US3124535A - Fur cleaning composition - Google Patents
Fur cleaning composition Download PDFInfo
- Publication number
- US3124535A US3124535A US3124535DA US3124535A US 3124535 A US3124535 A US 3124535A US 3124535D A US3124535D A US 3124535DA US 3124535 A US3124535 A US 3124535A
- Authority
- US
- United States
- Prior art keywords
- fur
- composition
- percent
- cleaning composition
- sawdust
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims description 46
- 238000004140 cleaning Methods 0.000 title claims description 18
- 239000007788 liquid Substances 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 4
- 239000011780 sodium chloride Substances 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- 239000002904 solvent Substances 0.000 description 20
- 238000005108 dry cleaning Methods 0.000 description 18
- 150000003512 tertiary amines Chemical class 0.000 description 18
- 125000000217 alkyl group Chemical group 0.000 description 16
- 235000014113 dietary fatty acids Nutrition 0.000 description 16
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 16
- 239000000194 fatty acid Substances 0.000 description 16
- 150000004665 fatty acids Chemical class 0.000 description 16
- 229920002545 silicone oil Polymers 0.000 description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 12
- 235000010469 Glycine max Nutrition 0.000 description 8
- 240000007842 Glycine max Species 0.000 description 8
- 239000002202 Polyethylene glycol Substances 0.000 description 8
- QIQXTHQIDYTFRH-UHFFFAOYSA-N Stearic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 8
- 125000004432 carbon atoms Chemical group C* 0.000 description 8
- 229920001223 polyethylene glycol Polymers 0.000 description 8
- -1 alkyl phenol Chemical compound 0.000 description 6
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 description 6
- 229910052742 iron Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000011707 mineral Substances 0.000 description 6
- 150000002989 phenols Chemical class 0.000 description 6
- 238000005201 scrubbing Methods 0.000 description 6
- 235000015096 spirit Nutrition 0.000 description 6
- 235000013162 Cocos nucifera Nutrition 0.000 description 4
- 240000007170 Cocos nucifera Species 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 4
- 150000001412 amines Chemical group 0.000 description 4
- 238000010009 beating Methods 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N oxane Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 4
- 239000008117 stearic acid Substances 0.000 description 4
- FDIPWBUDOCPIMH-UHFFFAOYSA-N 2-decylphenol Chemical compound CCCCCCCCCCC1=CC=CC=C1O FDIPWBUDOCPIMH-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N Nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 229940027983 antiseptics and disinfectants Quaternary ammonium compounds Drugs 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 231100000078 corrosive Toxicity 0.000 description 2
- 231100001010 corrosive Toxicity 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/42—Amino alcohols or amino ethers
- C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
Definitions
- This invention relates to compositions and methods for cleaning furs and, more specifically, fur garments such as coats and jackets.
- a conventional method of cleaning fur garments comprises scrubbing a garment with one of the ordinary dry cleaning solvents, tumbling the garment with sawdust and a dry cleaning solvent in a suitable container, and beating the garment, as with a stick, to remove the sawdust, which adheres tenaciously to the fur.
- cleaning and, if desired, glazing can be carried out by an initial scrubbing step followed by tumbling with sawdust and dry cleaning solvent without any need for beating the fur to remove the sawdust.
- a composition of a nature disclosed hereinbelow having both cleansing characteristics and capacity for inhibiting the adherence of sawdust to fur and, also, if desired, for glazing the fur.
- the composition above referred to comprises from 1 to 10 percent (preferably about 5 percent) of a quaternary amine, from 5 to 20 percent (preferably about percent) of tertiary amine, from 5 to 20 percent (preferably about 10 percent) of a polyethylene glycol ether of an alkylated phenol and if a glazing etfect is also desired, from 1 to 5 percent (preferably about 2 percent) of a silicone oil, the remainder being a dry cleaning solvent such as mineral spirits. If desired, a greater percentage of dry cleaning solvent can be used than indicated above, but then the composition is not diluted (when used) as much as indicated hereinbelow.
