US2770210A - Apparatus for coating - Google Patents

Apparatus for coating Download PDF

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US2770210A
US2770210A US626631A US62663145A US2770210A US 2770210 A US2770210 A US 2770210A US 626631 A US626631 A US 626631A US 62663145 A US62663145 A US 62663145A US 2770210 A US2770210 A US 2770210A
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particles
coating
air
stream
sheet
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US626631A
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Emery P Miller
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Ransburg Corp
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Ransburg Corp
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B5/00Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
    • B05B5/08Plant for applying liquids or other fluent materials to objects
    • B05B5/14Plant for applying liquids or other fluent materials to objects specially adapted for coating continuously moving elongated bodies, e.g. wires, strips, pipes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B5/00Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means
    • B05B5/001Electrostatic spraying apparatus; Spraying apparatus with means for charging the spray electrically; Apparatus for spraying liquids or other fluent materials by other electric means incorporating means for heating or cooling, e.g. the material to be sprayed

Definitions

  • This invention relates to the deposition of finely divided material upon an object in an electrostatic field.
  • tinned sheet steel commonly known as tin plate
  • tin plate used extensively for making soldered seam cans
  • oil is desirable as an aid in separating the sheets from the stack and as an aid in securing proper printing in the subsequent lithographing operation.
  • An excessive coat of oil on the tin plate interferes with the proper stacking of the blanks by causing the sheets to offset, interferes with the subsequent operations of soldering or lithographing, and has other disadvantages.
  • Another object is to apply to an article a thin continuous coating of liquid.
  • Another object is to apply to a continuous web of material a coating which is maintained substantially uniform over large areas.
  • Another object is the treatment of an article having spaced droplets or particles of liquid having dielectric properties on the order of vegetable, mineral or animal oils or molten waxes thereon to cause spreading or coalescence of the droplets or particles.
  • Another object is the provision of an improved process of introducing liquid coating material into an electrostatic field for deposition thereby.
  • Another object is the proportioning of the speed of a web with relation to the quantity of coating material deposited thereon.
  • a coating is deposited upon a surface in the form of discrete spaced particles of liquid, and the coated surface is subjected to an electrostatic field of sufiicient intensity to spread or coalesce the particles.
  • the coating is obtained by precipitating liquid particles upon the surface in an electrostatic ionizing field or zone, and the coated surface is exposed to an electrostatic field for a sufficient length of time to secure the desired degree of spreading of the particles.
  • the suspension of particles preferably is introduced at such velocity as to form an elongated stream or blanket of substantially uniform width and thickness in the absence of the electrostatic field, and the particles are electrostatically deflected toward the object to be coated and are deposited thereon.
  • a low velocity carrier air stream for the particles I am able to reduce or eliminate ambient air currents caused by the carrier Stream, which may cause adventitious deposits of parti- Patented Nov. 13, 1956 cles, and insure that the particles are deposited on the sheet adjacent the leading edge of the field so that the deposited particles will remain under the coalescing action of the field for a sufiicient length of time to insure adequate spreading or flow.
  • the spacing of the deposited particles will depend on their distribution in the stream, and the relative movement between the stream and the object to be coated.
  • the density or thickness of the coat applied is determined by the rate at which the material is supplied and the speed of the web or object to be coated.
  • the deforming action of the field will vary, depending on the dielectric properties of the liquid particles, their size, the time of exposure, the strength of the field, and other factors. Under comparable conditions of deposit without an electrostatic field and under the spreading influence of gravity, the particles would form a non-continuous coating. To obtain a continuous coat in the absence of an electrostatic field it would be necessary to deposit a sufficiently large number of particles in overlapping relation so that resultant contact between particles would induce subsequent flow to an even film. Such a film would contain more material and therefore would be thicker than that obtained with the same size particles in an electrostatic field where a greater dispersity of deposit can be secured and be coalesced, in accordance with the present invention. This feature of the invention is of particular value in instances where excessive coating is deleterious.
  • This arrangement employs the force of gravity to oppose the upward momentum of the particles introduced into the electrostatic field; assists in minimizing the agitating effect of ambient air currents; and. has the further advantage of avoiding dripping from the nozzle onto the sheet to be coated.
  • the induction nozzle is preferably of about the same width as the sheet to be coated, and the nozzle opening may be made adjustable so that the apparatus is suitable for treating sheets or webs of various widths.
  • the preferred embodiment of the atomizer or dispersion producing unit consists of an air stream type of fluid disintegrator in which intersecting streams of air and liquid are mingled in a plenum chamber, which may, if desired, contain a bafile or separator unit to break up or eliminate the large particles from the air stream. Where the larger size particles are not a disadvantage the bafliing and separation may be omitted.
  • the nebulizing of the liquid takes place in a plenum chamber at super-atmospheric pressure, and the stream of nebulized particles then is introduced into the electrostatic field, which is in effect in the free atmosphere.
  • the plenum chamber may be located in or outside the electrostatic field;
  • the provision of a plenum chamber in which the pressure is maintained intermediate between the pressure of the atornizing liquid or air supply and the atmospheric pressure provides a space in which-the air and the liquid particles are brought more nearly into velocity equilibrium and makes it possible to-i'ntroduee' the'strean'r of nebulized liquid into the electrostatic field at a lower velocity than is possible with air atomizer-s which" carry out the atomization in a one step pressure reduction.
  • This feature of the invention is not limited to the deposition of a coating of spaced particles, and may be employed for depositing a continuous or heavy coat in an electrostatic held, and results in better uniformity ofcoating, more complete utilization of coating material, and a higher output of liquid for each dispersion unit. If it is desired to have the atomization occur inthe vicinity of the field,- the walls ofthe plenum chamber may serve as a shield against action of the electrostatic field.
  • an air stream may serve as a carrier for the dispersed particles, and if desired, this air stream may be augmented by a supplementary air stream.
  • Al'soit is of'ad'vantage in some cases to provide an auxiliary airstreamthrough the electrostatic field which serves as an envelope for the stream of dispersed particles introduced therein.
  • an exhaust fan or the like for this purpose, there is provided a sub-atmosphericpressure area in the coating and spreading zone, whichis of benefit in connection with the introduction of the low velocity ncbulized liquid from the plenum chamber into the elec trostatic field.
