US2624667A - Cartridge for below-surface treatment of molten metals - Google Patents

Cartridge for below-surface treatment of molten metals Download PDF

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US2624667A
US2624667A US171066A US17106650A US2624667A US 2624667 A US2624667 A US 2624667A US 171066 A US171066 A US 171066A US 17106650 A US17106650 A US 17106650A US 2624667 A US2624667 A US 2624667A
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metal
container
cartridge
additive
plug
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US171066A
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Tour Sam
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JULIUS S W BATES
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JULIUS S W BATES
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    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04—Removing impurities by adding a treating agent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12222—Shaped configuration for melting [e.g., package, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12486—Laterally noncoextensive components [e.g., embedded, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12639—Adjacent, identical composition, components
    • Y10T428/12646—Group VIII or IB metal-base
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12639—Adjacent, identical composition, components
    • Y10T428/12646—Group VIII or IB metal-base
    • Y10T428/12653—Fe, containing 0.01-1.7% carbon [i.e., steel]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12729—Group IIA metal-base component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12736—Al-base component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771—Transition metal-base component
    • Y10T428/12778—Alternative base metals from diverse categories

Definitions

  • One of the difiiculties resides in the fact that the additive material being lighter (at the bath temperature) than the molten metal to be treated, will remain on the surface of the bath and therefore will not reach the bulk of the material to be treated.
  • cored solid pieces of metal basically of the composition of the molten metal bath, and in which the cores are composed of the additive, have been used.
  • the composite is selected sufficiently heavy to initially sink below the surface of the metal bath in the hope that it will there release the treating agent. This desideratum is not achieved. If the cored piece is open to the outside, such as an open ended tube, the major portion of the charge will have to be released by the time the piece has sunk an appreciable depth.
  • the cored piece is substantially closed, such as a tube with crimped or plugged ends, in which case dissolution of the body of the piece by the molten metal bath is relied upon for release of the charge, such release is effected substantially at the surface of the bath, since as the body of the composite is dissolved away by the molten metal bath, the ratio of core cavity to body of the composite reaches a point at which sinking takes place no longer. As more of the body is dissolved away, the composite rises towards the surface of the molten metal bath and by the time that sufficient of the body has been dissolved away to expose the additive, the
  • One object of the instant invention comprises,
  • an improved cartridge capable of discharging or exposing an additive at an effective treating level below the surface of a molten metal bath.
  • Fig. 1 is a vertical section through an embodiment of my invention.
  • Fig. 2 is a top view of the construction shown in Fig. 1.
  • I represents the body of the treating cartridge, which may be of any desired form.
  • the preferred form is substantially cylindrical.
  • a centrally located core cavity 2 of circular cross-section is provided.
  • the conical base 3 of the core cavity may constitute as much as 10% of the volume of the cavity 2.
  • Cavity 2 is filled with a quantity of the alkali or alkaline earth metal to be used as treating agent. This is preferably introduced in the form of a solid plug 4, filling or substantially filling the cavity 2 while leaving the conical base 3 empty to allow for the higher coefficient of expansion of the additive metal.
  • a pressure-retaining metal disc 6 is placed in the position shown on seat '1, at which time the metal of which the upper part of the cartridge is composed, is in the form shown in dotted outline 8 (Fig. 1), following which a suitable tool, such as a punch of an outside diameter equal to that of the recess 9, is forced into the top IQ of the cartridge, thereby forming from the sides of the recess the sealing ring I! of displaced metal bearing on disc 6.
  • a suitable tool such as a punch of an outside diameter equal to that of the recess 9
  • the conical base 3 terminates in tubular duct l2, which in turn connects with orifice l3.
  • Duct i2 and orifice I3 together form an aperture extending between cavity 2 and the outside of the cartridge 1.
  • Orifice i3 is closed by a plug it of fusible material, preferably metal, having a melting point above the melting point :of the additive metal and preferably below the boiling point of the same.
  • the fusible plug is adapted to release the additive metal as soon as the cartridge arrives at a temperature predetermined by the material of which the plug is composed, before the mass density of the cartridge as a whole has undergone any marked reduction due to the dissolving away of its exterior or due to its reaching a temperature approximately that of the liquid metal to be treated, and before the boiling of the additive metal can create an internal pressure which may burst the cartridge with explosive violence.
  • the I cartridge and disc will be formed of steel; if the additive metal is an alkali metal, the fusible plugs M and l 3; may be formed of aluminum, and if the additive metal is an alkaline earth metal, the
  • fusible plugs I l and It may be formed of copper.
  • the cartridge and disc will be formed of copper; if the additive metal is an alkali metal the fusible plugs i l and may be formed of aluminum, and if the additive metal is an alkaline earth metal, the fusible plugs l4 and I6 may be formed of a brass having a melting point above that of the alkaline earth metal and below that of copper.
  • the additive metal will release itself uniformly and harmlessly at a point adjacent the bottom of the charge, so that its full chemical effect is realized.
  • the percentage volume of its core cavity In order to assure that the treating cartridge and contents will have a specific gravity substantially in excess of that of the material of the liquid metal to be treated, and will therefore sink to the bottom before discharging its contents, the percentage volume of its core cavity,

