US2853427A - Process of preparing lubricating oils - Google Patents
Process of preparing lubricating oils Download PDFInfo
- Publication number
- US2853427A US2853427A US510573A US51057355A US2853427A US 2853427 A US2853427 A US 2853427A US 510573 A US510573 A US 510573A US 51057355 A US51057355 A US 51057355A US 2853427 A US2853427 A US 2853427A
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- United States
- Prior art keywords
- employed
- oil
- clay
- resulting
- propane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
- C10G21/06—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents characterised by the solvent used
- C10G21/12—Organic compounds only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G21/00—Refining of hydrocarbon oils, in the absence of hydrogen, by extraction with selective solvents
- C10G21/003—Solvent de-asphalting
Definitions
- This invention relates to lubricating oil compositions and in particular relates to a process for obtaining improved non-additive-lubrioating oil oompositionsespecially adapted for use in aircraft engines.
- the production of lubricating oils is in many respects an essentially empirical art notwithstanding the intensive research activity in this field.
- the applicability of a given processing step on a certain oil fraction derived from a defined crude is not necessarily conclusive that such processing step will even aid a comparable oil deriv'edfronr an entirely different base stock.
- the present invention relates particularly to a method of producing refined heavy mineral lubricating oil stocks, and compositions containing them, from intermediate or mixed base crudes such as East Texas and sweet West Texas reduced crudes.
- Lubricating oil stock, and compositions prepared therefrom, which are produced according to our invention are characterized by a low corrosion indication by the MacCoull-Ryder corrosionoxidation test (lead loss from a lead-lined steel bearing).
- the invention is effected by subjecting a defined feed stock to a particular series of refining operations including deasphalting, phenol treating, dewaxing and clay contacting.
- Improved lubricating oil fractions are produced according to our invention from heavy residua or reduced crudes of intermediate or mixed base crudes such as East Texas or sweet West Texas reduced crude or a blend of such crudes.
- Reduced crudes are the bottoms resulting upon distilling a crude oil to recover the naturally occurring gasoline, kerosene and similar light products.
- reduced crudes or heavy residua having viscosities of at least about 400 S. U. S. at 210 F., for example, viscosities of from about 400 to 750 S. U. S. at 210 F., are employed.
- the reduced crudes are subjected to a very critical series of steps which, in general, consist of contacting the feed fraction with a particular "Ice 2.
- the reduced crude in the first of the sequential operations which must be employed in our invention is contacted withabout 6 to 12 volumes of liquid propane, advantageously in a liquid-liquid contacting tower, at a tower top temperature of about 160 to 185 F the particular amount of propane and particular temperature employed being chosen to result in a highly selective dcasphalted yield of about 40 to 59 volume percent based on the reduced crude feed.
- the deasphalting step can be accomplished in any of the equipment which is now conventional in the art for liquid-liquid contact.
- the propane normally is recovered by flashing it from the deasphalted fraction.
- the deasphalted oil is-then contacted with about 2 to6 volumes of phenol at a temperature of about 180 to 220 F. in any known manner to produce a rafiinate.
- the amount of phenol and the temperature employed are chosen to result in a ratfinate having, a vi-s cosity index of about 94 to 103.
- the raffinate is then dewaxed both to remove the normal parafiinic waxes and the microcrystalline waxes such as petrolatum. Conditions, equipment and the like employed in dewaxing are well known.
- the temperatures employed during dewaxing normally are 0 to 20 F.
- the resulting dewaxed material then, preferably, percolates through a neutral clay, such as f-ullers earth or bauxite, at a temperature of about 100 to 300 F. and a yield rate of about 30 to 100 barrels per ton of clay employed.
- a neutral clay found to be especially suited for use in the present invention is available commercially as A-ttapulgus clay. While percolation constitutes the preferred clay treatment procedure, contact filtration also can be employed. Apparatus and procedures for clay treatment in accordance with the present invention may be those commonly employed in refinery operations.
- the resulting refined heavy lubricating oil fraction i. e. bright stock
- a portion of a lighter lubricating oil such as a neutral oil
- the resulting compositions contain about 5 to 20 volume percent of the neutral oil .and to volume percent of the bright stock.
- the neutral oils employed for the purpose of reducing viscosity to specification requirements can be those produced by conventional refinery procedure providing the resulting composition does not show a materially different lead loss than would the bright stock alone.
