US3079079A - Process and control apparatus for improving operating efficiency - Google Patents

Process and control apparatus for improving operating efficiency Download PDF

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US3079079A
US3079079A US736880A US73688058A US3079079A US 3079079 A US3079079 A US 3079079A US 736880 A US736880 A US 736880A US 73688058 A US73688058 A US 73688058A US 3079079 A US3079079 A US 3079079A
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flow
equation
catalyst
producing
reactor
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US736880A
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Jr Montgomery Phister
Charles G Laspe
Thomas M Stout
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Northrop Grumman Space and Mission Systems Corp
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Thompson Ramo Wooldridge Inc
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006Controlling or regulating processes
    • B01J19/0033Optimalisation processes, i.e. processes with adaptive control systems
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006Controlling or regulating processes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S203/00Distillation: processes, separatory
    • Y10S203/19Sidestream

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  • This invention relates to process control methods and apparatus for improving process operating efiiciency, and more particularly, to methods for obtaining the best balance between the amount of products made, the quality of these products, and the cost of operating various parts of the process for making the products.
  • control rules are very simple ones, usually arranging that the adjustment be some definite algebraic or other function of the measuremenis.
  • the control rules are somewhat arbitrary and rely to a great extent on the judgment and experience of the individual. In some cases they rely on calculations made by the individual, or on calculations made elsewhere and interpreted or employed by the human.
  • the present invention obviates the above disadvanfages of the prior art by providing a control technique which may be operated at high speed to solve complex equations relating to quality of materials, cost of prrducts, and amount of material that is processed (sometimes referred to as throughput).
  • the invention contemplates the maximization of profit by controlling certain process variables to compensate for changes measured in other variables.
  • the process is d:scribed in terms of three basic types of equations, which comprise what is sometimes called a ma'hematical model of the process.
  • the first equation is referred to as the objective equation and defines the profit obtained from operating the process in terms of variables related to the process, such as flow rate of materials. and rate of use of fuel, value of materials, a conversion function which defines the amount of raw material converted to a final product.
  • the second set of equations represents constraints in the operation of the process, such as flow rates (limited for instance by compressor or pump capacities) limitations on acceptable product quality, or market limitations on the desired quantity of the various products.
  • the third set of equations defines the relationships between the process variable, such as the various interrelationships between conversion, yields, flow rate, efficiency, temperature, pressure, and chemical and physical properties.
  • Another object of the invention is to obtain maximum operating efiiciency in a process considering such factors as the amount of a product to be produced, the quality of the product, and the cost of operating various parts of the process.
  • a further object of the invention is to provide a method for process control which is adapted for high speed correction based on a mathematical model of the process.
  • Yet another object of the invention is to provide a method and appropriate apparatus for maximizing the profit or operating return which may be obtained in running a process.
  • Still another object of the invention is to provide a process control system which is adapted for rapidly adjusting the method of operation of a process on the basis of measurements made by transducing means employed in the system.
  • a specific object of the invention is to provide a method for operating a chemical process wherein the flow rate of materials must be regulated at various points in order to obtain a maximum profit.
  • Another specific object of the invention is to.provide an automatic correlation of the conversion formula employed in controlling a chemical process in order to insure that the constants in the conversion equation accurately represent the conversion as it occurs in opera tion of the process.
  • FIG. 1 is a block diagram of a general form of process control system provided by the invention
  • FIG. 2 illustrates a specific form of the system provided by the invention for maximizing profit in a chemical process
  • FIG. 3 illustrates a typical general method of operation which may be employed in the use of the invention
  • FIG. 4 is a chart indicating the composition of the process material at points 191 and 102 in the embodiment of FIG. 2;
  • FIGS. 5a and 5b are graphs showing various curves of conversion versus flow rate for the embodiment of FIG. 2;
  • FIGS. 6a a d 6b are ots of lines of constant profit tor the embodiment of FIG. 2.
  • a process I00 receives certain materials and energy and produces certain finished products, waste material, and energy.
  • the process is controled by a computer controller 2% which receives certain input information a from the process and certain control signals B from an operator 300 and produces control signals for controlling the process and output signals or to provide the operator with certain information about the process.
  • Signals w are applied to output devices 400.
  • Computer-controller 200 is arranged to compute the control relationships in accordance with the mathematical model of the sysem.
  • the maximum profit will be obtained by considering the various costs and values of materialsand catalysts and the like over a typical operating period rather than an instant of time. Thereason for this is that certain costs will vary as the particular material is used. For example, it may be possible to maximize profit at a present instant byutilfzing a catalyst at a very high rate, but this'present use may increase the average cost of operating the system due to the low efficiency rate of output when the catalyst has been somewhat depleted. Thus, in this case it is preferred to interpret the profit equation as defining an operation over a pre determined interval of time during which some average values and costs may be defined.
  • the second set of equations defines certain constraints for the system which will be illustrated in particular with respect to a chemical process below. In general, these constraints will specify certain boundaries for such variables as the flow rates in the system or the amounts of material which may be supplied.
  • the third set of equations define-the interrelationships between variables, a typical equation for conversion being considered below.
  • process 100 is a chemical process utilizing, among other equipment, a reactor 110, a heat exchanger 120, a catalystjseparator 139 and a fractionat- 'material that does not'enter into the reaction, enters at'point 101 witha flow rate f and proceeds through heat exchanger 128 which increases its temperature.
  • the mixture then enters reactor 110 where a catalyst is added at flow rate f
  • the reaction is exothermic.
  • the hot product leaves reactor 110, passes through heat exchanger 120 where it is cooled and the reactor'feed' is heated, and enters catalyst separator 130.
  • the rmaining mater'ial consisting of inert substance, the product, and thatpart of thereactant not converted to product, passes point102 and enters fractionating tower 140.
  • the product is separated from the other components.
  • the product leaves the process at rate f
  • Associated with fractionating tower 140 is a condenser 141, a reboiler 142. and a reflux tank 143; the function of these components'is to'separate the output of tower 140 into products 1 and 2 which typically coud be hydrocarbons with'dilierent boiling points.
  • Product 1 is produced at' an output flow rate of-f and product 2 is produced at an output flow rate of f 3%,.
  • Transducer 2i provides a signal for a flow-recorder controller 219 which also receives a control signal of the 7 type from com-- puter 290 and. produces a signal for actuating valve 217' to regulate the amount of flow f
  • Computer 200 also receives other it signals indicating the flow, as for example, the signal derived from transducer 221 associated with flow-recorder 223 measuring the flow h to fractionat-- ing tower 140.
  • the output flow rate f is measured by transducer 225 and a corresponding'signal is produced by flow recorder 227 and sent to computer 299.
  • the graphs of FIG. 4 indicate the relative amounts of the various components at the two process points 101 and 102.
  • the process boundaries will be taken to be those indicated in FIG. 2.
  • a study of the relationship between this process and the rest of the operation'of the plant discloses the following boundary conditions: (1) Incoming material is available at instantaneous'flow rate f and contains x percent of reactant. Both of these quantities are independent variables that may vary over wide ranges. Often there is more of this incoming material than the reactor can use, and whatever is not used will be employed elsewhere in the plant. (2) Product-flow rate 7' can vary over a'wide range without effect on the rest of the plant.
