US3036906A - Apparatus for gasification of finely-divided fuels - Google Patents

Apparatus for gasification of finely-divided fuels Download PDF

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US3036906A
US3036906A US797736A US79773659A US3036906A US 3036906 A US3036906 A US 3036906A US 797736 A US797736 A US 797736A US 79773659 A US79773659 A US 79773659A US 3036906 A US3036906 A US 3036906A
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burner
gas collecting
chamber structure
gasification
space
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US797736A
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Zellerhoff Bruno
Klapp Arnold
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Beazer East Inc
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Koppers Co Inc
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/50Fuel charging devices
    • C10J3/506Fuel charging devices for entrained flow gasifiers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/093Coal
    • C10J2300/0936Coal fines for producing producer gas

Definitions

  • reaction space chamber and the gas collecting space chamber were constructed as one separate structural unit, namely the actual reaction space chamber was rigidly connected with the gas collecting space chamber and took part in the latters motion as stipulated by the expansion due to heat.
  • This single structure arrangement was selected since it was considered that the gas tightness of the entire apparatus would be achieved by a metal jacket enclosing all parts.
  • the apparatus conforming to the present invention consists in connecting the reaction space structure on one side rigidly with the supply lines for the reaction media and connecting the reaction space structure on the other side with the gas collecting space structure in a gastight but otherwise unrigid manner by an expansion joint structure, so that the gas collecting space and its structure can follow the motion stipulated by its expansion due to heat in contrast with the reaction space and its structure which is immovably arranged during the operation.
  • a section of a gasification apparatus is illustrated in the drawing by which the invention is explained in more detail.
  • the illustrated apparatus is designed for gasification of finely-divided fuel but there is no change in the basic structure when hydrocarbon oil, for example, is to be gasified instead of solid fuel. Only the construction of the burner located outside of the reaction space must be adapted to the particular fuel.
  • the entire gasification apparatus consists of the socalled burner head or reaction chamber structure 1 and the gas collecting space chamber structure 2.
  • the burner head itself is formed by fireproof masonry 3 in which is located an opening 4 which is conically widened toward the gas collecting space 2 of the gas collecting chamber structure 6.
  • This opening 4 is the actual reaction space in which the reaction between the fuel and gasification media takes place.
  • a water cooling jacket 5 is provided to regulate the temperature of the fireproof masonry 3.
  • the gas collecting space 2 is also surrounded by fireproof masonry chamber structure 6 which is covered by a water jacket 7.
  • the actual burner 8 also forms part of the burner head 1.
  • this consists of a worm 9 which conveys the finely-divided solid fuel in the direction toward reaction space 4.
  • Oxygen is supplied under a slightly increased pressure through the hollow shaft 10 of worm 9.
  • A' gastight packing consisting of the powdered fuel to be gasified is formed between the hollow shaft 10 and the outer wall 11 of the worm by the special conical structure of the mouthpiece of the burner, so that oxygen or other gases can not flow backward through the worm.
  • the oxygen draws the fuel from the annular packing and forms a homogeneous mixture with it.
  • the endotherrnically reacting gasification media is supplied through annular line 12 and is introduced in the reaction space 4 in such a direction that it surrounds the central zone of exothermic reaction between fuel and oxygen with an envelope moving in the same direction, which especially protects the fireproof masonry 3 from an excessive heat stress and also enters in reaction with the glowing ungasified fuel.
  • the reaction space 4 is supported on a bracket 13 and is moreover rigidly connected with the supply lines 8 of the reaction media.
  • the gas collecting chamber structure for space 2 is supported, on a place not illustrated in the drawing, so that it can follow the motions which are caused by the expansion due to heat.
  • male and female expansion joint members with a stufiing box seal 14 which permits a relative motion of the reaction space structure 4 and the gas collecting space 2 structure in relation to one another and also stops the escape of gas.
  • the stufiing box seal is arranged in a vicinity in which no high temperatures prevail, so that a gastight operation of this seal 14 is assured.
  • burner heads 1 of the described type are connected to gas-collecting space 2
  • these burner heads are advantageously rigidly connected with one another, and the type of connection is determined by the special form of the gas collecting space.
  • the supply line 8 of the reaction media is disconnected at any optional place and then the entire burner head can be withdrawn from the structure of gas collecting space 2.
  • Apparatus for gasification of finely-divided fuels in suspension in oxygen comprising: a burner nozzle rigidly connected with a burner chamber structure for injection of a mixture of fuel and gasification media into a reaction space in the burner chamber structure, said burner chamber having inner tapered walls to provide a reaction space conically widened in the direction of flow of the mixture; and a separate gas collecting chamber structure providing a gas collecting space in communication with said widened part of the burner chamber to receive the gases discharged therefrom, for discharge of the produced gas at the top and of the gasification residue separated therein at the bottom of the gas collecting space; characterized by, supply lines for introduction of the reaction media to the burner nozzle and rigidly connected to the burner nozzle, and a gas-tight expansion joint structure between the burner chamber structure and the gas collecting chamber structure, whereby the gas collecting chamber structure can follow the motions stipulated by its expansion due to heat in contrast with the rigid burner chamber structure which is immovably arranged during operation thereof.

