US282604A - Apparatus for the manufacture of bituminous-coal coke - Google Patents
Apparatus for the manufacture of bituminous-coal coke Download PDFInfo
- Publication number
- US282604A US282604A US282604DA US282604A US 282604 A US282604 A US 282604A US 282604D A US282604D A US 282604DA US 282604 A US282604 A US 282604A
- Authority
- US
- United States
- Prior art keywords
- coke
- ovens
- oven
- bituminous
- furnace
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000571 coke Substances 0.000 title description 34
- 238000004519 manufacturing process Methods 0.000 title description 6
- 239000002802 bituminous coal Substances 0.000 title description 5
- 239000007789 gas Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000003245 coal Substances 0.000 description 8
- 238000001816 cooling Methods 0.000 description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 239000005864 Sulphur Substances 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000004939 coking Methods 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 206010022000 influenza Diseases 0.000 description 4
- 239000000446 fuel Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000003416 augmentation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Inorganic materials [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B15/00—Other coke ovens
- C10B15/02—Other coke ovens with floor heating
Definitions
- JOHN F. BENNETT OF PITTSBURG, PENNSYLVANIA.
- My invention relates to apparatus for the I manufacture of bituminous-coal coke, in which furnaces are provided for eliminating and flues for conducting off those gases of the coal whose absence is necessary to the formation of coke; and the objects of my improvements are, first, to utilize the fuel to approximate its entire heating capacity; second, to obtain a coke of porous structure, and yet of suflicient strength to withstand the pressure it is sub- 2 5 jected to in blast-furnaces; third, to expel the ovens.
- Figure 1 represents an elevation, partly in section, of the plantused in the operation of my invention.
- Fig. 2 is a plan view of the same, showing the hood partially broken and in section.
- Fig. 3' is a cross-section of the oven illustrated in Fig. 5.
- Fig. 4 is an elevation of the oven shown in Fig. 5.
- Fig. 5 is a longitudinal section of the coking-ovens I employ; and
- Fig. 6 is a plan view of the furnace, illustrating the construction of the fines.
- A represents the furnace, having ovens a a a, whose sides have flues b b b, which transmit the products of combustion by means of fines c c c to the main flues (Z (Z (Z, which conduct them through flue d under the boilers D, and
- O is the house or hood, capable of hermetic closure. It is connected with the boilers D by pipes E D andwith the gas-holder F by pipe F.
- G represents the chimney discharging the products of combustion received from flue d.
- I represents a suitable fan-blower to induce a current of the waste gases into. the gasholder F.
- the ovens a a a of the furnace A whose roofs are flat-arched to utilize the entire heating capacity of the fuel, are filled by spreading small coal, or, preferably, pulverized, washed, and dried coal therein, to a depth about ten inches, in such a manner that it shall lay evenly on the floor except next to the wall, where its depth is slightly less than the average, by which binding due to swelling is obviated.
- the coke obtained from the beehive ovens is the best now obtainable for use in blast-furnaces, and its desirability is gaged by it's porosity, that having been in the oven about twenty-four hours being preferred, and its de sirability lessened in proportion as the length of stay in the oven is prolonged.
- the average loss of carbon is about thirteen per cent. and the increase of silica or ash proportional.
- the amount of sulphur eliminated in either the Belgian or the beehive oven rarely exceeds five per cent., whereas in open-pit coking as much as fifty per cent. is expelled. It is desirable, then, thatthe coke should have such a composition and be so manipulated that it shall, consistently with the requisites of porosity and strength, have a minimum quantity of sulphur andsilica (ash) fromagiven amount of coal.
- the objection to this method is that a greater quantity of water than necessary is applied, the efficiency of thecoke being lessened by the excess remaining therein.
- the loss is of a twofold nature, in that, first, the water, materially increasing the weight of the coke, causes corresponding augmentation in freightcharges; second, the water, absorbing heat in vaporizing, lessens the heat of the descending stock in the furnace and diminishes the value of the escaping gases as heating factors tothe ovens; and, finally, because that portion of' the water which is hygroscopically suspended in the coke does not vaporize until it enters the zone of fusion, where any reduction in temperature causes a serious deficiency in the quantity of metal smelted.
