US2407255A - Dust collecting composition and method - Google Patents
Dust collecting composition and method Download PDFInfo
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- US2407255A US2407255A US501132A US50113243A US2407255A US 2407255 A US2407255 A US 2407255A US 501132 A US501132 A US 501132A US 50113243 A US50113243 A US 50113243A US 2407255 A US2407255 A US 2407255A
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- dust
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- dust collecting
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/22—Materials not provided for elsewhere for dust-laying or dust-absorbing
Definitions
- This invention relates to air conditioning and is particularly directed to dust collecting compositions containing an ammonium salt of an acid ester of a polybasic inorganic oxyacid and a polyhydroxy aliphatic compound.
- filters so constructed constitute a fire hazard even when oils having high fiash points are used, not only because the dustladen oils are susceptible to spontaneous combustion but also because when a fire breaks out combustible fumes are discharged in the ventilating system so that the fire spreads more readily than otherwise. idly become dust laden and must either be discarded or cleaned, and the only suitable method available is the relatively expensive dry cleaning.
- the non-crystalline fluid salts of the acid esters of polybasic inorganic oxyacids and polyhydroxy aliphatic compounds are avoided by using as the collecting media for air-borne dust.
- the ammonium salts such as the ammonium phosphates, ammonium borates, and ammonium sulfates, of polyhydroxy aliphatic compounds to be of value for this purpose, since with the ammonium salt I not only avoid the disadvantages of the prior art compounds but also obtain a further and important advantage attributable to the flame-resisting action of the ammonium salts.
- dust filters of conventional design are treated to impregnate the pores of the dust filter with dust collecting compositions prepared according to my invention.
- I speak of pores of dust filter I use the term loosely with reference to the various Furthermore, such filters rap- 2 types of interstices which exist in the various types of filters.
- These structures may be fabricated, for example, by felting or matting fibrous materials such as fiber glass, waste, hair, excelsior or metal turnings in suitable supporting structures, or by depositing porous material such as wood flour on metal wire screens. Corrugated paper or successive layers of fabric can also be used.
- an adhesive such as latex, can be applied permanently to bind the structure into a, unit.
- the dust collecting liquids of my invention can be applied to the filter mats in any suitable manner, as for example by sprayin the liquid into the mat.
- the ammonium salts of acid esters of polybasic oxyacids and pclyhydroxy aliphatic compounds in addition to supplying the desired combustion-resistant dust collecting media and to preventing spontaneous combustion of collected dust, render flame-resistant the supporting structure when made from combustible material.
- These dust filters can be regenerated simply by washing with water and reapplying the dust collecting liquid, and in this respect provide greater economy and convenience as compared with dust filters impregnated with oil.
- a suitable composition is prepared a follows, the parts being by weight:
- phenyl mercury hydroxide I may use any fungicide capable of inhibiting growth of various micro-organisms whether bacteria, mold or fungi, but highly active non-volatile substances such as the phenyl mercury compounds are preferred.
- Other but less suitable materials include salicylanilide, sodium pentachlorophenolate, paranitrophenol and other nitro phenols, and the cupric derivative of propionyl acetone and salicylaldehyde.
- any suitable wetting agent e. g. any wetting agent which will reduce the interfaoial tension between dust and an aqueous solution.
- wetting agent e. g. any wetting agent which will reduce the interfaoial tension between dust and an aqueous solution.
- anion active wetting agents for example, the alkali metal salts of long chain alkyl sulfuric acids, the alkali metal salts of long chain substituted arc-- matic sulfonic acids, fatty acid soaps and the like.
- cation active wetting agents for example, long chain quaternary ammonium salts, betaines containing a long chain alkyl group and the like.
- my invention in its broader aspects is directed to fluid salts of acid esters of polybasic inorganic oxyacid-s and polyhydroxy aliphatic compounds including those which readily become liquid in the presence of plasticizer or solvent.
- Suitable polybasic inorganic oxyacids include acids such as boric, phosphoric and sulfuric acids. These may be esterified by any of the well-known methods of esterification.