  • the sheet or article to be coated is to be moved through the coating zone at a speed which may vary from time to time
  • a governing arrangement whereby the quantity rate of flow of the nebulized liquid is proportioned with respect to the rate of travel of the sheet or web to be coated. In the preferred embodiment this is accomplished by controlling the fioW-of air to the atomizer in accordance with the rate of travel of the web or object being coated.
  • the preferred embodiment employs a valved orifice to-control the air supply to the atomizer which is designed so that the flowthrough the orifice bears a predetermined relationto'the posi tion of the valve therein.
  • pilot load ing source of air pressure to govern-the position of' the valve, which pressure in turn bears a predeterminedor proportional relation to the speed'of travel of the web or sheet to be coated.
  • the pilot loading pressure preferably is obtained by the back pressure effect in a stream of'air solved natural or artificial waxes or otherjli'quids having dielectric properties whichare of the order-"of these materials.
  • the invention is applicable to the coating of sheet steel with vegetable oil: to produce an extremely thin oil coating thereon, to coating paper with a colored of pigmented molten Wax for the production of copying paper, or coating of cellophane (regenerated cellulose sheet or film) with a siccativ'e oilor composition for gravity or velocity of a carrier air stream-is employed field and partly to the action of the electrostatic 'field'in y precipitating and spreading the dielectric'oil" to cause the deposited particles to mergeor coalesceonthe'surface to be coated. It thus is possible to cause particles of rendering it moisture proof, or the waxing of fruit. Where a non-conducting sheet or object is to be coated, it will be” understood that a conducting backing therefor should be provided".
  • Figure l is a side view of a preferred embodiment of the invention.
  • Figure 2 is'a cross sectional view on li'neII-II of Figure 1',
  • Figure 3' is a perspective view with parts broken away of a preferred form of atomizer or disperser
  • Figure 4 is a partly diagrammatic view of an air pressure transformer for converting rotational motion into a proportional gas pressure
  • Figure 5 is a fragmentary view of an air valve" con troller
  • Figure 6 isa'diagram for explaining the operation of the controller shown in Figure 5.
  • FIG. 1 there is shown a framework or housing lconstructe'd of channel members and sheets or the like, and extending from the'side walls 2 and 3 are. sets of insulator bars 4 andS ( Figures 1' and 2) which are secured to the side walls 2, 3 in any suitable manner.
  • the insulator bars support metal electrode frames 8 and- 9, respectively, which are suitably spaced apart, and each frame supports one or more'suitable' ionizing electrodes 11 and12, respectively, which in the preferred embodiment comprise fine wires stretched taut on the frames.
  • any suitable construction of ionizing'electrodes may be employed, which" are connected by frames 8 and 9 and'wires'14'and 15' ( Figure 2)to' one output terminal of a high voltage pack (not shown), the Wire lsassing through the insulator bushing'l'd in the end wall 17 of to an'exhaust fan '(not shown) of any suitable type.
  • the hood is divided from the electrostatic field by a distributor or header bathe 21 "which-has a series of pe'rforations' 22 todistribute' the suction action ofthe hood over' the electrostatic field” and thus roduces relatively uniform flow of auxiliary air thrbu'ghth'e field.
  • a strip 26 of cleaned tinned steel passes belo'u'f'and part wayv arounda grounded idler roll 27. suitably journalled in the housing' 1, and thstr'ip' passes upwardly through the housing between'the electrode frames '8an'd' 9, .and at the top passes between'a dnv'er roll 28j ahd hold down rolls' 29,30; then" d'ownwardly'to a frying shear'and roller leveler (not shown).
  • the strip may also be driven byadrive bridle (not shownlin' advance of roller 27 i
  • the apparatus shown is adapted toapply' acoatingto I
  • the induction spouts or nozzles 35 and 36 receive a supply of dispersed particles from dispersion units 37 and 38 adjustably mounted upon adjustable support bars 41a and 42a ( Figures 1 and 2).
  • the spouts or nozzles 35, 36 extend in substantially a vertical direction and open upward, so that condensation that occurs within the spouts drips back to the oil supply, and no dripping can occur from the spouts onto the sheet to be coated.
  • the dispersion units are alike in construction only one will be described in detail.
  • the dispersion unit 37 comprises a container 41 of suitable form, such as a box or tank adapted to contain a liquid.
  • a container 41 of suitable form, such as a box or tank adapted to contain a liquid.
  • the tank are one or more vertical tubes 42, suitably supported in a bracket 43, which provides a small aperture at its upper end 44 and has its lower end 45 extending into a sump or trough 46 containing liquid to be atomized.
  • the level of liquid will be maintained at a fairly uniform level below the upper end 44 of tube 42, by manual or automatic replenishing means (not shown), and the space 47 above the liquid level serves as a plenum chamber.
  • An air jet pipe 48 enters the tank 41 and supplies a jet of air at its nozzle end 49 at a suitable pressure across the reduced end 44 of tube 42, whereby a stream of liquid is sucked up into the air jet and is disintegrated or atomized to form a spray.
  • a heating element 51 of any suitable type may be located in an insulated housing 52 below the sump to maintain a relatively uniform temperature therein and thus keep the liquid at a relatively uniform viscosity. Additional insulation of the walls of chamber 37 may be provided, if desired.
  • the spray 56 is composed of liquid particles of diverse sizes intermingled with air which imparts to the particles a forward velocity.
  • a bafile 58 which may be curved as shown, supported by brackets 59 on the wall of the tank, is interposed in the path of the spray, so that the larger particles in the spray impact against the bafiie and are disrupted into finer particles, or condense thereon and drip down into the tank.
  • the particles which are included in the air stream issuing from the induction nozzle 35 are in the form of a fine mist or fog.
  • the size of the plenum chamber and of the nozzle opening may be varied depending on the pressure gradient desired between the supply pressure and the pressure or velocity of the stream of dispersed particles.
  • the size opening of nozzle 35 to the air volume introduced preferably is such as to provide a substantially non-divergent stream of the dispersed particles passing therethrough as indicated by the dot and dash lines 60 ( Figure 1) so as to minimize disruption of the stream issuing from the mouth of the nozzle. This flow is aided by the auxiliary air stream in the electrostatic field induced by exhaust duct 19, which sets up in the field an enveloping, slowly moving stream of air.
  • the fog thus produced may be carried into the induction nozzles, I prefer to first dilute the fog by an auxiliary air stream which enters the tank 41 by pipe 61 above the liquid level and at a sufiicient velocity to agitate and dilute the fog, and assist in a further separation of larger particles.
