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Gas-expansion refrigerator

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US3431750A
US3431750A US3431750DA US3431750A US 3431750 A US3431750 A US 3431750A US 3431750D A US3431750D A US 3431750DA US 3431750 A US3431750 A US 3431750A
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tube
gas
end
expansion
invention
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Marcel Lefranc
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Philips Electronics North America Corp
Philips Corp
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Philips Corp
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures (not used)
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures (not used) requiring the use of refrigeration, e.g. of helium or hydrogen Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0257Construction and layout of liquefaction equipments, e.g. valves, machines
    • F25J1/0275Construction and layout of liquefaction equipments, e.g. valves, machines adapted for special use of the liquefaction unit, e.g. portable or transportable devices
    • F25J1/0276Laboratory or other miniature devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25BREFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT-PUMP SYSTEMS
    • F25B9/00Compression machines, plant, or systems, in which the refrigerant is air or other gas of low boiling point
    • F25B9/02Compression machines, plant, or systems, in which the refrigerant is air or other gas of low boiling point using Joule-Thompson effect; using vortex effect
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures (not used)
    • F25J1/0002Processes or apparatus for liquefying or solidifying gases or gaseous mixtures (not used) characterised by the fluid to be liquefied
    • F25J1/0005Light or noble gases
    • F25J1/001Hydrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures (not used)
    • F25J1/0002Processes or apparatus for liquefying or solidifying gases or gaseous mixtures (not used) characterised by the fluid to be liquefied
    • F25J1/0012Primary atmospheric gases, e.g. air
    • F25J1/0015Nitrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures (not used)
    • F25J1/0002Processes or apparatus for liquefying or solidifying gases or gaseous mixtures (not used) characterised by the fluid to be liquefied
    • F25J1/0012Primary atmospheric gases, e.g. air
    • F25J1/002Argon
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures (not used)
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures (not used) requiring the use of refrigeration, e.g. of helium or hydrogen Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0201Processes or apparatus for liquefying or solidifying gases or gaseous mixtures (not used) requiring the use of refrigeration, e.g. of helium or hydrogen Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using only internal refrigeration means, i.e. without external refrigeration
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00Processes or apparatus for liquefying or solidifying gases or gaseous mixtures (not used)
    • F25J1/02Processes or apparatus for liquefying or solidifying gases or gaseous mixtures (not used) requiring the use of refrigeration, e.g. of helium or hydrogen Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0221Processes or apparatus for liquefying or solidifying gases or gaseous mixtures (not used) requiring the use of refrigeration, e.g. of helium or hydrogen Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using the cold stored in an external cryogenic component in an open refrigeration loop
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00Processes characterised by the type or other details of the feed stream
    • F25J2210/42Nitrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00Processes or apparatus involving steps for expanding of process streams
    • F25J2240/40Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/42Modularity, pre-fabrication of modules, assembling and erection, horizontal layout, i.e. plot plan, and vertical arrangement of parts of the cryogenic unit, e.g. of the cold box

Description

March 11, 1969 M. LEFRANC 3,431,750

GAS-EXPANSION REFRIGERATOR Filed Nov. 7, 1966 FIG.3

INVENTR.

MARCEL i-:FRANC AGENT United States Patent 3,431,750 GAS-EXPANSION REFRIGERATOR Marcel LeFranc, Fourqueux, France, assignor to North American Philips Company Inc., New York, N.Y., a corporation of New York Filed Nov. 7, 1966, Ser. No. 592,507 Claims priority, application France, Dec. 2, 1965,

U.S. Cl. 62-514 7 Claims Int. Cl. F25j 1/00, 5 00 ABSTRACT 0F THE DISCLOSURE The invention relates to a small-size gas-expansion refrigerator.

There are already known single-expansion refrigerators of the Joule-Thompson type comprising a heat exchanger formed by a thin tube provided with ribs helically wound around a cylindrical mandril, which heat exchanger terminates in an expansion opening, the assembly being mounted in intimate frictional contact inside a tube thermally insulated by vacuum. The gas cooled by the expansion rises inside the thermally insulated tube in a counter-flow along the thin tube, which cools the gas not yet expanded, which process is cumulative and permits of liquefying the gas after a given period of time.

There are also known large liquefying or cooling systems for scientific purposes or large-scale industrial purposes, in which a cooling effect is obtained in two cooling Istages, the rst stage forming a pre-cooling stage for the second stage.

These systems are expensive, bulky and suitable only for special purposes.

The invention relates to a device of the first-mentioned kind, that is to say to a gas-expansion refrigerator and to a counteriiow heat-exchanger mounted in a tube of a high thermal insulation capacity, based on a two-stage cooling effect. The invention has for its object to provide a simple, eiiicacious, fairly cheap and small-size device.