- borates can be prepared by reaction with boric acid; phosphateare prepared by reaction with phosphoric acid, phosphorous pentoxide, phosphorous oxychloride, or ammonium acid phosphate, and sulfates are obtained by reaction with sulfuric acid, ammonium acid. sulfate, chlorosulfuric acid, or sulfamic acid.
- the ammonium sulfate esters are of particular interest since they can be prepared with high yield and free of by-products from sulfa-mic acid.
- Suitable polyhydroxy aliphatic compound include hydroxy acids such as glycollic, lactic, citric, tartaric, glyceric, hydroxybutyric, malic acids and their polyhydroxy derivatives; glycols such as ethylene, propylene and butylene glycols; and higher alcohols such as glycerin, pentaerythritol, sorbitol. mannitol, and polyalcohols obtained by the hydrogenation, or reduction by other means, of the triose, tetrose, pentose and hexose sugars.
- One or more of the hydroxy groups may be esterified by the polybasic acid. Also, if a tribasic acidis used, di-esters are suitable. Three carbon atoms for each inorganic acid radical is most suitable.
- the method of removing dust which comprises contacting dust-laden air with a water-soluble, substantially non-volatile liquid consisting essentially of an ammonium salt of an acid ester of a polybasic inorganic oxyacid and a polyhydroxy aliphatic compound, and water in proportions such that the liquid has a viscosity between about 20 poises and poises at 25 C.
- the method of removing dust which comprises contacting dust-laden air with a Water-soluble, substantially non-volatile liquid having a viscosity between about 20 poises and 80 poises at 25 C. consisting essentially of an ammonium salt of an acid ester of a polybasic inorganic oxyacid and a polyhydroxy aliphatic compound, a wetting agent, a fungicide, and suflicient water to provide a liquid of the specified viscosity.
- the method of removing dust which comprises contacting dust-laden air with a non-volatile liquid consisting essentially of glyceryl ammonium sulfate and water in proportion such that the liquid has a viscosity between about 20 poises and 80 poises at 25 C.
- the method of removing dust which comprises contacting dust-laden air with a non-volatile liquid consisting essentially of glyceryl ammonium sulfate, a wetting agent, a fungicide, and water in proportions, such that the liquid has a viscosity between about 20 poises and 80 poises at 25 C.
- a non-volatile liquid consisting essentially of glyceryl ammonium sulfate, a wetting agent, a fungicide, and water in proportions, such that the liquid has a viscosity between about 20 poises and 80 poises at 25 C.
- a dust collecting composition comprising a water-soluble substantially non-volatile liquid consisting essentially of an ammonium salt of an acid ester of a polybasic inorganic oxyacid' and a polyhydroxy aliphatic compound, and water in proportion such that the liquid has a viscosity between about 20 poises and 80 poises at 25 C.
- a dust collecting composition comprising a water-soluble, substantially non-volatile liquid consisting essentially of an ammonium salt of an acid ester of a polybasic inorganic acid and a polyhydroxy aliphatic compound, a wetting agent, a fungicide, and water in proportions such that the liquid has a viscosity between about 20 poises and 80 poises at 25 C.
- the liquid has a viscosity between about poises and 80 poises at C.
- a dust collecting composition comprising a water-soluble, substantially non-volatile liquid consisting essentially of glyceryl ammonium sulfate and water in proportions such that the liquid has a viscosity between about 20 poises and poises at 25 C.
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Description
, of such oils.
Patented Sept. 10, 1946 2,407,255 DUST COLLEETING COMPOSITION AND METHO Martin Eli Cupery, Wilmington, Del, assignor to E. I. du Pont de Nemours & Company, Wilmington, Del, a corporation of Delaware No Drawing. Original application June '7, 1946, Serial No. 339,331, now Patent No. 2,347,031, dated April 18,1944. Divided and this application'Scptember 3, 1943, Serial No. 501,132
8 Claims.
This invention relates to air conditioning and is particularly directed to dust collecting compositions containing an ammonium salt of an acid ester of a polybasic inorganic oxyacid and a polyhydroxy aliphatic compound.