  • the air streams in pipes 48 and 61 receive their supply from a common conduit 65 ( Figure 6), and are proportioned by suitable manually controlled valves (not shown). Any number of atomizer units desired may be contained within the confining chamber 41, two being employed in the embodiment shown.
  • the application or induction nozzle 35 preferably is elongated to about the width of the sheet to be coated, or slightly wider, and if desired, dampers 66 at each end may be provided, the dampers being manually positioned by handles 67 to adjust the width of the fog stream issuing from the spouts. These dampers may be locked in position during operation by any suitable means (not shown).
  • the ionizing zone extends between the ionizing electrodes 11 and 12 and the sheet 26, and it is preferred to have the openings or mouths of the induction spouts 35, 36 located within this zone.
  • the sheet 26 of tinned steel is driven through the apparatus at a uniform speed.
  • Streams of oil dispersed in air issue from the spouts 35 and 36 at a comparatively low rate of flow and the particles of oil therein are deflected by the electrostatic field and caused to deposit on the moving steel strip.
  • the particles are moved uniformly toward the sheet by the electrostatic force, and deposited on the sheet adjacent the edge of the field, as indicated at 70.
  • the dispersity on the sheet depends on the density and velocity of the fog and speed of the sheet.
  • the outer surface of the particles after being deposited may remain charged at the same polarity as the ionizing source, which would assist in repelling any floating particles in the field and would cause such floating particles to be deposited on a portion of the strip not previously coated lying between or adjacent particles already adhering to the strip.
  • the surface charge upon the free surface of such particles will cause the free surface to be attracted to the sheet and thus the droplet will be spread so long as this charge is maintained.
  • FIG. a here s Pa t y diagramma ically hown a r hs m s 75 which c mp s a vertica ha t c ying a plate 76. ich s ahlv r ve y horizontal shaft 77 in any suitable manner, and which in turn is suitably driven by a part of the drive mechanism for Sheet 26, such as the drive bridle.
  • Plate 76 carries two. yokes 81 and 82 in which are pivoted two rocker arms 83 and 84 carrying weights 85 and 86 at their ends.
  • a push rod 87 is suitably supported in the housing 75.
  • a diaphragm 90 is suitably secured by a cover 91 to provide a pressure chamber 92 with a port 9.3 having a conduit 94 connected thereto.
  • Port 93 connects with a passage 95 through the clamped periphery of the diaphragm and terminates in an Orifice 96.
  • a nozzle 97 is disposed opposite the orifice 96 and is connected by a suitable flexible coupling 98 to a conduit 99 which supplies to the nozzle a stream of air at a constant pressure.
  • the pressure in conduit 94 is transmitted to the chamher 101 ( Figures and 6) under a diaphragm 102 con tained within a housing103, a spring 104 exerting a bias on the diaphragm.
  • A' push rod 105 engaging diaphragm 102 engages a lever 10.6 pivoted at 107, which is urged against a bearing member 108.
  • a threaded rod 109 en: gages the bearing'108 and by means of a hand wheel 110 thereon, the bearing member can be moved toward or away from the pivot 107 to vary the mechanical advantage of lever 106.
  • the conduit 65 supplies air to the atomizing deviceillustrated in detail in Figure 3.
  • This conduit contains a valve indicated generally at 115 which embodies a seat or orifice 116 ( Figure 5) and a valve closure member 117, the seat and closure being of such form that the flow through the seat is proportional to the position of the closure.
  • the closure is securedto a stem 118 passing through a sealing device 119 of suitable construction andabutting adiaphragm 121 held between the housing 122 and 'a cover 123;
  • a spring 124 urges the diaphragm 121 upward and urges valve 117 into closed position.
  • a conduit 125 supplies a con- 7 stant pressure flow which is conducted by a conduit 126 to pressure chamber 127 and tends to oppose spring 1 24' to open valve 115.
  • the housing 128 which receives the conduit 125 provides a bleed orifice 131' ( Figure 6) by which air is bled to the atmosphere and a closure 132 secured to lever 133 pivoted at 134 controls the bleed therethrough.
  • Lever 133 and closure 132 are urged to open position by a spring 135, and a spring ferrule 136-is securedto a bar 137 which in turn is seeured to valve rod 118.
  • the ever 133 is urged by spring 135 into engagement with hearing member 108
  • a finger wheel 133 permits man I ual adjustmentof spring 135.
  • Valve 115. under h coh is W 'I??l ?h a n w o it o of 1 13 91? which the flow of air to the ato rn izing device 37 is pro ⁇ P -ha he en shred o heet 26- Whsn peed r Sheet 26' i sr a a an a ti n se t th bo e s:
  • An' apparatus comprising means for moving anobject'presenting a surface to be coated, gas ator'nizing means for producing a suspension of iin'el'y divided par ticles in a g'as st'rear'n, a gas conduit for supplying gas tgosaid atomi'zing means, valve means in said condiiit to control the How of 'in p redeterihinedrelation totthe' position of the valve thereof, a gas pressure contrpl am e h said v ve avihaa b e lth r r m, me
  • An apparatus comprising, means for moving an object to be coated, ionizing means in proximity to at least one surface of said object for producing and moving ions in a path toward said surface, means for producing a dispersion of liquid particles in a gas, a container surrounding said dispersion-producing means, an induction nozzle extending from said container into said ion path, said container and nozzle being of electrically conducting material and serving to electrically shield said dispersion as it is produced and conducted in the gas stream from the container to the ion path.
  • an electrostatic coating apparatus in Which electrically charged particles of liquid coating material in a coating zone are electrostatically deposited on the surface of an object passing through such coating zone, means for moving the object through the coating zone, coating-material supply means, a high-voltage source for creating electrical charges of opposite signs on the object and coating material particles, and a control device responsive to the rate of movement of said object through the coating zone and controlling said supply means to maintain a predetermined ratio between the speed of said surface and the rate of coating-material supply.
  • an electrostatic coating apparatus in which electrically charged particles of liquid coating material in a coating zone are electrostatically deposited on the surface of an object passing through such coating zone, means for moving the object through the coating zone, coating-material supply means having a discharge orifice, a high-voltage source for creating electrical charges of opposite signs on the object and coating material particles, and a control device controlling said supply means and coordinating With the speed of said surface both the Velocity and quantity-rate at which coating material is discharged through said orifice.