- Coke has been known to attract as much as thirty per cent. of its own weight of water from the air in damp weather, and retains water hygroscopically .with such'tcnacity that combustion only will release it.
- Coke drawn at a white heat from the bottom of a blast-furnace has been-found to contain five per cent. of water. It has hitherto been the practice to allow the coke to remain in the. oven for a short period after coking to cool before withdrawal; but this is (objectionable as involving, first, a decrease in the temperature of the oven, and, second, an unnecessary loss of time.
- a wagon, B is provided to convey the newlymade coke at theprecise juncture from the oven a to the hood 0, which isthen closed, with the exception of the aperturesat the top .and bottom, respectively, for the inlet and exit of the steam and the waste gases received through pipe F from the gas-holder F.
- Steam from the boilers D, through pipes E D, is admitted to impart a cooling saturation to the coke, yet not to such extent as to become open to the same objection, which is tenable against the use of water.
- the steam and cold gases may enter at the bottom and discharge at the top, or vice versa, until the coke is so cooled that it will not burn upon exposure to the air, after which I withdraw the wagon from the hood and the coke is ready for use.
- the ovens may be two or more stories high, generally three, as shown on the drawings, and of any suitable length and width; but I find it preferable to construct it twelve feet long, six feet wide, and eighteen inches high.
- Each oven is level at top and bottom, the top forming what may be termed a flat arch.
- Each oven or chamber has openings 1) b I) along its sides, near the roof, to allow the products of combustion access to the fines c c c, which are between the walls of the ovens, and which lead to the main fines d d d underneath the ovens, extending perpendicularly to the length of the ovens under the entire series.
- Each oven orchamber has a damper, H, in the side flue, c, to cut the main flue d off from the chamber while it is being discharged and refilled.
- a .furnace, A having fiat-arched-roof ovens a a a, passages b b b, fl'uesc c c d d d d, the fiues d d d running crosswise-the entire length of all the ovens employed, in combination with boilers D, pipes E D, and hood 0, substantially as described.
- a furnace, A having flat-arched-roof ovens a ac, passages b b b, flues c c 0 cl d d cl, the fines d d (1 running crosswise theentire length of all the ovens employed, in combination with boilers D, pipes E D, hood 0, flue d fan I, valve J, gasholder F, and pipe F,
- a furnace, A having flatarched-roof ovens to a a, passages b b b, fines c c c d d d d, in combination with boilers D, fine (2*, shaft G, fan I, valve J, gas-holder F, pipe F, pipes ED,'hood 0, cars B, and track B, for the purpose herein fully set forth.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Coke Industry (AREA)
Description
3 Sheets-Sheet 1.
(No Model.)
\ J. P. BENNETT. APPARATUS FOR THE MANUFACTURE OF BITUMINOUS GOAL 00KB. No. 282,604. Patented Aug. 7, 1883.
\Nxfimsses. wrenmm.
- N. Finns. Phololimraphan Washmgtoll. n.c.
(No Model.) 3 Sheets-Sheet J. F. BENNETT.
APPARATUS FOR THE MANUPAOTURE 0P BITUMINOUS COAL COKE.
No. 282,604. Patented Aug. '7, 1883.
KKK/9 N. PEYERS. Photo-Lithographer. Wnihinglan D. C.
3 Sheets-Sheet 3.
(No Model.)
v J. F. BENNETT. APPARATUS FOR THE MANUFACTURE OF BITUMINOUS GOAL COKE. No. 282,604.
XXWMZZT u. Penna nwwummr. wuhin icn. o c,
UNITED STATES I ATENT .rrrcE.
JOHN F. BENNETT, OF PITTSBURG, PENNSYLVANIA.
APPARATUS FOli THE MANUFACTURE OF BITUMINOUS-COAL COKE.
SPECIFICATION forming part of Letters Patent No. 282,604, dated August 7, 1883.
