US3291736A - Grease compositions containing alkyl succinic partial esters - Google Patents
Grease compositions containing alkyl succinic partial esters Download PDFInfo
- Publication number
- US3291736A US3291736A US412856A US41285664A US3291736A US 3291736 A US3291736 A US 3291736A US 412856 A US412856 A US 412856A US 41285664 A US41285664 A US 41285664A US 3291736 A US3291736 A US 3291736A
- Authority
- US
- United States
- Prior art keywords
- grease
- employed
- partial esters
- lubricating
- grease compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
- C10M107/50—Lubricating compositions characterised by the base-material being a macromolecular compound containing silicon
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/68—Esters
- C10M129/76—Esters containing free hydroxy or carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
- C10M2201/102—Silicates
- C10M2201/103—Clays; Mica; Zeolites
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/10—Compounds containing silicon
- C10M2201/105—Silica
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/024—Propene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/286—Esters of polymerised unsaturated acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/288—Partial esters containing free carboxyl groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/287—Partial esters
- C10M2207/289—Partial esters containing free hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/105—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing three carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/086—Imides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/10—Amides of carbonic or haloformic acids
- C10M2215/102—Ureas; Semicarbazides; Allophanates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/28—Amides; Imides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/02—Esters of silicic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/08—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having metal-to-carbon bonds
- C10M2227/081—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having metal-to-carbon bonds with a metal carbon bond belonging to a ring, e.g. ferocene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/02—Unspecified siloxanes; Silicones
- C10M2229/025—Unspecified siloxanes; Silicones used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/0405—Siloxanes with specific structure used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
- C10M2229/0415—Siloxanes with specific structure containing aliphatic substituents used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/042—Siloxanes with specific structure containing aromatic substituents
- C10M2229/0425—Siloxanes with specific structure containing aromatic substituents used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/043—Siloxanes with specific structure containing carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/043—Siloxanes with specific structure containing carbon-to-carbon double bonds
- C10M2229/0435—Siloxanes with specific structure containing carbon-to-carbon double bonds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/044—Siloxanes with specific structure containing silicon-to-hydrogen bonds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/044—Siloxanes with specific structure containing silicon-to-hydrogen bonds
- C10M2229/0445—Siloxanes with specific structure containing silicon-to-hydrogen bonds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/045—Siloxanes with specific structure containing silicon-to-hydroxyl bonds
- C10M2229/0455—Siloxanes with specific structure containing silicon-to-hydroxyl bonds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/046—Siloxanes with specific structure containing silicon-oxygen-carbon bonds
- C10M2229/0465—Siloxanes with specific structure containing silicon-oxygen-carbon bonds used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/047—Siloxanes with specific structure containing alkylene oxide groups
- C10M2229/0475—Siloxanes with specific structure containing alkylene oxide groups used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/048—Siloxanes with specific structure containing carboxyl groups
- C10M2229/0485—Siloxanes with specific structure containing carboxyl groups used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
- C10M2229/0505—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
- C10M2229/051—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing halogen
- C10M2229/0515—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing halogen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
- C10M2229/052—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing nitrogen
- C10M2229/0525—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing nitrogen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
- C10M2229/053—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing sulfur
- C10M2229/0535—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing sulfur used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
- C10M2229/054—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing phosphorus
- C10M2229/0545—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing phosphorus used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/02—Bearings
Definitions
- This invention relates to grease compositions and, in one of its aspects, the invention relates to grease compositions possessing non-staining rust inhibiting and improved structural properties. More particularly in this aspect, the invention relates to grease compositions possessing non-staining rust inhibiting and improved structural properties, employing certain surface-active additive compounds capable of imparting such characteristics to greases.
- Another object of the invention is to provide new and improved pigment-thickened silicone grease compositions containing a single additive which imparts rust inhibiting and improved structural properties.
- R and R' one is hydrogen, and the other is selected from the group consisting of alkyl and alkenyl "ice radicals containing from 8 to 18 carbon atoms and preferably from about 9 to about 15 carbon atoms
- R" is a residue of a polyhydric alcohol and preferably a residue of a polyhydric alcohol containing from 2 to 6 carbon atoms
- n is an integer from 1 to 4.
- These corrosion inhibitors are partial esters of an alkyl or alkenylsuccinic anhydride and, preferably, are the prod ucts obtained by the reaction of one molar equivalent of a polyhydric alcohol with two molar equivalents of the anhydride.
