US3397428A - Apparatus for the preparation of thermoplastic resinous composite articles - Google Patents

Apparatus for the preparation of thermoplastic resinous composite articles Download PDF

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Publication number
US3397428A
US3397428A US38973264A US3397428A US 3397428 A US3397428 A US 3397428A US 38973264 A US38973264 A US 38973264A US 3397428 A US3397428 A US 3397428A
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apparatus
thermoplastic resinous
die
generally
stream
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Donald Harold Jack
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Dow Chemical Co
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Dow Chemical Co
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C47/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C47/08Component parts, details or accessories; Auxiliary operations
    • B29C47/12Extrusion nozzles or dies
    • B29C47/14Extrusion nozzles or dies with broad opening, e.g. for sheets
    • B29C47/145Extrusion nozzles or dies with broad opening, e.g. for sheets specially adapted for bringing together components, e.g. melts within the die
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C47/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C47/04Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor of multilayered or multi-component, e.g. co-extruded layers or components or multicoloured articles or coloured articles
    • B29C47/06Multilayered articles or multi-component articles
    • B29C47/065Multilayered articles or multi-component articles with components in layered configuration, i.e. components merging at their long sides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C47/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C47/0009Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the articles
    • B29C47/0021Flat flexible articles, e.g. sheets, foils or films

Description

20, 1968 J. DONA 3,397,428

APPARATUS R PREPARATI OF THEMOPLASTIC INOUS COMPO E ARTICLES Filed Aug. 1964 INVENTOR. Hare/a 40k flona/a BY fizz Q2 7 HGE/VT We 7'TORNEY United States Patent APPARATUS FOR THE PREPARATION OF THER- MOPLASTIC RESINOUS COMPOSITE ARTICLES Harold Jack Donald, Midland, Mich., assignor to The Dow Chemical Company, Midland, Mich., a corporation of Delaware Filed Aug. 14, 1964, Ser. No. 389,732 4 Claims. (CI. 18-13) ABSTRACT OF THE DISCLOSURE Multilayer film or sheet is prepared by providing a heat plastified stream of at least two components generally concentrically arranged, to a sheeting die having a restrictor bar supported within the cavity, the bar being generally parallel and spaced from the extrusion slot.

This invention relates to the preparation of composite thermoplastic sheets. It more particularly relates to apparatus for the extrusion lamination of such articles.

Oftentimes it is desirable to prepare synthetic resinous film and sheet wherein a plurality of components are arranged in laminar fashion to provide desired characteristics. Many methods and techniques have been used including the preparation of individual films or sheets and lamination by means of adhesives or by utilizing one of the layers as a melt adhesive. In general such techniques are generally time consuming and expensive and do not ofier the choice of varying thickness of the various layers of the laminates without difliculty. For example, where various layers are prepared by means of adhering two or more sheets together, sheets must be obtained of the desired thickness and subsequently laminated.

In certain instances laminated sheets are prepared by extruding two or more separate layers and combining within a die. This technique usually involves a generally coaxial construction which may be referred to as a diewithin-a-die wherein two coplanar slots are utilized, one of the slots being an extrusion slot of a die disposed within another die. Such a configuration results in 'a three layer film wherein the outer layers are of like material and the inner layer originates from the inner die. Such an arrangement is generally expensive and not readily prepared from conventional slot of sheeting dies without extensive modific'atiion.

It is an object of this invention to provide a versatile and simple apparatus for the preparation of laminated thermoplastic resinous materials.

It is an object of this invention to provide an improved simplified apparatus for the preparation of laminated film and sheeting.

A further object of the invention is to provide apparatus for the preparation of laminates in substantially a single operation.

A further object of the invention is to provide apparatus which permits ready control of the thickness of the various layers of the laminate.