  • the independent variables are theincoming flow rate
  • the only product variable is x;,, the concentration of the desirable product inthe output of the catalyst separator.
  • the intermediate variables are hand. f the flow rates of raw material 'and catalyst into the reactor, respectivley.
  • Other important intermediate variables arelreactortemperature and pressure, catalyst-separator level, and fractionatingtower operating conditions.
  • the catalyst separator provides the bottleneck on unit capacity and determines the upper limits on the intermediate variables f and f
  • the total flow into the separator amy not exceed f and the catalyst flow rate may not exceed f Or fl+f2 fmax fa -f2 max
  • These equations comprise the constraint equations for this process.
  • reactor temperature and pressure are controlled at their desired maximums by conventional recorders and controllers.
  • the separation of feedstock flow into reactor feed and by-pass feed, and the ratio of catalyst-feed rate to reactor-teed rate is controlled by an operator, who adjusts the two ilow rates compatible with process limitations and with the established boundary conditions.
  • Equation 4 constitutes an example of the third type of equation for this process indicating the interrelation oi variables.
  • This equation for c is plotted in FIG. 5, wherein the maximum values for catalyst-flow rate and for combined catalystand feed-flow rates are also indi cated.
  • Equation 4 does not exactly describe the effect of all variables on conversion. In particular, there is reason to believe that unpredictable and unidentifiable factors tend to shift the conversion curves from one day to another and even from one eight-hour period to another. A typical set of operating points taken on two different days is shown in FIG.
  • Equation 3 the objective of any control system is to maximize the operating pro-fit function P of Equation 3; in Equation 3 the initial percentage of reactant in the feed (x is an independent variable beyond control; the conversion c is a function of f and f whose general form is indicated by Equation 4-; the two flow rates f and f are the intermediate variables subject to control; the physical characteristics of the process equipment set upper limits on these flow rates, Equation 2.
  • the control problem is now specified in enough detail so that the designer can see how it might operate.
  • the data must be used to evaluate constants k k and k of Equation 4 and provide a good fit of the curves to that data. With these constants determine-d, there are particular values of f and f which maximize the profit of Equation 3 for every value of reactant concentration x; (see Equations 5 and 6 below).
  • the control system must therefore measure x must calculate the appropriate values of f and f and must adjust the corresponding flow-control valves in the process.
  • the control system will, however, be complicated by several other afctors. First, it may be that there is not enough feed available to obtain maximum theoretical profit from the operation. Second, the optimum values of f and f may be such that the capacity of process equipment is exceeded. Finally, the control system must continually make sure that the functional relationship it uses to relate conversion with catalyst and feed flow rates, Equation 4, accurately represents plant conditions at the time.
  • Equation 3 To control the process, a computer must first find the maximum value for P of Equation 3, subject to the restriction that conversion 0 is a function of f and f as shown in Equation 4. Substituting Equation 4 in Equation 3, then taking the partial derivative of P with respect to f and setting it equal to zero,
  • Equation 5 and 6 The reactant feed concentration x; of Equations 5 and 6 is measured every time new values for f and f are to be determined. All of the other constants in Equations 5 and 6, and Equation 4 (which relates conversion to the unknown quantities) are known. Therefore, the computer must solve Equations 5 and 6 simultaneously for the flow rates f and f after substituting c from Equation 4. The result will be the optimal values for flow, which will be called h and fi The computer must now determine whether the optimal flow rates are obtainable in practice, and must determine what flow rates should actually be used if they are not. The effect of process limitations is most easily understood with reference to FIG. 6, wherein contours representing equal values of P in the f f plane are plotted. Because of the nature of Equations 3 and 4, there is only one point of maximum profit, represented by the coordinates (f Equipment limitations are represented by the straight lines,
  • Equation 3 the realizable maximum profit will always lie on one of the lines, Equations 7, 8, or 9, if one or more of Equations 2 and 10 are not satisfied.
  • the following procedure may be recognized for finding the proper operating point when the optimum operating point cannot be reached.
  • the process-flow rates should be set at the f and f coordinates corresponding to the largest P.
  • the digital control system When the digital control system has calculated the appropriate best values for f and f and has taken action to assure that the chosen flow rates are adjusted to the process, it must modify the constants of Equation 4 so as to make sure that the resulting curve is as accurate a prediction as possible of the relationships between conversion, 1; and f The digital control system does this by taking a measurement of conversion periodically, and relating the measured value to previously set values for f and f taking into account whatever delay exists in the process between the time a flow-rate adjustment is made at the reactor input, and the time the resulting'change in conversion is measured. The digital-control system will be required to keep a record of the average of such measurements over the past hours.
  • Equation 11 which is designed to take into account slow and unpredictable changes in the conversion-flow relationship, will be most effective only if fairly wide variations in f f and 0 occur over a period of ten hours.
  • One way to avoid this cluster is to require the control system to perturb the process occasionally, if process conditions do not themselves cause a perturbation.
  • the variables f and f may be set at arbitrary points some distance from their ideal values long enough for the conversion corresponding to those flow rates to be measured. A probably better way is to let the curve-fitting operation depend not only on the 20 most recent process points, but also on previous values of k k and k.
  • the control system Whose rough characteristics are now emerging clearly meets process objectives and no limitations on equipment capacity are exceeded. It now must be explained how the necessary process variables are to be measured and controlled and how the dynamics of the process are to be taken into account.
  • the principal process variables which must be measured are f,,, the available feed rate; x the percentage of the reactant in the feed; and conversion, which may be computed if x and x are known.
  • f the available feed rate
  • x the percentage of the reactant in the feed
  • conversion which may be computed if x and x are known.
  • Product concentration x can be found by measuring the flow rate of material into the fractionating tower and the flow rate at the tower bottom, and dividing the second by the first. This rough value for .15 may be refined somewhat by noting that the fractionating tower is normally operated so that some fixed percentage of the product appears at the tower top, regardless of tower-feed composition. If, for example, this particular tower is operated so that 5 percent of the distillate-flow rate is product, while approximately percent of the residue is product, then x can be found as follows:
  • the principal control system components required are a new instrument for the measurement of x;, the reactant composition, and the digital control computer itself.
  • the system designers study of the required computer proin must be extensive enough to allow him to specify computer precision, speed and memory capacity required.
  • the number and type of input and output transducers and lines must also be specified.
  • FIG. 3 a diagram is shown indicating various computing operations which are performed in order to control a process in accordance with the metuod of the invention.
  • the control process is continuous and may be entered at any point, there being various tests to determine Whether the time for any particular operation is appropriate.
  • this determination results in an answer of either yes or no.
  • the system then proceeds in step 302. to read in data indicated by dotted lines to be either at data of the type described above from the process or 5 data representing operators instructions, etc.
  • step 3432 After th data read-in step 3432, this data is then checked in step by comparing the data with a previous trend and/ or with known limitations.
  • step 3% the data is corrected smoothed and weighted averages may be obtained to correct for flows, temperature, pressure, and density.
  • step 3% the desired control function is com puted and variables may be generated. After this, a cletermii dion is made as to Whether or not the control settings are possible, in step 3%; if so, the various controllers are set in step If not, a warning is given the operator in step 368.
