US2572217A - Manufacture of viscose rayon - Google Patents
Manufacture of viscose rayon Download PDFInfo
- Publication number
- US2572217A US2572217A US140149A US14014950A US2572217A US 2572217 A US2572217 A US 2572217A US 140149 A US140149 A US 140149A US 14014950 A US14014950 A US 14014950A US 2572217 A US2572217 A US 2572217A
- Authority
- US
- United States
- Prior art keywords
- viscose
- filaments
- orifices
- spinbath
- manufacture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H35/00—Switches operated by change of a physical condition
- H01H35/24—Switches operated by change of fluid pressure, by fluid pressure waves, or by change of fluid flow
- H01H35/38—Switches operated by change of fluid pressure, by fluid pressure waves, or by change of fluid flow actuated by piston and cylinder
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
- D01F2/10—Addition to the spinning solution or spinning bath of substances which exert their effect equally well in either
Definitions
- anion active compounds such as highly sulphonated non-mineral oils of the type sold under the trade-name Prestabit Oil to viscose solutions in order to inhibit turbidity or milkiness in the rayon.
- Prestabit Oil a compound of the type sold under the trade-name
- the anion active compound in the viscose may -counteract or retard the effectiveness of the cation active compound in the spinbath with respect to spinneret incrustation.
- Another object of this invention is to use small amounts of a cation active compound either in the viscose solution whereby it will get into the spinbath'during the spinning operation, or add it directly to the spinbath in addition to adding it to the viscose.
- a further object of the invention is to utilize a particular class of cation active compounds that k are good dispersants and are sufiiciently soluble and stable in both alkali and viscose to prevent 'milkiness in the yarn while at the same time are sufficiently soluble and stable in the acid spinbath to prevent spinneret incrustation.
- R represents an aliphatic chain having from 8 to 24 carbon atoms therein and preferably from 12 to 14 carbon atoms.
- a; or y is at least one, and r-l-y is the total number of alkylene oxide chains which may be as low as 5 without any definite restriction on the upper limit although 12 to 18 or about 15 have been found .to be quite effective, and n is a small whole number from 2 to 4, both inclusive.
- Ethomeen 0/25 and Ethomeen 8/25 Specific Ethomeens which have proved very effective in preventing milkiness and spinneret incrustation are known as Ethomeen 0/25 and Ethomeen 8/25. Resolving these into their structural formulate the extent possible they are:
- the length of the aliphatic chain R depends on the oil from which the parent amine is prepared,
- the long chain aliphatic tertiary amine-alkylene oxide condensate is added in small quantities, e. g., 0.12% to 0.24% based on the weight of cellulose to the viscose and, if required, lesser amounts to the acid spinbath based on the weight of the spinbath,
- the viscose' is otherwise prepared in the normal manner and thereafter extruded through minute spinneret orifices into an acid spinbath to form filaments and the like therefrom. It was determined on examination of the finished rayon that it was 1- more 'efiective than Prestabit Oil in preventing inilkiness, even when five times as much Prestibit Oil was used. Furthermore, it was quite efiective in inhibiting spinneret incrustation.
- Ethomeen C/ and S/25 were added to the viscose in 0.12% and 0.24% quantities based on the weight of cellulose. These viscoses were spun in the normal manner at the normal maturity of 9.8 and at a higher maturity of 11 to 11.5. On examination of the finished rayon it compared favorably with, or was even superior in appearance to, rayon containing Prestabit Oil. 3 I g When the Ethomeens were added to the viscose in the above mentioned quantities and the viscose was spun in an acid spinbath containing cation active. material, it was determined that the pressure build-up behind the spinnerets was reduced markedly, indicating excellent inhibition of spinneret incrustation. This was confirmed by subsequent microscopic examination of the spinnerets.
- the step which comprises spinning the viscose filaments in the presence of a long chain aliphatic tertiary aminealkylene oxide condensate formed from the reaction of a lon chain aliphatic primary amine with an alkylene oxide whereby milkiness in the filaments and incrustation. of the orifices are inhibited.