- the residue of the polyhydric alcohol, as represented by R" may, generically, contain oxygen, sulfur or nitrogen in the chain as well as other substituents.
- the integer n represents a whole number from 1 to 4 to indicate that within the scope of the inhibitor compound are included the derivatives of diols, triols and other polyhydroxy compounds.
- Illustrative of a typical procedure for the preparation of the inhibitor compounds employed in the novel grease formulations of the present invention is the procedure in which the desired substituted succinic anhydride and alcohol charges are weighed into a suitable jacketed acidresisting vessel equipped with agitation, temperature recording means and a reflux condenser. This charge is heated at a temperature from about C. to about C., while agitating, and held at this temperature, While the progress of the reaction is observed periodically by withdrawing a sample and determining the neutralization number thereof. Heating is continued until the desired neutralization number is obtained, or until it remains substantially constant.
- the resulting reaction is represented as follows:
- the aforementioned partial ester inhibiting agents are combined with a grease-forming quantity of the thickening agent, and are present in the grease composition in an amount from about 0.01 to about 20 percent, by weight, and preferably in an amount from about 0.05 to about 5 percent, by Weight, of the total composition.
- a grease-forming quantity of the thickening agent may be employed as the thickening or gelling agent. These may include any of the conventional metal salts or soaps, which are dispersed in the lubricating vehicle in grease-forming quantities, in such degree as to impart to the resulting grease composition, the desired consistency.
- thickening agents that may be employed in the grease formulations of the present invention in conjunction with the aforementioned partial esters, comprise the non-soap thickeners, such as surface-modified clays and silicas, aryl ureas, calcium complexes and similar materials.
- non-soap thickeners such as surface-modified clays and silicas, aryl ureas, calcium complexes and similar materials.
- grease thickeners may be employed which do not melt and dissolve when used at relatively high temperatures; however, in all other respects, any material which is normally employed for thickening hydrocarbon fluids for forming greases can be used in preparing the improved greases of this invention.
- a particularly outstanding type of thickening agents are pigment thickeners comprising perylimid compounds.
- perylimid compounds Of special importance are the p-methoxy perylimid compounds, and more specifically p-methoxyphenyl-perylimid, when employed as a pigment thickening agent in combination with the aforementioned rust inhibiting partial esters.
- the preparation of perylimid greases, having incorporated therein thickening agents of the aforementioned perylimid types are described in detail in Patent 3,126,341 issued May 24, 1964, and the disclosure thereof is incorporated in the present application, by reference.
- Such perylimid greases, having incorporated therein the partial ester corrosion inhibitors of the present invention have outstanding thermal stability for high temperature operations, and are capable of functioning at temperatures as high as about 600 F. It should be noted, however, that various other types of thickening agents may be employed, in forming the novel greases of the present invention, if so desired.
- the lubricating vehicle employed in the novel greases of the present invention may comprise any of the conventional hydrocarbon oils of lubricating viscosity, and may include mineral or synthetic lubricating oils, aliphatic phosphates, esters and diesters, silicates, siloxanes and oxalkyl ethers and esters.
- Mineral lubricating oils may include mineral or synthetic lubricating oils, aliphatic phosphates, esters and diesters, silicates, siloxanes and oxalkyl ethers and esters.
- lubricating vehicle employed as the lubricating vehicle, may be of any suitable lubricating viscosity ranging from about 45 SSU at 100 F., to about 6000 SSU at 100 F., and preferably from about 50 to about 250 SSU at 210 F.
- oils may have viscosity indexes, varying from below 0 to about 100 or higher. Viscosity indexes from about 70 to about are preferred. The average molecular weights of these oils range from about 250 to about 800.
- the lubricating oil is employed in the grease composition in an amount sufiicient to constitute the balance of the total composition.
- the oil vehicles employed in the novel greases of the present invention may comprise mineral or synthetic oils of lubricating viscosity.
- mineral oils having a viscosity of at least 40 SSU at F., and particularly those within the range of about 60 SSU to about 6000 SSU at 100 F. may be employed.
- synthetic vehicles are employed rather than mineral oils, or in combination therewith, as the lubricating vehicle, various compounds of this type may be successfully utilized.