  • step Iii-3 may be employed to store miscellaneous constants for the neat calculation and then a check is made to see if it is the proper time to check the computer in step 3M.
  • a computer test program is performed in step 315 which, if giving an answer of yes, as to proper operation in step 316, proceeds no further, but if the answer is no a warning signal is generated in step to indicate to the operator the particular error.
  • a time determination is in step 318 as to the appropriateness of a check on the transducers. This is referred to as an alarm check.
  • step 31.9 is employed to check the various transducers. if the check is indicated to be negative an alarm is given in step 329, otherwise system proceeds to return to the first step in control calculation, namely, step 391, for another cycle.
  • the computing program illustrated in MG. 3 is intended only as a general guide for developing a particular control solution. A specific computing program will now be developed for the control problem of FIG. 2.
  • the example ere Will assume that trial values for h are substituted into Equation 5 to solve for a trial f which is then substituted into Equation 6 with the corresponding trial value for f Before beginning the computing opera tion the expected range of functions e are entered into the computer memory so that the multiplication of k by the trial f can be translated into the exponential value by reading out the corresponding function from a ernory location specified by the exponent.
  • Equation 6 if the trial values of f and f substituted into Equation 6 provide a solution the first phase of the computing is completed, otherwise a new trial value for h is entered into Equation 5 and the resulting trial f and f are then entered into Equation 6 for checkin This process is continued until the optimum values for J; and f are found.
  • Trial f values may be obtained by programming the computer adder to add one in the smallest unit denomination to the previous f
  • the computer is programmed to perform these comparisons and to set 11 and f at the optimum values if all constraints are satisfied. If any constraint is not complied with three possible computing routines are possible as outlined above. if f f the best setting for f is found by substituting f f for h in Equation 6 and solving for f This may be performed as a new computa tion or may be arranged to use the previous computation for trial f and f;,,, the results of which may be stored in the computer memory in addresses specified by f or or both.
  • the final computing phase involves the redetermination of constants k k and k from Equation 11. This is accomplished by performing successive divisions of measured x /x or by computing x according to Equation 12 and then dividing by measured x The values of f and f are set during this phase to provide a good correlation between c and these values.
  • the curve fitting computation may be performed on the basis of the solution of three simultaneous equations corresponding to the three derivative functions of Equation 11 as follows:
  • Equation 11a 'for example, appears as follows when expanded:
  • the other derivatives may be derived in a similar man net.
  • the actual computation sequence may follow lines discussed above by employing trial values until all equations check.
  • the present invention provides a novel method for controlling a process to maximize the profit which may be obtained from the products produced thereby.
  • the particular type of computing apparatus which may be employed to carry out the process of the invention has not been specified since many of the standard digital computers now available are suitable. It may be desirable, moreover, to provide a special-purpose digital computer for solving the equations of a particular program or to develop specialized analogue computing circuits. Such techniques are contemplated by the present invention as defined by the claims.
  • a system for producing a product as a composition of raw material including at least one catalyst, said sys tern comprising: a first transducer for sensing the how of raw material and producing a signal f indicating the total feed available for producing said product; an analyzer for detecting the percentage of active ingredients in said fiow of raw material andfor producing a signal representative thereof; a reactor for receiving said raw materials and said catalyst to perform a first chemical operation; a second transducer introduced into the raw material flow for said reactor for producing a signal f indicating the flow of material through said reactor; at third transducer for sensing the how of said catalyst into said reactor and for producing a corresponding flow signal f;; a control computer; means for producing signals representing the value and costs of raw material and products per unit llow; means for coupling the signals produced by said transducers and analyzer, and said signals representing value and cos-ts to said compu er, said computer including means operable to produce control signals which specify the proper setting for the flow of material and catalyst to yield a
  • first transducing means for generating a first signal indicating the flow rate of available raw material
  • second analyzing means for generating a second signal indicating the percentage of active ingredients in said raw material
  • third means for generating a third signal indicating the value and costs of said product and raw material
  • digital control means programmed to determine on the basis of said first, second, and third signals, a set point for said variable condition effective to maximize saidprofit; fourth means for generating a fourth signal indicating said set point; and means responsive to said fourth signal for selectively varying said variable condition to establish said set point.
  • said variable condition comprises the fiow rate of catalyst to be mixed with said raw material.

Description

Feb. 26, 1963 PROCESS AND.
Filed May 21, 1958 OPERATING EFFICIENCY 3 Sheets-Sheet 2 503 DATA FR 30,
OM CHECK DATA pRocEss i 502 %ORMPADRE wrm v 3 TIME, FOR CONTROL EN A o R WITH g f i READ N YES CALCULA'HON LIM\TAT\ONS DATA A DATA FROM I No 308) OPERATOR WARN DENSITY {PRESSURE OPERATOR T 304 305 coRREcTq$MooTu COMPLETE CONTROL Q DATA (as sETrMqs a, PRmT- A WEIGHT? AVERAGE ou'r VAR\ABLES 51TH NC\$ CORRECT LOWSOR TO MAKEVROFFI" TEMP. PussuRz MAX\MuM DENswy 4 YES 50.7 TEMPERATURE CHANGE CON sTAm-s' SET I 'Z\ 3| CONTROLLERS coMPLmFuNcTwNJ COLLECT PER'HNENT I WWH ENTER \m-o DATA Pom-rs OVER VAR\ABLE LAST PzmoD o RELATIONSH P5 OPERAFHON yES 3o 9 l A A l T\N\E R f y 3Q, 3&3, coRRELATmN CHECK L COMDUTE CONSTANT; STOREMSCELLANEOUS NO FOR BEST T CQNSTANTS FOR MATo-uNe NEXT CALCULAT\ONS T\N\E FOR 3M6 35, COMPUTER CHECK ANSWER COMPUTER YES No CORRECT TEST PROGRAM 2M8,
No [YES T\ MF FOR A LARM CHECK v 3 \7, WAR No YES N OPERATOR 3 2o CHECK FOR \NCDNSETENT 0R \NCORRECF INSTRUMENT VES RE D\M ,QRFR ALARM PRO$$ uPsETs =-R OPERATOR \N$TAB\ unas NO v v POSSIBLE SEVERAL ROqRAMS TO BE USED BY MONTGOMERY P/l/STER, JR.
PRocEss CONTROL OPERATOR 7N VE N TORS Feb. 26, 1963 P'HlsTER, JR; ETAL 3,079,079
M. PROCESS AND CONTROL APPARATUS FOR IMPROVING OPERATING EFFICIENCY Filed May 21, 1958 3 Sheets-Sheet 3 FuzsT DAY o SECOND D Y 0 0 g g 5 9 a i\- u; a N z 6 0 8 O w Q FLOW RATE)? FLow RATE, H
Mo/vr oME/zy Ply/572R, .//2 CHARLES G. LASPE. 7770/1/45 M 37007 INVENTORS United States Patent 3,079,979 PROCESS AND CONTRQL APPARATUS; FGR IMPRDVING UPERATING EFFiIClENCY Montgomery Phister, .irn, Palos Verdes Estates, Qharles G. Lnspe, Rolling Hills, and Thomas M. Stout, Redondo Beach, Calirl; said Phister and Laspe assignors to Thompson Rama Wooldrldge inc, Cleveland, Ohio, a
corporation of ()hio Filed May 21, I958, Ser. No. 736,88tl Claims. (iii. 235-151) This invention relates to process control methods and apparatus for improving process operating efiiciency, and more particularly, to methods for obtaining the best balance between the amount of products made, the quality of these products, and the cost of operating various parts of the process for making the products.
