US2336815A - Manufacture and use of fluorescent materials - Google Patents
Manufacture and use of fluorescent materials Download PDFInfo
- Publication number
- US2336815A US2336815A US379325A US37932541A US2336815A US 2336815 A US2336815 A US 2336815A US 379325 A US379325 A US 379325A US 37932541 A US37932541 A US 37932541A US 2336815 A US2336815 A US 2336815A
- Authority
- US
- United States
- Prior art keywords
- fluorescent
- rays
- emulsion
- barium sulphate
- support
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title description 38
- 238000004519 manufacturing process Methods 0.000 title description 15
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 98
- 239000000839 emulsion Substances 0.000 description 44
- 229910052709 silver Inorganic materials 0.000 description 17
- 239000004332 silver Substances 0.000 description 17
- -1 silver halide Chemical class 0.000 description 16
- 238000010304 firing Methods 0.000 description 14
- 238000010438 heat treatment Methods 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 8
- 238000002601 radiography Methods 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 230000005251 gamma ray Effects 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 230000002939 deleterious effect Effects 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- 239000001117 sulphuric acid Substances 0.000 description 3
- 235000011149 sulphuric acid Nutrition 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000005083 Zinc sulfide Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- IWOUKMZUPDVPGQ-UHFFFAOYSA-N barium nitrate Chemical compound [Ba+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O IWOUKMZUPDVPGQ-UHFFFAOYSA-N 0.000 description 2
- 159000000009 barium salts Chemical class 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 235000005811 Viola adunca Nutrition 0.000 description 1
- 240000009038 Viola odorata Species 0.000 description 1
- 235000013487 Viola odorata Nutrition 0.000 description 1
- 235000002254 Viola papilionacea Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000004833 fish glue Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003041 laboratory chemical Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000012857 radioactive material Substances 0.000 description 1
- 229910052705 radium Inorganic materials 0.000 description 1
- HCWPIIXVSYCSAN-UHFFFAOYSA-N radium atom Chemical compound [Ra] HCWPIIXVSYCSAN-UHFFFAOYSA-N 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical class [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- G—PHYSICS
- G21—NUCLEAR PHYSICS; NUCLEAR ENGINEERING
- G21K—TECHNIQUES FOR HANDLING PARTICLES OR IONISING RADIATION NOT OTHERWISE PROVIDED FOR; IRRADIATION DEVICES; GAMMA RAY OR X-RAY MICROSCOPES
- G21K4/00—Conversion screens for the conversion of the spatial distribution of X-rays or particle radiation into visible images, e.g. fluoroscopic screens
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/167—X-ray
- Y10S430/168—X-ray exposure process
Definitions
- This invention relates to the production of materials which fluoresce under the stimulus of X-rays and gamma-rays, to the production of fluorescent screens containing such materials,
- an intensifying screen may be defined by its intensification factor. This is the factor by which the exposure time would have to be multiplied if no intensifying screen were used, in order to give an image in the de- 5 veloped emulsion of equal density to that obtained with the aid of the screen.
- Intensifying screens are usually made as independent units and the same screen is used for many exposures. It has, however, been proposed to combine with .a silver halide photographic emulsion on a transparent support a layer of material which fluoresces under the influence of X-rays, the layer being incorporated in or on .the emulsion or embodied in the support.
- a silver halide photographic emulsion on a transparent support a layer of material which fluoresces under the influence of X-rays, the layer being incorporated in or on .the emulsion or embodied in the support.
- such combinations of fluorescent and light-sensitive materials have certain advantages, they have not found favour in practice largely because of the dificulty and expense in volved in the preparation of the known fluorescent substances Whieh can be so employed and which, when used in such combinations, can only be employed for one exposure.
- the invention is to provide fluorescent screens containing such fluorescent material and a still further object is to provide photographic materials containing such fluorescent material suit: able for the production of radiographs. Another object of the invention is to provide processes for the production of the new fluorescent mallerial.
- the product obtained is strongly fluorescent in the blue-violet and ultra-violetunder the influence of X-rays or gamma-rays and may be used as the fluorescent substance in a fluorescent .screen.
- Such material has an intensification factor .greater than 12 and, dependent on its purity and given elsewhere in this specification and inthe claims are determined by the following method.
