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Curtain coating process and apparatus

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US3462290A
US3462290A US3462290DA US3462290A US 3462290 A US3462290 A US 3462290A US 3462290D A US3462290D A US 3462290DA US 3462290 A US3462290 A US 3462290A
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coating
substrate
roll
curtain
pressure
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Herman J Kresse
Joe F Alix
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ConocoPhillips Holding Co
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ConocoPhillips Holding Co
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05BELECTRIC HEATING; ELECTRIC LIGHTING NOT OTHERWISE PROVIDED FOR
    • H05B3/00Ohmic-resistance heating
    • H05B3/62Heating elements specially adapted for furnaces
    • H05B3/64Heating elements specially adapted for furnaces using ribbon, rod, or wire heater
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/30Processes for applying liquids or other fluent materials performed by gravity only, i.e. flow coating
    • B05D1/305Curtain coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/40Distributing applied liquids or other fluent materials by members moving relatively to surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/007After-treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2252/00Sheets
    • B05D2252/02Sheets of indefinite length
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S118/00Coating apparatus
    • Y10S118/04Curtain coater

Description

Aug. 19, 1969 H. J. KRESSE ETAL 3,462,290

CURTAIN COATING PROCESS AND APPARATUS Filed March 31, 1966 COATING HEAD 7\i FALLING Fll-M RESILIENT ROLL COLLECTOR m DEGASSER AND L BACK TO MELT RESERVOIR FIG. 2

INVENTOR. JOE E AL/X 3 HERMAN J. KRESSE United States Patent 3,462,290 CURTAIN COATING PROCESS AND APPARATUS Herman J. Kresse, Houston, Tex., and Joe F. Alix, Ponca City, Okla, assignors to Continental Oil Company, Ponca City, Okla, a corporation of Delaware Filed Mar. 31, 1966, Ser. No. 539,046 Int. Cl. B4411 1/40, 1/44 US. Cl. 117--65.2 9 Claims ABSTRACT OF THE DISCLOSURE In a curtain coater, a resilient roller is placed against the uncoated side of coated substrate as said substrate passes over a chill roller, which is spaced downstream from the falling curtain of coating material.

This invention relates to applying a hot melt coating to at least one surface of a substrate. In one aspect, this invention relates to curtain coaters. In another aspect, this invention relates to an improved method of applying a hot melt to a substrate.

When applied to the coating of certain solid substrate materials with hot viscous liquids, such as molten Wax, molten synthetic resins, and blends of wax with synthetic resins (generally referred to as hot melts), most coating procedures are characterized in varying degree by a number of disadvantages. Among such disadvantages there may be mentioned: waste or uneconomical use of the coating material, decrease in flexibility of the substrate as a result of coating, and failure of the coating technique to successfully apply a smooth continuous coating which is free from cracks, bubbles, pinholes, blisters and the like.

In recent years, the curtain coater process has been developed to applying such hot melt coatings to substrates. In curtain coating, the stock to be coated is passed through a gravitating or falling curtain or film of the coating medium so that the coating medium impinges upon the exposed surface of the stock and is deposited thereon as a thin, relatively uniform film. The excess coating material which is not deposited on the stock is collected in a suitable receiving container and, preferably, degassed and cycled to the point of origin of the gravitating curtain for reuse. Preferably, the stock is preheated prior to coating; however, with relatively thin stocks such as cellophane, and similar thin plastic sheets, this is generally not required. In any case, the hot melt must be cooled below the tacky point prior to rolling the stock to prevent sticking. This is generally accomplished by passing the freshly coated stock around a chill roll. The conventional curtain coater has been very effective in coating porous substrates; however, when semi-porous substrates such as plastic film, glassine paper, pouch paper, grease-proof paper and the like are coated with a curtain coater; bubbles, pinholes or small areas of nonadhered coatings frequently result. These problems are largely eliminated by the process disclosed in the copending application of Politziner, Kresse, Wong and Gordy, filed Sept. 13, 1965, and having Ser. No. 486,787 and now abandoned. According to the method disclosed by Politziner et al., the hot melt is subjected to a degassing step prior to application. However, the stock itself can be the source of the gas bubbles, e.g., a small amount of moisture; also, a small amount of air can be entrapped at the point of impingement. While the degassed hot melt may give an apparently uniform, hole-free coating, the coating may not actually adhere uniformly and thus the coating will break subsequent to the coating. With porous substrates, steam formed by moisture or other gas will pass through the substrate, whereas with semi-porous 3,462,290 Patented Aug. 19, 1969 substrates, the gas flow meets with suificient pressure to be a source of potential diificulty. This is illustrated by clay-backed substrates. It has been found that little or no trouble is encountered when using the degassed hot melt to the coated side of the substrate. On the other hand, considerable difficulty is encountered on curtain coating the untreated side. This is probably due to the fact that the paper stock contains some moisture and when the hot melt is applied to the substrate, the steam produced passes readily through the substrate. However, when applying the coating to the untreated side, the steam does not readily pass through the clay and forms small bubbles in the film. On the chill roll, the steam is condensed and readsorbed by the substrate; however, the hot melt film does not adhere to the substrate.

