US2335331A - Lubricant - Google Patents
Lubricant Download PDFInfo
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- US2335331A US2335331A US393370A US39337041A US2335331A US 2335331 A US2335331 A US 2335331A US 393370 A US393370 A US 393370A US 39337041 A US39337041 A US 39337041A US 2335331 A US2335331 A US 2335331A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
- C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/04—Elements
- C10M2201/041—Carbon; Graphite; Carbon black
- C10M2201/042—Carbon; Graphite; Carbon black halogenated, i.e. graphite fluoride
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
- C10M2203/102—Aliphatic fractions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/022—Ethene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/026—Butene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/14—Synthetic waxes, e.g. polythene waxes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/17—Fisher Tropsch reaction products
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/30—Refrigerators lubricants or compressors lubricants
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/32—Wires, ropes or cables lubricants
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/34—Lubricating-sealants
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/36—Release agents or mold release agents
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/38—Conveyors or chain belts
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/40—Generators or electric motors in oil or gas winning field
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/42—Flashing oils or marking oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/44—Super vacuum or supercritical use
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/50—Medical uses
Definitions
- This invention relates to chemically resistant lubricants, and more particularly to nitrationresistant lubricants.
- the primary object of the present invention is to prepare satisfactory nitration-resistant lubricants and also to prepare such lubricants having the proper consistency for use either alone or when impregnated in a suitable packing material, for lubricating pumps which handle nitric acid or mixtures thereof with sulfuric acid.
- a nitration-resistant lubricant of proper consistency can be produced by blending together a major proportion of mineral white oil, a highly refined petrolatum wax and a polyisobutylene having a molecular weight of about 10,000 to 100,000.
- compositions were subjected to an acid-reaction test, using in some cases nitric acid alone (98% concentration) and in other cases a mixture of 80% nitric acid (98% concentration) and 20% fuming sulfuric acid, to see whether there was any discolorization, fumes, or any other apparent sign of reaction, and these compositions were also subjected to an explosion test in a steel bomb.
- This bomb test consisted of mixing 40% by weight per volume of acid, either nitric acid alone or a mixture of 80% nitric acid and 20% sulfuric acid, with 60% by weight of the lubricant to be tested. The mixing was done with a spatula and the mixture then placed in a steel bomb which'in turn was placed on top of a lead crushing block about 2 /2" high and 1 A in diameter.
- a No. 8 detonating cap was then placed in the grease chamber which is open at the top of the bomb; then on top of this was placed a steel cover weighing 6 /2 pounds.
- the detonating cap was exploded and the height to which the cover was blown was'measured, a'swell as the amount of compression of the lead crushing block. Unless the cover was thrown to a height of over 10 feet or the lead crushing block was -compressed more than 0.10 inch for the 8-pound cap, in the tests with the nitricacid alone, it was considered that the mixture gave no dangerous reaction, except in such cases where the reaction had been so violent during the mixing of the acid and the grease that most of the reaction took place before the mixture could be put in the bomb.
- A. S. T. M. penetration and Saybolt viscosity at 210 F.
- the approximate limits of the A. S. T. M. penetration should be as follows: 100 to about 300 unworked at 77 R, and preferably from about 150 to about 250; and the Saybolt viscosity should be from about 100 to about 500 seconds at 210 F.-, and preferably from about 200 to about 400.
- the results of a series of tests are reproduced herewith in Table 2 where a number of diiierent individual materials and mixtures thereof were submitted to a nitric acid test which consisted in mixing 4 grams of concentrated (08%) nitric acid with 6 grams ofthe material contemplated for use as a lubricant.
- the white oilused was a viscous white oil having a viscosity of approximately 340 seconds at F.
- the paramn wax was an ordinary refined paraffin wax having a melting point of about F.
- Two different kinds of petrolatum wax were used, of which the light colored one had a high melting point (about to 160 F.) and was relatively oilfree (containednot more than 3 or 3% of oil);
- the functions of the various constituents of the composition of this invention may be summarized briefly as follows.
