US3136831A - Casting method - Google Patents
Casting method Download PDFInfo
- Publication number
- US3136831A US3136831A US124116A US12411661A US3136831A US 3136831 A US3136831 A US 3136831A US 124116 A US124116 A US 124116A US 12411661 A US12411661 A US 12411661A US 3136831 A US3136831 A US 3136831A
- Authority
- US
- United States
- Prior art keywords
- core
- mandrel
- casting
- filler
- webbing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B21/00—Apparatus or methods for working-up explosives, e.g. forming, cutting, drying
- C06B21/0033—Shaping the mixture
- C06B21/0058—Shaping the mixture by casting a curable composition, e.g. of the plastisol type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/44—Moulds or cores; Details thereof or accessories therefor with means for, or specially constructed to facilitate, the removal of articles, e.g. of undercut articles
- B29C33/52—Moulds or cores; Details thereof or accessories therefor with means for, or specially constructed to facilitate, the removal of articles, e.g. of undercut articles soluble or fusible
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S425/00—Plastic article or earthenware shaping or treating: apparatus
- Y10S425/043—Rocket fuel core
Definitions
- the core comprises a flexible member which is made temporarily rigid by filling it with a soluble or meltable filler compound so that the rigidized core is held to a desired shape during casting but can be collapsed and removed through a small opening after the casting has hardened.
- a primary object of this invention is to provide a casting method wherein a core is provided which can be easily removed after the casting is completed.
- Another object of the present invention is to provide a casting method which has a high safety factor in core removal.
- Still another object of this invention is to provide a casting method wherein a core is used which leaves a completely smooth surface on the casting.
- Still another object of this invention is to provide an economical core which does not utilize expensive materials and which can be fabricated and used with a minimum of labor.
- a still further object of this invention is to provide a core structure which does not contaminate the propellant surface.
- Another object of this invention is to provide a core structure which can be installed and withdrawn through an opening smaller than the core.
- FIGURE 1 is a perspective view of a rigidized cor showing the mold in which the core is made.
- FIGURE 2 is an enlarged sectional view of a core made in accordance with the present invention.
- FIGURE 3 is a sectional view showing the method of making a casting employing the present invention.
- FIGURE 4 is a sectional view similar to FIGURE 3 showing one method of de-rigidizing the core.
- FIGURE 5 is a similar sectional view showing the removal of the flexible member from the otherwise finished casting.
- FIGURE 6 is a sectional view showing a casting which has been manufactured in accordance with the present invention.
- FIGURE 7 is a sectional view showing the method of utilizing the core of the present invention wherein the core is withdrawn through a small opening in a motor.
- FIGURE 8 is a view similar to FIGURE 7 showing a completed rocket motor made in accordance with the present invention.
- FIGURE 1 a mold 7 made of segments 8 and 10 which mold is used for'making the core of the present invention.
- the core is relatively simple and the mold merely has a first cylindrical section 12 and a second cylindrical section 14 connected by a disc-like section 16.
- the mold 7 can be made of any suitable material such asmetal, wood, plastic, ceramic, plaster or the like.
- a flexible member 18 is provided which generally conforms to the desired shape of the finished core or which can be stretched to the desired shape.
- the member 18 can be of any flexible material which is inert to the material being cast, which has sufiicient flexibility to conform to the desired shape and adequate mechanical and thermal stability to stand the ultimate casting and/ or curing operation.
- the flexible member is a rubber impregnated cloth preformed to the desired shape.
- the rubber impregnated cloth forms an excellent release agent for castable solid propellants.
- the member 18 is placed in the core mold 7 and the mold sections are closed around the member 18.
- a mandrel 20 is then placed through the core and a filler compound 22 is then run into the flexible member 18, preferably under pressure so that the member 18 is made to conform to the inner configuration of the mold.
- the filler material 22 can be any desired soluble or meltable material but is preferably a Water soluble plaster.
- the flexible member 18 can be rigidized by filling it in its entirety with the filler compound in some instances, portions of the rigid filler can be precast.
- a cylindrical pre-cast filler element 22a on the mandrel 20, enclose the same in the mold and then cast in place the center disc-like section 22b.
- a third pre-cast cylindrical section 22c can then be inserted to complete the core.
- the core now generally designated 24, is placed in a mold 26 and the casting compound 28 poured through the opening 30.
