US3123134A - Free-gas phase initial pressure - Google Patents

Free-gas phase initial pressure Download PDF

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US3123134A
US3123134A US3123134DA US3123134A US 3123134 A US3123134 A US 3123134A US 3123134D A US3123134D A US 3123134DA US 3123134 A US3123134 A US 3123134A
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    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/18Repressuring or vacuum methods

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  • the present invention relates to methods .for the recovery of oil from subsurface reservoirs and more particularly relates to an improved process for recovering additional oil from previously exploited, watered-out reservoirs.
  • the invention relates to a process for augmenting recovery from a wateredout reservoir by first establishing a high pressure free gas phase in thereservoir and thereafter reducing the pressure on the reservoir.
  • An oil reservoir where in jected water or natural water encroachment has reduced the oil saturation to a limit near the residual oil satura tion characteristic of the displacement of oil by water in that particular reservoir is generally referred to as a watered-out" reservoir.
  • the waterflooding process is considerably more attractive than many other secondary recovery processes because the water utilized can ordinarily be obtained at little cost and need not be recovered from the reservoir in order to make the process economically feasible.
  • Watertlooding processes are generally carried out until a high ratio of water to oil at the production well makes further exploitation unattractive from an economics standpoint.
  • Studies based in part upon the fluid content of cores taken from watered-out reservoirs indicate that from 20 to about 40 percent of the oil initially present may remain in a reservoir at the conclusion of a successful waterflooding project.
  • the present invention provides a new and improved process for the recovery of oil from watered-out reservoirs which is considerably more attractive from the economics standpoint than processes advocated in the past.
  • ice refers to gas not dissolved in liquids present in the system.
  • the use of this process generally permits the recovery of from about 30 to about 50 percent of the oil remaining in the affected portion of the reservoir after waterflooding and, where repeated pressuring and pressure reduction steps are utilized, may permit even more significant results.
  • the cost of the process is low and hence it can be applied to many reservoirs from which additional oil cannot be economically recovered by any other known method.
  • the process of the invention is normally carried out in a watered-out reservoir containing one or more injection wells and one or more production wells spaced at some distance from the injection wells. Gas is injected into the injection wells in quantities and at a pressure sufficient to establish the necessary free gas phase.
  • the production wells may be closed off prior to the introduction of gas at the injection wells. In some small reservoirs, however, it may be preferable to withdraw fluids from the production wells during the establishment of the free-gas phase.
  • the production wells may be subjected to a suitable back pressure while gas is being introduced at the injection well or may instead be allowed to flow free initially and may thereafter be closed off as additional gas is injected to build up the reservoir pressure to the desired level. Fol-lowing the establishment of the high pressure free-gas phase in this manner, the injection wells are closed 01? and the production wells are allowed to flow. If desired, back pressure may be maintained at the production wells and gradually reduced to control the flow. Substantial quantities of oil, together with gas and water, flow into the production wells and are produced. After substantially no quantities and at a pressure sufiicient to establish the requisite free-gas phase. Thereafter, gas injection is Oil, gas and water are produced until the oil production rate declines to an uneconomical level. Thereafter, gas may again be injected into the reservoir and the cycle repeated.
  • gases may be employed in carrying out the process of the invention, the principal requirement for the gas selected being that it not condense under reservoir conditions of temperature and pressure.
  • Gases whichrnay be utilized include air, natural gas, fiue gases,
  • Air and natural gas are preferred because of their ready availability and will be employed most frequently in practicing the invention.
  • the pressure of the free-gas phase established in the reservoir will generally range from about pounds per square inch to about 3,000 pounds per square inch. It has been found that the quantity of oil recovered in the process of the invention increases with increasing pressure but that the greater recovery realized at extremely high pressures generally does not warrant the higher compression costs incurred. For this reason, it is generally preferred to employ gas pressures ranging from about 400 to about 1,500 pounds per square inch. The pressure utilized will, of course, depend upon the pressure in the reservoir at the onset of the operation. Sufficient pressure to permit injection of the gas must be used and hence higher gas pressures may be utilized in after reducing the pressure.
  • the amount of gas injected into the reservoir to establish the free-gas phase will generally range between about one percent and about twenty-five percent of the reservoir pore volume, determined at the reservoir temperature and the pressure of the free-gas phase to be established in the reservoir.
  • the injection of gas in excess of about twentyfive percent of the reservoir pore volume has little or no effect upon the oil recovery obtained and in many cases may increase the cost of the operation to the point where it becomes economically unattractive.
  • EXAMPLE I In the first of a series of experiments. a 13-inch core of Weller sandstone measuring 2 inches in diameter was prepared by placing it in a section of pipe and using a low melting metal alloy which expands upon cooling to seal it in place. The pipe was provided with an inlet and a longitudinally opposed outlet for injecting and withdrawings fluids. The core was then saturated with about 65 volume percent oiland about volume percent connate water. In this initial test, crude oil obtained from the London field in Illinois was used. The saturated core was thereafter flushed with water until all of the oil displaceable by water had been recovered from it. The oil content of the core was then determined. It was found that the waterfiooding'reduced the oil content of the core to 24.3% of the pore volume.
