US2530804A - Lubricating compound - Google Patents

Lubricating compound Download PDF

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Publication number
US2530804A
US2530804A US53594A US5359448A US2530804A US 2530804 A US2530804 A US 2530804A US 53594 A US53594 A US 53594A US 5359448 A US5359448 A US 5359448A US 2530804 A US2530804 A US 2530804A
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United States
Prior art keywords
wax
mixture
soap
compound
petroleum
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Expired - Lifetime
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US53594A
Inventor
Bloomenthal Sidney
Fredric E Wood
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Automatic Electric Laboratories Inc
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Automatic Electric Laboratories Inc
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Priority to US53594A priority Critical patent/US2530804A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/14Synthetic waxes, e.g. polythene waxes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/16Paraffin waxes; Petrolatum, e.g. slack wax
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/17Fisher Tropsch reaction products
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/04Ethers; Acetals; Ortho-esters; Ortho-carbonates
    • C10M2207/046Hydroxy ethers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/123Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/22Acids obtained from polymerised unsaturated acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/282Esters of (cyclo)aliphatic oolycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28Esters
    • C10M2207/34Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/06Groups 3 or 13
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/06Instruments or other precision apparatus, e.g. damping fluids

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Description

Patented Nov. 21, 1950 LUBRICA'BING COMPOUND Sidney Blooment'hal', Chicago, and Fredric E. Wood, McHenry, 111., assignors to Automatic Electric Laboratories, Inc., Chicago, 111., a cornotation of Delaware No Drawing. Application October 8, 1948, Serial No. 53,594
Claims.
Our invention relates generally to an improved lubricating compound and more specifically to a lubricant which is especially adapted for use on the bearings of the calling device or dial of an automatic telephone.
Telephone dials are subjected to a wide range of temperature in their use in different locations and must not become sticky under any conditions. Certain of the gears and bearings in such dials are of brass and others of steel so that lubrication and prevention of corrosion are of prime importance.
The improved compound which we have developed for this purpose consists of 30% of a plastic petroleum such as that sold by the Gulf Oil Company as Plastic Petroleum B, of rust proofing oil such as Ensis N0. 211 sold by the Shell Oil Company, and 55% of dibutyl phthalate.
The first component may be of the type described in U. S. Patent No. 2,320,002, granted May 25, 1943 and provides the lubricating qualities at a wide range of temperatures, and remains on the gears and bearings of the device after more volatile components disappear to provide a low coeflicient of friction between moving parts even at low temperatures.
The plastic petroleum consists essentially of a mixture of a petroleum lubricating oil with a wax having a wax melting point above about 150 F. and having incorporated therein an amount of aluminum soap such that the ratio of soap to wax is of the order of 1:15.
The second component is a rust preventer and prevents oxygen from attacking the metallic surfaces on which it is present. One such component is described in U. S. Patent No. 2,334,158, granted November 9, 1943.
The rust preventer consists essentially of non gaseous hydrocarbons containing small amounts of a polycarboxylic acid having at least 16 carbon atoms and of a mutual solvent for hydrocarbons and water, such as an ethylene glycol mono alkyl ether.
The third component is a low volatility solvent for the plastic petroleum and remains liquid by itself to a temperature of -96 F. The presence of this component in the compound aids in the capillary fiow oi the compound into a bearing when applied to the outside edge thereof. The contact angle on steel for dibutyl phthalate is 0 and for brass is 35. The compound consequently tends to spread rapidly on steel and stops when it reaches brass. This quality tends to maintain the compound within a bearing when the adjacent parts are of brass.
While we have described the compound as consisting of certain definite proportions of the various elements, it will be apparent that such proportions may be varied slightly if desired. For instance a slight increase in the amount of dibutyl phthalate reduces the viscosity of the combination and improves the rate of flow during application, while an increase in the amount of the rust inhibitor may give added protection under conditions where severe humidity is encountered.
It will thus be apparent that we have provided a novel lubricating compound which has all the qualities desired for a mechanism which is subjected to wide ranges of temperature and humidity.
What we claim is:
1. A lubricating compound comprising approximately 30% of a mixture of a petroleum lubricating oil with a wax having a wax melting point above about F. and having incorporated therein an amount of aluminum soap such that the ratio of soap to wax is of the order of 1:15; 15% of a mixture of non-gaseous hydrocarbons containing small amounts of a poly carboxylic acid having at least 15 carbon atoms, and of a mutual solvent for hydrocarbons and water; and 55% of ditbuyl phthalate.
2. A lubricant comprising in combination a plastic petroleum consisting of a mixture of a petroleum lubricating oil, a wax having a wax melting point above about 150 F., and an aluminum soap, the soap to wax ratio being of the order of 1:15; a rust preventer consisting of a mixture of non-gaseous hydrocarbons containing small amounts of a poly carboxylic acid having at least 16 carbon atoms and a mutual solvent for hydrocarbons and water; and at least 50% of dibutyl phthalate.
3. A lubricating mixture comprising in combination about 30% of a plastic petroleum consisting of a mixture of a petroleum lubricating oil, a Wax having a wax melting point above about 150 F., and an aluminum soap, the soap to wax ratio being of the order of 1:15; at least 50% of a low volatility petroleum solvent; and a rust preventer consisting of a mixture of non-gaseous hydrocarbons containing small amounts of a polycarboxylic acid having at least 16 carbon atoms and a mutual solvent for hydrocarbons and water.
4. A rust proofing lubricant which flows more rapidly on steel than on brass comprising at least 50% of dibutyl phthalate, a small amount of a rust preventer consisting of a mixture of non-gaseous hydrocarbons containing small amounts of a polycarboxylic acid having at least 16 carbon atoms and a mutual solvent for bydrocarbons and water; and a larger amount of a plastic petroleum consisting of a mixture of a petroleum lubricating oil, a wax having a wax melting point above about 150 F., and an aluminum soap, the soap to wax ratio being of the order of 1:15.
5. A lubricant comprising in combination a 10 about 150 R, an aluminum soap, the wax to soap 15 ratio being about 15:1, and about 50% dibutyl phthalate.
SIDNEY BLOOMENTHAL. FREDRIC E. WOOD.
REFERENCES CITED The following references are of record in the file of this patent:
UNITED STATES PATENTS Number Name Date 2,396,191 Morgan Mar. 5, 1946 2,362,767 Morgan Nov. 14, 1944 2,334,158 Fuchs Nov. 9, 1943 2,320,002 Lutz May 25, 1943 2,215,590 Maverick Sept. 24, 1940 2,104,408 Wiezevich -4 Jan. 4, 1938

