US2918438A - Pigment starch paper coating composition containing polymethylol carbamyl polyazaalkane resins and article coated therewith - Google Patents
Pigment starch paper coating composition containing polymethylol carbamyl polyazaalkane resins and article coated therewith Download PDFInfo
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- US2918438A US2918438A US577451A US57745156A US2918438A US 2918438 A US2918438 A US 2918438A US 577451 A US577451 A US 577451A US 57745156 A US57745156 A US 57745156A US 2918438 A US2918438 A US 2918438A
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- United States
- Prior art keywords
- coating
- pigment
- paper
- polyazaalkane
- resin
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- 239000000049 pigment Substances 0.000 title claims description 24
- 229920005989 resin Polymers 0.000 title description 39
- 239000011347 resin Substances 0.000 title description 39
- 229920002472 Starch Polymers 0.000 title description 29
- 239000008107 starch Substances 0.000 title description 28
- 235000019698 starch Nutrition 0.000 title description 22
- 239000008199 coating composition Substances 0.000 title description 19
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 title 1
- 238000000576 coating method Methods 0.000 claims description 29
- 239000011248 coating agent Substances 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 25
- 239000000853 adhesive Substances 0.000 claims description 16
- 230000001070 adhesive effect Effects 0.000 claims description 16
- 229920001187 thermosetting polymer Polymers 0.000 claims description 10
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 7
- 239000011707 mineral Substances 0.000 claims description 7
- 239000012530 fluid Substances 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims 1
- 239000001913 cellulose Substances 0.000 claims 1
- 239000000123 paper Substances 0.000 description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 125000002091 cationic group Chemical group 0.000 description 10
- 239000002253 acid Substances 0.000 description 9
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000003086 colorant Substances 0.000 description 7
- 239000004927 clay Substances 0.000 description 6
- 235000010755 mineral Nutrition 0.000 description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 230000021235 carbamoylation Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- -1 amelide Chemical compound 0.000 description 3
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 3
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 125000005263 alkylenediamine group Chemical group 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229960003563 calcium carbonate Drugs 0.000 description 2
- 235000010216 calcium carbonate Nutrition 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 2
- YHRUOJUYPBUZOS-UHFFFAOYSA-N 1,3-dichloropropane Chemical compound ClCCCCl YHRUOJUYPBUZOS-UHFFFAOYSA-N 0.000 description 1
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- ZAXCZCOUDLENMH-UHFFFAOYSA-N 3,3,3-tetramine Chemical compound NCCCNCCCNCCCN ZAXCZCOUDLENMH-UHFFFAOYSA-N 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- QGLZXHRNAYXIBU-UHFFFAOYSA-N aldicarb Chemical compound CNC(=O)ON=CC(C)(C)SC QGLZXHRNAYXIBU-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
- 150000001913 cyanates Chemical class 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- QYXHJMXBZWOTJN-UHFFFAOYSA-N formaldehyde;guanidine Chemical compound O=C.NC(N)=N QYXHJMXBZWOTJN-UHFFFAOYSA-N 0.000 description 1
- 239000003966 growth inhibitor Substances 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- GKQPCPXONLDCMU-CCEZHUSRSA-N lacidipine Chemical compound CCOC(=O)C1=C(C)NC(C)=C(C(=O)OCC)C1C1=CC=CC=C1\C=C\C(=O)OC(C)(C)C GKQPCPXONLDCMU-CCEZHUSRSA-N 0.000 description 1
- 125000004184 methoxymethyl group Chemical group [H]C([H])([H])OC([H])([H])* 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 235000013808 oxidized starch Nutrition 0.000 description 1
- 239000001254 oxidized starch Substances 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 150000003567 thiocyanates Chemical class 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/54—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Definitions
- the present invention relates to fluid pigment-starch coating compositions useful for producing coated paper of improved wet-rub resistance, and to paper coated therewith. More particularly, the present invention relates to such coating compositions containing a small but eflective amount of a normally water-soluble thermosetting cationic polyazaalkane resin as supplementary water-resistant adhesive for said starch.
