US3353544A - Tobacco-smoke filters - Google Patents

Tobacco-smoke filters Download PDF

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Publication number
US3353544A
US3353544A US46243065A US3353544A US 3353544 A US3353544 A US 3353544A US 46243065 A US46243065 A US 46243065A US 3353544 A US3353544 A US 3353544A
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Prior art keywords
material
filter
rod
bonding
melting
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Expired - Lifetime
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Fordyce William Brian
Horsewell Henry George
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Brown and Williamson Holdings Inc
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Brown and Williamson Holdings Inc
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    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/16Use of materials for tobacco smoke filters of inorganic materials
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Mouthpieces for cigars or cigarettes
    • A24D3/02Manufacture of tobacco smoke filters
    • A24D3/0229Filter rod forming processes
    • A24D3/0241Filter rod forming processes by compacting particulated materials

Description

Nov. 21, 1967 w. B. FORDYCE ETAL .3 3535M TOBACCO-SMOKE FILTERS Filed June 8, 1965 United States Patent Ofiice 3,353,544 TOBACCO-SMOKE FILTERS William Brian Fordyce, Romsey, and Henry George Horsewell, Totton, England, assiguors to Brown and Williamson Tobacco Corporation, Louisville, Ky., a corporation of Delaware Filed June 8, 1965, Ser. No. 462,430 Claims priority, application Great Britain, June 10, 1964, 24,119/64 13 Claims. (Cl. 131-267) ABSTRACT OF THE DISCLfiSURE A tobacco smoke filter in the form of a bonded, porous, self-sustaining rod comprising a mixture of powdered or granular absorbent material and particulate low melting bonding material such as simple or complex hydrated salts of inorganic acids or metallic salts of organic acids with the bonding material having a melting point not in excess of 250 C. and the particle size of bonding material being at least substantially equal to the particle size of the filter material, and method of making same.

This invention concerns improvements relating to tobacco-smoke filters. The use of granular or powdered materials as components of cigarette filters is already known, but their incorporation in such a manner as to give even distribution and to avoid losses during manufacture and use presents difliculties. Proposals intended to avoid these difiiculties, for example distribution of the granular or powdered material within a fibrous mass or sheet of another filtering material or its enclosure in a cartridge or between filter plugs or between a plug and the tobacco rod, have met with only limited success. Attainment of even distribution may entail an undesirably slow rate of production and difliculty may be encountered in maintaining the content of material reasonably constant from one filter-tip to another.

An object of the present invention is to make possible rapid and convenient continuous manufacture of filters comprising powdered or granular materials, with little or no risk of losses during manufacture or subsequent use.

According to the invention, powdered or granular filter material for tobacco smoke is mixed with a powdered or granular, low melting, salt and the mixture is heated so that the filter material is bonded by the said salt. By a low-melting salt is meant one with a melting point below 250 C., but preferably with a melting point between 100 and 150 C.

In the accompanying drawing which illustrates the in-.

vention herein,

FIG. 1 is a longitudinal sectional view of a cigarette with the tobacco rod section broken away showing a typical filter construction; and

' FIG. 2 is an enlarged perspective view partly broken away of the bonded filter section of FIG. 1.

material 4 with the tip material encircling the end =prtion of the enrobed cigarette rod so as to mount the filter assembly to the end thereof. The filter assembly includes a mouthpiece element 5 of fibrous material and interposed between tobacco rod section 1 and mouthpiece element 5 is bonded section 6.

3,353,544 Patented Nov. 21, 1957 FIG. 2, which best illustrates bonded section 6, comprises particles of filter material 7 and particles of bond- .ing material 8. The partially broken away section of FIG. 2 illustrates the manner in which particles of bonding material 8 contact particles of filter material 7 so as to effect a bond therebetween. Since the bonding material is a low melting material, the particles when heated are melted or softened suflici-ently to contact the adjacent surfaces of the filter material. Then, when cooled, the low melting material will solidify to form a firmly bonded rod.

The filter material may be any adsorbent or absorbent material, with a desirable effect on tobacco smoke, which is available in powdered or granular form, for example charcoal, silica gel, zeolites, perlite, sepiolite, activated alumina, magnesium silicate, or mixtures thereof, or the like.