- Typical synthetic vehicles include: polypropylene, polypropylene glycol, trimethylol propane esters, neopentyl and pentae- 'rythritol esters, di-(Z-ethyl hexyl) sebacate, di-(Z-ethyl hexyl) adipate, di-butyl phthalte, polyethylene glycol di- (Z-ethyl hexoate), fluorocarbons, silicate esters, silanes, esters of phosphorus-containing acids, liquid ureas, ferrocene derivatives, hydrogenated mineral oils, chain type polyphenyls, siloxanes and silicones (polysiloxanes), alkylsubstituted diphenyl ethers typified by a butyl-substituted bis-(pphenoxy phenyl) ether, phenoxy phenyl ethers, etc. Particularly preferred, herein, are polysi
- the following examples will serve to illustrate the improved grease compositions of the present invention and their properties, as evidenced by respective bearing protection and 60 stroke worked penetration tests for the grease formulations therein described.
- the bearing protection against rust tests employed is identified as D1743- 60T, in ASTM Standards on Petroleum Products, 1961.
- the penetration test employed is identified as D2l7-52, in ASTM Standards of Petroleum Products, 1961.
- Example I A lubricating grease composition was prepared by admixing 235 parts by weight of p-methoxyphenyl perylimid pigment, 60 parts by Weight of denatured ethanol and 765 parts by weight of a polymethylphenyl silOXane.
- This polysiloxane had a molar ratio of methyl to phenyl groups of 20:1, molecular weight of approximately 4000 (as determined by vapor osmometry) and the following kinematic viscosity:
- Example II A second lubricating grease composition was prepared in a manner. similar to theprocedure employed TUNE??- ample I, except that 783.5 parts by weight of. the polysiloxane of Example I were employed and 26.5 parts by weight of a partial ester inhibitor, were added to the mixture.
- This inhibitor comprised the reaction product of two moles of dodecenylsuccinic anhydride and one mole of 2-methyl-2,4-pentane diol.
- This inhibitor was added to the polysiloxane as a solution in 60 parts by weight of denatured ethanol; also, 190 parts by weight of the perylimid pigment thickening agent of Example I were employed.
- R and R one is hydrogen, and the other is selected from the group consisting of alkyl and alkenyl radicals containing from 8 to 18 carbon atoms, R is a residue of a polyhydric alcohol, and n is an integer from 1 to 4.
- R and R one is hydrogen, and the other is selected from the group consisting of alkyl and alkenyl radicals containing from 8 to 18 carbon atoms, R is a residue of a polyhydric alcohol containing from 2 to 6 carbon atoms, and n is an integer from 1 to 4.
- a grease composition containing a silicone as a lubricating vehicle; a thickening agent; and as a corrosion inhibitor, a small amount of a partial ester having the general formula:
- R and. R one is hydrogen, and the other is selected from the group consisting of alkyl and alkenyl radicals containing from about 9 to about 15 carbon atoms, R is a residue of a polyhydric alcohol containing from 2 to 6 carbon atoms, and n is an integer from 1 to 4.
- R and R one is hydrogen, and the other is a branched chain dodecenyl group.
- R and R one is hydrogen, and the other is a branched chain dodecenyl group.
- R and R one is hydrogen, and the other is selected from the group consisting of alkyl and alkenyl radicals containing from 8 to 18 carbon atoms, R" is a residue of a polyhydric alcohol, and n is an integer from 1 to 4.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Description
United States Patent 3,291,736 GREASE COMPOSITIONS CONTAINING ALKYL SUCCINIC PARTIAL ESTERS Fritz A. Buehler, Cherry Hill, and John .11. Giammaria, Woodbnry, N.J., assignors to Mobil Gil Corporation, a corporation of New York No Drawing. Filed Nov. 20, 1964, Ser. No. 412,856 9 Claims. (Cl. 25249.6)
This invention relates to grease compositions and, in one of its aspects, the invention relates to grease compositions possessing non-staining rust inhibiting and improved structural properties. More particularly in this aspect, the invention relates to grease compositions possessing non-staining rust inhibiting and improved structural properties, employing certain surface-active additive compounds capable of imparting such characteristics to greases.
