US2672031A - Fractionation of gas mixtures - Google Patents
Fractionation of gas mixtures Download PDFInfo
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- US2672031A US2672031A US189357A US18935750A US2672031A US 2672031 A US2672031 A US 2672031A US 189357 A US189357 A US 189357A US 18935750 A US18935750 A US 18935750A US 2672031 A US2672031 A US 2672031A
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04151—Purification and (pre-)cooling of the feed air; recuperative heat-exchange with product streams
- F25J3/04187—Cooling of the purified feed air by recuperative heat-exchange; Heat-exchange with product streams
- F25J3/0423—Subcooling of liquid process streams
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04406—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
- F25J3/04412—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2200/00—Processes or apparatus using separation by rectification
- F25J2200/50—Processes or apparatus using separation by rectification using multiple (re-)boiler-condensers at different heights of the column
- F25J2200/54—Processes or apparatus using separation by rectification using multiple (re-)boiler-condensers at different heights of the column in the low pressure column of a double pressure main column system
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/02—Internal refrigeration with liquid vaporising loop
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S62/00—Refrigeration
- Y10S62/902—Apparatus
- Y10S62/905—Column
Definitions
- Figure 1 illustrates a double column in vertical section, the column being provided with an external heat interchanger for a purpose to be described, and
- Figure 2 illustrates a modified form of the apparatus having the interchanging elements located inside the low pressure section of the column.
- the column itself consists of two stacks of fractionating plates, as at H? and H, separated by a partition including a downwardly draining condenser I2.
- gaseous nitrogen is separated, in a variable degree of purity which depends on the number and effectiveness of the plates in this section, and a crude oxygen (for example, of 35% concentration) collects in a pool 43 in the base of the column.
- the gaseous nitrogen passes into condenser 52, in which it is liquefied, a part of the liquidreturning to reflux the plates of the lower section while a part is collected on an annular tray hi. From this tray the liquid nitrogen passes to the top of the upper section of the column, in which it functions as reflux liquid for the upper stack of plates, this section being maintained at a materially lower pressure, as for example 5 pounds gauge. In passing from the higher to the lower press re ill) a potrion of the liquid nitrogen is evaporated,
- this section separate the crude oxygen into two fractions: gaseous nitrogen, which passes out of the upper end of the tower, and liquid oxygen, which collects in a pool (5 surrounding condenser l2.
- gaseous nitrogen which passes out of the upper end of the tower
- liquid oxygen which collects in a pool (5 surrounding condenser l2.
- Each of these products may and ordinarily will be somewhat impure, depending on the overall efficiency of the column, but the purity of the nitrogen and the quantity of oxygen recoverable at any given degree of purity will be enhanced by the use of the step hereinafter described.
- the pressure of the first or higher pressure stage rises until it becomes stable at a point where the nitrogen, in condensing in condenser 12, is at a temperature slightly higher than that of the oxygen in pool Hi of the second or lower pressure stage, and is thus enabled to impart heat to the oxygen, constantly boiling it.
- the separated oxygen collecting in pool :5 which is one of the final products of the column, may be withdrawn in liquid form from below the surface of the pool, as at Hi. If preferred, the oxygen may be withdrawn as a vapor from the gaseous body above the surface of the pool, as at H.
- gaseous nitrogen and liquid nitrogen are used for identification only and do not imply that the nitrogen is in a state of purity.
- the nitrogen vapor condensing in condenser i2 is in equilihriurn with a liquid containing oxygen and therefore cannot be wholly oxygen-free, and the nitrogen vapor passing out of the upper end of the column also may contain an appreciable proportion or oxygen. While the operation or a double column is improved by reducing the oxygen content of the refluxing nitrogen to the iowest feasible point, the invention herein de scribed is functional so long as some fractionation takes place in the high-pressure section of the column, so that a boiling point difference is established.
- liquid nitrogen should be understood to refer to the liquid collecting in the upper end of the high-pressure sec tion, this liquid containing more nitrogen and less oxygen than the air feed.
- crude oxygen should be understood to refer to the liquid collecting in the base of the column, this liquid containing less nitrogen and more oxygen than the air feed.
