US2726992A - Process for removing carbonyl sulfide from liquefied petroleum gases - Google Patents
Process for removing carbonyl sulfide from liquefied petroleum gases Download PDFInfo
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- US2726992A US2726992A US418942A US41894254A US2726992A US 2726992 A US2726992 A US 2726992A US 418942 A US418942 A US 418942A US 41894254 A US41894254 A US 41894254A US 2726992 A US2726992 A US 2726992A
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- diethanolamine
- carbonyl sulfide
- hydrocarbon
- sulfide
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- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 title claims description 153
- 238000000034 method Methods 0.000 title claims description 36
- 239000003915 liquefied petroleum gas Substances 0.000 title description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 100
- 150000002430 hydrocarbons Chemical class 0.000 claims description 100
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 91
- 239000004215 Carbon black (E152) Substances 0.000 claims description 69
- 239000007791 liquid phase Substances 0.000 claims description 12
- 239000007789 gas Substances 0.000 claims description 11
- 239000003208 petroleum Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000012071 phase Substances 0.000 description 38
- 239000000243 solution Substances 0.000 description 36
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 32
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 30
- 239000007864 aqueous solution Substances 0.000 description 19
- 239000007788 liquid Substances 0.000 description 15
- 239000000203 mixture Substances 0.000 description 14
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 13
- 239000011593 sulfur Substances 0.000 description 13
- 229910052717 sulfur Inorganic materials 0.000 description 13
- 150000001875 compounds Chemical class 0.000 description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 9
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- 239000001257 hydrogen Substances 0.000 description 9
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 7
- 239000012808 vapor phase Substances 0.000 description 6
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 5
- 238000006477 desulfuration reaction Methods 0.000 description 4
- 230000023556 desulfurization Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 235000014676 Phragmites communis Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000003209 petroleum derivative Substances 0.000 description 2
- 239000011369 resultant mixture Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000006193 liquid solution Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 230000007420 reactivation Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/10—Purification; Separation; Use of additives by extraction, i.e. purification or separation of liquid hydrocarbons with the aid of liquids
Definitions
- This invention relates to a process for removing carbonyl sulfide from liquefied petroleum gases. More particularly, it relates to the removal of carbonyl sulfide, or both carbonyl sulfide and hydrogen sulde, from normally gaseous petroleum fractions by contacting said fractions in the liquid state with an aqueous solution of diethanolamine.
- carbonyl sulfide Among the sulfur-containing compounds commonly found in petroleum gases is carbonyl sulfide. This cornpound is rarely present in virgin petroleum fractions but is formed in most thermal and catalytic cracking operations, which are substantial sources of commercial liquefied petroleum gases. While the amount of carbonyl sulfide contained in liquefied petroleum gases derived from these cracking operations is generally small, usually on the order of several hundred parts per million, nevertheless this amount is still well beyond the allowable limits of a marketable product.
- Carbonyl sulfide is relatively inactive and has the general characteristics of an acid anhydride. lt is not particularly corrosive itself and its corresponding acid, monothiocarbonic acid, is not known in the free state; however, reaction of carbonyl sulfide with water results in the slow formation of hydrogen sulde, which is corrosive, and carbon dioxide. lf a liquid petroleum gas containing carbonyl sulfide is tested immediately after conventional desulfurization treatment, the treated gas will show no indication of the presence of corrosive sulfur, but upon several days standing, if moisture is present, the presence of corrosive sulfur, as free sulfur or hy- 2,726,992 Patented Dec.
- Patent 2,383,416 discloses a method of removing hydrogen sulfide from hydrocarbons with an aqueous solution of diethanolamine.
- the Kerns and Reed patents point out the difhculty of removing carbonyl sulfide from hydrocarbons containing it and indicate that carbonyl sulfide cannot be removed by contact with diethanolamine, Reed stating that:
- carbonyl sulfide can be effectively removed from normally gaseous carbonyl sulfide-containing petroleum fractions by rst liquefying the hydrocarbons and then contacting them with an aqueous solution of diethanolamine. It has also been found that hydrogen sulfide can also be removed from the hydrocarbons by the same treatment and that its removal can be accomplished simultaneously with the carbonyl sulfide removal.
- aqueous diethanolamine solution can be regenerated for reuse by heat by dispelling all of the sulfur-containing compounds removed by the diethanolamine solution from the hydrocarbons in the contacting stage or stages.
- Pursuant to the present invention normally gaseou petroleum hydrocarbons containing carbonyl sulfide are passed in the liquid phase into a contacting zone and intiinto two phases; one, a hydrocarbon phase having a lesser concentration of carbonyl sulfide than the original hydroy and the liquefied hydrocarbons, substantially free of carbonyl sulfide, is withdrawn from the last of the contacting zones.
- An aqueous solution of diethanolamine rs introduced into the last of the contacting Zones and 1s with- Vdrawn from thevfirst contacting zone in a spent or partially spent condition, and is then passed to a reactivator where the solution is regenerated by heat and recycled to the last of the contacting zones, thereby creating a cyclic passage of Vdiethanolamine solution.
- the liquefied hydrocarbon and the aqueous diethanolamine solution are intimately contacted and settled to separate a hydrocarbon phase and an aqueous diethanolamine phase. Over 99 percent of both carbonyl sulfide and hydrogen sulfide present in the original hydrocarbon 'feed can be removed in this manner.
- a great advantage of the use of aqueous diethanolamine solution to remove both carbonyl sulde and hydrogen sulfide from normally gaseous hydrocarbons is that the Y spent, or partially spent, diethanolamine solution may be reactivated, or regenerated, for further use in the contacting stages. All of the sulfur-containing compounds removed from the hydrocarbon feed by the diethanolamine can be expelled from the latter by heating and stripping with steam.
