US2566138A - Anticorrosion tank - Google Patents

Anticorrosion tank Download PDF

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Publication number
US2566138A
US2566138A US564350A US56435044A US2566138A US 2566138 A US2566138 A US 2566138A US 564350 A US564350 A US 564350A US 56435044 A US56435044 A US 56435044A US 2566138 A US2566138 A US 2566138A
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Prior art keywords
coating
zinc
tank
iron
paint
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US564350A
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Clark M Osterheld
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McGraw Electric Co
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McGraw Electric Co
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/70Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for
    • B65D85/84Containers, packaging elements or packages, specially adapted for particular articles or materials for materials not otherwise provided for for corrosive chemicals
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S220/00Receptacles
    • Y10S220/917Corrosion resistant container
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/923Physical dimension
    • Y10S428/924Composite
    • Y10S428/926Thickness of individual layer specified
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12729Group IIA metal-base component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12736Al-base component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12785Group IIB metal-base component
    • Y10T428/12792Zn-base component
    • Y10T428/12799Next to Fe-base component [e.g., galvanized]

Definitions

  • One object of my invention is to provide relatively simple, buteffective, means for preventing corrosion of an iron hotwater tank adapted to contain potable water. H Other objects of my invention will either be evident from a description of one form of tank embodying my invention, or will be pointed out in the course of such description and set forth in the appended claims.
  • Figure 1 is a vertical, sectional view through an ordinary domestic hot water tank, and,
  • Fig. 2 is a fragmentary view of an enlarged scale, showing a plurality of coats of paint applied to the inside surface of the tank.
  • an ordinary domestic hot water tank installed in homes is provided with a coating of galvanized zinc applied to the inner surface, as well as to the outer surface, by the so-called hot dip method. It is very diiiicult, if not impossible, to provide an imperforate zinc coating on the inner surface of a tank for the reason that the molten zinc contains other ingredients in the form of impurities, and further that a flux is provided to cover the surface of the molten zinc in the tank, and the result is that the zinc coating is perforate.
  • the water, while potable may be acidic, or alkaline, or saline; and the degree of acidity, or alkalinity, or salinity, while variable, is still small enough to make the water potable. If new the tank is filled with any one or a combination of the three different kinds of water, a galvanic action will occur between the zinc at the edge of the zinc coating surrounding a perforation where the iron is not covered by the zinc. This will cause dissociation of the zinc, which will continue with an attendant increase in the size of the opening Where the water contacts directly the iron surface of the tank.
  • the zinc coating is in direct contact with the inner surface of the iron tank, there is little, if any, resistance to the flow of current from the zinc through the water, and into and then through the tank at any or all perforations in the zinc coating.
  • the flow of current from the zinc is through only a relatively very short distance from the edge of the zinc coating to the iron, whereby the flow of protective ions from the zinc to the iron will not occur except at the edge of the zinc, so that a flow of iron ions into the liquid will take place.
  • FIG. 1 of the drawings I have there shown an ordinary hot water tank I I, made of iron, have a closure member l3 secured to the upper end thereof, with an opening ll centrally therein for a hot water outlet pipe. I provide further a lower. closure member l5, having a central opening I9 therein to receive a cold water inlet pipe, all in the usual manner.
  • Fig. 2 of the drawings I have there shown a small part of thewall of tank I i, and I have further shown the innerilayer of hot-dipped galvanized zinc 2 I, It is obvious that zinc is anodic to the iron of tankll, so that the hereinbefore described effects would take place in case only a single coating of a metal anodic to iron were provided.
  • Coatings 23 (of aluminum) and 25 (of magnesium) are of a metallic paint and may either be sprayed on, or may be applied in substantially the following manner: the tank H is positioned wtih its longitudinal axis in substantially horizontal position on means permitting of rotation of the tank; a certain amount of metallic paint, comprising first aluminum, is placed within the tank II, which is then rotated for a certain length of time.
  • the excess is permitted to run out through either opening 19 or ll, after which the paint is permitted to dry and is then baked on at a temperature on the order of 300 F. for a length of time on the order of 30 to 45 minutes.
  • a second coating of magnesium paint may be applied in substantially the same manner and is then baked on in substantially the same manner as was hereinbefore described for coating 23.
  • any one coating of paint may be on the order of several thousandths of an inch, and I may use several layers of coatings in succession, drying and baking them on one after the other. I may also use a plurality of layers of aluminum paint, applied as described above, instead of a plurality of layers of different kinds of metallic paint.
  • zinc is anodic to iron, and so also is aluminum, which is also anodic to zinc.
  • Magnesium is anodic not only to iron, but also to zinc, as well as to aluminum. The requisition being that the successive layers of metallic paint are anodic to the coating to which they are applied.
  • aluminum is self-protecting when subjected to potable acidic 3 water; that is, it will have provided thereon a layer of aluminum oxide, which is in itself a protection against dissociation. This, of course, will occur in case of a perforation or perforations in the outermost magnesium layer, and particularly in the presence of potable, acidic water.
  • An iron hot water tank having in direct contact with the interior iron surface thereof a protective lining for preventing corrosion of the interior by alkaline and acidic potable waters under varying temperature conditions, said lining consisting of ametal coating of zinc on the tank interior iron surface, an intermediate coating of aluminum paint on said zinc coating and an outer coating of magnesium paint on said aluminum coating.
  • An iron hot water tank having in direct contact with the interior iron surface thereof a CLARK M. OSTERHELD.