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Description

Patented Jan. 6, 1953 CARTRIDGE FOR BELOW-SURFACE TREAT- MENT F MOLTEN METALS Sam Tour, New York, N. Y., assignor to Julius S. W. Bates, Phoenix, Ariz.
Application June 29, 1950, Serial No. 171,066
6 Claims.
Table M. P B. P. Sp. Gr.
Barium 850 l, l40 3. Calcium. 810 1,240 1.54 LithiunL 186 l, 609:l;5 534 Magnesium 651 l, 110 l. 74 Potassium 62. 3 760 86 Sodium. 97. 5 880 971 Str0ntium 752 1, 150 2. 6
The difficulty in introducing purifying additives of lower specific gravity and with boiling points lower than the temperature of the molten metal to be treated, has been of long standing and up to now efficient ways of adding these additives have not been found.
One of the difiiculties resides in the fact that the additive material being lighter (at the bath temperature) than the molten metal to be treated, will remain on the surface of the bath and therefore will not reach the bulk of the material to be treated.
Attempts have been made to remedy this by securing the additive to the end of a rod and plunging it into the molten metal, thus pushing it underneath the surface thereof. This is extremely hazardous, particularly when the addi tive is one of high reactivity.
Alternatively, cored solid pieces of metal basically of the composition of the molten metal bath, and in which the cores are composed of the additive, have been used. In this case, the composite is selected sufficiently heavy to initially sink below the surface of the metal bath in the hope that it will there release the treating agent. This desideratum is not achieved. If the cored piece is open to the outside, such as an open ended tube, the major portion of the charge will have to be released by the time the piece has sunk an appreciable depth. If the cored piece is substantially closed, such as a tube with crimped or plugged ends, in which case dissolution of the body of the piece by the molten metal bath is relied upon for release of the charge, such release is effected substantially at the surface of the bath, since as the body of the composite is dissolved away by the molten metal bath, the ratio of core cavity to body of the composite reaches a point at which sinking takes place no longer. As more of the body is dissolved away, the composite rises towards the surface of the molten metal bath and by the time that sufficient of the body has been dissolved away to expose the additive, the
cartridge will have risen to substantially the bath surface.
One object of the instant invention comprises,
inter alia, an improved cartridge capable of discharging or exposing an additive at an effective treating level below the surface of a molten metal bath.
The invention will be fully understood from the following description read in conjunction with the drawings in which:
Fig. 1 is a vertical section through an embodiment of my invention; and
Fig. 2 is a top view of the construction shown in Fig. 1.
Referring to the drawings I represents the body of the treating cartridge, which may be of any desired form. The preferred form is substantially cylindrical. A centrally located core cavity 2 of circular cross-section is provided. The conical base 3 of the core cavity may constitute as much as 10% of the volume of the cavity 2. Cavity 2 is filled with a quantity of the alkali or alkaline earth metal to be used as treating agent. This is preferably introduced in the form of a solid plug 4, filling or substantially filling the cavity 2 while leaving the conical base 3 empty to allow for the higher coefficient of expansion of the additive metal.
After this addition a pressure-retaining metal disc 6 is placed in the position shown on seat '1, at which time the metal of which the upper part of the cartridge is composed, is in the form shown in dotted outline 8 (Fig. 1), following which a suitable tool, such as a punch of an outside diameter equal to that of the recess 9, is forced into the top IQ of the cartridge, thereby forming from the sides of the recess the sealing ring I! of displaced metal bearing on disc 6.
The conical base 3 terminates in tubular duct l2, which in turn connects with orifice l3. Duct i2 and orifice I3 together form an aperture extending between cavity 2 and the outside of the cartridge 1. Orifice i3 is closed by a plug it of fusible material, preferably metal, having a melting point above the melting point :of the additive metal and preferably below the boiling point of the same. The fusible plug is adapted to release the additive metal as soon as the cartridge arrives at a temperature predetermined by the material of which the plug is composed, before the mass density of the cartridge as a whole has undergone any marked reduction due to the dissolving away of its exterior or due to its reaching a temperature approximately that of the liquid metal to be treated, and before the boiling of the additive metal can create an internal pressure which may burst the cartridge with explosive violence.
Inasmuch as there may be conditions within the charge to be treated which will operate against the uniform heating of the cartridge o which, if the cartridge lands on the bottom with the orifice l3 downwardly, might cause the cartridge to be propelled back to the surface of the melt by rocket effect, I find it advisable to provide a second fusible plug located substantially opposite the first, and for this purpose I preferably form within the disc 5 the aperture 15, which is also closed by a fusible plug ill of fusible material, preferably of metal, having a melting point above the melting point of the additive metal charge and preferably below the boiling point of the same.