- the crude oxygen flows from pool l3 through conduit I! and an expansion valve l8 into one side of an indirect heat interchanger l9.
- conduit 20 conveying the vapor together with the residual liquid to a medial point in the upper column section, as at 2 l.
- the high-pressure nitrogen passes from the pool in tray l4 through conduit 22 to the opposite side of the interchanger, in which it preferably counterflows the crude oxygen, fiowing thence through conduit 23 and an expansion valve 2 to the upper end of the column as at 25.
- a similar interchange is performed within the lowpressure section of the column.
- a deep tray 25 is placed within the column at a medial height and a suitable transfer surface, such as a coil 2?, is fitted within it.
- Conduit 28 conducts highpressure liquid nitrogen to the coil, which discharges through conduit 29 and expansion valve 30 into the upper portion of the column at 25.
- the stream of crude oxygen flows through con duit 3i and an expansion valve 32 to a point of entry into the low-pressure section, which may be directed into the tray as at 33, or onto a plate above the tray as at 34, or onto a plate below the tray as at 35.
- a single expansion valve is shown and the valves in the branch connections are used as diversion valves only, but if preferred these may be individual expansion valves and any one or two of them may be omitted if the desired point of entry has been predetermined.
- the excessive quantity of vapor accompanying the liquid nitrogen entering the lowpressure section results in the entrainment of liquid mist in the nitrogen vapor leaving the column and also requires special means to prevent turbulent conditions on the topmost plate.
- the invention is described only in connection with the fractionation of air, it is equally adapted to and useful in the separation of any binary gas mixture. More broadly, the invention is useful in any fractionation in which a lowboiling reflux liquid is condensed at a relatively high pressure by the evaporation of the higherboiling component of the feed mixture at a relatively low pressure.
- the utility of the invention is not confined to column arrangements in which the low-pressure section is superimposed on the high-pressure, but extends to pairs of columns arranged in parallel.
- a heat interchanger having separate flow paths for two fluids; conduit means connecting the respective ends of one of said flow paths with said collecting means and with the upper portion of the lower-pressure section; conduit means connecting the respective ends of the other of said flow paths directly with the lower end of the higher-pressure section and with a medial point in the height of the lower-pressure section; an expansion valve in first said conduit means downstream from said interchanger and 7 an expansion valve in last said conduit means upstream from said interchanger.
- a heat interchanger comprising a tubular element and a surrounding vessel, the upper end of said vessel communicating for liquefied gaseous mixtures having sections adapted to be maintained at different pressures, each section being provided with means for producing repeateddirect contacts between liquids and vapors counterfiowing therein and the higher pressure section having means in its upper end for collecting a liquid enriched in the lower-boiling component of said gaseous mixture: a tubular element located at a medial height within the lower-pressure section and means for retaining a pool of liquid surrounding said element; a conduit connecting said collecting means with one end of said tubular element and a conduit connecting the other end of
- a tubular element located at a medial height within the lowerpressure section and means for retaining a pool of liquid surroundingsaid element; a conduit connecting said collecting means with said tubular element and a conduit connecting said tubular element with the upper portion of the lower-pressure section; an expansion valve in last said conduit; a conduit connecting the lower portion of the higher-pressure section with a. point in the lower-pressure section below said liquid pool and an expansion valve in said conduit, and means for directing liquids condensing in the upper portion of the lower-pressure section into said pool and from said pool into the lower portion of the lower-pressure section.
Description
Imp
March 16,, 1954 c U G 2,672,031
FRACTIIONATION OF GAS MIXTURES Original Filed June 27, 1945 T NITROGEN JJLILJI.
F!G.l no.2
C.J. SCHIL LING INVE TOR ATTORNEY Patented Mar. 16, 1954 FRAGTIONATION OF GAS MIXTURES Clarence J. Schilling, Allentown, Pa., assignor to Air Products Incorporated, Chattanooga, Tenn, a corporation of Michigan Continuation of application Serial No. 601,769,
June 27, 1945.
1950,- Serial No. 189,357
9 Claims.
column commonly used in air fractionation and illustrated in the attached drawings, in which Figure 1 illustrates a double column in vertical section, the column being provided with an external heat interchanger for a purpose to be described, and
Figure 2 illustrates a modified form of the apparatus having the interchanging elements located inside the low pressure section of the column.