The device according to the invention is mainly characterized in that it comprises in one tube of high thermal insulation capacity two elements, each of which comprises a heat exchanger followed 4by an expander to which the gas to be cooled is fed in parallel, whilst said elements are arranged side by side in thermal contact in said tube so that the first element operates as a preliminary cooler for the second element, arranged at the end of the tube. It is found that the eiiciency of the device is considerably higher than that of two elements mounted thermally in parallel.

The invention will be explained more fully with reference to the accompanying drawing, in which:

FIG. 1 shows partly in an exploded view the arrangement of the various elements of the tube. FIG. la shows a fragmentary and partial-sectional view of the tube.

FIG. 2 shows the form of the tube for the heat exchanger.

FIG. 3 shows the system of the connections an-d the ice circulation of the gas in the device according to the invention.

As stated above the device according to the invention comprises the parallel combination of two cooling elements A and B, mounted in the same double-walled tube or housing 7, the vacuum being maintained in the intermediate space as in the Dewar vessel. This tube is shown only diagrammatically in FIG. 3, since it is not essential for this invention. For the sake of clarity the diameter of the tube is shown on a greatly enlarged scale, and the walls of the tube dene first and second adjacent interior chambers A' and B. The heat exchanger of each of these elements operating on -a counter-flow, is formed by a nickel tube 1 (shown on an enlarged scale in FIG. 2) around which a squa-re-section silver wire 2 is wound, which serves as the ribs. The tube thus obtained is wound itself on a mandril formed by a thermal insulator, for example, of nylon, formed by two consecutive portions 50 (element A) and 51 (element B), interconnected by a `silver sleeve 52. The gas to be liquied (nitrogen or argon) enters under a high pressure to 200 bars) through an end piece 3, shown in a sectional view in FIG. l and comprising a porous copper filter 4. Two tubes 5 and 6 project from this end piece. The tube 6 is connected withthe expander 8, formed by a chamber communicating with the ambiance through an orifice of a few tenths of a mm. in diameter, which may be varied in vaccordance with the desired results. The gas escapes through two small apertures 9 of the sleeve 52, whilst being cooled, and returns along the tubes 5 and 6 in first and second passages defined between tubes (6 and 5) and (5') and the walls of chambers A and B respectively. The expander 8 thus produces the pre-cooling effect. At this place liquiiied nitrogen is accumulated in the sleeve 52. The tube 5 of nickel, not provided with ribs, is wound also around the tube 6 and the sleeve 52 and it feeds the second element B. The latter is formed substantially in the same manner as the former and comprises an exchanger with a wound wire 5 to form ribs 5 like the wire 6 of the element A and an expander 14, shown in FIG. 1 dismounted in three parts, that is to say an end piece 10 with screwthread, the end of which is provided with the disc 11 with the expansion opening and a socket 12, screwed onto the end piece 10 for mounting the assembly. The exchanger tube 5 opens out in the end piece 10 and the gas expands through the opening of the disc 11. Then the gas returns past the tube 5' (element B), and then the tubes 5 and 6 (element A). The liquilied nitrogen accumulates on the bottom of the tube 7, to which may advantageously be connected the cooling ring (not shown) of a tube of a mosaic infrared analyser, the junctions of which have to be cooled to very low temperatures. This application is, of course, not excluding other possibilities. A device .according to the invention may be employed in any case where the problems of size, manoeuvrability and low cost price are to be observed in particular.

The gases mentioned above are not the only gases that may be used; the tube 6 might be fed by nitrogen and the tube 5 by hydrogen for liquifying the latter.

The particular importance of the invention stands out in the small size, if it is considered that on this principle liquefying systems of 5 mms. in diameter and about l0 cms. in length can be constructed. The dimensions of the apparatus depend, of course, upon the cooling power and with the values mentioned above a power of 5 to 10 w. has to be envisaged.

The device according to the invention has a great adaptability in use. The expanders 8 and 14 are constructed in the same manner, so that the diameter of the openings of the discs such as 11 can be readily changed according to the gases employed and the desired powers: it is sufcient to remove the socket 12 and to replace the disc by 3 another having the appropriate opening. With the expander 8 this requires to remove the portion of the mandril 50 from the sleeve S2, which can be readily done, since the spring formed by the turns of the wire around this sleeve provides sufficient elasticity.