In air conditioning it is common to employ a fluid type air filter consisting in a porous barrier, placed across the air stream, in which, because relatively large pores are employed so as not substantially to hinder the passage of air therethru, there is included a suitable viscous liquid which serves to catch, wet and retain the dust particles in the filter. I-Ieretofore it has been more customary to employ highly refined mineral oils as the dust collecting medium in such filters, and the filters so roduced have sufiered in consequence of the undesirable characteristics Thus, filters so constructed constitute a fire hazard even when oils having high fiash points are used, not only because the dustladen oils are susceptible to spontaneous combustion but also because when a fire breaks out combustible fumes are discharged in the ventilating system so that the fire spreads more readily than otherwise. idly become dust laden and must either be discarded or cleaned, and the only suitable method available is the relatively expensive dry cleaning. It has been suggested to avoid certain of these defects by substituting very high fiash point liquids such as tricresyl phosphate, but such materials are somewhat objectionable because of odor and particularly in case of local fires, since then the odor permeates thruout the ventilating system.
I have now found that the disadvantages of the prior art are avoided by using as the collecting media for air-borne dust the non-crystalline fluid salts of the acid esters of polybasic inorganic oxyacids and polyhydroxy aliphatic compounds. Especially I have found the ammonium salts, such as the ammonium phosphates, ammonium borates, and ammonium sulfates, of polyhydroxy aliphatic compounds to be of value for this purpose, since with the ammonium salt I not only avoid the disadvantages of the prior art compounds but also obtain a further and important advantage attributable to the flame-resisting action of the ammonium salts.
In carrying out my invention dust filters of conventional design are treated to impregnate the pores of the dust filter with dust collecting compositions prepared according to my invention. When I speak of pores of dust filter I use the term loosely with reference to the various Furthermore, such filters rap- 2 types of interstices which exist in the various types of filters. These structures may be fabricated, for example, by felting or matting fibrous materials such as fiber glass, waste, hair, excelsior or metal turnings in suitable supporting structures, or by depositing porous material such as wood flour on metal wire screens. Corrugated paper or successive layers of fabric can also be used. In all these cases an adhesive, such as latex, can be applied permanently to bind the structure into a, unit.
The dust collecting liquids of my invention can be applied to the filter mats in any suitable manner, as for example by sprayin the liquid into the mat. The ammonium salts of acid esters of polybasic oxyacids and pclyhydroxy aliphatic compounds in addition to supplying the desired combustion-resistant dust collecting media and to preventing spontaneous combustion of collected dust, render flame-resistant the supporting structure when made from combustible material.
These dust filters can be regenerated simply by washing with water and reapplying the dust collecting liquid, and in this respect provide greater economy and convenience as compared with dust filters impregnated with oil.
A suitable composition is prepared a follows, the parts being by weight:
To 3000 parts dynamite grade glycerol, heated by external steam, 3660 parts recrystallized suliamic acid is added portionwise with stirring during a two-hour interval, while controlling the temperature with slight cooling at -120" C. The reaction is continued until all of the sulfamic acid dissolves and a constant low acid number is obtained. There are then added 20 parts of a, mixture containing approximately 59% sodium sulfate of commercial coconut oil alcohols, the remainder being essentially sodium sulfate and sodium chloride and known commercially as Aquarex D (wetting agent), and 0.2 part phenyl mercuric hydroxide (fungicide), and the mixture is heated at lid- C. for an additional four hours. The final solution is neutralized by the addition of 100 parts of 28% ammonium hydroxide solution and clarified by passing through a filter while hot. This composition has at 25 C.
a Gardner-Holdt bubble tube viscosity of about This composition is non-inflammable, free of odor, non-corrosive to steel, substantially non volatile, chemically stable, hygroscopic, and has surface tension characteristics similar to lubricating oils, and also good wetting action. It does not smoke or fume when placed in a flame or subjected to high temperatures.