Surface-active compounds have been found to exert two types of effects on grease compositions. One type involves structure modification by changing the thickener surface or the interaction between the thickening agent and the lubricating vehicle. Such additives function as structure improvers, stringiness agents, and the like. The other type of efiect is on the interaction between grease and metal surfaces. This grease-metal interaction is manifested in the form of corrosion inhibition, or as lubricity improvement, anti-wear, and other effects. Heretofore, various materials have been employed as rust inhibitors in grease compositions, or as structure improvers, making it possible to lower the concentration of the thickening agent. No attempt, however, has been made to incorporate into a grease formulation, a single additive material which is effective both as a rust inhibiting agent and as a structure improver. This is particularly applicable with respect to pigment thickened silicone grease compositions. Hence, prior to the present invention, no single additive material has been incorporated in grease formulations, which effectively imparts rust inhibiting and improved structural properties.
It is, therefore, an object of the present invention to provide new and improved grease compositions containing a single additive which imparts rust inhibiting and improved structural properties.
Another object of the invention is to provide new and improved pigment-thickened silicone grease compositions containing a single additive which imparts rust inhibiting and improved structural properties.
Other objects and advantages inherent in the invention will become apparent to those skilled in the art from the following detailed description.
In accordance with the present invention new and improved grease compositions are provided, exhibiting the aforementioned properties of rust inhibition and improved structure, which contain small amounts of a partial ester having the general formula:
wherein of R and R' one is hydrogen, and the other is selected from the group consisting of alkyl and alkenyl "ice radicals containing from 8 to 18 carbon atoms and preferably from about 9 to about 15 carbon atoms, R" is a residue of a polyhydric alcohol and preferably a residue of a polyhydric alcohol containing from 2 to 6 carbon atoms, and n is an integer from 1 to 4.
These corrosion inhibitors, as represented by the aboveindicated general formula, are partial esters of an alkyl or alkenylsuccinic anhydride and, preferably, are the prod ucts obtained by the reaction of one molar equivalent of a polyhydric alcohol with two molar equivalents of the anhydride. The residue of the polyhydric alcohol, as represented by R" may, generically, contain oxygen, sulfur or nitrogen in the chain as well as other substituents. The integer n represents a whole number from 1 to 4 to indicate that within the scope of the inhibitor compound are included the derivatives of diols, triols and other polyhydroxy compounds.
Illustrative of a typical procedure for the preparation of the inhibitor compounds employed in the novel grease formulations of the present invention, is the procedure in which the desired substituted succinic anhydride and alcohol charges are weighed into a suitable jacketed acidresisting vessel equipped with agitation, temperature recording means and a reflux condenser. This charge is heated at a temperature from about C. to about C., while agitating, and held at this temperature, While the progress of the reaction is observed periodically by withdrawing a sample and determining the neutralization number thereof. Heating is continued until the desired neutralization number is obtained, or until it remains substantially constant. The resulting reaction is represented as follows:
i 2C12H23CHC 0 H0-R-OH CHz-C 1| 1| C12H23CH'CO R-O C-CHfl CH2 HC-CmHz;
C(O)OH G(O)OH A more detailed description of the preparation and properties of the above described partial esters comprising the corrosion inhibitors present in the novel grease formulations of the present invention, are described in Patent 3,117,091, issued January 7, 1964, and the disclosure thereof is incorporated in the present application, by reference. A particularly outstanding application of the use of the aforementioned partial esters, is their incorporation in silicone-containing greases, as corrosion inhibitors, in which small amounts of a partial ester having the following general formula, is incorporated in such wherein of R and R one is hydrogen, and the other is a branched chain dodecenyl group.
Another outstanding application of the use of the aforementioned partial esters, is their incorporation in silicone-containing greases, as corrosion inhibitors, in which small amounts of a partial ester having the followwherein of R and R one is hydrogen, and the other is a branched chain dodecenyl group.
The outstanding benefit realized by incorporating the above-described partial esters in grease formulations, resides in the unusual property that these partial esters not only impart corrosion inhibiting properties to the grease, making possible the lowering of the concentration of the thickening agent, and at the same time providing good storage stability. Coupled with these important properties is the additional characteristic of these partial esters to act as a reservoir for the oil vehicle, thereby enhancing the prolonged efiicacy and life of the grease composition under the conditions of use.