Description

FUELS May 29, 1962 B. ZELLERHOFF ETAL APPARATUS FOR GASIFICATION OF FINELY-DIVIDED Filed March 6, 1959 INVENTORS. swA/aao KLAPP, 1m! azwvo 2544 EEHOF.
United States Patent 3,036,906 Patented May 29, 1962 3,036,906 APPARATUS FOR GASIFICATION OF FINELY-DIVIDED FUELS Bruno Zellerhofi', Essen-Warden, and Arnold Klapp, Essen, Germany, assignors, by mesne assignments, to Koppers Company, Inc., Pittsburgh, Pa., a corporation of Delaware Filed Mar. 6, 1959, Ser. No. 797,736 2 Claims. (Cl. 48-63) The present invention relates to an apparatus for gasification of finely-divided fuels in suspension in oxygen and, if desired, endotherrnically reacting gasification media, and is an improvement continuing-in-part common subject matter of Friedrich Totzek application No. 476,- 453, filed December 20, 1954, now US. Patent 2,898,204, for Process for Production of Combustible Gases, allowed November 21, 1958, which is owned by a common assignee and successively continues common subject matter of the assignees Totzek application Serial No. 297,- 965, filed July 9, 1952, now US. Patent 2,920,945, and through said application the common subject matter of the assignees Patents :Nos. 2,702,744; 2,702,743; 2,670,- 820, and the parent Totzek application Serial No. 43,950, filed August 12, 1948, and now abandoned.
Both solid fuels in powdered form as well as liquid fuels in vaporous form or in atomized form are considered as fuels. Steam or carbon dioxide or a mixture of both of these materials can be used as endothermically reacting media. Both pure oxygen as well as oxygen-enriched air are considered as oxygen in the scope of the present invention.
In such gasification apparatus it is known that a mixture of fuel and gasification media is injected through a burner-like nozzle into a burner chamber which has a reaction space which is conically widened in the direction of flow of the mixture. This reaction space (if desired several of them) discharges in a gas collecting chamber structure providing a gas collecting space from which the produced gas is discharged at the top and the separated gasification residue is discharged at the bottom.
Up to now the reaction space chamber and the gas collecting space chamber were constructed as one separate structural unit, namely the actual reaction space chamber was rigidly connected with the gas collecting space chamber and took part in the latters motion as stipulated by the expansion due to heat. This single structure arrangement was selected since it was considered that the gas tightness of the entire apparatus would be achieved by a metal jacket enclosing all parts.
The rigid connection of the reaction space structure with gas collecting space structure made it necessary to connect the supply lines of the reaction media to the burner nozzle with flexible passage means. Apart from the fact that certain operating difliculties result therefrom, the known apparatus had the inconvenience that extensive dismantling operations were frequently necessary for changing or repairing the reaction space chamber structure which was subject to the greatest stresses.
These diificulties are overcome by the present invention. The apparatus conforming to the present invention consists in connecting the reaction space structure on one side rigidly with the supply lines for the reaction media and connecting the reaction space structure on the other side with the gas collecting space structure in a gastight but otherwise unrigid manner by an expansion joint structure, so that the gas collecting space and its structure can follow the motion stipulated by its expansion due to heat in contrast with the reaction space and its structure which is immovably arranged during the operation.
A section of a gasification apparatus is illustrated in the drawing by which the invention is explained in more detail. The illustrated apparatus is designed for gasification of finely-divided fuel but there is no change in the basic structure when hydrocarbon oil, for example, is to be gasified instead of solid fuel. Only the construction of the burner located outside of the reaction space must be adapted to the particular fuel.
The entire gasification apparatus consists of the socalled burner head or reaction chamber structure 1 and the gas collecting space chamber structure 2. The burner head itself is formed by fireproof masonry 3 in which is located an opening 4 which is conically widened toward the gas collecting space 2 of the gas collecting chamber structure 6. This opening 4 is the actual reaction space in which the reaction between the fuel and gasification media takes place. A water cooling jacket 5 is provided to regulate the temperature of the fireproof masonry 3.