In actual practice in treating iron or steel the I cartridge and disc will be formed of steel; if the additive metal is an alkali metal, the fusible plugs M and l 3; may be formed of aluminum, and if the additive metal is an alkaline earth metal, the
fusible plugs I l and It may be formed of copper.
In actual practice when treating a charge of molten copper, the cartridge and disc will be formed of copper; if the additive metal is an alkali metal the fusible plugs i l and may be formed of aluminum, and if the additive metal is an alkaline earth metal, the fusible plugs l4 and I6 may be formed of a brass having a melting point above that of the alkaline earth metal and below that of copper.
In either case the additive metal will release itself uniformly and harmlessly at a point adjacent the bottom of the charge, so that its full chemical effect is realized.
In order to assure that the treating cartridge and contents will have a specific gravity substantially in excess of that of the material of the liquid metal to be treated, and will therefore sink to the bottom before discharging its contents, the percentage volume of its core cavity,
meaning thereby both the space occupied by the plug of additive metal together with the expansion space, should be less than substantially d,d TXIOO in which (is is the specific gravity of. the metal of said cartridge when solid and dc the specific gravity of the metal of said cartridge at its freezing point when molten.
The foregoing specific description is for purposes of illustration and not of limitation and it is therefore my intention that the invention be limited only by the appended claims or their equivalents wherein I have endeavored to claim broadly all inherent novelty.
I claim:
1. A cartridge for the treatment of a molten metal with a relatively small amount of an additive metal selected from the group consisting of the alkali and alkaline earth metals, consisting of a metal container defining and completely enveloping a cavity, a charge of said additive metal within said cavity, the weight of the container and charge exceeding the weight of a corresponding volume in liquid state of the metal of which the container is composed, the wall of said container defining an aperture extending between said cavity and the outside of said container, and at least one plug of fusible material of relatively small size in comparison with the size of said metal container blocking said aperture, the size of said plug being so limited that its fusion and removal will not reduce the weight of the cartridge below the weight of a corresponding volume in liquid state of the metal of which the container is composed said plug having a melting point above that of said additive metal and below that of the metal of which said container is composed and below the boiling point of said additive metal.
2. A cartridge according to claim 1 in which said container is composed of iron, said additive metal is an alkali metal and said plug of fusible material is aluminum.
3. A cartridge according to claim 1 in which said container is composed of iron, said additive metal is an alkaline earth metal and said plug of fusible material is copper.
4. A cartridge according to claim 1 in which said container is composed of copper, said additive metal is an alkali metal and said plug of fusible material is aluminum.
5. A cartridge according to claim 1 in which said container is composed of copper, said additive metal is an alkaline earth metal and said plug of fusible material is brass.
6. A cartridge for the treatment of a molten metal with a relatively small amount of an additive metal selected from the group consisting of the alkali and alkaline earth metals, consisting of a metal container defining and completely enveloping a cavity, a charge of said additive metal within said cavity, the weight of the container and charge exceeding the weight of a corresponding volume in liquid state of the metal of which the container is composed, the wall of said container defining a first aperture extending from said cavity to the outer surface of said container, a second aperture substantially opposite said first aperture extending from said cavity to the outer surface of said container, and a plug of fusible material of relatively small size in comparison with the size of said metal container blocking each said aperture, the size of said plugs being so limited that their fusion and removal will not reduce the weight of the cartridge below the weight of a corresponding volume in liquid state of the metal of which the container is composed said plug having a melting point above that of said additive metal and below that of the metal of which said container is composed and below the boiling point of said additive metal.
SAM TOUR.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATEFT'I'S Number Name Date 1,275,449 Lemon Aug. 13, 1918. 2,550,735 Tour May 1, 1951 FOREIGN PATENTS Number Country Date 317,493 Great Britain Dec. 1'7, 1930 OTHER REFERENCES Handbook of Chemistry and Physics, 28th Eddition, 1944, by Hodgman, published by Rubber Publishing Co., Cleveland, Ohio, pp. 358, 359. 402, 403.