Description

1956 E. P. MILLER APPARATUS FOR COATING 2 Sheets-Sheet 1 Flled Nov. 5, 1945 a n... DOAR m MM M mo R m NYJ/Q m m u E A A In E ..u u 103 E 9 ow m mdE Nov. 13, 1956 E. P. MILLER 4 2,770,210
APPARATUS FOR COATING Flled Nov. 5, 1945 2 Sheets-Sheet 2 N VEN TOR.
EMERY P. M/ZLE United States Patent F APPARATUS FOR COATING Emery P. Miller, Williams Creek, Ind., assignor, by direct and mesne assignments, to Ransburg Electro-Coating Corp., Indianapolis, Ind., a corporation of Indiana Application November 5, 1945, Serial No. 626,631
7 Claims. (Cl. 118-7) This invention relates to the deposition of finely divided material upon an object in an electrostatic field.
In the manufacture of tinned sheet steel, commonly known as tin plate, used extensively for making soldered seam cans, it is the practice to apply a thin coat of oil to the tinned surface of the tin plate, this coating generally being applied to the tinned plate or strip before it is cut into blanks for the forming presses. The coating of oil is desirable as an aid in separating the sheets from the stack and as an aid in securing proper printing in the subsequent lithographing operation. An excessive coat of oil on the tin plate interferes with the proper stacking of the blanks by causing the sheets to offset, interferes with the subsequent operations of soldering or lithographing, and has other disadvantages.
It is an object of the present invention to apply to the surface of an article, a thin coating of liquid.
Another object is to apply to an article a thin continuous coating of liquid.
Another object is to apply to a continuous web of material a coating which is maintained substantially uniform over large areas.
Another object is the treatment of an article having spaced droplets or particles of liquid having dielectric properties on the order of vegetable, mineral or animal oils or molten waxes thereon to cause spreading or coalescence of the droplets or particles.
Another object is the provision of an improved process of introducing liquid coating material into an electrostatic field for deposition thereby.
Another object is the proportioning of the speed of a web with relation to the quantity of coating material deposited thereon.
In accordance with one feature of the present invention, a coating is deposited upon a surface in the form of discrete spaced particles of liquid, and the coated surface is subjected to an electrostatic field of sufiicient intensity to spread or coalesce the particles. Preferably the coating is obtained by precipitating liquid particles upon the surface in an electrostatic ionizing field or zone, and the coated surface is exposed to an electrostatic field for a sufficient length of time to secure the desired degree of spreading of the particles. By depositing the particles upon a moving sheet or article adjacent one end of an ionizing electrostatic field, the field serves the dual function of precipitating the particles onto the surface and acting on the deposited particles as the surface moves therethrough to increase or assist spreading and coalescence of the particles.
The suspension of particles preferably is introduced at such velocity as to form an elongated stream or blanket of substantially uniform width and thickness in the absence of the electrostatic field, and the particles are electrostatically deflected toward the object to be coated and are deposited thereon. By employing a low velocity carrier air stream for the particles I am able to reduce or eliminate ambient air currents caused by the carrier Stream, which may cause adventitious deposits of parti- Patented Nov. 13, 1956 cles, and insure that the particles are deposited on the sheet adjacent the leading edge of the field so that the deposited particles will remain under the coalescing action of the field for a sufiicient length of time to insure adequate spreading or flow.
The spacing of the deposited particles will depend on their distribution in the stream, and the relative movement between the stream and the object to be coated. When the sheet or object to be coated is moved past the stream of particles, the density or thickness of the coat applied is determined by the rate at which the material is supplied and the speed of the web or object to be coated.
In the practice of the present invention I am able to obtain a continuous liquid coat on the surface of the sheet which is thinner than any continuous coat heretofore obtained by spray methods. This result I believe is in part due to the nature of the stream or blanket of mist which in the absence of an electrostatic field, retains its cross sectional shape for some distance; to the substantially uniform and unidirectional deflecting and depositing action of the electrostatic field on the mist stream; to the traveling of the web which increases the dispersity of the particles deposited; and to the deforming or spreading action of the electrostatic field on deposited particles which causes them to spread and to tend to coalesce and form a continuous coat. The deforming action of the field will vary, depending on the dielectric properties of the liquid particles, their size, the time of exposure, the strength of the field, and other factors. Under comparable conditions of deposit without an electrostatic field and under the spreading influence of gravity, the particles would form a non-continuous coating. To obtain a continuous coat in the absence of an electrostatic field it would be necessary to deposit a sufficiently large number of particles in overlapping relation so that resultant contact between particles would induce subsequent flow to an even film. Such a film would contain more material and therefore would be thicker than that obtained with the same size particles in an electrostatic field where a greater dispersity of deposit can be secured and be coalesced, in accordance with the present invention. This feature of the invention is of particular value in instances where excessive coating is deleterious.
I prefer to bring the particle suspension into the field through an induction nozzle opening upwardly and which extends generally in the direction of movement of the object to be coated. This arrangement employs the force of gravity to oppose the upward momentum of the particles introduced into the electrostatic field; assists in minimizing the agitating effect of ambient air currents; and. has the further advantage of avoiding dripping from the nozzle onto the sheet to be coated. In treating sheets; of material the induction nozzle is preferably of about the same width as the sheet to be coated, and the nozzle opening may be made adjustable so that the apparatus is suitable for treating sheets or webs of various widths. However, I do not intend to exclude the application of a low velocity diverging stream of atomized liquid in carrying out the invention.
The preferred embodiment of the atomizer or dispersion producing unit consists of an air stream type of fluid disintegrator in which intersecting streams of air and liquid are mingled in a plenum chamber, which may, if desired, contain a bafile or separator unit to break up or eliminate the large particles from the air stream. Where the larger size particles are not a disadvantage the bafliing and separation may be omitted.
According to another feature of the invention, the nebulizing of the liquid takes place in a plenum chamber at super-atmospheric pressure, and the stream of nebulized particles then is introduced into the electrostatic field, which is in effect in the free atmosphere.
The plenum chamber may be located in or outside the electrostatic field; The provision of a plenum chamber in which the pressure is maintained intermediate between the pressure of the atornizing liquid or air supply and the atmospheric pressure provides a space in which-the air and the liquid particles are brought more nearly into velocity equilibrium and makes it possible to-i'ntroduee' the'strean'r of nebulized liquid into the electrostatic field at a lower velocity than is possible with air atomizer-s which" carry out the atomization in a one step pressure reduction. This feature of the invention is not limited to the deposition of a coating of spaced particles, and may be employed for depositing a continuous or heavy coat in an electrostatic held, and results in better uniformity ofcoating, more complete utilization of coating material, and a higher output of liquid for each dispersion unit. If it is desired to have the atomization occur inthe vicinity of the field,- the walls ofthe plenum chamber may serve as a shield against action of the electrostatic field.
