US2954284A - Fuel comprising a mixture of ammonium nitrate and metal particles - Google Patents

Fuel comprising a mixture of ammonium nitrate and metal particles Download PDF

Info

Publication number
US2954284A
US2954284A US714942A US71494258A US2954284A US 2954284 A US2954284 A US 2954284A US 714942 A US714942 A US 714942A US 71494258 A US71494258 A US 71494258A US 2954284 A US2954284 A US 2954284A
Authority
US
United States
Prior art keywords
fuel
ammonium nitrate
metal particles
mixture
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US714942A
Inventor
Jr Harry A Toulmin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commonwealth Engineering Company of Ohio
Original Assignee
Commonwealth Engineering Company of Ohio
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commonwealth Engineering Company of Ohio filed Critical Commonwealth Engineering Company of Ohio
Priority to US714942A priority Critical patent/US2954284A/en
Application granted granted Critical
Publication of US2954284A publication Critical patent/US2954284A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B33/00—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide
    • C06B33/04—Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide the material being an inorganic nitrogen-oxygen salt
    • C—CHEMISTRY; METALLURGY
    • C06—EXPLOSIVES; MATCHES
    • C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
    • C06B31/00—Compositions containing an inorganic nitrogen-oxygen salt
    • C06B31/28—Compositions containing an inorganic nitrogen-oxygen salt the salt being ammonium nitrate
    • C06B31/30—Compositions containing an inorganic nitrogen-oxygen salt the salt being ammonium nitrate with vegetable matter; with resin; with rubber
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S149/00—Explosive and thermic compositions or charges
    • Y10S149/11—Particle size of a component
    • Y10S149/112—Inorganic nitrogen-oxygen salt
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S149/00—Explosive and thermic compositions or charges
    • Y10S149/11—Particle size of a component
    • Y10S149/114—Inorganic fuel

Definitions

  • the principal object of the invention is to provide a solid fuel which forms a suitable burning mixture useful as propellants, missiles, rockets, power plants, etc., and which may be used as a fuel for jet-driven airplanes, turbines, and the like, as employed in the fields of aviation, rail transportation and military equipment and operations.
  • a still further object of the invention is to provide a method for carrying out the combustion of powdered metal fuel mixtures of the character described which supply or release a suflicient amount of oxygen to maintain the combustion of the mixture once it is initiated.
  • the invention utilizes ammonium nitrate as one of the principal constituents and which decomposes to release nitrous oxide and water as steam.
  • Ammonium nitrate when heated decomposes in accordance wtih the equationheated Steam Gas N 0 2H2O NH N O a
  • Ammonium nitrate used in the propellent fuel preferably is of fertiziler grade and consists of prills which are free-flowable, and substantially free of moisture, the prills being ground to a particulate size of 1 to 10 microns.
  • ammonium nitrate is dried at a temperature of approximately 90 F. to prevent physical change until the moisture contact is reduced to about 0.1% by weight.
  • Control of the burning is provided by limiting the size of the nitrate particles, the burning rate increasing as the particulates are decreased in size. In this Way by selective use of different size particulates the rate of burning of the fuel may be varied and controlled.
  • powdered metal fuel containing ammonium nitrate examples include ammonium nitrate, it being understood that the proportions may be varied 5-10% either way to produce a powdered metal fuel mixture in accordance with applicants invention.
  • ammonium nitrate is admixed with the metal particulates.
  • the metal particulates are relatively small particle size and on the 1 order of one-half to one micron, with particle size of lessthan one micron in diameter preferred.
  • the mixture of ammonium nitrate and metal powder may be suitably compressed and used as a solid block fuel or used as a slurry mass by adding hydrocarbon liquids such as kerosene" or ariaromatic 'alkane in amounts from 10 to 30% by weight of the total mixture.
  • Example III a small amount of metallic soap is incorporated with the metal powder to catalyze its oxidation.
  • the metal soap may be admixed into the fuel as a powder or melted and sprayed onto the metal particulates, the latter method being preferred since a more uniform distribution of the soap in the fuel is obtained.
  • the metallic soaps employed are preferably selected from the polyvalent metals consisting of aluminum, magnesium, zinc; fatty acid esters of these metals, e.g., the metal stearates, palmitates, oleates and ricinoleates and the like are employed.
  • One readily available commercially is aluminum stearate.
  • This metallic soap catalyzer may approximate the weight of the metal particulates or range downward to 50% of the metal content of the fuel, depending upon the temperature of burning desired. For higher burning temperatures of the propellent gas larger amounts of metal particulates are used.
  • the rate of combustion or burning of the mixture is varied by varying of the proportionate amounts of the constituents and particulate size of constituents.
  • Ignition of the fuel mixture may be achieved by electrical means such as that produced by a spark plug or by the heating of a wire to incandescence in contact with the mixture.
  • a fuel consisting of the following constituents in parts by weight:
  • Percent Ammonium nitrate 70 Metal particles selected from the group consisting of aluminum, magnesium and zinc and mixtures thereof 15 Aluminum stearate 15 said metal particles having a size on the order of onehalf micron to one micron in diameter.
  • a fuel consisting of the following constituents in parts by weight:
  • Percent Ammonium nitrate 70 Metal particles of aluminum 15 Aluminum stearate 15 Percent Ammonium nitrate Metal particles of magnesium" 15 Aluminum stearate 15 said magnesium metal particles having a size on the order of one-half micron to one micron in diameter.
  • a fuel consisting of the following constituents in parts by weight:
  • I Percent Ammonium nitrate 70 Metal particles of zinc 15 Aluminum stearate 15 said zinc metal particles having a size on the order of one-half micron to one micron in diameter.