- the appended drawing is a diagrammatic illustration of one arrangement of apparatus and process ow suitable for the practice of the invention.
- au aqueous solution of diethanolamine is introduced into the first stage settler 14 and the second stage settler 19 ⁇ until both settlers 14 and 19 are approximately half full.
- the diethanolamine may be passed from the diethanolamine supply through lines 21, 16 and 18 yinto the second stage settler 19.
- the first stage settler 14 may be charged with diethanolamine by lines 21 and 15.
- the hydrocarbon may be taken directly from line as a product but in preferred operation it passes into the second stage settler as described. Two phases again separate in the second stage settler 19; an upper hydrocarbon layer and an aqueous diethanolamine lower layer. puried hydrocarbon product Substantially free of' both carbonyl sulfide and hydrogen sulfide is removed from the second stage settler 19 by line 20 and is then sent to storage or sales facilities.
- a fresh or reactivated aqueous solution of diethanolamine is passed from the diethanolamine sup-V ply through lines 21 and 16, .line mixer 17, and line 18 into the second stage settler 19.
- the diethanolamine solution is thoroughly mixed with the hydrocarbon mixture which is passing from the first stage settler 14 to the second stage settler 19.
- the diethanolamine solution in settler 19 settles formingV a lower layer which is removed by lineV 22, the rate of removal being adjusted to keep the second stage settler 19 about half full of said lower diethanolamine layer.
- a portion of the lower layer removed from settler 19 by line 22 may be re-introduced into line 16 by line 23 as recycle.
- the remainder of the lower layer removed by line 22 is passed through lines 24, 11 and 13 into the first stage settler 14.
- the partially spent diethanolamine solution is thoroughly mixed with the fresh hydrocarbon feed.
- the diethanolamine lower layer formed in settler 14, except for that required to keep the first stage settler 14 partially fullof said lower layer, is passed through line 25, and a portion of the diethanolamine may be recycled to line 11 by line 26, and the remainder passes through line 27 to storage or reactivation facilities.
- Example I A gaseous hydrocarbon feed composed of 95.0% (by volume) Cz hydrocarbons, 4.75% hydrogen sulfide, and 0.25% carbonyl sulfide was passed in the vapor phase into a contacting zone, where it was intimately contacted with a reactivated aqueous diethanolamine solution of the concentration 18% (by Weight) diethanolamine.
- the hydrocarbon feed treated in one operating day contained 22,800 pounds of hydrogen sulfide and 1,320 pounds of carbonyl sulfide. The hydrocarbons were removed from the contacting Zone and the weight of both hydrogen sulfide and carbonyl sulfide was determined.
- rfhe efliuent from the contacting zone contained pounds per day of hydrogen sulfide, and 750 pounds per day of carbonyl sulfide.
- vapor phase contact of the hydrocarbon feed with aqueous diethanolamine solution removed 99.0% of the hydrogen sulde present in the feed, and only 43.1% of the carbonyl sulfide.
- Example II VA hydrocarbon Afeed similar to that of Example I was treated pursuant to the invention and contained the fol- .effaepea lowing sulfur compounds in the proportions and amounts shown:
- the hydrocarbon efiuent from the first stage settler was then introduced into the second stage settler at a rate of 430 barrels per day and a pressure of 285 p. s. i. g. and contacted with an aqueous solution of diethanolamine containing 18% (by weight) of diethanolamine circulated through the second stage settler at the rate of 925 barrels per day.
- the volume ratio of diethanolamine solution to hydrocarbon circulated through the second stage settler ratio was 2.15/ 1.0.
- the hydrocarbon product from the second stage settler had carbonyl sulfide and hydrogen sulfide contents as indicated below. Percentage removal of these materials from the initial feed is indicated:
- Example III Example II is repeated, except that the liquefied C3 feed contained sulfur compounds in the following amounts:
- Example 6 The product from the first stage settler was contacted with diethanolamine solution at the same volume as in the first stage. r[he final product was analyzed as in Example 1I (inspections are shown below) Pounds Per Day Weight Compound Percent Hydrogen Sulfide Carbonyl Sulde- Mercaptans Contrasting Example I with Examples II and III, it will be noted that when the same hydrocarbon feed is contacted in vapor phase with an aqueous solution of diethanolamine, over 99 percent of the hydrogen sulfide is removed, but only 43.1 percent of the carbonyl sulfide is removed.
- Both hydrogen sulfide and carbonyl sulfide contents of the hydrocarbon feed can be reduced below 1% of their original concentration either, (l) by a first stage contact of the feed in vapor phase with aqueous diethanolamine followed by one or more stages in which the first stage product is liquefied and contacted with aqueous diethanolamine or, (2) by two or more stages in each of which the hydrocarbon feed is contacted in liquid phase with aqueous diethanolamine.
- volume ratios of approximately 2.5 volumes of aqueous diethanolamine solution to l volume of hydrocarbon feed were employed. Volume ratios of 0.1 to 1.0 up to over 5.0 to 1.0 have been used to effect over 99% carbonyl sulfide and hydrogen sulfide removal from hydrocarbon mixtures.
- the preferred volume ratio according to the present invention lies in the range 0.5/1.0 Vto 5.0/1.0 of diethanolamine solution to hydrocarbon feed.
- the period of time in which the liquid hydrocarbon feed is contacted with the diethanolamine solution has varied in operation from 1 second to many minutes, but the preferred range is from 1 to 20 seconds, since any greater contact time is unnecessary to effect the over 99% removal of both carbonyl sulfide and hydrogen sulfide as is done in the present invention.
