US3047385A - Production of color photographic images - Google Patents
Production of color photographic images Download PDFInfo
- Publication number
- US3047385A US3047385A US72298A US7229860A US3047385A US 3047385 A US3047385 A US 3047385A US 72298 A US72298 A US 72298A US 7229860 A US7229860 A US 7229860A US 3047385 A US3047385 A US 3047385A
- Authority
- US
- United States
- Prior art keywords
- group
- color
- image
- light
- cyan
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title description 8
- 239000000839 emulsion Substances 0.000 claims description 45
- -1 SILVER HALIDE Chemical class 0.000 claims description 33
- 229910052709 silver Inorganic materials 0.000 claims description 21
- 239000004332 silver Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 15
- 239000010410 layer Substances 0.000 description 49
- 150000001875 compounds Chemical class 0.000 description 29
- 239000000975 dye Substances 0.000 description 29
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 23
- 239000000463 material Substances 0.000 description 18
- 238000002360 preparation method Methods 0.000 description 16
- 238000010521 absorption reaction Methods 0.000 description 14
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 14
- 230000003647 oxidation Effects 0.000 description 13
- 238000007254 oxidation reaction Methods 0.000 description 13
- 238000001228 spectrum Methods 0.000 description 13
- 229910052708 sodium Inorganic materials 0.000 description 12
- 239000011734 sodium Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 238000001429 visible spectrum Methods 0.000 description 11
- 125000005843 halogen group Chemical group 0.000 description 10
- 239000000047 product Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 9
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 9
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 9
- 108010010803 Gelatin Proteins 0.000 description 8
- 229920000159 gelatin Polymers 0.000 description 8
- 239000008273 gelatin Substances 0.000 description 8
- 235000019322 gelatine Nutrition 0.000 description 8
- 235000011852 gelatine desserts Nutrition 0.000 description 8
- 230000001590 oxidative effect Effects 0.000 description 8
- 230000009102 absorption Effects 0.000 description 7
- 238000004061 bleaching Methods 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 7
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 230000020477 pH reduction Effects 0.000 description 6
- 239000004848 polyfunctional curative Substances 0.000 description 6
- 239000003381 stabilizer Substances 0.000 description 6
- 239000000080 wetting agent Substances 0.000 description 6
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 5
- 239000000084 colloidal system Substances 0.000 description 5
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 5
- 239000012153 distilled water Substances 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 230000000873 masking effect Effects 0.000 description 5
- 238000005691 oxidative coupling reaction Methods 0.000 description 5
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- 150000001340 alkali metals Chemical group 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- CBEQRNSPHCCXSH-UHFFFAOYSA-N iodine monobromide Chemical compound IBr CBEQRNSPHCCXSH-UHFFFAOYSA-N 0.000 description 4
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 125000004434 sulfur atom Chemical group 0.000 description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 4
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 3
- WLQMYDWPKCQDPQ-UHFFFAOYSA-N 2,6-ditert-butyl-4-chlorophenol Chemical compound CC(C)(C)C1=CC(Cl)=CC(C(C)(C)C)=C1O WLQMYDWPKCQDPQ-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 229910021538 borax Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 3
- 235000019341 magnesium sulphate Nutrition 0.000 description 3
- 125000004430 oxygen atom Chemical group O* 0.000 description 3
- 239000004328 sodium tetraborate Substances 0.000 description 3
- 235000010339 sodium tetraborate Nutrition 0.000 description 3
- MDWVSAYEQPLWMX-UHFFFAOYSA-N 4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 MDWVSAYEQPLWMX-UHFFFAOYSA-N 0.000 description 2
- SSQQUEKFNSJLKX-UHFFFAOYSA-N 4-bromo-2,6-ditert-butylphenol Chemical compound CC(C)(C)C1=CC(Br)=CC(C(C)(C)C)=C1O SSQQUEKFNSJLKX-UHFFFAOYSA-N 0.000 description 2
- FSEOAURMSDLSKL-UHFFFAOYSA-N 4-chloro-2,6-diphenylphenol Chemical compound OC1=C(C=2C=CC=CC=2)C=C(Cl)C=C1C1=CC=CC=C1 FSEOAURMSDLSKL-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000002180 anti-stress Effects 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- 159000000009 barium salts Chemical class 0.000 description 2
- 150000001555 benzenes Chemical class 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 2
- AJDUTMFFZHIJEM-UHFFFAOYSA-N n-(9,10-dioxoanthracen-1-yl)-4-[4-[[4-[4-[(9,10-dioxoanthracen-1-yl)carbamoyl]phenyl]phenyl]diazenyl]phenyl]benzamide Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2NC(=O)C(C=C1)=CC=C1C(C=C1)=CC=C1N=NC(C=C1)=CC=C1C(C=C1)=CC=C1C(=O)NC1=CC=CC2=C1C(=O)C1=CC=CC=C1C2=O AJDUTMFFZHIJEM-UHFFFAOYSA-N 0.000 description 2
- 150000004780 naphthols Chemical class 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000001043 yellow dye Substances 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- SKDGWNHUETZZCS-UHFFFAOYSA-N 2,3-ditert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(O)=C1C(C)(C)C SKDGWNHUETZZCS-UHFFFAOYSA-N 0.000 description 1
- AUEZNTKYSSUTGZ-UHFFFAOYSA-N 2,6-dicyclohexylphenol Chemical compound OC1=C(C2CCCCC2)C=CC=C1C1CCCCC1 AUEZNTKYSSUTGZ-UHFFFAOYSA-N 0.000 description 1
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 1
- KRAWOYVPVQRUAE-UHFFFAOYSA-N 2-(4-aminoanilino)acetic acid Chemical compound NC1=CC=C(NCC(O)=O)C=C1 KRAWOYVPVQRUAE-UHFFFAOYSA-N 0.000 description 1
- QPKNFEVLZVJGBM-UHFFFAOYSA-N 2-aminonaphthalen-1-ol Chemical class C1=CC=CC2=C(O)C(N)=CC=C21 QPKNFEVLZVJGBM-UHFFFAOYSA-N 0.000 description 1
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical class NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 description 1
- FLROJJGKUKLCAE-UHFFFAOYSA-N 3-amino-2-methylphenol Chemical class CC1=C(N)C=CC=C1O FLROJJGKUKLCAE-UHFFFAOYSA-N 0.000 description 1
- RPKZYDKWDQEUKE-UHFFFAOYSA-N 4-amino-2,3,5,6-tetraphenylphenol Chemical compound C1(=CC=CC=C1)C1=C(C(=C(C(=C1C1=CC=CC=C1)N)C1=CC=CC=C1)C1=CC=CC=C1)O RPKZYDKWDQEUKE-UHFFFAOYSA-N 0.000 description 1
- QNGVNLMMEQUVQK-UHFFFAOYSA-N 4-n,4-n-diethylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C=C1 QNGVNLMMEQUVQK-UHFFFAOYSA-N 0.000 description 1
- 101000737090 Agrotis ipsilon Neuropeptide CCHamide-2 Proteins 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000004133 Sodium thiosulphate Substances 0.000 description 1
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 235000011126 aluminium potassium sulphate Nutrition 0.000 description 1
- 150000008430 aromatic amides Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 125000006367 bivalent amino carbonyl group Chemical group [H]N([*:1])C([*:2])=O 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000006297 carbonyl amino group Chemical group [H]N([*:2])C([*:1])=O 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000012954 diazonium Substances 0.000 description 1
- 150000001989 diazonium salts Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000002440 hydroxy compounds Chemical class 0.000 description 1
- 239000005457 ice water Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229940050271 potassium alum Drugs 0.000 description 1
- GRLPQNLYRHEGIJ-UHFFFAOYSA-J potassium aluminium sulfate Chemical compound [Al+3].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRLPQNLYRHEGIJ-UHFFFAOYSA-J 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- ZUNKMNLKJXRCDM-UHFFFAOYSA-N silver bromoiodide Chemical compound [Ag].IBr ZUNKMNLKJXRCDM-UHFFFAOYSA-N 0.000 description 1
- 230000002226 simultaneous effect Effects 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 125000002130 sulfonic acid ester group Chemical group 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/62—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by introduction of halogen; by substitution of halogen atoms by other halogen atoms
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/18—Processes for the correction of the colour image in subtractive colour photography
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/32—Colour coupling substances
- G03C7/34—Couplers containing phenols
- G03C7/344—Naphtholic couplers
Definitions
- the present invention relates to the production of color photographic images, more particularly to a process of color correction utilizing an integral masking procedure.