- the polyisobutylene serves, as explained above,- prlmarily for increasing nitration-resistant properties of the composL' the dark petrolatum gave violent reaction, the
- Polyisobutylene 1 1 ing the light petrolatum with dark petrolatum in that composition resulted'ln an extremely violent reaction, .thus showing again that the dark petrolatum was much more reactive than the light petrolatum.
- Test- 22 A nitration-resistant lubricating grease was made with the following proportions of materials, in'per cent by weight:
- Viscous white oil 70 Light petrolatum wax 16 Paraflln wax 4 'Having an average molecular weight of about 12,000
- the white oil 'used I should be, as is commonly meant by that term,
- polyisobutylene was used in all of the such as an isobutylene-ethylene copolymer made from a mixture containing about or of isobutylene and the balance ethylene.
- the petrolatum to be used should be refined to make it light-colored as by clay filtering,- and if desired may also have reis used) may be varied substantially without departing from the fundamental principles of the invention, and the following tableis given to show the general scope of the invention:
- Composition ranges (Per cent by weight) Polymer, average mol. wt.:
- mathematical product of the. percent of polymer multiplied by the average molecular weight thereof should be at least 100,000, and preferably at least 120,000.
- a chemically-resistant lubricant having approximately the following composition in percent by weight: I
- Percent Mineral white oil 50-85 Petrolatum (light oil-free) 10-50 Paraffin w 0-10 and an amount of substantially saturated ali- -.pl"iatic hydrocarbon polymer selected according to Average mol. wt. of polymer Per cent 10,000 10-25 1&000. .x 30.000 715 80,000 5-10 2.
- Lubricant according to claim 1 containing polyisobutylene, the mathematical product of the percent of polymer tlmes'the, average molecular weight thereof being at least 120,000;
- Lubricant according to claim 1 whichwhen subjectedto the bomb explosion test described, does not crush the lead supporting block more than 01inch when tested width concentrated nitric acid alone and a No.8 detonating cap.
- a nitration-resistant lubricant having approximately the following composition in percent Paraffln w x 0-10 5.
- a lubricant packing material suitable for pumps handling nitrating acids which comprises chiefly acid-resistant Blue African asbestos impregnated with a nitration-resistant lubricant defined in claim 1.
Description
Patented Nov. 30,1943
2.33.331 Lunarcm Donald L. Wright, Westfleld, and Charles W. Bohmcr, Jr., Elizabeth, N. 1., assignors, by mesne assignments, to Jasco, Incorporated, a corporation of Louisiana No Drawing. Application May 14, 1941, Serial No. 393,370
Claims. (Cl. 252 59).
This invention relates to chemically resistant lubricants, and more particularly to nitrationresistant lubricants.
Experience has shown that the lubricants used on pump handling concentrated nitric acid or blends of nitric and sulfuric acids usually even-,
tually become nitrated with the result that explosions often occur. In'an effort to correct this condition. numerous lubricants have been tested and found comparatively ineflfective for prevent ing this nitration or unsuitable for other reasons. The lubricant for such pumps should preferably have a consistency corresponding to that of a The primary object of the present invention is to prepare satisfactory nitration-resistant lubricants and also to prepare such lubricants having the proper consistency for use either alone or when impregnated in a suitable packing material, for lubricating pumps which handle nitric acid or mixtures thereof with sulfuric acid.
It has now been found that a nitration-resistant lubricant of proper consistency can be produced by blending together a major proportion of mineral white oil, a highly refined petrolatum wax and a polyisobutylene having a molecular weight of about 10,000 to 100,000.
To illustr'atethe invention some experimental data are given on a number of different compositions containing various amounts of polyisobutylene having a molecular weight of 12,000, 60,000, or 80,000, as indicated in the table, and an artifi- 78% by weight otheavy mineral white oil, 18% by weight of a substantially colorless petrolatum wax having a melting point of about ISO-160 F., which had been decolorized by filtering through bauxite, and about 4% of paraflln wax of about 122 F. melting point, together in certain instances with the addition of an acid-resistant graphite. For comparison, the artificial petroleum jelly and parailln wax were also tested alone.
