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US3032102A - In situ combustion method - Google Patents

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US3032102A
US3032102A US72171058A US3032102A US 3032102 A US3032102 A US 3032102A US 72171058 A US72171058 A US 72171058A US 3032102 A US3032102 A US 3032102A
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stratum
air
concentration
flow
ignition
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Harry W Parker
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ConocoPhillips Co
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ConocoPhillips Co
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    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B43/00Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
    • E21B43/16Enhanced recovery methods for obtaining hydrocarbons
    • E21B43/24Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
    • E21B43/243Combustion in situ

Description

y 1, 1962 H. w. PARKER 3,032,102

IN SITU COMBUSTION METHOD Filed March 1?, 195a AUTOMATIC KCONTROLLER AIR AIR

OVERBURDEN NO AIR FLOW FIG. 3

l o 40 so I20 I40 TIME (MIN) FIG. 2

e. INVENTOR.

H.W. PARKER BY A ATTORNEYS rates This invention relates to an improved process for initiating in situ combustion in a carbonaceous stratum.

In situ combustion in the recovery of hydrocarbons from underground strata containing carbonaceous material is becoming more prevalent in the petroleum industry. In this technique of production, combustion is initiated in the carbonaceous stratum and the resulting combustion zone is caused to move thru the stratum by either inverse or direct air drive whereby the heat of combustion of a substantial proportion of the hydrocarbon in the stratum drives out and usually upgrades a substantial proportion of the remaining hydrocarbon material.

The ignition of carbonaceous material in a stratum around a borehole therein followed by injection of air thru the ignition borehole and recovery of product hydrocarbons and combustion gas thru another borehole in the stratum is a direct air drive process for effecting in situ combustion and recovery of hydrocarbons from the stratum. In this type of operation the stratum usually plugs in front of the combustion zone because a heavy viscous fluid bank collects in the stratum in advance of the combustion zone which prevents movement of air to the combustion process. To overcome this difliculty and permit the continued progress of the combustion zone thru the stratum, inverse air injection has been resorted to. By this technique, a combustion zone is established around an ignition borehole by any suitable means and air is fed thru the stratum to the combustion zone from one or more surrounding boreholes.

In operating With either direct or indirect air injection to produce hydrocarbons from a carbonaceous stratum by in situ combustion, it is necessary to first ignite the carbonaceous material in the stratum around a borehole therein. One method of ignition utilizes a downhole heater of either the electric or gas fired type to heat the wall of the ignition borehole and an annular section of the stratum surrounding the borehole. Another technique comprises placing charcoal in the ignition borehole adjacent the stratum to be ignited and burning the charcoal therein by igniting same while feeding O -cOntaining gas thereto. In any of these processes for igniting the carbonaceous stratum, a long preheating period is necessary to bring the temperature thereof up to ignition temperature, which is usually in the range of about 550 to 700 F. when contacting the hot stratum with air as the O containing gas. This invention is concerned with a method whereby the preheating period is substantially reduced.

Accordingly, the principal object of the invention is to provide an improved process for initiating combustion in a carbonaceous stratum. Another object is to reduce the preheating period required prior to the ignition of a carbonaceous stratum. A further object is to provide an improved method of controlling the ignition of a carbonaceous stratum to be produced by in situ combustion. Other objects of the invention will become apparent upon consideration of the accompanying disclosure.

A broad aspect of the invention comprises heating a section of a stratum containing combustible carbonaceous material to bring the same to ignition temperature and, while preheating said section, contacting the same with a stream of O -containing gas under controlled flow conditions.

