US2953434A - Process for sulfating titaniferous material - Google Patents

Process for sulfating titaniferous material Download PDF

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US2953434A
US2953434A US515524A US51552455A US2953434A US 2953434 A US2953434 A US 2953434A US 515524 A US515524 A US 515524A US 51552455 A US51552455 A US 51552455A US 2953434 A US2953434 A US 2953434A
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titanium
trivalent
sulfuric acid
slag
reaction
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Mckinney Robert Myers
Jr George Stuart Reeder
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EIDP Inc
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EI Du Pont de Nemours and Co
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    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B34/00—Obtaining refractory metals
    • C22B34/10—Obtaining titanium, zirconium or hafnium
    • C22B34/12—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08
    • C22B34/1236—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching
    • C22B34/124—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching using acidic solutions or liquors
    • C22B34/125—Obtaining titanium or titanium compounds from ores or scrap by metallurgical processing; preparation of titanium compounds from other titanium compounds see C01G23/00 - C01G23/08 obtaining titanium or titanium compounds from ores or scrap by wet processes, e.g. by leaching using acidic solutions or liquors containing a sulfur ion as active agent

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  • This invention relates to the solubilization of titan- :iferous materials and particularly to the preparation of soluble titanium sulfates suitable for use in the preparation of titanium dioxide pigments by hydrolysis. Still more particularly this invention relates to the prepara tion of such solutions from slags obtained by smelting iron from titanium bearing ores. V
  • vMethods of extracting the major portion of iron from titanium-iron ores, by high temperature electrothermic reduction and the formation of a titanium containing slag material are well known.
  • such methods are disclosed in US. Patent No. 2,476,453 issued to W. M. Pierce .et .al.
  • the slags thus obtained are a .source .of .titaniferous materials which are suitable for the preparation of acidic sulfate solutions and the subsequent recovery .of titanium dioxide pigments by hydrolytic precipitation.
  • this slag material as a titanium source contains a relatively small amount of iron.
  • a large amount of the titanium :(i.e., from 5-.25'% calculated as TiO is contained in the slag in the trivalent state, and this :trivalent titaniumreductively decomposes the sulfuric acid .used in ⁇ thesolubilizing process (also known as the attacks) thus resulting .in the evolution of obnoxious fumes and the loss of .acid. i
  • a :solid mass containing soluble titanium compounds is obtained, and this mass is dissolved in an aqueous solvent.
  • the present invention is concerned with the use of simple ferric iron compounds as distinguished from ferric iron compounds which contain metals other than iron in the combined state. These latter materials of which ilmenite and arizonite ted States Patent '2 are examples are not within the scope of this invention.
  • the probable function of the simple ferric iron compounds is that of an oxidizing agent.
  • our improved process for 5 .sulfating titaniferous slag material containing titanium in the trivalent state comprises reacting the titaniferous material with strong sulfuric acid in the presence of a simple ferric iron compound in an amount ranging from about 210% of the theoretical amount required to oxidize the trivalent titanium to the tetravalent state.
  • a solid mass conaining soluble trivalent and tetravalent titanium compounds is obtained, and this mass is dissolved in an aqueous solvent.
  • oxidizing agents such as hydrogen peroxide, sodium nitrate and nitric acid are also effective in the same manner as the ferric iron compounds.
  • our invention comprises admixing in a reaction vessel suitable for air agitation a finely ground titaniferous slag material, such as that which results from the electrosmelting of titaniferous ore from the Allard Lake Region of Canada, with at least a third of the strong sulfuric acid required for sulfation.
  • a finely ground titaniferous slag material such as that which results from the electrosmelting of titaniferous ore from the Allard Lake Region of Canada
  • Such slag usually contains from about -80% total titanium, calculated as titanium dioxide, and of this about 13-19% is in the reduced valence state. 2-10% of the amount of ,finely divided pigment grade iron oxide which would theoretically oxidize the trivalent titanium to tetravalent titanium is then added.
  • This ferric iron oxide is readily dispersed in the sulfuric acid mixture and dissolves to :form ferric sulfate during the period of the attack while the temperature is rising and the sulfuric acid is strong enough and hot .enough to readily oxidize trivalent titanium.
  • the sulfation reaction is initiated by raising the temperature of the acid-slag mixture. This can most conveniently be done by dilution, as described in US. Patent No. 1,889,027, or .by mixing other combinations of sulfuric acid, such as for example 60 B. and oleum. After initiation, the temperature rises slowly in a .period of about 4-5 minutes to a temperature in the range of 190-200 C. due to :the sulfation reaction.
  • This temperature rise is accompanied by the production of large volumes of steam given off by the reaction, and at the end of the period the sulfation products are set up as a hard porous mass in the reaction vessel. While some improvement in overall .yield is usually obtained by holding the reaction mass at this elevated temperature for several hours, the sulfation is essentially complete at this time. This mass will contain a small amount, about 5-l0%, of unreacted slag, but otherwise it will be completely soluble. During the reaction substantially no noxious vaporized products (e.g., H 8 and S0 from the decomposition of the sulfuric acid are obtained.