Application filed January 15,1883. (No model.) A i To all whom, it may concern;-
Be it known that I, J OHN FRANCIS BEN- NETT, a citizen of the United States, residing at Pittsburg, in the county of Allegheny and State of Pennsylvania, have invented certain new and useful improvements in apparatus for the manufacture of bituminous-coal coke, and for rapidly cooling said coke without causing it to lose strength or increase weight; and I do hereby declare that the following is a full, clear, and exact description of the invention, which will enable others skilled in the art to which it appertains to make and use the same.
My invention relates to apparatus for the I manufacture of bituminous-coal coke, in which furnaces are provided for eliminating and flues for conducting off those gases of the coal whose absence is necessary to the formation of coke; and the objects of my improvements are, first, to utilize the fuel to approximate its entire heating capacity; second, to obtain a coke of porous structure, and yet of suflicient strength to withstand the pressure it is sub- 2 5 jected to in blast-furnaces; third, to expel the ovens.
largest proportion of sulphur without affecting deleteriously the strength of the coke due to the presence of other gases; fourth, to obtain a maximum yield of coke from a given quantity of coal, and hence a minimum of ash therein; and, fifth, to cool the newly-made coke rapidly without adding to its weight materially or decreasing the temperature of the I attain these objects by the means illustrated in the accompanying drawings, in which Figure 1 represents an elevation, partly in section, of the plantused in the operation of my invention. Fig. 2 is a plan view of the same, showing the hood partially broken and in section. 'Fig. 3' is a cross-section of the oven illustrated in Fig. 5. Fig. 4 is an elevation of the oven shown in Fig. 5. Fig. 5 is a longitudinal section of the coking-ovens I employ; and Fig. 6 is a plan view of the furnace, illustrating the construction of the fines.
Similar letters refer to corresponding parts throughout the several views.
A represents the furnace, having ovens a a a, whose sides have flues b b b, which transmit the products of combustion by means of fines c c c to the main flues (Z (Z (Z, which conduct them through flue d under the boilers D, and
forward end caused by the chimney G. When f V the gases have deposited in the gas-holder any valuable substances suspended in them and been relieved of excess of temperature, they are conducted over the hot coke in the hood by pipe F to cool the coke, and thence discharged to the atmosphere.
B represents wagons running on rails B, which convey the newly-made coke from the furnace A to the hood 0, where it is cooled.
O is the house or hood, capable of hermetic closure. It is connected with the boilers D by pipes E D andwith the gas-holder F by pipe F.
G represents the chimney discharging the products of combustion received from flue d. H H Hare dampers regulating theegress of gases from the ovens a a a to the lines c 00. I represents a suitable fan-blower to induce a current of the waste gases into. the gasholder F.
' The ovens a a a of the furnace A, whose roofs are flat-arched to utilize the entire heating capacity of the fuel, are filled by spreading small coal, or, preferably, pulverized, washed, and dried coal therein, to a depth about ten inches, in such a manner that it shall lay evenly on the floor except next to the wall, where its depth is slightly less than the average, by which binding due to swelling is obviated. Ideem this method of spreading essential to the successful coking operation.
Having charged the ovens, I begin the operation by igniting wood and coal placed therein, allowing free draft of air. The flat roof materially assists at this juncture the elimination and distillation of the volatile gases by radiating the intense heat generated over the entire bed of coal, which diffusion of heat causes a material acceleration of the operation, which I deem necessary to obtain a coke of the desired structure and quality. When the coke rolling it on the track B into the hood 0, I
roll in front of the emptied oven a wagon having an adjustable horizontal platform thereon, from which the coal may be fed thereto. As rapidity of execution is essential both to prevent the ovens from cooling and the newlymade coke from burning by exposure to the atmosphere, as many men as can advantageously work together should be employed. When the oven is refilled, I repeat the operation by closing the doors 6 and opening air-apertures and the damper H. After some practice the workmen will be able accurately to judge the critical moment of withdrawal, which occurs when all the gaseshave been eliminated consistently with the necessity for retaining inherent strength in ordertowithstandpressureintheblast-furnace. So long as the requisite of strength is attained, it is not so material that all the volatile substances shallhave been expelled, inasmuch as y the entire elimination of these is at the expense 'of a considerable consumption of carbon,which causes alarger amount of ash (silica) and sulphur in the coke-two substances difficult to get rid of in the blast-furnace-while unconsumed volatile matter simply means loss of heat to the descending stock in the furnace, being absorbed bythe distilling volatile matter in the upper part of the furnace. This loss, however, is partially or wholly compen sated for by the richer quality of the gases evolved, which serve for heating the boilers and the ovens, and the air blown into the blastfurnace is consequently of higher temperature.