- the step which comprises spinning the viscose filaments in the presence of a small amount of a long chain aliphatic tertiary amine-alkylene oxide condensate formed from the reaction of a long chain aliphatic primary amine with an alkylene oxide whereby milkiness in the filaments and incrustation of the orifices are inhibited.
- the step which comprises spinning the viscose filaments in the presence of 0.12% to 0.24% based on the weight of the cellulose of a lon chain aliphatic tertiary aminealkylene oxide condensate formed from the reactionof a long chain aliphatic primary amine with an alkylene oxide whereby milkiness in the fila- -ments and incrustation of the orifices are inhibited.
- the step which comprises spinning the viscose filaments in the presence of along chain aliphatic tertiary amine-ethylene oxide condensate formed from the reaction of a long chain aliphatic primary amine with ethylene oxide whereby milkiness in the filaments and incrustation of the orifices are inhibited.
- the step which comprises spinning the viscose filaments in the presence of a small amount of a long chain aliphatic tertiary amine-ethylene oxide condensate formed from the reaction of a long chain aliphatic primary amine with ethylene oxide whereby milkiness in the filaments and incrustation of the orifices are inhibited.
- the step which comprises spinning the viscose filaments in the presence of 0.12% to 0.24% based on the weight of the cellulose of a long chain aliphatic tertiary amineethylene oxide condensate formed from the reaction of a long chain aliphatic primary amine with ethylene oxide whereby milkiness in the filaments and incrustation of the orifices are inhibited.
- the step which comprises adding a small amount of a long chain aliphatic tertiary amine-ethylene oxide condensate to the viscose solution and spinning the same into filaments whereby milkiness in the filaaments and incrustation of the orifices are inhibited 8.
- the step which comprises adding 0.12% to 0.24% based on the weight of the cellulose of a long chain aliphatic tertiary amine-ethylene oxide condensate to the viscose solution and spinning the same into filaments whereby milkiness in the filaments and incrustation of the orifices are inhibited.
- the step which comprises spinning the viscose filaments in the presence of a long chain aliphatic tertiary amine-ethylene oxide condensate formed from the reaction of a long chain aliphatic primary amine with about 15 moles of ethylene oxide whereby milkiness in the filaments and incrustation of the orifices are inhibited.
- R represents an aliphatic chain having at least 8 carbon atoms therein and :c-l-y equals the total number of moles of ethylene oxide at least 5, fortuitously separated into two chains to form the tertiary amine whereby milkiness in the filaments and incrustation of the orifices are inhibited.
- R represents an aliphatic chain having at least 8 carbon atoms therein and x+y equals about 15 moles of ethylene oxide, fortuitously separated into two chains to form the tertiary amine whereby milkiness in the filaments and incrustation of the orifices are inhibited.
Description
Patented Oct. 23, 1951 MANUFACTURE OF VISCOSE RAYON Gilbert I. Thurmond, Asheville, N. 0., assignor to American Enka Corporation, Enka, N. 0., a
corporation of Delaware- No Drawing. Application January 23, 1950. Serial No. 140,149
11 Claims.
a process involving the addition of surface active agents to the viscose solution and to the acid coagulating bath in order to improve the char-- acteristics of the finished product and to improve the spinning conditions generally.
It is known to add anion active compounds such as highly sulphonated non-mineral oils of the type sold under the trade-name Prestabit Oil to viscose solutions in order to inhibit turbidity or milkiness in the rayon. (See U. S. Patents Nos. 1,925,192 and 1,936,479.) While these compounds are effective in this respect; they, as well as all anion active materials have a tendency to promote clogging of spinneret orifices. .It was not until the use of cation active compounds (see U. S. Patent No. 2,125,031) was commenced that spinneret clogging was substantially prevented.