  • noxious vaporized products e.g., H 8 and S0 from the decomposition of the sulfuric acid are obtained.
  • the titanium sulfate solution obtained by dissolving the mass in dilute acid will contain about 5-20 grams per liter of trivalent titanium (expressed as TiO This can be oxidized quickly by "the addition of sodium nitrate, or allowed to be oxidized by the air used for agitation of the solution. Usually the trivalent titanium concentration is reduced to about 1-2 grams per liter (expressed as TiO for further processing.
  • air is passed through the reaction mixture for agitation, but under the strong acid conditionsof the attack reaction, the air has no appreciable oxidizing effect upon the trivalent titanium as Example 1 Canadian slag obtained by electrosmelting titaniferous iron ore was analyzed as follows:
  • This slag was reacted with the equivalent of 160 pounds of sulfuric acid of 100% H 80 per 100 pounds of slag by the following procedure. 15,000 pounds of 60 B. H 80 were placed in a 10,000 gallon reaction vessel with a conical bottom and 30,000 pounds of the above slag in finely ground condition were added. While agitating this mixture with air introduced from the bottom of the vessel, 300 pounds of pigment grade ferric oxide (82.5% Fe O 10.2% SiO equivalent to about 7.7% of the total requirement for the oxidation of all the trivalent titanium in the slag were then added to the acidslag mixture.
  • the sulfation reaction was then initiated by the addition of 20,000 pounds of oleum and within about 45 minutes the temperature of the reaction mixture reached 190 C., and a few minutes later a hard porous mass of sulfated slag was obtained. This mass was held at temperature for three hours and then dissolved by adding dilute sulfuric acid and then water. By air agitating the solution for four hours the trivalent titanium content was reduced to about 2 grams per liter. The solution was then ready for clarification and hydrolysis.
  • Example 2 Using the same slag and the same amount of sulfuric acid and slag as used in Example 1, 150 pounds of finely ground iron oxide (equivalent to about 3% of the total oxidation requirement of the trivalent titanium of the slag) were added just before the reaction started. The loss of sulfuric acid to reduction decomposition products including H 8 and S0 was less than about 1.5% of the total sulfuric acid used. The porous reaction mass, when dissolved in dilute sulfuric acid using air agitation produced a solution containing about 160 grams per liter of titanium (expressed as TiO about 20 grams per liter of which was in the trivalent state.
  • the final acid strength should be within the range of about 85-95% H 50 usually between 89 and 93%, and it is obvious that one may use 96100% H 50 or oleum with water or steam or weaker acid to obtain optimum acid strength for the slag material being sulfated.
  • the slag reaction mass After being sulfated the slag reaction mass is dissolved in dilute sulfuric acid or water, and the solution may be adjusted to any final degree of reduction by further addition of oxidizing agents.
  • This solution after suitable clarification can be hydrolyzed by usual methods. Satisfactory methods have been described in U.S. Patents Nos. 2,511,218 and 2,479,637 and Reissues 18,590, and 18,854.
  • ferric iron compounds can be utilized for the elemination of the noxious fumes evolved during sulfation of titaniferous slag containing trivalent titanium.
  • the preferred material for such use is ferric oxide which can be obtained in a finely divided state free from unwanted contaminating impurities.
  • ferric oxide which can be obtained in a finely divided state free from unwanted contaminating impurities.
  • other satisfactory simple ferric iron compounds include ferric sulfate, ferric sulfate dissolved in dilute sulfuric acid, oxidized copperas or basic ferric sulfate, magnetite, hematite, limonite, and ferric ammonium sulfate.
  • the present invention offers several distinct advantages. As the examples show, the loss of sulfuric acid is reduced to a minimum thereby eliminating the presence of obnoxious fumes in the air and steam mixture which is evolved from the sulfation reaction. The absence of these fumes in the latter mixture overcomes the necessity for costly processes of scrubbing to prevent air pollution. A further advantage resides in the fact that minor amounts of relatively pure oxidizing agents are used in the process, thus improving the quality of the final pigment product.
  • An improved process for sulfating a titaniferous material containing titanium in the trivalent state which comprises reacting said titaniferous material with strong sulfuric acid in the presence of an oxidizing agent selected from the group consisting of ferric iron oxides, ferric iron sulfates, hydrogen peroxide, sodium nitrate, and nitric acid, said oxidizing agent being present in an amount ranging from about 2 to 10% of the theoretical quantity required to oxidize the trivalent titanium to the tetravalent state, obtaining a solid mass containing soluble titanium compounds, and dissolving said mass in an aqueous solvent.
  • an oxidizing agent selected from the group consisting of ferric iron oxides, ferric iron sulfates, hydrogen peroxide, sodium nitrate, and nitric acid
  • An improved process for sulfating a titaniferous material containing titanium in the trivalent state which comprises reacting said titaniferous material with strong sulfuric acid in the presence of a ferric iron oxide in an amount ranging from about 2-10% of the theoretical quantity required to oxidize the trivalent titanium to the tetravalent state, obtaining a solid mass containing soluble titanium compounds and dissolving said mass in an aqueous solvent.