These features and other advantages in accordance with the present invention are achieved in a process for the extrusion of a thermoplastic resinous sheet or film wherein a heat plastified thermoplastic resinous material is eX- truded as 'a sheet and cooled below its thermoplastic temperat-ure, the improvement which comprises providing to a sheeting die a stream of thermoplastic resinous material, the stream comprising an inner portion and an outer portion generally concentrically arranged, passing the stream into a configuration adapted to form the stream into a sheet-like configuration, restraining the flow of the thermoplastic resinous materials within at least a central portion of the configuration in a direction generally 3,397,428 Patented Aug. 20, 1968 parallel to the transverse direction of the sheet to cause 'a generally even distribution of the inner portion of thermoplastic resinous material between generally uniform layers of the outer portion of the sheet.

The method employed with the present invention is readily practiced utilizing a sheet or slot extrusion die having an internal passage adapted to receive concentric streams of heat plastified thermoplastic resinous material, a pair of spaced apart die lips so constructed and arranged as to form an elongated extrusion slot or orifice, the extrusion slot or orifice being in communication with the internal passage, a flow restricting means disposed within the internal passage extending longitudinally within the passage in the direction of the extrusion slot, and being spaced from the walls of the internal passageway, the flow restrictor being so constructed and arranged so as to distribute concentric streams of thermoplastic resinous material entering the passageway in a generally uniform manner along at least a major portion of the length of the extrusion slot.

Further features and advantages of the present invention will become more apparent when the following specification is taken in connection with the drawing wherein:

FIGURE 1 is a cutaway schematic representation of a device in accordance with an apparatus in accordance with the present invention;

FIGURE 2 is a section of a die of FIGURE 1 taken along the line 22;

FIGURE 3 depicts a side view of an end plate of the device of FIGURE 1;

FIGURE 4 is a view of an alternate form of flow restrictor;

FIGURE 5 is an end view of the flow restrictor of FIGURE 4;

FIGURE 6 is a schematic representation of the distribution of thermoplastic resinous materials issuing from a die such as that of FIGURE 2 when the flow restrictor is removed;

FIGURE 7 is a schematic representation of the distribution of the thermoplastic resinous material when utilizbit holders for use with conventional socket membres. ing an extrusion die having a flow restrictor therein.

In FIGURE 1 there is illustrated a cutaway schematic representation of an apparatus generally designated by the reference numeral 10. The apparatus 10 comprises in cooperative combination a first extruder 12 adapted to deliver a stream of thermoplastic resinous material 13 to a conduit 14, a second extruder 16 adapted to deliver a thermoplastic resinous stream 18 to a conduit 19. The conduit 14 has a discharge opening 21 remotely disposed from the extruder 12 and the conduit 19 has a discharge opening 23 remotely disposed from the extruder 16. The conduits 14 and 16 are so constructed and arranged so that the discharge openings 21 and 23 are adapted to discharge a generally coaxial composite stream of thermoplastic resinous material comprising an annular stream formed from the stream 18 and a centrally disposed stream 13. The terminal portions of the conduits 14 and 19 discharge into a die generally designated by the reference numeral 25. The die 25 comprises an elongated die body 27 defining an extrusion slot or orifice 28, an entrance passageway 29 in operative communication with the conduit 18 which delivers a coaxially arranged stream of heat plastified thermoplastic resinous material to a cavity 31 defined by the die bodies 27. The entrance passageway 29 is remotely disposed from the extrusion orifice 28. The elongated cavity 31 is terminated at either end by end caps or plates 33 and 34. Disposed within the cavity 31 is a flow restrictor 35 supported by the end plates 33 and 34 and in spaced relationship to the walls of the housing 27 defining the cavity 31. A composite sheet 38 is shown emerging from the extrusion orifice 28.

In FIGURE 2 there is illustrated a cross section of the die 27 taken along the line 22 illustrating the internal configuration of the cavity 31, the flow restrictor and the extrusion orifice 38 which illustrates the spaced relationship of the flow restrictor 35 from the walls of the housing 27 defining the cavity 31.