- Examples II and III show an aqueous diethanolamine solution composed of 17.8 to 18.0% by weight of diethanolamine.
- diethanolamine concentrations from about 10 to about 30% have been employed to effect the same removal as accomplished in the examples, i. e. 99%, but a preferred concentration has been found to be in the range 15 to 25.
- volume ratio of diethanolamine solution to hydrocarbon is in the range 0.5/1 to 5l.
- the process of removing carbonyl sulfide from carbonyl sulfide-containing normally gaseous hydrocarbons which comprises passing said hydrocarbons in liquid phase into acontacting zone and intimately contacting said hydrocarbons with a solution consisting of diethanolamine and water, separating the mixture into a hydrocarbon phase having a lesser concentration of carbonyl sulfide than said hydrocarbon feed, and an aqueous diethanolamine phase, heating said separated diethanolamine phase and passing steam through it to strip the absorbed carbonyl sulfide therefrom and regenerate said diethanolamine phase, cooling said phase and contacting further quantities of carbonyl sulfide-containing liquefied hydrocarbons with the regenerated diethanolamine phase.
- the process for removing carbonyl sulfide from carbonyl sulfide-containing normally gaseous hydrocarbon feed which comprises passing said hydrocarbons in liquid phase into a contacting zone and intimately contacting said hydrocarbons in liquid phase with a solution consisting of diethanolamine and water, separating the mixture into a hydrocarbon phase having a lesser concentration of carbonyl sulfide than said hydrocarbon feed, and an aqueous diethanolamine phase, passing said liquid hydrocarbon phase into a second contacting zone and intimately contacting it with an aqueous solution of diethanolamine, separating the mixture into a liquid hydrocarbon phase substantially free of carbonyl sulfide, and an aqueous diethanolamine phase.
- the process for removing carbonyl sulfide from carbonyl sulfide-containing normally gaseous hydrocarbon feed which comprises passing said hydrocarbon feed in liquid phase into a contacting zone and contacting said hydrocarbon feed in liquid phase with an aqueous solution of diethanolamine, separating the mixture into a hydrocarbon phase having a lesser concentration of carbonyl sulfide than said hydrocarbon feed, and an aqueous diethanolamine phase, passing said liquid hydrocarbon into a second contacting zone and intimately contacting it with an aqueous solution of diethanolamine, separating the mixture into a liquid hydrocarbon phase substantially free of carbonyl sulfide, and an aqueous diethanolamine phase, and passing the separated aqueous diethanolamine phase from the second contacting zone into the first Vcontacting zone.
- the process for separating carbonyl sulfide from carbonyl sulfide-containing normally gaseous hydrocarbon which comprises maintaining a plurality of serially connected contacting zones, liquefying the normally gaseous hydrocarbon feed and passing it into the first of the serially connected contacting zones and withdrawing liquefied hydrocarbons substantially free of carbonyl sulfide from the last of said contacting zones, passing anV aqueous solution of diethanolamine into the last of said contacting zones and withdrawing spent diethanolamine solution from the first of said contacting zones, and in each zone intimately contacting the liquefied hydrocarbon and aqueous ,diethanolamine solution and settling the resultant mixture to separate a hydrocarbon phase and an aqueous diethanolamine phase.
- the process for separating carbonyl sulfide from carbonyl sulfide-containing normally gaseous hydrocarbon which comprises maintaining a plurality of serially connected contacting zones, liquefying the normally gaseous hydrocarbon feed and passing it into the first of the serially connected contacting zones and withdrawing liquefied hydrocarbons substantially free of carbonyl sulfide from the last of said contacting zones, passing an aqueous solution Odiethanolamine into the last of said ⁇ contacting zones and withdrawing spent diethanolamine solution from the first of said contacting zones, heating said spent diethanoiamine solution and passing steam through it to strip the absorbed carbonyl sulfide therefrom and regenrate said solution, cooling said solution and passing said regenerated diethanolamine solution into the last of said contacting zones; and in each zone intimately contacting the liquefied hydrocarbon and aqueous diethanolamine solution and settling the resultant mixture to separate a hydrocarbon phase and an aqueous diethanolamine phase.
- the process for removing carbonyl sulfide from carbonyl sulde-containing normally gaseous hydrocarbon feed which comprises passing said hydrocarbons in liquid phase into the first of two contacting zones and intimately contacting said hydrocarbons in liquid phase with a partially spent aqueous diethanolamine solution effluent from the second contacting zone, separating the mixture into a hydrocarbon phase having a .lesserconcentration of carbonyi sulfide than said hydrocarbon feed and an aqueous phase of spent diethanolamine, withdrawing the spent diethanolamine phase from the first contacting zone and passing the said liquid hydrocarbon phase into the second contacting yzone and intimately contacting it with a fresh aqueous solution of diethanolamine, separating the mixture into a liquid hydrocarbon phase substantially free of carbonyl sulfide, and an aqueous phase of partially spent diethanolamine solution, withdrawing the hydrocarbon phase as a product, withdrawing the partially spent aqueous diethanolamine solution from the second contacting zone and passing it into
Description
J. H; EASTHAGEN ETAL 2,726,992 PROCESS FOR REIMOVING CARBONYL SULPIDE Dec. 13, 1955 FORM LIQUEF'IED PETROLEUM GASES Filed March 26, 1954 HOWARD ALLEN, JA.