What is claimed is:

v1. A method of refrigerating a gas comprising the steps:

(a) fiowing a first gas through a first conduit disposed in a first passage, (b) expanding the first gas through a first valve, (c) counterfiowing the expanded gas in precooling heat exchange relationship with said first conduit and gas therein, (d) flowing a second gas through a second conduit disposed partly within said first passage and also within a second passage, (e) expanding gas in said second conduit through a second valve to a temperature lower than that in the first, (f) counterfiowing said second expanded gas in precooling heat exchange relationship with said second conduit and gas therein, (g) whereby some of the gas in said second conduit having been precooled by said first and second expanded gas, is liquefied upon the discharging and expansion thereof.

2. A gas-expansion refrigerator for use with pressurized gas from a source, comprising:

(a) a thermally-insulated housing having walls defining first and second separate parts of an interior chamber;

(b) a first tube disposed in the first part of the chamber, and a second tube disposed in both parts, first and second passages being defined in the first and second parts respectively, between said tubes and said chamber walls,

(c) each tube having an inlet for receiving said gas,

the first tube having a first expansion valve at its outlet end for discharging expanded gas at a first ternperature to counterfiow in said first passage in precooling heat exchange relationship with both tubes and gas within the tubes, the second tube having a second expansion valve at its outlet end for discharging expanded gas at a temperature lower than that at said first valve to counterow in said second passage in further precooling heat exchange relationship with said second tube.

3. Apparatus as defined in claim 2 wherein said chamber defines a longitudinal axis disposed generally vertically when the apparatus is operated with the second chamber part being below the first and having a closed bottom end, whereby liquefied gas accumulates in said closed end.

4. Apparatus as defined in claim 2 further comprising:

(a) first and second elongated mandrils disposed in end-to-end relationship, with the first and second tubes coiled around the rst and second mandrils respectively,

(b) a sleeve joining the adjacent ends of the mandrils and containing said first expansion valve therein; and

(c) a fitting carried by the remote end of the second mandril for containing the second expansion valve, which is thus situated adjacent said bottom end.

5. Apparatus as defined in claim 2 wherein the second expansion valve comprises (a) a hollow end piece into which pressurized gas from the second tube is introduced, (b) a closure member having a small aperture therein for sealing the remote end of the end piece, the aperture functioning as the expansion valve, and (c) means for securing the closure member to the end piece.

6. Apparatus as defined in claim 2 wherein the entering gas is under a pressure of about to 200 bars (millibars).

7. Apparatus as defined in claim 2 wherein at least one of said tubes comprises:

(a) a nickel conduit, and

(b) silver wire wound helically around the tube and secured thereto, the tube then formed into a helical coil with the silver wire extending therefrom as heatexchange elements.

References Cited UNITED STATES PATENTS 2,991,633 7/1961 Simon 62-514 3,018,643 l/l962 Evers 62-514 XR 3,055,192 9/1962 Dennis 62-514 XR 3,063,260 11/1962 Dennis 62-514 XR 3,095,711 7/1963 Wurtz 62-5l4 3,326,015 6/1967 Webster 62-514 MEYER PERLIN, Primary Examiner.

U.S. Cl. X.R. 62-467

US3431750A 1965-12-02 1966-11-07 Gas-expansion refrigerator Expired - Lifetime US3431750A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR40592A FR1465656A (en) 1965-12-02 1965-12-02 Cooler gas expander

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US3431750A true US3431750A (en) 1969-03-11

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US3431750A Expired - Lifetime US3431750A (en) 1965-12-02 1966-11-07 Gas-expansion refrigerator

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US (1) US3431750A (en)
BE (1) BE690641A (en)
DE (1) DE1501106A1 (en)
FR (1) FR1465656A (en)
GB (1) GB1114659A (en)
NL (1) NL6616749A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3590597A (en) * 1968-08-06 1971-07-06 Hymatic Eng Co Ltd Cooling apparatus employing the joule-thomson effect
US3714796A (en) * 1970-07-30 1973-02-06 Air Prod & Chem Cryogenic refrigeration system with dual circuit heat exchanger
WO1998017167A2 (en) * 1996-10-07 1998-04-30 Cryogen, Inc. Precooling system for joule-thomson probe
WO1999057494A1 (en) * 1998-05-07 1999-11-11 Cryogen, Inc. Precooling system for joule-thomson probe
US6151901A (en) * 1995-10-12 2000-11-28 Cryogen, Inc. Miniature mixed gas refrigeration system
US6182666B1 (en) 1996-12-26 2001-02-06 Cryogen, Inc. Cryosurgical probe and method for uterine ablation
US6237355B1 (en) 1999-06-25 2001-05-29 Cryogen, Inc. Precooled cryogenic ablation system
US6270494B1 (en) 1996-12-26 2001-08-07 Cryogen, Inc. Stretchable cryoprobe sheath
US6306129B1 (en) 1997-09-22 2001-10-23 Femrx, Inc. Cryosurgical system and method
US20080087030A1 (en) * 2006-10-17 2008-04-17 In Woong Park Water-cooled air conditioner