- a layer of the fluorescent material in powder form having a thickness equal to .20 gms. per square decimetre (i. e., sufficiently thick to give substantially the maximum emission of light from the surface of the layer) is placed behind and in contact with a normal type of blue-sensitive X-ray emulsion and exposed to X-rays .generated at k. v. p. and filtered through 2.5 mm,
- the intensification factor is defined as the ratio of the exposure necessary to produce a developed image of standard .densityin the absence of the-fluorescent .material to the-exposure necessary to produce a developed image presence of the fluorescent material.
- substantially pure is meant that the purest obtainable reagents should be employed to produce the product.
- Reagentshaving at least the degree of purity definedin the ,book Analar Standards for Laboratory Chemicals, formulated and issued jointly by The British Drug Houses Ltd., and Hopkin 8: Williams Ltd., and published in 1934, may be employed and it is preferable that the reagents should have an even greater degree of purity than is .required by these standards.
- the invention includes X-ray Or gamma-ray sensitive material for radiography which .comprises one or more support layers, at least one silver halide emulsion layer and substantially pure crystalline barium sulphate which has been fired as described distributed in one of the above layers or in a carrier layer attached to one of the support or silver halide emulsion layers to form an intensifying screen which will fluoresce under the stimulus of X-rays or of gamma-rays and so effect exposure of the emulsion layer.
- the material may be made in the form of a bipack in which the silver halide emulsion layer is carried on one support and, the intensifying screen is carried in or on another support layer.
- the emulsion layer and the screen may be carried on a single support layer, e. g., of pa er or cellulose film. as a unit.
- the fluorescent .material is preferably incorporated in a carrier layer situated between the support la er. and the emulsion layer, or is incorporated .in theemulsion or in the sup ort layer.
- the substantiallypure crystalline barium sulphate to be subjectedto firing to produce the fluorescent material of this invention may be made by anv suitable method.
- a most convenient. method is to form the barium sulphate as a precipitate by, double decomposition between a solution of a soluble barium salt, e. g., barium nitrate, and an excess of sulphuric acid or of a solution of an alkali sulphate. e. 2.. sodium sulphate or other colourless soluble sulphate.
- the precipitated barium sulphate is washed with a dilute so ution of sulphuric acid or pure distilled water before use. It is important, of course. that the purest obtainable reagents be used throughout, e. g., Analar reagents.-
- the firing operation is conveniently carried out in pure air in a muffle furnace, the barium sulphate being contained in a crucible composed of an inert material or lined with an inert material.
- the barium sulphate may be fired in an electrically heated'furnace in a mundaneble lined with pure calcined calcium sulphate or in an alumina crucible.
- V V The duration of the firing treatment in order to obtain the optimum results depends, inter alia, on the temperance of that treatment. In general, it may be noted that at anygiven firing temperature, increases in time of firing increase thefluorescent properties of the product up to a maximum after which further firing either has no effect or is definitely deleterious. Also, it may be noted that the lower thefiring temperature the longeris the time necessary to obtain the optimum results. In general, at lower firing temperatures the fluorescent properties of the prodnot are not usually so good as at the higher firing temperatures.
- the barium sulphate may be fired in the presence of a flux, e. g., magnesium sub phate or sodium sulphate, which is afterwards dissolved out.
- a flux e. g., magnesium sub phate or sodium sulphate
- the intensification factor of the barium sulphate material should be as high as possible, this is not so important where the intensifying screen is included with a support and photographicemulsion as a unitary element.
- barium sulphate material having an intensification factor of only 12-15 is often useful, though material of higher intensification factor, e. g., 20-30 or more may obviously be employed in such unitary products.
- Substantially pure crystalline barium sulphate which has not been subjected to the special firing treatment of this invention has negligible intensifying properties, and never approaches an intensification factor as high as 12.
- X-ray or gamma-ray screens incorporating the firedbarium sulphate maybe prepared by dispersingthe fired barium sulphate in any suitable carrier, e. g., a solution of a cellulose derivative or of a colourless synthetic resin, and then casting the resulting dispersion to form a film, or
- a screen produced in this way may be used in the usual manner of X-ray intensifying screens i. e., it may be placed'in contact with a silver halide emulsion and the emulsion and the screen exposed to X-rays, the fluorescent light emitted by the screenproducing a latent image in the emulsion more rapidly than the X-rays alone.