- Example A blend having a viscosity of 402 S. U. S. at 210 F. and consisting of 53 volume percent sweet West Texas reduced crude and 47 volume percent East Texas reduced crude was contacted with about 11.6 volumes of liquid propane in a liquid-liquid contacting tower at a tower top temperature of 169 F. to remove asphalts and recover a propane soluble fraction in an amount equivalent to about a 58.7 volume percent yield based on the blend.
- the propane was recovered by flashing and the deasphalted oil was then passed into a phenol treating unit and contacted with 2 volumes of phenol at a temperature of 190 F.
- the raffinate was then dewaxed employing 5 volumes of methylethyl ketone at F.
- the resulting dewaxed material was percolated through Attapulgus clay at a rate which resulted in a yield of 62 barrels per ton of clay. The temperature of the clay during the percolation was maintained at about 100 to 200 F.
- a lubricating oil composition was then made from the resulting refined bright stock by adding a neutral oil having a visocity of 600 S. U. S. at 100 F. to the bright stock until a viscosity of 1246 S. U. S. at 100 F. was ob tained.
- the resulting composition contained about 88 volume percent bright stock and 12 volume percent of the neutral oil.
- the composition was then subjected to carbon residue analysis and the MacCoull-Ryder test. The results obtained showed a carbon residue of 0.28 percent and a lead loss by the MacCoull-Ryder test of 11 mgs.
- the untreated blend had a lead bearing loss of well over 700 milligrams. It can be seen, therefore, that significant improvement resulted as the composition produced evidenced the very low lead loss of 11 mgs.
- the method of producing improved non-additive aircraft engine lubricating oil stock from mixed base reduced crudes which comprises contacting a mixed base reduced crude having a viscosity of at least about 400 S. U. S. at 210 F. with about 6 to 12 volumes of liquid propane at a temperature of about to 185 F. to obtain a deasphalted crude at a yield of about 40 to 59 volume percent based on the charge stock, extracting the resulting deasphalted oil with about 2 to 6 volumes of phenol at a temperature of about to 220 F.
Description
. 2,853,427 7 PROCESS OF PREPARING LUBRICATING OILS Herman R. Bentley, Hammond, Ind., and Maurice K.
Rauscli, Harvey, Ill., assignors to Sinclair Refining Company, New York, N. Y., a corporation of Maine No Drawing. Application May 23, 1955 Serial No. 510,573
1 Claim. (Cl. 19614.46)
This invention relates to lubricating oil compositions and in particular relates to a process for obtaining improved non-additive-lubrioating oil oompositionsespecially adapted for use in aircraft engines.
Certain manufacturers of aircraft engines have indicated that lubricating oil compositions having greater than a 500 milligram corrosion loss (lead loss of a lead coated steel bearing) as indicated by the MacC'oull-Ryder corrosion-oxidation test (see SAE Journal, August 1942) are considered excessively corrosive and advise Watchfulne'ss to avoid parts failure when such oils are in service. Frequently in manufacturing a saleable product the lead loss must be les than 50 milligrams. The need for reliable lubricants for aircraft engines is obvious since failu e to lubricate in service cannot be tolerated as a plurality of opportunities may not exist. Further, a lubricating oil composition requiring frequent tests as a controlon corrosion raises maintenance costs and can militate against its use. i
The production of lubricating oils is in many respects an essentially empirical art notwithstanding the intensive research activity in this field. The applicability of a given processing step on a certain oil fraction derived from a defined crude is not necessarily conclusive that such processing step will even aid a comparable oil deriv'edfronr an entirely different base stock. Thus, it is common procedure to produce lubricating oils having substantially the same characteristics from different base stocks by entirely different routes or processing steps. The present invention relates particularly to a method of producing refined heavy mineral lubricating oil stocks, and compositions containing them, from intermediate or mixed base crudes such as East Texas and sweet West Texas reduced crudes.
We have now discovered that an improved lubricating oil stock can be prepared, from an intermediate or mixed base crude, which is especially suitable as a non-additive aircraft engine lubricating oil. Lubricating oil stock, and compositions prepared therefrom, which are produced according to our invention are characterized by a low corrosion indication by the MacCoull-Ryder corrosionoxidation test (lead loss from a lead-lined steel bearing). The invention is effected by subjecting a defined feed stock to a particular series of refining operations including deasphalting, phenol treating, dewaxing and clay contacting.
