltd | CRT funnel glass capable of effectively recycling another glass member |
US20040259715A1 (en) * | 2001-07-27 | 2004-12-23 | Nippon Electric Glass Co., Ltd. | Method of preparing CRT funnel glass capable of effectively recycling another glass member |
US6865909B2 (en) | 2001-07-27 | 2005-03-15 | Nippon Electric Glass Co., Ltd | Method of preparing CRT funnel glass capable of effectively recycling another glass member |
US20050209086A1 (en) * | 2003-12-10 | 2005-09-22 | Asahi Glass Company, Limited | Panel glass for cathode ray tube |
US20140011035A1 (en) * | 2011-03-31 | 2014-01-09 | Nippon Sheet Glass Company, Limited | Glass composition suitable for chemical strengthening and chemically strengthened glass article |
Also Published As
Publication number | Publication date |
---|---|
NL6911535A (de) | 1970-03-10 |
JPS548684B1 (de) | 1979-04-18 |
FR2017469B1 (de) | 1974-06-14 |
GB1250425A (de) | 1971-10-20 |
FR2017469A1 (de) | 1970-05-22 |
BE734274A (de) | 1969-12-09 |
ES369365A1 (es) | 1971-06-01 |
DE1925406A1 (de) | 1970-08-13 |
DE1925406B2 (de) | 1971-03-25 |
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