US340023A - Coating metal for wire-drawing - Google Patents
Coating metal for wire-drawing Download PDFInfo
- Publication number
- US340023A US340023A US340023DA US340023A US 340023 A US340023 A US 340023A US 340023D A US340023D A US 340023DA US 340023 A US340023 A US 340023A
- Authority
- US
- United States
- Prior art keywords
- wire
- rods
- coating metal
- copper
- lime
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000576 coating method Methods 0.000 title description 4
- 238000005491 wire drawing Methods 0.000 title description 4
- 239000011248 coating agent Substances 0.000 title description 3
- 239000002184 metal Substances 0.000 title 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 7
- 235000011941 Tilia x europaea Nutrition 0.000 description 7
- 239000004571 lime Substances 0.000 description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 235000011167 hydrochloric acid Nutrition 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- -1 or soapstone Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M103/00—Lubricating compositions characterised by the base-material being an inorganic material
- C10M103/06—Metal compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
- C10M125/14—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
Definitions
- ⁇ Vhen iron is reduced by the drawing process. It is often necessary, in case a great reduction in diameter is desired, that the wire be frequently annealed and cleaned. If many successive drawings be effected without the intermediateannealingand cleaning, fractures will develop in the wire, the die will become I worn and roughened, and the wire will be roughened.
- the bath is applied to the rods by pouring or by dipping. After the rod or wire is thus treated it is dried, preferably in the baking oven. After the drying, the rod or wire'is subjected to the usual process of wire draw- 5 ing, except that itcan be drawn finer without fracture or roughening than has heretofore been the case.
- the bath may be prepared in either of several ways.
- a solution of copper chloride 40 may have added to it the lime or other added matter; or salt may be added to a solution of copper sulphate, (blue vitriol.)
- the chlorine of the salt combines with the copper and forms the copper chloride, while the sodium of the salt combines with the sulphuric acid and forms sodium sulphate.
- the lime or other matter may then be added, or it may have been put in with the salt; or a solution of copper sulphate and a solution of salt may be mixed, hot or cold, together with the lime, or alumina, 0 or soapstone.
- the solution may, ifdesired, be drawn off from the sodium-sulphate precipitate.
- Muriatic acid added to the bath to acid reaction is found to promote the deposition of the coating upon the rod on wire.
- the rod or wire becomes coated with copper in fine form, together with a fine powder of the 'lime, alumina, or soapstone.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Metal Extraction Processes (AREA)
Description
t t L STAT S ATENT Fries.
GEORGE W. WHYTE, OF ANN ARBOR, MICHIGAN, ASSIGNOR, BY MESNE AS- SIGNMENTS, TO SAID \VHYTE, AND J OHI\ CAHILL, OF JOLIET, ILLINOIS.
COATING METAL FOR WIRE-DRAWING.
SPECIFICATION forming part of Letters Patent No. 340,023, dated April 13, 1886.
Application filed January 18, 1886. Serial No. 188,975. (No specimens.)
To all whom, it may concern.-
Be it known that I, GEORGE W. WHYTE, of Ann Arbor, Vashtenaw county, Michigan, have invented certain new and. useful Im- 5 provementsiuthe'lreatment of Iron for \Vire- Drawing, of which the following is a specification.
\Vhen iron is reduced by the drawing process. it is often necessary, in case a great reduction in diameter is desired, that the wire be frequently annealed and cleaned. If many successive drawings be effected without the intermediateannealingand cleaning, fractures will develop in the wire, the die will become I worn and roughened, and the wire will be roughened.
\Vire-drawing withoutintermediate an nealing and cleaning is termed hard-drawing, and has heretofore been applied with ordinary wire rods only to slight reductions in diameter.
In the execution of my improvements Isubject the rods or wires to be drawn to a coating process, which permits hard-drawing to be 2 carried further than has been possible heretofore.
I treat the wire or rod to be drawn to a bath of copper solution, with which isincorporated lime, alumina, or soapstone, alone or together.
The bath is applied to the rods by pouring or by dipping. After the rod or wire is thus treated it is dried, preferably in the baking oven. After the drying, the rod or wire'is subjected to the usual process of wire draw- 5 ing, except that itcan be drawn finer without fracture or roughening than has heretofore been the case.