  • methane was injected into one end of the watered-out core at a pressure of about 1100 pounds per square inch. About 12 percent methane, based on core pore volume and measured at ambient temperature and the selected pressure was used. The fluids displaced by the injected gas were recovered at the opposite end of the core and analyzed. it was found that thus driving gas through the watered-out core displaced very little of the oil contained in the core, only about 0.1 percent of a pore volume.
  • iRecovery during the pressure reduction step of the process ranged from 10.8 percent to 15.0 percent, based upon pore volume. The data obtained are shown in Table 111.
  • the cores were then depressurized and the fluids produced with the gas were coilected and measured.
  • the oil recovery during the pressure reduction stage of the process ranged from 8.3 percent of the pore volume at an initial pressure of 190 pounds per square inch to 16.4 percent of the pore volume at an initial pressure of 1700 pounds per square inch.
  • the results of this second series of tests are set forth in greater detail in Table 11 below.
  • EXAMPLE 111 Further tests were carried out to determine the effect of the volume of gas injected upon oil recovery. The procedure employed was essentially the same as in the earlier tests except that the injected gas volumes ranged from about 4.6 percent up to about 722 percent, based upon core pore volume. All the tests were carried out at ferred to carry out the process of the invention by injecting only from about one percent to about twenty-five percent gas, based upon pore volume, into the reservoir. The fact that the injection of 722 percent gas resulted in the recovery of only 2.1 percent oil by gas drive in the above experiments clearly demonstraes that conventional gas drive processesv applied to non-watered-out reservoirs are not effective after a waterflooding process has been carried out.
  • An improved process for recovering oil from a watered-out oil bearing reservoir underlying the earths surface which comprises injecting a noncondensing gas into said reservoir through at least one well penetrating said reservoir, said gas being injected at a pressure within the range between about 100 and about 3,000 lbs. per square inch and in a quantity sufficient to establish a free-gas phase therein; discontinuing the injection of said gas; reducing the'pressure on said reservoir; and producing reservoir fluids through at least one well penetrating said reser- V011.
  • a process is defined by claim 1 wherein said noncondensing gas injected into said reservoir is natural gas.
  • An improved process for augmenting production from a well penetrating a watered-out oil-bearing reservoir which comprises injecting from about 1 to about 25 percent, based upon reservoir pore volume and measured at the injection temperature and pressure, of a noncondensing gas through said well into said reservoir at a pressure of from about 100 to about 3000 pounds per square inch to establish a free-gas phase therein, discontinuing the injection of said gas, reducing the pressure on said well, and recovering oil, gas and water flowing into said well from said reservoir.
  • An improved process for recovering oil from a watered-out subsurface oil-bearing reservoir following a waterfiooding operation which comprises injecting from about 1 percent to about 25 percent, based upon reservoir pore volume and measured at the injection temperature and pressure, of a noncondensing gas into said reservoir through at least one injection well at an injection pressure of from about 100 to about 3000 pounds per square inch whereby a free-gas phase is established in said reservoir; discontinuing the injection of said gas; reducing pressure onsaid reservoir at at least one production well spaced from said injection well; and withdrawing oil, water and gas flowing into said production well from said reservoir.
  • a process as defined by claim 8 including the additional steps of discontinuing the withdrawal of fluids from said reservoir after substantially no more oil can be recovered, injecting a noncondensing gas into said reservoir through said injection well at a pressure of from. about 100 to about 3000 pounds per square inch, reducing the pressure on said reservoir at said production well, and recovering additional oil from said production well.
  • a process as defined by claim 8 wherein, following injection of said gas at said injection well, the pressure on said reservoir is reduced at both said injection well and said production well and fluids are withdrawn from said reservoir through both said injection well and said production well.
  • a process is defined by claim 8 wherein said gas injected is a flue gas.
  • An improved process for recovering oil from a subterranean oil-bearing reservoir which comprises injecting water into said reservoir through at least one injection well, recovering fiuids from said reservoir through at least one production well spaced from said injection well, continuing said injection of water and recovery of fluids until said reservoir is watered-out, thereafter injecting from about 1 to about 25 percent, based upon reservoir pore volume and measured at the injection temperature and pressure, of air into said reservoir through said injection well at a pressure of from about 400 to about 1500 pounds per square inch to establish a freegas phase while maintaining a back pressure at said production well, discontinuing the injection of gas at said injection well, reducing the pressure on said reservoir at said production well, and recovering oil from said reservoir through said production well.

Description

March 3, 1964 J. R. KYTE ETAL RECOVERY or on. FROM WATERED-OUT REszRvoIRs Filed April 1. 1960 IF H/12 I I AIR Inventors Attorney A AIR 0 METHANE John R. Kyte Virgil 0. Noumunn By 2...) a. Q;
METHANE FREE-GAS PHASE INITIAL PRESSURE POUNDS PER SQUARE INCH 200 400 600 800 I000 I200 I400 I600 I800 2000 mmmmm wD40 mmOm {a mm Ouwm :0
.lnited States 't atent 3,123,134 RECOVERY OF. OIL FROM WATERED-OUT I RESERVOIRS John R. Kyte and Virgil 0. Naumaun, Tulsa, Okla, assignors to Jersey Production Research Company, a corporation of Delaware Filed Apr. 1, 1960, Ser. No. 19,310 14 Claims. (Cl. 1662) The present invention relates to methods .for the recovery of oil from subsurface reservoirs and more particularly relates to an improved process for recovering additional oil from previously exploited, watered-out reservoirs. In still greater particularity, the invention relates to a process for augmenting recovery from a wateredout reservoir by first establishing a high pressure free gas phase in thereservoir and thereafter reducing the pressure on the reservoir.