'Air or other o -containing gas is passed to the section of stratum being heated during the heating step, at a slow rate during the initial phases of the preheating and at a faster rate during the later phases thereof. The floW of air to the preheated area is regulated by analyzing the effluent therefrom for either 0 or CO and by controlling the rate of air flow so as to maintain the 0 concentration in the range of about 0.10 to about 10% by volume; or, when analyzed for CO concentration, regulating the flow to maintain the concentration of CO in the range of about 6 to 13 or 14% by volume. If the O concentration in the effluent exceeds the desired upper limit in the range of 0.10 to 10% by volume or if the concentration of CO in the efiiuent gas falls below a minimum in the range of 6 to 14% by volume, the fiow rate of air thru the stratum is decreased to bring the concentration of 0 or CO to a level in the preceding ranges. Conversely, if the 0 concentration in the efl iuent gas falls below a minimum in the range of 0.10 to 10% by volume, or if the CO concentration in the efiiuent gas exceeds a maximum in the range of 6 to 14% by volume. then the rate of how of air thru the heated stratum is increased. In other words, the concentration of either 0 or CO in the effluent gas is determined and the fiow rate of air is controlled so as to maintain the concentration of these constituents in the above ranges.

It has been found that by contacting the heated section of stratum during the preheating step with O and controlling the flow of 0 so as to maintain a low oxygen concentration (and high CO concentration) in the efiiuent from the heated section, the time required for establishing ignition of the stratum can be reduced at least in half. By this method the allowable rate of flow of O continuously increases during the preheating thus permitting self-sustaining ignition to start without the sudden shock of operating the ignition well after a long period of being shut in and the associated problems of flashing water to steam or a sudden rush of cold tar and water into the heated zone, particularly, when the inverse air injection method is utilized, with the ignition well serving as a production well.

It has been found that slow oxidation occurs during the early phases of the preheating step when air is fed to the heated area and, as the temperature of the stratum rises, the rate of oxidation increases. For this reason, it is feasible to preheat the section of stratum around an ignition borehole therein to raise the temperature thereof to about 200 to 300 P. (such as 250 F.) before contacting the same with a stream of air. However, air may be flowed to the section of stratum during the entire preheating period at increasing rates, as required to maintain the proper oxygen concentration in the eifiuent, so that when the ignition temperature is reached, ignition is automatically effected. In cases where a heating device is utilized for the preheating step, the same is removed when ignition is established.

Control of the 0 or CO concentration in the efiiuent from the section of stratum being heated automatically determines the air flow rate at any given time. Flow rates will vary widely during the preheating period probably because of the changing rate of oxidation of carbonaceous matter.

A rate as low as l or 2 standard cubic feet per hour per square foot of well bore area in the carbonaceous stratum comes within the scope of the process and rates will go as high as 200 s.c.f.h. per square foot of borehole area and higher, depending upon the permeability of the stratum and the character of the carbonaceous deposit therein.

A more complete understanding of the invention may be had by reference to the accompanying schematic drawing of which FIGURE 1 is an elevation showing an arrangement of apparatus in association with a carbona- 3 ceous stratum for effecting the process of the invention; FIGURE 2 shows a typical S-spot well pattern adapted to the process of the invention; and FIGURE 3 is a graph showing the relation between time and preheat temperature in preheating a section of carbonaceous stratum with and without air flow.

Referring to FIGURE 1, a carbonaceous stratum 10 is penetrated by an ignition borehole 12 and a number of injection boreholes 14 two of which are shown. Boreholes 14 are spaced, as shown in FIGURE 2, around borehole 12 in a generally annular pattern and spaced therefrom any suitable distance within the range of a few feet to several hundred feet, depending upon the permeability of the carbonaceous stratum and other factors. It is to be understood that, where the permeability is low, the stratum may be horizontally fractured in known manner.

Each well is provided with a casing '16 and a well head 18. A heater 20 is positioned in borehole 12 within stratum 10 so as to heat the wall of the borehole Within the carbonaceous stratum. Heater 20 may be of any type such as a gas fired heater, an electric heater, or a mass of incandescent charcoal. One type of gas fired heater which has been found particularly effective is that disclosed and claimed in the US application of A. S. Rogers et al., Serial No. 719,890, filed March 7, 1958. Charcoal has also been found to be very effective in preheating a carbonaceous stratum surrounding a borehole for in situ combustion purposes.

