US3374385A - Electron tube cathode with nickel-tungsten alloy base and thin nickel coating - Google Patents

Electron tube cathode with nickel-tungsten alloy base and thin nickel coating Download PDF

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US3374385A
US3374385A US294108A US29410863A US3374385A US 3374385 A US3374385 A US 3374385A US 294108 A US294108 A US 294108A US 29410863 A US29410863 A US 29410863A US 3374385 A US3374385 A US 3374385A
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nickel
base
coating
cathode
electron
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Charles T Lattimer
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RCA Corp
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    • H—ELECTRICITY
    • H01—BASIC ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J1/00—Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
    • H01J1/02—Main electrodes
    • H01J1/13—Solid thermionic cathodes
    • H01J1/14—Solid thermionic cathodes characterised by the material
    • H—ELECTRICITY
    • H01—BASIC ELECTRIC ELEMENTS
    • H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J1/00—Details of electrodes, of magnetic control means, of screens, or of the mounting or spacing thereof, common to two or more basic types of discharge tubes or lamps
    • H01J1/02—Main electrodes
    • H01J1/13—Solid thermionic cathodes
    • H01J1/20—Cathodes heated indirectly by an electric current; Cathodes heated by electron or ion bombardment
    • H01J1/26—Supports for the emissive material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00—Stock material or miscellaneous articles
    • Y10S428/922—Static electricity metal bleed-off metallic stock
    • Y10S428/923—Physical dimension
    • Y10S428/924—Composite
    • Y10S428/925—Relative dimension specified
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12611—Oxide-containing component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771—Transition metal-base component
    • Y10T428/12861—Group VIII or IB metal-base component
    • Y10T428/12944—Ni-base component