Improved lubricating oil fractions are produced according to our invention from heavy residua or reduced crudes of intermediate or mixed base crudes such as East Texas or sweet West Texas reduced crude or a blend of such crudes. Reduced crudes are the bottoms resulting upon distilling a crude oil to recover the naturally occurring gasoline, kerosene and similar light products. For purposes of the invention reduced crudes or heavy residua having viscosities of at least about 400 S. U. S. at 210 F., for example, viscosities of from about 400 to 750 S. U. S. at 210 F., are employed. The reduced crudes are subjected to a very critical series of steps which, in general, consist of contacting the feed fraction with a particular "Ice 2. amount of liquid propaneat defined temperatures to obtain a deasphalted reduced crude which is then phenol extracted under defined conditions, dewaxed employing known techniques, and percolated through a neutral clay at a defined rate. It is essential in the invention that each of these steps be employed and that they be employed in the sequence disclosed and under the conditions hereinafter established. For example, it is essential in the-propane deasphalting step that sufiicient propane be employed at a particular temperature so that a yield of about 40 to 59 percent of deasphalted oil is obtained on the basis of the heavy reduced crude employed. While lower yields can be employed, higher yields generally result in whereas the same cr-ude deasphalted to a 50 percent yield showed only about a 7 mg. loss, all subsequent treatment on each crude being identical. Accordingly, the details disclosed hereinafter must be followed carefully in order to practicethe present invention and obtain the results described. i
The reduced crude in the first of the sequential operations which must be employed in our invention is contacted withabout 6 to 12 volumes of liquid propane, advantageously in a liquid-liquid contacting tower, at a tower top temperature of about 160 to 185 F the particular amount of propane and particular temperature employed being chosen to result in a highly selective dcasphalted yield of about 40 to 59 volume percent based on the reduced crude feed. The deasphalting step can be accomplished in any of the equipment which is now conventional in the art for liquid-liquid contact. The propane normally is recovered by flashing it from the deasphalted fraction. I
The deasphalted oil is-then contacted with about 2 to6 volumes of phenol at a temperature of about 180 to 220 F. in any known manner to produce a rafiinate. As a general rule the amount of phenol and the temperature employed are chosen to result in a ratfinate having, a vi-s cosity index of about 94 to 103. The raffinate is then dewaxed both to remove the normal parafiinic waxes and the microcrystalline waxes such as petrolatum. Conditions, equipment and the like employed in dewaxing are well known. How-ever, particularly satisfactory results are obtained when the methylethyl ketone process is employed using about 200 to 600 volume percent of the solvent per volume of rafi'lnate. The temperatures employed during dewaxing normally are 0 to 20 F. The resulting dewaxed material then, preferably, percolates through a neutral clay, such as f-ullers earth or bauxite, at a temperature of about 100 to 300 F. and a yield rate of about 30 to 100 barrels per ton of clay employed. A neutral clay found to be especially suited for use in the present invention is available commercially as A-ttapulgus clay. While percolation constitutes the preferred clay treatment procedure, contact filtration also can be employed. Apparatus and procedures for clay treatment in accordance with the present invention may be those commonly employed in refinery operations.
The resulting refined heavy lubricating oil fraction, i. e. bright stock, can be employed as such as an aircraft engine lubricating oilvor, in the event that its viscosity does not conform to specification viscosity, a portion of a lighter lubricating oil, such as a neutral oil, can be added to cut the material to the desired viscosity. Normally, where neutral oil is employed, the resulting compositions contain about 5 to 20 volume percent of the neutral oil .and to volume percent of the bright stock. The neutral oils employed for the purpose of reducing viscosity to specification requirements can be those produced by conventional refinery procedure providing the resulting composition does not show a materially different lead loss than would the bright stock alone.
The invention will be described further in conjunction with the following example, it being understood that the specific details disclosed are not to be considered limiting.