United States Patent O PROCESS FOR REMOVING CARBONYL SULFIDE FROM LIQUEFIED PETROLEUM GASES John H. Easthagen, Berkeley, and Howard I. Allen, Jr.,
Oakland, Calif., assignors to California Research Corporation, San Francisco, Calif., a corporation of Delaware Application March 26, 1954, Serial No. 418,942
11 Claims. (Cl. 1961-32) This invention relates to a process for removing carbonyl sulfide from liquefied petroleum gases. More particularly, it relates to the removal of carbonyl sulfide, or both carbonyl sulfide and hydrogen sulde, from normally gaseous petroleum fractions by contacting said fractions in the liquid state with an aqueous solution of diethanolamine.
Presently there is a great demand for liquefied petroleum gases for use as household and automotive fuels. An important source of basic material for liquefied petroleum gas are C3 and C4 hydrocarbons produced in the various refining and cracking processes to which crude oil is subjected. The petroleum gases obtained from these processes contain appreciable quantities of sulfur-containing compounds which must be removed in order to produce a commercially acceptable liquefied petroleum gas. rlhe usual object of the various desulfurization processes that have been developed by the industry is to reduce the sulfur content of the finished product below the point at which serious corrosion would be observed. In the case of liquefied petroleum gas, the maximum allowable sulfur content is ordinarily much lower than in other petroleum products, since even a very low sulfur content, particularly in the form of free sulfur or hydrogen sulfide, is found to cause the formation of sulfur or sulfide deposits which cause faulty operation of the equipment in which the gas is employed. Such troublesome deposits are most commonly formed in the orifices of gas-air mixing equipment in industrial and household gas systems and in carbureting units of automotive equipment. Slow accumulation of such deposits resulting in operational failure may occur even where the sulfur content of the gas is very low. Consequently, highly efficient desulfurization is sought in the production of commercial liquefied petroleum gas.
Among the sulfur-containing compounds commonly found in petroleum gases is carbonyl sulfide. This cornpound is rarely present in virgin petroleum fractions but is formed in most thermal and catalytic cracking operations, which are substantial sources of commercial liquefied petroleum gases. While the amount of carbonyl sulfide contained in liquefied petroleum gases derived from these cracking operations is generally small, usually on the order of several hundred parts per million, nevertheless this amount is still well beyond the allowable limits of a marketable product.
Carbonyl sulfide is relatively inactive and has the general characteristics of an acid anhydride. lt is not particularly corrosive itself and its corresponding acid, monothiocarbonic acid, is not known in the free state; however, reaction of carbonyl sulfide with water results in the slow formation of hydrogen sulde, which is corrosive, and carbon dioxide. lf a liquid petroleum gas containing carbonyl sulfide is tested immediately after conventional desulfurization treatment, the treated gas will show no indication of the presence of corrosive sulfur, but upon several days standing, if moisture is present, the presence of corrosive sulfur, as free sulfur or hy- 2,726,992 Patented Dec. 13, 1955 drogen sulfide, will positively show upon testing. The relatively unreactive character of carbonyl sulfide itself and the slowness or its hydrolysis to the more reactive hydrogen sulfide makes efiicient carbonyl sulfide removal by conventional desulfurization methods virtually impossible.
Many methods and reagents have been proposed for the purpose or removing carbonyl sulfide and hydrogen sulfide, usually involving contact of the sulfide-containing hydrocarbons with a generally alkaline compound. Strongly alkaline solutions or suspensions of weakly basic or amphoteric metallic hydroxides, the metals of which form insoluble sulfides, have been proposed. Also, various primary amines have been employed. Kerns et al., in U. S. Patent 2,311,342, describe a process for the removal of carbonyl sulfide from hydrocarbons liquids by contacting the liquids with monoethanolamine. Reed, in U. S. Patent 2,383,416, discloses a method of removing hydrogen sulfide from hydrocarbons with an aqueous solution of diethanolamine. The Kerns and Reed patents, point out the difhculty of removing carbonyl sulfide from hydrocarbons containing it and indicate that carbonyl sulfide cannot be removed by contact with diethanolamine, Reed stating that:
Repeated tests, over long periods of time, have shown that diethanolamine in aqueous solution is inert toward carbonyl sulphide and that there is no appreciable reaction with carbon bisulphide or aldehydes. (P. 2, 2nd col., lines 3l-35.)
ln the past, carbonyl sulfide and hydrogen sulfide impurities in hydrocarbon mixtures have been removed by separate processes. For example, hydrogen sulfide has been removed by employing the method of Bottoms, in U. S. Reissue Patent 18,958, in which vaporized hydrocarbon mixtures are contacted with liquid solutions of amines, after which the carbonyl sulfide is separately removed for example, with monoethanolamine, or with an aqueous solution of monoethanolamine and an alkali metal hydroxide as shown in U. S. Patent 2,594,311.
It appears that when monoethanolamine is employed to remove carbonyl sulfide from carbonyl sulfide-contaminated gases, a stable reaction product of the monoethanolamine and carbonyl sulfide is formed and the monoethanolamine cannot be regenerated for use by a simple heat treatment.
It is an object of the present invention to provide a method for effecting substantially complete removal of carbonyl sulfide from petroleum products of the type employed as liquefied petroleum gases.
It is a further object to provide a method for the removal of both carbonyl sulfide and hydrogen sulfide impurities from petroleum mixtures simultaneously.
It has been found that carbonyl sulfide can be effectively removed from normally gaseous carbonyl sulfide-containing petroleum fractions by rst liquefying the hydrocarbons and then contacting them with an aqueous solution of diethanolamine. it has also been found that hydrogen sulfide can also be removed from the hydrocarbons by the same treatment and that its removal can be accomplished simultaneously with the carbonyl sulfide removal.
It has also been found that the aqueous diethanolamine solution can be regenerated for reuse by heat by dispelling all of the sulfur-containing compounds removed by the diethanolamine solution from the hydrocarbons in the contacting stage or stages.