Experience has shown that techniques utilized in the primary exploitation of subterranean oil-bearing reservoirs generally permit the recovery of only a small fraction of the total oil initially present in such reservoirs. In order to stimulate further production after the natural reservoir energy has largely been expended by primary recovery techniques, a number of secondary recovery processes have been developed. The most widely used of these is the waterfiooding process. By simply injecting water into an underground oil reservoir through one or more injection wells and forcing it in the direction of production wells spaced some distance from the injection wells, oil not recoverable by primary recovery techniques can be produced. An oil reservoir where in jected water or natural water encroachment has reduced the oil saturation to a limit near the residual oil satura tion characteristic of the displacement of oil by water in that particular reservoir is generally referred to as a watered-out" reservoir. The waterflooding process is considerably more attractive than many other secondary recovery processes because the water utilized can ordinarily be obtained at little cost and need not be recovered from the reservoir in order to make the process economically feasible.
Watertlooding processes are generally carried out until a high ratio of water to oil at the production well makes further exploitation unattractive from an economics standpoint. Studies based in part upon the fluid content of cores taken from watered-out reservoirs indicate that from 20 to about 40 percent of the oil initially present may remain in a reservoir at the conclusion of a successful waterflooding project. There are thus many watered-out reservoirs which contain large quantities of potentially recoverable oil. Efforts to produce this oil, however, have largely been unsuccessful. Solvent displacement processes and other methods which might permit additional recovery from watered-out reservoirs are generally too expensive to warrant their use in such reservoirs. Less costly processes, those based upon the use of air or a similar gaseous displacing agent for example, are normally less efiicient than watertlooding and hence are not effective in watered-out reservoirs. For this reason, ter- 551 exhaust gases from internal combustion engines and simitiary recovery from waterfiooded reservoirs has not been viewed favorably in the past.
The present invention provides a new and improved process for the recovery of oil from watered-out reservoirs which is considerably more attractive from the economics standpoint than processes advocated in the past. In accordance with the invention, it has now been found that appreciable quantities of oil can be recovered from an oil-bearing reservoir following watertlooding by establishing a high pressure free gas phase in the reservoir and thereafter reducing the reservoir pressure to produce the oil contained therein. The expression free-gas phase halted and the well is permitted to flow.
3,123,134 Patented Mar. 3, 1964 ice as used herein refers to gas not dissolved in liquids present in the system. The use of this process generally permits the recovery of from about 30 to about 50 percent of the oil remaining in the affected portion of the reservoir after waterflooding and, where repeated pressuring and pressure reduction steps are utilized, may permit even more significant results. The cost of the process is low and hence it can be applied to many reservoirs from which additional oil cannot be economically recovered by any other known method.
The process of the invention is normally carried out in a watered-out reservoir containing one or more injection wells and one or more production wells spaced at some distance from the injection wells. Gas is injected into the injection wells in quantities and at a pressure sufficient to establish the necessary free gas phase. In most reservoirs, particularly those in which a water drive contributed to primary recovery, the production wells may be closed off prior to the introduction of gas at the injection wells. In some small reservoirs, however, it may be preferable to withdraw fluids from the production wells during the establishment of the free-gas phase. During an operation of the latter type, the production wells may be subjected to a suitable back pressure while gas is being introduced at the injection well or may instead be allowed to flow free initially and may thereafter be closed off as additional gas is injected to build up the reservoir pressure to the desired level. Fol-lowing the establishment of the high pressure free-gas phase in this manner, the injection wells are closed 01? and the production wells are allowed to flow. If desired, back pressure may be maintained at the production wells and gradually reduced to control the flow. Substantial quantities of oil, together with gas and water, flow into the production wells and are produced. After substantially no quantities and at a pressure sufiicient to establish the requisite free-gas phase. Thereafter, gas injection is Oil, gas and water are produced until the oil production rate declines to an uneconomical level. Thereafter, gas may again be injected into the reservoir and the cycle repeated.
A number of gases may be employed in carrying out the process of the invention, the principal requirement for the gas selected being that it not condense under reservoir conditions of temperature and pressure. Gases whichrnay be utilized include air, natural gas, fiue gases,
l-ar gases available at low cost. Air and natural gas are preferred because of their ready availability and will be employed most frequently in practicing the invention.
The pressure of the free-gas phase established in the reservoir will generally range from about pounds per square inch to about 3,000 pounds per square inch. It has been found that the quantity of oil recovered in the process of the invention increases with increasing pressure but that the greater recovery realized at extremely high pressures generally does not warrant the higher compression costs incurred. For this reason, it is generally preferred to employ gas pressures ranging from about 400 to about 1,500 pounds per square inch. The pressure utilized will, of course, depend upon the pressure in the reservoir at the onset of the operation. Sufficient pressure to permit injection of the gas must be used and hence higher gas pressures may be utilized in after reducing the pressure.
high pressure reservoirs than would otherwise normally be used.