The functioning of the two-stage column is so well known that only the brieiest description is needed. Referring to Figure l, the column itself consists of two stacks of fractionating plates, as at H? and H, separated by a partition including a downwardly draining condenser I2.
Air under a relatively high pressure, for example 75 pounds gauge, and previously cooled to the point of incipient or partial liquefaction, is admitted into the lower compartment it. In this section gaseous nitrogen is separated, in a variable degree of purity which depends on the number and effectiveness of the plates in this section, and a crude oxygen (for example, of 35% concentration) collects in a pool 43 in the base of the column.
The gaseous nitrogen passes into condenser 52, in which it is liquefied, a part of the liquidreturning to reflux the plates of the lower section while a part is collected on an annular tray hi. From this tray the liquid nitrogen passes to the top of the upper section of the column, in which it functions as reflux liquid for the upper stack of plates, this section being maintained at a materially lower pressure, as for example 5 pounds gauge. In passing from the higher to the lower press re ill) a potrion of the liquid nitrogen is evaporated,
leaving the column as a saturated vapor.
The crude oxygen collecting in pool I3 is similarly expanded into the upper section of the column, but at a medial height. The plates in This application October 10,
this section separate the crude oxygen into two fractions: gaseous nitrogen, which passes out of the upper end of the tower, and liquid oxygen, which collects in a pool (5 surrounding condenser l2. Each of these products may and ordinarily will be somewhat impure, depending on the overall efficiency of the column, but the purity of the nitrogen and the quantity of oxygen recoverable at any given degree of purity will be enhanced by the use of the step hereinafter described.
By reason of the difference in the boiling points of oxygen and nitrogen, the pressure of the first or higher pressure stage rises until it becomes stable at a point where the nitrogen, in condensing in condenser 12, is at a temperature slightly higher than that of the oxygen in pool Hi of the second or lower pressure stage, and is thus enabled to impart heat to the oxygen, constantly boiling it.
The separated oxygen collecting in pool :5, which is one of the final products of the column, may be withdrawn in liquid form from below the surface of the pool, as at Hi. If preferred, the oxygen may be withdrawn as a vapor from the gaseous body above the surface of the pool, as at H.
It will he understood that, in this description and also in the appended claims, the terms gaseous nitrogen and liquid nitrogen are used for identification only and do not imply that the nitrogen is in a state of purity. The nitrogen vapor condensing in condenser i2 is in equilihriurn with a liquid containing oxygen and therefore cannot be wholly oxygen-free, and the nitrogen vapor passing out of the upper end of the column also may contain an appreciable proportion or oxygen. While the operation or a double column is improved by reducing the oxygen content of the refluxing nitrogen to the iowest feasible point, the invention herein de scribed is functional so long as some fractionation takes place in the high-pressure section of the column, so that a boiling point difference is established. Thus the term liquid nitrogen should be understood to refer to the liquid collecting in the upper end of the high-pressure sec tion, this liquid containing more nitrogen and less oxygen than the air feed. The term crude oxygen should be understood to refer to the liquid collecting in the base of the column, this liquid containing less nitrogen and more oxygen than the air feed.
I have discovered that the functioning of a two-stage fractionating system, as exemplified in the operation of the double column above described, may be improved materially by abstracting heat from the liquid nitrogen in its passage from the high-pressure to the low-pressure stage. Two methods of effecting this heat abstraction, by interchange against colder fluids, are illustrated in the two figures of the attached drawings.
Referring first to Fig. l, the crude oxygen flows from pool l3 through conduit I! and an expansion valve l8 into one side of an indirect heat interchanger l9. In this unit a portion of the crude oxygen vaporizes, conduit 20 conveying the vapor together with the residual liquid to a medial point in the upper column section, as at 2 l. The high-pressure nitrogen passes from the pool in tray l4 through conduit 22 to the opposite side of the interchanger, in which it preferably counterflows the crude oxygen, fiowing thence through conduit 23 and an expansion valve 2 to the upper end of the column as at 25.
