US2687362A

US2687362A - Soldering flux composition

Info

Publication number: US2687362A
Application number: US226281A
Authority: US
Inventors: Walter H C Rueggeberg
Original assignee: Tennessee Corp
Current assignee: Tennessee Corp
Priority date: 1951-05-14
Filing date: 1951-05-14
Publication date: 1954-08-24
Anticipated expiration: 1971-08-24

Description

Patented Aug. 24, 1954 UNITED STATES OFFICE signor to Tennessee C N. Y., a corporation of New York Fulton County, Ga., asorporation, New York,

No Drawing. Application May 14, 1951, Serial No. 226,281

12 Claims. 1

This invention relates to soldering flux compositions and more particularly to an aqueous fiuxing solution for use in the metal-working arts for purposes such as tinning steel, soldering various metals such as copper, brass, galvanized pipe and black pipe, andthe like.

One of the objects of the invention is to provide an improved soldering flux composition which is convenient to handle and use and effective in removing surface contamination from and cleaning the metal surfaces to be soldered or otherwise treated.

Another object is to provide an improved soldering flux composition having good detergent and emulsifying properties for the removal of greasy materials from the surfaces to be cleaned and soldered.

A further object is to provide an improved soldering flux composition capable of converting metallic surface contaminants into metal compounds soluble in aqueous media and hence easily removable from the surfaces to be cleaned and soldered.

A still further object is to provide an improved soldering flux composition of the type characterized in the preceding objects which is also adapted to minimize if not prevent entirely the occurrence of acid conditions at the soldered joint.

Fluxing compositions embodying the invention comprise an alkanolammonium salt of an alkyl benzene sulfonic acid together with a sub-' stantial excess of alkanolamine, the composition being dissolved in water to form an aqueous fluxing solution of suitable concentration for application to the surfaces to be cleaned and soldered.

The alkyl group or groups attached as side chains to the benzene nuclei of the sulfonic acid may be either straight chain or branched chain radicals and may be of any suitable length up to about 18 carbon atoms. However, longer side chains generally increase the effectiveness of the composition to some extent and 'hence are preferred. For example, good results have been obtained with toluene sulfonic acid, as well as with sulfonic acids containing larger alkyl groups such'as amylbenzene sulfonic acid and dodecylbenzene sulfonic acid. It will be understood that commercial alkylbenzenes can be used in which there may be considerable variation in the side chains. Thus in commercial amylbenzene, the side chain may be largely the iso compound; commercial dodecylbenzene has a side chain made up of polymerized propylene and therefore branched, While only about 90% of the material Cir has a side chain equivalent to C12, the remainder being 09 and C15 with probably some C18- For practical reasons, the use of alkylbenzenes having side chains averaging more than 18 carbon atoms is undesirable.

The alkanolamines preferred for use in the invention include the ethanolamines and the isopropanol amines and may be primary, secondary, or tertiary, although in general the tertiary compounds are preferred. The alkanolamine neutralizes the sulfonic acid, forming its alkanolammonium salt. It is important for reasons explained below to use a substantial excess of alkanolamine above the amount required for such neutralization. Preferably the proportions of sulfonic acid and alkanolamine should be of the order of one mole of acid to at least two moles of alkanolamine, but the proportion of alkanolamine can be susbtantially reduced, say to 1 moles or even less, while on the other hand it can be increased to three moles or more which may be desirable in some cases in order to obtain a completely liquid product for ease of handling.

The above mentioned fluxing agents are applied "to the work in the form of an aqueous soltuion of suitable concentration. For most purposes, a concentration of 30-60% by weight gives good results, but the amount of water used is not critical and maybe either more or less than this range.

While the absolute mechanism of the fiuxing action is not completely understood, it is presently believed that the good results obtained with fiuxing compositions such as described above are due to the following effects and reactions. The alkanolammonium salts of the alkyl benzene sulfonic acids are good detergents and emulsifying agents and hence effective in removing greasy materials and the like from the surfaces to be cleaned and soldered. On the other hand, the metallic compounds that contaminate the surfaces to be soldered comprise metal oxides and metal salts that are largely inorganic in nature. These compounds react with the fiuxing agents to form metal salts of the sulfonic acid, which are soluble in aqueous media in the presence of excess alkanolamine and hence can be removed readily from the surfaces to be cleaned.

The excess alkanolamine also minimizes or prevents the occurrence of acid conditions at the soldered joint. This effect is especiallyimportant in soldering wires in electric motors, rheostats, transformers and other electrical equipment where acid conditions generated at the point cause deterioration of the soldered connections and eventual breakdown. Excess alkanolamine tends to keep the flux from turning acid and to prevent the occurrence of acid conditions at the soldered joint. To be on the safe side, sufficient alkanolamine may be used to keep the system neutral or slightly alkaline even though all of the sulfur in the sulionio should be converted to sulfuric acid as the result of thermal decomposition.

The following are typical examples of fluxing solutions embodying the invention that have been used with good results:

of soldering may Water to form 5060% solution.

(Nora-This particular mixture is somewhat :gelatinous, but nevertheless effective as a flux.)

Moles Dodecylbenzene sulfonic acid 1 Monoisopropanolamine 3 Water to form 30-60% solution.

(NDTE.This mixture is completely liquid, and is preferred to the preceding composition because of greater :ease of handling.)