It is found that a very porous fuel is preferable for smelting ores in a blast-furnace, which I believe to be in consequence of the increased surface presented to the air with which it combines. For example, it has been found that in a compound ofseventy-two grains of saltpeter, with twelve grains of carbon from hemp-stalks, combustion is attained in ten seconds; with twelve grains of carbon from pine wood in seventeen seconds; with twelve grains of carbon proportion of ash is obtained by means of the- Belgian ovens; but these advantages are offset by the greater 'density thereof andthere- I tentiontherein of more sulphur, and the excess of moisture which inevitably followsthe mode of cooling the newly-made coke em- The coke now made ployed. The coke obtained from the beehive ovens is the best now obtainable for use in blast-furnaces, and its desirability is gaged by it's porosity, that having been in the oven about twenty-four hours being preferred, and its de sirability lessened in proportion as the length of stay in the oven is prolonged. In the beehive oven the average loss of carbon is about thirteen per cent. and the increase of silica or ash proportional. The amount of sulphur eliminated in either the Belgian or the beehive oven rarely exceeds five per cent., whereas in open-pit coking as much as fifty per cent. is expelled. It is desirable, then, thatthe coke should have such a composition and be so manipulated that it shall, consistently with the requisites of porosity and strength, have a minimum quantity of sulphur andsilica (ash) fromagiven amount of coal.
Inow proceed to describe the final operation'in the coking process, which consists in so cooling the newly-made hot cokethat there will neitherbe a decrease in the temperature of the coking-oven nor an increase in the weight of the coke.
Heretofore coke has been cooled by sprinkling water on it, either while in the oven or just subsequent to withdrawal therefrom, or
,both. The objection to this method is that a greater quantity of water than necessary is applied, the efficiency of thecoke being lessened by the excess remaining therein. The loss is of a twofold nature, in that, first, the water, materially increasing the weight of the coke, causes corresponding augmentation in freightcharges; second, the water, absorbing heat in vaporizing, lessens the heat of the descending stock in the furnace and diminishes the value of the escaping gases as heating factors tothe ovens; and, finally, because that portion of' the water which is hygroscopically suspended in the coke does not vaporize until it enters the zone of fusion, where any reduction in temperature causes a serious deficiency in the quantity of metal smelted. Coke has been known to attract as much as thirty per cent. of its own weight of water from the air in damp weather, and retains water hygroscopically .with such'tcnacity that combustion only will release it. Coke drawn at a white heat from the bottom of a blast-furnace has been-found to contain five per cent. of water. It has hitherto been the practice to allow the coke to remain in the. oven for a short period after coking to cool before withdrawal; but this is (objectionable as involving, first, a decrease in the temperature of the oven, and, second, an unnecessary loss of time.
In my invention, as before explained, a wagon, B, is provided to convey the newlymade coke at theprecise juncture from the oven a to the hood 0, which isthen closed, with the exception of the aperturesat the top .and bottom, respectively, for the inlet and exit of the steam and the waste gases received through pipe F from the gas-holder F. Steam from the boilers D, through pipes E D, is admitted to impart a cooling saturation to the coke, yet not to such extent as to become open to the same objection, which is tenable against the use of water. The steam and cold gases may enter at the bottom and discharge at the top, or vice versa, until the coke is so cooled that it will not burn upon exposure to the air, after which I withdraw the wagon from the hood and the coke is ready for use. I prefer cooling the hot coke by steam alone (inasmuch as the passage of steam through it removes a little of any sulphur contained therein) in the early part of the cooling operation, and later the charging of in'combustible gases alone, the purpose being to prevent any absorption of moisture by the coke. It will be sufficiently cooled when reduced to a temperature of 700 Fahrenheit.