It is an object of this invention to provide an improved method of curtain coating semior impervious substrates.

Another object of this invention is to provide a method for improving the adhesion of coatings to substrates.

Another object of this invention is to provide a method for flattening bubbles and closing of craters, pinholes and ruptures formed by applying hot melts to substrates with a curtain coater.

Another object of this invention is to provide a method for maintaining the flatness of thin substrates after applying hot melts to the surface thereof.

It is still another object of this invention to provide a method for improving the gloss and surface smoothness to surfaces applied to substrates.

Still another object of this invention is to improve heat transfer at the chill roll following application of hot melt to substrates, and still other objects, features and advantages of this invention will be apparent to those skilled in the art having been given this disclosure and the appended claims.

These objects are accomplished according to this invention by passing a substrate Which has been coated with a hot melt by means of a curtain coater over a chill roll and between said chill roll and a pressure roll.

As has been indicated, the substrates to which this invention is of particular usefulness are impervious substrates such as metallic foils, i.e., aluminum foil, etc., plastic sheets such as cellophane, polyethylene and other polymer and copolymer flexible sheeting materials and semi-pervious sheets such as clay-backed and lacquerbacked papers, pouch paper, greaseproof paper, glassine paper and the like.

The coating materials to which this invention is particularly useful are hot melts which are subject to applying to substrates, e.g., a falling curtain as utilized in a curtain coater. These materials are waxes, wax-copolymer blends and the like. In general, these materials have an inherent viscosity at 250 F. in the range of 15,000 to 100,000 cps. A typical wax-copolymer blend would be a hydrocarbon high melting wax with butyl rubber, or ethylene-vinylacetate copolymer. Such melts are known in the art, and are not a part of this invention.

The apparatus by which the present invention is practiced in one embodiment comprises a curtain coating device which can be of conventional type and which functions to provide a gravitating or downwardly propelled curtain or film of the coating composition; a conveyor system or means for moving the substrate stock to be coated through the gravitating curtain of the coating composition and a means for cooling the stock after coating. Preferably, the curtain coater will have conduit means for collecting and recycling to the curtain coating device all the excess coating composition which is not deposited upon the stock; means for preheating the stock when so desired and means for removing gas from the coating composition. An important feature of a preferred embodiment of the apparatus used in the practice of the present invention is a pressure roll in cooperation with the means for cooling so as to press the film against the stock as it passes over the cooling means. In a typical installation wherein a sheet of stock is continuously unrolled, passed through the curtain coater and is subsequently rerolled, the cooling means intermediate the curtain coater and the reroller will comprise a chill roll and a pressure roll so arranged that the pressure roll is held in contact with the stock as it passes over the cooling roll. Preferably, the pressure roll will have a resilient surface such as rubber or high melting plastic, e.g., butadiene, styrene copolymers, high melting point polyethylene or polyvinylchloride, copolymers of these with copolymerizable monomers or polyvinylfluorides such as Teflon.