Pursuant to the present invention, normally gaseou petroleum hydrocarbons containing carbonyl sulfide are passed in the liquid phase into a contacting zone and intiinto two phases; one, a hydrocarbon phase having a lesser concentration of carbonyl sulfide than the original hydroy and the liquefied hydrocarbons, substantially free of carbonyl sulfide, is withdrawn from the last of the contacting zones. An aqueous solution of diethanolamine rs introduced into the last of the contacting Zones and 1s with- Vdrawn from thevfirst contacting zone in a spent or partially spent condition, and is then passed to a reactivator where the solution is regenerated by heat and recycled to the last of the contacting zones, thereby creating a cyclic passage of Vdiethanolamine solution. In each contacting zone, the liquefied hydrocarbon and the aqueous diethanolamine solution are intimately contacted and settled to separate a hydrocarbon phase and an aqueous diethanolamine phase. Over 99 percent of both carbonyl sulfide and hydrogen sulfide present in the original hydrocarbon 'feed can be removed in this manner.
A great advantage of the use of aqueous diethanolamine solution to remove both carbonyl sulde and hydrogen sulfide from normally gaseous hydrocarbons is that the Y spent, or partially spent, diethanolamine solution may be reactivated, or regenerated, for further use in the contacting stages. All of the sulfur-containing compounds removed from the hydrocarbon feed by the diethanolamine can be expelled from the latter by heating and stripping with steam.
The results obtained in the employment of diethanolamine pursuant to the present invention are unexpected in two significant particulars; first, it is unexpected in view of the teachings of the prior art that any means could be found to edect carbonyl sulfide removal with diethanolamine and second, it is unexpected that diethanolamine,
which has been employed in the process until its capacity.
to remove carbonyl sulfide is spent, can be regenerated by simple steam stripping, especially in View of the fact that carbonyl sulfide and monoethanolamine form a stable reaction product as shown in Kerns et al., U. S. Patent 2,311,342.
The appended drawing is a diagrammatic illustration of one arrangement of apparatus and process ow suitable for the practice of the invention.
To start the process, au aqueous solution of diethanolamine is introduced into the first stage settler 14 and the second stage settler 19 `until both settlers 14 and 19 are approximately half full. This may be done by any con venient method, for example, the diethanolamine may be passed from the diethanolamine supply through lines 21, 16 and 18 yinto the second stage settler 19. The first stage settler 14 may be charged with diethanolamine by lines 21 and 15.
After both settlers 14 and 19 are about half full, liquefied hydrocarbon gases containing carbonyl sulfide and hydrogen sulfide are passed as feed through lines 10 and 11, line mixer 12, and line 13 into the first stage settler 14. Lines 11 and 13, and mixer 12 constitute the rst stage contacting zone. In the first stage settler 14, two separate phase are formed. An upper layer of hydrocarbons, containing a lesser concentration of carbonyl sulde and hydrogen sulfide than in the original hydrocarbon feed, and a lower layer of aqueous diethanolamine containing reacted carbonyl sulde and hydrogen sulde. The upper hydrocarbon layer is removed from the first stage settler 14 and passed through lines 15, 16, line mixer 17, and
line 18 into the second stage settler 19. Lines 16 and v18,-
and mixer 17 constitute the second stage contacting zone. The hydrocarbon may be taken directly from line as a product but in preferred operation it passes into the second stage settler as described. Two phases again separate in the second stage settler 19; an upper hydrocarbon layer and an aqueous diethanolamine lower layer. puried hydrocarbon product Substantially free of' both carbonyl sulfide and hydrogen sulfide is removed from the second stage settler 19 by line 20 and is then sent to storage or sales facilities.
At the same time as the hydrocarbon feed'is treated as described above, a fresh or reactivated aqueous solution of diethanolamine is passed from the diethanolamine sup-V ply through lines 21 and 16, .line mixer 17, and line 18 into the second stage settler 19. In the second stage contacting zone, i. e. lines 16 and 18 and mixer 17, the diethanolamine solution is thoroughly mixed with the hydrocarbon mixture which is passing from the first stage settler 14 to the second stage settler 19. The diethanolamine solution in settler 19 settles formingV a lower layer which is removed by lineV 22, the rate of removal being adjusted to keep the second stage settler 19 about half full of said lower diethanolamine layer. A portion of the lower layer removed from settler 19 by line 22 may be re-introduced into line 16 by line 23 as recycle. The remainder of the lower layer removed by line 22 is passed through lines 24, 11 and 13 into the first stage settler 14. In the first stage contacting zone, i. e. lines 11 and 13, and mixer 12, the partially spent diethanolamine solution is thoroughly mixed with the fresh hydrocarbon feed. The diethanolamine lower layer formed in settler 14, except for that required to keep the first stage settler 14 partially fullof said lower layer, is passed through line 25, and a portion of the diethanolamine may be recycled to line 11 by line 26, and the remainder passes through line 27 to storage or reactivation facilities.
It is readily apparent from the foregoing description that various modifications of the process can be made within the spirit of the present invention and the scope of the appended claims. VFor example, the process is suitable for use in conjunction with processes that remove only hydrogen sulfide, thereby utilizing the present invention only for carbonyl sulfide removal. A still further modification is the passing of the diethanolamine efiiuent from line 27 which is only partially spent into a vapor phase process which utilizes diethanolamine as an agent for the removal of hydrogen sulfide. Further, many equipment or apparatus modifications may be made by those skilled in the art, and still not depart from the scope of the present invention.