- the fired barium sulphate may be used to form a fluorescent layer in a unit comprising the silver halide emulsion and a single support layer as described above.
- This may, for example, be effected by dispersing the fluorescent product in a colloid carrier (e.
- a cellulose derivative, a colourless synthetic resin, a solution of gelatin or the like g., a cellulose derivative, a colourless synthetic resin, a solution of gelatin or the like
- coating the dispersion on a support by any of the usual coating methods employed in the photographic industry, drying the product and then coating a gelatino-silver halide emulsion of the type commonly employed for radiographic purposes on the top of the fluorescent layer, or the fluorescent barium sulphate may be dispersed in the photographic silver halide emulsion itself before it is coated on its support.
- fluorescent layer may be on the back of the support.
- the fluorescent layer When the fluorescent layer is coated on the face of the emulsion or on the back of the support, it maybe suspended in a carrier soluble in water or dilute alkali or other solvent which does not attack the emulsion or support for example, fish glue, or an acid resin, which will permit the ready removal of the fluorescent layer before or during processing of the emulsion.
- the fluorescent layer maybe of such a character that it can be stripped, in the wet or dry condition, from the assembly.
- a layer of the fired barium sulphate in a strippable material, e. g., collodion may be coated on to the surface of the emulsion remote from the support, and the layer may be removed before processing so that the finished radiograph can be viewed by reflected light if the support is not transparent or by transmitted light if the support is transparent.
- the fluorescent layer is coated on the silver halide emulsion layer there may, if desired, be a second emulsion layer on the opposite side of the support, the support being of course, in this case, transparent both to the rays and to visible light and thin.
- the fluorescent material of this invention possesses many advantages as the active fluorescent material in an X-ray or gamma-ray intensifying screen.
- it gives a screen having a satisfactory intensifying factor and unlike zinc sulphide it is efiective not only with X-rays generated at relatively low peak kilovoltages, but also with X-rays generated at high peak kilovoltages such as are used for the radiography of thick and/or very dense objects.
- it can readily be obtained in microcrystalline form screens containing it as the active ingredient yield radiograp-hs of very good definition.
- barium sulphate is a cheap material (compared, for example, with calcium tungstate) and unlike zinc sulphide has no deleterious effect on silver halide photographic emulsions, it can be economically employed, as mdicated above, as an element in a unitary product containing both emulsion and fluorescent screen, and used for a single exposure. Also screens made in accordance with the present invention are highly resistant to deleterious action on their fluorescent properties by water.
- Fluorescent barium sulphate material consisting essentially of substantially pure crystalline barium sulphate having an intensification factor of at least 12 and obtainable by heating substantially pure crystalline barium sulphate at a temperature of 900-4.150" C. for a period of at least 1 hour.
- Fluorescent barium sulphate material consisting essentially of substantially pure barium sulfate having an intensification factor of at least 20 and being substantially identical with that obtainable by heating substantially pure crystal-line barium sulfate at a temperature :of 900-1150" '0. for a period of several hours.
- Fluorescent barium sulphate material consisting essentially of substantially pure crystalline barium sulphate having an intensification factor of at least 12 and obtainable by heating substantially pure crystalline barium sulphate at a temperature of 1000 to 1060 C. for six to ten hours.
- An X-ray fluorescent screen comprising a support and a layer which fiuoresces under the influence of X-rays comprising substantially pure crystalline barium sulphate having an intensification factor of at least 20 obtainable by heating .substantially pure crystalline barium sulphate at a temperature of 900-1150 C. for a period of several hours.
- An X-ray sensitive screen assembly for radiography which comprises a silver halide photographic emulsion and a support for the emulsion in combination with a screen layer containing substantially pure crystalline barium sulphate having an intensification factor exceeding 12 which will fluoresce under the stimulus of X-rays or gamma-rays and produce a latent image in the photographic emulsion and is obtainable by heating substantially pure crystalline barium sulfate at a temperature of 900 to 1150 C. for a period of several hours.