Suitable salts of inorganic acids include simple salts in a crystalline hydrated form such as trisodium orthophosphate, sodium perborate, calcium bromide, aluminium bromide, ferrous sulphate and cupric nitrate. More complex salts of inorganic acids may also be used in the crystalline hydrated form, such as sodium aluminium sulphate (soda alum), potassium aluminium sulphate (potash alum) and potassium chromium sulphate (potassium chrome alum). Suitable salts of organic acids include magnesium stearate, aluminium stearate and crystalline hydrated magnesium acetate. In addition to being effective bonding materials, several of these salts, notably hydrated trisodium o-rthophosphate and hydrated sodium perborate, have a desirable effect upon the properties of the smoke passed through the filter, whereby the effectiveness of the powdered or granular filter material is enhanced.

The particle size of the filter material may be chosen to provide a desired porosity of the resultant mass and may, suitably, be smaller than 10 mesh and larger than mesh (British Standard Specification) per inch and is preferably between 20 and 50 mesh. Preferably, the bonding material has a particle size at least substantially the same as that of the filter material and is present in a proportion of between one part to three parts and equal parts,

by weight, with respect to the filter material. Preferably between 25 and 50% of the total initial mixture consists of bonding material.

According to one manner of carrying the invention into effect, the bonding and filter materials, intimately mixed, are fed on to a band of paper passing beneath a feed hopper in which the level of the mixture is kept substantially constant. The band, which has a channel shape imparted by a guide, passes, just beyond the hopper, under a gate device which regulates the level of the material. Supported in a channel, the band then passes below electrical heaters extending lengthwise of the band and provided with reflectors which direct the rays normally to the said band. The heaters preheat the mixture to cause the bonding material to begin to soften. The preheated mixture passes on the band into a ring die by which the band is folded around the mixture to form a rod.

This rod passes through electrically heated dies to complete the softening of the bonding material and to ensure firm bonding of the granules of the filter material to one another. The temperature in these dies should be such as to complete the said softening, while avoiding risk of impairing either of the materials. Each of the dies is of slightly larger circumference than the circumference required for the final rod. A hot-air stream may advantageously be introduced into the dies to reduce frictional drag on the rod.

The enrobed and heated rod next passes to dies which are cooled by a circulated refrigerant, suitably of a halogenated hydrocarbon type. Provision is made for dried refrigerated air to be introduced to the outer surface of the rod by way of radially disposed small holes. This flow of air not only assists in setting the rod in the desired size with an effective joint between the edges of the band, but also acts as an air bearing and reduces the risk of condensation of atmospheric moisture. The circumference of the cool dies is slightly less than that of the heated dies and may be slightly larger than that of the final rod.

From the last die, the rod passes on to a conventional endless cigarette-machine tape which provides the traction for the movement of the band and rod through the apparatus and carries the rod through a guide or garniture to a conventional cut-off device which divides it into lengths for future processing into filter-tip cigarettes.

The above described method and apparatus are more fully described in the specification of US. patent application Ser. No. 449,255.

If required it may be arranged for the granular or powdered material to be bonded to the paper. In this case, in order to ensure firm such bonding, it is recommended that a polyethylene-coated paper should be used instead of a plain paper.

In some cases, further heating may be applied before the cutting operation, or after completion of the rods, to ensure complete bonding of the powder or granules of the filter material. Suitably, this heating may be effected by a dielectric heating device.

One manner of carrying the invention into effect will now be more fully described by way of example:

2 parts by weight of granules of activated charcoal (Sutclilfe Speakman, Grade 270C) of mesh size 20-50 (British Standard Specification) were mixed with one part of trisodium orthophosphate dodecahydrate crystals previous sieved through a screen of mesh size 10. The mixture was fed continuously from a constant-level hopper to a band of polyethylene-coated paper 27.5 mm. wide travelling at a rate of 23 feet per minute.

The mixture then passed on the band below three infrared heaters, was formed into a rod by a ring-die and passed immediately into a set of three dies 25 mm. in circumference heated to about 200 C. and supplied, inside the dies, with a hot air stream at a temperature of about 250 C.