Example A blend having a viscosity of 402 S. U. S. at 210 F. and consisting of 53 volume percent sweet West Texas reduced crude and 47 volume percent East Texas reduced crude was contacted with about 11.6 volumes of liquid propane in a liquid-liquid contacting tower at a tower top temperature of 169 F. to remove asphalts and recover a propane soluble fraction in an amount equivalent to about a 58.7 volume percent yield based on the blend. The propane was recovered by flashing and the deasphalted oil was then passed into a phenol treating unit and contacted with 2 volumes of phenol at a temperature of 190 F. The raffinate was then dewaxed employing 5 volumes of methylethyl ketone at F. The resulting dewaxed material was percolated through Attapulgus clay at a rate which resulted in a yield of 62 barrels per ton of clay. The temperature of the clay during the percolation was maintained at about 100 to 200 F.
A lubricating oil composition was then made from the resulting refined bright stock by adding a neutral oil having a visocity of 600 S. U. S. at 100 F. to the bright stock until a viscosity of 1246 S. U. S. at 100 F. was ob tained. The resulting composition contained about 88 volume percent bright stock and 12 volume percent of the neutral oil. The composition was then subjected to carbon residue analysis and the MacCoull-Ryder test. The results obtained showed a carbon residue of 0.28 percent and a lead loss by the MacCoull-Ryder test of 11 mgs.
The untreated blend had a lead bearing loss of well over 700 milligrams. It can be seen, therefore, that significant improvement resulted as the composition produced evidenced the very low lead loss of 11 mgs.
In another experiment employing blends of the East Texas and sweet West Texas reduced crudes wherein the blends had viscosities which were below 400 S. U. S. at 210 F., i. e. 317 and 295 S. U. S., propane deasphalting was effected to a yield of 62.3 volume percent in one instance and to 65.1 volume percent in the second instance.
The runs were otherwise comparable to that of the example. The lead loss of the resulting bright stocks were not satisfactory being 496 mgs. in the instance of the 317 S. U. S. blend deasphalted to the 62.3 percent yield and 562 mgs. for the other blend.
In still another experiment, an intermediate base reduced crude evidencing a satisfactorily high viscosity, i. e. 480 S. U. S. at 210 F., was propane deasphalted to a 66 percent yield, with subsequent treatment being comparable to that of the example. The MacCoull-Ryder lead loss of the resulting bright stock was 475 mgs. Thus, it is apparent that both a high viscosity charge stock and a highly selective, highly severe propane deasphalting step must be employed to result in the low lead losses of the order of below mgs. of the lubricating oil stocks produced.
We claim:
The method of producing improved non-additive aircraft engine lubricating oil stock from mixed base reduced crudes which comprises contacting a mixed base reduced crude having a viscosity of at least about 400 S. U. S. at 210 F. with about 6 to 12 volumes of liquid propane at a temperature of about to 185 F. to obtain a deasphalted crude at a yield of about 40 to 59 volume percent based on the charge stock, extracting the resulting deasphalted oil with about 2 to 6 volumes of phenol at a temperature of about to 220 F. to obtain a Iaffinate, dewaxing the resulting raflinate, and percolating the resulting dewaxed rafiinate through a neutral clay at a yield rate of about 30 to 100 barrels per ton of clay at a temperature of about 100 to 300 F.