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  • Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
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Description

PROCESS FOR SULFATING TITANIFEROUS MATERIAL No Drawing. Filed June .14, 1955, Ser. No. 515,524
6 Claims. (Cl. 23-117) This invention relates to the solubilization of titan- :iferous materials and particularly to the preparation of soluble titanium sulfates suitable for use in the preparation of titanium dioxide pigments by hydrolysis. Still more particularly this invention relates to the prepara tion of such solutions from slags obtained by smelting iron from titanium bearing ores. V
vMethods of extracting the major portion of iron from titanium-iron ores, by high temperature electrothermic reduction and the formation of a titanium containing slag material are well known. For example, such methods are disclosed in US. Patent No. 2,476,453 issued to W. M. Pierce .et .al. The slags thus obtained, are a .source .of .titaniferous materials which are suitable for the preparation of acidic sulfate solutions and the subsequent recovery .of titanium dioxide pigments by hydrolytic precipitation.
A particular advantage of this slag material as a titanium source is that it contains a relatively small amount of iron. On the other hand, a large amount of the titanium :(i.e., from 5-.25'% calculated as TiO is contained in the slag in the trivalent state, and this :trivalent titaniumreductively decomposes the sulfuric acid .used in {thesolubilizing process (also known as the attacks) thus resulting .in the evolution of obnoxious fumes and the loss of .acid. i
it is among the objects of this invention to solubilize with the sulfuric acid, titaniferous materials containing "titaniumin a reduced valence state without appreciable loss of-the ,acid and the resulting evolution of :noxious, volatile decomposition products. It is a further object of this invention to provide a simplified process for .0011- trolling the impurity .content and the evolution of ob-v noxious fumes during the solubilization of trivalent titaniferous materials With sulfuric acid.
These and other objects of the invention are accomplished by providing an improved process for :sulfating .a .titaniferons material containing titanium in the trivalent state which comprises reacting the titaniferousjm'aterial with strong sulfuric acid in the presence of a simple ferric iron compound. The .amount .of ferric iron compound which is used may be equal to or greater than that which is theoretically required for the ferric compound to oxidize the trivalent titanium of the slag to the tetravalent state. Of course, amounts substantially less than theoretical :may be used; in fact, it has been unexpectedly found that amounts down to 2-10% of the theoretical are also elfective. At the completion of the reaction a :solid mass containing soluble titanium compounds is obtained, and this mass is dissolved in an aqueous solvent. It should be noted that the present invention is concerned with the use of simple ferric iron compounds as distinguished from ferric iron compounds which contain metals other than iron in the combined state. These latter materials of which ilmenite and arizonite ted States Patent '2 are examples are not within the scope of this invention. The probable function of the simple ferric iron compounds is that of an oxidizing agent.
In a preferred embodiment, our improved process for 5 .sulfating titaniferous slag material containing titanium in the trivalent state comprises reacting the titaniferous material with strong sulfuric acid in the presence of a simple ferric iron compound in an amount ranging from about 210% of the theoretical amount required to oxidize the trivalent titanium to the tetravalent state. At the completion of the reaction a solid mass conaining soluble trivalent and tetravalent titanium compounds is obtained, and this mass is dissolved in an aqueous solvent. In this aspect of the invention, oxidizing agents such as hydrogen peroxide, sodium nitrate and nitric acid are also effective in the same manner as the ferric iron compounds.