- Aqueous pigment-starch coating compositions for paper are widely employed at the present time in the paper industry for the manufacture of glossy paper such as is generally used for magazines, catalogues, book jackets, etc. and for the manufacture of coated paperboard, insulating board and the like.
- the pigment is generally clay, and the principal function of the starch is to act as adhesive for the pigment.
- coated paper containing starch as the adhesive is that the paper possesses practically no wet-rub resistance, and thus the appearance of such paper may be ruined beyond practicalrepair even by a few drops of water.
- Mineral pigment-starch coating compositions for paper are generally formulated to contain to 25 parts by weight of starch per 100 parts of pigment therein, and sufficient water is provided to produce a fluid composition having a suitable viscosity for the application method intended, the solids content of the composition being from about 20% to about 75% by weight.
- the pigment may be clay, titanium dioxide, lithopone, satin white, blanc fixe, etc. and the principal types of starches used as adhesives are dextrin, oxidized starch, enzyme-converted starch, and chlorinated starch.
- compositions usually contain minor amounts of materials added to impart special properties such as an alkali or a phosphate salt to maintain the pigment in defiocculated condition, casein, wax sizes, viscosity decreasing agents such as are shown in US. Patents Nos. 2,566,861 and 2,566,- 862, colored pigments such as ultramarine, perfume, mold growth inhibitors, etc.
- Coating compositions having an acid pH are disadvantageous for a number of important reasons. In the first place, low pH retards penetration of the coating composition into the surface of the paper resutling in inferior adhesion. Secondly, coated papers are very commonly employed for offset printing, and acidity retards 2,918,438 Patented Dec. 22, 1959 the rate at which ofiset inks dry. Thirdly, acid conditions favor flocculation of pigment in the coating composition with undesirable increase in viscosity resulting in decrease of machine speed. Fourthly, acid coating compositions are troublesome to handle in that they tend to cause corrosion of any steel equipment with which they come in contact. Finally, acid-sensitive pigments such as ordinary ultramarine blue are bleached or turned offcolor by incorporation in such compositions. The compositions of the present invention are improvements over the compositions of the patent.
- coating colors of the present invention need not contain any acid catalyst and thus may be applied at an alkaline pH, values up to about 9.5 being fully suitable. Even at the latter value, conversion of the resin to hydrophobic or cured form is so rapid that highly water-resistant coatings are obtainable on normal high-temperature machine cure or after a conventional cure of only a few days at room temperature. The coating is thus fully useful without acid when applied either in conventional manner or on the machine as may be desired. At alkaline pH values the pigment is in well-deflocculated form and acid sensitive pigments such as ultramarine do not deteriorate when blended therewith.
- compositions of the present invention may thus be described as fluid aqueous coating colors comprising a major amount of a paper-coating mineral pigment as principal coating component, a minor amount of a papercoating starch as principal adhesive for the pigment, and a small but effective amount of a water-soluble cationic thermosetting polymethylolcarbamyl polyazaalkane resin as supplementary adhesive.
- the pH of the composition preferably but not necessarily is alkaline, and the composition may contain such added components as are customarily present in paper-coating compositions.
- pigment-starch coating compositions become so strongly wet-rub resistant even at an alkaline pH when containing only a small amount of polymethylolcarbamyl polyazaalkane resin is unknown, and we do not wish to be restricted to any particular theory.
- the principal raw material of the resins of the patent are amino constituents (urea, melamine, etc.) having a molecular weight less than 250, whereas the principal raw material of the resins used in making the coating colors of the present invention are polyazaalkanes having molecular Weights in excess of, and usually very greatly in excess of 1000. This larger molecular size may be the cause of the superior behavior of the resin at alkaline pH values.
- compositions according to the present invention as supplementary water-resistant adhesive are small. A distinct improvement is noted when the amount of resin is as little as 2 /2% of the weight of the starch. Evidently, then, there is no amount of resin however small which will not confer at least some improvement. 0n the other hand, no great additional increase in water-resistance is obtained when the resin becomes the major component of the adhesive. Thus compositions wherein the resinzstarch ratio are in excess of 50:50 are not within the scope of,
- the coating compositions of the present invention may be prepared by forming an aqueous paper-coating starch solution, thoroughly blending therein an aqueous solution of the resin, adjusting the pH of the solution to a value above 6 (the minimum value at which pigment dispersions remain stable) and then mixing the pigment (preferably as a deflocculated aqueous slurry) with the starch solution.