Where an air stream is employed for producing the dispersion it may serve as a carrier for the dispersed particles, and if desired, this air stream may be augmented by a supplementary air stream. Al'soit is of'ad'vantage in some cases to provide an auxiliary airstreamthrough the electrostatic field which serves as an envelope for the stream of dispersed particles introduced therein. When employing an exhaust fan or the like for this purpose, there is provided a sub-atmosphericpressure area in the coating and spreading zone, whichis of benefit in connection with the introduction of the low velocity ncbulized liquid from the plenum chamber into the elec trostatic field.
Where the sheet or article to be coated is to be moved through the coating zone at a speed which may vary from time to time I prefer to employ a governing arrangement whereby the quantity rate of flow of the nebulized liquid is proportioned with respect to the rate of travel of the sheet or web to be coated. In the preferred embodiment this is accomplished by controlling the fioW-of air to the atomizer in accordance with the rate of travel of the web or object being coated. The preferred embodiment employs a valved orifice to-control the air supply to the atomizer which is designed so that the flowthrough the orifice bears a predetermined relationto'the posi tion of the valve therein. I prefer to employ a pilot load ing source of air pressure to govern-the position of' the valve, which pressure in turn bears a predeterminedor proportional relation to the speed'of travel of the web or sheet to be coated. The pilot loading pressure preferably is obtained by the back pressure effect in a stream of'air solved natural or artificial waxes or otherjli'quids having dielectric properties whichare of the order-"of these materials.
In particular, when applying'a coating'ofnon-dryin'g or slowly drying oil, I am ableto deposit athin'ner -film in a given time in an electrostatic field than when the'force of dielectric oil to coalesce on a surface in an electrostatic field' which if deposited without an electrostatic field would" surface texture, although it will be understood that the nature of the coating applied will be modified depending" on the porosity of the web or object,.the relative adhering or wetting. nature of the web or object and the coating material for each other; and other factors. Thus, for example, the invention is applicable to the coating of sheet steel with vegetable oil: to produce an extremely thin oil coating thereon, to coating paper with a colored of pigmented molten Wax for the production of copying paper, or coating of cellophane (regenerated cellulose sheet or film) with a siccativ'e oilor composition for gravity or velocity of a carrier air stream-is employed field and partly to the action of the electrostatic 'field'in y precipitating and spreading the dielectric'oil" to cause the deposited particles to mergeor coalesceonthe'surface to be coated. It thus is possible to cause particles of rendering it moisture proof, or the waxing of fruit. Where a non-conducting sheet or object is to be coated, it will be" understood that a conducting backing therefor should be provided".
The invention will be described in greater detail in connection with the accompanying drawings. wherein a preferred embodiment of the invention is disclosed by way of example, and wherein,
Figure l is a side view of a preferred embodiment of the invention,
Figure 2 is'a cross sectional view on li'neII-II of Figure 1',
Figure 3' is a perspective view with parts broken away of a preferred form of atomizer or disperser,
Figure 4 is a partly diagrammatic view of an air pressure transformer for converting rotational motion into a proportional gas pressure,
Figure 5 is a fragmentary view of an air valve" con troller, and
Figure 6 isa'diagram for explaining the operation of the controller shown in Figure 5.
Referring to Figure 1, there is shown a framework or housing lconstructe'd of channel members and sheets or the like, and extending from the'side walls 2 and 3 are. sets of insulator bars 4 andS (Figures 1' and 2) which are secured to the side walls 2, 3 in any suitable manner. The insulator bars support metal electrode frames 8 and- 9, respectively, which are suitably spaced apart, and each frame supports one or more'suitable' ionizing electrodes 11 and12, respectively, which in the preferred embodiment comprise fine wires stretched taut on the frames. However, any suitable construction of ionizing'electrodes may be employed, which" are connected by frames 8 and 9 and'wires'14'and 15' (Figure 2)to' one output terminal of a high voltage pack (not shown), the Wire lsassing through the insulator bushing'l'd in the end wall 17 of to an'exhaust fan '(not shown) of any suitable type. The hood is divided from the electrostatic field by a distributor or header bathe 21 "which-has a series of pe'rforations' 22 todistribute' the suction action ofthe hood over' the electrostatic field" and thus roduces relatively uniform flow of auxiliary air thrbu'ghth'e field.
A strip 26 of cleaned tinned steel passes belo'u'f'and part wayv arounda grounded idler roll 27. suitably journalled in the housing' 1, and thstr'ip' passes upwardly through the housing between'the electrode frames '8an'd' 9, .and at the top passes between'a dnv'er roll 28j ahd hold down rolls' 29,30; then" d'ownwardly'to a frying shear'and roller leveler (not shown). The strip ma also be driven byadrive bridle (not shownlin' advance of roller 27 i The apparatus shown is adapted toapply' acoatingto I At the top of the housing-is located a i both sides of the strip 26 and includes a pair of induction nozzles 35 and 36 on opposite sides of the strip. However, where coating on only one side of the strip is desired, it will be understood that only one induction nozzle is employed. The induction spouts or nozzles 35 and 36 receive a supply of dispersed particles from dispersion units 37 and 38 adjustably mounted upon adjustable support bars 41a and 42a (Figures 1 and 2). The spouts or nozzles 35, 36 extend in substantially a vertical direction and open upward, so that condensation that occurs within the spouts drips back to the oil supply, and no dripping can occur from the spouts onto the sheet to be coated. As the dispersion units are alike in construction only one will be described in detail.
Referring to Figure 3, the dispersion unit 37 comprises a container 41 of suitable form, such as a box or tank adapted to contain a liquid. Within the tank are one or more vertical tubes 42, suitably supported in a bracket 43, which provides a small aperture at its upper end 44 and has its lower end 45 extending into a sump or trough 46 containing liquid to be atomized. The level of liquid will be maintained at a fairly uniform level below the upper end 44 of tube 42, by manual or automatic replenishing means (not shown), and the space 47 above the liquid level serves as a plenum chamber. An air jet pipe 48 enters the tank 41 and supplies a jet of air at its nozzle end 49 at a suitable pressure across the reduced end 44 of tube 42, whereby a stream of liquid is sucked up into the air jet and is disintegrated or atomized to form a spray. If desired, a heating element 51 of any suitable type may be located in an insulated housing 52 below the sump to maintain a relatively uniform temperature therein and thus keep the liquid at a relatively uniform viscosity. Additional insulation of the walls of chamber 37 may be provided, if desired.