- the casting compound 28 might well be a rubber-like material with an oxidizer salt therein, as is well known in the solid propellant art.
- the mold is filled, it is heated to polymerize the propellant, whereupon it will form the solid polymerized material 32.
- the mandrel 20 is withdrawn leaving a central opening through which Water can be passed as at 34. This dissolves out the filler compound leaving only the flexible member 18 in place.
- an organic solvent might be used in the case of some 1 filler materials or in the case of other filler materials the filler might be merely heated and allowed to drip out. If only one end of the core is accessible, the solvent must be introduced and withdrawn from the s'arne'end; After substantially all of the filler material has been withdrawn as' is shown in FIGURE 4, the flexible 'm'ember 18 can now be withdrawn from the casting as is shown in FIG- URE 5.
- the mold 26 is then disassembled leaving the' casting with its irregular opening 38 as is shown in FIGURE 6.
- FIGURES 7 and 8 the invention is illustrated in connection with a rocket motor leavingianopening smaller designated'40 is made of fiberglass 42.
- the core includes a small neck portion 44 which is smaller than the desired core.
Description
R. D. ZINN CASTING METHOD June 9, 1964 2 Sheets-Sheet 1 Filed July 14, 1961 Fly. 5
R. D. ZINN CASTING METHOD June 9, 1964 2 Sheets-Sheet 2 Filed July 14, 1961 INVENTORZ 2A man/0 0. Z//v/v BY I A T 7' Ol/VE X5 United States Patent 015 ice 3,136,831 Patented June 9, 1964 This invention relates to a novel casting technique and more particularly relates to a core structure whereby castings with complicated coring can be made with cores which are easily removable from the casting after the latter has hardened. The invention is particularly applicable to the casting of propellants in solid propellant rocket enginesand will be described in terms of casting such propellants. However, it will be apparent from the specification which follows that the invention is been used wherein the coreis made of a plurality of keyed segments of a solid material which can be removed in pieces. Suchmethods havenot been fully satisfactory from several standpoints. For, one thing, in the removal of such cores, there is always the possibility of damaging the casting since many castings are made of materials which can be easily damaged. Another disadvantage is that the castings are frequently made of a highly combustible material and there is always the possibilty of fire or explosion when heat or mechanical force is applied to the casting to remove the core. Further, many of the prior art methods do not leave a completely smooth inner surface but the surface frequently has small ridges or other irregularities therein. The core material of many prior art methods contaminates the propellant grain, causing ignition difliculties.
In accordance with the present invention, a method and apparatus are provided for the manufacture of castings wherein the core comprises a flexible member which is made temporarily rigid by filling it with a soluble or meltable filler compound so that the rigidized core is held to a desired shape during casting but can be collapsed and removed through a small opening after the casting has hardened.
A primary object of this invention is to provide a casting method wherein a core is provided which can be easily removed after the casting is completed.
Another object of the present invention is to provide a casting method which has a high safety factor in core removal.
Still another object of this invention is to provide a casting method wherein a core is used which leaves a completely smooth surface on the casting.
Still another object of this invention is to provide an economical core which does not utilize expensive materials and which can be fabricated and used with a minimum of labor.
A still further object of this invention is to provide a core structure which does not contaminate the propellant surface.
Another object of this invention is to provide a core structure which can be installed and withdrawn through an opening smaller than the core.
Other objects and features of advantage of the present invention will be apparent from the specification which follows.
In the drawings forming part of this application:
FIGURE 1 is a perspective view of a rigidized cor showing the mold in which the core is made.
FIGURE 2 is an enlarged sectional view of a core made in accordance with the present invention.
FIGURE 3 is a sectional view showing the method of making a casting employing the present invention.
FIGURE 4 is a sectional view similar to FIGURE 3 showing one method of de-rigidizing the core.
FIGURE 5 is a similar sectional view showing the removal of the flexible member from the otherwise finished casting.
FIGURE 6 is a sectional view showing a casting which has been manufactured in accordance with the present invention.
FIGURE 7 is a sectional view showing the method of utilizing the core of the present invention wherein the core is withdrawn through a small opening in a motor.
FIGURE 8 is a view similar to FIGURE 7 showing a completed rocket motor made in accordance with the present invention.