- the pigment slurry and starch may be mixed followed by addition of pigment.
- the supplementary materials such as viscosity depressants, colorants etc. are best added last. Compositions affording somewhat better wet rub resistance are generally obtained when the resin is added to the starch before the starch is cooked and this is therefore preferred.
- the cationic polymethylolcarbamyl polyazaalkane resins referred to above may be prepared in a number of ways. Three principal steps are involved: preparation of a water-soluble polyazaalkane; carbamylation; and conversion of the carbamylated polyazaalkane to thermosetting form by introducing methylol groups.
- the polyazaalkanes are high molecular weight polyalkylenepolyamines, and may be prepared in a number of ways. According to one method, a water-soluble alkylenediamine such as ethylenediamine, 1,3-propanediamine, etc. is reacted with an alkylene dichloride such as 1,3-dichloropropane containing not more than 6 carbon atoms or an equivalent mixture of dichloroalkanes. The reaction is'advantageously performed in the presence of an acid acceptor and preferably a slight molar excess of amine is used over that theoretically necessary so as to ensure development of a polymer of maximum molecular size. In similar manner an intermediate polyalkylenepolyamine may be employed such as triethylenetetramine, tripropylenetetramine, 3,3-iminobispropylamine, etc. in place of the alkylenediamines.
- an intermediate polyalkylenepolyamine may be employed such as triethylenetetramine, tripropylene
- a suitable high molecular weight polyazaalkane may be prepared by homopolymerizing ethylenimine and similar alkylenimines. The corresponding high molecular weight polyalkylenepolyamines are obtained.
- the polyazaalkanes become suitable as raw materials for the resins described above when their molecular size is such that their viscosity as 60% aqueous solutions at 25 C. is at least about N on the Gardner-Holdt scale. Results improve as the molecular size of the polyalkylenepolyamine increases, and there is no limit to their maximum molecular size except that of convenience, the range of useful molecular size ending when the polymer is barely pourable. Wet-rub resistance of the applied coating improves rapidly as the viscosity of the polyazaalkane rises.
- We prefer the minimum viscosity of the polyalkylenepolyamine to be A on the Gardner-Holdt scale as 33% aqueous solutions at 25 C. and in practice we employ polymers having a viscosity of T or more at the same dilution on the same scale.
- the polyazaalkanes may be substantially completely straight chained as in the case of polymerized ethylenimine, or may contain 6 membered rings as part of the chain. Rings of this type form when 3,3-iminobispropylamine is condensed with ethylene dichloride.
- The. polyalkylenepolyamine chains may carry such substituents as do not interfere with the essential characteristics of basicity and water-solubility.
- substituents which may be carried include non-ionic hydrophobic and hydrophilic substituents represented by aryl (phenyl, totyl, xylyl, methoxyphenyl) alkyl (methyl, ethyl, phenethyl); methoxymethyl; and cationic substituents including quaternary ammonium, amine, amide, and hydroxy substituents.
- the carbamylation or thiocarbamylation step may be performed by reacting a water-soluble polyazaalkane with urea, thiourea or similar material so as to unite the reagents with evolution of ammonia.
- the condensation may beperformed in a ball mill at -200 C. or with the reagents in aqueous medium at reflux temperature.
- the carbamylated or thiocarbamylated polyalkylenepolyamine is'reacted with formaldehyde or other suitable aldehyde to form a thermosetting resin.
- the resins are complex and are therefore most conveniently described as resins corresponding to those formed by first reacting a salt of a water-soluble polyalkylenepolyamine having a molecular size such that an aqueous solution containing 60% by weight of resin solids has a viscosity at 25 C. of at least M on the Gardner-Holdt scale, with a material selected from the group consisting of the water-soluble metal cyanates and thiocyanates, and then reacting with suflicient formaldehyde to form a water-soluble thermosetting resin.
- Example I The following illustrates the manufacture of a series of coating compositions according to the present invention and the preparation of coated paper of high wet-rub resistance therewith.