The amount of gas injected into the reservoir to establish the free-gas phase will generally range between about one percent and about twenty-five percent of the reservoir pore volume, determined at the reservoir temperature and the pressure of the free-gas phase to be established in the reservoir. The injection of gas in excess of about twentyfive percent of the reservoir pore volume has little or no effect upon the oil recovery obtained and in many cases may increase the cost of the operation to the point where it becomes economically unattractive. The use of from about 1 percent to about 15 percent of gas, based upon reservoir pore volume, is preferable in most instances.
The exact nature and objects of the process of the invention can best be understood by considering the results obtained in experimental work during which oil recovered from the core during this pressure reduction step. The final oil content of the core was 14.7 percent of the pore volume. This represents a forty percent reduction in the oil content of the core following waterflooding.
Following the initial test described above. additional tests were carried out in similar manner using air, nitrogen, flue gas and methane. Gas pressures were varied between about 200 pounds per square inch and about 1630 pounds per square inch. Tests were carried out with Soltrol, a refined white oil having a. viscosity of 1.4 centipoises, as well as with the Loudon crude oil. A 45-inch Weller sandstone core was employed in some of the tests. The amount of gas injected ranged from 9 to 16 percent of the pore volume. The results obtained in this first series of experiments are set forth in Table I below.
Table I EFFECT OF GAS COMPOSITION ON OIL RECOVERY FROM WATERED-OUT CORES Oil Con- Oil (on- Oil lte- Oil Con- Oil Re- Gas Intent After" tout. After covered by tent After covered by Run Oil Gas Gas Prtsjoetiul, lor- Waturflootl, (his Drive, (his Drive, Pressure Pressure sure, psi. cont loro l'tl't'tnt Percent Percent Redue- Reduc- Volunie Pore Vol lorv \ol- Porn Voltion, Pertion, Perutuo time urne cont Pore cent; Pore Volume Volume Methane" 1,100 12 24. 3 34. 2 0. l 14. 7 9. 5 Nitrogen" 1. 630 12 La. 2 22. 0 0. 2 13. 1 8.9 Air 1,000 11. 5 28.0 97.3 0.2 19.1 8.7 Flue Gas" S 15 34. 1 33. 9 0. 2 24. 5 9. 4 Methane. 930 16 32. 4 32.3 0.1 23.1 9. 2 -tl0 470 12 35.3 35. 1 0.2 22.3 12.8 Air 500 11 33. 4 33. 2 l). 2 21. 9 11. 3 .Methaneu 940 10 33. 'r' 33. 6 0. 1 19. 6 14. 0 Air 1,000 11 33.9 33. 7 0.2 21.0 12. 7 Methane" 1.100 9 33. 2 32. 7 0. 5 18.0 13. 8 Air l, 170 10 33. 0 32. 9 0. 1 18. 1 15. 0 Methane 210 10 33. 9 6 0. 3 24. t) 9. 6 Air 200 .10 33. 9 33. 7 0. 2 26. 7 7. 1
was recovered from watered-out cores by first establishing high pressure,free-gas phases in the cores and there- The attached drawing which shows the relationship between the initial pressure of the free-gas phase established and the oil recovered upon reduction of the pressure further illustrates the invention.
EXAMPLE I In the first of a series of experiments. a 13-inch core of Weller sandstone measuring 2 inches in diameter was prepared by placing it in a section of pipe and using a low melting metal alloy which expands upon cooling to seal it in place. The pipe was provided with an inlet and a longitudinally opposed outlet for injecting and withdrawings fluids. The core was then saturated with about 65 volume percent oiland about volume percent connate water. In this initial test, crude oil obtained from the London field in Illinois was used. The saturated core was thereafter flushed with water until all of the oil displaceable by water had been recovered from it. The oil content of the core was then determined. It was found that the waterfiooding'reduced the oil content of the core to 24.3% of the pore volume.
Following the waterfiooding as described above, methane was injected into one end of the watered-out core at a pressure of about 1100 pounds per square inch. About 12 percent methane, based on core pore volume and measured at ambient temperature and the selected pressure was used. The fluids displaced by the injected gas were recovered at the opposite end of the core and analyzed. it was found that thus driving gas through the watered-out core displaced very little of the oil contained in the core, only about 0.1 percent of a pore volume.
After a high pressure, free gas phase had been established in the core as described above, the pressure upon the core was reduced and the fluids produced with the escaping gas were collected and analyzed. A significant quantity of oil, about 9.5 percent of the pore volume, was
From the above table it can be seen that driving gas through the watered-out cores did not permit the recovery of significant quantities of oil. This confirms earlier experience and is not unexpected. since it is known that waterfiooding in general is considerably more effective than gas drive as a method for displacing oil from subsurface reservoirs. The data show, however, that the formation of a free-gas phase followed by a pressure reduction step resulted in the recovery of from about 20 percent to about percent of the oil present in the cores following waterfiooding. The process of the invention thus permits the recovery of significant quantities of oil which cannot be recovered by ordinary waterfiooding and gas driving techniques.
The data set forth above also demonstrate that the process of the invention may be carried out with a variety of gases. Air, nitrogen, methane and flue gas all permitted the recovery of substantial quantities of oil. In most cases the results obtained with methane and line gas were only slightly better than those obtained with air and nitrogen, indicating that gas solubility in the oil may be of some significance but that the effect due to solubility is small. The fact that substantial recoveries were obtained with both the Loudon crude oil and the refined white oil indicates that the process is not greatly dependent upon the properties of the oil in the reservoir andmay be applied to reservoirs containing oils which vary considerably with respect to their composition, vis cosity, gravity and other characteristics.