Thus, in order to improve both the yarn and the spinning conditions it has been necessary to add an anion active compound to the viscose solution and a cation active compound to the acid spinbath. This is obviously objectionable because the two classes of materials come in con-v tact with one another during the spinning operation and have a tendency toward compound formation and mutual precipitation. In addition,
the anion active compound in the viscose may -counteract or retard the effectiveness of the cation active compound in the spinbath with respect to spinneret incrustation.
Accordingly, on a theoretical basis it would be more feasible to use either one or more anion active compounds or One or more cation active; compounds in both the viscose solution and spinbath. However, since it is known that anion active materials cannot be used in the spinbath for practical reasons, it is necessary that the material common to both the viscose solution and the spinbath be cationic in character.
It is therefore the object of the present invention to provide a cation active compound that serves both the purpose of inhibiting milkiness in the viscose yarn and reducing spinneret incrustation in the spinbath.
Another object of this invention is to use small amounts of a cation active compound either in the viscose solution whereby it will get into the spinbath'during the spinning operation, or add it directly to the spinbath in addition to adding it to the viscose.
A further object of the invention is to utilize a particular class of cation active compounds that k are good dispersants and are sufiiciently soluble and stable in both alkali and viscose to prevent 'milkiness in the yarn while at the same time are sufficiently soluble and stable in the acid spinbath to prevent spinneret incrustation.
It has now been determined that if a long chain aliphatic primary amine is caused to react with an alkylene oxide such as ethylene oxide to form a tertiary amine, its properties can be modified to the extent of rendering it suitable for preventing or inhibitingmilkiness in the yarn while at the same time reducing spinneret incrustation. By controlling the length of the alkylene oxide chains, derivatives can be prepared that are soluble and stable in both the alkaline viscose solution and the acid spinbath. The necessary length of the alkylene oxide chains is dependent on the length of the alkyl group in the amine because the hydrocarbon group becomes more hydrophobic as the chain length increases whereas the alkylene oxide chain becomes more hydrophilic as the chain length increases. Therefore, it is only necessary to control the length of the alkylene oxide chain so that it predominates over the alkyl group in the amine whereby the condensate is rendered sufficiently soluble in an aqueous solution to be effective for the purposes here involved.
Compounds of this type are known in the trade as Ethomeens and reaction products of long chain aliphatic primary amines with ethylene oxide, the reaction being represented generally as follows:
}OY.H2HO)=H RNHQ (z monaho RN (CflHnOMH In the above formula, R represents an aliphatic chain having from 8 to 24 carbon atoms therein and preferably from 12 to 14 carbon atoms. a; or y is at least one, and r-l-y is the total number of alkylene oxide chains which may be as low as 5 without any definite restriction on the upper limit although 12 to 18 or about 15 have been found .to be quite effective, and n is a small whole number from 2 to 4, both inclusive.
Specific Ethomeens which have proved very effective in preventing milkiness and spinneret incrustation are known as Ethomeen 0/25 and Ethomeen 8/25. Resolving these into their structural formulate the extent possible they are:
The length of the aliphatic chain R depends on the oil from which the parent amine is prepared,
fwith.
which in the case of C/25 is coco and 5/25 is soya. In both cases moles of ethylene oxide are added to the amine. The ethylene oxide apparently separates fortuitously into two chains designated as a: and y to form the tertiary amine. It has been demonstrated that the second mole of ethylene oxide is more strongly attracted to the amino nitrogen than it is to the hydroxyl group so that a bishydroxy ethyl alkyl amine is formed. After a total of 5 moles of ethylene oxide had been added to the primary amine it was determined that it had been over 99% converted into a tertiary amine. Therefore, theoretically, the reaction product may contain as low as 5 moles of ethylene oxide provided the solubility is sufficient in alkali and acid although thus far it has been determined for optimum results, about 15 moles of ethylene oxide are required for the reaction.