In a typical prior art control system, some combination of operators and control and measurement equipment is used to maintain proper process conditions by reading process instruments and making adjuslments. The magnitude and direction of the adjustments are determined sometimes by equipment and sometimes by human judgment. In the case of adjustments made by equipment, the control rules are very simple ones, usually arranging that the adjustment be some definite algebraic or other function of the measuremenis. In the case of adjustments made by humans, the control rules are somewhat arbitrary and rely to a great extent on the judgment and experience of the individual. In some cases they rely on calculations made by the individual, or on calculations made elsewhere and interpreted or employed by the human. Because of the complexity of most modern processes, because of the frequency with which changes occur which should result in adjustments in the process, and because of the comparative unsophistication of the human-machine control system described above, processes are normally not operated in the best way. The result is that upsets occur, equipment is misused, production is lost, operating costs are hIgh, or some combination of these and other bad effects occurs.
The present invention obviates the above disadvanfages of the prior art by providing a control technique which may be operated at high speed to solve complex equations relating to quality of materials, cost of prrducts, and amount of material that is processed (sometimes referred to as throughput). In particular terms, the invention contemplates the maximization of profit by controlling certain process variables to compensate for changes measured in other variables.
To effect the desired maximization of profit, the process is d:scribed in terms of three basic types of equations, which comprise what is sometimes called a ma'hematical model of the process. The first equation is referred to as the objective equation and defines the profit obtained from operating the process in terms of variables related to the process, such as flow rate of materials. and rate of use of fuel, value of materials, a conversion function which defines the amount of raw material converted to a final product. The second set of equations represents constraints in the operation of the process, such as flow rates (limited for instance by compressor or pump capacities) limitations on acceptable product quality, or market limitations on the desired quantity of the various products. The third set of equations defines the relationships between the process variable, such as the various interrelationships between conversion, yields, flow rate, efficiency, temperature, pressure, and chemical and physical properties.
Accordingly, it is an object of the present invention to provide a process control system for controlling adjustments in the operation of a process so that it is operated in the most economical fashion.
ice
Another object of the invention is to obtain maximum operating efiiciency in a process considering such factors as the amount of a product to be produced, the quality of the product, and the cost of operating various parts of the process.
A further object of the invention is to provide a method for process control which is adapted for high speed correction based on a mathematical model of the process.
Yet another object of the invention is to provide a method and appropriate apparatus for maximizing the profit or operating return which may be obtained in running a process.
Still another object of the invention is to provide a process control system which is adapted for rapidly adjusting the method of operation of a process on the basis of measurements made by transducing means employed in the system. i
A specific object of the invention is to provide a method for operating a chemical process wherein the flow rate of materials must be regulated at various points in order to obtain a maximum profit.
Another specific object of the invention is to.provide an automatic correlation of the conversion formula employed in controlling a chemical process in order to insure that the constants in the conversion equation accurately represent the conversion as it occurs in opera tion of the process.
The novel features which are believed to be characteristic of the invention, both as to its organization and method of operation, together with further objects and advantages thereof, will be better understood from the following description considered in connection with the accompanying drawings. It is to be expressly understood, however, that the drawings are for the purpose of illustration and description only, and are not intended as a definition of the limits of the invention.
FIG. 1 is a block diagram of a general form of process control system provided by the invention;
FIG. 2 illustrates a specific form of the system provided by the invention for maximizing profit in a chemical process;
FIG. 3 illustrates a typical general method of operation which may be employed in the use of the invention;
FIG. 4 is a chart indicating the composition of the process material at points 191 and 102 in the embodiment of FIG. 2;
FIGS. 5a and 5b are graphs showing various curves of conversion versus flow rate for the embodiment of FIG. 2; and
FIGS. 6a a d 6b are ots of lines of constant profit tor the embodiment of FIG. 2.
Reference is now made to FIG. 1 wherein it will be noted that a process I00 receives certain materials and energy and produces certain finished products, waste material, and energy. The process is controled by a computer controller 2% which receives certain input information a from the process and certain control signals B from an operator 300 and produces control signals for controlling the process and output signals or to provide the operator with certain information about the process. Signals w are applied to output devices 400.
Computer-controller 200 is arranged to compute the control relationships in accordance with the mathematical model of the sysem. The first equation defines the profit P in terms of the following equation where V =value of the ith product C170 =cost of operating the process which is proportional to the flow rate of the ith product fp fl f =flow rate of the ith product, flow rate of the jth product, flow rate of the jth raw material Cr =cost of the jth raw material Cro =operating cost proportional to the flow rate of the jth rawmaterial Coo =othervariable cost of operating the process It will be noted that time is not included as a variable in the above profit function'exce'pt as it is inherent in the flow rates fp and f'r It should be understood, therefore, that thetpro-fit equation may be construed to represent an instant of time, in which case pro-fit is maximized for that instant only, or it may be construed to represent a profit function over a periodof time. In theusual applicationjof the invention, the maximum profit will be obtained by considering the various costs and values of materialsand catalysts and the like over a typical operating period rather than an instant of time. Thereason for this is that certain costs will vary as the particular material is used. For example, it may be possible to maximize profit at a present instant byutilfzing a catalyst at a very high rate, but this'present use may increase the average cost of operating the system due to the low efficiency rate of output when the catalyst has been somewhat depleted. Thus, in this case it is preferred to interpret the profit equation as defining an operation over a pre determined interval of time during which some average values and costs may be defined.
The second set of equations defines certain constraints for the system which will be illustrated in particular with respect to a chemical process below. In general, these constraints will specify certain boundaries for such variables as the flow rates in the system or the amounts of material which may be supplied. The third set of equations define-the interrelationships between variables, a typical equation for conversion being considered below.
The general technique of the invention can best be described with respect to a specific example indicated in PEG. 2. In this case process 100 is a chemical process utilizing, among other equipment, a reactor 110, a heat exchanger 120, a catalystjseparator 139 and a fractionat- 'material that does not'enter into the reaction, enters at'point 101 witha flow rate f and proceeds through heat exchanger 128 which increases its temperature. The mixture then enters reactor 110 where a catalyst is added at flow rate f The reaction is exothermic. The hot product leaves reactor 110, passes through heat exchanger 120 where it is cooled and the reactor'feed' is heated, and enters catalyst separator 130. After removal of the catalyst, the rmaining mater'ial, consisting of inert substance, the product, and thatpart of thereactant not converted to product, passes point102 and enters fractionating tower 140. Here the product is separated from the other components. The product leaves the process at rate f Associated with fractionating tower 140 is a condenser 141, a reboiler 142. and a reflux tank 143; the function of these components'is to'separate the output of tower 140 into products 1 and 2 which typically coud be hydrocarbons with'dilierent boiling points. Product 1 is produced at' an output flow rate of-f and product 2 is produced at an output flow rate of f 3%,.
flow rate f of the input material. This signal is applied to computer 280.