The spray 56 is composed of liquid particles of diverse sizes intermingled with air which imparts to the particles a forward velocity. Preferably, a bafile 58, which may be curved as shown, supported by brackets 59 on the wall of the tank, is interposed in the path of the spray, so that the larger particles in the spray impact against the bafiie and are disrupted into finer particles, or condense thereon and drip down into the tank. As a result of the baffling and disrupting action of bafiie 58 and the change of direction of flow of the stream in passing into the nozzle 35, the particles which are included in the air stream issuing from the induction nozzle 35 are in the form of a fine mist or fog. By bringing about atomization of the liquid in a plenum chamber, prior to introduction of the dispersion into the electrostatic field, I am able to step down the air velocity issuing into the electrostatic field to reduce or eliminate turbulence therein. The size of the plenum chamber and of the nozzle opening may be varied depending on the pressure gradient desired between the supply pressure and the pressure or velocity of the stream of dispersed particles. The size opening of nozzle 35 to the air volume introduced preferably is such as to provide a substantially non-divergent stream of the dispersed particles passing therethrough as indicated by the dot and dash lines 60 (Figure 1) so as to minimize disruption of the stream issuing from the mouth of the nozzle. This flow is aided by the auxiliary air stream in the electrostatic field induced by exhaust duct 19, which sets up in the field an enveloping, slowly moving stream of air.
While for certain uses the fog thus produced may be carried into the induction nozzles, I prefer to first dilute the fog by an auxiliary air stream which enters the tank 41 by pipe 61 above the liquid level and at a sufiicient velocity to agitate and dilute the fog, and assist in a further separation of larger particles. In the preferred embodiment, the air streams in pipes 48 and 61 receive their supply from a common conduit 65 (Figure 6), and are proportioned by suitable manually controlled valves (not shown). Any number of atomizer units desired may be contained within the confining chamber 41, two being employed in the embodiment shown. The application or induction nozzle 35 preferably is elongated to about the width of the sheet to be coated, or slightly wider, and if desired, dampers 66 at each end may be provided, the dampers being manually positioned by handles 67 to adjust the width of the fog stream issuing from the spouts. These dampers may be locked in position during operation by any suitable means (not shown). The ionizing zone extends between the ionizing electrodes 11 and 12 and the sheet 26, and it is preferred to have the openings or mouths of the induction spouts 35, 36 located within this zone.
The operation of the apparatus so far described now will be explained. The sheet 26 of tinned steel is driven through the apparatus at a uniform speed. Streams of oil dispersed in air issue from the spouts 35 and 36 at a comparatively low rate of flow and the particles of oil therein are deflected by the electrostatic field and caused to deposit on the moving steel strip. Because of the low velocity of the fog or mist entering the electrostatic field and the substantial absence of turbulent flow between the end of the spout and the deposition area of the moving sheet, the particles are moved uniformly toward the sheet by the electrostatic force, and deposited on the sheet adjacent the edge of the field, as indicated at 70. The dispersity on the sheet depends on the density and velocity of the fog and speed of the sheet. For a given stream of dispersed particles, a higher sheet velocity will cause the particles to be deposited in a more disperse spacing. By employing a plenum chamber in which a reduction of pressure of the stream of dispersed particles occurs I am able to introduce the fog into the electrostatic field at a reduced velocity. As a consequence the electrostatically charged particles flow in a curved stream or wall indicated at 70 (Figure 1) which intersects the strip to be coated near the leading edge of the field, and the particles coming into contact with the strip are held thereon by their own wetting action and by the attractive force of the charge of opposite polarity carried by the strip. Furthermore, in the case of fog particles of a liquid which is a relatively poor conductor, the outer surface of the particles after being deposited may remain charged at the same polarity as the ionizing source, which would assist in repelling any floating particles in the field and would cause such floating particles to be deposited on a portion of the strip not previously coated lying between or adjacent particles already adhering to the strip. In addition the surface charge upon the free surface of such particles will cause the free surface to be attracted to the sheet and thus the droplet will be spread so long as this charge is maintained. Furthermore, the action of the electrostatic field in lowering the surface tension of the liquid particles deposited on the strip assist in causing relatively poor wetting liquids or liquids of relatively good dielectric properties to adhere to and spread over and coalesce on the surface of the strip. Thus there is obtained an extremely thin coating of oil on the tinned strip. In explaining the theory of operation of the apparatus and method, I do not wish to be confined to such theory in claiming my invention.
While ordinarily the strip travels at a uniform rate through the coating machine, there are times, for example, during the automatic welding of the ends of two successive strips in the continuous type strip steel mill, when the travel speed is reduced by about one half. Also when starting or stopping the operation, there is a gradual deceleration or acceleration of the strip. In the preferred embodiment of the invention herein disclosed, I regulate or control the volume rate of flow of the fog blanket issuing from the induction nozzle proportionately with the lineal speed of the steel web, so that-a relatively uniform deposition of the particles will be made regardless of variations in the rate of travel of the steel strip. The mechanism by which this is accomplished now will be described.
Referrin o Figure a here s Pa t y diagramma ically hown a r hs m s 75 which c mp s a vertica ha t c ying a plate 76. ich s ahlv r ve y horizontal shaft 77 in any suitable manner, and which in turn is suitably driven by a part of the drive mechanism for Sheet 26, such as the drive bridle. Plate 76 carries two. yokes 81 and 82 in which are pivoted two rocker arms 83 and 84 carrying weights 85 and 86 at their ends. A push rod 87 is suitably supported in the housing 75. and at its lower end carries a collar 88 adapted to be engaged by the ends of rocker arms 83 and 84. At the top of the housing, a diaphragm 90 is suitably secured by a cover 91 to provide a pressure chamber 92 with a port 9.3 having a conduit 94 connected thereto. Port 93 connects with a passage 95 through the clamped periphery of the diaphragm and terminates in an Orifice 96. A nozzle 97 is disposed opposite the orifice 96 and is connected by a suitable flexible coupling 98 to a conduit 99 which supplies to the nozzle a stream of air at a constant pressure. As this apparatus is commercial- 131 available a more detailed description of its construction is not required.