In accordance with the invention the long chain aliphatic tertiary amine-alkylene oxide condensate is added in small quantities, e. g., 0.12% to 0.24% based on the weight of cellulose to the viscose and, if required, lesser amounts to the acid spinbath based on the weight of the spinbath,
of course taking the necessary precautions to insure an .even and uniform admixture there- In practice, it has been determined that certain advantages are realized if the condensate is added in the premanufacturing stages, e. g., during the shredding operation whereby the alkali cellulose-appears to become more flufiy which enhances subsequent treating operations.
After the addition of the condensate the viscose' is otherwise prepared in the normal manner and thereafter extruded through minute spinneret orifices into an acid spinbath to form filaments and the like therefrom. It was determined on examination of the finished rayon that it was 1- more 'efiective than Prestabit Oil in preventing inilkiness, even when five times as much Prestibit Oil was used. Furthermore, it was quite efiective in inhibiting spinneret incrustation.
Experiments were conducted with respect to solubility and stability of Ethomeen (3/25 and 58/25 in acid and alkali using 2.0% solutions. .The results are tabulated as follows:
From the above it can be concluded that the compounds in question are adequately soluble and stable in both media.
In conducting several comparative tests for milkiness reduction, Ethomeen C/ and S/25 were added to the viscose in 0.12% and 0.24% quantities based on the weight of cellulose. These viscoses were spun in the normal manner at the normal maturity of 9.8 and at a higher maturity of 11 to 11.5. On examination of the finished rayon it compared favorably with, or was even superior in appearance to, rayon containing Prestabit Oil. 3 I g When the Ethomeens were added to the viscose in the above mentioned quantities and the viscose was spun in an acid spinbath containing cation active. material, it was determined that the pressure build-up behind the spinnerets was reduced markedly, indicating excellent inhibition of spinneret incrustation. This was confirmed by subsequent microscopic examination of the spinnerets.
It can be seen that the use of small amounts of long chain aliphatic tertiary amine-ethylene oxide condensates in accordance. with this invention produces several important advantages in the manufacture of viscose rayon. The invention is therefore not to be limited in an manner other than by the scope defined in the appended claims.
What is claimed is:
1. In the manufacture of viscose yarn wherein a viscose solution is extruded through minute orifices into an acid spinbath to form filaments and the like therefrom, the step which comprises spinning the viscose filaments in the presence of a long chain aliphatic tertiary aminealkylene oxide condensate formed from the reaction of a lon chain aliphatic primary amine with an alkylene oxide whereby milkiness in the filaments and incrustation. of the orifices are inhibited.
2. In the manufacture of viscose yarn wherein a viscose solution is extruded through minute orifices into an acid spinbath to form filaments and the like therefrom, the step which comprises spinning the viscose filaments in the presence of a small amount of a long chain aliphatic tertiary amine-alkylene oxide condensate formed from the reaction of a long chain aliphatic primary amine with an alkylene oxide whereby milkiness in the filaments and incrustation of the orifices are inhibited.
3. In the manufacture of viscose yarn wherein a viscose solution is extruded through minute orifices into anacid spinbath to form filaments and the like therefrom, the step which comprises spinning the viscose filaments in the presence of 0.12% to 0.24% based on the weight of the cellulose of a lon chain aliphatic tertiary aminealkylene oxide condensate formed from the reactionof a long chain aliphatic primary amine with an alkylene oxide whereby milkiness in the fila- -ments and incrustation of the orifices are inhibited.
4. In the manufacture of viscose yarn wherein a viscose solution is extruded through minute orifices into an acid spinbath to form filaments and the like therefrom, the step which comprises spinning the viscose filaments in the presence of along chain aliphatic tertiary amine-ethylene oxide condensate formed from the reaction of a long chain aliphatic primary amine with ethylene oxide whereby milkiness in the filaments and incrustation of the orifices are inhibited.
