US2414313A - Process of coating web surfaces - Google Patents
Process of coating web surfaces Download PDFInfo
- Publication number
- US2414313A US2414313A US621162A US62116245A US2414313A US 2414313 A US2414313 A US 2414313A US 621162 A US621162 A US 621162A US 62116245 A US62116245 A US 62116245A US 2414313 A US2414313 A US 2414313A
- Authority
- US
- United States
- Prior art keywords
- clay
- web
- spray
- resin
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/54—Starch
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
Definitions
- This invention relates-to a,-process of coating web surfaces. It relates particularly to the coating of web surfaces with a clay-resin composition.
- This application is a division of my copending application Serial No. 551,059;
- My invention has great utility in the paper making art, so for purposesof explanation and illustration it will be described in connection with its application to that art and particularly the application to paper of a coating material.
- the invention is not so limited, however, also having utility in other arts, as, for example, the art of coating fabric webs, or fibres before the webs are formed.
- the word web as used hereafter in the specification and in the claims comprehends webs of paper fabric or other material and also fibres as above referred to.
- the spray-dried product has a number of important advantages. Amongthese is the advantage that when such product is made into an aqueous dispersion with starch or other adhesive and applied to paper it forms a superior coating with a lesser amount of expensive raw material. Papers coated with such a coating material respond veryfavorably to the standard wax test and uniformly give higher values than if the same ingredients are mixed in aqueous dispe rsion in the ordinary way.
- the coated web is calendered.
- the coated web is preferably heat treated to polymerize the resin. I find it advantageous to calender the coated web cold and thereafter heat treat the calendered web. For best results, I find, the coated and cold-calendered web should be subjected to a temperature of in the neighborhood of 100 C.
- the heat-treating temperature is about C. and the time of heat-treating about twenty minutes.
- an accelerator such as ammonium chloride
- the pH value of clay is about 4.5.
- Coated papers prepared as above explained exhibit. properties markedly superior to papers coated with an admixture of resin in aqueous dispersion with a clay slip.
- the wax test indicia are several points higher.
- the coating is relatively tenacious or adherent to the paper and the paper exhibits superior water-repellent properties and better finish (higher gloss).
- An advantage of the spray-drying process as applied to the treatment of resinous compositions, and particularly clay-resin compositions, is that the resin is not polymerized in the process.
- the spray-dried material may be incorporated in the ultimate product and thereafter polymerized.
- I avoid polymerization of the resin during spray-drying by limiting the time during which the material is subjected to a temperature above the polymerization temperature of the resin to prevent polymerization. This can be done because the time required for the spray-drying of the material is less than the time required for polymerization of the resin.
- a process of coating a web surface comprising applying to the surface a liquid dispersion of a spray-dried clay-resin composition and starch, calenderingthe coated surface and heating the coated web to polymerize the resin.
- a process of coating a web surface comprising applying to th surface a liquid dispersion of a spray-dried clay-resin composition and starch, calendering the coated surface and there-.
- a process of coating a web surface comprising spray-drying a liquid dispersion of urea-formaldehyde resin and clay, forming a liquid disperacidity of said dispersion to a pH value of about 4.5, applying the same to a web surface .and calendering said surface.
- a process of coating a web surface comprising forming a liquid dispersion of a spray-dried clay and urea-formaldehyde resin composition
- a process of coating a web surface comprising applying to the surface a liquid dispersion- 'a spray-dried composition containing about 20 parts clay to 1 part urea-formaldehyde resin by weight, which dispersion contains ,an amount of sion of said spray-dried material, adjusting the starch equalv to about 15% by weight of the clay.
- a process of coating a web surface comprising applying "to the surface a liquid dispersion of a spray-dried composition containing about 20 parts clay to 1 part urea-formaldehyde resin by weight, which dispersion contains an amount of starch equal to about 15% by weight of the clay,
- a process of coating 9. web surface comprising applying to the surface a liquid dispersion of a spray-dried clay-resin composition containing between about 15 and about 25 parts of clay-to .1 part of resin together with starch and calendering the coating surface.
- a process of coating'a web surface comprising applying to the surface a liquid dispersion of a spray-dried clay-resin composition and starch. coldacalendering the coated surface and thereafter subjecting the web to a temperature at least about as high as C. for a period ranging betweenabout 15 and about 25 minutes.