The operation of the apparatus so far described in connection with Figure 4 now will be explained. At a given sheet speed air issuing from nozzle 9.7 will enter orifice 96 and through passage 95 will develop a pressure in chamber 92 and'conduit 94. Nozzle 97 willassume a position relative to orifice 96 such that the force of the air pressure in chamber 92 on diaphragm 90 counterbalances the upward thrust on rod 87 due to centrifugal force on weights 85, 86. The pressure in chamber 92 is at all times proportional to. the speed of the shaft '77 or strip 26 (Figure 1) and therefore the pressure supplied to conduit 94 is also proportional to the speed of strip 26.
The pressure in conduit 94 is transmitted to the chamher 101 (Figures and 6) under a diaphragm 102 con tained within a housing103, a spring 104 exerting a bias on the diaphragm. A' push rod 105 engaging diaphragm 102 engages a lever 10.6 pivoted at 107, which is urged against a bearing member 108. A threaded rod 109 en: gages the bearing'108 and by means of a hand wheel 110 thereon, the bearing member can be moved toward or away from the pivot 107 to vary the mechanical advantage of lever 106.
As previously mentioned, the conduit 65 supplies air to the atomizing deviceillustrated in detail in Figure 3. This conduit contains a valve indicated generally at 115 which embodies a seat or orifice 116 (Figure 5) and a valve closure member 117, the seat and closure being of such form that the flow through the seat is proportional to the position of the closure. The closure is securedto a stem 118 passing through a sealing device 119 of suitable construction andabutting adiaphragm 121 held between the housing 122 and 'a cover 123; A spring 124 urges the diaphragm 121 upward and urges valve 117 into closed position. A conduit 125 supplies a con- 7 stant pressure flow which is conducted by a conduit 126 to pressure chamber 127 and tends to oppose spring 1 24' to open valve 115.
The housing 128 which receives the conduit 125provides a bleed orifice 131' (Figure 6) by which air is bled to the atmosphere and a closure 132 secured to lever 133 pivoted at 134 controls the bleed therethrough. Lever 133 and closure 132 are urged to open position by a spring 135, and a spring ferrule 136-is securedto a bar 137 which in turn is seeured to valve rod 118. The ever 133 is urged by spring 135 into engagement with hearing member 108 A finger wheel 133permits man I ual adjustmentof spring 135.
The operation of the control apparatus now will be described. Assuming the sheet '26 is moving at a constant speed, the pressure in chamber 92 (Figure and in conduit 94 is constant and is proportional to the speed of s t 2 h s ihfli s i' s f h m as s $2 ,1 1.91
r 1 21 ondu te here o. y cond it. 4.. he d a hra m w l tak up a ns ti Qt a s st h ih hr h Pr s e i ch mb r 9 ps esl hr th bias. d smiss;
.5. which n has de ends on the n s t f' a t rs 1 a valve 5;. T w t sh 0f ssure 3. elative to orifice 131 will similarly be established by these two conditions. Under conditions of fined bleed at oris 3 e. nr h s n ha w l d te m hs h position of valve and thus determine the rate of flow of air through conduit 65 to the pipes 61 and 48. When h eet a mes lower speed, t e sh h s in ih a fetch h W i t 8 a d .6. sa ers t m inors inward and allows nozzle to take up a new position of balance with orif ce 96 so that the pressure in chamher 9Z'JCQndHit a t ambe 01 draw t f sat' ahish l s Spring 1 t PM ev r 1 3 siswhwarsi is move closure 132 further from orifice 131 to allow a greater bleed therethrough, which results in a reduction of l di p shreih chambe n a urther s:
s ia al e 9 r duc t flow of air throu h conduit 65 to the atomizing device. Valve 115. under h coh is W 'I??l ?h a n w o it o of 1 13 91? which the flow of air to the ato rn izing device 37 is pro} P -ha he en shred o heet 26- Whsn peed r Sheet 26' i sr a a an a ti n se t th bo e s:
scribed will again establish the proper relation between sa s-d of s'shse and the flaw o air o th at z: s dev e BY n s atihs h 11 W f. a t h atQm z-- ing device with the speed of the sheetpthe flow of mi s ma e ial su n f m zle 3. s ikew s rre at d. q l s s ih s 9 the heet speed to bta n a consistently the sheet speed.
Various modifications may be made in the invention ssr h sl it u d ar n m h p rit n shops srss ii hh rsths h h sih mean fqrmo in a iss 9 he satsr qaia h' means i proshnhy to a ast has htfes sf, sa d hhisc m ps for prq hs na a SPmiQ 9 quid a tis s n a as stream a c hduit for introduei g a str m of d ersed part b w n eshis t a d ihh zihs insane sa d ehdui erminatin in the 99 Pa h be ween h n in means an Q i et to l ase s i she th in h sm Path a d-m aslcoorditlh t e t 9 fl w Q s id s ream Q 'di per ed-par: is w t the s ee f a d hhiest- 2 Air apparatuscomprisingrneans for moving an ob-s ject presenting esurfacej to be coated, electrostatic? ionizingmeans in proximity to said surface,' means for intro duping finely divided material into the electrostatic remfor deposit upon said surface, and means coordinatingthe speed of said surface and rate of fiow of said finely yided material.
3( An' apparatus comprising means for moving anobject'presenting a surface to be coated, gas ator'nizing means for producing a suspension of iin'el'y divided par ticles in a g'as st'rear'n, a gas conduit for supplying gas tgosaid atomi'zing means, valve means in said condiiit to control the How of 'in p redeterihinedrelation totthe' position of the valve thereof, a gas pressure contrpl am e h said v ve avihaa b e lth r r m, me
connected to said valve to, vary said bleed; 'and means uhif hh de s o ma r a nde e dent at I responsive to the speed of said surface and connected to said last named means to vary said bleed.
5. An apparatus comprising, means for moving an object to be coated, ionizing means in proximity to at least one surface of said object for producing and moving ions in a path toward said surface, means for producing a dispersion of liquid particles in a gas, a container surrounding said dispersion-producing means, an induction nozzle extending from said container into said ion path, said container and nozzle being of electrically conducting material and serving to electrically shield said dispersion as it is produced and conducted in the gas stream from the container to the ion path.