- An X-ray sensitive element for radiography which comprises a silver halide photographic emulsion, a support for the emulsion and a screen layer containing substantially pure crystalline barium sulphate having an intensification factor exceeding 20 substantially identical with that obtainable by heating substantially pure crystalline barium sulfate at a temperature of 900-1150" C. for a period of several hours, which will fluoresce under the stimulus of X-rays or gamma-rays and produce a latent image in the photographic emulsion, the whole combined to form a unitary product.
- An X-ray sensitive element for radiography which comprises a silver halide photographic emulsion, a support for the emulsion and, between the emulsion and the support, a screen layer containing substantially pure crystalline barium sulphate having an intensification factor exceeding 12, which will fluoresce under the stimulus of X-rays or gamma-rays and produce a latent image in the photographic emulsion and is obtainable by heating substantially pure crystalline barium sulfate at a temperature of 900 to 1150 C. for a period of several hours.
- An X-ray sensitive element for radiography which comprises a silver halide photographic emulsion, and a support for the emulsion which support contains incorporated in it a screen layer containing substantially pure crystalline barium sulphate having an intensification factor exceeding 12 which will fluoresce under the stimulus of X-rays or gamma-rays and produce a latent image in the photographic emulsion and is obtainable by heating substantially pure crystalline barium sulfate at a temperature of 900 to 1150 C. for a period of several hours.
- An X-ray sensitive element for radiography which comprises a silver halide photographic emulsion, a support for the emulsion and, coated on an outer surface of the assembly of emulsion and support, a screen layer containing substantially pure crystalline barium sulphate having an intensification factor exceeding 12 which will fluoresce under the stimulus of X-rays or gamma rays'and produce a latent image in the barium sulphate having an intensification factor exceeding 12, which will fluoresce under the stimulus of X-rays or gamma-rays and produce a latent image in the photographic emulsion and is obtainable by heating substantially pure crystalline barium sulfate at a temperature of 900 to 1150" C. for a period of several hours.
Description
Dec. 14, 1943. H. s. TASKER MANUFACTURE AND USE OF FLUORESCENT MATERIAL Filed Feb. 17, 1941 HOURS OF HRING Hard S THIKH'INVENTOR.
ATTORNEY Patented Dec. 14, 1943 NET!) 1- MANUFACTURE AND USE OF FLUORESCENT MATERIALS Hardwicke Slingsby Tasker, Ilford, England, as-
signor to Ilford Limited, Ilford, England, a
British company Application February 17, 1941, Serial No. 379,325
In Great Britain April 9, 1940 15 Claims.
This invention relates to the production of materials which fluoresce under the stimulus of X-rays and gamma-rays, to the production of fluorescent screens containing such materials,
and to the production of photographic products embodying such fluorescent materials and suitable for the production of X-ray and gammaray photographs, that is, so-called radiographs.
It is well known that X-rays and gamma-rays from radium and other radio-active materials are capable of forming latent images in silver halide emulsions and that it is possible therefore tensifying screen is placed in contact with a silver halide photographic emulsion coated on a support and the combination is exposed to the rays with the result that the fluorescent light emitted .by the screen forms a latent image in the emulsion more quickly than the rays alone could do.
The effectiveness of an intensifying screen may be defined by its intensification factor. This is the factor by which the exposure time would have to be multiplied if no intensifying screen were used, in order to give an image in the de- 5 veloped emulsion of equal density to that obtained with the aid of the screen.
Intensifying screens are usually made as independent units and the same screen is used for many exposures. It has, however, been proposed to combine with .a silver halide photographic emulsion on a transparent support a layer of material which fluoresces under the influence of X-rays, the layer being incorporated in or on .the emulsion or embodied in the support. However, while such combinations of fluorescent and light-sensitive materials have certain advantages, they have not found favour in practice largely because of the dificulty and expense in volved in the preparation of the known fluorescent substances Whieh can be so employed and which, when used in such combinations, can only be employed for one exposure.
It is an object of this invention to provide a new fluorescent material. A further object of of copper.
.of the same density in the 40- the invention is to provide fluorescent screens containing such fluorescent material and a still further object is to provide photographic materials containing such fluorescent material suit: able for the production of radiographs. Another object of the invention is to provide processes for the production of the new fluorescent mallerial.