- the cyan dye which should absorb red light and transmit green and blue light usually absorbs a small amount of green and blue light, as well as a major proportion of red light.
- the magenta dye which should absorb green light and transmit blue and red light usually absorbs a considerable amount of blue light and a small amount of red light, as well as a major proportion of green light.
- the yellow dye which should absorb blue light and transmit green and red light is usually satisfactory.
- a color-corrected image is formed in a photographic element, comprising a silver halide emulsion layer and a color coupler (more particularly a color coupler of the naphthol type) which is reactive with the oxidation product of an aromatic amino developing agent to form by color development a primary dye image (more particularly a cyan dye-image) which absorbs a major proportion of light in one region of the visible spectrum (more particularly the red light) and undesirably absorbs a minor proportion of light in at least one other region of the visible spectrum (more particularly the green light), by treating the exposed and color-developed photographic element with an oxidizing solution (more particularly a photographic bleaching bath), in the presence of a 4- amino-pyrazolone-3compound, which after oxidation couples with the residual color coupler, whereby a secondary dye image (more particularly a magenta dye image) having a gradation opposite to that of said primary dye image, and absorbing light in at least one of said unwanted minor absorption regions (
- a further object is to provide a new method for the preparation of an integral mask in color film, more particularly to provide a yellow to orange colored image compensating the unwanted absorption of blue light by the cyan image dye.
- an imagewise exposed photographic element comprising a silver halide emulsion layer and a color coupler of the naphthol type which is reactive with the oxidation product of an aromatic amino developing agent to form by color development a cyan dye image.
- the image-wise exposed and color-developed photographic silver halide emulsion layer comprises also an aromatic monocylic hydroxy compound containing a sterically hindering substituent in both ortho-positions, and being substituted in the pposition of the hydroxy-group either or not with a substituent which splits off by the oxidative coupling of the aromatic monocyclic hydroxy compound with the residual color coupler of the naphthol type during the treatment in an oxidizing solution, eg a photographic bleaching bath.
- a photographic material containing color couplers of the following general formula:
- X represents a member selected from the group consisting of an oxygen atom, a sulfur atom, a NHCO group, a C0NH- group, a -SO NH- group, a NHSO group, a Nalkyl group and a sulfonyl group;
- Y represents a member selected from the group consisting of an hydrogenatom and a halogen atom
- D represents an aliphatic radical comprising a linear chain of at least 5 and at most 20 carbon atoms, preferably 14, 16, or 18 carbon atoms;
- M represents a member selected from the group consisting of an hydrogen atom, analkali metal atom and an ammonium group.
- N (2 cetyloxy 5 sulfo) phenyl 1 hydroxy 4- chloro-Z-naphthoic acid amide sodium salt
- N (2 cetylrnercapto 5' sulfo) phenyl 1 hydroxy- 2-naphthoic acid amide sodium salt
- N (2 cetylmercapto 5 sulfo) phenyl 1 hydroxy- 4-bromo-2-naphthoic acid amide sodium salt
- N (2' methyl cetylamino sulfio) droXy-4-chloro-2-naphthoic acid amide sodium salt
- N (6' cetylsulfonylphenyl) 1 hydroxy 2 naphthoic acid amide-3-sodium sulfonate
- color couplers for cyan can be prepared e.g. by condensation of l-hydroxy-Z-naphthoic acid or its derivatives with the suitable aromatic amides according to German patent application No. G 30,287, filed August 13, 1960.
- phenyl 1 hy- Suitable mask forming compounds are e.g. phenols containing a sterically hindering substituent such as a tertiary butyl group, a phenyl group or a cyclohexyl group, in both ortho-positions in respect to the hydroxyl group and which further may contain in the p-position in respect of the hydroxyl group a substituent with labile character during oxidative coupling such as a halogen atom, a sulfonic acid group, a sulfonic acid ester group, a carboxylic acid group or a substituted methylene group.
- a substituent with labile character during oxidative coupling such as a halogen atom, a sulfonic acid group, a sulfonic acid ester group, a carboxylic acid group or a substituted methylene group.
- the barium salt dissolved in 50 cm. of water can be converted into a sodium salt by adding to this solution a solution of 3.4 g. of sodium sulfate in cm. of water.
- the formed barium sulfate is sucked off and the filtrate is evaporated to dryness.
- PREPARATION 7 The preparation of 2,6-diphenyl-4-chlorophenol. 7.8 g. (0.03 mol) of 2,6-diphenyl-4-amino-diphenylphenol prepared according to A. Luttringhaus Ann, 542, 257 (1939), are diazotized in 8.5 cm. of concentrated hydrochloric acid, 0111. of water and 20 cm? of dioxane at 0 C. with a concentrated aqueous solution of 2.1 g. (0.03 mol) of sodium nitrite. The solution of the diazonium salt is added at room temperature to 170 cm. of concentrated hydrochloric (acid containing cuprochloride. (The cuprochloride is prepared from 10.5 g.
- the mask forming compound is incorporated in one of the layers present in the light-sensitive photographic material, preferably in the red sensitive silver halide emulsion layer containing a color coupler for cyan and wherein the mask image is to be formed by 'oxidative coupling of the residual color coupler for cyan present in that layer with the mask forming substance.
- the mask-forming compounds of the present invention may be used together with one of the mask-forming compounds disclosed in our US. patent application Serial No. 70,914 filed November 22, 1960, for Production of Color Photographic Images, which by oxidative coupling with color couplers for cyan of the naphthol class yield magenta to red colored mask images, compensating mainly the undesirable side-absorption in the green part of the spectrum of the cyan image; in this way a cyan image can be obtained, the undesirable side-absorptions of which in the blue as well as in the green part of the spectrum are almost completely compensated.
- the color couplers and mask compounds can be incorporated into a photographic silver halide emulsion prepared by means of the colloids usually employed therefor, such as for instance gelatin, polyvinyl alcohol, collodion or other natural or synthetic colloids.
- the silver halide emulsion can be coated on a support consisting of paper, glass, nitrocellulose, cellulose esters such as cellulose triacetate, polyester, polystyrene or another natural or synthetic resin, and forms part of a photographic material with one or more emulsion layers.