For some stocks it is desirable to include in the ap paratus used in practicing the invention, humidifying means for adding sufiicient moisture to the stock to be coated to prevent excessive dehydration of the stock and fiber embrittlement in those cases where the stock is preheated prior to the application of the coating thereto.

The coating material useful in this invention is any hot melt suitable for use in a falling film or curtain coater. In general, these materials are mixtures of paraffin and/ or microcrystalline wax with a compatible resin. Most frequently the melt is such a wax with an ethylene-vinylacetate copolymer, e.g., 30% wax and 70% copolymer of 80% ethylene with 20% vinylacetate. Other polymers and copolymers are sometimes used such as polyethylene, polystyrene, polybutadiene, butadiene-styrene copolymer, vinylchloride and its copolymer. The only limitation being that the blend or melt will form a free-flowing film at the extrusion temperature which should be low enough so that the substrate is not damaged at the point of contact. Thus, any melt having a viscosity in the range of 15,000 to 100,000 cps. at 250 F. can be used. Although 250 F. is the reference temperature, the coater reservoir or extrusion temperature will generally be higher than this, e.g., 270 to 400 F. As a rule of thumb, it can be said that for each 50 F. raise in temperature, the actual viscosity will be halved. Thus, if a blend having a reference viscosity of 100,000 cps. at 250 F. were heated to 350 F., the film viscosity would be about 25,000 centipoises. The pressure in a curtain coater extruder or film former ranges generally from 5 to 20 p.s.i.g. as compared to 100 to 500 p.s.i.g. in the conventional extruder coater. The falling film flows upon the substrate to be coated, and the excess runs off, is collected, degassed and returned to the film former where the temperature and pressure desired for the particular melt is maintained. The substrate then passes over a chill roll wherein the coated material is cooled to a temperature wherein it is no longer tacky, and the coated substrate can then be rerolled on the reroller. The chiller is ordinarily cooled with refrigerated water; however, with some hot melts, a lower temperature may be required and some other cooling medium such as alcohol or ethylene glycol can be employed. The amount of cooling required is such that the coated material can be rerolled without sticking. Thus, the temperature of the chill -roll will be dependent upon the nature of the melt, the speed of the substrate, the surface area (heat transfer surface) of the chill roll and the like. In general, this temperature varies from 5 to 150 F. All of the above is known in the art as used in the coating industry not only with curtain waters, but coaters in general, and no detailed description is deemed necessary in this specification.

As far as the present invention is concerned, the temperature of the coating as it enters the nip between the pressure roll and the chill roll should be such that the coating material has set sufficiently that it will not rupture as the gas bubbles are compressed and yet retain sufficient adhesion properties to adhere to the substrate when bubbles and the like are forced by the pressure roll against the substrate. As will be understood by those skilled in the art, this temperature will be dependent upon the nature of the coating and the substrate, and each individual case will have its own range which can readily be determined by the skilled operator. This temperature will generally range from about to F., but is not necessarily limited thereto. This temperature can be regulated by controlling the temperature of the substrate and the falling film temperature and the feed rate of the substrate. This feed rate generally will vary from about 200 ft. per minute to 1000 ft. per minute or more. The film thickness will also affect the required temperature, and in turn the film thickness is affected by the rate at which hot melt is supplied to the coating head and the substrate feed rate. In general, a thickness from about 0.1 mil to 10 mils is desired. In some applications, a prechill roll can be used to control the temperature of the coating at the nip. The prechill roll also serves a useful purpose where the substrate has been previously coated on the reverse side, e.g., with thermoplastic lacquer or hot melt, in that the hot curtain can soften the underside of the substrate and the prechill -roll serves to resolidify this reverse side coating and prevent its being marred by the pressure roll.

The invention will be further described with reference to the accompanying drawings of which FIGURE 1 is a schematic illustration of a conventional curtain coater incorporating a resilient pressure roll and FIGURE 2 is a schematic of such a curtain coater utilizing a prechill roll.

FIGURE 3 is a schematic illustration of an embodiment of the invention wherein the chill roll is also utilized for prechill.