- the percentages above disclosed are percentages by weight.
- the above mentioned quaternary ammonium compound is a salt, ordinarily the chloride, of an alkyl trimethyl ammonium compound wherein the alkyl group contains from 8 to 18 carbon atoms.
- Examples of such quaternary ammonium compounds are those in which the alkyl group has been derived from fatty acids (by reduction of the carboxyl group), such as soya fatty acid, coconut fatty acid or stearic acid.
- R signifies an alkyl group containing from 8 to 18 carbon atoms and wherein x and y signify numbers totalling from 2 to 10.
- the alkyl group may be derived from a fatty acid (by reduction of the carboxyl group), such as soya fatty acid, coconut fatty acid or stearic acid.
- polyethylene glycol ether of an alkylated phenol is a condensation product of from 2 to 10 molecules of ethylene oxide with one molecule of an alkyl phenol wherein the alkyl group contains from 8 to 10 carbon atoms, for instance, octyl, nonyl or decyl phenol.
- the above mentioned silicone oil is a polydimethyl or polydiethyl siloxane.
- the above mentioned four materials are avail- 7 parts by volume) of solvent for each part of my composition.
- the garment is first scrubbed with this solution and thereafter tumbled with sawdust and an additional amount of diluted composition using, for instance, about two liquid ounces of my composition (before dilution). Garments thus treated are throughly cleaned. The sawdust can be removed by simply shaking the garments.
- a silicone oil is included with my composition, the fur is also glazed.
- a specific'composition according to the present invention contains 2.5 percent (by weight) of alkyl trimethyl ammonium chloride wherein the alkyl group is derived from soya fatty acid; 10 percent of a tertiary amine having the above indicated structural formula in which the alkyl group is derived from soya fatty acid and in which x and y total between 8 and 10; 10 percent of nonyl phenol condensed with about 10 molecules of ethylene oxide; 2 percent of polydimethylsiloxane; and 75.5 percent of mineral spirits.
- sawdust does not adhere tenaciously to fur which has been immersed in a dry cleaning solvent having the above disclosed composition dispersed or dissolved therein.
- This effect is brought about jointly by thespecific quaternary ammonium compound and the specific tertiary. amine included with my composition. Either one of these compounds (the quaternary ammonium compound and the tertiary amine), when used singly, will under some conditions inhibit the tendency of the sawdust to adhere to the fur. But to bring about this result under all conditions of use and at all times of use, both the quaternary ammonium compound and the tertiary amine must be used in combination. The tertiary amine also performs another important function.
- a composition is made up containing all the above mentioned materials except only the tertiary amine, then water or moisture contacting such an incomplete composition will be quite corrosive to metals, in particular, iron, with the result that the use of such an incomplete composition in iron or other metal equipment will be impractical, since moisture can never be completely excluded.
- the complete composition of my invention can be used in iron or other metal equipment without causing corrosion.
- the polyethylene glycol ether of alkylated phenol forming part of my composition functions as a detergent; to keep the other ingredients, in particular, the silicone oil, in stable dispersion or solution; and also to cause the fur to be Wetted or penetrated by dry cleaning solvent having my composition dissolved or dispersed therein.
- the silicone oil when used, serves to make the fur glossy and shiny.
- a liquid, fur cleaning composition comprising: from 1 to 10 parts by weight of an alkyl trimethyl ammonium salt wherein the alkyl group contains from 8 to 18 carbon atoms; from 5 to 20 parts by weight of a tertiary amine having the structural formula:
- composition according to claim 1 which further includes from 1- to 5 parts by weight of a silicone oil selected from the group consisting of the polydimethyl and polydiethyl siloxanes.
Description
3,124,535 FUR CLEANING CGMPGSITIDN Willis C. Ware, 1018 N. Clark St., Chicago, Ill. No Drawing. Filed Sept. 10, 1956, Ser. No. 608,702 3 Claims. (Cl. 252-153) This invention relates to compositions and methods for cleaning furs and, more specifically, fur garments such as coats and jackets.