In preparing the improved grease compositions of the present invention, the aforementioned partial ester inhibiting agents are combined with a grease-forming quantity of the thickening agent, and are present in the grease composition in an amount from about 0.01 to about 20 percent, by weight, and preferably in an amount from about 0.05 to about 5 percent, by Weight, of the total composition. A wide variety of materials may be employed as the thickening or gelling agent. These may include any of the conventional metal salts or soaps, which are dispersed in the lubricating vehicle in grease-forming quantities, in such degree as to impart to the resulting grease composition, the desired consistency. Other thickening agents that may be employed in the grease formulations of the present invention in conjunction with the aforementioned partial esters, comprise the non-soap thickeners, such as surface-modified clays and silicas, aryl ureas, calcium complexes and similar materials. In general, grease thickeners may be employed which do not melt and dissolve when used at relatively high temperatures; however, in all other respects, any material which is normally employed for thickening hydrocarbon fluids for forming greases can be used in preparing the improved greases of this invention.
A particularly outstanding type of thickening agents are pigment thickeners comprising perylimid compounds. Of special importance are the p-methoxy perylimid compounds, and more specifically p-methoxyphenyl-perylimid, when employed as a pigment thickening agent in combination with the aforementioned rust inhibiting partial esters. The preparation of perylimid greases, having incorporated therein thickening agents of the aforementioned perylimid types, are described in detail in Patent 3,126,341 issued May 24, 1964, and the disclosure thereof is incorporated in the present application, by reference. Such perylimid greases, having incorporated therein the partial ester corrosion inhibitors of the present invention, have outstanding thermal stability for high temperature operations, and are capable of functioning at temperatures as high as about 600 F. It should be noted, however, that various other types of thickening agents may be employed, in forming the novel greases of the present invention, if so desired.
The lubricating vehicle employed in the novel greases of the present invention, may comprise any of the conventional hydrocarbon oils of lubricating viscosity, and may include mineral or synthetic lubricating oils, aliphatic phosphates, esters and diesters, silicates, siloxanes and oxalkyl ethers and esters. Mineral lubricating oils,
employed as the lubricating vehicle, may be of any suitable lubricating viscosity ranging from about 45 SSU at 100 F., to about 6000 SSU at 100 F., and preferably from about 50 to about 250 SSU at 210 F. These oils may have viscosity indexes, varying from below 0 to about 100 or higher. Viscosity indexes from about 70 to about are preferred. The average molecular weights of these oils range from about 250 to about 800. The lubricating oil is employed in the grease composition in an amount sufiicient to constitute the balance of the total composition.
As previously indicated, the oil vehicles employed in the novel greases of the present invention may comprise mineral or synthetic oils of lubricating viscosity. When high temperature stability is not a requirement of the finished grease, mineral oils having a viscosity of at least 40 SSU at F., and particularly those within the range of about 60 SSU to about 6000 SSU at 100 F. may be employed. In instances, where synthetic vehicles are employed rather than mineral oils, or in combination therewith, as the lubricating vehicle, various compounds of this type may be successfully utilized. Typical synthetic vehicles include: polypropylene, polypropylene glycol, trimethylol propane esters, neopentyl and pentae- 'rythritol esters, di-(Z-ethyl hexyl) sebacate, di-(Z-ethyl hexyl) adipate, di-butyl phthalte, polyethylene glycol di- (Z-ethyl hexoate), fluorocarbons, silicate esters, silanes, esters of phosphorus-containing acids, liquid ureas, ferrocene derivatives, hydrogenated mineral oils, chain type polyphenyls, siloxanes and silicones (polysiloxanes), alkylsubstituted diphenyl ethers typified by a butyl-substituted bis-(pphenoxy phenyl) ether, phenoxy phenyl ethers, etc. Particularly preferred, herein, are polysiloxanes, such as polymethylphenyl siloxanes, and m-bis-(mphenoxyphenoxy) benzene. v
The following examples will serve to illustrate the improved grease compositions of the present invention and their properties, as evidenced by respective bearing protection and 60 stroke worked penetration tests for the grease formulations therein described. The bearing protection against rust tests employed is identified as D1743- 60T, in ASTM Standards on Petroleum Products, 1961. The penetration test employed is identified as D2l7-52, in ASTM Standards of Petroleum Products, 1961.