I nowpoint out more specifically the desirable portions of the ovens a a a.
The ovens may be two or more stories high, generally three, as shown on the drawings, and of any suitable length and width; but I find it preferable to construct it twelve feet long, six feet wide, and eighteen inches high. Each oven is level at top and bottom, the top forming what may be termed a flat arch. Each oven or chamber has openings 1) b I) along its sides, near the roof, to allow the products of combustion access to the fines c c c, which are between the walls of the ovens, and which lead to the main fines d d d underneath the ovens, extending perpendicularly to the length of the ovens under the entire series. Thence they are conducted under the boiler D by flue d, whence, after having given up their heat to the boilers, they are drawn through the flue c, either into the shaft by its natural draft, or into the gas-holder F by fan I, the valve J having previously been opened. Each oven orchamber has a damper, H, in the side flue, c, to cut the main flue d off from the chamber while it is being discharged and refilled.
Having thus fully described my invention, what I claim as new, and desire to secure by Letters Patent of the United States, is
1. A .furnace, A, having fiat-arched-roof ovens a a a, passages b b b, fl'uesc c c d d d d, the fiues d d d running crosswise-the entire length of all the ovens employed, in combination with boilers D, pipes E D, and hood 0, substantially as described.
2. A furnace, A, having flat-arched-roof ovens a ac, passages b b b, flues c c 0 cl d d cl, the fines d d (1 running crosswise theentire length of all the ovens employed, in combination with boilers D, pipes E D, hood 0, flue d fan I, valve J, gasholder F, and pipe F,
substantially as specified. I
3. A furnace, A, having flatarched-roof ovens to a a, passages b b b, fines c c c d d d d, in combination with boilers D, fine (2*, shaft G, fan I, valve J, gas-holder F, pipe F, pipes ED,'hood 0, cars B, and track B, for the purpose herein fully set forth. I
JOHN FRANCIS BENNETT.
Witnesses:
J. J. MOOORMIOK, M. J. MCDONALD.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US282604A true US282604A (en) | 1883-08-07 |
Family
ID=2351813
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US282604D Expired - Lifetime US282604A (en) | Apparatus for the manufacture of bituminous-coal coke |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US282604A (en) |
-
0
- US US282604D patent/US282604A/en not_active Expired - Lifetime
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US9193913B2 (en) | Reduced output rate coke oven operation with gas sharing providing extended process cycle | |
| Valia | Coke production for blast furnace ironmaking | |
| US282604A (en) | Apparatus for the manufacture of bituminous-coal coke | |
| US1627536A (en) | Process of and apparatus for operating cupolas | |
| US1941462A (en) | Method of producing coked fuel agglomerates | |
| US2167100A (en) | Process of preliminary oxidation of caking coal with subsequent coking thereof | |
| US1877123A (en) | Producing coked agglomerates | |
| Duschak et al. | The metallurgy of quicksilver | |
| US1194151A (en) | doherty | |
| US1204789A (en) | Method and apparatus for low-temperature distillation of coal. | |
| US1467460A (en) | Gas making | |
| US1551945A (en) | Continuous-heating furnace | |
| US516663A (en) | Ore-roasting furnace | |
| US692972A (en) | Furnace for refining lead and zinc fume. | |
| US2752298A (en) | Vertical retort | |
| US1442116A (en) | Method of destruction of refuse | |
| US303206A (en) | Method of and apparatus for feeding stock to blast-furnaces | |
| US1214520A (en) | Process of operating gas-fired furnaces. | |
| US1024678A (en) | Process for increasing the temperature of combustion in gas-fired furnaces. | |
| CN106010586A (en) | Method for improving coking quality of top loading coke oven | |
| US3254986A (en) | Integrated charring and ore reduction methods and apparatus | |
| Cooper | By-product coking | |
| US1187049A (en) | Method of carbonizing fuel in vertical-retort gas-benches for the production of gas and carbonized fuel. | |
| US1636975A (en) | Retort oven for low-temperature carbonization | |
| Cochrane | On a New Mode of Coking in Ovens, Applied to the Staffordshire Slack |