These various compositions were subjected to an acid-reaction test, using in some cases nitric acid alone (98% concentration) and in other cases a mixture of 80% nitric acid (98% concentration) and 20% fuming sulfuric acid, to see whether there was any discolorization, fumes, or any other apparent sign of reaction, and these compositions were also subjected to an explosion test in a steel bomb.
This bomb test consisted of mixing 40% by weight per volume of acid, either nitric acid alone or a mixture of 80% nitric acid and 20% sulfuric acid, with 60% by weight of the lubricant to be tested. The mixing was done with a spatula and the mixture then placed in a steel bomb which'in turn was placed on top of a lead crushing block about 2 /2" high and 1 A in diameter.
A No. 8 detonating cap was then placed in the grease chamber which is open at the top of the bomb; then on top of this was placed a steel cover weighing 6 /2 pounds. The detonating cap was exploded and the height to which the cover was blown was'measured, a'swell as the amount of compression of the lead crushing block. Unless the cover was thrown to a height of over 10 feet or the lead crushing block was -compressed more than 0.10 inch for the 8-pound cap, in the tests with the nitricacid alone, it was considered that the mixture gave no dangerous reaction, except in such cases where the reaction had been so violent during the mixing of the acid and the grease that most of the reaction took place before the mixture could be put in the bomb.
The results of this series of tests are shown in cial or synthetic petroleum Jelly containing about the following table.
Turn 1 l No.8cap Polylsobutylene Artificial 'gjf petfileyum 112" 3g mnsotamnNoi 98% HNOI 12,000 60,000 80,0) Color Fumes Comp Height Color Fumes Comp Height Feet 25 an in 10 m weight ranging from 12,000 to 80,000 made the artificial petroleum jelly sufilciently nitration-resistant to be satisfactory. g
It should also be noted in'connection with the above tests that since the increase in viscosity of the synthetic petroleum jelly is directly proportional to the amount of polyisobutylene added and also directly proportional to the molecular weight of the polyisobutylene, 1% of polymer having a molecularweight of 80,000 will increase the viscosity of the artificial petroleum jelly almost as much as (actually about '7 or 8%) of a polymer having a molecular weight of 12,000. Now, it is desired to have a non-fluid lubricant, i. e., one which is not fluid, at ordinary temperatures and yet which is soft enough or plastic enough to be pressed into the pump shaft bearings, etc.; and, therefore, it is obvious that the constituents must be compounded in such proportions as to produce a composition falling within these limits of consistency, which may be measured by A. S. T. M. penetration and Saybolt viscosity at 210 F. The approximate limits of the A. S. T. M. penetration should be as follows: 100 to about 300 unworked at 77 R, and preferably from about 150 to about 250; and the Saybolt viscosity should be from about 100 to about 500 seconds at 210 F.-, and preferably from about 200 to about 400. Because of this reason and also because the amount of nitration-resistant property imparted to the composition appears to be directly proportional to the amount of polyisobutylene added, more or less independently of the molecular weight, providing it is not below the minimum desired limit of about 10,000, it is preterable to use 10% of the 12,000 molecular weight polyisobutylene rather than the slightly more than 1% of the 80,000 molecular weight polyiso- V assassr cents have been made heretofore, but they are not satisfactory for the present purposes which require a plastic but-non-fiuid lubricant. Petrolatum is also a. valuable constituent because of its protopet structure, by which is meant that it has the characteristic of helping to hold the oil in the composition, i. e., the petrolatum helps to prevent the oil from running out of the composition. Finally, the mineral white oil, which is the major constituent of the artificial petroleum jelly used in the above described test, is necessary in order to impart proper softening or plasticizing characteristics, i. e., to obtain the proper consistency. To further illustrate the advantages of th present invention, the results of a series of tests are reproduced herewith in Table 2 where a number of diiierent individual materials and mixtures thereof were submitted to a nitric acid test which consisted in mixing 4 grams of concentrated (08%) nitric acid with 6 grams ofthe material contemplated for use as a lubricant. lhe acid and lubricant were mixed together and the mixture watched for signs of reaction. In cases where the acid and lubricant are immiscible, the mere fact that no reaction occurred does not necessarily mean that the substance being tested is acid resistant, as perhaps the lack of reaction is primarily due to lack of miscibility.