Claims (1)

1. A LUBRICATING COMPOUND COMPRISING APPROXIMATELY 30% OF A MIXTURE OF A PETROLEUM LUBRICATING OIL WITH A WAX HAVING A WAX MELTING POINT ABOVE ABOUT 150*F. AND HAVING NCORPORATED THEREIN AN AMOUNT OF ALUMINUM SOAP SUCH THAT THE RATIO OF SOAP TO WAX IS OF THE ORDER OF 1:15; 15% OF A MIXTURE OF NON-GASEOUS HYDROCARBONS CONTAINING SMALL AMOUNTS OF A POLY CARBOXYLIC ACID HAVING AT LEAST 16 CARBON ATOMS, AND OF A MUTUAL SOLVENT FOR HYDROCARBONS AND WATER; AND 55% OF DIBUTYL.
US53594A 1948-10-08 1948-10-08 Lubricating compound Expired - Lifetime US2530804A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2104408A (en) * 1933-09-20 1938-01-04 Standard Oil Dev Co Lubricant
US2215590A (en) * 1935-07-20 1940-09-24 Standard Oil Dev Co Lubricating composition
US2320002A (en) * 1941-08-22 1943-05-25 Gulf Research Development Co Petroleum lubricating jelly
US2334158A (en) * 1941-09-29 1943-11-09 Shell Dev Rust-preventive composition
US2362767A (en) * 1942-06-03 1944-11-14 Cities Service Oil Co Lubricants
US2396191A (en) * 1944-01-25 1946-03-05 Cities Service Oil Co Instrument lubricant

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2104408A (en) * 1933-09-20 1938-01-04 Standard Oil Dev Co Lubricant
US2215590A (en) * 1935-07-20 1940-09-24 Standard Oil Dev Co Lubricating composition
US2320002A (en) * 1941-08-22 1943-05-25 Gulf Research Development Co Petroleum lubricating jelly
US2334158A (en) * 1941-09-29 1943-11-09 Shell Dev Rust-preventive composition
US2362767A (en) * 1942-06-03 1944-11-14 Cities Service Oil Co Lubricants
US2396191A (en) * 1944-01-25 1946-03-05 Cities Service Oil Co Instrument lubricant

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