Description

United States Patent 2,954,284 Patented Sept. 2-7, 195
FUEL COMPRISING A MIXTURE OF AMMO- NIUM NITRATE AND METAL PARTICLES Harry A. Toulmin, Jr., Dayton, Ohio, assignor to The Commonwealth Engineering Company of Ohio, Dayton, Ohio N0 Drawing. Filed Feb. 13, 1958, Ser. No. 714,942
4 Claims. (Cl. 52--.5)
The principal object of the invention is to provide a solid fuel which forms a suitable burning mixture useful as propellants, missiles, rockets, power plants, etc., and which may be used as a fuel for jet-driven airplanes, turbines, and the like, as employed in the fields of aviation, rail transportation and military equipment and operations.
It is another object of the invention to provide a composition useful as fuel which is adapted to burn at a non-explosive rate and produce a large amount of gases.
It is a further object of the invention to provide a powdered fuel mixture which can be used in the form of a slurry or admixed with liquid hydrocarbons, and which releases a large amount of exothermic heat upon burning.
A still further object of the invention is to provide a method for carrying out the combustion of powdered metal fuel mixtures of the character described which supply or release a suflicient amount of oxygen to maintain the combustion of the mixture once it is initiated.
The invention utilizes ammonium nitrate as one of the principal constituents and which decomposes to release nitrous oxide and water as steam.
Ammonium nitrate when heated, as shown below, decomposes in accordance wtih the equationheated Steam Gas N 0 2H2O NH N O a Ammonium nitrate used in the propellent fuel preferably is of fertiziler grade and consists of prills which are free-flowable, and substantially free of moisture, the prills being ground to a particulate size of 1 to 10 microns.
The ammonium nitrate is dried at a temperature of approximately 90 F. to prevent physical change until the moisture contact is reduced to about 0.1% by weight.
Control of the burning is provided by limiting the size of the nitrate particles, the burning rate increasing as the particulates are decreased in size. In this Way by selective use of different size particulates the rate of burning of the fuel may be varied and controlled.
Examples of the powdered metal fuel containing ammonium nitrate are illustrated below, it being understood that the proportions may be varied 5-10% either way to produce a powdered metal fuel mixture in accordance with applicants invention.
Example II Parts by Range weight Percent Ammonium nitrate (Dry Ex. I) 80 v 704?!) Metal particles (Al, Mg, Zn) 20 10-30 Example III Parts by Range weight Percent Ammonium nitrate (Dry Ex. I) 70 60-80 Metal Particles (Al, Mg, Zn).-.. 15 10-20 Metal soap (Aluminum stearate) 15 1020 In preparing the powdered metal mixture, ammonium nitrate is admixed with the metal particulates. The metal particulates are relatively small particle size and on the 1 order of one-half to one micron, with particle size of lessthan one micron in diameter preferred. The mixture of ammonium nitrate and metal powder may be suitably compressed and used as a solid block fuel or used as a slurry mass by adding hydrocarbon liquids such as kerosene" or ariaromatic 'alkane in amounts from 10 to 30% by weight of the total mixture.
In Example III, a small amount of metallic soap is incorporated with the metal powder to catalyze its oxidation. The metal soap may be admixed into the fuel as a powder or melted and sprayed onto the metal particulates, the latter method being preferred since a more uniform distribution of the soap in the fuel is obtained. The metallic soaps employed are preferably selected from the polyvalent metals consisting of aluminum, magnesium, zinc; fatty acid esters of these metals, e.g., the metal stearates, palmitates, oleates and ricinoleates and the like are employed. One readily available commercially is aluminum stearate.
This metallic soap catalyzer may approximate the weight of the metal particulates or range downward to 50% of the metal content of the fuel, depending upon the temperature of burning desired. For higher burning temperatures of the propellent gas larger amounts of metal particulates are used.
It has been found by tests that the combination of the metal particles with the ammonium nitrate when heated to burning in air releases large quantities of nitro gen, oxygen and gases heated to very high temperatures and on the order of 5000 C. and higher. The powdered metal particles along, such as aluminum metal, burn at a temperature of around 3500 C. and produce an intense heat. The high temperatures produced during burning of the metal particles causes rapid decomposition of the admixture and release of large volumes of gases. vaporization of any water formed during the reaction forms steam, which is decomposed into hydrogen a zlmd ozygen at the high temperature of the burning met Metal particulates are preferably selected from the light metal group and consisting of aluminum, magnesium, zinc, tin and the like or mixtures thereof. The presence of metallic soap catalyzes the burning so that the same takes place at a uniform rate and yet is under suflicient control so that the fuel does not explode but provides a continuing expanding gaseous force useful as a propellant or propulsion jet prime mover.
The rate of combustion or burning of the mixture is varied by varying of the proportionate amounts of the constituents and particulate size of constituents.
Ignition of the fuel mixture may be achieved by electrical means such as that produced by a spark plug or by the heating of a wire to incandescence in contact with the mixture.
It is understood that various changes and additions in equivalent materials may be substituted for those set forth in the above examples when compounding the composition of this invention and that the proportionate amounts of the constituents may be varied, as heretofore described, and depending upon the particular use to which the mixture is to be put. Such changes and variations are deemed to be contemplated to come Within the spirit and scope of this invention and which are particularly set forth in the appended claims.
What is claimed is:
1. A fuel consisting of the following constituents in parts by weight:
Percent Ammonium nitrate 70 Metal particles selected from the group consisting of aluminum, magnesium and zinc and mixtures thereof 15 Aluminum stearate 15 said metal particles having a size on the order of onehalf micron to one micron in diameter.
2. A fuel consisting of the following constituents in parts by weight:
Percent Ammonium nitrate 70 Metal particles of aluminum 15 Aluminum stearate 15 Percent Ammonium nitrate Metal particles of magnesium" 15 Aluminum stearate 15 said magnesium metal particles having a size on the order of one-half micron to one micron in diameter.
4. A fuel consisting of the following constituents in parts by weight:
I Percent Ammonium nitrate 70 Metal particles of zinc 15 Aluminum stearate 15 said zinc metal particles having a size on the order of one-half micron to one micron in diameter.
References Cited in the file of this patent UNITED STATES PATENTS 1,506,322 ONeill Aug. 26, 1924 2,159,234 Taylor May 23, 1939 2,416,639 Pearsall Feb. 25, 1947 2,477,549 Van Loenen July 26, 1949 2,530,493 Van Loenen Nov. 21, 1950 OTHER REFERENCES 43rd Report National Advisory Committee for Aeronautics (1957), pages 24.
Chem. and Eng. News (11), Jan. 6, 1958, pages 79-81.
Chem. and Eng. News (I), May 27, 1957, pages 22-3.