' It has now been discovered, and this forms the basis of the present invention, that if substantially pure crystalline barium sulphate is sub jected to a firing treatment at temperatures of the order of 900 to 1150 C. for several hours, the product obtained is strongly fluorescent in the blue-violet and ultra-violetunder the influence of X-rays or gamma-rays and may be used as the fluorescent substance in a fluorescent .screen.
Such material has an intensification factor .greater than 12 and, dependent on its purity and given elsewhere in this specification and inthe claims are determined by the following method.
A layer of the fluorescent material in powder form, having a thickness equal to .20 gms. per square decimetre (i. e., sufficiently thick to give substantially the maximum emission of light from the surface of the layer) is placed behind and in contact with a normal type of blue-sensitive X-ray emulsion and exposed to X-rays .generated at k. v. p. and filtered through 2.5 mm, The intensification factor is defined as the ratio of the exposure necessary to produce a developed image of standard .densityin the absence of the-fluorescent .material to the-exposure necessary to produce a developed image presence of the fluorescent material.
By the expression substantially pure is meant that the purest obtainable reagents should be employed to produce the product. Reagentshaving at least the degree of purity definedin the ,book Analar Standards for Laboratory Chemicals, formulated and issued jointly by The British Drug Houses Ltd., and Hopkin 8: Williams Ltd., and published in 1934, may be employed and it is preferable that the reagents should have an even greater degree of purity than is .required by these standards. In particular it has been found that the presence, even in minute amounts, of iron, manganese, chromium and .copper, and to a lesser degree, nickel or cobalt .impairs the fluorescent properties of the product. However, it is permissible for there to be present in the fluorescent materials of this invention a considerable proportion, e. g., 20% or even more of the closely related pure calcium and pure strontium sulphates, and the expression substantially pure is to be understood with this qualification. It may be noted that since it is desirable for a fluorescent screen material to be highly resistant to moisture, an unduly large proportion of calciumor strontiurnsulphate is undesirable. r V
The invention includes X-ray Or gamma-ray sensitive material for radiography which .comprises one or more support layers, at least one silver halide emulsion layer and substantially pure crystalline barium sulphate which has been fired as described distributed in one of the above layers or in a carrier layer attached to one of the support or silver halide emulsion layers to form an intensifying screen which will fluoresce under the stimulus of X-rays or of gamma-rays and so effect exposure of the emulsion layer. The material may be made in the form of a bipack in which the silver halide emulsion layer is carried on one support and, the intensifying screen is carried in or on another support layer. Alternatively the emulsion layer and the screen may be carried on a single support layer, e. g., of pa er or cellulose film. as a unit. In this case the fluorescent .material is preferably incorporated in a carrier layer situated between the support la er. and the emulsion layer, or is incorporated .in theemulsion or in the sup ort layer.
'The substantiallypure crystalline barium sulphate to be subiectedto firing to produce the fluorescent material of this invention may be made by anv suitable method. A most convenient. method is to form the barium sulphate as a precipitate by, double decomposition between a solution of a soluble barium salt, e. g., barium nitrate, and an excess of sulphuric acid or of a solution of an alkali sulphate. e. 2.. sodium sulphate or other colourless soluble sulphate. Preferably the precipitated barium sulphate is washed with a dilute so ution of sulphuric acid or pure distilled water before use. It is important, of course. that the purest obtainable reagents be used throughout, e. g., Analar reagents.-
The firing operation is conveniently carried out in pure air in a muffle furnace, the barium sulphate being contained in a crucible composed of an inert material or lined with an inert material. Thus. for example, the barium sulphate may be fired in an electrically heated'furnace in a cruelble lined with pure calcined calcium sulphate or in an alumina crucible. V V The duration of the firing treatment in order to obtain the optimum results depends, inter alia, on the temperance of that treatment. In general, it may be noted that at anygiven firing temperature, increases in time of firing increase thefluorescent properties of the product up to a maximum after which further firing either has no effect or is definitely deleterious. Also, it may be noted that the lower thefiring temperature the longeris the time necessary to obtain the optimum results. In general, at lower firing temperatures the fluorescent properties of the prodnot are not usually so good as at the higher firing temperatures.