In this series of tests the white oilused was a viscous white oil having a viscosity of approximately 340 seconds at F. The paramn wax was an ordinary refined paraffin wax having a melting point of about F. Two different kinds of petrolatum wax were used, of which the light colored one had a high melting point (about to 160 F.) and was relatively oilfree (containednot more than 3 or 3% of oil);
whereas the dark petrolaturii had a melting point of about -165, an A. S. T. M. penetration of about 60-70, and contained about 10% of oil. The results of this series of tests are as follows:
TABLE 2 Nitric acid reaction tests Light, Dark Test to Poraflln Polyiso- No. oil wax m butyleno Remarks 10..-- 100 Poor contact-no reaction. 11 100 Do. 12.--. 100 Slight reaction. 13.-.. 100 Violent 14.... 80 20 Poor contact-no reaction. 16-.-. 80 20 Reaction. 16-.-. 00 2) Extremely violent reaction. 17--.- 60 60 Violent 18---- 67 8 25 D0. 19.--. 67 8 25 Extremely violent reaction. 2)..-- Bl 22 7 10 No reaction. 21--- 01 22 7 10 D0.
butylene which would give equivalent increase in 60 From the above table of data, it is noted that viscosity. Similarly, 20% ot the 12,000 molecular weight polyisobutylene would produce much better nitration-resistance than about 4 or 5%,
of 60,000 molecular weight polyisobutylene which would give substantially the some increase in viscosity;
The functions of the various constituents of the composition of this invention may be summarized briefly as follows. The polyisobutylene serves, as explained above,- prlmarily for increasing nitration-resistant properties of the composL' the dark petrolatum gave violent reaction, the
, light petrolatum gave a slight reaction. and the white oil and parafiln wax were inconclusive because they gave poor contact with the nitric acid. A mixture of 80% ot white oil and 20% of paramn wax likewise gave poor contact. 0n the other hand. a mixture of 80% of white oil and 20% of light petrolatum gave a reaction and a mixture oi 80% of white oil and 20% of dark component mixture (test 18) containing 67% of white oil, 8% of para-inn wax and 25% of light petrolatum gave a violent reaction; and replacwere miscible with nitric acid).
Polyisobutylene 1 1 ing the light petrolatum with dark petrolatum in that composition resulted'ln an extremely violent reaction, .thus showing again that the dark petrolatum was much more reactive than the light petrolatum. A comparison of test 13 where 100% of dark petrolatum gave a violent reaction, with test 16 where only 20% of dark petrolatum mixed with 80% of white oil gave an extremely violent reaction, seems to indicate either that the white oil per so would be very reactive with the nitric acid if it were miscible therewith or that the white oil would permit much better contact between the dark petrolatum and the acid, which would mean that the fluidity of the mixture and the compatibility of the components are important factors if any one constituent is at all reactive. Likewise, by comparison of tests 13 and 17, it is observed that the replacement of half of the dark-petrolatum by paraflin wax did not substantially reduce the intensity of the reaction. Finally, it isobserved that in tests 20 and 21, compositions containing a major proportion of whiteoil and also about 22% of light petrolatum and a small amount of paraffin wax, together with of polyisobutylene gave no reaction (in spite of the fact thatthe materials This shows the powerful acid-resisting or nitration-resisting properties of the polyisobutylene.
Test- 22 A nitration-resistant lubricating grease was made with the following proportions of materials, in'per cent by weight:
Viscous white oil 70 Light petrolatum wax 16 Paraflln wax 4 'Having an average molecular weight of about 12,000
I to 15,000.
This composition was found to have the following P ysical properties:
A. S. T.M. penetration unworked (at 77 F.) 227 Saybolt viscosity at 210 F seconds 347 Viscosity index About 127 Test 23 unworked (at 77 F.) should usually be between the approximate limits of 100 and 300, and preferably about 150-250; and the viscosity expressed ceived an acid treatment, e. g., by the use of concentrated or fuming sulfuric acid, and preferably should be substantially oil-free (i. e., contaning not more than about 2% of oil), if it has not received an acid treatment. The white oil 'used I should be, as is commonly meant by that term,
and white oil (together with paraflin wax, if any in seconds Saybolt Universal at 210 F. should usually be between the approximate limits of 100 and 500, preferably'about 200 to 400. Usually the V. I. (viscosity index) should be above 110 and preferably it should be above 120.