Claims (1)

1. A FUEL CONSISTING OF THE FOLLOWING CONSTITUENTS IN PARTS BY WEIGHT: PERCENT AMMONIUM NITRATE ------------------------------------- 70 METAL PARTICLES SELECTED FROM THE GROUP CONSISTING OF ALUMINUM, MAGNESIUM AND ZINC AND MIXTURES THEREOF --------------------------------------------- 15 ALUMINUM STEARATE ----------------------------------- 15 AID METAL PARTICLES HAVING A SIZE ON THE ORDER OF ONE''HALF MICRON IN DIAMETER.
US714942A 1958-02-13 1958-02-13 Fuel comprising a mixture of ammonium nitrate and metal particles Expired - Lifetime US2954284A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US714942A US2954284A (en) 1958-02-13 1958-02-13 Fuel comprising a mixture of ammonium nitrate and metal particles

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US714942A US2954284A (en) 1958-02-13 1958-02-13 Fuel comprising a mixture of ammonium nitrate and metal particles

Publications (1)

Publication Number Publication Date
US2954284A true US2954284A (en) 1960-09-27

Family

ID=24872101

Family Applications (1)

Application Number Title Priority Date Filing Date
US714942A Expired - Lifetime US2954284A (en) 1958-02-13 1958-02-13 Fuel comprising a mixture of ammonium nitrate and metal particles

Country Status (1)