- thermosetting resin was prepared by reacting 31.7 parts of ethylene dichloride and 53.1 parts of 3,3'-iminobispropylamine in 20.2 parts of water, the temperature being controlled so that it slowly rose to reflux.
- reaction of theethylene dichloride was complete, the reaction mixture was cooled to 35 C. and 81.2 parts of water and 65.4 parts of 32% HCl were slowly added, the exotherm being controlled by cooling.
- the mixture was again cooled to 35 C. and 104 parts of KCNO added and the mixture maintained at 70 C. for 30 minutes. There were then added 112 parts of Water and 197 parts of 37% formalin and the mixture allowed to react at 75 C. for 90 minutes after which 335 parts of water were added and the mixture cooled to 30 C. to stop the reaction.
- the resulting aqueous solution had an alkaline pH.
- the coating colors were formed by stirring the-clay dispersions into the adhesive compositions thus prepared and stirring for one hour.
- the pH values and Brookfield viscosities of the colors were determined and are shown in the table below.
- the coating colors thus obtained were coated on a 50- lb. basis weight sulfide-soda raw stock at a coating weight of about 15 lbs. per ream using a laboratory doctor blade coater. Sheets were dried as shown in the table below,
- the wet-rub values were determined by the finger method wherein the coated sheet is laid fiat with black coating being subject to removal in this manner.
- a value of 10 designates a substantially completely wet-rub resistant coating, the value indicating that practically none of the coating could be rubbed off in the manner described.
- Intermediate values deslgnate intermediate results.
- Run A shows that the control coating possessed no water resistance regardless of the temperature at which the paper was dried.
- Run A shows that the presence of only a very minor amount of the cationic resin (5% on the weight of the starch or 1% on the weight of the clay) caused a significant increase in the wet-rub resistance both in the case of the oven-dried paper and in the case of paper which had been merely air dried.
- Runs B and C show that 7.5% and 10% of the resin gave coatings which received maximum ratings.
- the table further shows a very beneficial increase in wax pick values resulting from presence of the resin and demonstrates that the foregoing improvements were obtained without any significant sacrifice to gloss.
- Example 2 comprising a major amount of a paper-coating mineral pigment as principal coating component, a minor amount of a paper coating starch as principal adhesive for said pigment, and a small but efiective amount of a water-soluble cationic thermosetting polymethylolcarbamyl polyazaalkane resin'as supplementary adhesive.
- composition according to claim 1 wherein the pH of said composition is between 7 and 9.5.
- a composition according to claim 1 wherein the paper-coating mineral pigment comprises calcium carbonate.
- thermoset form A web according to claim 4 wherein the cationic resin is in thermoset form.
Description
United States Patent() 2,918,438 PIGMENT STARCH PAPER COATING COMPOSI- TION CONTAINING POLYMETHYLOL CARBA- MYL POLYAZAALKANE RESINS AND ARTICLE COATED THEREWITH Daniel D. Ritson, Riverside, and Yun Jen, Stamford, Conn., assignors to American Cyanamid Company, New York, N.Y., a corporation of Maine No Drawing. Application April 11, 1956 Serial No. 577,451
5 Claims. (Cl. 260-173 The present invention relates to fluid pigment-starch coating compositions useful for producing coated paper of improved wet-rub resistance, and to paper coated therewith. More particularly, the present invention relates to such coating compositions containing a small but eflective amount of a normally water-soluble thermosetting cationic polyazaalkane resin as supplementary water-resistant adhesive for said starch.
Aqueous pigment-starch coating compositions for paper are widely employed at the present time in the paper industry for the manufacture of glossy paper such as is generally used for magazines, catalogues, book jackets, etc. and for the manufacture of coated paperboard, insulating board and the like. The pigment is generally clay, and the principal function of the starch is to act as adhesive for the pigment.
The principal disadvantage of coated paper containing starch as the adhesive is that the paper possesses practically no wet-rub resistance, and thus the appearance of such paper may be ruined beyond practicalrepair even by a few drops of water.