FIGURE 3 depicts an end view of an end plate such as the plate 34 having therein mounting or bolt holes 40 for attachment to the die body 27 and an opening 41 adapted to receive a bolt to support the flow restrictor 35. Beneficially the plate 34 is somewhat larger than the cross section of the die body 27 and the mounting holes 40 and the openings 41 are made larger than the bodies of the bolts which they receive thereby permitting the flow restrictor 35 to be selectively positioned within the cavity 31. The flow restrictor 35 of the embodiment of FIG- URES 1 and 2 is generally cylindrical in nature.

However, in certain instances it is desirable to employ a noncylindrical flow restrictor such as that illustrated in FIGURES 4 and 5. The flow restrictor of FIGURES 4 and 5 generally designated by the reference numeral 45 comprises a body 46 having a leading edge 47 adapted to initially engage the coaxial stream issuing from the passageway such as the passageway 29. The flow restrictor 45 has two curved surfaces of a generally similar nature 48 and 49 which diverge from each other adjacent the leading edge 47 and terminate at a trailing edge 50 remotely disposed from the leading edge 47. The body 46 is so constructed and arranged so that the opposed surfaces 48 and 49 remote from the leading and trailing edges are spaced at a greater distance in the central region than at the ends 52 and 53 of the body 46. Oppositely disposed threaded apertures 55 and 56 are provided in the ends 52 and 53 respectively in order to facilitate the mounting or positioning of the flow restrictor within the cavity such as the cavity 31 of the embodiment of FIG- URES 1 and 2. In combination with a die housing such as the housing 27, the flow restrictor 45 serves to provide a pair of selectively restricted internal passageways providing communication between the extrusion orifice 38 and the inlet passageway 29.

In FIGURE 6 there is illustrated a schematic representation of a film or sheet 60 wherein the width has been reduced and the thickness increased for the convenience of illustration. The sheet 60 comprises a first thermoplastic resinous material 61 encapsulated within a second thermoplastic resinous material 62. Although the sheet 60 has a generally rectangular configuration the portion 61 has a generally elliptical configuration of the inner layer from the generally rectangular configuration of FIG- URE 7.

In operation of the apparatus of the present invention, multilayer sheets are readily prepared from any extrudable thermoplastic resinous material. Particularly advantageous are those materials which comprise tarnsparent polymers or which may be extruded into thin transparent films. The resultant products are readily adapted to a wide variety of uses as the surface characteristics of the film are generally determined by the thermoplastic material utilized to form the surface of the product and the physical characteristics by the inner or encapsulated polymeric material such as the layers 61 and 66 of FIGURES 6 and 7, respectively. Thus, for example, the apparatus of the present invention is particularly suited for the preparation of composite films wherein polypropylene is encapsulated or laminated between two layers of polyethylene. The heat sealing characteristics of the polyethylene are admirably suited for such applications as bread overwraps, while the polypropylene in the center layer provides stiffness and rigidity lacking in the polyethylene. Further the optical characteristics of such combined films are beneficially improved and increased clarity is obtained.

For example, utilizing an apparatus generally as illustrated in FIGURE 1, a 1 mil composite film is readily prepared by extruding from extruder 12 a stream of linear polypropylene at a rate of about 40 pounds per hour. The extruder 16 provides a stream of polyethylene at a rate of about 30 pounds per hour. The resultant film had a thickness of 0.80 mil and had a relatively uniform distribution of the polypropylene with the polyethylene. The