Referring now to the drawings by reference characters, there is shown in FIGURE 1 a mold 7 made of segments 8 and 10 which mold is used for'making the core of the present invention. In the present illustration the core is relatively simple and the mold merely has a first cylindrical section 12 and a second cylindrical section 14 connected by a disc-like section 16. It will be understood, of course, that the simple symmetrical shape shown is only for purposes of illustration and that the mold for the core can be made in substantially any desired shape. The mold 7 can be made of any suitable material such asmetal, wood, plastic, ceramic, plaster or the like. In making the core, a flexible member 18 is provided which generally conforms to the desired shape of the finished core or which can be stretched to the desired shape. The member 18 can be of any flexible material which is inert to the material being cast, which has sufiicient flexibility to conform to the desired shape and suficient mechanical and thermal stability to stand the ultimate casting and/ or curing operation. Preferably the flexible member is a rubber impregnated cloth preformed to the desired shape. The rubber impregnated cloth forms an excellent release agent for castable solid propellants. The member 18 is placed in the core mold 7 and the mold sections are closed around the member 18. A mandrel 20 is then placed through the core and a filler compound 22 is then run into the flexible member 18, preferably under pressure so that the member 18 is made to conform to the inner configuration of the mold. The filler material 22 can be any desired soluble or meltable material but is preferably a Water soluble plaster. Although the flexible member 18 can be rigidized by filling it in its entirety with the filler compound in some instances, portions of the rigid filler can be precast. Thus, to make the core shown in FIGURE 2, one might first place a cylindrical pre-cast filler element 22a on the mandrel 20, enclose the same in the mold and then cast in place the center disc-like section 22b. A third pre-cast cylindrical section 22c can then be inserted to complete the core.
After the core has been completed, the core, now generally designated 24, is placed in a mold 26 and the casting compound 28 poured through the opening 30. In the instance illustrated, the casting compound 28 might well be a rubber-like material with an oxidizer salt therein, as is well known in the solid propellant art. After the mold is filled, it is heated to polymerize the propellant, whereupon it will form the solid polymerized material 32. At this point, the mandrel 20 is withdrawn leaving a central opening through which Water can be passed as at 34. This dissolves out the filler compound leaving only the flexible member 18 in place. Although for purposes of illustration water has been shown as being passed through the center,
an organic solvent might be used in the case of some 1 filler materials or in the case of other filler materials the filler might be merely heated and allowed to drip out. If only one end of the core is accessible, the solvent must be introduced and withdrawn from the s'arne'end; After substantially all of the filler material has been withdrawn as' is shown in FIGURE 4, the flexible 'm'ember 18 can now be withdrawn from the casting as is shown in FIG- URE 5. The mold 26 is then disassembled leaving the' casting with its irregular opening 38 as is shown in FIGURE 6. In FIGURES 7 and 8 the invention is illustrated in connection with a rocket motor leavingianopening smaller designated'40 is made of fiberglass 42. The core includes a small neck portion 44 which is smaller than the desired core. Here the rubber impregnated-cloth mandrel 46 is inserted through the neck opening 44 and filled with .a water soluble plaster 48. The propellant 50 is then than the desired core. Here a single'piece case generally I poured in place and cured. The plaster48 is then dissolved out and the cloth 46* can then be pulled out. This (q) placing in a die a continuous open-ended-webbing I member capable of being filled to form a solid, openended body, said webbing member having suflicient flexibility to conform to the desired shape of ahollow portion of said die, said die having" a passage extending through at least one end thereof to said hollow portion; a