Mineral pigment-starch coating compositions for paper are generally formulated to contain to 25 parts by weight of starch per 100 parts of pigment therein, and sufficient water is provided to produce a fluid composition having a suitable viscosity for the application method intended, the solids content of the composition being from about 20% to about 75% by weight. The pigment may be clay, titanium dioxide, lithopone, satin white, blanc fixe, etc. and the principal types of starches used as adhesives are dextrin, oxidized starch, enzyme-converted starch, and chlorinated starch. In addition the compositions usually contain minor amounts of materials added to impart special properties such as an alkali or a phosphate salt to maintain the pigment in defiocculated condition, casein, wax sizes, viscosity decreasing agents such as are shown in US. Patents Nos. 2,566,861 and 2,566,- 862, colored pigments such as ultramarine, perfume, mold growth inhibitors, etc.
A number of such pigment-starch coating compositions and methods for the preparation thereof are disclosed in chapter XVIII of the book Pulp and Paper by James P. Casey, vol. II, copyright 1952 by Interscience Publishers, Inc.
US. Patent No. 2,399,489, granted on April 30, 1946, to C. G. Landes discloses that coating compositions containing a carbamyl-amine-aldehyde resin such as urea-, thiourea-, melamine-, amelide, or guanidine-formaldehyde resins possess considerable water resistance when applied to paper. The coating compositions of the patent are acid as required to cause conversion of the resin to water-resistant or hydrophobic form.
Coating compositions having an acid pH, however, are disadvantageous for a number of important reasons. In the first place, low pH retards penetration of the coating composition into the surface of the paper resutling in inferior adhesion. Secondly, coated papers are very commonly employed for offset printing, and acidity retards 2,918,438 Patented Dec. 22, 1959 the rate at which ofiset inks dry. Thirdly, acid conditions favor flocculation of pigment in the coating composition with undesirable increase in viscosity resulting in decrease of machine speed. Fourthly, acid coating compositions are troublesome to handle in that they tend to cause corrosion of any steel equipment with which they come in contact. Finally, acid-sensitive pigments such as ordinary ultramarine blue are bleached or turned offcolor by incorporation in such compositions. The compositions of the present invention are improvements over the compositions of the patent.
The discovery has now been made that aqueous mineral pigment-starch paper-coating compositions are greatly improved by the presence therein of a minor amount of a water-soluble cationic thermosetting polymethylolcarbamyl polyazaalkane resin. We have found that when paper is coated with mineral pigment-starch compositions containing a minor amount of the resin described, the wet-rub resistance of the coated paper after drying is much higher than would otherwise be the case.
It is a principal advantage of coating colors of the present invention that they need not contain any acid catalyst and thus may be applied at an alkaline pH, values up to about 9.5 being fully suitable. Even at the latter value, conversion of the resin to hydrophobic or cured form is so rapid that highly water-resistant coatings are obtainable on normal high-temperature machine cure or after a conventional cure of only a few days at room temperature. The coating is thus fully useful without acid when applied either in conventional manner or on the machine as may be desired. At alkaline pH values the pigment is in well-deflocculated form and acid sensitive pigments such as ultramarine do not deteriorate when blended therewith.
The compositions of the present invention may thus be described as fluid aqueous coating colors comprising a major amount of a paper-coating mineral pigment as principal coating component, a minor amount of a papercoating starch as principal adhesive for the pigment, and a small but effective amount of a water-soluble cationic thermosetting polymethylolcarbamyl polyazaalkane resin as supplementary adhesive. The pH of the composition preferably but not necessarily is alkaline, and the composition may contain such added components as are customarily present in paper-coating compositions.
The reason why pigment-starch coating compositions become so strongly wet-rub resistant even at an alkaline pH when containing only a small amount of polymethylolcarbamyl polyazaalkane resin is unknown, and we do not wish to be restricted to any particular theory. We point out, however, that this improvement may be associated with the difference in molecular weight of the principal raw material employed. The principal raw material of the resins of the patent are amino constituents (urea, melamine, etc.) having a molecular weight less than 250, whereas the principal raw material of the resins used in making the coating colors of the present invention are polyazaalkanes having molecular Weights in excess of, and usually very greatly in excess of 1000. This larger molecular size may be the cause of the superior behavior of the resin at alkaline pH values.