EXAMPLE XI A second series of experiments were carried out to determine the effect of pressure upon the process of the in vention. The Weiler sandstone cores employed in the previous tests were cleaned, dried and resaturatedwith connate water and the refined white oil referred to earlier and then wa-terfiooded until no more oil could be displaced. The oil content of the watered-out core was determined for each run and was found to be about 33 to 34 percent in terms of core pore volume. From 9 to 12 percent methane or air, measured at the pressure selected andbased upon core pore volume, was then injected into the core during each run. The pressures utilized ranged from 190 pounds per square inch to 1700 a pressure of 1150 pounds per square inch. Air was employed as the injection gas and Soltrol, a refined white oil, was used as the oil. iRecovery during the pressure reduction step of the process ranged from 10.8 percent to 15.0 percent, based upon pore volume. The data obtained are shown in Table 111.
Table III EFFECT OF GAS VOLUME 0N OIL RECOVERY Oil Con- Oil Con- 01] Re- 011 Con- Oil Re- Gus Intent Alter tent After covered by tent Alter covered by Gus Presected. Per- Waterflood, Gas Drive, Gas Drive, Pressure Pressure Run 011 Gas sure, p.s.i. cent Pore Percent Percent Percent Reduc, Reduc- Volume Pore Vol- Porn 701- Pore Voltion, Pertlon, Perurns ume ume cent Pore oent'Pore Volume Volume l 1,150 4.6 33.9 33.9 o 19.6 14 a 1,150 33.3 33.2 0.1 18.2 0 1,150 12 33.4 33.0 0.4 19.9 13 1 I, 150 688 33.4 32.6 0.8 17.7 14.9 1,150 711 33.5 31.4 2.1 20.6 10 8 pounds per square inch. The fluids displaced from the cores were collected and analyzed. The oil recovered as a result or" the gas drive ranged from 0.1 to 0.5 percent, based upon core pore volume. The cores were then depressurized and the fluids produced with the gas were coilected and measured. The oil recovery during the pressure reduction stage of the process ranged from 8.3 percent of the pore volume at an initial pressure of 190 pounds per square inch to 16.4 percent of the pore volume at an initial pressure of 1700 pounds per square inch. The results of this second series of tests are set forth in greater detail in Table 11 below.
Inspection of the data set forth in Table III shows that increasing the volume of gas injected above 4.6 percent of the pore volume had little elfect upon the oil recovery obtained. Substantially the same recovery was obtained by pressure reduction after 4.6 percent gas, based upon pore volume, had been injected as was obtained following the injection of much larger quantities of gas. In an actual reservoir, substantially less than 4.6 percent gas will normally be elfective. The injected gas does not sweep the entire reservoir and hence the etfective gas concentration in the swept area is higher than the volume of injected gas would indicate. For this reason, it is pre- T able II EFFECT OF GAS PRESSURE ON OIL RECOVERY FROM WATERED-OUT CORES O11 Con- O11 Con- 011 Re- 011 Con- 011 Re- Gss Intent Alter tent Alter covered by tent Aiter covered by Gas Presjected Per- Waterflood, Gas Drive, Gas Drive, Pressure Pressure Run Oil Gas sure, p.s.i. cent are Percent Percent Percent Reduc- Reduc- Volume Pore Vol- Pore Vol- Pore Voltion, Perflon, Perume ume ume cent Pore cent Pore Volume Volume Methane 190 9 33. 5 33.3 0. 2 25. 0 8. 3 210 10 33. 9 33. 6 0. 3 24. 0 9. 6 450 9 33. 8 33. 7 0. 1 21. 2 12 5 470 12 35. 3 35.1 0. 2 22. 3 12. 8 900 9 33. 7 33. 5 0. 2 20. 2 13. 3 900 9 33. 3 33. 2 0. 1 10. 2 14. 0 040 9 34. 3 34.1 0. 2 20. 9 13. 2 940 10 33. 7 33. 6 0. 1 19. 6 14.0 1,100 9 33.2 32. 7 0.5 18.9 13.8 1, 700 9 33. 5 33. 3 0. 2 16. 9 16. 4 200 10 33. 9 33. 7 0. 2 26. t1 7. 1 500 11 33.4 33.2 0.2 21.9 11.3 1,000 11 33.9 33.7 0.2 21.0 127 1.500 10 33.3 33.2 0. 1 18.2 15.0 1, 500 12 34.2 9 0.3 18.2 15.7 1, 500 10 34. 0 33.9 0. 1 17. T 16. 2 I, 500 10 34. 0 33. 9 0.1 21. 2 12. 7
The data in Table 11 show that the oil recovery from a watered-out core increases with increases in the initial pressure of the free-gas stage established in the core prior to the pressure reduction step. These data are presented graphically in the drawing, from which it can be seen that the recovery increases with pressure rapidly up to about 400 pounds per square inch and that the rate of increase is slower thereafter. Because the cost of compressing gas becomes prohibitively high at extremely high pressures, it is generally preferred to carry out the process of the invention at pressures between about 400 pounds per square inch and about 1500 pounds per square inch.