In the modification illustrated in Fig. 2 a similar interchange is performed within the lowpressure section of the column. A deep tray 25 is placed within the column at a medial height and a suitable transfer surface, such as a coil 2?, is fitted within it. Conduit 28 conducts highpressure liquid nitrogen to the coil, which discharges through conduit 29 and expansion valve 30 into the upper portion of the column at 25. The stream of crude oxygen flows through con duit 3i and an expansion valve 32 to a point of entry into the low-pressure section, which may be directed into the tray as at 33, or onto a plate above the tray as at 34, or onto a plate below the tray as at 35. In the drawing a single expansion valve is shown and the valves in the branch connections are used as diversion valves only, but if preferred these may be individual expansion valves and any one or two of them may be omitted if the desired point of entry has been predetermined.
The immediate effect of this abstraction of heat from the liquid nitrogen is to reduce, or even to eliminate, the vaporization of the liquid nitrogen stream as it passes the nitrogen expansion valve into a zone of reduced pressure.
The liquid nitrogen leaves the lower section of the column at its boiling point under the pressure existing in this (high pressure) section. In passing to the lower pressure existing in the upper section, without the use of my invention, it must vaporize to such extent as to bring it to its boiling point at the lower pressure. This vaporization has at least three undesirable effects, all of which are reduced or even eliminated by the use of the steps herein described. These undesirable effects are:
First, the excessive quantity of vapor accompanying the liquid nitrogen entering the lowpressure section results in the entrainment of liquid mist in the nitrogen vapor leaving the column and also requires special means to prevent turbulent conditions on the topmost plate.
Second, and this becomes more important as the oxygen content of the liquid nitrogen increases, the vaporization of liquid results in the loss of some oxygen which would otherwise be fractionated from the mixture and added to the oxygen production.
Third, the vaporization of liquid reduces the quantity of reflux available for those plates of the upper section which are located above the crude oxygen inlet. This reduction in reflux necessitates either an increase in the number of plates, the acceptancev of a reduced oxygen prostream;
duction or purity, or any two or even all three of these disadvantages.
The abstraction of heat from the liquid nitro gen, prior to its expansion, reduces all three of these undesirable efiects and, if performed to a sufficient extent, results in their complete elimination.
While the invention is described only in connection with the fractionation of air, it is equally adapted to and useful in the separation of any binary gas mixture. More broadly, the invention is useful in any fractionation in which a lowboiling reflux liquid is condensed at a relatively high pressure by the evaporation of the higherboiling component of the feed mixture at a relatively low pressure. Thus the utility of the invention is not confined to column arrangements in which the low-pressure section is superimposed on the high-pressure, but extends to pairs of columns arranged in parallel.
I claim:
1. In a liquefied gas fractionating operation conducted in two zones maintained at a higher and at a lower pressure respectively, with upfiowing vapors in repeated direct contacts with downfiowing liquids in each zone; the sequence of steps consisting in withdrawing a stream of a relatively high-boiling liquid and a stream of a relatively low-boiling liquid from the higher pressure zone; cooling the first mentioned stream solely by expanding it to the lower pressure; bringing the lower-boiling liquid without change of phase into heat interchange relation with said expanded stream and thereby cooling said lower-boiling expanding said cooled lower-boiling stream to the lower pressure, and introducing both said expanded streams into the lower-pressure zone.
2. In a liquefied gas fractionating operation conducted in two zones maintained at a higher and at a lower pressure respectively, with upfiowing vapors in repeated direct contacts with downfiowing liquids in each zone; the sequence of steps consisting in withdrawing liquid streams of a relatively high-boiling and a relatively low-boiling component from the higher-pressure zone; cooling the higher-boiling stream solely by expanding it to the lower pressure; and cooling the liquid lower-boiling stream under the higher pressure by heat interchange with the higherboiling stream under the lower pressure.
3. In a liquefied gas fractionating operation conducted in two zones maintained at a higher and at a lower pressure respectively: the sequence of steps consisting in withdrawing a relatively low-boiling liquid stream from the upper end of the higher-pressure zone; expanding said liquid stream to the lower pressure and introducing the expanded stream into the lower-pressure zone, and cooling said liquid stream prior to said expansion by heat interchange with a mixed liquid drawn in part from the lower end of the higher-pressure zone and in part from the upper portion of the lower-pressure zone, said mixed liquid boiling at substantially the lower pressure during said interchange.