The amount of cationic resin present in coating compositions according to the present invention as supplementary water-resistant adhesive is small. A distinct improvement is noted when the amount of resin is as little as 2 /2% of the weight of the starch. Evidently, then, there is no amount of resin however small which will not confer at least some improvement. 0n the other hand, no great additional increase in water-resistance is obtained when the resin becomes the major component of the adhesive. Thus compositions wherein the resinzstarch ratio are in excess of 50:50 are not within the scope of,
the invention. While the amount of cationic resin which need be present in any one instance is primarily determined by the use to which the paper coated therewith will be put, our results to date indicate that greatest improvement in wet-rub resistance conferred per increment of resin present occurs in the range of about 5%30% of resin based on the weight of the starch, and this range is therefore preferred.
The coating compositions of the present invention may be prepared by forming an aqueous paper-coating starch solution, thoroughly blending therein an aqueous solution of the resin, adjusting the pH of the solution to a value above 6 (the minimum value at which pigment dispersions remain stable) and then mixing the pigment (preferably as a deflocculated aqueous slurry) with the starch solution. Alternatively the pigment slurry and starch may be mixed followed by addition of pigment. The supplementary materials such as viscosity depressants, colorants etc. are best added last. Compositions affording somewhat better wet rub resistance are generally obtained when the resin is added to the starch before the starch is cooked and this is therefore preferred.
The cationic polymethylolcarbamyl polyazaalkane resins referred to above may be prepared in a number of ways. Three principal steps are involved: preparation of a water-soluble polyazaalkane; carbamylation; and conversion of the carbamylated polyazaalkane to thermosetting form by introducing methylol groups.
The polyazaalkanes are high molecular weight polyalkylenepolyamines, and may be prepared in a number of ways. According to one method, a water-soluble alkylenediamine such as ethylenediamine, 1,3-propanediamine, etc. is reacted with an alkylene dichloride such as 1,3-dichloropropane containing not more than 6 carbon atoms or an equivalent mixture of dichloroalkanes. The reaction is'advantageously performed in the presence of an acid acceptor and preferably a slight molar excess of amine is used over that theoretically necessary so as to ensure development of a polymer of maximum molecular size. In similar manner an intermediate polyalkylenepolyamine may be employed such as triethylenetetramine, tripropylenetetramine, 3,3-iminobispropylamine, etc. in place of the alkylenediamines.
Alternatively still, a suitable high molecular weight polyazaalkane may be prepared by homopolymerizing ethylenimine and similar alkylenimines. The corresponding high molecular weight polyalkylenepolyamines are obtained.
The polyazaalkanes become suitable as raw materials for the resins described above when their molecular size is such that their viscosity as 60% aqueous solutions at 25 C. is at least about N on the Gardner-Holdt scale. Results improve as the molecular size of the polyalkylenepolyamine increases, and there is no limit to their maximum molecular size except that of convenience, the range of useful molecular size ending when the polymer is barely pourable. Wet-rub resistance of the applied coating improves rapidly as the viscosity of the polyazaalkane rises. We prefer the minimum viscosity of the polyalkylenepolyamine to be A on the Gardner-Holdt scale as 33% aqueous solutions at 25 C. and in practice we employ polymers having a viscosity of T or more at the same dilution on the same scale.
The polyazaalkanes may be substantially completely straight chained as in the case of polymerized ethylenimine, or may contain 6 membered rings as part of the chain. Rings of this type form when 3,3-iminobispropylamine is condensed with ethylene dichloride. V
The. polyalkylenepolyamine chains may carry such substituents as do not interfere with the essential characteristics of basicity and water-solubility. substituents which may be carried include non-ionic hydrophobic and hydrophilic substituents represented by aryl (phenyl, totyl, xylyl, methoxyphenyl) alkyl (methyl, ethyl, phenethyl); methoxymethyl; and cationic substituents including quaternary ammonium, amine, amide, and hydroxy substituents.