Description

March 19, 1968 c. T. LATTIMER 3,374,385
ELECTRON TUBE GATHODE WITH NICKEL-TUNGSTEN ALLOY BASE AND THIN NICKEL COATING Filed July 10. 1965,
IN VEN TOR. AMP/ff 2' 1077/1155,
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I? my United States Patent ELECTRON TUBE CATHODE WITH NICKEL- TUNGSTEN ALLOY BASE AND THIN NICK- EL COATING Charles T. Lattimer, Marion, 11111., assignor to Radio Corporation of America, a corporation of Delaware Filed July 10, 1963, Ser. No. 294,108 11 Claims. (Cl. 313-337) This invention relates to cathodes for electron tubes and particularly to indirectly heated cathodes comprising nickel-tungsten alloy base elements having a coating of electron emissive material thereon.
It is an object of this invention to provide an improved indirectly heated cathode having a base element which combines: (a) good electron emissive properties, (b) surface properties which result in good adherence of the emissive coating thereto, and (c) satisfactory life expectancy.
It is also an object of this invention toprovide an improved indirectly heated cathode of the class having a base element of nickel-tungsten alloy.
According to the invention, an indirectly heated cath ode for an electron tube comprises a metal base element, of, e.g., nickel-tungsten alloy, having a thin coating of nickel thereon. A layer of suitable electron emissive materials is deposited on the nickel coating.
In the drawing:
FIGURE 1 is a longitudinal section of a cathode ray tube including a cathode embodying the invention, and
FIGURE 2 is an enlarged section of the cathode of the tube of FIGURE 1.
Referring to the drawing, a cathode ray tube comprises an envelope 12 in which is disposed a heater 14, an indirectly heated cathode 16, an apertured cup-shaped control grid 18, an apertured cup-shaped screen grid 20, a tubular focusing electrode 22, and an anode. The anode comprises a tubular electron gun element 24, a conductive coating 26 on the internal surface on one portion of the envelope 12, and a metalized phosphor screen 28 on the internal surface of another portion of the envelope. The gun element 24, the conductive coating 26, and the metalized phosphor screen 28 are all electrically connected together and to an anode terminal schematically illustrated by the arrow 30. The metalized screen 28 comprises a layer of phosphor 32 on the envelope 12 and a conductive coating 34, of, for example, evaporated aluminum, thereon. I
Refering to FIGURE 2, the indirectly heated cathode 16 includes a base element 36 which comprises a tubular sleeve portion 38 closed at one end with a transverse end wall portion 40. The base element 36 is composed of metal which exhibits desirable electron emissive properties superior to those of a nickel base element and to which certain electron emissive materials do not satisfactorily adhere. The base element 36 may be an alloy of high nickel content. It is preferably a nickel-tungsten alloy, and hereinafter by way of example will be referred to as such. A thin coating 42 of nickel is provided on the external surface of the end wall 40. A layer 44 of suitable electron emissive material such as a mixture of barium, calcium, and strontium oxides is deposited on top of the nickel coating 42.
I have discovered that by virtue of the nickel coating 42, good adherence of the electron emissive materials 44 to the base element 36 can be obtained without at the same time destroying the advantage of the superior electron emissive properties imparted by the nickel-tungsten alloy base element. It appears that in operation of the cathode 16, the nickel coating 42 is dissipated by very 3,374,385 Patented Mar. 19, 1968 slow diffusion into the nickel-tungsten base element 36. Accordingly, the nickel coating 42 is made sufiiciently thick to give a desired life expectancy. Insofar as providing the desired adherence is concerned, the nickel coating 42 need be only thick enough to completely cover the base element. The maximum thickness to which the nickel coating 42 should be applied is limitet to that beyond which the inherent electron emissive properties of the nickel-tungsten alloy base is lost. If the nickel coating 42 is too thick, the cathode 16 will undesirably act as though it had a nickel base element rather than a nickel-tungsten base element.
I have found that the nickel coating 42 may be applied in thicknesses up to 0.0006 inch without adversely affect ing the emission properties of the nickel-tungsten base. Satisfactory adherence of the emissive materials is provided under normal operating conditions with a nickel coating 42 which is 0.0002 inch thick. A preferred thickness of the nickel coating 42 in cathodes for use in monochrome television picture tubes is about 0.0002 inch. In certain small power transmitting tubes, a nickel coating of about 0.0005 inch is preferred.
The method by which the nickel coating 42 is applied to the nickel-tungsten base 36 is not critical. Electroplating involving standard known solutions, schedules, and techniques has been successfully used. For example a one gallon aqueous solution containing 32 ounces of nickel sulfate (NiSO -7H D), 6 ounces of nickel chloride (NiCl -GH O), and 4 ounces of boric acid (H BO at a pH of 4-4.5 has been found satisfactory. The electroplating is carried out with the solution at a temperature of 115-160" F. and with a plating current density of 20- amperes/square foot.
As an alternative to electroplating, the nickel coating 42 may, for example, be applied by standard cladding techniques wherein a nickel sheet is laid against a nickeltungsten sheet and the two rolled together and to a desired thickness. As a third alternative, the nickel coating 42 may be applied by conventional spray techniques where metallic nickel is sprayed in molten form or in the form of nickel powder in a binder onto the surface of the nickel-tungsten base element 36. Carbonyl nickel powder having particle sizes of 3-7 microns may be used in the latter case.
The nickel used for the coating 42 can be of the type commercially used for nickel cathode base elements, A
purity such as that obtained in commercial electroplating procedures with no special attention being given to avoidance of impurities is satisfactory.
The particular kind of electron emissive materials which are to be applied to the nickel coating 42 are not critical. The barium, calcium, strontium oxides used by way of example in the cathode 16 are well known in the art, are widely used, and are highly preferred. However, other known electron emissive materials may be used. Industry conventional methods and thicknesses of the layer 44 may be used. For example, application of the emissive materials may be by spraying, dipping, or electrophoresis.
The nickel-tungsten alloy for the base element 36 is preferrably provided with a tungsten content of from 2 to 4 percent, although there may be more or less than these percentages. A tungsten percentage of about 4 percent is preferred. Although such an alloy is conventionally re-. ferred to in the industry as nickel-tungsten, it also may contain traces of impurities such as magnesium, manganese, iron, cobalt, and carbon. Such impurities are usually present in quantities of 0.1 weight percent or less, each, and are, in some cases, desirable if not essential for providing good electron emissive properties.
Although the invention is herein described by way of example as embodied in a cathode ray tube, the invention is in no way limited to cathode ray tubes. Cathodes embodying the invention may be used in other types of electron tubes such as power transmitting tubes, receiving tubes, traveling wave tubes, and television camera tubes, to name a few. Generally speaking, a cathode embodying the invention may be used in most places where an indirectly heated cathode having an emissive coating is called for. For example, the invention may be embodied in a planar disc-like cathode or in a hollow cylindrical cathode in which either the inner or outer surface of the cylindrical wall serves as the nickel coated part on which the electron emissive materials are deposited.