In detail, our invention comprises admixing in a reaction vessel suitable for air agitation a finely ground titaniferous slag material, such as that which results from the electrosmelting of titaniferous ore from the Allard Lake Region of Canada, with at least a third of the strong sulfuric acid required for sulfation. Such slag usually contains from about -80% total titanium, calculated as titanium dioxide, and of this about 13-19% is in the reduced valence state. 2-10% of the amount of ,finely divided pigment grade iron oxide which would theoretically oxidize the trivalent titanium to tetravalent titanium is then added. This ferric iron oxide is readily dispersed in the sulfuric acid mixture and dissolves to :form ferric sulfate during the period of the attack while the temperature is rising and the sulfuric acid is strong enough and hot .enough to readily oxidize trivalent titanium. The sulfation reaction is initiated by raising the temperature of the acid-slag mixture. This can most conveniently be done by dilution, as described in US. Patent No. 1,889,027, or .by mixing other combinations of sulfuric acid, such as for example 60 B. and oleum. After initiation, the temperature rises slowly in a .period of about 4-5 minutes to a temperature in the range of 190-200 C. due to :the sulfation reaction. This temperature rise is accompanied by the production of large volumes of steam given off by the reaction, and at the end of the period the sulfation products are set up as a hard porous mass in the reaction vessel. While some improvement in overall .yield is usually obtained by holding the reaction mass at this elevated temperature for several hours, the sulfation is essentially complete at this time. This mass will contain a small amount, about 5-l0%, of unreacted slag, but otherwise it will be completely soluble. During the reaction substantially no noxious vaporized products (e.g., H 8 and S0 from the decomposition of the sulfuric acid are obtained. The titanium sulfate solution obtained by dissolving the mass in dilute acid (usually of about 510% strength) will contain about 5-20 grams per liter of trivalent titanium (expressed as TiO This can be oxidized quickly by "the addition of sodium nitrate, or allowed to be oxidized by the air used for agitation of the solution. Usually the trivalent titanium concentration is reduced to about 1-2 grams per liter (expressed as TiO for further processing. Duringthe reaction period, air is passed through the reaction mixture for agitation, but under the strong acid conditionsof the attack reaction, the air has no appreciable oxidizing effect upon the trivalent titanium as Example 1 Canadian slag obtained by electrosmelting titaniferous iron ore was analyzed as follows:
13.9% in the trivalent state; 55.7% in the tetravalent state.
This slag was reacted with the equivalent of 160 pounds of sulfuric acid of 100% H 80 per 100 pounds of slag by the following procedure. 15,000 pounds of 60 B. H 80 were placed in a 10,000 gallon reaction vessel with a conical bottom and 30,000 pounds of the above slag in finely ground condition were added. While agitating this mixture with air introduced from the bottom of the vessel, 300 pounds of pigment grade ferric oxide (82.5% Fe O 10.2% SiO equivalent to about 7.7% of the total requirement for the oxidation of all the trivalent titanium in the slag were then added to the acidslag mixture. The sulfation reaction was then initiated by the addition of 20,000 pounds of oleum and within about 45 minutes the temperature of the reaction mixture reached 190 C., and a few minutes later a hard porous mass of sulfated slag was obtained. This mass was held at temperature for three hours and then dissolved by adding dilute sulfuric acid and then water. By air agitating the solution for four hours the trivalent titanium content was reduced to about 2 grams per liter. The solution was then ready for clarification and hydrolysis. Analysis of the air-steam mixture evolved from the reaction indicated that less than about 0.4% of the sulfuric acid had been decomposed to form H 8, S and other decomposition products of H 50 A similar reaction made without the addition of Fe O to the acid-slag mixture resulted in a loss by reduction of sulfuric acid to H 5, S0 and other products of about 8% of the total H 80 added.