Country Link
US (1) US2954284A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3062856A (en) * 1958-09-26 1962-11-06 Alclio Gaetano F D Metal-containing polymers and preparation thereof
US3105747A (en) * 1960-12-22 1963-10-01 Shell Oil Co Combustible solid dispersions
US3113518A (en) * 1960-08-11 1963-12-10 Dow Chemical Co Container for explosive materials
US3128254A (en) * 1958-06-25 1964-04-07 Dal Mon Research Co Polymeric boron compositions
US3250652A (en) * 1964-02-03 1966-05-10 John E Claiborne Exothermic composition containing zinc and ammonium chloride
US3374127A (en) * 1965-08-13 1968-03-19 Aquitaine Petrole Compressed metal containing ternary explosive composition
DE1265725B (en) * 1961-04-20 1968-04-11 Progil Process for the production of aqueous phosphoric acid solutions of increased purity
US5534437A (en) * 1993-06-14 1996-07-09 Bio-Waste Technologies, International, Ltd. Co-composting process and apparatus for treating solid waste and sewage sludge
EP1074533A1 (en) * 1999-08-06 2001-02-07 Nihon Plast Co., Ltd. Gas generating agent
US6605167B1 (en) * 2000-09-01 2003-08-12 Trw Inc. Autoignition material for a vehicle occupant protection apparatus

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1506322A (en) * 1919-12-05 1924-08-26 O'neill John Hugh Method and means of producing heat
US2159234A (en) * 1935-03-11 1939-05-23 Ici Ltd Gas-producing nondetonating composition
US2416639A (en) * 1944-07-08 1947-02-25 Ensign Bickford Co Slow-burning powder composition
US2477549A (en) * 1947-01-22 1949-07-26 Permanente Metals Corp Explosive composition
US2530493A (en) * 1948-06-19 1950-11-21 Kaiser Aluminium Chem Corp Magnesium-containing incendiary composition and process of producing same

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1506322A (en) * 1919-12-05 1924-08-26 O'neill John Hugh Method and means of producing heat
US2159234A (en) * 1935-03-11 1939-05-23 Ici Ltd Gas-producing nondetonating composition
US2416639A (en) * 1944-07-08 1947-02-25 Ensign Bickford Co Slow-burning powder composition
US2477549A (en) * 1947-01-22 1949-07-26 Permanente Metals Corp Explosive composition
US2530493A (en) * 1948-06-19 1950-11-21 Kaiser Aluminium Chem Corp Magnesium-containing incendiary composition and process of producing same

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3128254A (en) * 1958-06-25 1964-04-07 Dal Mon Research Co Polymeric boron compositions
US3062856A (en) * 1958-09-26 1962-11-06 Alclio Gaetano F D Metal-containing polymers and preparation thereof
US3113518A (en) * 1960-08-11 1963-12-10 Dow Chemical Co Container for explosive materials
US3105747A (en) * 1960-12-22 1963-10-01 Shell Oil Co Combustible solid dispersions
DE1265725B (en) * 1961-04-20 1968-04-11 Progil Process for the production of aqueous phosphoric acid solutions of increased purity
US3250652A (en) * 1964-02-03 1966-05-10 John E Claiborne Exothermic composition containing zinc and ammonium chloride
US3374127A (en) * 1965-08-13 1968-03-19 Aquitaine Petrole Compressed metal containing ternary explosive composition
US5534437A (en) * 1993-06-14 1996-07-09 Bio-Waste Technologies, International, Ltd. Co-composting process and apparatus for treating solid waste and sewage sludge
EP1074533A1 (en) * 1999-08-06 2001-02-07 Nihon Plast Co., Ltd. Gas generating agent
US6605167B1 (en) * 2000-09-01 2003-08-12 Trw Inc. Autoignition material for a vehicle occupant protection apparatus

Similar Documents

Publication Publication Date Title
US2890108A (en) Catalyzed metal fuel
US2954284A (en) Fuel comprising a mixture of ammonium nitrate and metal particles
US3122429A (en) Jet or rocket fuel
Pfeil et al. Characterization of ethylenediamine bisborane as a hypergolic hybrid rocket fuel additive
Natan et al. Hypergolic ignition by fuel gellation and suspension of reactive or catalyst particles
US2771739A (en) Rocket propulsion method
US2978864A (en) Ammonium nitrate explosives
US3773947A (en) Process of generating nitrogen using metal azide
US2986456A (en) Liquid hydrocarbon fuel containing powdered coal, metal, and catalyst
US2989388A (en) Fuel and propellant composition
Zamostianu et al. Burn rate of a novel boron-AN-water green solid propellant
Solomon et al. Active boron dispersion and ignition in gel droplet
US3069854A (en) Catalyzed fuel mixture and method of burning
US3243326A (en) Fluidized metal fuel composition
US3006746A (en) Solid fuel and propellant composition
US3081595A (en) Rocket propulsion method employing catalytic decomposition of hydrazine
Murugesan et al. Experimental investigation on aluminum-based water ramjet for propelling high-speed underwater vehicles
US3151009A (en) Catalyzed metal fuel
US3006745A (en) Catalyzed metal fuel
US2710793A (en) Solid gas generating units
US3004841A (en) Jet or rocket fuel
US3147091A (en) Jet or rocket fuel
US3032451A (en) Solid jet or rocket fuel
US4161104A (en) Ignition of hydrazine-type monopropellants
US3213609A (en) High energy propellant and process employing hydrazines and nitro compounds