The rod was immediately cooled to a temperature of about C. in series of four cool dies, 24.8 mm. in circumference, into the interior of which dry refrigerated air was introduced through holes of 0.015 inch diameter at a pressure of 7-8 lbs/sq. in. A cut-off device cut the rod into 78 mm. lengths. Filters produced from the rod material were firmly bonded and even in packing had a circumference of 24.6 mm.

mm. sections of the rod lengths were cut and attached to cigarettes of 72 mm. length. The cigarettes were smoked to a 23 mm. butt using a smoking machine which gave a puff of 35 cc. volume and two seconds duration once per minute. Analysis of the smoke gave the following results:

Analysis of the material trapped by the filter, and of the smoke passing through the filter, showed a substantial reduction in the tar to nicotine ratio with a removal of more than 35% of acids and phenols, and a removal of more than 75% of the aldehydes, hydrogen cyanide an hydrogen sulphide present in the smoke.

We claim:

1. A method of producing a bonded, self-sustaining, porous tobacco smoke filter which comprises mixing particles of tobacco smoke filter material with particles of low melting bonding material selected from the group consisting of the hydrates of simple and complex crystal- 2- line metallic salts of inorganic acids and metallic salts of organic acids, the particle size of the bonding material being at least substantially equal to the particle size of filter material; feeding the mixture at a substantially constant rate onto a moving channel-shaped paper band; folding the paper band and mixture into a rod; heating the folded rod to a temperature not in excess of 250 C. to soften the low melting bonding material so that the softened low melting bonding maetrial contacts surfaces of the particles of filter material; and then cooling the heated rod to solidify the low melting bonding material to form a firmly bonded rod.

2. A method according to claim 1, wherein the particle sizes of the two materials are between 20 and 50 mesh.

3. A method according to claim 1, wherein the lowmelting material constitutes 25 to 50% of the mixture.

4. A method according to claim 1, wherein the lowmelting material comprises hydrated trisodium orthophosphates and the filter material granular carbon particles.

5. A method according to claim 1 wherein the lowmelting material is selected from the group consisting of trisodium orthophosphate, sodium perborate, calcium bromide, aluminum bromide, ferrous sulphate, cupric nitrate, sodium aluminum sulphate, potassium aluminum sulphate, potassium chromium sulphate, magnesium stearate, aluminum stearate and hydrated magnesium acetate.

6. A method of producing a bonded, self-sustaining, porous tobacco smoke filter which comprises mixing particles of activated charcoal tobacco smoke filter material with particles of trisodium orthophosphate dodecahydrate low melting bonding material, the particle size of the bonding material being at least substantially equal to the particle size of the filter material; feeding the mixture at a substantially constant rate onto a moving channelshaped paper band; folding the paper band and mixture into a rod; heating the folded rod to a temperature not in excess of 250 C. to soften the low melting material so that the softened material contacts the surfaces of the particles of filter material and then cooling the heated rod to solidify the low melting material to form a firmly bonded rod.

7. The method as set forth in claim 6 wherein 2 parts by weight of activated charcoal is mixed with 1 part of trisodium orthophosphate dodecahydrate and the particle size of both materials is between 20 and 50 mesh.

8. A tobacco smoke filter comprising a bonded, porous, self-sustaining rod formed of a mixture of particles of a tobacco smoke filter material and a particulate low melting bonding material selected from the group consisting of the hydrates of simple and complex crystalline metallic salts of an inorganic acid and metallic salts of an organic acid, the bonding material having a melting point not in excess of 250 C.; the particle size of the bonding material being at least substantially equal to the particle size of the filter material so that the bonding material is in adhesive contact with surfaces of the filter material to form a tobacco smoke filter.

9. A filter means according to claim 8, wherein the filter material comprises granular carbon particles and the low-melting material is hydrated trisodium orthophosphate.

10. A filter means according to claim 8 wherein the low-melting material is selected from the group consisting of trisodium orthophosphate, sodium perborate, calcium bromide, aluminum bromide, ferrous sulphate, cupri-c nitrate, sodium aluminum sulphate, potassium aluminum sulphate, potasssium chromium sulphate, magnesium stearate, aluminum stearate and hydrated magnesium acetate.