A conventional method of cleaning fur garments comprises scrubbing a garment with one of the ordinary dry cleaning solvents, tumbling the garment with sawdust and a dry cleaning solvent in a suitable container, and beating the garment, as with a stick, to remove the sawdust, which adheres tenaciously to the fur.
According to the present invention, cleaning and, if desired, glazing, can be carried out by an initial scrubbing step followed by tumbling with sawdust and dry cleaning solvent without any need for beating the fur to remove the sawdust. For effecting this result, I incorporate with the dry cleaning solvent used both in the scrubbing and tumbling steps a composition (of a nature disclosed hereinbelow) having both cleansing characteristics and capacity for inhibiting the adherence of sawdust to fur and, also, if desired, for glazing the fur.
The composition above referred to comprises from 1 to 10 percent (preferably about 5 percent) of a quaternary amine, from 5 to 20 percent (preferably about percent) of tertiary amine, from 5 to 20 percent (preferably about 10 percent) of a polyethylene glycol ether of an alkylated phenol and if a glazing etfect is also desired, from 1 to 5 percent (preferably about 2 percent) of a silicone oil, the remainder being a dry cleaning solvent such as mineral spirits. If desired, a greater percentage of dry cleaning solvent can be used than indicated above, but then the composition is not diluted (when used) as much as indicated hereinbelow. The percentages above disclosed are percentages by weight.
The above mentioned quaternary ammonium compound is a salt, ordinarily the chloride, of an alkyl trimethyl ammonium compound wherein the alkyl group contains from 8 to 18 carbon atoms. Examples of such quaternary ammonium compounds are those in which the alkyl group has been derived from fatty acids (by reduction of the carboxyl group), such as soya fatty acid, coconut fatty acid or stearic acid.
The above mentioned tertiary amine has the following structural formula:
(om-orIz-o) X-H H2 OH2O)y-H wherein R signifies an alkyl group containing from 8 to 18 carbon atoms and wherein x and y signify numbers totalling from 2 to 10. The alkyl group may be derived from a fatty acid (by reduction of the carboxyl group), such as soya fatty acid, coconut fatty acid or stearic acid.
The above mentioned polyethylene glycol ether of an alkylated phenol is a condensation product of from 2 to 10 molecules of ethylene oxide with one molecule of an alkyl phenol wherein the alkyl group contains from 8 to 10 carbon atoms, for instance, octyl, nonyl or decyl phenol.
The above mentioned silicone oil is a polydimethyl or polydiethyl siloxane.
The above mentioned four materials (quaternary ammonium compound, tertiary amine, polyethylene glycol ether of an alkylatcd phenol and silicone oil) are avail- 7 parts by volume) of solvent for each part of my composition. The garment is first scrubbed with this solution and thereafter tumbled with sawdust and an additional amount of diluted composition using, for instance, about two liquid ounces of my composition (before dilution). Garments thus treated are throughly cleaned. The sawdust can be removed by simply shaking the garments. When a silicone oil is included with my composition, the fur is also glazed.
A specific'composition according to the present invention (giving by way of an example) contains 2.5 percent (by weight) of alkyl trimethyl ammonium chloride wherein the alkyl group is derived from soya fatty acid; 10 percent of a tertiary amine having the above indicated structural formula in which the alkyl group is derived from soya fatty acid and in which x and y total between 8 and 10; 10 percent of nonyl phenol condensed with about 10 molecules of ethylene oxide; 2 percent of polydimethylsiloxane; and 75.5 percent of mineral spirits.