The gas collecting space 2 is also surrounded by fireproof masonry chamber structure 6 which is covered by a water jacket 7. The actual burner 8 also forms part of the burner head 1. In the present case this consists of a worm 9 which conveys the finely-divided solid fuel in the direction toward reaction space 4. Oxygen is supplied under a slightly increased pressure through the hollow shaft 10 of worm 9. A' gastight packing consisting of the powdered fuel to be gasified is formed between the hollow shaft 10 and the outer wall 11 of the worm by the special conical structure of the mouthpiece of the burner, so that oxygen or other gases can not flow backward through the worm. By exit of the oxygen from the hollow shaft 10, the oxygen draws the fuel from the annular packing and forms a homogeneous mixture with it. This mixture is immediately ignited on entering the reaction space 4 in which a high temperature prevails. The endotherrnically reacting gasification media is supplied through annular line 12 and is introduced in the reaction space 4 in such a direction that it surrounds the central zone of exothermic reaction between fuel and oxygen with an envelope moving in the same direction, which especially protects the fireproof masonry 3 from an excessive heat stress and also enters in reaction with the glowing ungasified fuel. The reaction space 4 is supported on a bracket 13 and is moreover rigidly connected with the supply lines 8 of the reaction media. The gas collecting chamber structure for space 2 is supported, on a place not illustrated in the drawing, so that it can follow the motions which are caused by the expansion due to heat. In order to achieve a gastightness between reaction space 4, on the one hand, and the gas-collecting space 2 on the other hand, there is provided male and female expansion joint members with a stufiing box seal 14 which permits a relative motion of the reaction space structure 4 and the gas collecting space 2 structure in relation to one another and also stops the escape of gas. The stufiing box seal is arranged in a vicinity in which no high temperatures prevail, so that a gastight operation of this seal 14 is assured.
When several burner heads 1 of the described type are connected to gas-collecting space 2, these burner heads are advantageously rigidly connected with one another, and the type of connection is determined by the special form of the gas collecting space.
If an exchange of burner head 1 is necessary, the supply line 8 of the reaction media is disconnected at any optional place and then the entire burner head can be withdrawn from the structure of gas collecting space 2.
We claim:
1. Apparatus for gasification of finely-divided fuels in suspension in oxygen, comprising: a burner nozzle rigidly connected with a burner chamber structure for injection of a mixture of fuel and gasification media into a reaction space in the burner chamber structure, said burner chamber having inner tapered walls to provide a reaction space conically widened in the direction of flow of the mixture; and a separate gas collecting chamber structure providing a gas collecting space in communication with said widened part of the burner chamber to receive the gases discharged therefrom, for discharge of the produced gas at the top and of the gasification residue separated therein at the bottom of the gas collecting space; characterized by, supply lines for introduction of the reaction media to the burner nozzle and rigidly connected to the burner nozzle, and a gas-tight expansion joint structure between the burner chamber structure and the gas collecting chamber structure, whereby the gas collecting chamber structure can follow the motions stipulated by its expansion due to heat in contrast with the rigid burner chamber structure which is immovably arranged during operation thereof.
2. Apparatus as claimed in claim 1, and in which the expansion joint is constituted of rnale and a female expansion joint members with a stutfing box seal between the reaction chamber structure and the gas collecting chamber structure for sealing the gasification apparatus.
References Cited in the file of this patent UNITED STATES PATENTS 1,793,849 Groninger Feb. 24, 1931 2,085,584 Haskell June 29, 1937 2,385,508 Hammond Sept. 25, 1945 2,468,318 Young et al. Apr. 26, 1949 2,777,813 Totzek Jan. 15, 1957 2,873,172 Leslie et al Feb. 10, 1959 2,924,269 Genovese Feb. 9, 1960 2,976,128 Latham et a1. Mar. 21, 1961

Claims (1)