Description

Aug. 28, 1 951 C. M. OSTERHELD ANTICORROSION TANK Filed Nov. 20, 1944 INVENTOR c M OSTE'RHELD ATT') i atentec l Aug. 28, 1951 Clark Ost'i'helistoughton, Wis., assignor to :McGraw Electric Company, E lgin, 111., a corporation of Delaware Application meats 20, 1944, Serial No. 564,350 2 Claims. (Cl. f11'7'-'-'-71) My invention relates to iron-hot water tanks and particularly to means for rendering the same resistant to corrosion. V r
One object of my invention is to provide relatively simple, buteffective, means for preventing corrosion of an iron hotwater tank adapted to contain potable water. H Other objects of my invention will either be evident from a description of one form of tank embodying my invention, or will be pointed out in the course of such description and set forth in the appended claims.
In the drawings, H i
Figure 1 is a vertical, sectional view through an ordinary domestic hot water tank, and,
Fig. 2 is a fragmentary view of an enlarged scale, showing a plurality of coats of paint applied to the inside surface of the tank.
At the present tim an ordinary domestic hot water tank installed in homes is provided with a coating of galvanized zinc applied to the inner surface, as well as to the outer surface, by the so-called hot dip method. It is very diiiicult, if not impossible, to provide an imperforate zinc coating on the inner surface of a tank for the reason that the molten zinc contains other ingredients in the form of impurities, and further that a flux is provided to cover the surface of the molten zinc in the tank, and the result is that the zinc coating is perforate.
The water, while potable, may be acidic, or alkaline, or saline; and the degree of acidity, or alkalinity, or salinity, while variable, is still small enough to make the water potable. If new the tank is filled with any one or a combination of the three different kinds of water, a galvanic action will occur between the zinc at the edge of the zinc coating surrounding a perforation where the iron is not covered by the zinc. This will cause dissociation of the zinc, which will continue with an attendant increase in the size of the opening Where the water contacts directly the iron surface of the tank. Since the zinc coating is in direct contact with the inner surface of the iron tank, there is little, if any, resistance to the flow of current from the zinc through the water, and into and then through the tank at any or all perforations in the zinc coating. As the zinc is dissociated, with a consequent increase in the size of the perforations in the zinc, the flow of current from the zinc is through only a relatively very short distance from the edge of the zinc coating to the iron, whereby the flow of protective ions from the zinc to the iron will not occur except at the edge of the zinc, so that a flow of iron ions into the liquid will take place.
, Referring now to Fig. 1 of the drawings, I have there shown an ordinary hot water tank I I, made of iron, have a closure member l3 secured to the upper end thereof, with an opening ll centrally therein for a hot water outlet pipe. I provide further a lower. closure member l5, having a central opening I9 therein to receive a cold water inlet pipe, all in the usual manner.
Referring now to Fig. 2 of the drawings, I have there shown a small part of thewall of tank I i, and I have further shown the innerilayer of hot-dipped galvanized zinc 2 I, It is obvious that zinc is anodic to the iron of tankll, so that the hereinbefore described effects would take place in case only a single coating of a metal anodic to iron were provided.
I provide a second coating 23 made of an aluminum paint; and I then provide thereover a third coating 25 of a magnesium paint. Coatings 23 (of aluminum) and 25 (of magnesium) are of a metallic paint and may either be sprayed on, or may be applied in substantially the following manner: the tank H is positioned wtih its longitudinal axis in substantially horizontal position on means permitting of rotation of the tank; a certain amount of metallic paint, comprising first aluminum, is placed within the tank II, which is then rotated for a certain length of time.
After the application of the first layer '23 of aluminum paint, the excess is permitted to run out through either opening 19 or ll, after which the paint is permitted to dry and is then baked on at a temperature on the order of 300 F. for a length of time on the order of 30 to 45 minutes.
After this, a second coating of magnesium paint may be applied in substantially the same manner and is then baked on in substantially the same manner as was hereinbefore described for coating 23.
The thickness of any one coating of paint may be on the order of several thousandths of an inch, and I may use several layers of coatings in succession, drying and baking them on one after the other. I may also use a plurality of layers of aluminum paint, applied as described above, instead of a plurality of layers of different kinds of metallic paint.
As has been hereinbefore stated, zinc is anodic to iron, and so also is aluminum, which is also anodic to zinc. Magnesium is anodic not only to iron, but also to zinc, as well as to aluminum. The requisition being that the successive layers of metallic paint are anodic to the coating to which they are applied.
It may be here pointed out that aluminum is self-protecting when subjected to potable acidic 3 water; that is, it will have provided thereon a layer of aluminum oxide, which is in itself a protection against dissociation. This, of course, will occur in case of a perforation or perforations in the outermost magnesium layer, and particularly in the presence of potable, acidic water.
Various modifications may be made in the device embodying my invention without departing from the spirit and scope thereof, and all such modifications coming clearly within the scope of the appended claims shall be considered as part of my invention I claim as my invention:
1. An iron hot water tank having in direct contact with the interior iron surface thereof a protective lining for preventing corrosion of the interior by alkaline and acidic potable waters under varying temperature conditions, said lining consisting of ametal coating of zinc on the tank interior iron surface, an intermediate coating of aluminum paint on said zinc coating and an outer coating of magnesium paint on said aluminum coating.
2. An iron hot water tank having in direct contact with the interior iron surface thereof a CLARK M. OSTERHELD.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 1,381,085 Dantsizen June 7, 1921 1,615,585 Humphries Jan. 25, 1927 1,699,274 Bohart Jan. 15, 1929 1,855,077 Wildt Apr. 19, 1932 1,958,765 Perkins May 15. 1934 2,142,024 Hall Dec. 27, 1938 2,186,285 Eickmeyer Jan. 9, 1940 2,217,719 Williams Oct. 15, 1940 2,299,090 Hothersall Oct. 20, 1942 2,428,526 Osterheld Oct. '7, 1947 2,490,978 Osterheld Dec. 13, 1949 FOREIGN PATENTS Number Country Date 747 Australia Nov. 19, 1936 OTHER REFERENCES Edwards-Aluminum Paint & Powder, 2nd ed., published 1936 by Reinhold Publ. Corp., New York, N. Y., pages 90, 91.