11. A filter means according to claim 8 wherein the low-melting material constitutes 25 to 50% of the mixture.

12. A tobacco smoke filter comprising a bonded, porous, self-sustaining rod formed from a mixture of particles of activated charcoal tobacco smoke filter material and particles of trisodium orthophosphate dodecahydrate low melting bonding material, the bonding material having a melting point no greater than 250 C.; the particle size of the bonding material being at least substantially equal to the particle size of the filter material.

13. A tobacco smoke filter as set forth in claim 12 wherein 2 parts by weight of activated charcoal is mixed with 1 part of trisodium orthophosphate dodecahydrate and the particle size of both materials is between 20 and 50 mesh.

References Cited UNITED STATES PATENTS 5 2,940,456 6/1960 Touey 131 20s 3,217,715 11/1965 Berger et al. 131-10 3,320,961 5/1967 Hughes et al. 131267 FOREIGN PATENTS 10 287,549 4/1953 Switzerland.

LUCIE H. LAUDENSLAGER, Primary Examiner.

Claims (2)

1. A METHOD OF PRODUCING A BONDED, SELF-SUSTAINING, POROUS TOBACCO SMOKE FILTER WHICH COMPRISES MIXING PARTICLES OF TOBACCO SMOKE FILTER MATERIAL WITH PARTICLES OF LOW MELTING BONDING MATERIAL SELECTED FROM THE GROUP CONSISTING OF THE HYDRATES OF SIMPLE AND COMPLEX CRYSTALLINE METALLIC SALTS OF INORGANIC ACIDS AND METALLIC SALTS OF ORGANIC ACIDS, THE PARTICLE SIZE OF THE BONDING MATERIAL BEING AT LEAST SUBSTANTIALLY EQUAL TO THE PARTICLE SIZE OF FILTER MATERIAL; FEEDING THE MIXTURE AT A SUBSTANTIALLY CONSTANT RATIO ONTO A MOVING CHANNEL-SHAPED PAPER BAND; FOLDING THE PAPER BAND AND MIXTURE INTO A ROD; HEATING THE FOLDED ROD TO A TEMPERATURE NOT IN EXCESS OF 250*C. TO SOFTEN THE LOW MELTING BONDING MATERIAL SO THAT THE SOFTENED LOW MELTING BONDING MATERIAL CONTACTS SURFACES OF THE PARTICLES OF FILTER MATERIAL; AND THEN COOLING THE HEATED ROD TO SOLIDIFY THE LOW MELTING BONDING MATERIAL TO FORM A FIRMLY BONDED ROD.
8. A TOBACCO SMOKE FILTER COMPRISING A BONDED, POROUS, SELF-SUSTAINING ROD FORMED OF A MIXTURE OF PARTICLES OF A TOBACCO SMOKE FILTER MATERIAL AND A PARTICULATE LOW MELTING BONDING MATERIAL SELECTED FROM THE GROUP CONSISTING OF THE HYDRATES OF SIMPLE AND COMPLEX CRYSTALLINE METALLIC SALTS OF AN INORGANIC ACID AND METALLIC SALTS OF AN ORGANIC ACID, THE BONDING MATERIAL HAVING A MELTING POINT NOT IN EXCESS OF 250*C.; THE PARTICLE SIZE OF THE BONDING MATERIAL BEING AT LEAST SUBSTANTIALLY EQUAL TO THE PARTICLE SIZE OF THE FILTER MATERIAL SO THAT THE BONDING MATERIAL IS IN ADHESIVE CONTACT WITH SURFACES OF THE FILTER MATERIAL TO FORM A TOBACCO SMOKE FILTER.
US3353544A 1964-06-10 1965-06-08 Tobacco-smoke filters Expired - Lifetime US3353544A (en)

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GB2411964A GB1103823A (en) 1964-06-10 1964-06-10 Improvements relating to tobacco-smoke filters

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US3353544A true US3353544A (en) 1967-11-21