Air lines 22 connect with each injection well head 18 and with a source of air supply, such as blower 24, thru line 26. An automatic controller 28 is positioned in the air line circuit between line 26 and lines 22 to control the amount of air passing to the air injection wells. An effluent line 30 from well head 18 of ignition well 12 connects with an analyzer 32 which is provided with an exhaust line 35. Analyzer 32 is operatively connected with automatic controller 28 vial line 36. Tubing 34 serves as an exhaust and as production tubing.

Analyzer 32 may be any oxygen analyzer or CO analyzer of any construction or design which satisfactorily analyzes the effluent gas for or CO concentration. The analyzer may be of the paramagnetic, conductive bridge type, or of the well known absorbent type. A Beckmann paramagnetic oxygen analyzer has been found very satisfactory in field tests in in situ combustion. It is also feasible to periodically analyze the effluent gas by well known laboratory methods to determine either the 0 content or the CO content and periodically regulate the flow of air or other O -containing gas to the injection wells so as to maintain the 0 or CO concentration in the effluent within the desired ranges or at a substantially constant value within said ranges. However, automatic continuous analyzers and controllers are available from commercial sources for effecting the controls of the process.

FIGURE 3 shows curves plotted from laboratory tests on igniting tar sand on a small scale oil well arrangement. In the tests, a section of tar sand 4 /2 inches thick and 7 inches in diameter was clamped between two flanges so that air could be forced into the sides of the cylinder thru the cylindrical surface and produced from a well drilled along its axis. This gave a system of radial fiow similar to that employed in field operations. The rock or sand was heated by means of an electric heater in the well bore. In tests in which the well bore was preheated without flow of air thru the rock during the preheating operation, the time for heating to ignition temperautre was of the order of 40 minutes. In another test with the same arrangement of apparatus and tar sand, air was fiowed thru the sand during the preheating operation and the effluent gas from the well bore was analyzed for carbon dioxide. (A continuous oxygen analyzer was not available in the laboratory at the time.) The flow of air was controlled to maintain a carbon dioxide concentration in the range of 6 to 13 percent in the effluent gas from the well bore. A temperature of 600 F. (the approximate ignition temperature) was reached approximately 2 /2 times as rapidly as in the tests without air flow, as measured by a thermocouple one-half inch from the well bore. runs are plotted and shown in FIGURE 3.

Certain modifications of the invention will become apparent to those skilled in the art and the illustrative details disclosed are not to be construed as imposing unnecessary limitations on the invention.

I claim:

1. A process for initiating in situ combustion in a carbonaceous stratum comprising preheating a section of said stratum around a borehole therein to raise same to ignition temperature; during said preheating, passing O -containing gas thru said section at gradually increasing fiow rate from a low flow rate to a substantially higher flow rate at the time when said temperature is reached; analyzing gaseous efiiuent from said section to determine the concentration of a constituent thereof selected from the group consisting of O and CO regulating the flow rate of said gas to said section in accordance with the resulting concentration to maintain a desired concentration of said constituent in said efiiuent, said range being 0.10 to 10% by volume when regulating in response to 0 concentration and 6 to 14 percent by volume when regulating in response to CO concentration; continuing the preheating step until the ignition temperature of the carbonaceous material in said stratum is reached; and continuing the flow of said gas to said section so as to ignite carbonaceous material therein.

2. The process of claim 1 wherein the concentration of O is used to regulate the fiow of O -containing gas.

3. The process of claim 1 wherein the concentration of CO is used to regulate the flow of O -containing gas.

4. A process for initiating in situ combustion in a stratum containing carbonaceous material comprising preheating a section of said stratum around a borehole therein to raise the temperature of said material to the ignition point; while the temperature of the wall of the borehole is rising thru the range of about 250 F. to about 600 F., passing a stream of air thru said section; analyzing gaseous effluent from said section to determine the concentration of a constituent thereof selected from the group consisting of O and CO regulating the flow of air to said section in response to said concentration to maintain same in a seleced range, said range being 0.10 to 10% by volume when regulating in response to 0 concentration and 6 to 14 percent by volume when regulating in response to CO concentration; and continuing the preheating and flow of air until ignition of said material is effected.