extrusion conditions for the outer layer, that is, temperature rate and the like, is substantially that of the polymer alone. However, the encapsulated layer exhibis wider tolerance in temperature than when extruded alone. The generally cylindrical spreader bar or flow restrictor 35 of the embodiment illustrated in FIGURE 1 is eminently satisfactory for systems wherein the heat plastified thermoplastic resinous streams have flow viscosities at their extrusion temperatures within about the same order of magnitude. The resultant film or sheet is generally satisfactory for all but the most precise requirements. When an extremely uniform film is required, that is, one wherein the relative thickness of the layers is substantially constant across a major portion of the width. The spreader bar illustrated in FIGURES 4 and 5 is employed. A spreader bar such as the spreader bar 45 in cooperative combination with a housing such as the housing 27 tends to equalize the pressure drop alonga streamline extending from the die orifice such as the orifice 38 to the polymer inlet passageway 29. Similarly in cases where the cavity 31 has a small cross sectional area relative to its length a fiow restrictor of nonuniform cross section is generally desirable. Inherently the apparatus of the present invention prepares a film or sheet on which the central layer does not extend to the outer edges thereof. However, this is an advantage rather than a disadvantage in that such edges are trimmed from the sheet or film and discarded as scrap. The configuration of the film or sheet as prepared in accordance with the present invention is particularly beneficial in that the portion trimmed away may comprise essentially material of the second stream only and thereby returned and utilized as feed stock for the second extruder either alone or in admixture with virgin polymer. The thermoplastic resinous compositions employed in the present invention may include dyes, pigments, stabilizers and similar well known additives. Frequently it is advantageous when initially adjusting a dye to employ a colored composition or a composition containing a small quantity of an opaque filler in the first stream, such as the stream supplied by the extruder 12. In this way the configuration of the inner layer is readily determined by the measurement of optical density. For most composite sheets and films visual observation of the extruded film is sufiiciently accurate to provide a satisfactory product.

When utilizing a positionable bar such as the bar 35 of FIGURES 1 and .2, a thickness of the outer layers of the composite sheet are readily controlled by displacing the bar toward one or the other of the walls of the cavity 31. Such adjustment is readily accomplished by loosening the bolts holding the end plates 34 and positioning the spreader bar and end plates as a unit. Alternately, for more extreme variations the bar 35 is positioned relative to the plate 34 by loosening the appropriate bolts. If desired, more complicated bar adjusting apparatus may be employed if it is desired to position the bar 35 while the unit is in operation.

As is apparent from the foregoing specification, the apparatus of the present invention is susceptible of being embodied with various alterations and modifications which may differ particularly from those that have been described in the preceding specification and description. For this reason, it is to be fully understood that all of the foregoing is intended to be merely illustrative and is not to be construed or interpreted as being restrictive or otherwise limiting of the present invention, excepting as it is set forth and defined in the hereto appended claims.

What is claimed is:

1. An apparatus for the preparation of a multilayer sheet comprising in cooperative combination a slot extrusion die having an internal passage adapted to receive concentric streams of heat plastified thermoplastic resinous material from an entrance passageway, a pair of spaced apart die lips so constructed and arranged so as to form an elongated extrusion orifice, the extrusion die defining a cavity therein having walls and ends, the walls being generally parallel to the orifice, the cavity providing communication with the internal passage and the extrusion orifice, an elongate flow restricting means disposed within the internal passage extended longitudinally within the passage in a direction of the extrusion slot and being spaced from the entrance passageway and the internal surface of the die defining the cavity between the entrance passageway and the slot, means to deliver a first stream of heat plastified thermoplastic resinous material to a first conduit, a means adapted to deliver a second stream of heat plastified thermoplastic resinous material to a second conduit, a first conduit and a second conduit, each of the conduits having first ends adapted to receive heat plastified thermoplastic resinous material from the first and second means to deliver, respectively, the first conduit and the second conduit having discharge ends generally concentrically arranged so as to deliver concentric streams of heat plastified thermoplastic resinous material to the entrance passageway.

2. The apparatus of claim 1 wherein the fiow restrictor is a generally cylindrical bar disposed within the extrusion die and adjustably supported by a pair of end plates.

3. The apparatus of claim 1 wherein the flow restrictor is an elongated bar disposed within the internal passage and having a trailing edge and a leading edge, the leading edge being positioned adjacent the source of the concentric streams, the trailing edge being positioned generally adjacent the extrusion orifice, and restricting How of material within the internal passageway to a greater degree in the center portion thereof than at the end portions thereof.

4. The apparatus of claim 1 wherein the means to provide the first and second heat plastified streams are first and second extruders, respectively.