The viscosity of the composition can be readily adjusted as' desired simply by diluting it Wit water. It is desirable that the viscosity be relatively high, preferably between 20 poises and 30 poises at 25 (7., although higher and lower viscosities may be used in some cases. A composition having suitable viscosity characteristics is obtained by diluting the composition described above with 20 per cent by weight of water.
In place of phenyl mercury hydroxide I may use any fungicide capable of inhibiting growth of various micro-organisms whether bacteria, mold or fungi, but highly active non-volatile substances such as the phenyl mercury compounds are preferred. Other but less suitable materials include salicylanilide, sodium pentachlorophenolate, paranitrophenol and other nitro phenols, and the cupric derivative of propionyl acetone and salicylaldehyde.
In place of Aquarex D I may use any suitable wetting agent, e. g. any wetting agent which will reduce the interfaoial tension between dust and an aqueous solution. These include anion active wetting agents, for example, the alkali metal salts of long chain alkyl sulfuric acids, the alkali metal salts of long chain substituted arc-- matic sulfonic acids, fatty acid soaps and the like. They also include cation active wetting agents, for example, long chain quaternary ammonium salts, betaines containing a long chain alkyl group and the like.
While I have illustrated my invention with particular reference to glyceryl ammonium sulfate which exemplifies all the desirable attributes of my invention, it will be understood that my invention is in its broader aspects not limited thereto but that other ester-salts having similar characteristics may also be employed.
Thus my invention in its broader aspects is directed to fluid salts of acid esters of polybasic inorganic oxyacid-s and polyhydroxy aliphatic compounds including those which readily become liquid in the presence of plasticizer or solvent. Suitable polybasic inorganic oxyacids include acids such as boric, phosphoric and sulfuric acids. These may be esterified by any of the well-known methods of esterification. For example, borates can be prepared by reaction with boric acid; phosphateare prepared by reaction with phosphoric acid, phosphorous pentoxide, phosphorous oxychloride, or ammonium acid phosphate, and sulfates are obtained by reaction with sulfuric acid, ammonium acid. sulfate, chlorosulfuric acid, or sulfamic acid. The ammonium sulfate esters are of particular interest since they can be prepared with high yield and free of by-products from sulfa-mic acid.
Suitable polyhydroxy aliphatic compound include hydroxy acids such as glycollic, lactic, citric, tartaric, glyceric, hydroxybutyric, malic acids and their polyhydroxy derivatives; glycols such as ethylene, propylene and butylene glycols; and higher alcohols such as glycerin, pentaerythritol, sorbitol. mannitol, and polyalcohols obtained by the hydrogenation, or reduction by other means, of the triose, tetrose, pentose and hexose sugars.
,The carbon chains in these compounds can be straight or branched chains and they can be saturated or unsaturated. Other atoms than carbon atoms can be present in the chain, including oxygen or nitrogen. That is, the polyhydroxy compounds can be ethers such as polyethylene glycol or polyglycerol, amine-s such as diand triethanolamine, or esters such as those from a hydroxy acid and an alcohol, from an unsubstituted straight or branched chain aliphatic acid and a glycol or higher polyhydric alcohol, or from a hydroxy acid and a glycol or higher polyhydric alcohol. The triose, tetrose, pentose and hexose sugars are also suitable for the preparation of the ester-salts. Preferably these compounds should not contain more than six carbon atoms.
One or more of the hydroxy groups may be esterified by the polybasic acid. Also, if a tribasic acidis used, di-esters are suitable. Three carbon atoms for each inorganic acid radical is most suitable.
The ester-salts may in some instances be used alone but preferably are used in compositions containing other materials adapted to preserve or modify the properties of the ester-salts. Thus I may include fungicides and wetting agents of the character described and plasticizer or solvents of which water is particularly suitable. Other materials such as the various polyhydroxy aliphatic compounds listed above may be used either alone or in combination with water to plasticize or modify the viscosity of the compositions. Similarly, viscosity or plasticity-building agents may be included in limited amounts Where desired, in-- cluding colloidal materials such as glue, gelatine, Irish moss, water-solubl methyl cellulose, starch acetate, gum karaya, polyvinyl alcohol, and the like.