The following examples illustrate the removal of carbonyl sulfide and hydrogen sulfide from normally gaseous hydrocarbons pursuant to the invention.
n Example I A gaseous hydrocarbon feed composed of 95.0% (by volume) Cz hydrocarbons, 4.75% hydrogen sulfide, and 0.25% carbonyl sulfide was passed in the vapor phase into a contacting zone, where it Was intimately contacted with a reactivated aqueous diethanolamine solution of the concentration 18% (by Weight) diethanolamine. The hydrocarbon feed treated in one operating day contained 22,800 pounds of hydrogen sulfide and 1,320 pounds of carbonyl sulfide. The hydrocarbons were removed from the contacting Zone and the weight of both hydrogen sulfide and carbonyl sulfide was determined. rfhe efliuent from the contacting zone contained pounds per day of hydrogen sulfide, and 750 pounds per day of carbonyl sulfide. Thus, vapor phase contact of the hydrocarbon feed with aqueous diethanolamine solution removed 99.0% of the hydrogen sulde present in the feed, and only 43.1% of the carbonyl sulfide.
Example II VA hydrocarbon Afeed similar to that of Example I was treated pursuant to the invention and contained the fol- .effaepea lowing sulfur compounds in the proportions and amounts shown:
W ht P ds ercentl eig oun emova Compound Percent Per Day From Feed Hydrogen Sulde 190 93. 5 Carbouyl Sulfide 006 5 98.9 Mercaptans 33 250 10. 7
The hydrocarbon efiuent from the first stage settler was then introduced into the second stage settler at a rate of 430 barrels per day and a pressure of 285 p. s. i. g. and contacted with an aqueous solution of diethanolamine containing 18% (by weight) of diethanolamine circulated through the second stage settler at the rate of 925 barrels per day. The volume ratio of diethanolamine solution to hydrocarbon circulated through the second stage settler ratio was 2.15/ 1.0. The hydrocarbon product from the second stage settler had carbonyl sulfide and hydrogen sulfide contents as indicated below. Percentage removal of these materials from the initial feed is indicated:
P d PercelnzRe- Weight oun s move rom Compound Per Original Percent Day Feed (Weight) Hydrogen Sulde 003 2. 4 99 Plus. Carbonyl Sultide .001 7 99.84. Mercaptans 20 151. 46.1.
Example III Example II is repeated, except that the liquefied C3 feed contained sulfur compounds in the following amounts:
Pounds Weight Compound Per Percent Day Hydrogen Sulde 58 432 Carbonyl Snldp 39 288 Mercaptans 59 435 W ht P d lercemal eig oun s emov Compound Percent Per Day From Feed Hydrogen Fulde .087 64 85.2 Cnrboriyl Sulde--. .0014 1 99.6 Mercftp tens 345 256 41. 2
6 The product from the first stage settler was contacted with diethanolamine solution at the same volume as in the first stage. r[he final product was analyzed as in Example 1I (inspections are shown below) Pounds Per Day Weight Compound Percent Hydrogen Sulfide Carbonyl Sulde- Mercaptans Contrasting Example I with Examples II and III, it will be noted that when the same hydrocarbon feed is contacted in vapor phase with an aqueous solution of diethanolamine, over 99 percent of the hydrogen sulfide is removed, but only 43.1 percent of the carbonyl sulfide is removed. However, if the hydrocarbon feed in liquid phase is contacted with an aqueous solution of diethanolamine, and if only one such contacting stage is employed, about 99 percent of the carbonyl sulfide is removed. However, if only one liquid contact stage is employed, only to 94 percent of the hydrogen sulfide present in the original feed is removed.
Both hydrogen sulfide and carbonyl sulfide contents of the hydrocarbon feed can be reduced below 1% of their original concentration either, (l) by a first stage contact of the feed in vapor phase with aqueous diethanolamine followed by one or more stages in which the first stage product is liquefied and contacted with aqueous diethanolamine or, (2) by two or more stages in each of which the hydrocarbon feed is contacted in liquid phase with aqueous diethanolamine.
In the process of the present invention as shown in Examples II and III, volume ratios of approximately 2.5 volumes of aqueous diethanolamine solution to l volume of hydrocarbon feed were employed. Volume ratios of 0.1 to 1.0 up to over 5.0 to 1.0 have been used to effect over 99% carbonyl sulfide and hydrogen sulfide removal from hydrocarbon mixtures. The preferred volume ratio according to the present invention lies in the range 0.5/1.0 Vto 5.0/1.0 of diethanolamine solution to hydrocarbon feed.
The period of time in which the liquid hydrocarbon feed is contacted with the diethanolamine solution has varied in operation from 1 second to many minutes, but the preferred range is from 1 to 20 seconds, since any greater contact time is unnecessary to effect the over 99% removal of both carbonyl sulfide and hydrogen sulfide as is done in the present invention.
Examples II and III show an aqueous diethanolamine solution composed of 17.8 to 18.0% by weight of diethanolamine. However, diethanolamine concentrations from about 10 to about 30% have been employed to effect the same removal as accomplished in the examples, i. e. 99%, but a preferred concentration has been found to be in the range 15 to 25.
We claim:
1. The method of removing carbonyl sulfide from no11 mally gaseous petroleum hydrocarbons containing car bonyl sulde which comprises intimately contacting said hydrocarbon gases in liquid phase with a solution consisting of diethanolamine and water.
2. The method as defined in claim 1 wherein the volume ratio of diethanolamine solution to hydrocarbon is in the range 0.5/1 to 5l.
3. The method as defined in claim l wherein the time of contact between the hydrocarbon and the diethanolamine solution is in the range 1 to 20 seconds.
4. The method as defined in claim 1 wherein the concentration of aqueous diethanolamine solution is in the range from about 10 to 30% by Weight of diethanolamine.