5. In the manufacture of viscose yarn wherein a viscose solution is extruded through minute orifices into an acid spinbath to form filaments and the like therefrom, the step which comprises spinning the viscose filaments in the presence of a small amount of a long chain aliphatic tertiary amine-ethylene oxide condensate formed from the reaction of a long chain aliphatic primary amine with ethylene oxide whereby milkiness in the filaments and incrustation of the orifices are inhibited.
6. In the manufacture of viscose yarnwherein a viscose solution is extruded through minute orifices into an acid spinbath to form filaments and. the like therefrom, the step which comprises spinning the viscose filaments in the presence of 0.12% to 0.24% based on the weight of the cellulose of a long chain aliphatic tertiary amineethylene oxide condensate formed from the reaction of a long chain aliphatic primary amine with ethylene oxide whereby milkiness in the filaments and incrustation of the orifices are inhibited.
7. In the manufacture of viscose yarn wherein a viscose solution is extruded through minute orifices into an acid spinbath to form filaments and the like therefrom, the step which comprises adding a small amount of a long chain aliphatic tertiary amine-ethylene oxide condensate to the viscose solution and spinning the same into filaments whereby milkiness in the filaaments and incrustation of the orifices are inhibited 8. In the manufacture of viscose yarn wherein a viscose solution is extruded through minute orifices into an acid spinbath to form filaments and the like therefrom, the step which comprises adding 0.12% to 0.24% based on the weight of the cellulose of a long chain aliphatic tertiary amine-ethylene oxide condensate to the viscose solution and spinning the same into filaments whereby milkiness in the filaments and incrustation of the orifices are inhibited.
9. In the manufacture of viscose yarn wherein a viscose solution is extruded through minute orifices into an acid spinbath to form filaments and the like therefrom, the step which comprises spinning the viscose filaments in the presence of a long chain aliphatic tertiary amine-ethylene oxide condensate formed from the reaction of a long chain aliphatic primary amine with about 15 moles of ethylene oxide whereby milkiness in the filaments and incrustation of the orifices are inhibited.
10. In the manufacture of viscose yarn wherein a viscose solution is extruded through minute orifices into an acid spinbath to form filaments and the like therefrom, the step which comprises spinning the viscose filaments in the presence of a soluble, stable cation active compound having the following formula:
in which R represents an aliphatic chain having at least 8 carbon atoms therein and :c-l-y equals the total number of moles of ethylene oxide at least 5, fortuitously separated into two chains to form the tertiary amine whereby milkiness in the filaments and incrustation of the orifices are inhibited.
11. In the manufacture of viscose yarn wherein a viscose solution is extruded through minute orifices into an acid spinbath to form filament and the like therefrom, the step which comprises spinning the viscose filaments in the presence of a soluble, stable cation active compound having the following formula:
in which R represents an aliphatic chain having at least 8 carbon atoms therein and x+y equals about 15 moles of ethylene oxide, fortuitously separated into two chains to form the tertiary amine whereby milkiness in the filaments and incrustation of the orifices are inhibited.