References Cited UNITED STATES PATENTS 1,245,898 11/1917 Gates 1812 2,090,404 8/ 1937 Parkhurst l812 2,402,281 6/1946 Green 264-177 3,274,646 9/1966 Krystof 1813 3,290,727 12/1966 Patzetakis 18-13 ROBERT F. WHITE, Primary Examiner.

G. AUVILLE, Assistant Examiner.

US3397428A 1964-08-14 1964-08-14 Apparatus for the preparation of thermoplastic resinous composite articles Expired - Lifetime US3397428A (en)

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Cited By (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3487505A (en) * 1967-08-21 1970-01-06 Dow Chemical Co Laminates
US3528130A (en) * 1965-07-22 1970-09-15 Dow Chemical Co Extrusion apparatus
US3729889A (en) * 1970-09-14 1973-05-01 Pet Inc Modular insulated panel system
US3860372A (en) * 1971-02-26 1975-01-14 Dow Chemical Co Adjustable feedblock for encapsulated multilayer extrusion
US4221757A (en) * 1978-01-20 1980-09-09 Produits Chimiques Ugine Kuhlmann Polyvinylidene fluoride-polyurethane laminates and method
US4415519A (en) * 1978-09-25 1983-11-15 Produits Chimiques Ugine Kuhlmann Method of making polyvinylidene fluoride-thermoplastic resin laminates
WO1986002316A1 (en) * 1984-10-12 1986-04-24 Princeton Packaging, Inc. Two-color sheet, article, method and apparatus
US4592938A (en) * 1985-03-25 1986-06-03 Mobil Oil Corporation Method of producing an internally reinforced thermoplastic film and film and articles produced therefrom
US4619802A (en) * 1984-05-21 1986-10-28 Peter Cloeren Die with combining adaptor insert and melt-lamination process
US4780258A (en) * 1987-07-17 1988-10-25 P.C.E. Corp. Coextruded laminate having barrier layers
US4784815A (en) * 1987-06-05 1988-11-15 P.C.E. Corp. Edge-laminating apparatus and process
US4789513A (en) * 1987-06-05 1988-12-06 P.C.E. Corp. Coextrusion apparatus and process
US4937031A (en) * 1988-11-18 1990-06-26 General Electric Company Process for preparing thermoplastic composites
US5190711A (en) * 1988-06-09 1993-03-02 American National Can Company Methods for processing polymers
US5234330A (en) * 1991-06-14 1993-08-10 Eastman Kodak Company Dies
US5375990A (en) * 1992-09-10 1994-12-27 Extrusion Dies, Inc. Feed block for coextrusion apparatus
US5780067A (en) * 1996-09-10 1998-07-14 Extrusion Dies, Inc. Adjustable coextrusion feedblock
US5848769A (en) * 1996-08-26 1998-12-15 Minnesota Mining & Manufacturing Company Drag reduction article
US5882774A (en) * 1993-12-21 1999-03-16 Minnesota Mining And Manufacturing Company Optical film
US5976424A (en) * 1996-07-31 1999-11-02 Minnesota Mining And Manufacturing Company Method for making multilayer optical films having thin optical layers
US6245401B1 (en) 1999-03-12 2001-06-12 Kimberly-Clark Worldwide, Inc. Segmented conformable breathable films
US20010046086A1 (en) * 1998-12-23 2001-11-29 3M Innovative Properties Company Polymeric interference film
US6583930B1 (en) 1989-06-20 2003-06-24 3M Innovative Properties Birefringent interference polarization
US6626206B1 (en) 2000-01-20 2003-09-30 Extrusion Dies, Inc. Feedblock for adjusting the dimensions of a set of co-extruded layers of a multi-layer sheet
US20050271861A1 (en) * 2004-06-08 2005-12-08 3M Innovative Properties Company Coextruded profiled webs
US20060147686A1 (en) * 2004-12-30 2006-07-06 3M Innovative Properties Company Method of extruding articles
US20070172628A1 (en) * 2006-01-25 2007-07-26 3M Innovative Properties Company Intermittently bonded fibrous web laminate
US20070194482A1 (en) * 2006-02-21 2007-08-23 Bfs Diversified Products, Llc Co-extrusion process for preparing roofing membranes
US20080009821A1 (en) * 2006-07-10 2008-01-10 3M Innovative Properties Company Net hook fasteners
US20080138598A1 (en) * 2006-12-08 2008-06-12 3M Innovative Properties Company Apparatus and Method for Co-Extrusion of Articles Having Discontinuous Phase Inclusions
US20090137168A1 (en) * 2005-08-29 2009-05-28 Richard Peng Thermoplastic roofing membranes
US20090181216A1 (en) * 2006-02-17 2009-07-16 Peng Lichih R Roofing Membranes Including Fluoropolymer
US20090269565A1 (en) * 2006-05-18 2009-10-29 Richard Peng Polymeric laminates including nanoclay
US7852560B2 (en) 1993-12-21 2010-12-14 3M Innovative Properties Company Display incorporating reflective polarizer