As disclosed hereinabove, sawdust does not adhere tenaciously to fur which has been immersed in a dry cleaning solvent having the above disclosed composition dispersed or dissolved therein. This effect is brought about jointly by thespecific quaternary ammonium compound and the specific tertiary. amine included with my composition. Either one of these compounds (the quaternary ammonium compound and the tertiary amine), when used singly, will under some conditions inhibit the tendency of the sawdust to adhere to the fur. But to bring about this result under all conditions of use and at all times of use, both the quaternary ammonium compound and the tertiary amine must be used in combination. The tertiary amine also performs another important function. If a composition is made up containing all the above mentioned materials except only the tertiary amine, then water or moisture contacting such an incomplete composition will be quite corrosive to metals, in particular, iron, with the result that the use of such an incomplete composition in iron or other metal equipment will be impractical, since moisture can never be completely excluded. The complete composition of my invention, on the other hand, can be used in iron or other metal equipment without causing corrosion. The polyethylene glycol ether of alkylated phenol forming part of my composition functions as a detergent; to keep the other ingredients, in particular, the silicone oil, in stable dispersion or solution; and also to cause the fur to be Wetted or penetrated by dry cleaning solvent having my composition dissolved or dispersed therein. The silicone oil, when used, serves to make the fur glossy and shiny.
Many details may be varied without departing from my invention and it is therefore not my intention to limit the patent granted on this invention otherwise then necessitated by the scope of the appended claims.
The invention is claimed as follows:
1. A liquid, fur cleaning composition comprising: from 1 to 10 parts by weight of an alkyl trimethyl ammonium salt wherein the alkyl group contains from 8 to 18 carbon atoms; from 5 to 20 parts by weight of a tertiary amine having the structural formula:
(pm-capo) .-n
NR @Hi-cm-mw 3,124,535 Patented Mar. 10, 1964 2. A composition according to claim 1 which further includes from 1- to 5 parts by weight of a silicone oil selected from the group consisting of the polydimethyl and polydiethyl siloxanes.
3. A fur cleaning composition according to claim 1 wherein said dry cleaning solvent is mineral spirits.
References Cited in the file of this patent UNITED STATES PATENTS 1,317,130 Heineke Sept. 23, 1919 1,747,324 Savitt Feb. 18, 1930 1,902,232 Haertel Mar. 21, 1933 1,923,178 Ulrich et al. Aug. 22, 1933 2,165,356
OTHER 7 REFERENCES Dow Corning Silicone Note Book, Fluid Series No. 3,
Dunbar July 11, 1939 15 Sept-19 48. Dow Corning Corp. pages 10 and 21.
Claims (1)
1. A LIQUID, FUR CLEANING COMPOSITION COMPRISING: FROM 1 TO 10 PARTS BY WEIGHT OF AN ALKYL TRIMETHYL AMMONIUN SALT WHEREIN THE ALKYL GROUP CONTAINS FROM 8 TO 18 CARBON ATOMS; FROM 5 TO 20 PARTS BY WEIGHT ARY AMINE HAVING THE STRUCTURAL FORMULA:
Publications (1)
Publication Number | Publication Date |
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US3124535A true US3124535A (en) | 1964-03-10 |
Family
ID=3453951
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US3124535D Expired - Lifetime US3124535A (en) | Fur cleaning composition |
Country Status (1)
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US (1) | US3124535A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2318268A1 (en) * | 1975-07-16 | 1977-02-11 | Procter & Gamble Europ | TEXTILE TREATMENT COMPOSITIONS |