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BE (1) BE668015A (en)
DE (1) DE1517261A1 (en)
FR (1) FR1437830A (en)
GB (1) GB1103823A (en)
NL (1) NL142874B (en)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4896683A (en) * 1988-10-17 1990-01-30 Hercules Incorporated Selective delivery and retention of nicotine by-product from cigarette smoke
US20040182401A1 (en) * 2001-08-02 2004-09-23 Ichiro Atobe Cigarette filter
US20050066984A1 (en) * 2003-09-30 2005-03-31 Crooks Evon Llewellyn Filtered cigarette incorporating an adsorbent material
US20050066983A1 (en) * 2003-09-30 2005-03-31 Clark Melissa Ann Filtered cigarette incorporating an adsorbent material
US20050066981A1 (en) * 2003-09-30 2005-03-31 Crooks Evon Llewellyn Filtered cigarette incorporating an adsorbent material
US20050066980A1 (en) * 2003-09-30 2005-03-31 Crooks Evon Llewellyn Filtered cigarette incorporating an adsorbent material
US20050126395A1 (en) * 2001-07-16 2005-06-16 Blackburn Andrew J. Filter element
US20050133051A1 (en) * 2003-12-22 2005-06-23 Philip Morris Usa Inc. Composite materials and their use in smoking articles
US20050133052A1 (en) * 2003-11-21 2005-06-23 Philip Morris Usa Inc. Cigarette filter
US20060112964A1 (en) * 2004-11-10 2006-06-01 Philip Morris Usa Inc. Capsuled adsorbent flavored filter
US20070056600A1 (en) * 2005-09-14 2007-03-15 R. J. Reynolds Tobacco Company Filtered smoking article
US7966743B2 (en) * 2007-07-31 2011-06-28 Eastman Kodak Company Micro-structured drying for inkjet printers
US8066011B2 (en) 2003-09-30 2011-11-29 R. J. Reynolds Tobacco Company Filtered cigarette incorporating an adsorbent material
US20130221562A1 (en) * 2010-10-15 2013-08-29 Celanese Acetate Llc Apparatuses, Systems, and Associated Methods for Forming Porous Masses for Smoke Filter
US8739802B2 (en) 2006-10-02 2014-06-03 R.J. Reynolds Tobacco Company Filtered cigarette
US9491971B2 (en) 2005-12-13 2016-11-15 Philip Morris Usa Inc. Specifically-defined smoking article with activated carbon sorbent and sodium bicarbonate-treated fibers and method of treating mainstream smoke

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4253508A (en) * 1979-01-19 1981-03-03 Bodai Industries, Inc. Selective filtering of tobacco smoke by enhanced filtration efficiency
US4811745A (en) * 1988-02-04 1989-03-14 Hercules Incorporated Method and device for control of by-products from cigarette smoke
US5038803A (en) * 1988-02-04 1991-08-13 Hercules Incorporated Method and device for control of by-products from cigarette smoke
US5048546A (en) * 1989-12-15 1991-09-17 Hsu Chi Hsueh Filter and method of treating tobacco smoke to reduce materials harmful to health
EP0532159A1 (en) * 1991-07-18 1993-03-17 Hoechst Celanese Corporation Removal of nicotine from tobacco smoke

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2940456A (en) * 1956-02-08 1960-06-14 Eastman Kodak Co Fibrous tobacco smoke filter containing finely divided solids
US3217715A (en) * 1965-05-24 1965-11-16 American Filtrona Corp Smoke filter and smoking devices formed therewith
US3320961A (en) * 1963-07-22 1967-05-23 Brown & Williamson Tobacco Cigarette filters

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2940456A (en) * 1956-02-08 1960-06-14 Eastman Kodak Co Fibrous tobacco smoke filter containing finely divided solids
US3320961A (en) * 1963-07-22 1967-05-23 Brown & Williamson Tobacco Cigarette filters
US3217715A (en) * 1965-05-24 1965-11-16 American Filtrona Corp Smoke filter and smoking devices formed therewith