Example 2 Using the same slag and the same amount of sulfuric acid and slag as used in Example 1, 150 pounds of finely ground iron oxide (equivalent to about 3% of the total oxidation requirement of the trivalent titanium of the slag) were added just before the reaction started. The loss of sulfuric acid to reduction decomposition products including H 8 and S0 was less than about 1.5% of the total sulfuric acid used. The porous reaction mass, when dissolved in dilute sulfuric acid using air agitation produced a solution containing about 160 grams per liter of titanium (expressed as TiO about 20 grams per liter of which was in the trivalent state.
Methods of sulfation of titanium ores are well known. A convenient method, and one that has been generally utilized in performing of the present invention, is described in US. Patent No. 1,889,027. The sulfation reaction for the solubilization of the titanium content of slags may be carried out in the same type of equipment used previously for the sulfation of ilmenite, and for mixtures of slag and ilmenite. The reaction is analogous and only slight adjustments of the strength of acid used need be made. In general, the final acid strength should be within the range of about 85-95% H 50 usually between 89 and 93%, and it is obvious that one may use 96100% H 50 or oleum with water or steam or weaker acid to obtain optimum acid strength for the slag material being sulfated.
After being sulfated the slag reaction mass is dissolved in dilute sulfuric acid or water, and the solution may be adjusted to any final degree of reduction by further addition of oxidizing agents. This solution after suitable clarification can be hydrolyzed by usual methods. Satisfactory methods have been described in U.S. Patents Nos. 2,511,218 and 2,479,637 and Reissues 18,590, and 18,854.
Many simple ferric iron compounds can be utilized for the elemination of the noxious fumes evolved during sulfation of titaniferous slag containing trivalent titanium. The preferred material for such use is ferric oxide which can be obtained in a finely divided state free from unwanted contaminating impurities. Examples of other satisfactory simple ferric iron compounds include ferric sulfate, ferric sulfate dissolved in dilute sulfuric acid, oxidized copperas or basic ferric sulfate, magnetite, hematite, limonite, and ferric ammonium sulfate.
The present invention offers several distinct advantages. As the examples show, the loss of sulfuric acid is reduced to a minimum thereby eliminating the presence of obnoxious fumes in the air and steam mixture which is evolved from the sulfation reaction. The absence of these fumes in the latter mixture overcomes the necessity for costly processes of scrubbing to prevent air pollution. A further advantage resides in the fact that minor amounts of relatively pure oxidizing agents are used in the process, thus improving the quality of the final pigment product.
We claim:
1. An improved process for sulfating a titaniferous material containing titanium in the trivalent state which comprises reacting said titaniferous material with strong sulfuric acid in the presence of an oxidizing agent selected from the group consisting of ferric iron oxides, ferric iron sulfates, hydrogen peroxide, sodium nitrate, and nitric acid, said oxidizing agent being present in an amount ranging from about 2 to 10% of the theoretical quantity required to oxidize the trivalent titanium to the tetravalent state, obtaining a solid mass containing soluble titanium compounds, and dissolving said mass in an aqueous solvent.
2. An improved process for sulfating a titaniferous material containing titanium in the trivalent state which comprises reacting said titaniferous material with strong sulfuric acid in the presence of a ferric iron oxide in an amount ranging from about 2-10% of the theoretical quantity required to oxidize the trivalent titanium to the tetravalent state, obtaining a solid mass containing soluble titanium compounds and dissolving said mass in an aqueous solvent.
3. The process of claim 2 in which the ferric iron oxide is substantially pure ferric oxide.
4. The process of claim 2 in which the ferric iron oxide is hematite.
5. The process of claim 2 in which the ferric iron oxide is limonite.
6. The process of claim 1 in which the oxidizing agent is ferric sulfate.
Dana: A Textbook of Mineralogy, pages 483-485 and 505-6, 4th edition, 1932, John Wiley and Sons, NY.