5. The process of removing carbonyl sulfide from carbonyl sulfide-containing normally gaseous hydrocarbons which comprises passing said hydrocarbons in liquid phase into acontacting zone and intimately contacting said hydrocarbons with a solution consisting of diethanolamine and water, separating the mixture into a hydrocarbon phase having a lesser concentration of carbonyl sulfide than said hydrocarbon feed, and an aqueous diethanolamine phase, heating said separated diethanolamine phase and passing steam through it to strip the absorbed carbonyl sulfide therefrom and regenerate said diethanolamine phase, cooling said phase and contacting further quantities of carbonyl sulfide-containing liquefied hydrocarbons with the regenerated diethanolamine phase.
6. The process for removing carbonyl sulfide from carbonyl sulfide-containing normally gaseous hydrocarbon feed which comprises passing said hydrocarbons in liquid phase into a contacting zone and intimately contacting said hydrocarbons in liquid phase with a solution consisting of diethanolamine and water, separating the mixture into a hydrocarbon phase having a lesser concentration of carbonyl sulfide than said hydrocarbon feed, and an aqueous diethanolamine phase, passing said liquid hydrocarbon phase into a second contacting zone and intimately contacting it with an aqueous solution of diethanolamine, separating the mixture into a liquid hydrocarbon phase substantially free of carbonyl sulfide, and an aqueous diethanolamine phase.
7, The process for removing carbonyl sulfide from carbonyl sulfide-containing normally gaseous hydrocarbon feed which comprises passing said hydrocarbon feed in liquid phase into a contacting zone and contacting said hydrocarbon feed in liquid phase with an aqueous solution of diethanolamine, separating the mixture into a hydrocarbon phase having a lesser concentration of carbonyl sulfide than said hydrocarbon feed, and an aqueous diethanolamine phase, passing said liquid hydrocarbon into a second contacting zone and intimately contacting it with an aqueous solution of diethanolamine, separating the mixture into a liquid hydrocarbon phase substantially free of carbonyl sulfide, and an aqueous diethanolamine phase, and passing the separated aqueous diethanolamine phase from the second contacting zone into the first Vcontacting zone.
8. The process for separating carbonyl sulfide from carbonyl sulfide-containing normally gaseous hydrocarbon which comprises maintaining a plurality of serially connected contacting zones, liquefying the normally gaseous hydrocarbon feed and passing it into the first of the serially connected contacting zones and withdrawing liquefied hydrocarbons substantially free of carbonyl sulfide from the last of said contacting zones, passing anV aqueous solution of diethanolamine into the last of said contacting zones and withdrawing spent diethanolamine solution from the first of said contacting zones, and in each zone intimately contacting the liquefied hydrocarbon and aqueous ,diethanolamine solution and settling the resultant mixture to separate a hydrocarbon phase and an aqueous diethanolamine phase.
9. The process for separating carbonyl sulfide from carbonyl sulfide-containing normally gaseous hydrocarbon which comprises maintaining a plurality of serially connected contacting zones, liquefying the normally gaseous hydrocarbon feed and passing it into the first of the serially connected contacting zones and withdrawing liquefied hydrocarbons substantially free of carbonyl sulfide from the last of said contacting zones, passing an aqueous solution Odiethanolamine into the last of said `contacting zones and withdrawing spent diethanolamine solution from the first of said contacting zones, heating said spent diethanoiamine solution and passing steam through it to strip the absorbed carbonyl sulfide therefrom and regenrate said solution, cooling said solution and passing said regenerated diethanolamine solution into the last of said contacting zones; and in each zone intimately contacting the liquefied hydrocarbon and aqueous diethanolamine solution and settling the resultant mixture to separate a hydrocarbon phase and an aqueous diethanolamine phase. 1f). The process for removing carbonyl sulfide from carbonyl sulde-containing normally gaseous hydrocarbon feed which comprises passing said hydrocarbons in liquid phase into the first of two contacting zones and intimately contacting said hydrocarbons in liquid phase with a partially spent aqueous diethanolamine solution effluent from the second contacting zone, separating the mixture into a hydrocarbon phase having a .lesserconcentration of carbonyi sulfide than said hydrocarbon feed and an aqueous phase of spent diethanolamine, withdrawing the spent diethanolamine phase from the first contacting zone and passing the said liquid hydrocarbon phase into the second contacting yzone and intimately contacting it with a fresh aqueous solution of diethanolamine, separating the mixture into a liquid hydrocarbon phase substantially free of carbonyl sulfide, and an aqueous phase of partially spent diethanolamine solution, withdrawing the hydrocarbon phase as a product, withdrawing the partially spent aqueous diethanolamine solution from the second contacting zone and passing it into the first contacting zone,
1l. The process for removing carbonyl sulfide and hydrogen sulfide from a normally gaseous hydrocarbon feed containing substantial amounts of these materials which comprises passing the carbonyl sulfide and hydrogen sulfide-containing hydrocarbons into a contacting zone and intimately contacting said hydrocarbons in vapor phase with anaqueous solution of diethanolamine, removing the gaseous yhydrocarbons from said contacting zone, liquefying the normally gaseous hydrocarbon effluent from the contacting zone, passing the said liquefied hydrocarbons into a second contacting zone and intimately contacting said liquid hydrocarbons with an aqueous solution of diethanolamine, separating Vthe mixture into a liquid hydrocarbon phase having a lesser concentration of carbonyl sulfide and hydrogen sulfide than said hydrocarbon feed, and an aqueous diethanolamine phase, pass-V ing the separated diethanolamine phase from the second contacting zone into the first contacting zone, passing said liquid hydrocarbon phase into Va third contacting zone and intimately contacting it with an aqueous solution of diethanolamine, separating the mixture into a liquid hydrocarbon phase substantially free of carbonyl sulfide and hydrogen suifide, and an aqueous diethanolamine phase, and passing the separated diethanolamine phase from tue third contacting zone into the second contacting zone.