The carbamylation or thiocarbamylation step may be performed by reacting a water-soluble polyazaalkane with urea, thiourea or similar material so as to unite the reagents with evolution of ammonia. The condensation may beperformed in a ball mill at -200 C. or with the reagents in aqueous medium at reflux temperature. We have found that generally better carbamylation is obtained by first forming the acid salt of the polyazaalkane and then reacting with a soluble metal cyanate or thiocyanate. The evidence is that the reaction should be carried to at least 25% of theoretical maximum completion, and complete carbamylation appears preferable.
In the third step, the carbamylated or thiocarbamylated polyalkylenepolyamine is'reacted with formaldehyde or other suitable aldehyde to form a thermosetting resin.
The particular manner in which the resins are prepared forms no part of the present invention.
The resins are complex and are therefore most conveniently described as resins corresponding to those formed by first reacting a salt of a water-soluble polyalkylenepolyamine having a molecular size such that an aqueous solution containing 60% by weight of resin solids has a viscosity at 25 C. of at least M on the Gardner-Holdt scale, with a material selected from the group consisting of the water-soluble metal cyanates and thiocyanates, and then reacting with suflicient formaldehyde to form a water-soluble thermosetting resin.
The invention will be more particularly described in connection with the examples which follow. These examples illustrate embodiments of the invention and are not to be construed in limitation thereof.
Example I The following illustrates the manufacture of a series of coating compositions according to the present invention and the preparation of coated paper of high wet-rub resistance therewith.
The thermosetting resin was prepared by reacting 31.7 parts of ethylene dichloride and 53.1 parts of 3,3'-iminobispropylamine in 20.2 parts of water, the temperature being controlled so that it slowly rose to reflux. When reaction of theethylene dichloride was complete, the reaction mixture was cooled to 35 C. and 81.2 parts of water and 65.4 parts of 32% HCl were slowly added, the exotherm being controlled by cooling. The mixture was again cooled to 35 C. and 104 parts of KCNO added and the mixture maintained at 70 C. for 30 minutes. There were then added 112 parts of Water and 197 parts of 37% formalin and the mixture allowed to react at 75 C. for 90 minutes after which 335 parts of water were added and the mixture cooled to 30 C. to stop the reaction. The resulting aqueous solution had an alkaline pH.
Four batches of clay slurry were prepared by vigorously agitating 503 parts of a kaolinite paper coating clay in 230 parts of slightly alkaline water containing 1 part of tetrasodium pyrophosphate and 0.5 parts of sodium carbonate as defiocculating agents.
Four adhesive solutions were prepared by cooking paper coating chlorinated starch at F. for 20 minutes, the cationic resin where present being added at the start of the cook, the cook pH being 8.5. The composition of the adhesives is shown in the table.
The coating colors were formed by stirring the-clay dispersions into the adhesive compositions thus prepared and stirring for one hour. The pH values and Brookfield viscosities of the colors were determined and are shown in the table below.
The coating colors thus obtained were coated on a 50- lb. basis weight sulfide-soda raw stock at a coating weight of about 15 lbs. per ream using a laboratory doctor blade coater. Sheets were dried as shown in the table below,
calendered, and their gloss, wax pick and wet-rub values determined.
The wet-rub values were determined by the finger method wherein the coated sheet is laid fiat with black coating being subject to removal in this manner. A value of 10 designates a substantially completely wet-rub resistant coating, the value indicating that practically none of the coating could be rubbed off in the manner described. Intermediate values deslgnate intermediate results.
Results were as follows.
Coating Color Control A B C Clay slurry, g1 734. 6 734. 5 734. 5 734. 5 Adhesive:
Coating starch 89.9%), g.... 100. 5 100. 5 100. 5 100. 5 'Water, 240. 218. 6 207. 3 196.0 Resin (15%), g N11 30.0 45. 0 60. 0
Total weight, g 1,075.0 1,083 6 1,087.3 1,091.0
Percentages:
Total solids, percent 55 55 55 55 Starch on clay percent 18 18 18 18 Resin on stare percent Nil 7. 5 Coating Color-Properties:
pH 7.6 s. o 8.1 8.1 Visc (Brkfld., 100 r.p m.)-- 1, 440 5, 000 5, 700 6, 040 Coated Paper-Propertie Gloss (Ingersoll) 39 38 38 40 5 Wax pick test (Denn1son). 6. 5 8 8 8 5 Wet Rub Test: Oven dry (1 min. at 300 F.). 0 8 10 10 Air Dry:
1 For composition see text above.
The table shows that the control coating possessed no water resistance regardless of the temperature at which the paper was dried. Run A shows that the presence of only a very minor amount of the cationic resin (5% on the weight of the starch or 1% on the weight of the clay) caused a significant increase in the wet-rub resistance both in the case of the oven-dried paper and in the case of paper which had been merely air dried.