What is claimed is:
1. An indirectly heated cathode for an electron tube comprising:
(a) a base element which exhibits desirable electron emissive properties superior to those of a nickel base element and to which electron emissive materials do not satisfactorily adhere, consisting of nickel-tungsten alloy,
(b) a coating of nickel having a thickness not greater than 0.0006 inch on a portion of the surface of said base element, and
(c) a layer of electron emissive material on said nickel coating.
2. An indirectly heated cathode for an electron tube comprising:
(a) a base element which exhibits desirable electron emissive properties superior to those of a nickel base element and to which electron emissive materials do not satisfactorily adhere, consisting of an alloy including from 2 percent to 4 percent tungsten by weight and the remainder substantially nickel,
(b) a coating of nickel having a thickness not greater than 0.0006 inch on a portion of the surface of said base element, and
(c) a layer of electron emissive material on said nickel coating.
3. In an electron tube including a cathode and an anode, said cathode comprising:
(a) a base element which exhibits desirable electron emissive properties superior to those of a nickel base element and to which electron emissive materials do not satisfactorily adhere, consisting of nickel-tungsten alloy having a trace of at least one of the elements of the group consisting of manganese, magnesium, iron, cobalt, and carbon,
(b) a coating of nickel having a thickness not greater than 0.0006 inch on a portion of the surface of said base element, and
(c) a layer of electron emissive material comprising a mixture of barium oxide, calcium oxide, and strontium oxide on said nickel coating.
4. An indirectly heated cathode for an electron tube comprising:
(a) a base element which exhibits desirable electron emissive properties superior to those of a nickel base element and to which electron emissive materials do not satisfactorily adhere, consisting of nickel-tungsten alloy,
(b) an electroplated coating of nickel having a thickness not greater than 0.0006 inch on a portion of the surface of said base element, and
(c) a layer of electron emissive material on said nickel coating.
5. In an electron tube including a cathode and an anode,
said cathode comprising:
(a) a base element which exhibits desirable electron emissive properties superior to those of a nickel base element and to which electron emissive materials do not satisfactorily adhere, consisting of nickel-tungsten alloy,
(b) a 0.0002-0.0006 inch thick coating of nickel on a portion of the surface of said base element, and
(c) a layer of electron emissive material on said nickel coating.
6. In an electron tube comprising an anode, a cathode for thermionically emitting electrons which are directed to said anode, and heater means adjacent to said cathode for heating said cathode to a thermionic electron-emissive temperature, said cathode comprising:
(a) a base element which exhibits desirable electron emissive properties superior to those of a nickel base element and to which electron emissive materials do not satisfactorily adhere, consisting of nickel-tungsten alloy,
(b) a coating of nickel about 0.0005 inch thick on a portion of the surface of said base element, and
(c) a layer of electron emissive material on said nickel coating.
7. An indirectly heated cathode for an electron tube comprising:
(a) a base element which exhibits desirable electron emissive properties superior to those of a nickel base element and to which electron emissive materials do not satisfactorily adhere, consisting of nickel-tungsten alloy containing from 2 percent to 4 percent tungsten by weight and including a trace of at least one element of the group consisting of manganese, magnesium, iron, cobalt, and carbon,
(b) a 0.0002-0.0006 inch thick coating of nickel on a portion of said surface of said base element, and
(c) a layer of electron emissive material comprising a mixture of barium oxide, calcium oxide, and strontium oxide on said nickel coating.
8. In an electron tube comprising an anode, a cathode for thermionically emitting electrons which are directed to said anode, and heater means adjacent to said cathode for heating said cathode to a thermionic electron-emissive temperature, said cathode comprising:
(a) a nickel-tungsten base element which exhibits de sirable electron emissive properties superior to those of a nickel base element and to which electron emissive materials do not satisfactorily adhere, comprising a hollow cylindrical sleeve portion and a transverse end wall portion,
(b) a coating of nickel about 0.0002 inch thick electroplated on the surface of said end wall portion, and
(c) a layer of electron emissive material on said nickel coating.
9. An indirectly heated cathode for-an electron tube comprising:
(a) a base element which exhibits desirable electron emissive properties superior to those of a nickel base element and to which electron emissive materials do not satisfactorily adhere, consisting of nickel-tungsten alloy,
(b) a coating of nickel having a thickness not greater than 0.0006 inch on a portion of the surface of said base element, and
(c) a layer of electron emissive material on said nickel coating,
(d) said coating having a thickness sufficient to provide satisfactory adherence of said emissive materials to said base element for a reasonable life of operation and being thinner than that at which said base element would exhibit emission properties characteristic of a nickel base element.
10. In an electron tube comprising an anode, a cathode for thermionically emitting electrons which are directed to said anode, and heater means adjacent to said cathode for heating said cathode to a thermionic electron-emissive temperature, said cathode comprising:
(a) a base element which exhibits desirable electron emissive properties superior to those of a nickel base element and to which electron emissive materials do not satisfactorily adhere, consisting of an alloy including from 2 :percent to 4 percent tungsten by weight and the remainder substantially nickel,
(b) an electroplated coating of nickel having a thickness not greater than 0.0006 inch on a portion of the surface of said base element, and
(c) a layer of electron emissive material on said nickel coating,
(d) said coating being sufiiciently thick to provide a satisfactory adherence of said emissive material to said base element which adherence is greater than would exist in the absence of said coating, and sufi'iciently thick that it is not dissipated during a reasonable life of operation, and thinner than that at which said nickel-coated nickel-tungsten base element would exhibit electron emission properties more nearly characteristic of a nickel base element than of a nickeltungsten base element.
11. An oxide coated cathode for an electron tube, said cathode comprising a core metal of about 4% tungsten, a trace of magnesium and the remainder substantially nickel,
a layer of nickel having a thickness of about .0002 inch plated on said core metal, and a layer of emitter materials applied over said layer of nickel.
References Cited UNITED STATES PATENTS 1/1939 Armstrong et al. 313311 X 12/1956 Hall 313-82 3/ 1959 Millis 313-346 11/1959 Beck et al 313311 X 7/1961 Grenoble 29183.5 10/1961 Horner et a1. 313337 9/1962 Fink 29-183.5
9/ 1964 Kuebrich et a1. 29-198 2/1965 Sato et al 3133 11 X FOREIGN PATENTS 2/ 1957 Australia.
6/ 1958 Great Britain.
5/ 1942 Great Britain.
5/1956 Great Britain.
4/1961 Great Britain.
5/1963 Great Britain.
JOHN W. HUCKERT, Primary Examiner. A. I. JAMES, Assistant Examiner.