References Cited in the file of this patent UNTrED STATES PATENTS Y 2,238,201 Wilson et al p Apr. 15, 1941 2,311,342 Kerns et al Feb. 16, 1943 2,564,970 Hanson Aug. 21, 1951 2,594,311 Johnson et al Apr. 29, 1952 OTHER REFERENCES Petroleum Refiner, vol. 32, No. 9, September 1953, page 124.
Claims (1)
1. THE METHOD OF REMOVING CARBONYL SULFIDE FROM NONMALLY GASEOUS PETROLEUM HYDROCARBONS CONTAINING CARBONYL SULFIDE WHICH COMPRISES INTIMATELY CONTACTING SAID HYDROCARBON GASES IN LIQUID PHASE WITH A SOLUTION CONSISTING OF DIETHANOLAMINE AND WATER.
Priority Applications (1)
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US418942A US2726992A (en) | 1954-03-26 | 1954-03-26 | Process for removing carbonyl sulfide from liquefied petroleum gases |
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US418942A US2726992A (en) | 1954-03-26 | 1954-03-26 | Process for removing carbonyl sulfide from liquefied petroleum gases |
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US2726992A true US2726992A (en) | 1955-12-13 |
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US418942A Expired - Lifetime US2726992A (en) | 1954-03-26 | 1954-03-26 | Process for removing carbonyl sulfide from liquefied petroleum gases |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2892775A (en) * | 1954-04-16 | 1959-06-30 | Tidewater Oil Company | Diethanolamine recovery by steam stripping |
US4233141A (en) * | 1979-04-27 | 1980-11-11 | The Ralph M. Parsons Company | Process for removal of carbonyl sulfide in liquified hydrocarbon gases with absorption of acid gases |
US4749555A (en) * | 1986-10-02 | 1988-06-07 | Shell Oil Company | Process for the selective removal of hydrogen sulphide and carbonyl sulfide from light hydrocarbon gases containing carbon dioxide |
US5298228A (en) * | 1992-09-08 | 1994-03-29 | Atlantic Richfield Company | Method and apparatus for treating hydrocarbon gas streams contaminated with carbonyl sulfide |
US9126879B2 (en) | 2013-06-18 | 2015-09-08 | Uop Llc | Process for treating a hydrocarbon stream and an apparatus relating thereto |
US9284493B2 (en) | 2013-06-18 | 2016-03-15 | Uop Llc | Process for treating a liquid hydrocarbon stream |
US9283496B2 (en) | 2013-06-18 | 2016-03-15 | Uop Llc | Process for separating at least one amine from one or more hydrocarbons, and apparatus relating thereto |
US9327211B2 (en) | 2013-06-18 | 2016-05-03 | Uop Llc | Process for removing carbonyl sulfide in a gas phase hydrocarbon stream and apparatus relating thereto |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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US2238201A (en) * | 1937-09-18 | 1941-04-15 | Carbide & Carbon Chem Corp | Purification of hydrocarbon liquids |
US2311342A (en) * | 1941-03-15 | 1943-02-16 | Standard Oil Dev Co | Sulphur removal from hydrocarbons |
US2564970A (en) * | 1946-11-08 | 1951-08-21 | Phillips Petroleum Co | Liquid-liquid contacting |
US2594311A (en) * | 1949-04-23 | 1952-04-29 | California Research Corp | Removal of carbonyl sulfide from liquefied petroleum gas |
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1954
- 1954-03-26 US US418942A patent/US2726992A/en not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2238201A (en) * | 1937-09-18 | 1941-04-15 | Carbide & Carbon Chem Corp | Purification of hydrocarbon liquids |
US2311342A (en) * | 1941-03-15 | 1943-02-16 | Standard Oil Dev Co | Sulphur removal from hydrocarbons |
US2564970A (en) * | 1946-11-08 | 1951-08-21 | Phillips Petroleum Co | Liquid-liquid contacting |
US2594311A (en) * | 1949-04-23 | 1952-04-29 | California Research Corp | Removal of carbonyl sulfide from liquefied petroleum gas |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2892775A (en) * | 1954-04-16 | 1959-06-30 | Tidewater Oil Company | Diethanolamine recovery by steam stripping |
US4233141A (en) * | 1979-04-27 | 1980-11-11 | The Ralph M. Parsons Company | Process for removal of carbonyl sulfide in liquified hydrocarbon gases with absorption of acid gases |
US4749555A (en) * | 1986-10-02 | 1988-06-07 | Shell Oil Company | Process for the selective removal of hydrogen sulphide and carbonyl sulfide from light hydrocarbon gases containing carbon dioxide |
US5298228A (en) * | 1992-09-08 | 1994-03-29 | Atlantic Richfield Company | Method and apparatus for treating hydrocarbon gas streams contaminated with carbonyl sulfide |
US9126879B2 (en) | 2013-06-18 | 2015-09-08 | Uop Llc | Process for treating a hydrocarbon stream and an apparatus relating thereto |
US9284493B2 (en) | 2013-06-18 | 2016-03-15 | Uop Llc | Process for treating a liquid hydrocarbon stream |
US9283496B2 (en) | 2013-06-18 | 2016-03-15 | Uop Llc | Process for separating at least one amine from one or more hydrocarbons, and apparatus relating thereto |
US9327211B2 (en) | 2013-06-18 | 2016-05-03 | Uop Llc | Process for removing carbonyl sulfide in a gas phase hydrocarbon stream and apparatus relating thereto |
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