Citations (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1317130A (en) * | 1919-09-23 | Process for cleaning- ftjrs | ||
US1747324A (en) * | 1928-03-10 | 1930-02-18 | Benjamin M Savitt | Process of cleaning furs, fabrics, and the like |
US1902232A (en) * | 1933-03-21 | Cleaner for furs and the like and protiess of cleaning | ||
US1923178A (en) * | 1930-03-20 | 1933-08-22 | Ig Farbenindustrie Ag | Hydroxy alkyl ethers of tertiary amines and process of preparing same |
US2165356A (en) * | 1935-03-13 | 1939-07-11 | Ici Ltd | Dry-cleaning fluid |
US2174762A (en) * | 1935-04-13 | 1939-10-03 | Ig Farbenindustrie Ag | Condensation products derived from amines and method of producing them |
US2591663A (en) * | 1948-05-27 | 1952-04-08 | Root Nathan | Method of cleaning furs |
US2669546A (en) * | 1949-12-23 | 1954-02-16 | Alrose Chemical Company | Detergents containing imidazoline lactates |
US2697075A (en) * | 1951-12-21 | 1954-12-14 | California Research Corp | Dry-cleaning compositions |
US2729576A (en) * | 1953-09-29 | 1956-01-03 | Davies Young Soap Company | Method of dry cleaning fabric and simultaneously rendering the same antistatic |
US2751358A (en) * | 1949-11-28 | 1956-06-19 | Shell Dev | Non-foaming detergents |
US2758977A (en) * | 1951-05-25 | 1956-08-14 | Gen Aniline & Film Corp | Detergent composition and method of producing same |
US2759975A (en) * | 1952-05-28 | 1956-08-21 | Gen Aniline & Film Corp | Mixed alkyl-benzyl-alkylol quaternary ammonium salts |
US2799599A (en) * | 1957-07-16 | Lustered fur hairs and method for | ||
US2807557A (en) * | 1951-04-16 | 1957-09-24 | Clifford R Carney | Method of treating furs |
US2861949A (en) * | 1956-09-10 | 1958-11-25 | Willis C Ware | Fur glazing composition and method for preparing same |
-
0
- US US3124535D patent/US3124535A/en not_active Expired - Lifetime
Patent Citations (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2799599A (en) * | 1957-07-16 | Lustered fur hairs and method for | ||
US1902232A (en) * | 1933-03-21 | Cleaner for furs and the like and protiess of cleaning | ||
US1317130A (en) * | 1919-09-23 | Process for cleaning- ftjrs | ||
US1747324A (en) * | 1928-03-10 | 1930-02-18 | Benjamin M Savitt | Process of cleaning furs, fabrics, and the like |
US1923178A (en) * | 1930-03-20 | 1933-08-22 | Ig Farbenindustrie Ag | Hydroxy alkyl ethers of tertiary amines and process of preparing same |
US2165356A (en) * | 1935-03-13 | 1939-07-11 | Ici Ltd | Dry-cleaning fluid |
US2174762A (en) * | 1935-04-13 | 1939-10-03 | Ig Farbenindustrie Ag | Condensation products derived from amines and method of producing them |
US2591663A (en) * | 1948-05-27 | 1952-04-08 | Root Nathan | Method of cleaning furs |
US2751358A (en) * | 1949-11-28 | 1956-06-19 | Shell Dev | Non-foaming detergents |
US2669546A (en) * | 1949-12-23 | 1954-02-16 | Alrose Chemical Company | Detergents containing imidazoline lactates |
US2807557A (en) * | 1951-04-16 | 1957-09-24 | Clifford R Carney | Method of treating furs |
US2758977A (en) * | 1951-05-25 | 1956-08-14 | Gen Aniline & Film Corp | Detergent composition and method of producing same |
US2697075A (en) * | 1951-12-21 | 1954-12-14 | California Research Corp | Dry-cleaning compositions |
US2759975A (en) * | 1952-05-28 | 1956-08-21 | Gen Aniline & Film Corp | Mixed alkyl-benzyl-alkylol quaternary ammonium salts |
US2729576A (en) * | 1953-09-29 | 1956-01-03 | Davies Young Soap Company | Method of dry cleaning fabric and simultaneously rendering the same antistatic |
US2861949A (en) * | 1956-09-10 | 1958-11-25 | Willis C Ware | Fur glazing composition and method for preparing same |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2318268A1 (en) * | 1975-07-16 | 1977-02-11 | Procter & Gamble Europ | TEXTILE TREATMENT COMPOSITIONS |
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