The bath may be prepared in either of several ways. Thus a solution of copper chloride 40 may have added to it the lime or other added matter; or salt may be added to a solution of copper sulphate, (blue vitriol.) The chlorine of the salt combines with the copper and forms the copper chloride, while the sodium of the salt combines with the sulphuric acid and forms sodium sulphate. The lime or other matter may then be added, or it may have been put in with the salt; or a solution of copper sulphate and a solution of salt may be mixed, hot or cold, together with the lime, or alumina, 0 or soapstone. In thus making the copper chloride the solution may, ifdesired, be drawn off from the sodium-sulphate precipitate.
Muriatic acid added to the bath to acid reaction is found to promote the deposition of the coating upon the rod on wire.
The rod or wire becomes coated with copper in fine form, together with a fine powder of the 'lime, alumina, or soapstone.
The following formula may be followed with 5 satisfaction: Take copper sulphate about fifty per cent, by weight; alumina, lime, or soapstone, or a mixture of them, about ten per cent, by weight; water in quantity to form the slime; muriatic acid to acid reaction, and 6 heat the bath to about boiling. Apply, preferably hot, to rods or wire, dry the rods or wire, and wire-draw, as usual.
I desire to make mention of the fact that it is not new, broadly, to coat wire with a film 7o ofcopperto facilitate d rawing the wirethrough the die in its further reduction. To this I make no claim.
I claim as my invention- That improvement in the art oftreatiug rods 5 or wire in wire-drawing which consists in subjecting the rods or wires to a bath of copper solution and alumina, lime, or soapstone, drying the treated rods or wire, and then reducing the diameter of the rods or wire by wire -drawing process, substantially as set forth.
GEO. \V. \VHYTE.
Vitnesses:
J. W. SEE, W. A. SEWARD.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US340023A true US340023A (en) | 1886-04-13 |
Family
ID=2409107
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US340023D Expired - Lifetime US340023A (en) | Coating metal for wire-drawing |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US340023A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050230383A1 (en) * | 2004-03-01 | 2005-10-20 | Kraft Foods Holdings, Inc. | Multi-purpose food preparation kit |
-
0
- US US340023D patent/US340023A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050230383A1 (en) * | 2004-03-01 | 2005-10-20 | Kraft Foods Holdings, Inc. | Multi-purpose food preparation kit |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102753714A (en) | Magnesium-lithium alloy, rolling material, model product and preparation method thereof | |
| NO119299B (en) | ||
| GB1593509A (en) | Process for coating stainless steel strip with a lead/tin alloy | |
| DE3242625A1 (en) | METHOD FOR THE PRODUCTION OF HOT-GALVANIZED STEEL SHEETS | |
| EP3906328A1 (en) | Aluminum-based coating for flat steel products for press mold hardening components, and method for producing same | |
| US340023A (en) | Coating metal for wire-drawing | |
| US2159510A (en) | Method of coating copper or its alloys with tin | |
| US2921865A (en) | Method of forming cold extrusion lubricants having a zinc phosphate undercoating | |
| US3161549A (en) | Solution for forming zinc phosphate coatings on metallic surfaces | |
| US3712826A (en) | Method of improving the surface of galvanized steel material | |
| JPS63238921A (en) | Drawing method for steel materials | |
| US3398010A (en) | Masking composition for galvanized metal | |
| JPS6115132B2 (en) | ||
| JP2004115908A (en) | Method of producing coated steel product, the steel product, and coating composition | |
| DE2601067A1 (en) | PROCESS FOR FIRE-DIPPING ALUMINATION OF COMPACT PRODUCTS MADE OF IRON ALLOYS | |
| DE3835789A1 (en) | IMPROVED METHOD FOR PRODUCING SEAMLESS TUBES AND SIMILAR ITEMS FROM A TITANIUM ALLOY | |
| US3160481A (en) | Mate tin plate | |
| US1832979A (en) | Method of cleaning metals | |
| JP2012219365A (en) | Manufacturing method of metallic material for plastic woking and worked metal product | |
| RU2345963C1 (en) | Protective technical coating for steel and alloys | |
| US2527828A (en) | Method of coating zinc base alloys | |
| US705456A (en) | Iridescent coating of copper, bronze, or like surfaces. | |
| US288150A (en) | aikee | |
| US2032700A (en) | Process of heating steel for hardening | |
| JP2756318B2 (en) | Flux for hot-dip Zn-Al alloy plating |