4. In a liquefied gas fractionating operation conducted in two zones maintained at a higher and at a lower pressure respectively, with upfiowing vapors in repeated direct contacts with downflowing liquids in each zone, the combination of steps comprising: withdrawing a liquid stream rich in the lower-boiling components of said gas from the higher-pressure zone; expanding said liquid stream to the lower pressure and. introducing said expanded stream into the lower-pressure zone, and cooling said liquid stream prior to said expansion by heat interchange with a liquid derived from at least one of said zones, said liquid being initially at the temperature at which it existed in the zone from which it was derived and boiling at substantially the lower pressure during said interchange.
5. In a liquefied gas fractionating operation conducted in two zones maintained at a higher and at a lower pressure respectively: the sequence of steps consisting in withdrawing a liquid stream rich in the lower-boiling components of said gas from the upper end of the higher-pressure zone; expanding said liquid stream to the lower pressure and introducing the expanded stream into the lower-pressure zone, and cooling said liquid stream prior to said expansion by heat interchange with a liquid refluxing from the upper portion of the lower-pressure zone and boiling therein at the lower pressure.
,6. In combination with a fractionating column for liquefied gaseous mixtures having sections adapted to be maintained at difierent pressures, at least the higher pressure section having means for producing repeated direct contacts between liquids and vapors counterfiowing therein and having means in its upper end for collecting a liquid rich in the lower-boiling component of said gaseous mixture: a heat interchanger having separate flow paths for two fluids; conduit means connecting the respective ends of one of said flow paths with said collecting means and with the upper portion of the lower-pressure section; conduit means connecting the respective ends of the other of said flow paths directly with the lower end of the higher-pressure section and with a medial point in the height of the lower-pressure section; an expansion valve in first said conduit means downstream from said interchanger and 7 an expansion valve in last said conduit means upstream from said interchanger.
'7. In combination with a fractionating column for liquefied gaseous mixtures having sections adapted to be maintained at diflerent pressures, at least the higher pressure section having means for producing repeated direct contacts between liquids and vapors counterfiowing therein and having means in its upper end for collecting -a liquid rich in the lower-boiling component of said gaseous mixture: a heat interchanger comprising a tubular element and a surrounding vessel, the upper end of said vessel communicating for liquefied gaseous mixtures having sections adapted to be maintained at different pressures, each section being provided with means for producing repeateddirect contacts between liquids and vapors counterfiowing therein and the higher pressure section having means in its upper end for collecting a liquid enriched in the lower-boiling component of said gaseous mixture: a tubular element located at a medial height within the lower-pressure section and means for retaining a pool of liquid surrounding said element; a conduit connecting said collecting means with one end of said tubular element and a conduit connecting the other end of said tubular element with the upper portion of the lower-pressure section; an expansion valve in last said conduit downstream from said element; a conduit arranged to convey liquid from the lower portion of the higher-pressure section into said liquid pool and an expansion valve in last said conduit, and means for directing liquids condensing in the upper portion of the lower pressure section into said liquid pool.
9. In combination with a fractionating column for liquefied gaseous mixtures having sections adapted to be maintained at different pressures, each section having means for producing repeated direct contacts between liquids and vapors counterflowing therein and the higher-pressure section having means in its upper end for collecting a liquid rich in the lower-boiling component of said gaseous mixture: a tubular element located at a medial height within the lowerpressure section and means for retaining a pool of liquid surroundingsaid element; a conduit connecting said collecting means with said tubular element and a conduit connecting said tubular element with the upper portion of the lower-pressure section; an expansion valve in last said conduit; a conduit connecting the lower portion of the higher-pressure section with a. point in the lower-pressure section below said liquid pool and an expansion valve in said conduit, and means for directing liquids condensing in the upper portion of the lower-pressure section into said pool and from said pool into the lower portion of the lower-pressure section.
CLARENCE J. SCHILLING.