Claims (1)

1. A CARTRIDGE FOR THE TREATMENT OF A MOLTEN METAL WITH A RELATIVELY SMALL AMOUNT OF AN ADDITIVE METAL SELECTED FROM THE GROUP CONSISTING OF THE ALKALI AND ALKALINE EARTH METALS, CONSISTING OF A METAL CONTAINER DEFINING AND COMPLETELY ENVELOPING A CAVITY, A CHARGE OF SAID ADDITIVE METAL WITHIN SAID CAVITY, THE WEIGHT OF THE CONTAINER AND CHARGE EXCEEDING THE WEIGHT OF A CORRESPONDING VOLUME IN LIQUID STATE OF THE METAL OF WHICH THE CONTAINER IS COMPOSED, THE WALL OF SAID CONTAINER DEFINING AN APERTURE EXTENDING BETWEEN SAID CAVITY AND THE OUTSIDE OF SAID CONTAINER, AND AT LEAST ONE PLUG OF FUSIBLE MATERIAL OF RELATIVELY SMALL SIZE IN COMPARISON WITH THE SIZE OF SAID METAL CONTAINER BLOCKING SAID APERTURE, THE SIZE OF SAID PLUG BEING SO LIMITED THAT ITS FUSION AND REMOVAL WILL NOT REDUCE THE WEIGHT OF THE CARTRIDGE BELOW THE WEIGHT OF A CORRESPONDING VOLUME IN LIQUID STATE OF THE METAL OF WHICH THE CONTAINER IS COMPOSED SAID PLUG HAVING A MELTING POINT ABOVE THAT OF SAID ADDITIVE METAL AND
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2995439A (en) * 1959-02-02 1961-08-08 Union Carbide Corp Preparation of high purity chromium and other metals

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1275449A (en) * 1918-02-01 1918-08-13 Herbert L Lemon Metal package.
GB317493A (en) * 1928-08-18 1930-12-17 Alexandr Glazunov A process of removing the last traces of oxygen from iron alloys
US2550735A (en) * 1947-08-02 1951-05-01 Julius S W Bates Cartridge for below-surface treatment of molten metals

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1275449A (en) * 1918-02-01 1918-08-13 Herbert L Lemon Metal package.
GB317493A (en) * 1928-08-18 1930-12-17 Alexandr Glazunov A process of removing the last traces of oxygen from iron alloys
US2550735A (en) * 1947-08-02 1951-05-01 Julius S W Bates Cartridge for below-surface treatment of molten metals

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2995439A (en) * 1959-02-02 1961-08-08 Union Carbide Corp Preparation of high purity chromium and other metals

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