' (b) inserting a mandrel through said passageiinto said webbing material in said hollow portion whereby 'to envelope the sides of said mandrel, with said webbing material; 7
'(c) injecting into the space between said' mandrel and the adjacent webbing a flowable' filler material capable of being treated to form a rigid, soluble filler, 'the position of said mandrel beingradjusted such that s after said filler is injected the'ends ofjsaid' mandrel remain uncovered;
(d) treating said filler material to cause to harden l I to forms a rigid'core; f
('e) molding casting' mateiial about'said core while 7 maintaining the ends of said mandrel in an exposed condition and withdrawing said mandrel to provide a passage entirelythrough said core;
(f)- flowinga-solvent for said filler material thronghr I the Pa SOformed wherebyto dissolveandre- 'moveisaidfiller; l, r r I casting so formed;
2. The method of claim wherein the filler material a I I water-solubleplasten' i v V 3'. The method of claim 1 wherein thewebbing member is a rubber impregnated cloth. V
7 References Cited; in the'fil'e of :this patent V UNiTED STATES PATENTS (g) and removing the said fleidble webbing'jfromth'ev
Claims (1)
1. A METHOD OF MAKING A CASTING HAVING A HOLLOW PORTION THEREIN COMPRISING: (A) PLACING INA DIE A CONTINUOUS OPEN-ENDED WEBBING MEMBER CAPABLE OF BEING FILLED TO FORM A SOLID, OPENENDED BODY, SAID WEBBING MEMBER HAVING SUFFICIENT FLEXIBILITY TO CONFORM TO THE DESIRED SHAPE OF A HOLLOW PORTION OF SAID DIE, SAID DIE HAVING A PASSAGE EXTENDING THROUGH AT LEAST ONE END THEREOF TO SAID HOLLOW PORTION; (B) INSERTING A MANDREL THROUGH SAID PASSAGE INTO SAID WEBBING MATERIAL IN SAID HOLLOW PORTION WHEREBY TO ENVELOPE THE SIDES OF SAID MANDREL WITH SAID WEBBING MATERIAL; (C) INJECTING INTO THE SPACE BETWEEN SAID MANDREL AND THE ADJACENT WEBBING A FLOWABLE FILLER MATERIAL CAPABLE OF BEING TREATED TO FORM A RIGID, SOLUBLE FILLER, THE POSITION OF SAID MANDREL BEING ADJUSTED SUCH THAT AFTER SAID FILLER IS INJECTED THE ENDE OF SAID MANDREL REMAIN UNCOVERED; (D) TREATING SAID FILLER MATERIAL TO CAUSE IT TO HARDEN TO FORM A RIGID CORE;
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US124116A US3136831A (en) | 1961-07-14 | 1961-07-14 | Casting method |
Applications Claiming Priority (1)
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US124116A US3136831A (en) | 1961-07-14 | 1961-07-14 | Casting method |
Publications (1)
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US3136831A true US3136831A (en) | 1964-06-09 |
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US124116A Expired - Lifetime US3136831A (en) | 1961-07-14 | 1961-07-14 | Casting method |
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Cited By (44)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3250829A (en) * | 1963-03-03 | 1966-05-10 | Thiokol Chemical Corp | Method of making a combustioninhibited solid propellant grain |
US3261891A (en) * | 1964-03-20 | 1966-07-19 | Thiokol Chemical Corp | Membrane core for solid propellant rocket motors and casting method using same |
US3270999A (en) * | 1963-04-12 | 1966-09-06 | Thiokol Chemical Corp | Segmented core for molding a cavity in a cast solid propellant rocket motor |
US3345693A (en) * | 1965-01-27 | 1967-10-10 | Thiokol Chemical Corp | Apparatus for forming ignition surfaces in solid propellant motors |
US3410942A (en) * | 1965-05-24 | 1968-11-12 | Full Mold Process Inc | Casting method |
US3467745A (en) * | 1966-03-29 | 1969-09-16 | Carborundum Co | Method of forming hot pressed refractory carbide bodies having shaped cavities |
US3692892A (en) * | 1969-02-24 | 1972-09-19 | Jerome H Lemelson | Casting and molding method |
US3713361A (en) * | 1970-08-31 | 1973-01-30 | Us Navy | Method and apparatus for manufacture of and improvements in explosive transfer link |
US3776683A (en) * | 1972-01-31 | 1973-12-04 | Precision Flexmold | Apparatus for molding articles |
US3815863A (en) * | 1972-06-13 | 1974-06-11 | F Andeweg | Collapsible flexible material candle mold |