5. The process of claim 4 wherein said air is passed thru said stratum into said borehole.

6. The process of claim 5 wherein said air is supplied to said section thru a series of air-injection boreholes surrounding said borehole.

7. The process of claim 4 wherein 0 concentration is used to regulate the flow of air.

8. The process of claim 4 wherein CO concentration is used to regulate the flow of air.

9. The process of claim 4 wherein the O concentration is determined and same is maintained in the range of 0.10 to 5.0% by volume.

10. A process for igniting a combustible carbonaceous stratum around an ignition borehole therein comprising preheating to ignition temperature a section of stratum adjacent said borehole; during the preheating, passing air into said section at a very low flow rate in the range of 1 to 200 standard cubic feet per hour per square foot of area of said borehole thru which gas is passing, during the initial phase of said preheating, and increasing the flow rate of air as the temperature of said section increases so as to reach a very higher flow rate of air in said range when said temperature is reached, thereby igniting said The test data for the two types of section in a short period of time; and continuing the feeding of air to the hot stratum so as to initiate in situ combustion of said stratum.

11. The process of claim 10 including the steps of measuring the 0 concentration in the gaseous efiiuent and regulating the flow rate of air so as to maintain said concentration of O in the range of 0.10 to 10% by volume of said efiiuent.

12. The process of claim 10 including the steps of measuring the CO concentration in the gaseous efiiuent and regulating the flow rate of air so as to maintain said concentration of CO in the range of 6 to 14% by volume of said effluent.

13. The process of claim 10 wherein air is injected thru at least one offset borehole thru said stratum to said section during preheating and thereafter to sustain combustion and initiate an inverse drive combustion.

References Cited in the file of this patent UNITED STATES PATENTS

US3032102A 1958-03-17 1958-03-17 In situ combustion method Expired - Lifetime US3032102A (en)