Examples of suitable types of analyzers which may be employed for the purpose of device 210 are found on pages 364 and 365 of the Chemical Engineering Catalogue of 1958 published by the Reinhold Publishing Co., 431 Park Ave., N.Y. Suitable flow-recorder controllers, recorders and valves are shown on pages 1506 A-D of this catalogue. The various transducers are standard equipment in the present practice of the art and therefore are not considered here as modifications specified by the instant invention.
After passing beyond transducer 211, the flow divides near point nu with flow rate f,,-j corresponding to unused feed. I
Flow at rate h then proceeds beyond transducer 215 and valve 217 to heat exchanger 120. Transducer 2i provides a signal for a flow-recorder controller 219 which also receives a control signal of the 7 type from com-- puter 290 and. produces a signal for actuating valve 217' to regulate the amount of flow f Computer 200 also receives other it signals indicating the flow, as for example, the signal derived from transducer 221 associated with flow-recorder 223 measuring the flow h to fractionat-- ing tower 140. The output flow rate f is measured by transducer 225 and a corresponding'signal is produced by flow recorder 227 and sent to computer 299.
The graphs of FIG. 4 indicate the relative amounts of the various components at the two process points 101 and 102. The process boundaries will be taken to be those indicated in FIG. 2. A study of the relationship between this process and the rest of the operation'of the plant discloses the following boundary conditions: (1) Incoming material is available at instantaneous'flow rate f and contains x percent of reactant. Both of these quantities are independent variables that may vary over wide ranges. Often there is more of this incoming material than the reactor can use, and whatever is not used will be employed elsewhere in the plant. (2) Product-flow rate 7' can vary over a'wide range without effect on the rest of the plant.
The objectiveis to'obtain maximum operating profit from the operation of the unit. It will be assumed that maintenance costs are constant, unaffected by operation of the process. For this reason and because in general the operation of the unit from one minute to the next does "not afiect its operation in the future, the act of maximiz ing total operating profit is equivalent to'maximizing the instantaneous-profit derived frorn'the unit. An expres- 'sic-n for the profit objective follows:
f =fiow rate of incoming material f =fiow rate of material at points 101 and 102 f1x =fiow rate of product'at point 192 j V =value of desired product at point 102 V =value of that material at point 102 whichv is not product V =value"of rawmaterial, if notproces'sedinthis unit ,f =flow rate of catalyst V loss in value of catalyst in process C=c'onstant operating costs The effect of heat losses on cost is 'neglible. The cata lyst, on the other hand, is very expensive and is one of 1 the major costs of operation.
The independent variables are theincoming flow rate The only product variable is x;,, the concentration of the desirable product inthe output of the catalyst separator. The intermediate variables are hand. f the flow rates of raw material 'and catalyst into the reactor, respectivley. Other important intermediate variables arelreactortemperature and pressure, catalyst-separator level, and fractionatingtower operating conditions. In the existing installation, the catalyst separator provides the bottleneck on unit capacity and determines the upper limits on the intermediate variables f and f The total flow into the separator amy not exceed f and the catalyst flow rate may not exceed f Or fl+f2 fmax fa -f2 max These equations comprise the constraint equations for this process.
The operation of the reactor is generally specified by quoting a conversion for the reactor, defined as the ratio of the amount of desired product at point 102 to the amount of that raw material at point 191 which theoretically could have been converted entirely to desired product. If this is expressed as c=x /x x can be replaced in Equation 1 by x obtaining Conversion is known to be a function of reactor temperature and pressure, catalyst flow, and feed flow. The temperature and pressure variations are such that ideal operation is clearly at the maximum safe temperature and pressure ratings of the process equipment. Conversion is also known to increase with catalyst-flow rate.
In the system illustrate-d, reactor temperature and pressure are controlled at their desired maximums by conventional recorders and controllers. The separation of feedstock flow into reactor feed and by-pass feed, and the ratio of catalyst-feed rate to reactor-teed rate is controlled by an operator, who adjusts the two ilow rates compatible with process limitations and with the established boundary conditions.
The dynamics of the process (the variation in output parameters as a function of time with variations on the independent and operating variables) are largely unknown. Experience indicates that a change in flow at the input to the reactor reaches its final value at the fractionating-tower feed about 15 minutes later, and at the fractionating-tower output about 45 min. later.
A theoretical analysis of the kinetics of the reaction and of the relationship between all process variables proves impossible. However, a careful study of the available operating data on conversion and on the relationship between feed-flow rate, catalyst-flow rate, and conversion makes it possible to establish certain correlations between these variables and to write a mathematical expression relating them that provides the best possible iit to available operating data. in the equation below expressing this mathematical relationship, constants k k and are chosen to make this curve best fit on typical data.
Equation 4 constitutes an example of the third type of equation for this process indicating the interrelation oi variables. This equation for c is plotted in FIG. 5, wherein the maximum values for catalyst-flow rate and for combined catalystand feed-flow rates are also indi cated.
Unfortunately, Equation 4 does not exactly describe the effect of all variables on conversion. In particular, there is reason to believe that unpredictable and unidentifiable factors tend to shift the conversion curves from one day to another and even from one eight-hour period to another. A typical set of operating points taken on two different days is shown in FIG. 5b, and the curve of Equation 4 is fitted to each set of points by suitably choosing parameters k k and k Reviewing his collection of data at this point, the systern designer can make the following statements: the objective of any control system is to maximize the operating pro-fit function P of Equation 3; in Equation 3 the initial percentage of reactant in the feed (x is an independent variable beyond control; the conversion c is a function of f and f whose general form is indicated by Equation 4-; the two flow rates f and f are the intermediate variables subject to control; the physical characteristics of the process equipment set upper limits on these flow rates, Equation 2.
The control problem is now specified in enough detail so that the designer can see how it might operate. The data must be used to evaluate constants k k and k of Equation 4 and provide a good fit of the curves to that data. With these constants determine-d, there are particular values of f and f which maximize the profit of Equation 3 for every value of reactant concentration x; (see Equations 5 and 6 below). In its simplest form, the control system must therefore measure x must calculate the appropriate values of f and f and must adjust the corresponding flow-control valves in the process.
The control system will, however, be complicated by several other afctors. First, it may be that there is not enough feed available to obtain maximum theoretical profit from the operation. Second, the optimum values of f and f may be such that the capacity of process equipment is exceeded. Finally, the control system must continually make sure that the functional relationship it uses to relate conversion with catalyst and feed flow rates, Equation 4, accurately represents plant conditions at the time.