GILBERT I. THURMOND.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 2,174,762 Schuette et a1. Oct. 3, 1939 2,214,352 Schoeller et al. Sept. 10, 1940
Claims (1)
1. IN THE MANUFACTURE OF VISCOSE YARN WHEREIN A VISCOSE SOLUTION IS EXTRUDED THROUGH MINUTE ORIFICES INTO AN ACID SPINBATH TO FORM FILAMENTS AND THE LIKE THEREFROM, THE STEP WHICH COMPRISES SPINNING THE VISCOSE FILAMENTS IN THE PRESENCE OF A LONG CHAIN ALIPHATIC TERTIARY AMINEALKYLENE OXIDE CONDENSATE FORMED FROM THE REACTION OF A LONG CHAIN ALIPHATIC PRIMARY AMINE WITH AN ALKYLENE OXIDE WHEREBY MILKINESS IN THE FILAMENTS AND INCRUSTATION OF THE ORIFICES ARE INHIBITED.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL69004D NL69004C (en) | 1950-01-23 | ||
BE499517D BE499517A (en) | 1950-01-23 | ||
GB25162/37A GB499517A (en) | 1950-01-23 | 1937-09-16 | Improvements relating to fluid pressure operated electric relays |
US140149A US2572217A (en) | 1950-01-23 | 1950-01-23 | Manufacture of viscose rayon |
GB28831/50A GB709986A (en) | 1950-01-23 | 1950-11-24 | Improved process for the manufacture of viscose rayon |
DEA11039A DE954547C (en) | 1950-01-23 | 1950-12-05 | Process for the production of artificial structures, such as threads or films, from viscose |
ES0195760A ES195760A1 (en) | 1950-01-23 | 1950-12-12 | A PROCEDURE FOR THE MANUFACTURE OF VISCOSE RAY |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US140149A US2572217A (en) | 1950-01-23 | 1950-01-23 | Manufacture of viscose rayon |
Publications (1)
Publication Number | Publication Date |
---|---|
US2572217A true US2572217A (en) | 1951-10-23 |
Family
ID=22489963
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US140149A Expired - Lifetime US2572217A (en) | 1950-01-23 | 1950-01-23 | Manufacture of viscose rayon |
Country Status (6)
Country | Link |
---|---|
US (1) | US2572217A (en) |
BE (1) | BE499517A (en) |
DE (1) | DE954547C (en) |
ES (1) | ES195760A1 (en) |
GB (2) | GB499517A (en) |
NL (1) | NL69004C (en) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1033371B (en) * | 1955-08-18 | 1958-07-03 | Courtaulds Inc | Process for the production of hydrate cellulose threads or fibers |
US2852334A (en) * | 1954-11-03 | 1958-09-16 | American Viscose Corp | Method of producing viscose rayon |
US2916391A (en) * | 1954-11-03 | 1959-12-08 | American Viscose Corp | Process of producing viscose rayon |
US2971817A (en) * | 1955-06-29 | 1961-02-14 | American Viscose Corp | Producing all skin rayon |
US2978292A (en) * | 1955-03-18 | 1961-04-04 | American Enka Corp | Manufacture of rayon |
US2993798A (en) * | 1955-09-13 | 1961-07-25 | Spinnfaser Ag | Viscose spinning solution containing xanthated lower alcohol |
US3007766A (en) * | 1958-01-04 | 1961-11-07 | American Enka Corp | Production of viscose rayon |
US3014810A (en) * | 1958-09-08 | 1961-12-26 | Armour & Company Of Delaware | Pigment composition and method of manufacture |
US3016305A (en) * | 1956-05-10 | 1962-01-09 | Kunstzijdespinnerij Nyma Nv | Manufacture of thick-skinned or allskin shaped articles from viscose |
US3026170A (en) * | 1957-11-29 | 1962-03-20 | American Enka Corp | Manufacture of viscose rayon |
US3097414A (en) * | 1958-10-30 | 1963-07-16 | Woodell | |
US3418405A (en) * | 1962-09-10 | 1968-12-24 | Kurashiki Rayon Co | Method of manufacturing flat viscose fibers |
US5719118A (en) * | 1995-10-30 | 1998-02-17 | Tomah Products, Inc. | Detergent compositions having polyalkoxylated amine foam stabilizers and method for cleaning including stabilized detergent foam |
US6221822B1 (en) | 1995-10-30 | 2001-04-24 | Tomah Products, Inc. | Detergent compositions having polyalkoxylated amine foam stabilizers |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1041639B (en) * | 1957-07-16 | 1958-10-23 | Glanzstoff Ag | Process for the production of threads or fibers from regenerated cellulose by spinning viscose |