Referring now to the drawings, substrate 2. from supply roll 1 is passed over rollers 3, 4 and 5 under coating head 6 which has an elongated nozzle at its lower end so as to provide a falling film or curtain 7 which impinges on the substrate 2 thus coating same. Excess coating material from curtain 7 falls over the sides of the substrate into overflow collector 8 and is passed via conduit 9 back through a degasser (not shown) to the melt reservoir (not shown). This reservoir is equipped with suitable means for maintaining the desired temperature, e.g., internal heating coils or jacket, and a pump for delivering coating material to the coating head 6 at a controlled rate. If desired, an agitator can be provided as is known in the art. The coated substrate then passes through the nip 15 between a pressure roller 10 (preferably having a resilient surface) and chill roller 11 and over rollers 12 and 13 to rewind, not shown. In FIGURE 2, a prechill roller 14 is put ahead of rollers 10 and 11, otherwise the operation and description is the same as FIGURE 1, and the same numbers are used to illustrate the corresponding parts. The pressure between the pressure roll and chill roll can vary over a wide range, say from 10 lbs./in. of nip to 500 lbs./in. of nip and preferably from 25 to 150 lbs. per inch of nip.

Referring to FIGURE 3, the substrate after passing the gravitating film passes over roller 16 and back around chill roll 11 and then between the nip formed by chill roll 11 and resilient pressure roll 10. In this case, the chill roll serves as prechill as well as final chill. The remaining rollers are numbered as in FIGURE 1 and only so much of this embodiment is shown as to illustrate the modification.

A number of runs were made using the equipment of FIGURE 1. The pressure between the rubber roll 10 and chill roll 11 was 50 pounds per inch of nip. The resilient or rubber roll 10 had a rubber surface of 70 Shore A hardness. The chill roll was of metal finish. In all of the runs, the coating composition was a mixture of parafiin wax and ethylene-vinyl-acetate copolymer. The mixture was varied to obtain the desired viscosity at 250 F.

EXAMPLE 1 Wax blend: Viscosity at 250 F.=42,750 c.p.s.

Substrate: Aluminum foil-pouch stock laminate, coating foil side.

Melt temperature: 370 F.

Web feed rate: 800 f.p.m. (feet per minute).

Coating weight 22.3 lbs/3000 ft.

With no pressure roll, the coating contained visible bubbles. With the pressure roll at 50 lbs/inch, the bubbles were flattened and the general appearance of the coating was much improved. The flattened portions appeared to have adhered to the substrate.

EXAMPLE II Wax blend: Viscosity at 250 F.=57,250 c.p.s. Substrate: 30# blassine paper.

Coating temperature 360 F.

Web feed rate: 1100 f.p.m.

Coating weight: 10.5 lbs/3000 ft.

With no pressure roll, the coating was rough and had many air inclusions between the film and substrate. The coating was easily abraded over the air inclusions.

When the pressure roll was used, the coating was smooth and of good appearance. Adhesion and resistance to abrasion was greatly improved.

EXAMPLE III Wax blend: Viscosity at 250 F.=3,000 c.p.s.

Substrate: 30# clay-coated bleached kraft, coating nonclay side.

Coating temperature: 285 F.

Web speed: 1000 f.p.m.

Coating weight: 9.9 lbs/3000 ft.

In the absence of the pressure roll, the coating Was rough and contained many pinholes.

With pressure roll, the coating was smooth, of good appearance and apparently free of pinholes.

EXAMPLE IV Wax blend: Viscosity at 250 F.=1280 c.p.s. Substrate: 1 mil thick cellophane.

Coating temperature: 255 F.

Web speed: 275 f.p.m.