6. In an electrostatic coating apparatus in Which electrically charged particles of liquid coating material in a coating zone are electrostatically deposited on the surface of an object passing through such coating zone, means for moving the object through the coating zone, coating-material supply means, a high-voltage source for creating electrical charges of opposite signs on the object and coating material particles, and a control device responsive to the rate of movement of said object through the coating zone and controlling said supply means to maintain a predetermined ratio between the speed of said surface and the rate of coating-material supply.
7. In an electrostatic coating apparatus in which electrically charged particles of liquid coating material in a coating zone are electrostatically deposited on the surface of an object passing through such coating zone, means for moving the object through the coating zone, coating-material supply means having a discharge orifice, a high-voltage source for creating electrical charges of opposite signs on the object and coating material particles, and a control device controlling said supply means and coordinating With the speed of said surface both the Velocity and quantity-rate at which coating material is discharged through said orifice.
References Cited in the file of this patent UNITED STATES PATENTS 738,347 Myers Sept. 8, 1903 1,788,600 Smyser Jan. 13, 1931 1,855,869 Pugh Apr. 26, 1932 2,047,525 Thode July 14, 1936 2,078,790 Bucy Apr. 27, 1937 2,159,351 Burns May 23, 1939 2,187,837 Paasche Jan. 23, 1940 2,191,827 Benner Feb. 27, 1940 2,221,338 Wintermute Nov. 12, 1940 2,334,648 Ransburg Nov. 16, 1943 2,421,787 Helmuth June 10, 1947 2,447,664 Pegg Aug. 24, 1948
US626631A 1945-11-05 1945-11-05 Apparatus for coating Expired - Lifetime US2770210A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2889805A (en) * 1955-01-21 1959-06-09 Goodrich Co B F Electrostatic flocking apparatus
US2981225A (en) * 1959-01-22 1961-04-25 Gamewell Co Wire insulation coloring apparatus
US2994618A (en) * 1957-01-22 1961-08-01 Trion Inc Method and apparatus for electrostatic coating
US3065106A (en) * 1958-11-14 1962-11-20 Electro Dispersion Corp Pan greasing method and apparatus
US4608942A (en) * 1984-05-12 1986-09-02 Fanetech Institute Limited Method of continuously spraying liquids onto lengthy bodies moving at high speed
US4797686A (en) * 1985-05-01 1989-01-10 Burlington Industries, Inc. Fluid jet applicator for uniform applications by electrostatic droplet and pressure regulation control
US4839202A (en) * 1986-09-29 1989-06-13 Aluminum Company Of America Method and apparatus for coating a moving substrate
ES2071576A2 (en) * 1993-08-04 1995-06-16 Navalon Saez Concepcion Method for continuous painting of metallic link chains and the corresponding installation
US20070190261A1 (en) * 2006-02-10 2007-08-16 Ronald Darnell Overspray apparatus and process

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US1788600A (en) * 1924-02-07 1931-01-13 James S Smyser Abrasive article and manufacture of same
US1855869A (en) * 1928-12-31 1932-04-26 Western Electric Co Method of and apparatus for coating articles
US2047525A (en) * 1931-09-18 1936-07-14 Thode Adolf Insulating method for electric and thermo-technical purposes, and apparatus for accomplishing the same
US2078790A (en) * 1931-12-24 1937-04-27 Atlas Powder Co Offset process
US2159351A (en) * 1937-01-18 1939-05-23 M J B Company Method of and means for waxing tin plate
US2187837A (en) * 1936-11-19 1940-01-23 Jens A Paasche Multiple action surface treatment
US2191827A (en) * 1934-04-12 1940-02-27 Carborundum Co Apparatus for applying liquid to fabric
US2221338A (en) * 1936-10-21 1940-11-12 Research Corp Deposition of material
US2334648A (en) * 1939-06-29 1943-11-16 Harper J Ransburg Method of spray-coating articles
US2421787A (en) * 1945-01-26 1947-06-10 Harper J Ransburg Company Electrostatic coating method
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US738347A (en) * 1902-11-04 1903-09-08 John N Myers Fabric-coating machine.
US1788600A (en) * 1924-02-07 1931-01-13 James S Smyser Abrasive article and manufacture of same
US1855869A (en) * 1928-12-31 1932-04-26 Western Electric Co Method of and apparatus for coating articles
US2047525A (en) * 1931-09-18 1936-07-14 Thode Adolf Insulating method for electric and thermo-technical purposes, and apparatus for accomplishing the same
US2078790A (en) * 1931-12-24 1937-04-27 Atlas Powder Co Offset process
US2191827A (en) * 1934-04-12 1940-02-27 Carborundum Co Apparatus for applying liquid to fabric
US2221338A (en) * 1936-10-21 1940-11-12 Research Corp Deposition of material
US2187837A (en) * 1936-11-19 1940-01-23 Jens A Paasche Multiple action surface treatment
US2159351A (en) * 1937-01-18 1939-05-23 M J B Company Method of and means for waxing tin plate
US2334648A (en) * 1939-06-29 1943-11-16 Harper J Ransburg Method of spray-coating articles
US2421787A (en) * 1945-01-26 1947-06-10 Harper J Ransburg Company Electrostatic coating method
US2447664A (en) * 1945-02-01 1948-08-24 Westinghouse Elec Elevator Co Electrostatic coating apparatus and method

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2889805A (en) * 1955-01-21 1959-06-09 Goodrich Co B F Electrostatic flocking apparatus
US2994618A (en) * 1957-01-22 1961-08-01 Trion Inc Method and apparatus for electrostatic coating
US3065106A (en) * 1958-11-14 1962-11-20 Electro Dispersion Corp Pan greasing method and apparatus
US2981225A (en) * 1959-01-22 1961-04-25 Gamewell Co Wire insulation coloring apparatus
US4608942A (en) * 1984-05-12 1986-09-02 Fanetech Institute Limited Method of continuously spraying liquids onto lengthy bodies moving at high speed
US4797686A (en) * 1985-05-01 1989-01-10 Burlington Industries, Inc. Fluid jet applicator for uniform applications by electrostatic droplet and pressure regulation control
US4839202A (en) * 1986-09-29 1989-06-13 Aluminum Company Of America Method and apparatus for coating a moving substrate
ES2071576A2 (en) * 1993-08-04 1995-06-16 Navalon Saez Concepcion Method for continuous painting of metallic link chains and the corresponding installation
US20070190261A1 (en) * 2006-02-10 2007-08-16 Ronald Darnell Overspray apparatus and process

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