By way of example, it may be stated that when pure precipitated barium sulphate is fired .at .temperatures'of 100-0 to 1060 C. the intensification factor of the product increases with time of firing of the barium sulphate and reachesa value of about -50 after 6 to 10 hours firing. The accompanying drawing illustrates the variation of intensification factor with time of firing at 1050 C. in a particular case.
If desired, the barium sulphate may be fired in the presence of a flux, e. g., magnesium sub phate or sodium sulphate, which is afterwards dissolved out.
' During the firing operation some sintering of the barium sulphate may occur and if so it is desirable to grind the product to'a fine powder preferably wetted with water before employing it for the production of a fluorescent screen.
Whilst in the production of an intensifying screen as a separate unit intended, in use, to be placed next to a photographic element, it is desirable that the intensification factor of the barium sulphate material should be as high as possible, this is not so important where the intensifying screen is included with a support and photographicemulsion as a unitary element. In this latter case barium sulphate material having an intensification factor of only 12-15 is often useful, though material of higher intensification factor, e. g., 20-30 or more may obviously be employed in such unitary products. Substantially pure crystalline barium sulphate which has not been subjected to the special firing treatment of this invention has negligible intensifying properties, and never approaches an intensification factor as high as 12.
X-ray or gamma-ray screens incorporating the firedbarium sulphate maybe prepared by dispersingthe fired barium sulphate in any suitable carrier, e. g., a solution of a cellulose derivative or of a colourless synthetic resin, and then casting the resulting dispersion to form a film, or
coating on a paper or other support. Gelatin and other'hydrophilic colloids may also be used as carriers. A screen produced in this way may be used in the usual manner of X-ray intensifying screens i. e., it may be placed'in contact with a silver halide emulsion and the emulsion and the screen exposed to X-rays, the fluorescent light emitted by the screenproducing a latent image in the emulsion more rapidly than the X-rays alone.
Alternatively, the fired barium sulphate may be used to form a fluorescent layer in a unit comprising the silver halide emulsion and a single support layer as described above. This may, for example, be effected by dispersing the fluorescent product in a colloid carrier (e. g., a cellulose derivative, a colourless synthetic resin, a solution of gelatin or the like), coating the dispersion on a support by any of the usual coating methods employed in the photographic industry, drying the product and then coating a gelatino-silver halide emulsion of the type commonly employed for radiographic purposes on the top of the fluorescent layer, or the fluorescent barium sulphate may be dispersed in the photographic silver halide emulsion itself before it is coated on its support.
Other arrangements of the unit, in addition to those mentioned above in which the fired barium sulphate is located between the support and the sensitive layer or in the support, are possible, but it is necessary to take into account the parent to visible light and to the rays, the
fluorescent layer may be on the back of the support. When the fluorescent layer is coated on the face of the emulsion or on the back of the support, it maybe suspended in a carrier soluble in water or dilute alkali or other solvent which does not attack the emulsion or support for example, fish glue, or an acid resin, which will permit the ready removal of the fluorescent layer before or during processing of the emulsion.
Again, the fluorescent layer maybe of such a character that it can be stripped, in the wet or dry condition, from the assembly. Thus for example a layer of the fired barium sulphate in a strippable material, e. g., collodion, may be coated on to the surface of the emulsion remote from the support, and the layer may be removed before processing so that the finished radiograph can be viewed by reflected light if the support is not transparent or by transmitted light if the support is transparent.
When the fluorescent layer is coated on the silver halide emulsion layer there may, if desired, be a second emulsion layer on the opposite side of the support, the support being of course, in this case, transparent both to the rays and to visible light and thin.
Owing to the insolubility of the fired barium sulphate in the usual photographic developing and fixing baths, unless it is coated on the surface and removed in the manner described above, it remains in the finished radiograph and although this is a disadvantage for some purposes, it is of no importance where the support is opaque, for example of paper, and the radiograph is viewed by reflected light.