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US1245898A (en) * 1916-07-25 1917-11-06 Revere Rubber Co Die for tire-tubing machines.
US2090404A (en) * 1936-10-22 1937-08-17 Fiberloid Corp Machine for extruding plastic material
US2402281A (en) * 1943-10-11 1946-06-18 Lee B Green Extrusion molding
US3274646A (en) * 1963-05-13 1966-09-27 Rowlaud Products Inc Apparatus for making extruded sheet material
US3290727A (en) * 1961-09-05 1966-12-06 Petzetakis Aristovoulos George Apparatus for forming composite elements

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Publication number Priority date Publication date Assignee Title
US1245898A (en) * 1916-07-25 1917-11-06 Revere Rubber Co Die for tire-tubing machines.
US2090404A (en) * 1936-10-22 1937-08-17 Fiberloid Corp Machine for extruding plastic material
US2402281A (en) * 1943-10-11 1946-06-18 Lee B Green Extrusion molding
US3290727A (en) * 1961-09-05 1966-12-06 Petzetakis Aristovoulos George Apparatus for forming composite elements
US3274646A (en) * 1963-05-13 1966-09-27 Rowlaud Products Inc Apparatus for making extruded sheet material

Cited By (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3528130A (en) * 1965-07-22 1970-09-15 Dow Chemical Co Extrusion apparatus
US3487505A (en) * 1967-08-21 1970-01-06 Dow Chemical Co Laminates
US3729889A (en) * 1970-09-14 1973-05-01 Pet Inc Modular insulated panel system
US3860372A (en) * 1971-02-26 1975-01-14 Dow Chemical Co Adjustable feedblock for encapsulated multilayer extrusion
US4221757A (en) * 1978-01-20 1980-09-09 Produits Chimiques Ugine Kuhlmann Polyvinylidene fluoride-polyurethane laminates and method
US4415519A (en) * 1978-09-25 1983-11-15 Produits Chimiques Ugine Kuhlmann Method of making polyvinylidene fluoride-thermoplastic resin laminates
US4619802A (en) * 1984-05-21 1986-10-28 Peter Cloeren Die with combining adaptor insert and melt-lamination process
WO1986002316A1 (en) * 1984-10-12 1986-04-24 Princeton Packaging, Inc. Two-color sheet, article, method and apparatus
US4731004A (en) * 1984-10-12 1988-03-15 Princeton Packaging, Inc. Side-by-side co-extrusion of film using multiple materials
US4592938A (en) * 1985-03-25 1986-06-03 Mobil Oil Corporation Method of producing an internally reinforced thermoplastic film and film and articles produced therefrom
US4789513A (en) * 1987-06-05 1988-12-06 P.C.E. Corp. Coextrusion apparatus and process
US4784815A (en) * 1987-06-05 1988-11-15 P.C.E. Corp. Edge-laminating apparatus and process
US4780258A (en) * 1987-07-17 1988-10-25 P.C.E. Corp. Coextruded laminate having barrier layers
US5190711A (en) * 1988-06-09 1993-03-02 American National Can Company Methods for processing polymers
US4937031A (en) * 1988-11-18 1990-06-26 General Electric Company Process for preparing thermoplastic composites
US6583930B1 (en) 1989-06-20 2003-06-24 3M Innovative Properties Birefringent interference polarization
US5234330A (en) * 1991-06-14 1993-08-10 Eastman Kodak Company Dies
US5375990A (en) * 1992-09-10 1994-12-27 Extrusion Dies, Inc. Feed block for coextrusion apparatus