Example I A lubricating grease composition was prepared by admixing 235 parts by weight of p-methoxyphenyl perylimid pigment, 60 parts by Weight of denatured ethanol and 765 parts by weight of a polymethylphenyl silOXane. This polysiloxane had a molar ratio of methyl to phenyl groups of 20:1, molecular weight of approximately 4000 (as determined by vapor osmometry) and the following kinematic viscosity:
Temperature, F.: Centistokes 210 3O 100 8O 65 2000 Example II A second lubricating grease composition was prepared in a manner. similar to theprocedure employed TUNE??- ample I, except that 783.5 parts by weight of. the polysiloxane of Example I were employed and 26.5 parts by weight of a partial ester inhibitor, were added to the mixture. This inhibitor comprised the reaction product of two moles of dodecenylsuccinic anhydride and one mole of 2-methyl-2,4-pentane diol. This inhibitor was added to the polysiloxane as a solution in 60 parts by weight of denatured ethanol; also, 190 parts by weight of the perylimid pigment thickening agent of Example I were employed. After processing the resulting grease formulation in the same manner as described in Example I, a final grease formulation was obtained, which presented a smooth buttery appearance, and having a 60 stroke worked penetration, according to the aforementioned ASTM D2l752 penetration test, of 285, and wheel bearing rust protection suflicient to pass the aforementioned ASTM bearing protection test Dl743-60T.
From the foregoing examples, on a comparative basis, it will be apparent, with respect to the significance of incorporating the aforementioned specific type of partial ester in grease formulations in general, and in pigment thickened silicone greases in particular, that the grease formulation of Example II exhibits a much higher consistency with a thickener concentration reduced to the extent of almost 20 percent, as compared with the thickener content of the grease of Example I. This will be observed from the respective worked penetration values, which are a reciprocal function of consistency. Such increased consistency, therefore, permits the use of smaller amounts of the relatively expensive pigment thickener and the incorporation of increased amounts of the lubricating fluid into a grease of specified consistency and results in longer grease life. It will also be noted that the buttery characteristic of the novel grease formulations of the present invention, impart to bearings lubricated therewith, an improved seal against external contamination of dust or corrosive vapor. A soft or stringy characteristic of a grease would not permit the immovable barrier outside of the rolling elements, which a buttery nature would permit. It will also be noted from Example II that improved rust inhibition is realized in the novel grease formulations of the present invention, as evidenced by the ASTM test in accordance with method D1743-60T.
While preferred embodiments of the novel grease compositions of the present invention, and the method for their preparation, have been described for purposes of illustration, it will be understood that various modifications and adaptations thereof, which will be obvious to those skilled in the art, may be made without departing from the spirit of the invention.
We claim:
1. A grease composition containing a silicone as a lubricating vehicle; a thickening agent; and as a corrosion inhibitor, a small amount of a partial ester having the general formula:
wherein of R and R one is hydrogen, and the other is selected from the group consisting of alkyl and alkenyl radicals containing from 8 to 18 carbon atoms, R is a residue of a polyhydric alcohol, and n is an integer from 1 to 4.
2. The grease composition of claim 1 wherein said partial ester is present in an amount, by weight, from about 0.01 to about 20 percent of the total composition.
3. The grease composition of claim 1 wherein said partial ester is present in an amount, by Weight, from about 0.05 to about 5 percent of the total composition.
6 4. A grease composition containing a silicone as a lubricating vehicle; a thickening agent; and as a corrosion inhibitor, a small amount of a partial ester having the general formula:
wherein of R and R one is hydrogen, and the other is selected from the group consisting of alkyl and alkenyl radicals containing from 8 to 18 carbon atoms, R is a residue of a polyhydric alcohol containing from 2 to 6 carbon atoms, and n is an integer from 1 to 4.
5. A grease composition containing a silicone as a lubricating vehicle; a thickening agent; and as a corrosion inhibitor, a small amount of a partial ester having the general formula:
wherein of R and. R one is hydrogen, and the other is selected from the group consisting of alkyl and alkenyl radicals containing from about 9 to about 15 carbon atoms, R is a residue of a polyhydric alcohol containing from 2 to 6 carbon atoms, and n is an integer from 1 to 4.
6. A grease composition containing a silicone as a lubricating vehicle; a thickening agent; and as a corrosion inhibitor, a small amount of a partial ester having the general formula:
wherein of R and R one is hydrogen, and the other is a branched chain dodecenyl group.
7. A grease composition containing a silicone as a lubricating vehicle; a thickening agent; and as a corrosion inhibitor, a small amount of a partial ester having the general formula:
wherein of R and R one is hydrogen, and the other is a branched chain dodecenyl group.