The fluorescent material of this invention possesses many advantages as the active fluorescent material in an X-ray or gamma-ray intensifying screen. Thus it gives a screen having a satisfactory intensifying factor and unlike zinc sulphide it is efiective not only with X-rays generated at relatively low peak kilovoltages, but also with X-rays generated at high peak kilovoltages such as are used for the radiography of thick and/or very dense objects. Further, since it can readily be obtained in microcrystalline form screens containing it as the active ingredient yield radiograp-hs of very good definition.
Again, since barium sulphate is a cheap material (compared, for example, with calcium tungstate) and unlike zinc sulphide has no deleterious effect on silver halide photographic emulsions, it can be economically employed, as mdicated above, as an element in a unitary product containing both emulsion and fluorescent screen, and used for a single exposure. Also screens made in accordance with the present invention are highly resistant to deleterious action on their fluorescent properties by water.
What I claim is: Y
1. Fluorescent barium sulphate material consisting essentially of substantially pure crystalline barium sulphate having an intensification factor of at least 12 and obtainable by heating substantially pure crystalline barium sulphate at a temperature of 900-4.150" C. for a period of at least 1 hour.
2. Fluorescent barium sulphate material consisting essentially of substantially pure barium sulfate having an intensification factor of at least 20 and being substantially identical with that obtainable by heating substantially pure crystal-line barium sulfate at a temperature :of 900-1150" '0. for a period of several hours.
3. Fluorescent barium sulphate material .consisting essentially of substantially pure crystalline barium sulphate having an intensification factor of at least 12 and obtainable by heating substantially pure crystalline barium sulphate at a temperature of 1000 to 1060 C. for six to ten hours.
4. An X-ray fluorescent screen comprising a support and a layer which fiuoresces under the influence of X-rays comprising substantially pure crystalline barium sulphate having an intensification factor of at least 20 obtainable by heating .substantially pure crystalline barium sulphate at a temperature of 900-1150 C. for a period of several hours.
5. An X-ray sensitive screen assembly for radiography which comprises a silver halide photographic emulsion and a support for the emulsion in combination with a screen layer containing substantially pure crystalline barium sulphate having an intensification factor exceeding 12 which will fluoresce under the stimulus of X-rays or gamma-rays and produce a latent image in the photographic emulsion and is obtainable by heating substantially pure crystalline barium sulfate at a temperature of 900 to 1150 C. for a period of several hours.
6. An X-ray sensitive element for radiography which comprises a silver halide photographic emulsion, a support for the emulsion and a screen layer containing substantially pure crystalline barium sulphate having an intensification factor exceeding 20 substantially identical with that obtainable by heating substantially pure crystalline barium sulfate at a temperature of 900-1150" C. for a period of several hours, which will fluoresce under the stimulus of X-rays or gamma-rays and produce a latent image in the photographic emulsion, the whole combined to form a unitary product.
7. An X-ray sensitive element for radiography which comprises a silver halide photographic emulsion, a support for the emulsion and, between the emulsion and the support, a screen layer containing substantially pure crystalline barium sulphate having an intensification factor exceeding 12, which will fluoresce under the stimulus of X-rays or gamma-rays and produce a latent image in the photographic emulsion and is obtainable by heating substantially pure crystalline barium sulfate at a temperature of 900 to 1150 C. for a period of several hours.
8. An X-ray sensitive element for radiography which comprises a silver halide photographic emulsion, and a support for the emulsion which support contains incorporated in it a screen layer containing substantially pure crystalline barium sulphate having an intensification factor exceeding 12 which will fluoresce under the stimulus of X-rays or gamma-rays and produce a latent image in the photographic emulsion and is obtainable by heating substantially pure crystalline barium sulfate at a temperature of 900 to 1150 C. for a period of several hours.
9. An X-ray sensitive element for radiography which comprises a silver halide photographic emulsion, a support for the emulsion and, coated on an outer surface of the assembly of emulsion and support, a screen layer containing substantially pure crystalline barium sulphate having an intensification factor exceeding 12 which will fluoresce under the stimulus of X-rays or gamma rays'and produce a latent image in the barium sulphate having an intensification factor exceeding 12, which will fluoresce under the stimulus of X-rays or gamma-rays and produce a latent image in the photographic emulsion and is obtainable by heating substantially pure crystalline barium sulfate at a temperature of 900 to 1150" C. for a period of several hours.