IT8223293V0 (en) * | 1982-10-27 | 1982-10-27 | Ima Spa | HELIOGRAPHIC PAPER, PROVIDED, IN CORRESPONDENCE WITH THE NONSENSITIZED SIDE, OF A THERMO-ADHESIVE SUBSTANCE, OPPORTUNITY DISTRIBUTED. |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2174762A (en) * | 1935-04-13 | 1939-10-03 | Ig Farbenindustrie Ag | Condensation products derived from amines and method of producing them |
US2214352A (en) * | 1935-06-22 | 1940-09-10 | Gen Aniline & Film Corp | Process for the production of condensation products containing onium groups |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE667744C (en) * | 1930-11-30 | 1938-11-19 | I G Farbenindustrie Akt Ges | Process for the preparation of condensation products which are soluble or easily dispersible in water |
DE696780C (en) * | 1935-06-23 | 1940-09-28 | I G Farbenindustrie Akt Ges | Process for the production of technically valuable condensation products |
-
0
- NL NL69004D patent/NL69004C/xx active
- BE BE499517D patent/BE499517A/xx unknown
-
1937
- 1937-09-16 GB GB25162/37A patent/GB499517A/en not_active Expired
-
1950
- 1950-01-23 US US140149A patent/US2572217A/en not_active Expired - Lifetime
- 1950-11-24 GB GB28831/50A patent/GB709986A/en not_active Expired
- 1950-12-05 DE DEA11039A patent/DE954547C/en not_active Expired
- 1950-12-12 ES ES0195760A patent/ES195760A1/en not_active Expired
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2174762A (en) * | 1935-04-13 | 1939-10-03 | Ig Farbenindustrie Ag | Condensation products derived from amines and method of producing them |
US2214352A (en) * | 1935-06-22 | 1940-09-10 | Gen Aniline & Film Corp | Process for the production of condensation products containing onium groups |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2852334A (en) * | 1954-11-03 | 1958-09-16 | American Viscose Corp | Method of producing viscose rayon |
US2916391A (en) * | 1954-11-03 | 1959-12-08 | American Viscose Corp | Process of producing viscose rayon |
US2978292A (en) * | 1955-03-18 | 1961-04-04 | American Enka Corp | Manufacture of rayon |
US2971817A (en) * | 1955-06-29 | 1961-02-14 | American Viscose Corp | Producing all skin rayon |
DE1033371B (en) * | 1955-08-18 | 1958-07-03 | Courtaulds Inc | Process for the production of hydrate cellulose threads or fibers |
US2993798A (en) * | 1955-09-13 | 1961-07-25 | Spinnfaser Ag | Viscose spinning solution containing xanthated lower alcohol |
US3016305A (en) * | 1956-05-10 | 1962-01-09 | Kunstzijdespinnerij Nyma Nv | Manufacture of thick-skinned or allskin shaped articles from viscose |
US3026170A (en) * | 1957-11-29 | 1962-03-20 | American Enka Corp | Manufacture of viscose rayon |
US3007766A (en) * | 1958-01-04 | 1961-11-07 | American Enka Corp | Production of viscose rayon |
US3014810A (en) * | 1958-09-08 | 1961-12-26 | Armour & Company Of Delaware | Pigment composition and method of manufacture |
US3097414A (en) * | 1958-10-30 | 1963-07-16 | Woodell | |
US3418405A (en) * | 1962-09-10 | 1968-12-24 | Kurashiki Rayon Co | Method of manufacturing flat viscose fibers |
US5719118A (en) * | 1995-10-30 | 1998-02-17 | Tomah Products, Inc. | Detergent compositions having polyalkoxylated amine foam stabilizers and method for cleaning including stabilized detergent foam |
US6221822B1 (en) | 1995-10-30 | 2001-04-24 | Tomah Products, Inc. | Detergent compositions having polyalkoxylated amine foam stabilizers |
Also Published As
Publication number | Publication date |
---|---|
ES195760A1 (en) | 1952-05-16 |
NL69004C (en) | |
GB709986A (en) | 1954-06-02 |
GB499517A (en) | 1939-01-25 |
DE954547C (en) | 1956-12-20 |
BE499517A (en) |
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