EXAMPLE 111 Further tests were carried out to determine the effect of the volume of gas injected upon oil recovery. The procedure employed was essentially the same as in the earlier tests except that the injected gas volumes ranged from about 4.6 percent up to about 722 percent, based upon core pore volume. All the tests were carried out at ferred to carry out the process of the invention by injecting only from about one percent to about twenty-five percent gas, based upon pore volume, into the reservoir. The fact that the injection of 722 percent gas resulted in the recovery of only 2.1 percent oil by gas drive in the above experiments clearly demonstraes that conventional gas drive processesv applied to non-watered-out reservoirs are not effective after a waterflooding process has been carried out.
EXAMPLE 1V inlet. It was found that substantial quantities of oil were produced from the cores in this manner. The results of these tests are set forth in Table IV.
The core was repressured to 1050 pounds per square inch and again the pressure was reduced. In this second cycle, 4.5% oil was recovered. A third cycle carried out in the Table IV EFFECT OF PRESSURE REDUCTION ON RECOVERY FROM SINGLE WELL Oil Con- Oll Con- Oil 120- Oil Con- Oil Re- Gas Intent After tent After covered by tent After covered by I Gas Presjt-cted, Ier- Waterflood, Gas Drive, Gas Drive, Pressure Pressure Run Oil Gas sure, p.s.i. ccnt Pore Percent Percent Percent Retluc- Reduc- Volume Pore Vol- Pore Vol- Port: Vollion, lertion, Perumc unto ulnu cent Pore cent Pore Volume Volume A Soltrnl Air 1,150 4. 3 34.1 34.1 27. Z 6. 9 B "do .do l. 150 4. 33 8 33. 7 0. l 27. 6 6 l c (in rln 1,150 12 33 .9 33.7 0.2 21.9 11.8
same manner yielded 3.5% oil. additional recovery was obtained.
A second set of tests using methane and Wyrol confirmed the results obtained with the heavy oil. When In a fourth cycle, no
repeated cycles were used with a methane-Soltrol system;
however, no additional recovery resulted following the initial pressure reduction step. The results obtained in the two sets of tests using Wyrol appear in Table V.
Table V EFFECT OF REPEATED CYCLES ON RECOVERY FROM WATERED-OUI CORES Oil Con- Oil Con- Oil Rc Oil Con- Oil Re- Gns Intcnt After tent After covered by tent After covered by Gas Presjccted, Per- Watcrfloml, Gus Drive, Gas Drive. Pressure Pressure Run Oil Gas sure, p.s.i. cent Pore Percent Percent Percent Reduc- Reduc- Volume Pore Vol- Pore Vol- Pore Voltion, Pertion, Pertime time urne cent Pore cent Pore Volume Volume A Wyrol Methane- 1, 050 12 37.4 30.9 0.5 30. 5 64 Second Cycle Do do 1.050 12 26.0 4 5 Third Cycle Do do 1,050 12 22.5 3 5 Fourth Cycle Do .do... 1,050 12 22.5 0 13 Wyrol Mcthanc. 1,050 12 36.2 36.1 0.1 28.2 7. 9
Second Cycle Do d0 1.050 12 25.2 3 0 Third Cycle Do l0 1,050 12 25.2 0
pected. Recovery by means of a single well provides an attractive method for securing additional oil from many small watered-out fields.
EXAMPLE V Tests similar to those described earlier were carried out to determine the elfect of repeated repressuring and pressure reduction cycles in the process of the invention. The
first of these utilized methane and Wyrol, a heavy, refined white oil having a viscosity of about centipoises. The core employed was first saturated with the Wyrol and connate water. After waterfiooding until no more oil could be displaced, a free gas phase was established in it will be noted that repeated gas injection and pressure reduction steps permitted the recovery of substantially more of the heavy viscous oil than could be recovered in a single cycle. There are many watered-out reservoirs which contain such heavy oils and hence repeated cycles can often be employed to advantage. In reservoirs containing less viscous oils similar to Soltrol, repeated cycles have little effect.
It will be recognized that several modifications may be made in the process described above without departing from the scope of the invention. In many cases, for example, it may be desirable to inject gas into a wateredout reservoir through one well and to thereafter reduce the reservoir pressure and produce reservoir fluids through both that well and adjacent wells. This and other similar modifications will be readily apparent to those skilled in the art.
What is claimed is:
1. An improved process ,for recovering oil from a watered-out oil bearing reservoir underlying the earths surface which comprises injecting a noncondensing gas into said reservoir through at least one well penetrating said reservoir, said gas being injected at a pressure within the range between about 100 and about 3,000 lbs. per square inch and in a quantity sufficient to establish a free-gas phase therein; discontinuing the injection of said gas; reducing the'pressure on said reservoir; and producing reservoir fluids through at least one well penetrating said reser- V011.
2. A process as defined by claim 1 wherein said gas is injected at a pressure of from about 400 to about 1,500 pounds per square inch.
3. A process as defined by claim 1 wherein said non- I condensing gas injected into said reservoir is air.
4. A process is defined by claim 1 wherein said noncondensing gas injected into said reservoir is natural gas.
5. A process as defined by claim 1 wherein a noncondensing gas is reinjected into said reservoir and the pressure thereon is again reduced after the rate at which fluids are produced from the reservoir declines to an undesirably low level.