Claims (1)

1. AN INDIRECTLY HEATED CATHODE FOR AN ELELCTRON TUBE COMPRISING: (A) A BASE ELEMENT WHICH EXHIBITS DESIRABLE ELECTRON EMISSIVE PROPERTIES SUPERIOR TO THOSE OF A NICKEL BASE ELEMENT AND TO WHICH ELECTRON EMISSIVE MATERIALS DO NOT SATISFACTORILY ADHERE, CONSISTING OF NICKEL-TUNGSTEN ALLOY, (B) A COATING OF NICKEL HAVING A THICKNESS NOT GREATER THAN 0.0006 INCH ON A PORTION OF THE SURFACE OF SAID BASE ELEMENT, AND (C) A LAYER OF ELECTRON EMISSIVE MATERIAL ON SAID NICKEL COATING.
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3463978A (en) * 1966-12-22 1969-08-26 Machlett Lab Inc Monolithic electrode for electron tubes
US3693007A (en) * 1970-05-25 1972-09-19 Egyesuelt Izzolampa Oxide cathode for an electric discharge device
US3958146A (en) * 1974-02-08 1976-05-18 Gte Sylvania Incorporated Fast warm up picture tube cathode cap having high heat emissivity surface on the interior thereof
US4081713A (en) * 1976-01-28 1978-03-28 Hitachi, Ltd. Directly heated oxide cathode
US4129801A (en) * 1976-07-07 1978-12-12 Hitachi, Ltd. Cathode for cathode ray tube of directly heating type and process for producing the same cathode
DE2842661A1 (en) * 1977-09-30 1979-04-19 Hitachi Ltd ELECTRON TUBE CATHODE AND ITS PRODUCTION
US4220891A (en) * 1978-04-05 1980-09-02 Hitachi, Ltd. Directly heated cathode for electron tube
US4349766A (en) * 1979-04-28 1982-09-14 Hitachi, Ltd. Directly heated cathode for electron tube

Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2143853A (en) * 1935-10-22 1939-01-17 Tungsten Electrodeposit Corp Spark plug
GB545926A (en) * 1941-09-09 1942-06-18 Philips Nv Improvements in or relating to electric discharge tubes
GB749256A (en) * 1953-02-24 1956-05-23 Emi Ltd Improvements in or relating to cathodes for electron discharge devices
US2773212A (en) * 1953-08-14 1956-12-04 Westinghouse Electric Corp Electron gun
GB797095A (en) * 1955-08-25 1958-06-25 Standard Telephones Cables Ltd Carrier for oxide cathodes
US2848410A (en) * 1955-05-13 1958-08-19 Strners Chemiske Lab H Apparatus for the electrolytic polishing of limited surface portions of a metallic workpiece
US2912611A (en) * 1953-08-14 1959-11-10 Int Standard Electric Corp Thermionic cathodes
GB866194A (en) * 1958-04-29 1961-04-26 Superior Tube Co Improvements in indirectly-heated nickel alloy cathodes
US2993264A (en) * 1955-12-23 1961-07-25 Gen Electric Protective coating for molybdenum
US3005926A (en) * 1959-05-22 1961-10-24 Westinghouse Electric Corp Cathode for electron discharge device
US3055087A (en) * 1954-06-07 1962-09-25 Union Carbide Corp Carbonyl metal plated product
GB926845A (en) * 1961-03-21 1963-05-22 Westinghouse Electric Corp Electronic tube component
US3147547A (en) * 1960-03-10 1964-09-08 Gen Electric Coating refractory metals
US3170772A (en) * 1961-01-05 1965-02-23 Tokyo Shibaura Electric Co Oxide coated cathodes for electron tubes

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2143853A (en) * 1935-10-22 1939-01-17 Tungsten Electrodeposit Corp Spark plug
GB545926A (en) * 1941-09-09 1942-06-18 Philips Nv Improvements in or relating to electric discharge tubes
GB749256A (en) * 1953-02-24 1956-05-23 Emi Ltd Improvements in or relating to cathodes for electron discharge devices
US2912611A (en) * 1953-08-14 1959-11-10 Int Standard Electric Corp Thermionic cathodes
US2773212A (en) * 1953-08-14 1956-12-04 Westinghouse Electric Corp Electron gun
US3055087A (en) * 1954-06-07 1962-09-25 Union Carbide Corp Carbonyl metal plated product
US2848410A (en) * 1955-05-13 1958-08-19 Strners Chemiske Lab H Apparatus for the electrolytic polishing of limited surface portions of a metallic workpiece
GB797095A (en) * 1955-08-25 1958-06-25 Standard Telephones Cables Ltd Carrier for oxide cathodes
US2993264A (en) * 1955-12-23 1961-07-25 Gen Electric Protective coating for molybdenum
GB866194A (en) * 1958-04-29 1961-04-26 Superior Tube Co Improvements in indirectly-heated nickel alloy cathodes
US3005926A (en) * 1959-05-22 1961-10-24 Westinghouse Electric Corp Cathode for electron discharge device
US3147547A (en) * 1960-03-10 1964-09-08 Gen Electric Coating refractory metals
US3170772A (en) * 1961-01-05 1965-02-23 Tokyo Shibaura Electric Co Oxide coated cathodes for electron tubes
GB926845A (en) * 1961-03-21 1963-05-22 Westinghouse Electric Corp Electronic tube component

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3463978A (en) * 1966-12-22 1969-08-26 Machlett Lab Inc Monolithic electrode for electron tubes
US3693007A (en) * 1970-05-25 1972-09-19 Egyesuelt Izzolampa Oxide cathode for an electric discharge device
US3958146A (en) * 1974-02-08 1976-05-18 Gte Sylvania Incorporated Fast warm up picture tube cathode cap having high heat emissivity surface on the interior thereof
US4081713A (en) * 1976-01-28 1978-03-28 Hitachi, Ltd. Directly heated oxide cathode
US4129801A (en) * 1976-07-07 1978-12-12 Hitachi, Ltd. Cathode for cathode ray tube of directly heating type and process for producing the same cathode
DE2842661A1 (en) * 1977-09-30 1979-04-19 Hitachi Ltd ELECTRON TUBE CATHODE AND ITS PRODUCTION
DE2842661C2 (en) * 1977-09-30 1984-07-12 Hitachi, Ltd., Tokio/Tokyo Directly heated oxide cathode for electron tubes and process for their manufacture
US4220891A (en) * 1978-04-05 1980-09-02 Hitachi, Ltd. Directly heated cathode for electron tube
US4349766A (en) * 1979-04-28 1982-09-14 Hitachi, Ltd. Directly heated cathode for electron tube

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