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Cited By (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3221809A (en) * 1963-06-14 1965-12-07 Socony Mobil Oil Co Inc Method of heating a subterranean reservoir containing hydrocarbon material
US3298434A (en) * 1964-05-27 1967-01-17 Thomas T Graham Gasification of coal
US3470954A (en) * 1968-10-16 1969-10-07 Mobil Oil Corp Temperature control in an in situ combustion production well
US3775073A (en) * 1971-08-27 1973-11-27 Cities Service Oil Co In situ gasification of coal by gas fracturing
US3892270A (en) * 1974-06-06 1975-07-01 Chevron Res Production of hydrocarbons from underground formations
US3905422A (en) * 1974-09-23 1975-09-16 Texaco Inc Method for recovering viscous petroleum
US3964545A (en) * 1972-11-24 1976-06-22 Esorco Corporation Processes for secondarily recovering oil
US3997005A (en) * 1975-10-23 1976-12-14 The United States Of America As Represented By The United States Energy Research And Development Administration Method for control of subsurface coal gasification
US4151877A (en) * 1977-05-13 1979-05-01 Occidental Oil Shale, Inc. Determining the locus of a processing zone in a retort through channels
US4163475A (en) * 1978-04-21 1979-08-07 Occidental Oil Shale, Inc. Determining the locus of a processing zone in an in situ oil shale retort
US4296809A (en) * 1980-07-21 1981-10-27 Gulf Research & Development Company In situ gasification of bituminous coal
US4299285A (en) * 1980-07-21 1981-11-10 Gulf Research & Development Company Underground gasification of bituminous coal
US4344484A (en) * 1978-08-17 1982-08-17 Occidental Oil Shale, Inc. Determining the locus of a processing zone in an in situ oil shale retort through a well in the formation adjacent the retort
US4369841A (en) * 1980-12-29 1983-01-25 Occidental Oil Shale, Inc. Method for igniting an in situ oil shale retort
US4369842A (en) * 1981-02-09 1983-01-25 Occidental Oil Shale, Inc. Analyzing oil shale retort off-gas for carbon dioxide to determine the combustion zone temperature
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US20020029885A1 (en) * 2000-04-24 2002-03-14 De Rouffignac Eric Pierre In situ thermal processing of a coal formation using a movable heating element
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US20040140096A1 (en) * 2002-10-24 2004-07-22 Sandberg Chester Ledlie Insulated conductor temperature limited heaters
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US7051808B1 (en) 2001-10-24 2006-05-30 Shell Oil Company Seismic monitoring of in situ conversion in a hydrocarbon containing formation
US7066254B2 (en) 2001-04-24 2006-06-27 Shell Oil Company In situ thermal processing of a tar sands formation
US7090013B2 (en) 2001-10-24 2006-08-15 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to produce heated fluids
US7104319B2 (en) 2001-10-24 2006-09-12 Shell Oil Company In situ thermal processing of a heavy oil diatomite formation
US7121342B2 (en) 2003-04-24 2006-10-17 Shell Oil Company Thermal processes for subsurface formations
US7165615B2 (en) 2001-10-24 2007-01-23 Shell Oil Company In situ recovery from a hydrocarbon containing formation using conductor-in-conduit heat sources with an electrically conductive material in the overburden
US20070031335A1 (en) * 2001-04-10 2007-02-08 Aya Jakobovits Nucleic acids and corresponding proteins useful in the detection and treatment of various cancers
US20070045266A1 (en) * 2005-04-22 2007-03-01 Sandberg Chester L In situ conversion process utilizing a closed loop heating system
US20080093071A1 (en) * 2005-01-13 2008-04-24 Larry Weiers In Situ Combustion in Gas Over Bitumen Formations
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US20100206570A1 (en) * 2008-10-13 2010-08-19 Ernesto Rafael Fonseca Ocampos Circulated heated transfer fluid systems used to treat a subsurface formation
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US7866388B2 (en) 2007-10-19 2011-01-11 Shell Oil Company High temperature methods for forming oxidizer fuel
US8151907B2 (en) 2008-04-18 2012-04-10 Shell Oil Company Dual motor systems and non-rotating sensors for use in developing wellbores in subsurface formations
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Cited By (306)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3221809A (en) * 1963-06-14 1965-12-07 Socony Mobil Oil Co Inc Method of heating a subterranean reservoir containing hydrocarbon material
US3298434A (en) * 1964-05-27 1967-01-17 Thomas T Graham Gasification of coal
US3470954A (en) * 1968-10-16 1969-10-07 Mobil Oil Corp Temperature control in an in situ combustion production well
US3775073A (en) * 1971-08-27 1973-11-27 Cities Service Oil Co In situ gasification of coal by gas fracturing
US3964545A (en) * 1972-11-24 1976-06-22 Esorco Corporation Processes for secondarily recovering oil