Coating weight: 38.7 lbs/3000 ft.

often desirable to pass the moving coated substrate through a reflective or insulated tunnel or additional heat can be supplied such as by infrared lights or the like to keep the coating soft prior to the substrate contacting the chill roll. In case of glassine paper, wax paper or the like being coated on the opposite side, it will be found advantageous to use the prechill roll of FIGURE 2. In case of heavy substrate, it is sometimes desirable to preheat the substrate prior to coating. Here the use of heated rolls, infrared heating, or the like would be used prior to applying the coating composition. It should also be obvious to those skilled in the art that the number of rollers shown can vary and that the passage of the coated substrate between the nip of the resilient and chill roll can vary from that shown, e.g., the substrate need not pass over the resilient roll, but by placing the chill roll on top and the resilient roll below, the substrate could pass directly to the nip 15. Other changes can be made by those skilled in the art without departing from the scope and spirit of the invention. While all of the cylindrical surfaces have been described as rollers, it is obvious that low friction stationary bars can also be used.

Having thus described the invention, we claim:

1. In a curtain coater wherein a hot melt is gravitated as a film upon a substrate to be coated and said substrate is continuously passed beneath the gravitating film and over a chill rodd spaced downstream from said gravitating film, the improvement comprising a pressure roll in alignment with said chill roll and adjacent said roll and exerting a pressure upon said chill roll and so aligned that said substrate with the resulting film passes between the nip formed between said chill roll and said pressure roll with the coated side of said substrate in contact with said chill roll and the underside of said substrate is in contact with said pressure roll.

2. In the process of coating a substrate with a hot melt coating composition by passing the substrate continuously through a gravitating liquid curtain of said hot melt and setting the melt by passing the coated substrate over a cooling cylinder being spaced downstream from said gravitating liquid curtain, the improvement comprising applying a pressure by means of a resilient roll against the uncoated side of said substrate as it passes over said cooling cylinder.

3. The improvement of claim 2 wherein the temperature of the coating is controlled so as to be only partially set when said pressure is applied.

4. The improvement of claim 3 wherein said pressure is at least 10 pounds per inch of nip between said cooling cylinder and said resilient roll.

5. The improvement of claim 3 wherein the temperature is controlled by precooling the film prior to applying said pressure.

6. In the process of coating a substrate by continuously passing said substrate through a gravitating hot curtain of the coating material and downstream from said gravitating hot curtain setting said coating by passing the coated substrate over a first rotating cylinder having means for regulating the temperature of said rotating cylinder to a temperature wherein said film is set, the improvement comprising passing said coated substrate between the nip formed by said rotating cylinder and a second rotating cylinder having a resilient surface and co-acting with said first rotating cylinder so as to apply a pressure to the backside of said substrate.

7. The improvement of claim 6 wherein said coating material is only partially set where said substrate coated with coating material enters said nip.

8. The improvement of claim 7 wherein the pressure in the nip between said first rotating cylinder and said second rotating cylinder is at least 10 pounds per inch of nip.

9. The improvement of claim 7 wherein said pressure is in the range 25 to pounds per inch of nip.

References Cited UNITED STATES PATENTS 3,284,228 11/1966 Ekstrom et al. 11765.2 2,443,222 6/1948 Bergstein 117-158 X 2,753,275 7/1956 Wiles et a1 117-155 X 2,882,182 4/1959 Tench 117--158 X 3,218,212 11/1965 Underwood 156-244 3,308,006 3/1967 Kresse et al. 161235 X 3,376,244 4/1968 Rundle 161-235 X EARL M. BERGERT, Primary Examiner T. R. SAVOIE, Assistant Examiner US. Cl. X.R.

US3462290A 1966-03-31 1966-03-31 Curtain coating process and apparatus Expired - Lifetime US3462290A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4577585A (en) * 1984-04-23 1986-03-25 Anselmo Anthony G Method and apparatus for making a color blended wall covering
US5447753A (en) * 1991-06-07 1995-09-05 Nippon Paper Industries Co., Ltd. Method of manufacturing coated paper for printing
US5611859A (en) * 1995-06-07 1997-03-18 Kimberly-Clark Corporation Apparatus for coating a strip of paper
US5795320A (en) * 1995-06-07 1998-08-18 Kimberly-Clark Worldwide, Inc. Paper applicator containing a compostable coating
WO1998047630A1 (en) * 1997-04-21 1998-10-29 Bachofen + Meier Ag Maschinenfabrik Method and device for applying dispersions on a strip of material
US5984888A (en) * 1995-06-07 1999-11-16 Kimberly-Clark Worldwide, Inc. Applicator and coating
WO2001053004A2 (en) * 2000-01-24 2001-07-26 Weirton Steel Corporation Polymeric coated metal strip and method for producing same
US20130030399A1 (en) * 2005-04-29 2013-01-31 The Procter & Gamble Company Polymeric film exhibiting improved anti-blocking characteristics and process of making