- the multilayer material usually comprises the following elements: a support, a red-sensitive emulsion layer having a color coupler for cyan, a green-sensitive emulsion layer having a color coupler for magenta and a blue-sensitive emulsion layer having a color coupler for yellow.
- a yellow filter composed in most of the cases of a gelatin layer containing dispersed colloid silver, located between the blue-sensitive emulsion layer and the emulsion layer sentitized to green.
- the color couplers are not only possible to incorporate the color couplers into the lightsensitive silver halide emulsion layer itself but they can also be incorporated into an adjacent non-light-sensitive colloid layer or into a non-light-sensitive layer which is separated from the light-sensitive emulsion layer by a water-permeable colloid layer.
- the process according to the invention proceeds as follows: silver halide is reduced to silver at the exposed areas in a color developing bath containing a primary amine aromatic developing agent which is at the same time oxidized.
- the oxidized developing agent reacts with the color coupler and forms a 'dyestuif, the mask tf-orming compound according to the invention not being affected.
- the material comes into the bleaching bath wherein the oxidation of the mask forming compound takes place.
- the remaining color coupler still available at the non-exposed areas of the material couples oxidatively with the oxidation product of the compound thus formed whereby the colored mask is formed.
- the photographic color material is Washed with water, fixed and dried.
- aromatic amino-compounds can be used as developers for such material: mono, diand triaminoaryl compounds, more especially N,N-dialkyl-p-phenylenediamines, such as N,N-diethyl-p-phenylenediamine and N,N-diethyl-Z-methyl-p-phenylene diamine, and derivatives thereof such as N,N-dialkyl-N-sulphomethylor carboXymethyl-p-phenylenediamine.
- monoamino-developers should be cited: aminophenols and amino-cresols or their halogen derivatives and also the amino-naphthols.
- the bleaching bath generally contains potassium bromide, borax, magnesium sulphate and especially potassium ferricyanide. These elements are dissolved in precisely determined amounts of water so that a solution with a determined pH value is obtained.
- the usual additives such as hardeners, wetting agents and stabilizers and the necessary quantity of distilled water are added to the emulsion in order to obtain 1 kg. of emulsion ready for coating.
- the emulsion is coated on a suitable support and dried. After exposure through a grey wedge with a constant 0.15, the photographic material composed in this way is developed for 9 min. at C. in a color-developing bath with the following composition:
- This material is rinsed for 30 minutes at 18 to 20 C. and fixed for 5 minutes at 20 C. in a fixing bath of the following composition:
- Potassium ferricyanide 100 Potassium bromide 15 Borax 2O Magnesium sulphate 50 Water to 1000 cm. (pH 8.6).
- Rinsing is continued for another 10 min. at 18 to 20 and finally the material is dried.
- a cyan image also a yellow-colored mask image is formed, with a gradation opposed to that of the cyan image, and which compensates the side absorption of the cyan image in the blue.
- Example 2 To a /2 kg. of red-sensitive 'bromo-iodide emulsion (2% iodide) containing ,4; mol of silver halide are added 10 g. of N (6' cetylsulfonylphenyl) 1 hydroxy-Z- naphthoic acid amide-3'-sodium sulfonate dissolved in 193 cm. of water and 7 cm. of an aqueous solution of sodium hydroxide 2 N and 10 g. of bis-(3,5-di-tert-butyl-4- hydroxyphenyl)-methane dissolved in cm. of ethyleueglycol monomethylether.
- emulsion After acidification to pH 6 and after addition of the usual additives such as hardeners, wetting agents, and stabilizers and the necessary quantity of distilled water to obtain 1 kg. emulsion, the emulsion is coated on a suitable support and dried. After a further treatment according to Example 1, a cyan image is obtained wherein the disturbing influence of the sideabsorption in the blue is reduced by the formed yellow masking image with opposite gradation to the cyan image.
- Example 3 To a /2 kg. of red-sensitive bromo-iodide emulsion (2% iodide) containing mol of silver halide are added 10 g. of N-(6-cetylsulfonylphenyl)-1-hydroxy-2-naphthoic acid amide-3-sodium sulfonate dissolved in 193 cm. of water and 7 cm. of an aqueous solution of sodium hydroxide 2 N and 10 g. of 2,6-di-tert-butylphenol- 4 carboxylic acid dissolved in 100 cm. of ethyleneglycol monomethylether.
- emulsion After acidification to pH 6 and after addition of the usual additives such as hardeners, wetting agents and stabilizers and the necessary quantity of distilled water to obtain 1 kg. emulsion, the emulsion is coated on a suitable support and dried. After a further treatment according to Example 1, a cyan image is obtained wherein the disturbing influence of the side-absorption in the blue is reduced by the formed yellow masking image with opposite gradation to the cyan image.
- Example 4 To a /2 kg. of red-sensitive bromo-iodide emulsion (2% iodide) containing mol of silver halide are added 10 g. of N-(6-cetylsulfonylphenyl)-1-hydroxy-2-naphthoic acid amide-3-sodium sulfonate dissolved in 193 cm. of water and 7 cm. of an aqueous solution of sodium hydroxide 2 N and 10 g. of 2,6-di-tert-butyl-4- bromo-phenol dissolved in 100 cm. of ethyleneglycol monomethylether.
- emulsion After acidification to pH 6 and after addition of the usual additives such as hardeners, wetting agents and stabilizers and the necessary quantity of distilled water to obtain 1 kg. emulsion, the emulsion is coated on a suitable support and dried. After a further treatment according to Example 1, a cyan image is obtained wherein the disturbing influence of the side-absorption in the blue is reduced by the formed yellow masking image with opposite gradation to the cyan image.
- this emulsion forms part of a multilayer photographic material consisting of the following superposed layers in the indicated sequence: a support, an antihalation layer, a gelatin insulating layer, the above-mentioned red-sensitive emulsion layer with color coupler for cyan, a gelatin interlayer, a green-sensitive emulsion layer, a yellow filter layer, a blue-sensitive emulsion layer with color coupler for yellow and at last a gelatin overcoat as antistress layer.
- Example 1 After exposure through a grey wedge with a constant 0.15 the photographic material is developed and further treated as in Example 1. A mainly cyan-colored image is obtained together with a yellow dye image in the red-sensitive layer, said yellow image being of opposite gradation in respect of the cyan dye image and reducing the disturbing influence of the side-absorption in the blue in the formed cyan image.
- Example 6 To /2 kg. of a red-sensitive bromo-iodide emulsion (2% iodide) containing mol of silver halide are added 9 g. of N-(6'-cetylsulfonylphenyl)-1-hydroxy-2-naphthoic acid amide-3'-sodium sulfonate dissolved in a mixture of 175 cm? of Water and 6.3 cm. of an aqueous solution of sodium hydroxide 2 N, 2 g. of 1,2-dimethyl- 4-amino-5-nonylpyrazolone-3 dissolved in 20 cm. of ethanol with a little sodium hydroxide and 2 g.
- this emulsion forms part of a multilayer photographic material consisting of the following superposed layers in the indicated sequence: a support, an antihalation layer, a gelatin insulating layer, the above-mentioned red-sensitive emulsion layer with color coupler for cyan, a gelatin interlayer, a green-sensitive emulsion layer, a yellow filter layer, a blue-sensitive emulsion layer with color coupler for yellow and at last a gelatin overcoat as antistress layer.
- a grey wedge with a constant 0.15 the photographic material is developed and further treated as in Example 1.