6. An improved process for augmenting production from a well penetrating a watered-out oil-bearing reservoir which comprises injecting from about 1 to about 25 percent, based upon reservoir pore volume and measured at the injection temperature and pressure, of a noncondensing gas through said well into said reservoir at a pressure of from about 100 to about 3000 pounds per square inch to establish a free-gas phase therein, discontinuing the injection of said gas, reducing the pressure on said well, and recovering oil, gas and water flowing into said well from said reservoir.
7. A process as defined by claim 6 wherein an exhaust gas from an internal combustion engine is injected into said reservoir as said noncondensing gas.
8. An improved process for recovering oil from a watered-out subsurface oil-bearing reservoir following a waterfiooding operation which comprises injecting from about 1 percent to about 25 percent, based upon reservoir pore volume and measured at the injection temperature and pressure, of a noncondensing gas into said reservoir through at least one injection well at an injection pressure of from about 100 to about 3000 pounds per square inch whereby a free-gas phase is established in said reservoir; discontinuing the injection of said gas; reducing pressure onsaid reservoir at at least one production well spaced from said injection well; and withdrawing oil, water and gas flowing into said production well from said reservoir.
9. A process as defined by claim 8 wherein irom about 1 percent to about percent air, based upon reservo r pore volume and measured at the injection pressure, 18 injected into said reservoir as said noncondensmg gas.
10. A process as defined by claim 8 wherein from about 1 percent to about 15 percent natural gas, based upon reservoir pore volume and measured at the injection pressure, is injected into said reservoir as said noncondensing gas.
11. A process as defined by claim 8 including the additional steps of discontinuing the withdrawal of fluids from said reservoir after substantially no more oil can be recovered, injecting a noncondensing gas into said reservoir through said injection well at a pressure of from. about 100 to about 3000 pounds per square inch, reducing the pressure on said reservoir at said production well, and recovering additional oil from said production well.
12. A process as defined by claim 8 wherein, following injection of said gas at said injection well, the pressure on said reservoir is reduced at both said injection well and said production well and fluids are withdrawn from said reservoir through both said injection well and said production well.
13. A process is defined by claim 8 wherein said gas injected is a flue gas.
14. An improved process for recovering oil from a subterranean oil-bearing reservoir which comprises injecting water into said reservoir through at least one injection well, recovering fiuids from said reservoir through at least one production well spaced from said injection well, continuing said injection of water and recovery of fluids until said reservoir is watered-out, thereafter injecting from about 1 to about 25 percent, based upon reservoir pore volume and measured at the injection temperature and pressure, of air into said reservoir through said injection well at a pressure of from about 400 to about 1500 pounds per square inch to establish a freegas phase while maintaining a back pressure at said production well, discontinuing the injection of gas at said injection well, reducing the pressure on said reservoir at said production well, and recovering oil from said reservoir through said production well.
References Cited in the file of this patent UNITED STATES PATENTS 1,067,868 Dunn July 22, 1913 2,669,307 Mulholland et al Feb. 16, 1954 2,875,831 Martin et ai. Mar. 3, 1959 OTHER REFERENCES Petroleum Production Engineering,- Exploitation, by Uren, 2nd edition, published by McGraw-Hill Book Co. of New York in 1939, pages 423 to 426.
Dickey et al.: Article in Secondary Recovery of Oil 0' in the United States, see. ed. pub. 1950 by American Petroleum Institute, W. 50th St., New York, N.Y. pages 444 to 462.
Talash et al.: Article in the Petroleum Engineer, Sept. 1957, pages 3-27 to B30.

Claims (1)

1. AN IMPROVED PROCESS FOR RECOVERING OIL FROM A WATERED-OUT OIL BEARING RESERVOIR UNDERLYING THE EARTH''S SURFACE WHICH COMPRISES INJECTING A NONCONDENSING GAS INTO SAID RESERVOIR THROUGH AT LEAST ONE WELL PENETRATING SAID RESERVOIR, SAID GAS BEING INJECTED AT A PRESSURE WITHIN THE RANGE BETWEEN ABOUT 100 AND ABOUT 3,000 LBS. PER SQUARE INCH AND IN A QUANTITY SUFFICIENT TO ESTABLISH A FREE-GAS PHASE THEREIN; DISCONTINUING THE INJECTION OF SAID GAS; RE-
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Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3266569A (en) * 1962-09-14 1966-08-16 Marathon Oil Co Recovery of viscous unsaturated crude by intermittent gas injection
US3283818A (en) * 1963-12-31 1966-11-08 Phillips Petroleum Co Removal of water blocks from oil and gas wells
US3333637A (en) * 1964-12-28 1967-08-01 Shell Oil Co Petroleum recovery by gas-cock thermal backflow