US7852560B2 (en) 1993-12-21 2010-12-14 3M Innovative Properties Company Display incorporating reflective polarizer
US5882774A (en) * 1993-12-21 1999-03-16 Minnesota Mining And Manufacturing Company Optical film
US7297393B2 (en) 1993-12-21 2007-11-20 3M Innovative Properties Company Optical film
US6613421B2 (en) 1993-12-21 2003-09-02 3M Innovative Properties Company Optical film
US7083847B2 (en) 1993-12-21 2006-08-01 3M Innovative Properties Company Optical film
US5976424A (en) * 1996-07-31 1999-11-02 Minnesota Mining And Manufacturing Company Method for making multilayer optical films having thin optical layers
US5848769A (en) * 1996-08-26 1998-12-15 Minnesota Mining & Manufacturing Company Drag reduction article
US5780067A (en) * 1996-09-10 1998-07-14 Extrusion Dies, Inc. Adjustable coextrusion feedblock
US20010046086A1 (en) * 1998-12-23 2001-11-29 3M Innovative Properties Company Polymeric interference film
US6245401B1 (en) 1999-03-12 2001-06-12 Kimberly-Clark Worldwide, Inc. Segmented conformable breathable films
US6626206B1 (en) 2000-01-20 2003-09-30 Extrusion Dies, Inc. Feedblock for adjusting the dimensions of a set of co-extruded layers of a multi-layer sheet
US7678316B2 (en) 2004-06-08 2010-03-16 3M Innovative Properties Company Coextruded profiled webs
US7968172B2 (en) 2004-06-08 2011-06-28 3M Innovative Properties Company Coextruded profiled webs
US20050271861A1 (en) * 2004-06-08 2005-12-08 3M Innovative Properties Company Coextruded profiled webs
US20100136297A1 (en) * 2004-06-08 2010-06-03 3M Innovative Properties Company Coextruded profiled webs
US7897081B2 (en) 2004-12-30 2011-03-01 3M Innovative Properties Company Method of extruding articles
US20060147686A1 (en) * 2004-12-30 2006-07-06 3M Innovative Properties Company Method of extruding articles
US7749924B2 (en) 2005-08-29 2010-07-06 Bfs Diversified Products, Llc Thermoplastic roofing membranes
US20090137168A1 (en) * 2005-08-29 2009-05-28 Richard Peng Thermoplastic roofing membranes
US20070172628A1 (en) * 2006-01-25 2007-07-26 3M Innovative Properties Company Intermittently bonded fibrous web laminate
US8034431B2 (en) 2006-01-25 2011-10-11 3M Innovative Properties Company Intermittently bonded fibrous web laminate
US20090181216A1 (en) * 2006-02-17 2009-07-16 Peng Lichih R Roofing Membranes Including Fluoropolymer
US20070194482A1 (en) * 2006-02-21 2007-08-23 Bfs Diversified Products, Llc Co-extrusion process for preparing roofing membranes
US20090269565A1 (en) * 2006-05-18 2009-10-29 Richard Peng Polymeric laminates including nanoclay
US20080009821A1 (en) * 2006-07-10 2008-01-10 3M Innovative Properties Company Net hook fasteners
US7622180B2 (en) 2006-07-10 2009-11-24 3M Innovative Properties Company Net hook fasteners
US20100025881A1 (en) * 2006-07-10 2010-02-04 3M Innovative Properties Company Net hook fasteners
US20080138598A1 (en) * 2006-12-08 2008-06-12 3M Innovative Properties Company Apparatus and Method for Co-Extrusion of Articles Having Discontinuous Phase Inclusions

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