Claims (1)

1. AN IRON HOT WATER TANK HAVING IN DIRECT CONTACT WITH THE INTERIOR IRON SURFACE THEREOF A PROTECTIVE LINING FOR PREVENTING CORROSION OF THE INTERIOR BY ALKALINE AND ACIDIC POTABLE WATERS UNDER VARYING TEMPERATURE CONDITIONS, SAID LINING CONSISTING OF A METAL COATING OF ZINC ON THE TANK INTERIOR IRON SURFACE, AN INTERMEDIATE COATING OF ALUMINUM PAINT ON SAID ZINC COATING AND AN OUTER COATING OF MAGNESIUM PAINT ON SAID ALUMINUM COATING.
US564350A 1944-11-20 1944-11-20 Anticorrosion tank Expired - Lifetime US2566138A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2982040A (en) * 1959-04-21 1961-05-02 Robert G Keller Combined label and rust inhibitor
US3012318A (en) * 1955-12-22 1961-12-12 Artcraft Venetian Blind Mfg Co Metal strip such as that used in roll-up awnings
US3100581A (en) * 1959-04-21 1963-08-13 Aluminum Co Of America Duplex aluminous metal article
US3438754A (en) * 1965-02-18 1969-04-15 Republic Steel Corp Zinc-coated steel with vapor-deposited aluminum overlay and method of producing same
US4783896A (en) * 1986-12-11 1988-11-15 A. O. Smith Corporation Method of making cathodically protected water heater
US4838208A (en) * 1986-12-11 1989-06-13 A.O. Smith Corporation Cathodically protected water heater
US4879801A (en) * 1986-12-11 1989-11-14 A. O. Smith Corporation Cathodically protected water heater
US20090200319A1 (en) * 2008-02-08 2009-08-13 Gopala Krishna Vinjamuri Metallic liner for a fiber wrapped composite pressure vessel for compressed gas storage and transportation
US20110177358A1 (en) * 2010-01-20 2011-07-21 United States Pipe And Foundry Company, Llc Protective coating for metal surfaces