- a process of coating a web surface comprising forming a liquid dispersion of' a spraydried clay and urea-formaldehyde resin composition containing between about 15 and about 25 priod ranging between about 15 and about25 minutes.
Description
Patented Jan. 14, 1947 PROCESS OF COATING WEB SURFACES Thomas Gostage Leek, New York, N. Y., assignor to Edgar Brothers Company, Metuchen, N. J., a corporation of New Jersey No Drawing.
Original application August 24,
1944, Serial No. 551,059. Divided and this application October 8, 1945, Serial No. 621,162
11'Claims. 1
This invention relates-to a,-process of coating web surfaces. It relates particularly to the coating of web surfaces with a clay-resin composition. This application is a division of my copending application Serial No. 551,059;
My invention has great utility in the paper making art, so for purposesof explanation and illustration it will be described in connection with its application to that art and particularly the application to paper of a coating material. The invention is not so limited, however, also having utility in other arts, as, for example, the art of coating fabric webs, or fibres before the webs are formed. The word web as used hereafter in the specification and in the claims comprehends webs of paper fabric or other material and also fibres as above referred to.
I have found that by spray-drying an admixture ,of resin dispersion and clay slip a powder is formed which when dispersed with an adhesive, such as starch, produces a paper coating material which imparts superior properties to paper coated with it. When such an admixtureis I spray-dried there results a clay-resin composition comprising particles composed of a portion of clay and a portion of resin physically joined together The product is in powder form. The resin tends to coat the clay and the spray-drying normally results in a powder comprising particles of clay individually coated with resin.
As explained in -iny said copending applicatoin, the spray-dried product has a number of important advantages. Amongthese is the advantage that when such product is made into an aqueous dispersion with starch or other adhesive and applied to paper it forms a superior coating with a lesser amount of expensive raw material. Papers coated with such a coating material respond veryfavorably to the standard wax test and uniformly give higher values than if the same ingredients are mixed in aqueous dispe rsion in the ordinary way.
'I have found that when the spray-dried material is to be used for coating paper or other web excellent results are obtained by spray-drying an admixture of a water dispersion of urea-formaldehyde resin and a clay slip, forming a water dispersion of the spray-dried material with starch and applying the same to the web. Desirably between about fifteen and about twenty-five parts of clay by weight to one part of resin are employed. The preferred proportion is twenty parts of clay to one part of resin. The starch should have a weight at least about of the weight of the, spray-dried clay-resin composition em- 2 ployed, preferably about The starch is preferably cooked in the usual way.
After the coating material consisting of a water dispersion of the spray-dried clay-resin composition and starch is applied to the web the coated web is calendered. The coated web is preferably heat treated to polymerize the resin. I find it advantageous to calender the coated web cold and thereafter heat treat the calendered web. For best results, I find, the coated and cold-calendered web should be subjected to a temperature of in the neighborhood of 100 C.
or somewhat higher for a period ranging between about fifteen and about twenty-five minutes. Preferably the heat-treating temperature is about C. and the time of heat-treating about twenty minutes.
Preferably, I adjust the acidity of the dispersion of spray-dried clay-resin composition, as by the addition of an accelerator, such as ammonium chloride, to the pH value approximating the optimum pH value for polymerization of the resin. For example, I- adjust the acidity of "a disperson of a spray-dried composition of clay and urea-formaldehyde resin by adding ammonium l chloride to bring the dispersion to a pH value of about 4.5, which is the optimum pH value for pplymerization of urea-formaldehyde resin. The pH value of clay is about 4.5.
Coated papers prepared as above explained exhibit. properties markedly superior to papers coated with an admixture of resin in aqueous dispersion with a clay slip. The wax test indicia are several points higher. The coating is relatively tenacious or adherent to the paper and the paper exhibits superior water-repellent properties and better finish (higher gloss).
An advantage of the spray-drying process as applied to the treatment of resinous compositions, and particularly clay-resin compositions, is that the resin is not polymerized in the process. Thus the spray-dried material may be incorporated in the ultimate product and thereafter polymerized. I avoid polymerization of the resin during spray-drying by limiting the time during which the material is subjected to a temperature above the polymerization temperature of the resin to prevent polymerization. This can be done because the time required for the spray-drying of the material is less than the time required for polymerization of the resin.