References Cited in the file of this patent UNITED STATES PATENTS Number Name Date 1,426,461 Claude Aug. 22, 1922 1,626,345 LeRouge Apr. 26, 1927 1,784,120 Van Nuys Dec. 9, 1930 1,970,299 Frankl Aug. 14, 1934 2,009,084 Gomonet July 23, 1935 2,035,516 Wilkinson Mar. 31, 1936 2,386,297 Dennis Oct. 9, 1945 2,527,301 Fausek Oct. 24, 1950 FOREIGN PATENTS Number Country Date 703,862 France May '7, 1931
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US189357A US2672031A (en) | 1950-10-10 | 1950-10-10 | Fractionation of gas mixtures |
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US189357A US2672031A (en) | 1950-10-10 | 1950-10-10 | Fractionation of gas mixtures |
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US2672031A true US2672031A (en) | 1954-03-16 |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2897656A (en) * | 1955-03-30 | 1959-08-04 | Philips Corp | Gas-fractionating system |
US3516262A (en) * | 1967-05-01 | 1970-06-23 | Mc Donnell Douglas Corp | Separation of gas mixtures such as methane and nitrogen mixtures |
EP0639746A1 (en) * | 1993-08-16 | 1995-02-22 | The Boc Group, Inc. | Air separation |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1426461A (en) * | 1917-12-06 | 1922-08-22 | Air Liquide | Method of separating the constituents of gaseous mixtures |
US1626345A (en) * | 1922-03-16 | 1927-04-26 | L Air Liquide Soc | Method of separating gaseous mixtures |
US1784120A (en) * | 1926-10-23 | 1930-12-09 | Air Reduction | Separation of the constituents of gaseous mixtures |
FR703862A (en) * | 1929-12-13 | 1931-05-07 | Air Liquide | Improvements in gas mixture separation processes |
US1970299A (en) * | 1929-04-19 | 1934-08-14 | American Oxythermic Corp | Low pressure process for separating low boiling gas mixtures |
US2009084A (en) * | 1933-05-04 | 1935-07-23 | Air Reduction | Process of separating air and similar gaseous mixtures by liquefaction and rectification |
US2035516A (en) * | 1934-08-01 | 1936-03-31 | Air Reduction | Method of separating the constituents of gaseous mixtures |
US2386297A (en) * | 1943-10-07 | 1945-10-09 | Air Reduction | Separation of the constituents of gaseous mixtures by liquefaction and rectification |
US2527301A (en) * | 1943-08-04 | 1950-10-24 | Arthur J Fausek | Method of separating the constituents of gaseous mixtures |
-
1950
- 1950-10-10 US US189357A patent/US2672031A/en not_active Expired - Lifetime
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1426461A (en) * | 1917-12-06 | 1922-08-22 | Air Liquide | Method of separating the constituents of gaseous mixtures |
US1626345A (en) * | 1922-03-16 | 1927-04-26 | L Air Liquide Soc | Method of separating gaseous mixtures |
US1784120A (en) * | 1926-10-23 | 1930-12-09 | Air Reduction | Separation of the constituents of gaseous mixtures |
US1970299A (en) * | 1929-04-19 | 1934-08-14 | American Oxythermic Corp | Low pressure process for separating low boiling gas mixtures |
FR703862A (en) * | 1929-12-13 | 1931-05-07 | Air Liquide | Improvements in gas mixture separation processes |
US2009084A (en) * | 1933-05-04 | 1935-07-23 | Air Reduction | Process of separating air and similar gaseous mixtures by liquefaction and rectification |
US2035516A (en) * | 1934-08-01 | 1936-03-31 | Air Reduction | Method of separating the constituents of gaseous mixtures |
US2527301A (en) * | 1943-08-04 | 1950-10-24 | Arthur J Fausek | Method of separating the constituents of gaseous mixtures |
US2386297A (en) * | 1943-10-07 | 1945-10-09 | Air Reduction | Separation of the constituents of gaseous mixtures by liquefaction and rectification |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2897656A (en) * | 1955-03-30 | 1959-08-04 | Philips Corp | Gas-fractionating system |
US3516262A (en) * | 1967-05-01 | 1970-06-23 | Mc Donnell Douglas Corp | Separation of gas mixtures such as methane and nitrogen mixtures |
EP0639746A1 (en) * | 1993-08-16 | 1995-02-22 | The Boc Group, Inc. | Air separation |
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