- the red-sensitive layer of both materials besides a cyan image, also a yellow colored as well as a magenta colored mask image are formed, which images compensate the side absorptions of the cyan image in the blue and in the green part of the spectrum.
- Y represents a member selected from the group consisting of an hydrogen atom and a halogen atom
- D represents an aliphatic radical comprising a linear chain of at least 5 and at most 20 carbon atoms
- M represents a member selected from the group consisting of an hydrogen atom, an alkali metal atom and an ammonium group
- R and R each represents a sterically hindering group selected from the group consisting of tert-butyl, cyclohexyl and phenyl;
- R represents a member selected from the group consisting of a hydrogen atom, a halogen atom and a radical which is sufficiently unstable for splitting oil on treatment of said mask forming compound with an oxidizing solution in the presence of said color coupler.
- X represents a member selected from the group consisting of an oxygen atom, a sulfur atom, a
- Y represents a member selected from the group consisting of an hydrogen atom and a halogen atom
- L' D represents an aliphatic radical comprising a linear chain of at least 5 and at most 20 carbon atoms
- M represents a member selected from the group consisting of an hydrogen atom, an alkali metal atom and an ammonium group
- R and R each represents a sterically hindering group selected from the group consisting of tert-butyl, cyclohexyl and phenyl;
- R represents a member selected from the group consisting of a hydrogen atom, a halogen atom and a radical which is sufliciently unstable for splitting 01f on treatment of said mask forming compound with an oxidizing solution in the presence of said color coupler;
- said color coupler being also reactive with the oxidation products of said mask forming compounds to form a magenta to red colored dve image and a yellow to orange colored dye image said dye images having a gradation opposite to that of said cyan dye image, and transmitting substantially all the light in the red region of the spectrum, said magenta to red colored dye image absorbing light in the green region of the spectrum, and said yellow to orange colored dye image absorbing light in the blue region of the spectrum, which method comprises exposing said layers to light, developing at least said layer containing said color coupler, by color development with an aromatic amino developing agent, whereby said cyan dye image is formed in the developed areas by coupling, leaving in the undeveloped areas of said one layer residual color coupler, and treating at least said layer containing said residual color coupler, and said mask forming compounds, with a bleaching bath, said treatment resulting in the oxidation of said mask forming compounds, whereby said magenta to red colored dye image and said yellow to orange colored dye image is formed by coupling said oxidized mask-forming
- Photographic element having superposed silver halide emulsion layers sensitive to difierent regions of the visible spectrum, at least one of said layers containing a color coupler of the formula:
- X represents a member selected from the group consisting of an oxygen atom, a sulfur atom, a
- Y represents a member selected from the group consisting of an hydrogen atom and a halogen atom
- D represents an aliphatic radical comprising a linear chain of at least 5 and at most 20 carbon atoms
- M represents a member selected from the group consisting of an hydrogen atom, an alkali metal atom and an ammonium group
- R and R each represents a sterically hindering group selected from the group consisting of tert-butyl, cyclohexyl and phenyl;
- R represents a member selected from the group consisting of a hydrogen atom, a halogen atom and a radical which is sufficiently unstable for splitting ofl on treatment of said mask forming compound with an oxidizing solution in the presence of said color coupler,
- said color coupler being also reactive with the oxidation product of said mask-forming compound to form a secondary dye image having a gradation opposite to that of said cyan dye image, and absorbing light in at least one of said unwanted minor absorption regions but transmittingsubstantially all the light in the red absorption region of the spectrum.
- Photographic element having superposed silver halide emulsion layers sensitive to diiterent regions of the visible spectrum, at vleast one of said layers containing a color coupler of the formula:
- X represents a member selected from the group consiting of an oxygen :atom, a sulfur atom, a NHCO-- group, a CO-NH group, a SO NH group, a NHSO group, a N-alkyl group and a sulfonyl group;
- Y represents a member selected from the group consisting of an hydrogen atom and a halogen atom
- D represents an aliphatic radical comprising a linear chain of at least 5 and at most carbon atoms
- M represents a member selected from the group consisting of an hydrogen atom, an alkali metal atom and an ammonium group
- R and R each represents a sterically hindering group selected from the group consisting of tert-butyl, cyclohexyl and phenyl;
- R represents a member selected from the group consisting of a hydrogen atom, a halogen atom and a radical which is sufficiently unstable for splitting olt on treatment of said mask forming compound with an oxidizing solution in the presence of said color coupler,
- R represents a lower alkyl group
- R represents a member selected from the group con sis-ting of a lower alkyl group and an aryl group of the benzene series, and a substituted aryl group p of the benzene series;
- R represents an aliphatic radical comprising a linear chain of at least 5 and at most 20 carbon atoms
- said color coupler being also reactive with the oxidation products of said mask forming compounds to form a yellow to orange colored dye image and a magenta to red colored dye image, said dye images having a gradation opposite to that of said cyan image, and transmitting substantially all the light in the red region of the spectrum, said magneta to red colored dye image absorbing light in the green region of the spectrum, and said yellow to orange colored dye image absorbing light in the blue region of the spectrum.
Description
ilnited States Fa -tent 3,047,385 PRODUCTION OF COLOR PHOTOGRAPHKC lNlAGES Maurice Antoine de Raniaix and Jan Jaelren, Hove-Antwerp, Belgium, assignors to Gevaert Photo-Producten N.V., Mortsel, Belgium, a Belgian company No Drawing. Filed Nov. 29, 1960, Ser. No. 72,298
Claims priority, application Great Britain Nov. 30, 1959 6 Claims. (Cl. 96-9) The present invention relates to the production of color photographic images, more particularly to a process of color correction utilizing an integral masking procedure.
It is known that dyes formed by color development in subtractive multicolor photographic pictures do not transmit all of the light which practical considerations demand. The cyan dye which should absorb red light and transmit green and blue light usually absorbs a small amount of green and blue light, as well as a major proportion of red light. The magenta dye which should absorb green light and transmit blue and red light usually absorbs a considerable amount of blue light and a small amount of red light, as well as a major proportion of green light. The yellow dye which should absorb blue light and transmit green and red light is usually satisfactory.
Due to the above mentioned unwanted side-absorptions of the dyes formed by color development, it is practically impossible to obtain a true reproduction of the original colors on printing multicolor photographic transparencies containing such dyes.
Correction of the colors on printing is therefore desirable, and this is usually done by masking. Since separate masks are difficult to register with the color transparency, it is desirable that the mask be integral with the color images.
A process for the production of a color photographic image wherein the mask is integral with the color image is described in our US. patent application Serial No. 705,508, filed December 27, 1957, in US. patent application Serial No. 66,964, filed November 3, 1960, by Raphael Karel Van Poucke, Arthur Henri De Cat and Marcel Hendrik Verbrugghe for Process for the Manufacture of Color Photographic Images and Color Correction, in our US. patent application Serial No. 70,914 filed November 22, 1960, for Production of Color Photographic Images, and in US. patent application Serial No. 77,117, filed November 14, 1960, by Jozef Frans Willems and Jan Jaeken for Production of Color Photographic Images.