8. A grease composition containing a polysiloxane, as a lubricating vehicle; a perylimid, as a thickening agent; and, as a corrosion inhibitor, a small amount of a partial ester having the general formula:
wherein of R and R one is hydrogen, and the other is selected from the group consisting of alkyl and alkenyl radicals containing from 8 to 18 carbon atoms, R" is a residue of a polyhydric alcohol, and n is an integer from 1 to 4.
9. A grease composition containing polymethylphenylsiloxane, as a lubricating vehicle; p-rnethoxyphenyl perylimid, as a thickening agent; and, as a corrosion inhibitor, a small amount of a partial ester having the general formula:
0 0 km (L6H 11-66 H( 3R 616 116-6 l-OR" O (I) 1 11 wherein of R and R one is hydrogen, and the other is selected from the group consisting of alkyl and alkenyl radicals containing from 8 to 18 carbon atoms, R" is'a residue of a polyhydric alcohol containing from 2 to 6 carbon atoms, and n is an integer from 1 to 4.
References Cited by the Examiner UNITED STATES PATENTS 2,647,872 8/1953 Peterson 252 28 2,682,489 6/1954 Fuchs 252-56 X 3,045,042 7/1962 Staker 260-485 3,053,768 9/1962 Cupper 252 49.6
3,126,341 3/1964 Zakin 252 51.5
FOREIGN PATENTS 1,370,420 6/1964 France.
DANIEL E. WYMAN, Primary Examiner.
W. H. CANNON, Assistant Examiner.
UNITED STATES PATENT OFFICE CERTIFICATE OF CORRECTION Patent No. 3,291,736 December 13, 1966 Fritz A. Buehler et a1.
hat error appears in the above numbered pat- It is hereby certified 1;
hat the said Letters Patent should read as ent requiring correction and t corrected below.
Column 7, lines 11 to 20, the formula should appear as shown below instead of as in the patent:
This certificate supersedes the certificate of correction issued September 19, 1967.
Signed and sealed this 22nd day of October 1968.
(SEAL) Attest:
EDWARD J. BRENNER EDWARD M.FLETCHER,JR.
Commissioner of Patents Attesting Officer
Claims (1)
1. A GREAST COMPOSITION CONTAINING A SILICONE AS A LUBRICATING VEHICLE; A THICKENING AGENT; AND AS A CORRSION INHIBITOR, A SMALL AMOUNT OF A PARTIAL ESTER HAVING THE GENERAL FORMULA:
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US412856A US3291736A (en) | 1964-11-20 | 1964-11-20 | Grease compositions containing alkyl succinic partial esters |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US412856A US3291736A (en) | 1964-11-20 | 1964-11-20 | Grease compositions containing alkyl succinic partial esters |
Publications (1)
Publication Number | Publication Date |
---|---|
US3291736A true US3291736A (en) | 1966-12-13 |
Family
ID=23634775
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US412856A Expired - Lifetime US3291736A (en) | 1964-11-20 | 1964-11-20 | Grease compositions containing alkyl succinic partial esters |
Country Status (1)
Country | Link |
---|---|
US (1) | US3291736A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3671433A (en) * | 1970-12-17 | 1972-06-20 | Dow Corning | Lubricant compositions |
US3720615A (en) * | 1969-08-11 | 1973-03-13 | Kao Corp | Oil-soluble rust preventive composition |
US4839068A (en) * | 1987-10-01 | 1989-06-13 | The Lubrizol Corporation | Polysuccinate esters and lubricating compositions comprising same |
CN1045470C (en) * | 1997-04-24 | 1999-10-06 | 中国石油化工总公司 | Aviation lubricating grease |
DE212015000271U1 (en) | 2014-11-25 | 2017-09-06 | Basf Se | Corrosion inhibitors for fuels and lubricants |
DE212016000150U1 (en) | 2015-07-24 | 2018-03-16 | Basf Se | Corrosion inhibitors for fuels and lubricants |
US11566197B2 (en) | 2018-09-19 | 2023-01-31 | Innospec Limited | Quaternary ammonium compound and fuel composition |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2647872A (en) * | 1950-01-27 | 1953-08-04 | Shell Dev | Grease composition |
US2682489A (en) * | 1950-11-30 | 1954-06-29 | Fuchs George Hugo Von | Rust preventing compositions and process |
US3045042A (en) * | 1957-08-16 | 1962-07-17 | Monsanto Chemicals | Acid polyester succinates |