To control the process, a computer must first find the maximum value for P of Equation 3, subject to the restriction that conversion 0 is a function of f and f as shown in Equation 4. Substituting Equation 4 in Equation 3, then taking the partial derivative of P with respect to f and setting it equal to zero,
V.V 1-k i lfl) m1(V3 V1) Similary, setting the partial derivative of E with respect to f equal to zero,
The reactant feed concentration x; of Equations 5 and 6 is measured every time new values for f and f are to be determined. All of the other constants in Equations 5 and 6, and Equation 4 (which relates conversion to the unknown quantities) are known. Therefore, the computer must solve Equations 5 and 6 simultaneously for the flow rates f and f after substituting c from Equation 4. The result will be the optimal values for flow, which will be called h and fi The computer must now determine whether the optimal flow rates are obtainable in practice, and must determine what flow rates should actually be used if they are not. The effect of process limitations is most easily understood with reference to FIG. 6, wherein contours representing equal values of P in the f f plane are plotted. Because of the nature of Equations 3 and 4, there is only one point of maximum profit, represented by the coordinates (f Equipment limitations are represented by the straight lines,
f 2 =f 2 max and the feed-availability limitation is represented by the 7 single straight line fi=fa one of the three'inequalities of Equations 2 and 10, namely:
is not satisfied, the optimum flow rates cannot be used. Note that the lines defined by Equations 7 and 8 are fixed, but that the line defined by Equation 9 shifts from time to time as feed availability varies. Furthermore, the coordinates of the optimum point will also shift as x and conversion equation constants k k and k vary.
Some procedure must be specified for enabling the computer-control system to find the best settings for f; and
f when one or more of the inequalities of Equations 2 and 10 are not satisfied, as in FIG. 6b. The procedure to be followed may be based on the fact that, for the simple profit function of Equation 3, the realizable maximum profit will always lie on one of the lines, Equations 7, 8, or 9, if one or more of Equations 2 and 10 are not satisfied. With this in mind, the following procedure may be recognized for finding the proper operating point when the optimum operating point cannot be reached.
( If fa fmax Find the maximum value of P from Equation 3 along the line f1+f2 fmaxwith fZ fZ max- Find the maximum value of? along the line f =f max 'Compare these two values of P. The process flow rates should be set at the h and f coordinates corresponding to the larger P.
( If index f2 max fa fmax Find the maximum value of P along the line f with f2 fmax fa- Find the maximum value of P along the line f +f =f with fmax fa f2 f2-max- Find the maximum value of P along the line f =f max with f 1 fmax f 2 max- Compare these three values of P. The process-flow rates should be set at the f and f coordinates corresponding to the largest P.
Find the maximum value of P along the line f =f with f2 f2 max Find the maximum value of P along the line f =f max with -0f Compare these two values of P. The process flow rates should be set at the f and f coordinates corresponding to the larger P.
When the digital control system has calculated the appropriate best values for f and f and has taken action to assure that the chosen flow rates are adjusted to the process, it must modify the constants of Equation 4 so as to make sure that the resulting curve is as accurate a prediction as possible of the relationships between conversion, 1; and f The digital control system does this by taking a measurement of conversion periodically, and relating the measured value to previously set values for f and f taking into account whatever delay exists in the process between the time a flow-rate adjustment is made at the reactor input, and the time the resulting'change in conversion is measured. The digital-control system will be required to keep a record of the average of such measurements over the past hours. The computer thus has a list of 20 sets of three numbers each (f f and c) and it must find k k and k such that these 20 points provide a best fit for the resulting curve. If the 20 points are labeled 0 i f (i=1, 2, 3, 20) then k k and k may be evaluated by minimizing the following function with respect to the three variables.
It will be observed that the curve-fitting operation of Equation 11, which is designed to take into account slow and unpredictable changes in the conversion-flow relationship, will be most effective only if fairly wide variations in f f and 0 occur over a period of ten hours. Putting it another way, it is meaningless to fit the curve of Equation 4 to a set of 20 points all clustered together in a small area of FIGURE 5b. Such a cluster would occur if, over a period of 10 hours or more, there was little or no variations in x and f did not get lower than f One way to avoid this cluster is to require the control system to perturb the process occasionally, if process conditions do not themselves cause a perturbation. In other Words, the variables f and f may be set at arbitrary points some distance from their ideal values long enough for the conversion corresponding to those flow rates to be measured. A probably better way is to let the curve-fitting operation depend not only on the 20 most recent process points, but also on previous values of k k and k The control system Whose rough characteristics are now emerging clearly meets process objectives and no limitations on equipment capacity are exceeded. It now must be explained how the necessary process variables are to be measured and controlled and how the dynamics of the process are to be taken into account.
The principal process variables which must be measured are f,,, the available feed rate; x the percentage of the reactant in the feed; and conversion, which may be computed if x and x are known. There is no difliculty involved in measuring f Flow measuring devices are Widely used and are cheap and reliable. The measurement of stream composition is more difficult. There is a continuous analytical instrument available which can measure the concentration of the reactant in the feed stream, but no instrument is available to measure product concentration in the fractionating-tower feed (point 102) or to measure the remaining reactant concentration in that feed.
Product concentration x can be found by measuring the flow rate of material into the fractionating tower and the flow rate at the tower bottom, and dividing the second by the first. This rough value for .15 may be refined somewhat by noting that the fractionating tower is normally operated so that some fixed percentage of the product appears at the tower top, regardless of tower-feed composition. If, for example, this particular tower is operated so that 5 percent of the distillate-flow rate is product, while approximately percent of the residue is product, then x can be found as follows:
where f =fl0W rate of product from fractionating system, and f =tower-feed rate So far, no mention has been made of the frequency with which measurements and computations are to take place. It is now necessary to specify these frequencies and to discuss how they will react on the control system and on the process. First, adjustments will be made in h and f as often as it is possible to measure the reactant concentration, and to carry out the calculations necessary to find f and f These calculations are not dependent upon measurements made later in the process, and there can therefore be no instability due to feedback. The modifications to Equation 4, on the other hand, will be carried out much more infrequently and will be based upon data accumulated over a long period of time. Specifically, one value of conversion will be obtained every halfrhour by averaging instantaneous samples of flow rates and of reactant percentages over that period of time.
.To each value of conversion so obtained, appropriate average value of f and i will be determined. These three numbers, together with the corresponding numbers for the 19 previous half-hourly intervals are employed in Equation ll to determine in, k and k Adjustments in these it values thus take place very slowly, being aifected only by data obtained over a long period of time. it is at this point that feedback is introduced into the control system. However, the feedback is smoothed and delayed to such an extent that it will not upset the dynamic equilibrium of the process.
The principal control system components required are a new instrument for the measurement of x;, the reactant composition, and the digital control computer itself. The system designers study of the required computer proin must be extensive enough to allow him to specify computer precision, speed and memory capacity required. The number and type of input and output transducers and lines must also be specified.
Reference is now made to FIG. 3 where a diagram is shown indicating various computing operations which are performed in order to control a process in accordance with the metuod of the invention. As indicated in FIG. 3 the control process is continuous and may be entered at any point, there being various tests to determine Whether the time for any particular operation is appropriate. For convenience, it will be assumed that we are presently considerin' the possibility of a control calculation in step This determination results in an answer of either yes or no. In the case of a yes answer the system then proceeds in step 302. to read in data indicated by dotted lines to be either at data of the type described above from the process or 5 data representing operators instructions, etc.
After th data read-in step 3432, this data is then checked in step by comparing the data with a previous trend and/ or with known limitations. In step 3% the data is corrected smoothed and weighted averages may be obtained to correct for flows, temperature, pressure, and density. in step 3% the desired control function is com puted and variables may be generated. After this, a cletermii dion is made as to Whether or not the control settings are possible, in step 3%; if so, the various controllers are set in step If not, a warning is given the operator in step 368.