According to said first three pending applications, a color-corrected image is formed in a photographic element, comprising a silver halide emulsion layer and a color coupler (more particularly a color coupler of the naphthol type) which is reactive with the oxidation product of an aromatic amino developing agent to form by color development a primary dye image (more particularly a cyan dye-image) which absorbs a major proportion of light in one region of the visible spectrum (more particularly the red light) and undesirably absorbs a minor proportion of light in at least one other region of the visible spectrum (more particularly the green light), by treating the exposed and color-developed photographic element with an oxidizing solution (more particularly a photographic bleaching bath), in the presence of a 4- amino-pyrazolone-3compound, which after oxidation couples with the residual color coupler, whereby a secondary dye image (more particularly a magenta dye image) having a gradation opposite to that of said primary dye image, and absorbing light in at least one of said unwanted minor absorption regions (more particularly the green light) but transmitting substantially all the light in said major absorption region (more particularly the red light) is formed.
ice
It is an object of the present invention to provide an improved method for correcting the colors of a photographic image used for printing. A further object is to provide a new method for the preparation of an integral mask in color film, more particularly to provide a yellow to orange colored image compensating the unwanted absorption of blue light by the cyan image dye. Other objects will appear from the following description and examples.
These objects are accomplished by treating an imagewise exposed photographic element comprising a silver halide emulsion layer and a color coupler of the naphthol type which is reactive with the oxidation product of an aromatic amino developing agent to form by color development a cyan dye image. The image-wise exposed and color-developed photographic silver halide emulsion layer comprises also an aromatic monocylic hydroxy compound containing a sterically hindering substituent in both ortho-positions, and being substituted in the pposition of the hydroxy-group either or not with a substituent which splits off by the oxidative coupling of the aromatic monocyclic hydroxy compound with the residual color coupler of the naphthol type during the treatment in an oxidizing solution, eg a photographic bleaching bath.
It has been found indeed that by oxidative coupling of the mask-forming compounds of the present invention with color couplers for cyan of the naphthol class a yellow to orange color mask image is obtained which compensates the undesirable side-absorption in the blue part of the spectrum of the cyan image obtained by color development of the exposed areas of the layer containing said cyan coupler.
According to a preferred embodiment of the present invention, a photographic material is used containing color couplers of the following general formula:
| I we omen-Q S 03M D Y wherein:
X represents a member selected from the group consisting of an oxygen atom, a sulfur atom, a NHCO group, a C0NH- group, a -SO NH- group, a NHSO group, a Nalkyl group and a sulfonyl group;
Y represents a member selected from the group consisting of an hydrogenatom and a halogen atom;
D represents an aliphatic radical comprising a linear chain of at least 5 and at most 20 carbon atoms, preferably 14, 16, or 18 carbon atoms;
M represents a member selected from the group consisting of an hydrogen atom, analkali metal atom and an ammonium group.
Suitable compounds which give good results and which correspond to the above general Formula I are:
N (2' cetyloxy 5 sulfo) phenyl 1 hydroxy 2- naphtholic acid amide sodium salt,
N (2 cetyloxy 5 sulfo) phenyl 1 hydroxy 4- chloro-Z-naphthoic acid amide sodium salt, N (2 cetylrnercapto 5' sulfo) phenyl 1 hydroxy- 2-naphthoic acid amide sodium salt, N (2 cetylmercapto 5 sulfo) phenyl 1 hydroxy- 4-bromo-2-naphthoic acid amide sodium salt,
N (2' cetylmercapto 5 sulfo) phenyl l hydroxy- 4-chloro-2-naphthoic acid amide sodium salt,
N (2 palmitoylamino 4' sulfo) phenyl 1 hydroxy-Z-napthoic acid amide sodium salt,
3 N (2' methyl cetylamino sulfio) droXy-4-chloro-2-naphthoic acid amide sodium salt, N (6' cetylsulfonylphenyl) 1 hydroxy 2 naphthoic acid amide-3-sodium sulfonate, N-(6-cetylsulfonylphenyl)-1-hydroxy-4-chloro 2 naphthoic acid amide-3'-sodium sulfonate, N-(4'-cetylsulfonyl)-1-hydroxy-2-naphthoic acid amide- 3-sodium sulfonate.
These color couplers for cyan can be prepared e.g. by condensation of l-hydroxy-Z-naphthoic acid or its derivatives with the suitable aromatic amides according to German patent application No. G 30,287, filed August 13, 1960.
phenyl 1 hy- Suitable mask forming compounds are e.g. phenols containing a sterically hindering substituent such as a tertiary butyl group, a phenyl group or a cyclohexyl group, in both ortho-positions in respect to the hydroxyl group and which further may contain in the p-position in respect of the hydroxyl group a substituent with labile character during oxidative coupling such as a halogen atom, a sulfonic acid group, a sulfonic acid ester group, a carboxylic acid group or a substituted methylene group.
PREPARATION 1 The preparation of 2,6-di-tert-butyl-4-bromophenol is described by H. Hart, 1. Am. Chem. Soc., 73, p. 3181 (1951).
PREPARATION 2 The preparation of bis-(3,5-di-tert-butyl-4-hydroxyphenyl)-methane is described by T. Cofiield, J. Am. Chem. Soc, 79, p. 5021 (1957).
PREPARATION 3 The preparation of 2,6-di-tert-butyl-phenol-4-carboxylic acid is described by G. Yoke, J. Org. Chem. 21, p. 1291 (1956).
PREPARATION 4 The preparation of 2,6-di-tert-butyl-4-chlorophenol is described by H. Hart, J. Am. Chem. Soc., 73, p. 1381 (1951).
PREPARATION 5 The preparation of 2,6-di-tert-butylphenol-4-sulfonic acid. 10.3 g. (0.05 mol) of di-ter-t-butylphenol are slowly added to 20 0111. of concentrated sulfuric acid Whilst stirring and keeping the temperature at 45 C. The mixture is further stirred for /2 h. at 45-50 C. The reaction mixture is poured into ice-water. After extraction of the residual di-tert-butyl-phenol with ether barium carbonate is added. The barium sulfate precipitate formed is sucked off and the filtrate is evaporated to dryness. The residue contains g. of the barium salt of 2,6 di-tert-butylphenol-4-sulfonic acid. The barium salt dissolved in 50 cm. of water can be converted into a sodium salt by adding to this solution a solution of 3.4 g. of sodium sulfate in cm. of water. The formed barium sulfate is sucked off and the filtrate is evaporated to dryness.
PREPARATION 6 The preparation of 2,6-dicyclohexylphenol is described y H. Lefebvre, Compt. Rend., 220, 783 (1945).
PREPARATION 7 The preparation of 2,6-diphenyl-4-chlorophenol. 7.8 g. (0.03 mol) of 2,6-diphenyl-4-amino-diphenylphenol prepared according to A. Luttringhaus Ann, 542, 257 (1939), are diazotized in 8.5 cm. of concentrated hydrochloric acid, 0111. of water and 20 cm? of dioxane at 0 C. with a concentrated aqueous solution of 2.1 g. (0.03 mol) of sodium nitrite. The solution of the diazonium salt is added at room temperature to 170 cm. of concentrated hydrochloric (acid containing cuprochloride. (The cuprochloride is prepared from 10.5 g. of copper sulfate, 27,3 g. of sodium chloride, 22.3 g. of sodium metabisulfite and 14.7 g. of sodium hydroxide.) Simultaneou ly with an evolution of n g n a p p e i 4 formed which is sucked off. After washing with water 2,6-diphenyl-4-chlorophenol is obtained, which melts with decomposition at C.