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1381085A (en) * 1919-11-01 1921-06-07 Gen Electric Coating metals
US1615585A (en) * 1926-02-25 1927-01-25 Metals Prot Corp Process of producing corrosion-resisting coatings on iron and steel and product
US1699274A (en) * 1926-03-13 1929-01-15 Nat Canners Ass Process and product for preventing discoloration of canned foods
US1855077A (en) * 1931-05-06 1932-04-19 Joseph W Early Hot water boiler
US1958765A (en) * 1932-10-05 1934-05-15 Joseph H Perkins Container for food and other products
AU74736A (en) * 1936-11-03 1936-11-19 Process and materials forthe protection of iron and steel surfaces from corrosion
US2142024A (en) * 1936-09-30 1938-12-27 Egyptian Lacquer Mfg Company Coating surfaces of zinc-base
US2186285A (en) * 1937-12-22 1940-01-09 Dayton Pump & Mfg Co Plated storage tank and method of making
US2217719A (en) * 1938-09-27 1940-10-15 Karl D Williams Protection of steel shafting against corrosion
US2299090A (en) * 1938-12-31 1942-10-20 American Can Co Container and method of producing the same
US2428526A (en) * 1945-01-29 1947-10-07 Mcgraw Electric Co Anticorrosion tank
US2490978A (en) * 1944-03-20 1949-12-13 Mcgraw Electric Co Corrosion prevention

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1381085A (en) * 1919-11-01 1921-06-07 Gen Electric Coating metals
US1615585A (en) * 1926-02-25 1927-01-25 Metals Prot Corp Process of producing corrosion-resisting coatings on iron and steel and product
US1699274A (en) * 1926-03-13 1929-01-15 Nat Canners Ass Process and product for preventing discoloration of canned foods
US1855077A (en) * 1931-05-06 1932-04-19 Joseph W Early Hot water boiler
US1958765A (en) * 1932-10-05 1934-05-15 Joseph H Perkins Container for food and other products
US2142024A (en) * 1936-09-30 1938-12-27 Egyptian Lacquer Mfg Company Coating surfaces of zinc-base
AU74736A (en) * 1936-11-03 1936-11-19 Process and materials forthe protection of iron and steel surfaces from corrosion
US2186285A (en) * 1937-12-22 1940-01-09 Dayton Pump & Mfg Co Plated storage tank and method of making
US2217719A (en) * 1938-09-27 1940-10-15 Karl D Williams Protection of steel shafting against corrosion
US2299090A (en) * 1938-12-31 1942-10-20 American Can Co Container and method of producing the same
US2490978A (en) * 1944-03-20 1949-12-13 Mcgraw Electric Co Corrosion prevention
US2428526A (en) * 1945-01-29 1947-10-07 Mcgraw Electric Co Anticorrosion tank

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3012318A (en) * 1955-12-22 1961-12-12 Artcraft Venetian Blind Mfg Co Metal strip such as that used in roll-up awnings
US2982040A (en) * 1959-04-21 1961-05-02 Robert G Keller Combined label and rust inhibitor
US3100581A (en) * 1959-04-21 1963-08-13 Aluminum Co Of America Duplex aluminous metal article
US3438754A (en) * 1965-02-18 1969-04-15 Republic Steel Corp Zinc-coated steel with vapor-deposited aluminum overlay and method of producing same
US4783896A (en) * 1986-12-11 1988-11-15 A. O. Smith Corporation Method of making cathodically protected water heater
US4838208A (en) * 1986-12-11 1989-06-13 A.O. Smith Corporation Cathodically protected water heater
US4879801A (en) * 1986-12-11 1989-11-14 A. O. Smith Corporation Cathodically protected water heater
US20090200319A1 (en) * 2008-02-08 2009-08-13 Gopala Krishna Vinjamuri Metallic liner for a fiber wrapped composite pressure vessel for compressed gas storage and transportation
US8474647B2 (en) * 2008-02-08 2013-07-02 Vinjamuri Innovations, Llc Metallic liner with metal end caps for a fiber wrapped gas tank
US20110177358A1 (en) * 2010-01-20 2011-07-21 United States Pipe And Foundry Company, Llc Protective coating for metal surfaces
US8697251B2 (en) 2010-01-20 2014-04-15 United States Pipe And Foundry Company, Llc Protective coating for metal surfaces

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