USRE28733E (en) * | 1971-10-29 | 1976-03-09 | Method of making a cast guide for folding flexible sheets | |
US3952627A (en) * | 1962-08-27 | 1976-04-27 | Thiokol Corporation | Slot former assembly for use in solid propellant rocket motors |
US4100249A (en) * | 1975-11-28 | 1978-07-11 | Scolarma | Method of and apparatus for molding a receptacle |
US4298566A (en) * | 1980-01-07 | 1981-11-03 | International Telephone And Telegraph Corporation | Method of molding electrical connector insulator |
FR2521481A1 (en) * | 1982-02-12 | 1983-08-19 | Marchal Et Cie Ets | Cellulosic film liner for expandable polystyrene core - in curable rubber cover, to prevent adhesion between core and cover before the latter hardens |
WO1984003857A1 (en) * | 1983-03-28 | 1984-10-11 | Park Chem Co | Pressure molding process using salt cores and a composition for making cores |
US4489469A (en) * | 1983-04-18 | 1984-12-25 | Williams International Corporation | Process for the production of gas turbine engine rotors and stators |
US4559191A (en) * | 1983-08-15 | 1985-12-17 | Celanese Corporation | Production of ceramic fibers |
EP0170178A2 (en) * | 1984-08-01 | 1986-02-05 | DEUTSCHE FORSCHUNGSANSTALT FÜR LUFT- UND RAUMFAHRT e.V. | Removable core for producing tubular structures from fibre composites |
US4767505A (en) * | 1984-10-17 | 1988-08-30 | Takara Co., Ltd. | Method of rotationally molding a synthetic resin doll |
US4817911A (en) * | 1985-11-18 | 1989-04-04 | Infanti Chair Manufacturing, Corp. | Apparatus for forming ice sculptures |
US4904423A (en) * | 1983-03-28 | 1990-02-27 | Park Chemical Company | Pressure molding process using salt cores and composition for making cores |
US4945808A (en) * | 1987-01-30 | 1990-08-07 | Ici Australia Operations Proprietary Limited | Primer |
US5176866A (en) * | 1989-02-28 | 1993-01-05 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for producing a resin product having a bent hollow portion and a core usable for the same process |
US5630305A (en) * | 1991-08-26 | 1997-05-20 | Hlasnicek; Richard S. | Surface covering unit methods of use and manufacture |
US5975189A (en) * | 1992-07-30 | 1999-11-02 | Suguru Nemoto | Method of fabricating a metallic article using a non-sand core |
US5985197A (en) * | 1997-04-23 | 1999-11-16 | Radius Engineering, Inc. | Method of manufacturing a composite golf club head |
US6036470A (en) * | 1996-03-29 | 2000-03-14 | Basso, Jr.; Robert J. | Mandrel for producing composite tubular parts |
US20020030302A1 (en) * | 2000-09-08 | 2002-03-14 | Cleary James Paul | Handicraft kit and related process for creating displayable imprints |
EP0924423A3 (en) * | 1997-12-18 | 2002-05-02 | United Technologies Corporation | Method of manufacturing solid fuel rocket motors |
US6398992B1 (en) * | 1999-01-11 | 2002-06-04 | Theodore L. Jacobson | Use of state-change materials in reformable shapes templates or tooling |
US20020190439A1 (en) * | 1997-04-23 | 2002-12-19 | Nelson Ronald H. | Method of manufacturing a composite golf club head |
US6780352B2 (en) | 1999-01-11 | 2004-08-24 | 2Phase Technologies, Inc. | Use of state-change materials in reformable shapes, templates or tooling |
US20050035477A1 (en) * | 1999-01-11 | 2005-02-17 | 2Phase Technologies, Inc. | Use of state-change materials in reformable shapes, templates or tooling |
US7025004B2 (en) | 1999-07-08 | 2006-04-11 | Aai Corporation | Passenger rail car sliding door with high platform threshold |
US20090026659A1 (en) * | 2007-07-25 | 2009-01-29 | United Technologies Corporation | Hybrid Mandrels |
US20090217642A1 (en) * | 2008-02-28 | 2009-09-03 | Fuller Jerome K | Radial flow stereolithographic rocket motor |
US20090321092A1 (en) * | 2008-06-20 | 2009-12-31 | Elkhart Brass Manufacturing Company, Inc. | Fire fighting device with waterway |
US20100281850A1 (en) * | 2008-02-28 | 2010-11-11 | Fuller Jerome K | Buried radial flow stereolithographic rocket motor |
WO2013019898A1 (en) * | 2011-08-01 | 2013-02-07 | The Aerospace Corporation | Systems and methods for casting hybrid rocket motor fuel grains |
US8844133B2 (en) | 2008-02-28 | 2014-09-30 | The Aerospace Corporation | Stereolithographic rocket motor manufacturing method |