The chemical formulae of the compounds according to the above seven preparations are given hereinafter in a separate table in column 7.
According to a preferred embodiment of the present invention, the mask forming compound is incorporated in one of the layers present in the light-sensitive photographic material, preferably in the red sensitive silver halide emulsion layer containing a color coupler for cyan and wherein the mask image is to be formed by 'oxidative coupling of the residual color coupler for cyan present in that layer with the mask forming substance.
The mask-forming compounds of the present invention may be used together with one of the mask-forming compounds disclosed in our US. patent application Serial No. 70,914 filed November 22, 1960, for Production of Color Photographic Images, which by oxidative coupling with color couplers for cyan of the naphthol class yield magenta to red colored mask images, compensating mainly the undesirable side-absorption in the green part of the spectrum of the cyan image; in this way a cyan image can be obtained, the undesirable side-absorptions of which in the blue as well as in the green part of the spectrum are almost completely compensated.
For carrying out the process according to the present invention, the color couplers and mask compounds can be incorporated into a photographic silver halide emulsion prepared by means of the colloids usually employed therefor, such as for instance gelatin, polyvinyl alcohol, collodion or other natural or synthetic colloids. The silver halide emulsion can be coated on a support consisting of paper, glass, nitrocellulose, cellulose esters such as cellulose triacetate, polyester, polystyrene or another natural or synthetic resin, and forms part of a photographic material with one or more emulsion layers. The multilayer material usually comprises the following elements: a support, a red-sensitive emulsion layer having a color coupler for cyan, a green-sensitive emulsion layer having a color coupler for magenta and a blue-sensitive emulsion layer having a color coupler for yellow. Usually there is a yellow filter composed in most of the cases of a gelatin layer containing dispersed colloid silver, located between the blue-sensitive emulsion layer and the emulsion layer sentitized to green. It is not only possible to incorporate the color couplers into the lightsensitive silver halide emulsion layer itself but they can also be incorporated into an adjacent non-light-sensitive colloid layer or into a non-light-sensitive layer which is separated from the light-sensitive emulsion layer by a water-permeable colloid layer.
The process according to the invention proceeds as follows: silver halide is reduced to silver at the exposed areas in a color developing bath containing a primary amine aromatic developing agent which is at the same time oxidized. The oxidized developing agent reacts with the color coupler and forms a 'dyestuif, the mask tf-orming compound according to the invention not being affected. After the color development, the material comes into the bleaching bath wherein the oxidation of the mask forming compound takes place. The remaining color coupler still available at the non-exposed areas of the material couples oxidatively with the oxidation product of the compound thus formed whereby the colored mask is formed. Subsequently, the photographic color material is Washed with water, fixed and dried.
The following aromatic amino-compounds can be used as developers for such material: mono, diand triaminoaryl compounds, more especially N,N-dialkyl-p-phenylenediamines, such as N,N-diethyl-p-phenylenediamine and N,N-diethyl-Z-methyl-p-phenylene diamine, and derivatives thereof such as N,N-dialkyl-N-sulphomethylor carboXymethyl-p-phenylenediamine. As useful monoamino-developers should be cited: aminophenols and amino-cresols or their halogen derivatives and also the amino-naphthols.
The bleaching bath generally contains potassium bromide, borax, magnesium sulphate and especially potassium ferricyanide. These elements are dissolved in precisely determined amounts of water so that a solution with a determined pH value is obtained.
The following examples illustrate the invention without limiting, however, the scope thereof.
I Example 1 To /2 kg. of red-sensitive bromoiodide emulsion (2% iodide) containing mol of silver halide are added g. of N (6'-cetylsulfonylphenyl)-1-hydroxy-2-naphthoic acid amide-3-sodium sulfonate dissolved in 193 cm. of water and 7 cm. of aqueous sodium hydroxide 2 N and 10 g. of 2,6-di-tert-4-chlorobutylphenol dissolved in 100 cm. of ethyleneglycolmonomethylether. After acidification to pH 6 the usual additives such as hardeners, wetting agents and stabilizers and the necessary quantity of distilled water are added to the emulsion in order to obtain 1 kg. of emulsion ready for coating. The emulsion is coated on a suitable support and dried. After exposure through a grey wedge with a constant 0.15, the photographic material composed in this way is developed for 9 min. at C. in a color-developing bath with the following composition:
Water to 1000 cm. (pH-=10.6).
This material is rinsed for 30 minutes at 18 to 20 C. and fixed for 5 minutes at 20 C. in a fixing bath of the following composition:
G. Sodium thiosulphate 200 Sodium 'bisulphite Potassium alum 20 Sodium biacetate 20 Boric acid u 7.5
Water to 1000 cm? (pH- 4.0).
Next, the material is rinsed again for 10 minutes at 18 to 20 C. and treated for 5 minutes in a bleaching bath of the following composition:
Potassium ferricyanide 100 Potassium bromide 15 Borax 2O Magnesium sulphate 50 Water to 1000 cm. (pH=8.6).
Then the material is rinsed again for 10 min. at 18 to 20 C. and fixed for 5 min. at 20 C. in a bath of the following composition:
, G. Sodium thiosulphate- 130 Borax 20 Magnesium sulphate 50 Water to 1000 cm. (pH=8.9).
Rinsing is continued for another 10 min. at 18 to 20 and finally the material is dried. In the exposed and proc- 'essed strip, besides a cyan image also a yellow-colored mask image is formed, with a gradation opposed to that of the cyan image, and which compensates the side absorption of the cyan image in the blue.
Example 2 To a /2 kg. of red-sensitive 'bromo-iodide emulsion (2% iodide) containing ,4; mol of silver halide are added 10 g. of N (6' cetylsulfonylphenyl) 1 hydroxy-Z- naphthoic acid amide-3'-sodium sulfonate dissolved in 193 cm. of water and 7 cm. of an aqueous solution of sodium hydroxide 2 N and 10 g. of bis-(3,5-di-tert-butyl-4- hydroxyphenyl)-methane dissolved in cm. of ethyleueglycol monomethylether. After acidification to pH 6 and after addition of the usual additives such as hardeners, wetting agents, and stabilizers and the necessary quantity of distilled water to obtain 1 kg. emulsion, the emulsion is coated on a suitable suport and dried. After a further treatment according to Example 1, a cyan image is obtained wherein the disturbing influence of the sideabsorption in the blue is reduced by the formed yellow masking image with opposite gradation to the cyan image.
Example 3 To a /2 kg. of red-sensitive bromo-iodide emulsion (2% iodide) containing mol of silver halide are added 10 g. of N-(6-cetylsulfonylphenyl)-1-hydroxy-2-naphthoic acid amide-3-sodium sulfonate dissolved in 193 cm. of water and 7 cm. of an aqueous solution of sodium hydroxide 2 N and 10 g. of 2,6-di-tert-butylphenol- 4 carboxylic acid dissolved in 100 cm. of ethyleneglycol monomethylether. After acidification to pH 6 and after addition of the usual additives such as hardeners, wetting agents and stabilizers and the necessary quantity of distilled water to obtain 1 kg. emulsion, the emulsion is coated on a suitable support and dried. After a further treatment according to Example 1, a cyan image is obtained wherein the disturbing influence of the side-absorption in the blue is reduced by the formed yellow masking image with opposite gradation to the cyan image.