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4896683A (en) * 1988-10-17 1990-01-30 Hercules Incorporated Selective delivery and retention of nicotine by-product from cigarette smoke
US7160366B2 (en) 2001-07-16 2007-01-09 Mast Carbon International Ltd. Filter element
US20050126395A1 (en) * 2001-07-16 2005-06-16 Blackburn Andrew J. Filter element
US20040182401A1 (en) * 2001-08-02 2004-09-23 Ichiro Atobe Cigarette filter
US20050066983A1 (en) * 2003-09-30 2005-03-31 Clark Melissa Ann Filtered cigarette incorporating an adsorbent material
US20050066981A1 (en) * 2003-09-30 2005-03-31 Crooks Evon Llewellyn Filtered cigarette incorporating an adsorbent material
US20050066984A1 (en) * 2003-09-30 2005-03-31 Crooks Evon Llewellyn Filtered cigarette incorporating an adsorbent material
US8066011B2 (en) 2003-09-30 2011-11-29 R. J. Reynolds Tobacco Company Filtered cigarette incorporating an adsorbent material
US7856990B2 (en) 2003-09-30 2010-12-28 R. J. Reynolds Tobacco Company Filtered cigarette incorporating an adsorbent material
US7827997B2 (en) 2003-09-30 2010-11-09 R. J. Reynolds Tobacco Company Filtered cigarette incorporating an adsorbent material
US7669604B2 (en) 2003-09-30 2010-03-02 R.J. Reynolds Tobacco Company Filtered cigarette incorporating an adsorbent material
US20050066980A1 (en) * 2003-09-30 2005-03-31 Crooks Evon Llewellyn Filtered cigarette incorporating an adsorbent material
US7237558B2 (en) 2003-09-30 2007-07-03 R. J. Reynolds Tobacco Company Filtered cigarette incorporating an adsorbent material
US7240678B2 (en) 2003-09-30 2007-07-10 R. J. Reynolds Tobacco Company Filtered cigarette incorporating an adsorbent material
US9554594B2 (en) 2003-09-30 2017-01-31 R.J. Reynolds Tobacco Company Filtered cigarette incorporating an adsorbent material
US20050133052A1 (en) * 2003-11-21 2005-06-23 Philip Morris Usa Inc. Cigarette filter
US9107455B2 (en) * 2003-11-21 2015-08-18 Philip Morris Usa Inc. Cigarette filter
US8746254B2 (en) 2003-12-22 2014-06-10 Philip Morris Usa Inc. Composite materials and their use in smoking articles
US20050133051A1 (en) * 2003-12-22 2005-06-23 Philip Morris Usa Inc. Composite materials and their use in smoking articles
US8381738B2 (en) 2003-12-22 2013-02-26 Philip Morris Usa Inc. Composite materials and their use in smoking articles
US20060174899A9 (en) * 2003-12-22 2006-08-10 Philip Morris Usa Inc. Composite materials and their use in smoking articles
US20060112964A1 (en) * 2004-11-10 2006-06-01 Philip Morris Usa Inc. Capsuled adsorbent flavored filter
US20070056600A1 (en) * 2005-09-14 2007-03-15 R. J. Reynolds Tobacco Company Filtered smoking article
US9491971B2 (en) 2005-12-13 2016-11-15 Philip Morris Usa Inc. Specifically-defined smoking article with activated carbon sorbent and sodium bicarbonate-treated fibers and method of treating mainstream smoke
US8739802B2 (en) 2006-10-02 2014-06-03 R.J. Reynolds Tobacco Company Filtered cigarette
US7966743B2 (en) * 2007-07-31 2011-06-28 Eastman Kodak Company Micro-structured drying for inkjet printers
US9027566B2 (en) * 2010-10-15 2015-05-12 Celanese Acetate Llc Apparatuses, systems, and associated methods for forming porous masses for smoke filter
US20130221562A1 (en) * 2010-10-15 2013-08-29 Celanese Acetate Llc Apparatuses, Systems, and Associated Methods for Forming Porous Masses for Smoke Filter

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Publication number Publication date Type
DE1517261A1 (en) 1970-04-16 application
BE668015A (en) 1965-12-01 grant
GB1103823A (en) 1968-02-21 application
FR1437830A (en) 1966-05-06 grant
NL6507440A (en) 1965-12-13 application
NL142874B (en) 1974-08-15 application

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