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2443222A (en) * 1945-02-23 1948-06-15 Robert Morris Bergstein Process for waxing paper
US2753275A (en) * 1952-02-05 1956-07-03 Marathon Corp Method of continuously coating paper with wax and resultant product
US2882182A (en) * 1955-08-30 1959-04-14 Sun Oil Co Method of preparing a wax coated fibrous sheet material
US3218212A (en) * 1960-06-14 1965-11-16 Union Carbide Corp Method of and apparatus for forming a clear glossy laminate
US3284228A (en) * 1962-02-14 1966-11-08 Tetra Pak Ab Method of rendering polyolefine surfaces non-adherent
US3308006A (en) * 1961-10-19 1967-03-07 Continental Oil Co Laminated corrugated paper board
US3376244A (en) * 1964-10-30 1968-04-02 Chevron Res Polypropylene wax film

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2443222A (en) * 1945-02-23 1948-06-15 Robert Morris Bergstein Process for waxing paper
US2753275A (en) * 1952-02-05 1956-07-03 Marathon Corp Method of continuously coating paper with wax and resultant product
US2882182A (en) * 1955-08-30 1959-04-14 Sun Oil Co Method of preparing a wax coated fibrous sheet material
US3218212A (en) * 1960-06-14 1965-11-16 Union Carbide Corp Method of and apparatus for forming a clear glossy laminate
US3308006A (en) * 1961-10-19 1967-03-07 Continental Oil Co Laminated corrugated paper board
US3284228A (en) * 1962-02-14 1966-11-08 Tetra Pak Ab Method of rendering polyolefine surfaces non-adherent
US3376244A (en) * 1964-10-30 1968-04-02 Chevron Res Polypropylene wax film

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4577585A (en) * 1984-04-23 1986-03-25 Anselmo Anthony G Method and apparatus for making a color blended wall covering
US5447753A (en) * 1991-06-07 1995-09-05 Nippon Paper Industries Co., Ltd. Method of manufacturing coated paper for printing
US5611859A (en) * 1995-06-07 1997-03-18 Kimberly-Clark Corporation Apparatus for coating a strip of paper
US5795320A (en) * 1995-06-07 1998-08-18 Kimberly-Clark Worldwide, Inc. Paper applicator containing a compostable coating
US5984888A (en) * 1995-06-07 1999-11-16 Kimberly-Clark Worldwide, Inc. Applicator and coating
WO1998047630A1 (en) * 1997-04-21 1998-10-29 Bachofen + Meier Ag Maschinenfabrik Method and device for applying dispersions on a strip of material
WO2001053004A2 (en) * 2000-01-24 2001-07-26 Weirton Steel Corporation Polymeric coated metal strip and method for producing same
WO2001053004A3 (en) * 2000-01-24 2002-01-10 Weirton Steel Corp Polymeric coated metal strip and method for producing same
US20130030399A1 (en) * 2005-04-29 2013-01-31 The Procter & Gamble Company Polymeric film exhibiting improved anti-blocking characteristics and process of making
US9096731B2 (en) * 2005-04-29 2015-08-04 The Procter & Gamble Company Polymeric film exhibiting improved anti-blocking characteristics and process of making
US20150314490A1 (en) * 2005-04-29 2015-11-05 The Procter & Gamble Company Polymeric Film Exhibiting Improved Anti-Blocking Characteristics and Process of Making
US9637603B2 (en) * 2005-04-29 2017-05-02 The Procter & Gamble Company Polymeric film exhibiting improved anti-blocking characteristics and process of making

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NL6701880A (en) 1967-10-02 application
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FR1511838A (en) 1968-02-02 grant

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