Example 4 To a /2 kg. of red-sensitive bromo-iodide emulsion (2% iodide) containing mol of silver halide are added 10 g. of N-(6-cetylsulfonylphenyl)-1-hydroxy-2-naphthoic acid amide-3-sodium sulfonate dissolved in 193 cm. of water and 7 cm. of an aqueous solution of sodium hydroxide 2 N and 10 g. of 2,6-di-tert-butyl-4- bromo-phenol dissolved in 100 cm. of ethyleneglycol monomethylether. After acidification to pH 6 and after addition of the usual additives such as hardeners, wetting agents and stabilizers and the necessary quantity of distilled water to obtain 1 kg. emulsion, the emulsion is coated on a suitable support and dried. After a further treatment according to Example 1, a cyan image is obtained wherein the disturbing influence of the side-absorption in the blue is reduced by the formed yellow masking image with opposite gradation to the cyan image.
To a /2 kg. of red-sensitive silver bromo-iodide emulsion (2% iodide) containing mol of silver halide aIe added 10 g. of N-(6cetylsulfonylphenyl)-l-hydroxy-2- naphthoic acid amide-3'-sodium sulfonate dissolved in 193 cm. of water and 7 cm. of an aqueous solution of sodium hydroxide 2 N and 10 g. of 2,6-di-tert-butyl-4- chlorophenol dissolved in 100 cm. of ethyleneglycolmonomethyl ether. After acidification to pH 6, the usual additives such as hardeners, wetting agents and stabilizers and the necessary quantity of distilled water are added to the emulsion in order to obtain 1 kg. of emulsion ready to be coated. After coating this emulsion forms part of a multilayer photographic material consisting of the following superposed layers in the indicated sequence: a support, an antihalation layer, a gelatin insulating layer, the above-mentioned red-sensitive emulsion layer with color coupler for cyan, a gelatin interlayer, a green-sensitive emulsion layer, a yellow filter layer, a blue-sensitive emulsion layer with color coupler for yellow and at last a gelatin overcoat as antistress layer. After exposure through a grey wedge with a constant 0.15 the photographic material is developed and further treated as in Example 1. A mainly cyan-colored image is obtained together with a yellow dye image in the red-sensitive layer, said yellow image being of opposite gradation in respect of the cyan dye image and reducing the disturbing influence of the side-absorption in the blue in the formed cyan image.
Example 6 To /2 kg. of a red-sensitive bromo-iodide emulsion (2% iodide) containing mol of silver halide are added 9 g. of N-(6'-cetylsulfonylphenyl)-1-hydroxy-2-naphthoic acid amide-3'-sodium sulfonate dissolved in a mixture of 175 cm? of Water and 6.3 cm. of an aqueous solution of sodium hydroxide 2 N, 2 g. of 1,2-dimethyl- 4-amino-5-nonylpyrazolone-3 dissolved in 20 cm. of ethanol with a little sodium hydroxide and 2 g. of 2,6-ditert-butyl-4-chlorophenol dissolved in 20 cm? of ethyleneglycolmonomethylether. After acidification with acetic acid to pH 6 and after addition of the usual additives such as hardeners, wetting agents and stabilizers and the necessary quantity of water, one obtains 1 kg. emulsion ready to be coated. After coating, this emulsion forms part of a multilayer photographic material consisting of the following superposed layers in the indicated sequence: a support, an antihalation layer, a gelatin insulating layer, the above-mentioned red-sensitive emulsion layer with color coupler for cyan, a gelatin interlayer, a green-sensitive emulsion layer, a yellow filter layer, a blue-sensitive emulsion layer with color coupler for yellow and at last a gelatin overcoat as antistress layer. After exposure through a grey wedge with a constant 0.15 the photographic material is developed and further treated as in Example 1. In the red-sensitive layer of both materials, besides a cyan image, also a yellow colored as well as a magenta colored mask image are formed, which images compensate the side absorptions of the cyan image in the blue and in the green part of the spectrum.
TABLE Prepara- H tion: (3H3 l CH3 1 CH (I JCH CH CH3 Br (EH (EH CH3'CCHa CH3(|3CH;
CHa-Cfi-CH: GH3(|]-CH3 em on:
COOH $113 I CH3 3 .l CH C CCH:
CH3 CH3 I OH OH (3H3 ([3113 4 CHa-([3 (|3CHa CH3 CH OH (3H3 l 1 5 CH3[C- (])CH3 CH CH3 TABLE Qontlnued Preparatron CH2CH2 /CH2C: 6 CH2 CH OH CH? We claim:
1. A method of forming a color corrected image in a photographic element having at least one silver halide emulsion layer containing a color coupler of the formula:
([311 XD we O-NH- wherein:
group, a CONH group, a -SO -NH- group, a -NHSO group, a N-alky1 group and a sulfonyl group;
Y represents a member selected from the group consisting of an hydrogen atom and a halogen atom;
D represents an aliphatic radical comprising a linear chain of at least 5 and at most 20 carbon atoms;
M represents a member selected from the group consisting of an hydrogen atom, an alkali metal atom and an ammonium group,
and which is reactive with the oxidation product of an aromatic amino developing agent to form by color development a cyan dye image which absorbs a major pro portion of light in the red region of the visible spectrum, and undesirably absorbs a minor proportion of light in at least one other region of the visible spectrum, which method comprises treating said photographic element, after image-wise exposure and color development, with an oxidizing solution in the presence of a mask forming compound of the formula:
SOaM
a wherein:
R and R each represents a sterically hindering group selected from the group consisting of tert-butyl, cyclohexyl and phenyl;
R represents a member selected from the group consisting of a hydrogen atom, a halogen atom and a radical which is sufficiently unstable for splitting oil on treatment of said mask forming compound with an oxidizing solution in the presence of said color coupler.
2. Method of forming a color corrected image according to claim 1 wherein the mask forming compound is incorporated in the photographic element, and the oxidizing solution is a photographic bleaching bath.
3. Method of forming a color corrected image in a 9 photographic element having superposed silver halide emulsion layers sensitive to difierent regions of the visible spectrum, at least one of said layers containing a color coupler of the formula:
I l @CO-NHQ SOsM wherein:
X represents a member selected from the group consisting of an oxygen atom, a sulfur atom, a
group, a -CO--NH group, a -SO NH group, a -NH-SO group, a -N-alky-l group and a sulfonyl group;
Y represents a member selected from the group consisting of an hydrogen atom and a halogen atom;
L' D represents an aliphatic radical comprising a linear chain of at least 5 and at most 20 carbon atoms;
M represents a member selected from the group consisting of an hydrogen atom, an alkali metal atom and an ammonium group,
and which is reactive with the oxidation product of an aromatic amino developing agent to form by color development a cyan dye image which absorbs a major proq portion of light in the red region of the visible spectrum and undesirably absorbs a minor proportion of light in the green and blue regions of the spectrum, said photographic element containing a mask forming compound of the formula:
wherein:
R and R each represents a sterically hindering group selected from the group consisting of tert-butyl, cyclohexyl and phenyl;
R represents a member selected from the group consisting of a hydrogen atom, a halogen atom and a radical which is sufliciently unstable for splitting 01f on treatment of said mask forming compound with an oxidizing solution in the presence of said color coupler;
said color coupler being also reactive with the oxidation products of said mask forming compounds to form a magenta to red colored dve image and a yellow to orange colored dye image said dye images having a gradation opposite to that of said cyan dye image, and transmitting substantially all the light in the red region of the spectrum, said magenta to red colored dye image absorbing light in the green region of the spectrum, and said yellow to orange colored dye image absorbing light in the blue region of the spectrum, which method comprises exposing said layers to light, developing at least said layer containing said color coupler, by color development with an aromatic amino developing agent, whereby said cyan dye image is formed in the developed areas by coupling, leaving in the undeveloped areas of said one layer residual color coupler, and treating at least said layer containing said residual color coupler, and said mask forming compounds, with a bleaching bath, said treatment resulting in the oxidation of said mask forming compounds, whereby said magenta to red colored dye image and said yellow to orange colored dye image is formed by coupling said oxidized mask-forming compounds with said residual color coupler.