Whil I have described certain present preferred methods of practicing the invention it is to be distinctly understood that the invention is not limited thereto but may be otherwise variing applying to the surface a liquid dispersion of a spray-dried clay-resin composition and starch and calendering theqcoated surface.
2. A process of coating a web surface comprising applying to the surface a liquid dispersion of a spray-dried clay-resin composition and starch, calenderingthe coated surface and heating the coated web to polymerize the resin.
3. A process of coating a web surface comprising applying to th surface a liquid dispersion of a spray-dried clay-resin composition and starch, calendering the coated surface and there-.
after heating the coated web to a temperature of about 105 C. for about 20 minutes.
4. A process of coating a web surface comprising spray-drying a liquid dispersion of urea-formaldehyde resin and clay, forming a liquid disperacidity of said dispersion to a pH value of about 4.5, applying the same to a web surface .and calendering said surface.
5. A process of coating a web surface comprising forming a liquid dispersion of a spray-dried clay and urea-formaldehyde resin composition,
adjusting the acidity of said dispersion to a pH value of about 4.5, applying the same to a web surface, calendering said surface and thereafter heating the coated web to a temperature of about 105 C. for about twenty minutes.
6. A process of coating a web surface comprising applying to the surface a liquid dispersion- 'a spray-dried composition containing about 20 parts clay to 1 part urea-formaldehyde resin by weight, which dispersion contains ,an amount of sion of said spray-dried material, adjusting the starch equalv to about 15% by weight of the clay.
calendering the coated surface and heating the coated web to polymerize the resin.
8. A process of coating a web surface comprising applying "to the surface a liquid dispersion of a spray-dried composition containing about 20 parts clay to 1 part urea-formaldehyde resin by weight, which dispersion contains an amount of starch equal to about 15% by weight of the clay,
calendaring the coated'surface and thereafter heating the coated web to a temperature of about 105 C. for about twenty minutes.
9. A process of coating 9. web surface comprising applying to the surface a liquid dispersion of a spray-dried clay-resin composition containing between about 15 and about 25 parts of clay-to .1 part of resin together with starch and calendering the coating surface.
10. A process of coating'a web surface comprising applying to the surface a liquid dispersion of a spray-dried clay-resin composition and starch. coldacalendering the coated surface and thereafter subjecting the web to a temperature at least about as high as C. for a period ranging betweenabout 15 and about 25 minutes. 1
11. A process of coating a web surface comprising forming a liquid dispersion of' a spraydried clay and urea-formaldehyde resin composition containing between about 15 and about 25 priod ranging between about 15 and about25 minutes.
THOMAS G OSTAGE LEEK
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US621162A US2414313A (en) | 1944-08-24 | 1945-10-08 | Process of coating web surfaces |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US55105944A | 1944-08-24 | 1944-08-24 | |
US621162A US2414313A (en) | 1944-08-24 | 1945-10-08 | Process of coating web surfaces |
Publications (1)
Publication Number | Publication Date |
---|---|
US2414313A true US2414313A (en) | 1947-01-14 |
Family
ID=27069642
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US621162A Expired - Lifetime US2414313A (en) | 1944-08-24 | 1945-10-08 | Process of coating web surfaces |
Country Status (1)
Country | Link |
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US (1) | US2414313A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2514689A (en) * | 1946-11-07 | 1950-07-11 | Eastman Kodak Co | Sized paper |
US2583274A (en) * | 1947-04-30 | 1952-01-22 | Monsanto Chemicals | Process for producing mineralcoated paper |
US2656286A (en) * | 1945-08-29 | 1953-10-20 | Cons Water Power & Paper Co | Process of coating paper webs and product thereof |
US3380842A (en) * | 1963-09-20 | 1968-04-30 | Georgia Pacific Corp | Decorative composition and a process for its use |
-
1945
- 1945-10-08 US US621162A patent/US2414313A/en not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
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None * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2656286A (en) * | 1945-08-29 | 1953-10-20 | Cons Water Power & Paper Co | Process of coating paper webs and product thereof |
US2514689A (en) * | 1946-11-07 | 1950-07-11 | Eastman Kodak Co | Sized paper |
US2583274A (en) * | 1947-04-30 | 1952-01-22 | Monsanto Chemicals | Process for producing mineralcoated paper |
US3380842A (en) * | 1963-09-20 | 1968-04-30 | Georgia Pacific Corp | Decorative composition and a process for its use |
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