US3892270A (en) * 1974-06-06 1975-07-01 Chevron Res Production of hydrocarbons from underground formations
USRE30019E (en) * 1974-06-06 1979-06-05 Chevron Research Company Production of hydrocarbons from underground formations
US3905422A (en) * 1974-09-23 1975-09-16 Texaco Inc Method for recovering viscous petroleum
US3997005A (en) * 1975-10-23 1976-12-14 The United States Of America As Represented By The United States Energy Research And Development Administration Method for control of subsurface coal gasification
US4151877A (en) * 1977-05-13 1979-05-01 Occidental Oil Shale, Inc. Determining the locus of a processing zone in a retort through channels
US4163475A (en) * 1978-04-21 1979-08-07 Occidental Oil Shale, Inc. Determining the locus of a processing zone in an in situ oil shale retort
US4344484A (en) * 1978-08-17 1982-08-17 Occidental Oil Shale, Inc. Determining the locus of a processing zone in an in situ oil shale retort through a well in the formation adjacent the retort
US4296809A (en) * 1980-07-21 1981-10-27 Gulf Research & Development Company In situ gasification of bituminous coal
US4299285A (en) * 1980-07-21 1981-11-10 Gulf Research & Development Company Underground gasification of bituminous coal
US4369841A (en) * 1980-12-29 1983-01-25 Occidental Oil Shale, Inc. Method for igniting an in situ oil shale retort
US4369842A (en) * 1981-02-09 1983-01-25 Occidental Oil Shale, Inc. Analyzing oil shale retort off-gas for carbon dioxide to determine the combustion zone temperature
US4415031A (en) * 1982-03-12 1983-11-15 Mobil Oil Corporation Use of recycled combustion gas during termination of an in-situ combustion oil recovery method
US4448249A (en) * 1982-06-18 1984-05-15 Occidental Research Corporation Method of in situ oil shale retort ignition with oxygen control
US4683947A (en) * 1985-09-05 1987-08-04 Air Products And Chemicals Inc. Process and apparatus for monitoring and controlling the flammability of gas from an in-situ combustion oil recovery project
US6997255B2 (en) 2000-04-24 2006-02-14 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation in a reducing environment
US20020033257A1 (en) * 2000-04-24 2002-03-21 Shahin Gordon Thomas In situ thermal processing of hydrocarbons within a relatively impermeable formation
US20020038711A1 (en) * 2000-04-24 2002-04-04 Rouffignac Eric Pierre De In situ thermal processing of a hydrocarbon containing formation using heat sources positioned within open wellbores
US20020043367A1 (en) * 2000-04-24 2002-04-18 Rouffignac Eric Pierre De In situ thermal processing of a hydrocarbon containing formation to increase a permeability of the formation
US20020043365A1 (en) * 2000-04-24 2002-04-18 Berchenko Ilya Emil In situ thermal processing of a coal formation with a selected ratio of heat sources to production wells
US20020053431A1 (en) * 2000-04-24 2002-05-09 Wellington Scott Lee In situ thermal processing of a hydrocarbon containing formation to produce a selected ratio of components in a gas
US20020053432A1 (en) * 2000-04-24 2002-05-09 Berchenko Ilya Emil In situ thermal processing of a hydrocarbon containing formation using repeating triangular patterns of heat sources
US20020029885A1 (en) * 2000-04-24 2002-03-14 De Rouffignac Eric Pierre In situ thermal processing of a coal formation using a movable heating element
US20020057905A1 (en) * 2000-04-24 2002-05-16 Wellington Scott Lee In situ thermal processing of a hydrocarbon containing formation to produce oxygen containing formation fluids
US20020056551A1 (en) * 2000-04-24 2002-05-16 Wellington Scott Lee In situ thermal processing of a hydrocarbon containing formation in a reducing environment
US20020077515A1 (en) * 2000-04-24 2002-06-20 Wellington Scott Lee In situ thermal processing of a hydrocarbon containing formation to produce hydrocarbons having a selected carbon number range
US20020084074A1 (en) * 2000-04-24 2002-07-04 De Rouffignac Eric Pierre In situ thermal processing of a hydrocarbon containing formation to increase a porosity of the formation
US20020104654A1 (en) * 2000-04-24 2002-08-08 Shell Oil Company In situ thermal processing of a coal formation to convert a selected total organic carbon content into hydrocarbon products
US7096953B2 (en) 2000-04-24 2006-08-29 Shell Oil Company In situ thermal processing of a coal formation using a movable heating element
US6994160B2 (en) 2000-04-24 2006-02-07 Shell Oil Company In situ thermal processing of a hydrocarbon containing formation to produce hydrocarbons having a selected carbon number range
US6973967B2 (en) 2000-04-24 2005-12-13 Shell Oil Company Situ thermal processing of a coal formation using pressure and/or temperature control
US7011154B2 (en) 2000-04-24 2006-03-14 Shell Oil Company In situ recovery from a kerogen and liquid hydrocarbon containing formation
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