12. Process for'the production of barium sulphate material adapted to fluoresce strongly under the influence of X-rays and gamma-rays,
which comprises heating substantially pure crystalline barium sulphate-at 900-1150 C. for a period of at least one hour.
13.;Process for the production of barium sulphate material adapted to fluoresce strongly under the influence of X-rays and gamma rays which comprises heating substantially pure crystalline .barium sulphate at 9001150 C. for a period of 6-10 hours.
14. Process for the production of barium sulphate material adapted to fluoresce strongly under the influence of. X-rays and gamma-rays which comprises forming substantially pure crystalline barium sulphate by double decomposition between a solution of a pure barium salt in water and a solution in water of a compound selected from'the group consisting of sulphuric acid, alkali metal sulphates and other soluble colourless sulphates, drying the product and thereafter heating it to 900-1150 C. for a period of at least one hour.
15. Process for the production of barium sulphate material adapted to fluoresce strongly under the influence of X-rays and gamma-rays which comprises heating substantially pure crystalline barium sulphate in admixture with a'water-soluble salt acting as a flux at 900-1150" C. for aperiod of several hours and thereafter dissolving out said water-soluble flux. I
HARDWICKE SLINGSBY TASKER.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB2336815X | 1940-04-09 |
Publications (1)
Publication Number | Publication Date |
---|---|
US2336815A true US2336815A (en) | 1943-12-14 |
Family
ID=10904119
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US379325A Expired - Lifetime US2336815A (en) | 1940-04-09 | 1941-02-17 | Manufacture and use of fluorescent materials |
Country Status (1)
Country | Link |
---|---|
US (1) | US2336815A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2694153A (en) * | 1950-08-03 | 1954-11-09 | Frederic W Reuter | X-ray intensifying screen |
US2809294A (en) * | 1954-12-23 | 1957-10-08 | Haloid Co | Xeroradiographic plates or elements |
-
1941
- 1941-02-17 US US379325A patent/US2336815A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2694153A (en) * | 1950-08-03 | 1954-11-09 | Frederic W Reuter | X-ray intensifying screen |
US2809294A (en) * | 1954-12-23 | 1957-10-08 | Haloid Co | Xeroradiographic plates or elements |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3300311A (en) | X-ray intensifying screens employing a water soluble copolymer of alkyl acrylate and acrylic acid | |
DE1547791C3 (en) | Electron beam sensitive photographic recording material | |
US3891852A (en) | Neutron detection and radiography | |
GB1398326A (en) | Intensifying screen | |
US4130429A (en) | Combination of photosensitive elements suited for use in radiography | |
US4130428A (en) | Combination of photosensitive elements suited for use in radiography | |
DE2165764A1 (en) | Silver halide photographic light sensitive materials | |
US3300310A (en) | X-ray intensifying screens employing aqueous ethyl alcohol-soluble nylon binders | |
US4049454A (en) | Color radiography | |
DE1123557B (en) | Light-developable, direct recording photographic material, especially for oscillographic recordings | |
DE2449149B2 (en) | Radiographic recording material | |
US2336815A (en) | Manufacture and use of fluorescent materials | |
DE2614352A1 (en) | RADIOGRAPHIC PROCEDURE AND SENSITIVE MATERIAL FOR THIS | |
DE2051240A1 (en) | Inorganic phosphors suitable for radiographic purposes | |
DE2327962A1 (en) | PHOTOGRAPHIC IMAGE GAIN PROCESS | |
DE1772026A1 (en) | Photographic recording material | |
US2289997A (en) | Production and use of fluorescent materials | |
US4140531A (en) | Light-handleable photographic materials | |
DE2254306C2 (en) | Process for producing colored x-ray images | |
KR900005416B1 (en) | X-ray intensifying screen | |
US2289384A (en) | Manufacture and use of fluorescent lead sulphate materials | |
JPS62215942A (en) | Heat-developable photosensitive material for x-ray photography | |
DE2510068A1 (en) | IMPROVED X-RAY PHOTOGRAPHIC RECORDING MATERIAL | |
DE1177484B (en) | Process for the preparation of light developable direct recording silver halide emulsions | |
US3521058A (en) | Method of improving the definition of detail of both hard and soft substance in radiographs |