Poll wing the completion of the control calculation and se ting a determ ation is made as to whether or not a correlation check may be made. Actually, this check may be nrde in a different sequence or perhaps even simultaneo sly with the above-mentioned calculation. However, for the purpose of the present example, it will be assumed that this check is made following the control calculation. if the time is proper for the correlation check, as in -i a d in step 3%, the system proceeds with step during which pertinent data points are analyzed over a previous period, and in step .3311 various functions are computed on the basis of variable relationships. In step 35.2, then, the constants which had previously been assumed for the computing step 395 are re-evaluated to provide the best matching. Here the Equation 11 mentioned above may be employed. Following step 312, step Iii-3 may be employed to store miscellaneous constants for the neat calculation and then a check is made to see if it is the proper time to check the computer in step 3M. if the time is proper, a computer test program is performed in step 315 which, if giving an answer of yes, as to proper operation in step 316, proceeds no further, but if the answer is no a warning signal is generated in step to indicate to the operator the particular error. Following the computer test program a time determination is in step 318 as to the appropriateness of a check on the transducers. This is referred to as an alarm check. if be time is proper, step 31.9 is employed to check the various transducers. if the check is indicated to be negative an alarm is given in step 329, otherwise system proceeds to return to the first step in control calculation, namely, step 391, for another cycle.
The computing program illustrated in MG. 3 is intended only as a general guide for developing a particular control solution. A specific computing program will now be developed for the control problem of FIG. 2.
During the first phase of the program the computer must be controlled to solve Equations 5 and 6 above to determine the optimum values for f and F For convenient reference these equations are repeated as follows:
While many solution approaches are possible, the example ere Will assume that trial values for h are substituted into Equation 5 to solve for a trial f which is then substituted into Equation 6 with the corresponding trial value for f Before beginning the computing opera tion the expected range of functions e are entered into the computer memory so that the multiplication of k by the trial f can be translated into the exponential value by reading out the corresponding function from a ernory location specified by the exponent. if the trial values of f and f substituted into Equation 6 provide a solution the first phase of the computing is completed, otherwise a new trial value for h is entered into Equation 5 and the resulting trial f and f are then entered into Equation 6 for checkin This process is continued until the optimum values for J; and f are found. Trial f values may be obtained by programming the computer adder to add one in the smallest unit denomination to the previous f The specific computing sequence for determining trial f from trial f may be specified as follows: R V -V 1; 3= z 2; i 1 5 t 23 e lfl; e from memory f =R R (1-R )-k R The check on the trial values according to Equation 6 may be performed as follows: R =1+k f R =(R Rm fwRg Chflck: f1f2- C2R7/R1O=R When the equality check above verifies the optimum values for f and f the computing system is then ready for the second phase of the program, the checking of the constraints. These are illustrated for the embodiment of FIG. 2 in Equations 2 and 10 repeated here for convenience as follows:
The computer is programmed to perform these comparisons and to set 11 and f at the optimum values if all constraints are satisfied. If any constraint is not complied with three possible computing routines are possible as outlined above. if f f the best setting for f is found by substituting f f for h in Equation 6 and solving for f This may be performed as a new computa tion or may be arranged to use the previous computation for trial f and f;,,, the results of which may be stored in the computer memory in addresses specified by f or or both. This substitution provides the solution for the best value for f to maximize the profit function P along the line f1+f4=fma A similar computation must then be performed along the line f =f max by solving Equation 5 with f max substituted for f to provide a value for h. The values for these two constrained sets of values for h and 1; must be compared to respective constraints f f max and f f +f If they are both permitted the selection is then made by solving profit Equation 3 to determine which provides the maximum profit.
If either of the constrained computations provides values for flow which still exceed the respective con- -straints the maximum value for the fiow'ratewithin the constraint area should be selected. Thus, if the solution for f along the line f +f =f provides a maximum profit value for f which is greater than f f max would be the value selected. If the result was negative f would be selected.
If the input flow rate f is less than f and greater .than i -13 the maximum value for P should be etermined along all of the boundary lines f =f f2=f2 max; and f1+f2=fmax- The best Value for it f2 in each of these cases can again be determined by solving the derivative Equation 5 or 6. The values are then compared to respective constraint conditions outlined above and finally all P values are computed from Equation 3 and compared to provide the best flow rates in view of the constraints.
The last possible input flow condition where fa max f2 max is determined in a similar manner along the lines f1=fa and f2 f2 max- The program control procedure thus far may be sum- 'marized in outline form as follows:
C. Continue trials and checks until check equation is satisfied 11. Check constraint equations and recompute along constraint lines to find maximum profit it optimum settings of f and f are not permissible A. Perform comparisons specified by constraint equations f2 f2 max;f1+f2 fmax; fl fe. B. If all constraints satisfied then set controllers to optimum f and H. C. If any constraint not satisfied then:
(i) For f f solve for maximum constrained profit along lines f +f =f and f 2 2 max For fmax f2 max fa fmax solve for maxi mum constrained profit along lines f =f f1+f2=fmox and f2 f2 max (3) For f f f max solve for maximum constrained profit along lines f1 =f and f 2 2 max D. Set flow rates f and f if not previously set to maximum allowable values.
The final computing phase involves the redetermination of constants k k and k from Equation 11. This is accomplished by performing successive divisions of measured x /x or by computing x according to Equation 12 and then dividing by measured x The values of f and f are set during this phase to provide a good correlation between c and these values.
The curve fitting computation may be performed on the basis of the solution of three simultaneous equations corresponding to the three derivative functions of Equation 11 as follows:
Equation 11a, 'for example, appears as follows when expanded:
The other derivatives may be derived in a similar man net. The actual computation sequence may follow lines discussed above by employing trial values until all equations check.
From the foregoing description it should now be apparent that the present invention provides a novel method for controlling a process to maximize the profit which may be obtained from the products produced thereby. The particular type of computing apparatus which may be employed to carry out the process of the invention has not been specified since many of the standard digital computers now available are suitable. It may be desirable, moreover, to provide a special-purpose digital computer for solving the equations of a particular program or to develop specialized analogue computing circuits. Such techniques are contemplated by the present invention as defined by the claims.
We claim:
1. A system for producing a product as a composition of raw material including at least one catalyst, said sys tern comprising: a first transducer for sensing the how of raw material and producing a signal f indicating the total feed available for producing said product; an analyzer for detecting the percentage of active ingredients in said fiow of raw material andfor producing a signal representative thereof; a reactor for receiving said raw materials and said catalyst to perform a first chemical operation; a second transducer introduced into the raw material flow for said reactor for producing a signal f indicating the flow of material through said reactor; at third transducer for sensing the how of said catalyst into said reactor and for producing a corresponding flow signal f;; a control computer; means for producing signals representing the value and costs of raw material and products per unit llow; means for coupling the signals produced by said transducers and analyzer, and said signals representing value and cos-ts to said compu er, said computer including means operable to produce control signals which specify the proper setting for the flow of material and catalyst to yield a maximum profit.
2. The system defined in claim 1 wherein means are included operating said control computer to produce control signals to regulate the flow corresponding to signals and f to maximize profit P in the following equation 3. The system defined in claim 2 wherein means are included operating said control computer during a second computing phase to check the constraints j where f represents the maximum flow rate through said reactor represents the maximum rate of iiow of said catalyst f represents the total raw material feedrate other than catalyst.