Although polyisobutylene was used in all of the such as an isobutylene-ethylene copolymer made from a mixture containing about or of isobutylene and the balance ethylene.
As indicated above, the petrolatum to be used should be refined to make it light-colored as by clay filtering,- and if desired may also have reis used) may be varied substantially without departing from the fundamental principles of the invention, and the following tableis given to show the general scope of the invention:
Composition ranges (Per cent by weight) Polymer, average mol. wt.:
- 10,000 10-25 12,000 8-20 30,000 7-15 80,000 5-10 White oil 50-85, preferably 60-80 Petrolatum (substantially oil-free) 10-50, preferably 15-30 Paraflin w 0-10 In the above table it is to be understood that only one type of polymer is necessary in any particular composition, but the table showing four different molecular weights is given so that the proper proportion to be used may be determined according to the molecular weight of the polymer being used; if the polymer to be used has an average molecular weight, intermediate the various ones shown, the amount to be used may readily be determined byinterpolation. Ordinarily, the
mathematical product of the. percent of polymer multiplied by the average molecular weight thereof should be at least 100,000, and preferably at least 120,000.
It is not intended that this invention be limited to any of the particular examples which have been given forthe sake of illustration nor unnecessarily by any theories as to the operation of the invention, but only by the appended claims in which it is intended to claim all novelty inherent in the'invention as broadly as the prior art per;
mits- We claim: 1. A chemically-resistant lubricant having approximately the following composition in percent by weight: I
. Percent Mineral white oil 50-85 Petrolatum (light oil-free) 10-50 Paraffin w 0-10 and an amount of substantially saturated ali- -.pl"iatic hydrocarbon polymer selected according to Average mol. wt. of polymer Per cent 10,000 10-25 1&000. .x 30.000 715 80,000 5-10 2. Lubricant according to claim 1 containing polyisobutylene, the mathematical product of the percent of polymer tlmes'the, average molecular weight thereof being at least 120,000;
3. Lubricant according to claim 1 whichwhen subjectedto the bomb explosion test described, does not crush the lead supporting block more than 01inch when tested width concentrated nitric acid alone and a No.8 detonating cap.
4. A nitration-resistant lubricant having approximately the following composition in percent Paraffln w x 0-10 5. A lubricant packing material suitable for pumps handling nitrating acids, which comprises chiefly acid-resistant Blue African asbestos impregnated with a nitration-resistant lubricant defined in claim 1.
DONALD L; WRIGHT. CHARLES w. BOHM'ER, J
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US393370A US2335331A (en) | 1941-05-14 | 1941-05-14 | Lubricant |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US393370A US2335331A (en) | 1941-05-14 | 1941-05-14 | Lubricant |
Publications (1)
Publication Number | Publication Date |
---|---|
US2335331A true US2335331A (en) | 1943-11-30 |
Family
ID=23554420
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US393370A Expired - Lifetime US2335331A (en) | 1941-05-14 | 1941-05-14 | Lubricant |
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Country | Link |
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US (1) | US2335331A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3080330A (en) * | 1959-05-29 | 1963-03-05 | Exxon Research Engineering Co | Rust preventive compositions of paraffinic mineral oil thickened with polyethylene and microcrystalline wax |
US5736490A (en) * | 1993-09-03 | 1998-04-07 | Exxon Research And Engineering Company | Automotive white-oil based lubricant composition |
-
1941
- 1941-05-14 US US393370A patent/US2335331A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3080330A (en) * | 1959-05-29 | 1963-03-05 | Exxon Research Engineering Co | Rust preventive compositions of paraffinic mineral oil thickened with polyethylene and microcrystalline wax |
US5736490A (en) * | 1993-09-03 | 1998-04-07 | Exxon Research And Engineering Company | Automotive white-oil based lubricant composition |
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