1. APPARATUS FOR GASIFICATION OF FINELY-DIVIDED FUELS IN SUSPENSION IN OXYGEN, COMPRISING: A BURNER NOZZLE RIGIDLY CONNECTD WITH A BURNER CHAMBER STRUCTURE FOR INJECTION OF A MIXTURE OF FUEL AND GASIFICATION MEDIA INTO A REACTION SPACE IN THE BURNER CHAMBER STRUCTURE, SAID BURNER CHAMBER HAVING INNER TAPERED WALLS TO PROVIDE A REACTION SPACE CONICALLY WIDENED IN THE DIRECTION OF FLOW OF THE MIXTURE; AND A SEPARATE GAS COLLECTING CHAMBER STRUCTURE PROVIDING A GAS COLLECTING SPACE IN COMMUNICATION WITH SAID WIDENED PART OF THE BURNER CHAMBER TO RECEIVE THE GASES DISSCHARGED THEREFROM, FOR DISCHARGE OF THE PRODUCED GAS AT THE TOP AND OF THE GASIFICATION REDISUE SEPARATED THEREIN AT THE BOTTOM OF THE GAS COLLECTING SPACE; CHARACTERIZED BY SUPPLY LINES FOR INTRODUCTION OF THE REACTION MEDIA TO THE BURNER NOZZLE AND RIGIDLY CONNECTED TO THE BURNER NOZZLE, AND A GAS-TIGHT EXPANSION JOINT STRUCTURE BETWEEN THE BURNER CHAMBER STRUCTURE AND THE GAS COLLECTING CHAMBER STRUCTURE, WHEREBY THE GAS COLLECTING CHAMBER STRUCTURE CAN FOLLOW THE MOTIONS STIPULATED BY ITS EXPANSION DUE TO HEAT IN CONTRAST WITH THE RIGID BURNER CHAMBER STRUCTURE WHICH IS IMMOVABLY ARRANGED DURING OPERATION THEREOF,
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4209304A (en) * 1978-06-30 1980-06-24 Texaco Inc. Coal gasification-method of feeding dry coal
US4218222A (en) * 1978-09-07 1980-08-19 Texaco Inc. Method of charging solids into coal gasification reactor
US4302353A (en) * 1977-05-11 1981-11-24 Veba Oel Ag Method for the production of synthesis gas

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1793849A (en) * 1929-10-15 1931-02-24 Holmes B Groninger Tuyere for blast furnaces
US2085584A (en) * 1934-04-11 1937-06-29 Gen Electric Apparatus for producing a gas atmosphere
US2385508A (en) * 1943-10-23 1945-09-25 Blaw Knox Co Combustion of coal
US2468318A (en) * 1947-10-23 1949-04-26 Young James Kean Rotary retort
US2777813A (en) * 1951-05-25 1957-01-15 Koppers Co Inc Apparatus for the performance of endothermic reactions between solid and gaseous media
US2873172A (en) * 1955-11-23 1959-02-10 Phillips Petroleum Co Process and apparatus for making carbon black and quenching smoke from carbon black furnaces
US2924269A (en) * 1956-10-01 1960-02-09 United States Steel Corp Blast furnace stove gas-port and burner nozzle connection
US2976128A (en) * 1959-01-28 1961-03-21 Continental Carbon Co Apparatus for making carbon black

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1793849A (en) * 1929-10-15 1931-02-24 Holmes B Groninger Tuyere for blast furnaces
US2085584A (en) * 1934-04-11 1937-06-29 Gen Electric Apparatus for producing a gas atmosphere
US2385508A (en) * 1943-10-23 1945-09-25 Blaw Knox Co Combustion of coal
US2468318A (en) * 1947-10-23 1949-04-26 Young James Kean Rotary retort
US2777813A (en) * 1951-05-25 1957-01-15 Koppers Co Inc Apparatus for the performance of endothermic reactions between solid and gaseous media
US2873172A (en) * 1955-11-23 1959-02-10 Phillips Petroleum Co Process and apparatus for making carbon black and quenching smoke from carbon black furnaces
US2924269A (en) * 1956-10-01 1960-02-09 United States Steel Corp Blast furnace stove gas-port and burner nozzle connection
US2976128A (en) * 1959-01-28 1961-03-21 Continental Carbon Co Apparatus for making carbon black

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4302353A (en) * 1977-05-11 1981-11-24 Veba Oel Ag Method for the production of synthesis gas
US4209304A (en) * 1978-06-30 1980-06-24 Texaco Inc. Coal gasification-method of feeding dry coal
US4218222A (en) * 1978-09-07 1980-08-19 Texaco Inc. Method of charging solids into coal gasification reactor

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