6 a Runs B and C show that 7.5% and 10% of the resin gave coatings which received maximum ratings. The table further shows a very beneficial increase in wax pick values resulting from presence of the resin and demonstrates that the foregoing improvements were obtained without any significant sacrifice to gloss.
It is known as a result of subsequent work that comparable results are obtained when the pH is increased to as much as 9.5 due to the presence of calciumcarbonate as part of the pigment.
' Example 2 ance, comprising a major amount of a paper-coating mineral pigment as principal coating component, a minor amount of a paper coating starch as principal adhesive for said pigment, and a small but efiective amount of a water-soluble cationic thermosetting polymethylolcarbamyl polyazaalkane resin'as supplementary adhesive.
2. A composition according to claim 1 wherein the pH of said composition is between 7 and 9.5.
3. A composition according to claim 1 wherein the paper-coating mineral pigment comprises calcium carbonate.
4. A water-laid cellulosic web coated on at least one side with a composition according to claim 1.
5. A web according to claim 4 wherein the cationic resin is in thermoset form.
References Cited in the file of this patent UNITED STATES PATENTS 2,555,057 Porter et al. May 29, 1951 2,616,874 Yost et al. Nov. 4, 1952 FOREIGN PATENTS 474,601 Great Britain Apr. 1, 1937
Claims (1)
1. A FLUID AQUEOUS COMPOSITION USEFUL FOR PROVIDING CELLULOSE WEBS WITH COATINGS OF IMPROVED WET-RUB RESISTANCE, COMPRISING A MAJOR AMOUNT OF A PAPER-COATING MINERAL PIGMENT AS PRINCIPAL COATING COMPONENT, A MINOR AMOUNT OF A PAPER COATING STARCH AS PRINCIPAL ADHESIVE FOR SAID PIGMENT, AND A SAMLL BUT EFFECTIVE AMOUNT OF A WATER-SOLUBLE CATIONIC THERMOSETTING POLYMETHYLOLCARBAMYL POLYAZAALKANE RESIN AS SUPPLEMENTARY ADHESIVE.
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US577451A US2918438A (en) | 1956-04-11 | 1956-04-11 | Pigment starch paper coating composition containing polymethylol carbamyl polyazaalkane resins and article coated therewith |
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US577451A US2918438A (en) | 1956-04-11 | 1956-04-11 | Pigment starch paper coating composition containing polymethylol carbamyl polyazaalkane resins and article coated therewith |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3138566A (en) * | 1960-01-08 | 1964-06-23 | Gen Mills Inc | Fluid resins prepared from epoxidized unsaturated fatty acids or esters |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB474601A (en) * | 1936-03-30 | 1937-11-01 | Ig Farbenindustrie Ag | Improvements in the manufacture and production of nitrogenous condensation products |
US2555057A (en) * | 1947-12-10 | 1951-05-29 | Warren S D Co | Process for the production of paper coating adhesives |
US2616874A (en) * | 1951-07-19 | 1952-11-04 | Rohm & Haas | Methylol derivatives of ureido-polyamines |
-
1956
- 1956-04-11 US US577451A patent/US2918438A/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB474601A (en) * | 1936-03-30 | 1937-11-01 | Ig Farbenindustrie Ag | Improvements in the manufacture and production of nitrogenous condensation products |
US2555057A (en) * | 1947-12-10 | 1951-05-29 | Warren S D Co | Process for the production of paper coating adhesives |
US2616874A (en) * | 1951-07-19 | 1952-11-04 | Rohm & Haas | Methylol derivatives of ureido-polyamines |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3138566A (en) * | 1960-01-08 | 1964-06-23 | Gen Mills Inc | Fluid resins prepared from epoxidized unsaturated fatty acids or esters |
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