US3053768A (en) * | 1958-12-23 | 1962-09-11 | Union Carbide Corp | Synthetic lubricant compositions |
US3126341A (en) * | 1960-07-29 | 1964-03-24 | Certificate of correction | |
FR1370420A (en) * | 1962-10-04 | 1964-08-21 | Shell Int Research | Lubricants with superior properties |
-
1964
- 1964-11-20 US US412856A patent/US3291736A/en not_active Expired - Lifetime
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2647872A (en) * | 1950-01-27 | 1953-08-04 | Shell Dev | Grease composition |
US2682489A (en) * | 1950-11-30 | 1954-06-29 | Fuchs George Hugo Von | Rust preventing compositions and process |
US3045042A (en) * | 1957-08-16 | 1962-07-17 | Monsanto Chemicals | Acid polyester succinates |
US3053768A (en) * | 1958-12-23 | 1962-09-11 | Union Carbide Corp | Synthetic lubricant compositions |
US3126341A (en) * | 1960-07-29 | 1964-03-24 | Certificate of correction | |
FR1370420A (en) * | 1962-10-04 | 1964-08-21 | Shell Int Research | Lubricants with superior properties |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3720615A (en) * | 1969-08-11 | 1973-03-13 | Kao Corp | Oil-soluble rust preventive composition |
US3671433A (en) * | 1970-12-17 | 1972-06-20 | Dow Corning | Lubricant compositions |
US4839068A (en) * | 1987-10-01 | 1989-06-13 | The Lubrizol Corporation | Polysuccinate esters and lubricating compositions comprising same |
WO1989011520A1 (en) * | 1988-05-26 | 1989-11-30 | The Lubrizol Corporation | Polysuccinate esters and lubricating compositions comprising same |
CN1045470C (en) * | 1997-04-24 | 1999-10-06 | 中国石油化工总公司 | Aviation lubricating grease |
DE212015000271U1 (en) | 2014-11-25 | 2017-09-06 | Basf Se | Corrosion inhibitors for fuels and lubricants |
DE212016000150U1 (en) | 2015-07-24 | 2018-03-16 | Basf Se | Corrosion inhibitors for fuels and lubricants |
US11566197B2 (en) | 2018-09-19 | 2023-01-31 | Innospec Limited | Quaternary ammonium compound and fuel composition |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3788993A (en) | Lubricating compositions | |
US3185644A (en) | Lubricating compositions containing amine salts of boron-containing compounds | |
US3969237A (en) | Lubricant compositions containing benzotriazole derivatives as copper passivators | |
US2930758A (en) | Ester-base lubricant containing anti-oxidant mixtures | |
CA1220212A (en) | Multifunctional additives | |
JPWO2007116725A1 (en) | Lubricating base oil | |
US3759827A (en) | Lubricant compositions | |
US3291736A (en) | Grease compositions containing alkyl succinic partial esters | |
US4174285A (en) | Lubricant compositions and ether or ester of 1-hydroxybenzotriazole as antioxidant in the compositions | |
US4100083A (en) | Lubricant compositions containing an amine salt of a half ester of succinic acid | |
JPS62138591A (en) | Benzotriazole derivative and organic composition containing the same | |
US3609077A (en) | Lubricant compositions | |
US3336227A (en) | Polyalkylene glycol-diorthosilicic acid ester lubricants and power transmitting fluids | |
US3214377A (en) | Phenylamides of organoamine polyacetic acids as anti-oxidants in greases | |
US4187186A (en) | Lubricant compositions containing esters of benzotriazolecarboxylic acid | |
US3383315A (en) | Polyalkylene glycol-diorthosilicic acid ester lubricants and power transmitting fluids | |
US3446739A (en) | Hydrocarbon lubricating compositions containing mixtures of an alkyl phosphite and fatty acid esters for imparting limited-slip properties | |
US3761405A (en) | Anti oxidants | |
US3422017A (en) | Lubricant compositions containing amine salts | |
EP0001492B1 (en) | Certain oxazolines as load-carrying additives for gear oils | |
US3813339A (en) | Acid-terminated hydroxy ester compounds as lubricating oil additives | |
US2852466A (en) | Grease compositions wherein the thickener comprises a metal salt of an nu-acylaminoorganocarboxylic acid | |
US3384588A (en) | Lubricants containing p-polyphenyl | |
US3532626A (en) | Lubricant compositions | |
US3226324A (en) | Lubricant composition containing phenothiazine and dipyridylamine |