4. Method of forming a color corrected image according to claim 3, wherein said mask-forming compounds are contained in at least said one layer containing said color coupler.
5. Photographic element having superposed silver halide emulsion layers sensitive to difierent regions of the visible spectrum, at least one of said layers containing a color coupler of the formula:
X represents a member selected from the group consisting of an oxygen atom, a sulfur atom, a
group, a -CONH group, a -SO NH- group, a -NHSO group, a -N-alkyl group and a sulfonyl group;
Y represents a member selected from the group consisting of an hydrogen atom and a halogen atom;
D represents an aliphatic radical comprising a linear chain of at least 5 and at most 20 carbon atoms;
M represents a member selected from the group consisting of an hydrogen atom, an alkali metal atom and an ammonium group,
and which is reactive with the oxidation product of an aromatic amino developing agent to form by color development a cyan image which absorbs a major proportion of light in the red region of the visible spectrum, and undesirably absorbs a minor proportion of light in at least one other region of the visible spectrum, and containing a mask forming compound of the formula:
wherein:
R and R each represents a sterically hindering group selected from the group consisting of tert-butyl, cyclohexyl and phenyl;
R represents a member selected from the group consisting of a hydrogen atom, a halogen atom and a radical which is sufficiently unstable for splitting ofl on treatment of said mask forming compound with an oxidizing solution in the presence of said color coupler,
said color coupler being also reactive with the oxidation product of said mask-forming compound to form a secondary dye image having a gradation opposite to that of said cyan dye image, and absorbing light in at least one of said unwanted minor absorption regions but transmittingsubstantially all the light in the red absorption region of the spectrum.
6. Photographic element having superposed silver halide emulsion layers sensitive to diiterent regions of the visible spectrum, at vleast one of said layers containing a color coupler of the formula:
on air-1) wherein:
X represents a member selected from the group consiting of an oxygen :atom, a sulfur atom, a NHCO-- group, a CO-NH group, a SO NH group, a NHSO group, a N-alkyl group and a sulfonyl group;
Y represents a member selected from the group consisting of an hydrogen atom and a halogen atom;
D represents an aliphatic radical comprising a linear chain of at least 5 and at most carbon atoms;
M represents a member selected from the group consisting of an hydrogen atom, an alkali metal atom and an ammonium group,
and which is reactive with the oxidation product of an aromatic amino developing agent to form by color development a cyan image which absorbs a major proportion of light in the red region of the visibile spectrum, and undesirably absorbs a minor proportion of light in the green and blue regions of the visible spectrum, and containing a mask forming compound of the formula 12 wherein:
R and R each represents a sterically hindering group selected from the group consisting of tert-butyl, cyclohexyl and phenyl;
R represents a member selected from the group consisting of a hydrogen atom, a halogen atom and a radical which is sufficiently unstable for splitting olt on treatment of said mask forming compound with an oxidizing solution in the presence of said color coupler,
and containing a mask-forming compound of the formula:
H,N-O C=0 wherein:
R represents a lower alkyl group;
R represents a member selected from the group con sis-ting of a lower alkyl group and an aryl group of the benzene series, and a substituted aryl group p of the benzene series;
R represents an aliphatic radical comprising a linear chain of at least 5 and at most 20 carbon atoms;
said color coupler being also reactive with the oxidation products of said mask forming compounds to form a yellow to orange colored dye image and a magenta to red colored dye image, said dye images having a gradation opposite to that of said cyan image, and transmitting substantially all the light in the red region of the spectrum, said magneta to red colored dye image absorbing light in the green region of the spectrum, and said yellow to orange colored dye image absorbing light in the blue region of the spectrum.
No references cited.
Claims (1)
1. A METHOD OF FORMING A COLOR CORRECTED IMAGE IN A PHOTOGRAPHIC ELEMENT HAVING AT LEAST ONE SILVER HALIDE EMULSION LAYER CONTAINING A COLOR COUPLER OF THE FORMULA:
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB40580/59A GB975940A (en) | 1959-11-30 | 1959-11-30 | Improvements in or relating to the production of colour photographic images |
Publications (1)
Publication Number | Publication Date |
---|---|
US3047385A true US3047385A (en) | 1962-07-31 |
Family
ID=10415602
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US72298A Expired - Lifetime US3047385A (en) | 1959-11-30 | 1960-11-29 | Production of color photographic images |
Country Status (3)
Country | Link |
---|---|
US (1) | US3047385A (en) |
DE (1) | DE1140455B (en) |
GB (1) | GB975940A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3186843A (en) * | 1962-04-27 | 1965-06-01 | Polaroid Corp | Photographic developer containing hindered phenols |
US3245788A (en) * | 1959-11-13 | 1966-04-12 | Gevaert Photo Prod Nv | Production of color photographic images |
US3293032A (en) * | 1961-08-02 | 1966-12-20 | Gevaert Photo Prod Nv | Process for the preparation of colour images |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1282458B (en) * | 1964-10-03 | 1968-11-07 | Wolfen Filmfab Veb | Process for producing color corrected color photographic images |
US5508140A (en) * | 1994-12-21 | 1996-04-16 | Eastman Kodak Company | Toners and developers containing quaternary phosphonium 3,5-Di-tertiary-alkyl-4-hydroxybenzenesulfonates as charge-control agents |
US5491044A (en) * | 1994-12-21 | 1996-02-13 | Eastman Kodak Company | Toners and developers containing quaternary ammonium 3,5-di-tertiary-alkyl-4-hydroxybezenesulfonate salts as charge-control agents |
US7772097B2 (en) | 2007-11-05 | 2010-08-10 | Asm America, Inc. | Methods of selectively depositing silicon-containing films |
-
1959
- 1959-11-30 GB GB40580/59A patent/GB975940A/en not_active Expired
-
1960
- 1960-11-29 US US72298A patent/US3047385A/en not_active Expired - Lifetime
- 1960-11-29 DE DEG31033A patent/DE1140455B/en active Pending
Non-Patent Citations (1)
Title |
---|
None * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3245788A (en) * | 1959-11-13 | 1966-04-12 | Gevaert Photo Prod Nv | Production of color photographic images |
US3245787A (en) * | 1959-11-13 | 1966-04-12 | Gevaert Photo Prod Nv | Production of color photographic images |
US3293032A (en) * | 1961-08-02 | 1966-12-20 | Gevaert Photo Prod Nv | Process for the preparation of colour images |
US3186843A (en) * | 1962-04-27 | 1965-06-01 | Polaroid Corp | Photographic developer containing hindered phenols |
Also Published As
Publication number | Publication date |
---|---|
GB975940A (en) | 1964-11-25 |
DE1140455B (en) | 1962-11-29 |
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