US9038368B2 (en) | 2011-08-01 | 2015-05-26 | The Aerospace Corporation | Systems, methods, and apparatus for providing a multi-fuel hybrid rocket motor |
CN107524545A (en) * | 2017-08-21 | 2017-12-29 | 西安长峰机电研究所 | Detachable umbrella disk |
EP3744965A1 (en) * | 2019-05-31 | 2020-12-02 | Raytheon Technologies Corporation | Solid rocket motor propellant manufacture and configurations |
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Cited By (54)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3952627A (en) * | 1962-08-27 | 1976-04-27 | Thiokol Corporation | Slot former assembly for use in solid propellant rocket motors |
US3250829A (en) * | 1963-03-03 | 1966-05-10 | Thiokol Chemical Corp | Method of making a combustioninhibited solid propellant grain |
US3270999A (en) * | 1963-04-12 | 1966-09-06 | Thiokol Chemical Corp | Segmented core for molding a cavity in a cast solid propellant rocket motor |
US3261891A (en) * | 1964-03-20 | 1966-07-19 | Thiokol Chemical Corp | Membrane core for solid propellant rocket motors and casting method using same |
US3345693A (en) * | 1965-01-27 | 1967-10-10 | Thiokol Chemical Corp | Apparatus for forming ignition surfaces in solid propellant motors |
US3410942A (en) * | 1965-05-24 | 1968-11-12 | Full Mold Process Inc | Casting method |
US3467745A (en) * | 1966-03-29 | 1969-09-16 | Carborundum Co | Method of forming hot pressed refractory carbide bodies having shaped cavities |
US3692892A (en) * | 1969-02-24 | 1972-09-19 | Jerome H Lemelson | Casting and molding method |
US3713361A (en) * | 1970-08-31 | 1973-01-30 | Us Navy | Method and apparatus for manufacture of and improvements in explosive transfer link |
USRE28733E (en) * | 1971-10-29 | 1976-03-09 | Method of making a cast guide for folding flexible sheets | |
US3776683A (en) * | 1972-01-31 | 1973-12-04 | Precision Flexmold | Apparatus for molding articles |
US3815863A (en) * | 1972-06-13 | 1974-06-11 | F Andeweg | Collapsible flexible material candle mold |
US4100249A (en) * | 1975-11-28 | 1978-07-11 | Scolarma | Method of and apparatus for molding a receptacle |
US4298566A (en) * | 1980-01-07 | 1981-11-03 | International Telephone And Telegraph Corporation | Method of molding electrical connector insulator |
FR2521481A1 (en) * | 1982-02-12 | 1983-08-19 | Marchal Et Cie Ets | Cellulosic film liner for expandable polystyrene core - in curable rubber cover, to prevent adhesion between core and cover before the latter hardens |
WO1984003857A1 (en) * | 1983-03-28 | 1984-10-11 | Park Chem Co | Pressure molding process using salt cores and a composition for making cores |
US4904423A (en) * | 1983-03-28 | 1990-02-27 | Park Chemical Company | Pressure molding process using salt cores and composition for making cores |
US4489469A (en) * | 1983-04-18 | 1984-12-25 | Williams International Corporation | Process for the production of gas turbine engine rotors and stators |
US4559191A (en) * | 1983-08-15 | 1985-12-17 | Celanese Corporation | Production of ceramic fibers |
EP0170178A2 (en) * | 1984-08-01 | 1986-02-05 | DEUTSCHE FORSCHUNGSANSTALT FÜR LUFT- UND RAUMFAHRT e.V. | Removable core for producing tubular structures from fibre composites |
EP0170178A3 (en) * | 1984-08-01 | 1987-07-22 | Deutsche Forschungs- Und Versuchsanstalt Fur Luft- Und Raumfahrt E.V. | Removable core for producing tubular structures from fibre composites |
US4767505A (en) * | 1984-10-17 | 1988-08-30 | Takara Co., Ltd. | Method of rotationally molding a synthetic resin doll |
US4817911A (en) * | 1985-11-18 | 1989-04-04 | Infanti Chair Manufacturing, Corp. | Apparatus for forming ice sculptures |
US4945808A (en) * | 1987-01-30 | 1990-08-07 | Ici Australia Operations Proprietary Limited | Primer |
US5176866A (en) * | 1989-02-28 | 1993-01-05 | Asahi Kasei Kogyo Kabushiki Kaisha | Process for producing a resin product having a bent hollow portion and a core usable for the same process |
US5630305A (en) * | 1991-08-26 | 1997-05-20 | Hlasnicek; Richard S. | Surface covering unit methods of use and manufacture |
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US6036470A (en) * | 1996-03-29 | 2000-03-14 | Basso, Jr.; Robert J. | Mandrel for producing composite tubular parts |
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