4. In combination with apparatus operating to produce a product from a non-uniformly available and non-homogeneous raw material by causing said raw material to be acted upon by a plurality of conditions including at least one selectively variable condition, means for varying said variable condition to maximize the profit obtainable from said product, said means comprising:
first transducing means for generating a first signal indicating the flow rate of available raw material; second analyzing means for generating a second signal indicating the percentage of active ingredients in said raw material; third means for generating a third signal indicating the value and costs of said product and raw material; digital control means programmed to determine on the basis of said first, second, and third signals, a set point for said variable condition effective to maximize saidprofit; fourth means for generating a fourth signal indicating said set point; and means responsive to said fourth signal for selectively varying said variable condition to establish said set point. 5. The combination of claim 4 wherein said variable condition comprises the fiow rate of catalyst to be mixed with said raw material.
14 References Cited in the file of this patent UNITED STATES PATENTS 2,712,414 Ziebolz et al. June 5, 1955 2,836,730 Early May 27, 1958 2,881,235 Pool Apr. 7, 1959 3,002,818 Berger Oct. 3, 1961 3,005,411 Metz Oct. 24, 1961 3,005,911 Burhans Oct. 24, 1961 OTHER REFERENCES

Claims (1)

1. A SYSTEM FOR PRODUCING A PRODUCT AS A COMPOSITION OF RAW MATERIAL INCLUDING AT LEAST ONE CATALYST, SAID SYSTEM COMPRISING: A FIRST TRANSDUCER FOR SENSING THE FLOW OF RAW MATERIAL AND PRODUCING A SIGNAL FA INDICATING THE TOTAL FEED AVAILABLE FOR PRODUCING SAID PRODUCT; AN ANALYZER FOR DETECTING THE PERCENTAGE OF ACTIVE INGREDIENTS IN SAID FLOW OF RAW MATERIAL AND FOR PRODUCING A SIGNAL REPRESENTATIVE THEREOF; A REACTOR FOR RECEIVING SAID RAW MATERIALS AND SAID CATALYST TO PERFORM A FIRST CHEMICAL OPERATION; A SECOND TRANSDUCER INTRODUCED INTO THE RAW MATERIAL FLOW FOR SAID REACTOR FOR PRODUCING A SIGNAL F1 INDICATING THE FLOW OF MATERIAL THROUGH SAID REACTOR; A THIRD TRANSDUCER FOR SENSING THE FLOW OF SAID CATALYST INTO SAID REACTOR AND FOR PRODUCING A CORRESPONDING FLOW SIGNAL F2; A CONTROL COMPUTER; MEANS FOR PRODUCING SIGNALS REPRESENTING THE VALUE AND COSTS OF RAW MATERIAL AND PRODUCTS PER UNIT FLOW; MEANS FOR COUPLING THE SIGNALS PRODUCED BY SAID TRANSDUCERS AND ANALYZER, AND SAID SIGNALS REPRESENTING VALUE AND COSTS TO SAID COMPUTER, SAID COMPUTER INCLUDING MEANS OPERABLE TO PRODUCE CONTROL SIGNALS WHICH SPECIFY THE PROPER SETTING FOR THE FLOW OF MATERIAL AND CATALYST TO YIELD A MAXIMUM PROFIT.
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US3296097A (en) * 1962-04-23 1967-01-03 Phillips Petroleum Co Predictive control of distillation column internal reflux
US3308040A (en) * 1963-03-08 1967-03-07 Phillips Petroleum Co Controlling the operation of a train of distillation columns
US3321280A (en) * 1964-06-26 1967-05-23 Exxon Research Engineering Co Computer control method for production of butyl rubber
US3322938A (en) * 1963-02-15 1967-05-30 Sun Oil Co Automatic control systems for optimizing heat transfer to a fluid flowing through parallel connected heat exchangers
US3343436A (en) * 1962-12-28 1967-09-26 Gen Electric Control means for sequencing a plurality of glass scoring means
US3354053A (en) * 1966-12-27 1967-11-21 Phillips Petroleum Co Controlling heat supply and product purities in the operation of a distillation column
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US3275988A (en) * 1961-08-21 1966-09-27 Du Pont Programmed batch sequence controller
US3267264A (en) * 1962-02-20 1966-08-16 Phillips Petroleum Co Analysis apparatus using controlled logic circuitry
US3296097A (en) * 1962-04-23 1967-01-03 Phillips Petroleum Co Predictive control of distillation column internal reflux
US3343436A (en) * 1962-12-28 1967-09-26 Gen Electric Control means for sequencing a plurality of glass scoring means
US3322938A (en) * 1963-02-15 1967-05-30 Sun Oil Co Automatic control systems for optimizing heat transfer to a fluid flowing through parallel connected heat exchangers
US3308040A (en) * 1963-03-08 1967-03-07 Phillips Petroleum Co Controlling the operation of a train of distillation columns
US3321280A (en) * 1964-06-26 1967-05-23 Exxon Research Engineering Co Computer control method for production of butyl rubber
US4208712A (en) * 1964-12-09 1980-06-17 Mobil Oil Corporation Multi-unit optimization
US3509326A (en) * 1965-02-23 1970-04-28 Ibm Closed loop control system with adaptive filter
US3354053A (en) * 1966-12-27 1967-11-21 Phillips Petroleum Co Controlling heat supply and product purities in the operation of a distillation column
US3654447A (en) * 1970-04-23 1972-04-04 Geigy Chem Corp Electronic instrumentation system for catalytic cyanogen chloride trimerization
US3891836A (en) * 1972-04-21 1975-06-24 Mobil Oil Corp Apparatus for optimizing multiunit processing systems
US4318178A (en) * 1980-05-28 1982-03-02 Phillips Petroleum Co. Control of a cracking furnace
US4991721A (en) * 1988-08-15 1991-02-12 Iowa State University Research Foundation, Inc. Automation of an air-screen seed cleaner
US5067067A (en) * 1989-07-05 1991-11-19 Eastman Kodak Company Method for evaluating and designing lenses
US5155677A (en) * 1989-11-21 1992-10-13 International Business Machines Corporation Manufacturing process optimizations
US5301125A (en) * 1990-09-26 1994-04-05 Exxon Research & Engineering Company Spectroscopic determination of amount of one constituent of a fluid mixture in another constituent or in the fluid mixture itself, following separation of the mixture into its constituents
US5328787A (en) * 1993-05-24 1994-07-12 Eastman Kodak Company Method for assessing and controlling the sensitometric characteristics of photographic products
US5499197A (en) * 1994-04-05 1996-03-12 Fou; Hsu-Chao Intelligent and all-bearing control circuit device of reverse osmosis drinking water machine
US20060190113A1 (en) * 2004-12-10 2006-08-24 Florence Boutemy Novel network production planning method
US7873429B2 (en) 2004-12-10 2011-01-18 L'Air Liquide, Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des Procedes Georges Clause Network production planning method
US20090287319A1 (en) * 2008-03-26 2009-11-19 Attarwala Fakhruddin T Universal model predictive controller
US8126575B2 (en) * 2008-03-26 2012-02-28 Fakhruddin T Attarwala Universal model predictive controller

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