Although my dust collecting compositions are most often used on filter mats, pads or screens, their utility is not thus limited and may be used wherever dust-containin gases are caused to flow past, to impinge upon or to pass thru the composition or a surface covered with th composition.
This application is a division f my copending application Serial No. 339.331 filed June 7, 1940, which issued as Patent 2,347,031, April 18, 1944.
I claim:
1. In air conditioning the method of removing dust which comprises contacting dust-laden air with a water-soluble, substantially non-volatile liquid consisting essentially of an ammonium salt of an acid ester of a polybasic inorganic oxyacid and a polyhydroxy aliphatic compound, and water in proportions such that the liquid has a viscosity between about 20 poises and poises at 25 C.
2. In air conditioning the method of removing dust which comprises contacting dust-laden air with a Water-soluble, substantially non-volatile liquid having a viscosity between about 20 poises and 80 poises at 25 C. consisting essentially of an ammonium salt of an acid ester of a polybasic inorganic oxyacid and a polyhydroxy aliphatic compound, a wetting agent, a fungicide, and suflicient water to provide a liquid of the specified viscosity.
3. In air conditioning the method of removing dust which comprises contacting dust-laden air with a non-volatile liquid consisting essentially of glyceryl ammonium sulfate and water in proportion such that the liquid has a viscosity between about 20 poises and 80 poises at 25 C.
4. In air conditioning the method of removing dust which comprises contacting dust-laden air with a non-volatile liquid consisting essentially of glyceryl ammonium sulfate, a wetting agent, a fungicide, and water in proportions, such that the liquid has a viscosity between about 20 poises and 80 poises at 25 C.
5. A dust collecting composition comprising a water-soluble substantially non-volatile liquid consisting essentially of an ammonium salt of an acid ester of a polybasic inorganic oxyacid' and a polyhydroxy aliphatic compound, and water in proportion such that the liquid has a viscosity between about 20 poises and 80 poises at 25 C.
6. A dust collecting composition comprising a water-soluble, substantially non-volatile liquid consisting essentially of an ammonium salt of an acid ester of a polybasic inorganic acid and a polyhydroxy aliphatic compound, a wetting agent, a fungicide, and water in proportions such that the liquid has a viscosity between about 20 poises and 80 poises at 25 C.
' proportions such that the liquid has a viscosity between about poises and 80 poises at C.
8. A dust collecting composition comprising a water-soluble, substantially non-volatile liquid consisting essentially of glyceryl ammonium sulfate and water in proportions such that the liquid has a viscosity between about 20 poises and poises at 25 C.
MARTIN ELI CUPERY.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US501132A US2407255A (en) | 1940-06-07 | 1943-09-03 | Dust collecting composition and method |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US339331A US2347031A (en) | 1940-06-07 | 1940-06-07 | Air filter |
US501132A US2407255A (en) | 1940-06-07 | 1943-09-03 | Dust collecting composition and method |
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US2407255A true US2407255A (en) | 1946-09-10 |
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US501132A Expired - Lifetime US2407255A (en) | 1940-06-07 | 1943-09-03 | Dust collecting composition and method |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3017239A (en) * | 1958-11-03 | 1962-01-16 | Fram Corp | Air conditioner filters having germicidal properties |
US4333845A (en) * | 1978-08-11 | 1982-06-08 | Grow Group, Inc. | Coating composition thinner for decreasing pollution resulting from the application of a coating composition |
US4339248A (en) * | 1976-11-08 | 1982-07-13 | Grow Group, Inc. | Process for the purification of gaseous effluent from industrial processes |
-
1943
- 1943-09-03 US US501132A patent/US2407255A/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3017239A (en) * | 1958-11-03 | 1962-01-16 | Fram Corp | Air conditioner filters having germicidal properties |
US4339248A (en) * | 1976-11-08 | 1982-07-13 | Grow Group, Inc. | Process for the purification of gaseous effluent from industrial processes |
US4333845A (en) * | 1978-08-11 | 1982-06-08 | Grow Group, Inc. | Coating composition thinner for decreasing pollution resulting from the application of a coating composition |
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