References Cited in the file of this patent Q UNITED STATES PATENTS 1,978,361 Beiswenger Oct. 23, 1934 2,143,882 Keith et a1. Jan. 17, 1939 2,215,359 Livingstonet a1. Sept. 17, 1940 2,255,283 Forrest Sept. 9, 1941 2,341,874 Lovell Feb. 15, 1944 2,346,127 Simpson et al Apr. 11, 1944 2,420,108 Stratford et a1. May 6, 1947 2,552,436 Bennett et al. May 8, 1951 2,570,044 Benedict et a1 Oct. 2, 1951 2,603,587 Simms July 15, 1952 2,687,982 Baumann Aug. 31, 1954
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US510573A US2853427A (en) | 1955-05-23 | 1955-05-23 | Process of preparing lubricating oils |
Applications Claiming Priority (1)
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US510573A US2853427A (en) | 1955-05-23 | 1955-05-23 | Process of preparing lubricating oils |
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US2853427A true US2853427A (en) | 1958-09-23 |
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US510573A Expired - Lifetime US2853427A (en) | 1955-05-23 | 1955-05-23 | Process of preparing lubricating oils |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2939838A (en) * | 1957-06-24 | 1960-06-07 | Texaco Inc | Petroleum treating process |
US3011974A (en) * | 1959-06-22 | 1961-12-05 | Gulf Research Development Co | Process for preparing a multiviscosity lubricating oil |
US3103972A (en) * | 1959-12-28 | 1963-09-17 | Phillips Petroleum Co | Miscible-fluid flooding technique |
US4764265A (en) * | 1985-07-26 | 1988-08-16 | Shell Oil Company | Process for the manufacture of lubricating base oils |
Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1978361A (en) * | 1932-05-03 | 1934-10-23 | Standard Oil Dev Co | Process for treating heavy residues |
US2143882A (en) * | 1935-08-15 | 1939-01-17 | Standard Oil Co | Propane deresinating |
US2215359A (en) * | 1936-06-10 | 1940-09-17 | Standard Oil Co | Solvent extraction |
US2255283A (en) * | 1938-11-21 | 1941-09-09 | Standard Oil Co | Refining of heavy oils |
US2341874A (en) * | 1942-05-11 | 1944-02-15 | Shell Dev | Manufacture of turbine oils |
US2346127A (en) * | 1941-03-20 | 1944-04-11 | Socony Vacuum Oil Co Inc | Treatment of solvent refined oils with adsorbents |
US2420108A (en) * | 1944-07-13 | 1947-05-06 | Standard Oil Dev Co | Process for treating a solvent-extracted petroleum distillate with clay and lime |
US2552436A (en) * | 1947-12-06 | 1951-05-08 | Standard Oil Dev Co | Process for treating lubricating oil with solid adsorbents |
US2570044A (en) * | 1948-12-23 | 1951-10-02 | Phillips Petroleum Co | Propane fractionation of reduced crude oil with recycle of a solvent extract |
US2603587A (en) * | 1950-01-04 | 1952-07-15 | Phillips Petroleum Co | Propane fractionation of lubricating oil stocks |
US2687982A (en) * | 1950-11-24 | 1954-08-31 | Standard Oil Dev Co | Combination deasphalting, phenol treating, and dewaxing process |
-
1955
- 1955-05-23 US US510573A patent/US2853427A/en not_active Expired - Lifetime
Patent Citations (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1978361A (en) * | 1932-05-03 | 1934-10-23 | Standard Oil Dev Co | Process for treating heavy residues |
US2143882A (en) * | 1935-08-15 | 1939-01-17 | Standard Oil Co | Propane deresinating |
US2215359A (en) * | 1936-06-10 | 1940-09-17 | Standard Oil Co | Solvent extraction |
US2255283A (en) * | 1938-11-21 | 1941-09-09 | Standard Oil Co | Refining of heavy oils |
US2346127A (en) * | 1941-03-20 | 1944-04-11 | Socony Vacuum Oil Co Inc | Treatment of solvent refined oils with adsorbents |
US2341874A (en) * | 1942-05-11 | 1944-02-15 | Shell Dev | Manufacture of turbine oils |
US2420108A (en) * | 1944-07-13 | 1947-05-06 | Standard Oil Dev Co | Process for treating a solvent-extracted petroleum distillate with clay and lime |
US2552436A (en) * | 1947-12-06 | 1951-05-08 | Standard Oil Dev Co | Process for treating lubricating oil with solid adsorbents |
US2570044A (en) * | 1948-12-23 | 1951-10-02 | Phillips Petroleum Co | Propane fractionation of reduced crude oil with recycle of a solvent extract |
US2603587A (en) * | 1950-01-04 | 1952-07-15 | Phillips Petroleum Co | Propane fractionation of lubricating oil stocks |
US2687982A (en) * | 1950-11-24 | 1954-08-31 | Standard Oil Dev Co | Combination deasphalting, phenol treating, and dewaxing process |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2939838A (en) * | 1957-06-24 | 1960-06-07 | Texaco Inc | Petroleum treating process |
US3011974A (en) * | 1959-06-22 | 1961-12-05 | Gulf Research Development Co | Process for preparing a multiviscosity lubricating oil |
US3103972A (en) * | 1959-12-28 | 1963-09-17 | Phillips Petroleum Co | Miscible-fluid flooding technique |
US4764265A (en) * | 1985-07-26 | 1988-08-16 | Shell Oil Company | Process for the manufacture of lubricating base oils |
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