Moles Dodecylbenzene-sulfonic acid 1 Diisopropanolamine "a..- 2 Water to form 4050% solution.

Dodecylbenzene sulfonic acid 1 Triisopropanolamine 2 Water to form 40-50% solution.

It will be understood that the invention is not restricted to the details particularly set/forth in the foregoing description and examples, and that various other embodiments of the invention may now be devised by those skilled in the art without departing from its spirit. Reference should therefore be had to the appended claims for a-definition of the limits of the invention.

What is claimed is:

1. A soldering flux composition consisting essentially of an alkanolammonium salt of an alkyl benzene sulfonic acid having not more than about 18 carbon atoms in the alkyl side chain and excess alkanolamine in the approximate proportions of one mole of acid and from 1 /2 to about three moles of alkanolamine, said alkanolamine being selected from the group consisting of primary, secondary and tertiary ethanolamines and isopropanolamines.

2. A soldering flux composition consisting essentiallyof an alkanolammonium salt of an alkyl benzene sulfonic acid having not more than about 18 carbon atoms in the alkyl side chain and excess alkanolamine in the approximate proportions of one mole of acid and two moles of alkanolamine, said alkanolamine being selected from the group consisting of primary, secondary and tertiary ethanolamines and isopropanolamines.

3. A fluxing solution adaptedxfor use in soldering metals and consisting essentially of'a'n aqueous solution of an alkanolamine and an alkanolammonium salt of an alkyl benzene sulfonic acid having not more than about 18 carbon atoms in the alkyl side chain in the approximate proportions of one mole of acid and from 1 /2 to about three moles of alkanolamine, said alkanolamine being selected from the group consisting of primary, secondary and tertiary ethanolamines and isopropanolamines.

4. A fluxing solution adapted for use in soldering metals and consisting essentially of an aqueous solution of an alkanolamine and an alkanolammonium salt of analkyl benzene sulfonic acid having not more than about 18 carbon atoms in the alkyl side chain in the approximate proportions of one mole of acid and two moles of alkanolamine, said alkanolamine being selected irom the group consisting of primary, secondary and tertiary ethanolamines and isopropanolamines.

5. A soldering flux sentially of approximately one benzene sulfonic acid having not more than about 18 carbon atoms in the alkyl side chain and about two moles of triethanolamine.

6. A fluxing solution adapted for use in soldering metals and consisting essentially of an aqueous solution of triethanolamine and triethanolammonium salt of an alkyl benzene sulfonic acid having not more than about 18 carbon atoms in the alkyl side chain, said acid and triethanole amine being in the proportions of one mole of acid and from 1 /2 moles of triethanolamine.

7. A fiuxing solution as defined in claim 6, said solution containing from 30% to 60% by weight of said acid and triethanolamine.

8. A soldering flux composition consisting essentially of approximately one mole of an alkyl benzene sulfonic acid having not more than about 18 carbon atoms in the alkyl side chain and about two moles of triisopropanolamine.

9. A fluxing solution adapted for use in solderto about three ing metals and consisting essentially of an aqueous solution of triisopropanolamine and triisopropanolammonium salt of an alkyl benzenesulfonic acid having not more than about 18 carbon atoms in the alkyl side chain, said acid and triisopropanolamine being in the proportions of the approximately one mole of acid and from 1 to about three moles of triisopropanolamine.

10. A fiuxing solution as defined in claim 9,-

said solution containing from 30% to 60% by weight of said acid and triisopropanolamine.

11. A soldering flux consisting essentially of an alkanolammonium salt of an alkyl benzene sulfonic acid having about twelve carbon atoms in the alkyl side chain and excess alkanolamine in the approximate proportions of one mole of acid to two moles of alkanolamine. said alkanolamine being selected from the group consisting of primary, ethanolamines and isopropanolamines.

12. A fluxing solution adapted for use in soldering metals and consisting essentially of an aqueous solution containing about 30% to 60% by, weight of alkanolammonium salt of an alkyl composition consisting esmole of an .alkyl approximately secondary and tertiary benzene sulfonic acid having about twelve carbon atoms in the alkyl side chain and excess alkanoiamine in the approximate proportionsot one mole ofacid to two moles of alkanolamine, said alkanolamine being selected from the group consisting of primary, secondary and tertiary ethanolamines and isopropanolamines.

References Cited in the file 01' this patent Number 6 Name Date McQuaid Dec. 16, 1930 Taylor Dec. 16, 1930 McQuaid Mar. 6, 1934 Freeman Sept. 12, 1939 Flett May 19, 1942 Di Ginlio May 23, 1950

Claims

1. A SOLDERING FLUX COMPOSITION CONSISTING ESSENTIALLY OF AN ALKANOLAMMONIUM SALT OF AN ALKYL BENZENE SULFONIC ACID HAVING NOT MORE THAN ABOUT 18 CARBON ATOMS IN THE ALKYL SIDE CHAIN AND EXCESS ALKANOLAMINE IN THE APPROXIMATE PROPORTIONS OF ONE MOLE OF ACID AND FROM 11/2 TO ABOUT THREE MOLES OF ALKANOLAMINE, SAID ALKANOLAMINE BEING SELECTED FROM THE GROUP CONSISTING OF PRIMARY, SECONDARY AND TERTIARY ETHANOLAMINES AND ISOPROPANOLAMINES.