Claims (1)

1. AN IMPROVED PROCESS FOR SULFATING A TITANIFEROUS MATERIAL CONTAINING TITANIUM IN THE TRIVALENT STATE WHICH COMIPRISES REACTING SAID TITANIFEROUS MATERIAL WITH STRONG SULFURIC ACID IN THE PRESENCE OF AN OXIDIZING AGENT SELECTED FROM THE GROUP CONSISTING OF FERRIC IRON OXIDES, FERRIC IRON SULFATES, HYDROGEN PEROXIDE, SODIUM NITRATE, AND NITRIC ACID, SAID OXIDIZING AGENT BEING PRESENT IN AN AMOUNT RANGING FROM ABOUT 2 TO 10% OF THE THEORETICAL QUANTITY REQUIRED TO OXIDIZE THE TRIVALENT TITANIUM TO THE TETRAVALENT STATE, OBTAINING A SOLID MASS CONTAINING SOLUBLE TITANIUM COMPOUNDS, AND DISSOLVING SAID MASS IN AN AQUEOUS SOLVENT.
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3149963A (en) * 1961-04-14 1964-09-22 British Titan Products Process relating to ore beneficiation
US3170771A (en) * 1961-01-30 1965-02-23 Continental Titanium Corp Apparatus for continuous digestion of titanium bearing materials
DE2951799A1 (en) * 1979-12-21 1981-07-02 Bayer Ag, 5090 Leverkusen METHOD FOR PRODUCING A HYDROLYZABLE TITANYL SULFATE SOLUTION
EP0031062A3 (en) * 1979-12-21 1981-10-07 Bayer Ag Leaching of ternary starting mixtures
US4325920A (en) * 1980-11-12 1982-04-20 Qit-Fer Et Titane Du Quebec, Inc. Method to oxidize Ti+3 during the sulfuric acid digestion of titaniferous slags
DE10255262A1 (en) * 2002-11-27 2004-06-09 Sachtleben Chemie Gmbh Process for the oxidation of Ti3 + to Ti4 + in the production of titanium dioxide using the sulfate process

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2631924A (en) * 1951-03-24 1953-03-17 Du Pont Preparation of hydrolyzable titanium sulfate solutions

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2631924A (en) * 1951-03-24 1953-03-17 Du Pont Preparation of hydrolyzable titanium sulfate solutions

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3170771A (en) * 1961-01-30 1965-02-23 Continental Titanium Corp Apparatus for continuous digestion of titanium bearing materials
US3149963A (en) * 1961-04-14 1964-09-22 British Titan Products Process relating to ore beneficiation
DE2951799A1 (en) * 1979-12-21 1981-07-02 Bayer Ag, 5090 Leverkusen METHOD FOR PRODUCING A HYDROLYZABLE TITANYL SULFATE SOLUTION
EP0031062A3 (en) * 1979-12-21 1981-10-07 Bayer Ag Leaching of ternary starting mixtures
US4325920A (en) * 1980-11-12 1982-04-20 Qit-Fer Et Titane Du Quebec, Inc. Method to oxidize Ti+3 during the sulfuric acid digestion of titaniferous slags
DE10255262A1 (en) * 2002-11-27 2004-06-09 Sachtleben Chemie Gmbh Process for the oxidation of Ti3 + to Ti4 + in the production of titanium dioxide using the sulfate process
EP1426335A3 (en) * 2002-11-27 2008-12-03 Sachtleben Chemie GmbH Process for the oxidation of Ti3+ to Ti4+ during titanium dioxide preparation according to the sulphate process
DE10255262B4 (en) * 2002-11-27 2015-02-12 Sachtleben Chemie Gmbh Process for the oxidation of Ti3 + to Ti4 + in the production of titanium dioxide by the sulphate process

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