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4237699A (en) * 1979-05-23 1980-12-09 Air Products And Chemicals, Inc. Variable flow cryostat with dual orifice
FR2568357B1 (en) * 1984-07-25 1987-01-30 Air Liquide Method and quench probe by Joule-Thomson effect
DE3941314A1 (en) * 1989-12-14 1991-06-20 Bodenseewerk Geraetetech Kuehlvorrichtung
DE4135764C1 (en) * 1991-10-30 1993-02-25 Bodenseewerk Geraetetechnik Gmbh, 7770 Ueberlingen, De

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2991633A (en) * 1958-03-17 1961-07-11 Itt Joule-thomson effect cooling system
US3018643A (en) * 1959-09-15 1962-01-30 Philco Corp Cryogenic refrigerating means
US3055192A (en) * 1960-12-01 1962-09-25 Specialties Dev Corp Cooling apparatus
US3063260A (en) * 1960-12-01 1962-11-13 Specialties Dev Corp Cooling device employing the joule-thomson effect
US3095711A (en) * 1962-01-31 1963-07-02 Jr Howard P Wurtz Double cryostat
US3326015A (en) * 1965-07-07 1967-06-20 British Oxygen Co Ltd Gas liquefier

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2991633A (en) * 1958-03-17 1961-07-11 Itt Joule-thomson effect cooling system
US3018643A (en) * 1959-09-15 1962-01-30 Philco Corp Cryogenic refrigerating means
US3055192A (en) * 1960-12-01 1962-09-25 Specialties Dev Corp Cooling apparatus
US3063260A (en) * 1960-12-01 1962-11-13 Specialties Dev Corp Cooling device employing the joule-thomson effect
US3095711A (en) * 1962-01-31 1963-07-02 Jr Howard P Wurtz Double cryostat
US3326015A (en) * 1965-07-07 1967-06-20 British Oxygen Co Ltd Gas liquefier

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3590597A (en) * 1968-08-06 1971-07-06 Hymatic Eng Co Ltd Cooling apparatus employing the joule-thomson effect
US3714796A (en) * 1970-07-30 1973-02-06 Air Prod & Chem Cryogenic refrigeration system with dual circuit heat exchanger
US6530234B1 (en) 1995-10-12 2003-03-11 Cryogen, Inc. Precooling system for Joule-Thomson probe
US5758505A (en) * 1995-10-12 1998-06-02 Cryogen, Inc. Precooling system for joule-thomson probe
US6151901A (en) * 1995-10-12 2000-11-28 Cryogen, Inc. Miniature mixed gas refrigeration system
WO1998017167A2 (en) * 1996-10-07 1998-04-30 Cryogen, Inc. Precooling system for joule-thomson probe
WO1998017167A3 (en) * 1996-10-07 1998-09-03 Cryogen Inc Precooling system for joule-thomson probe
US6182666B1 (en) 1996-12-26 2001-02-06 Cryogen, Inc. Cryosurgical probe and method for uterine ablation
US6193644B1 (en) 1996-12-26 2001-02-27 Cryogen, Inc. Cryosurgical probe with sheath
US6451012B2 (en) 1996-12-26 2002-09-17 Cryogen, Inc. Cryosurgical method for endometrial ablation
US6270494B1 (en) 1996-12-26 2001-08-07 Cryogen, Inc. Stretchable cryoprobe sheath
US6475212B2 (en) 1996-12-26 2002-11-05 Cryogen, Inc. Cryosurgical probe with sheath
US6306129B1 (en) 1997-09-22 2001-10-23 Femrx, Inc. Cryosurgical system and method
WO1999057494A1 (en) * 1998-05-07 1999-11-11 Cryogen, Inc. Precooling system for joule-thomson probe
US6237355B1 (en) 1999-06-25 2001-05-29 Cryogen, Inc. Precooled cryogenic ablation system
USRE40049E1 (en) * 1999-06-25 2008-02-12 Ams Research Corporation Precooled cryogenic ablation system
US20080087030A1 (en) * 2006-10-17 2008-04-17 In Woong Park Water-cooled air conditioner
US8281614B2 (en) 2006-10-17 2012-10-09 Lg Electronics Inc. Water-cooled air conditioner
US8286445B2 (en) * 2006-10-17 2012-10-16 Lg Electronics Inc. Water-cooled air conditioner

Also Published As

Publication number Publication date Type
NL6616749A (en) 1967-06-05 application
BE690641A (en) 1967-06-02 grant
FR1465656A (en) 1967-01-13 grant
GB1114659A (en) 1968-05-22 application
DE1501106A1 (en) 1970-01-08 application

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