US3386513A (en) * 1965-04-20 1968-06-04 Mobil Oil Corp Recovery of viscous crude by fluid injection
US3455385A (en) * 1967-12-26 1969-07-15 Marathon Oil Co Production of crude oil from a watered-out subterranean formation
US3480081A (en) * 1967-02-20 1969-11-25 Continental Oil Co Pressure pulsing oil production process
US3525396A (en) * 1968-12-26 1970-08-25 Mobil Oil Corp Alternate gas and water flood process for recovering petroleum
US3525395A (en) * 1968-12-26 1970-08-25 Mobil Oil Corp Alternate gas and water flood process for recovering oil
US3599717A (en) * 1969-12-03 1971-08-17 Mobil Oil Corp Alternate flood process for recovering petroleum
US4040487A (en) * 1975-06-23 1977-08-09 Transco Energy Company Method for increasing the recovery of natural gas from a geo-pressured aquifer
US4090564A (en) * 1976-05-24 1978-05-23 Transco Energy Company Method for increasing the recovery of oil and gas from a water invaded geo-pressured water drive oil reservoir
US4116276A (en) * 1976-05-24 1978-09-26 Transco Energy Company Method for increasing the recovery of natural gas from a geo-pressured aquifer
US4161047A (en) * 1977-10-19 1979-07-17 Riley Edwin A Process for recovery of hydrocarbons
US4509596A (en) * 1984-01-23 1985-04-09 Atlantic Richfield Company Enhanced oil recovery
US4676314A (en) * 1985-12-06 1987-06-30 Resurrection Oil Corporation Method of recovering oil
US4683948A (en) * 1986-05-23 1987-08-04 Atlantic Richfield Company Enhanced oil recovery process employing carbon dioxide
US4819724A (en) * 1987-09-03 1989-04-11 Texaco Inc. Modified push/pull flood process for hydrocarbon recovery
US4953619A (en) * 1986-10-10 1990-09-04 University Of Waterloo Enhanced oil recovery process
US5025863A (en) * 1990-06-11 1991-06-25 Marathon Oil Company Enhanced liquid hydrocarbon recovery process
WO2017189864A1 (en) * 2016-04-27 2017-11-02 Highlands Natural Resources, Plc Method of forming a gas phase in water saturated hydrocarbon reservoirs

Citations (3)

* Cited by examiner, † Cited by third party
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US1067868A (en) * 1911-04-13 1913-07-22 Irwin L Dunn Method of increasing the productiveness of oil-wells.
US2669307A (en) * 1950-06-13 1954-02-16 Sinclair Oil & Gas Co Petroleum production process
US2875831A (en) * 1951-04-16 1959-03-03 Oil Recovery Corp Dissemination of wetting agents in subterranean hydrocarbon-bearing formations

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1067868A (en) * 1911-04-13 1913-07-22 Irwin L Dunn Method of increasing the productiveness of oil-wells.
US2669307A (en) * 1950-06-13 1954-02-16 Sinclair Oil & Gas Co Petroleum production process
US2875831A (en) * 1951-04-16 1959-03-03 Oil Recovery Corp Dissemination of wetting agents in subterranean hydrocarbon-bearing formations

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3266569A (en) * 1962-09-14 1966-08-16 Marathon Oil Co Recovery of viscous unsaturated crude by intermittent gas injection
US3283818A (en) * 1963-12-31 1966-11-08 Phillips Petroleum Co Removal of water blocks from oil and gas wells
US3333637A (en) * 1964-12-28 1967-08-01 Shell Oil Co Petroleum recovery by gas-cock thermal backflow
US3386513A (en) * 1965-04-20 1968-06-04 Mobil Oil Corp Recovery of viscous crude by fluid injection
US3480081A (en) * 1967-02-20 1969-11-25 Continental Oil Co Pressure pulsing oil production process
US3455385A (en) * 1967-12-26 1969-07-15 Marathon Oil Co Production of crude oil from a watered-out subterranean formation
US3525396A (en) * 1968-12-26 1970-08-25 Mobil Oil Corp Alternate gas and water flood process for recovering petroleum
US3525395A (en) * 1968-12-26 1970-08-25 Mobil Oil Corp Alternate gas and water flood process for recovering oil
US3599717A (en) * 1969-12-03 1971-08-17 Mobil Oil Corp Alternate flood process for recovering petroleum
US4040487A (en) * 1975-06-23 1977-08-09 Transco Energy Company Method for increasing the recovery of natural gas from a geo-pressured aquifer
US4090564A (en) * 1976-05-24 1978-05-23 Transco Energy Company Method for increasing the recovery of oil and gas from a water invaded geo-pressured water drive oil reservoir
US4116276A (en) * 1976-05-24 1978-09-26 Transco Energy Company Method for increasing the recovery of natural gas from a geo-pressured aquifer
US4161047A (en) * 1977-10-19 1979-07-17 Riley Edwin A Process for recovery of hydrocarbons
US4509596A (en) * 1984-01-23 1985-04-09 Atlantic Richfield Company Enhanced oil recovery
US4676314A (en) * 1985-12-06 1987-06-30 Resurrection Oil Corporation Method of recovering oil
US4683948A (en) * 1986-05-23 1987-08-04 Atlantic Richfield Company Enhanced oil recovery process employing carbon dioxide
US4953619A (en) * 1986-10-10 1990-09-04 University Of Waterloo Enhanced oil recovery process
US4819724A (en) * 1987-09-03 1989-04-11 Texaco Inc. Modified push/pull flood process for hydrocarbon recovery
US5025863A (en) * 1990-06-11 1991-06-25 Marathon Oil Company Enhanced liquid hydrocarbon recovery process
WO2017189864A1 (en) * 2016-04-27 2017-11-02 Highlands Natural Resources, Plc Method of forming a gas phase in water saturated hydrocarbon reservoirs

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