US2318196A

US2318196A - Treatment of hydrocarbons

Info

Publication number: US2318196A
Application number: US404388A
Authority: US
Inventors: Joseph A Chenicek
Original assignee: Universal Oil Products Co
Current assignee: Universal Oil Products Co
Priority date: 1941-07-28
Filing date: 1941-07-28
Publication date: 1943-05-04
Anticipated expiration: 1960-05-04

Description

Patented May 4, 1943 main TREATMENT OF HYDROCARBONS Joseph A. Chenicek, Chicago, Ill., assignor to Universal Oil Products Company, a corporation of Delaware Chicago, 111.,

No Drawing. Application July 28, 1941, Serial No. 404,388

. 15 Claims.

of gum and other deterioration products when the gasoline is stored. More particularly, it relates to improvement in the stabilizing effects obtainable by the addition of inhibitors to cracked gasolines.

In one specific embodiment the invention cemprises stabilizing hydrocarbon distillate such as cracked gasoline against deterioration in the presence of oxygen containing gases, by adding thereto a gum inhibitor and an activating compound comprising essentially an amino pyridine.

The use of gum inhibitors to prevent formation of color, gum, and other oxidation products in hydrocarbon distillates such as cracked gasoline is widely practiced. According to my invention, improved results are obtained by adding to the inhibited hydrocarbons a small quantity of a compound which is not itself a gum inhibitor but which enhances the activity or potency of the um inhibitor. According to this invention relatively smaller amounts of the inhibitor can be used to produce the same improvement in storage stability than when the inhibitor is used without the activator. Thus, for example, a considerable quantit of the active inhibitor component normally used can be replaced by the activating compound to produce the same desired storage stability. Another advantage is that with a given quantity of inhibitor a higher induction period is obtainable when the activating compound is added than could be obtained by the addition of an equivalent quantity of the inhibitor itself.

This invention has the advantage in certain instances of permitting the use of relatively smaller quantities of expensive inhibitors by replacing them with smaller quantities of a less expensive activating compound.

In some cases gum inhibitors of relatively great potency are but slightly soluble in gasoline so that sufficient quantity of inhibitor cannot be added to. give the desired protection without the formation' of sediment. In other cases when inhibitors' are added in sufficient quantity to give the necessary protection against deterioration, objectionable discoloration of the gasoline occurs. As a result the commercial utility of the compounds is limited. B means of the present invention it becomes feasible to use many of these compounds as gum inhibitors due to the fact that the desired storage stability is obtainable without using such large quantities of the inhibitor.

Thus, for example, if a given inhibitor could not be used from the practical standpoint in concentrations greater than 0.005% and this percentage would not give a satisfactory gasoline from the standpoint of storage stability. a few thousandths of a per cent of an amino pyridine can be added to the gasoline together with the inhibitor in question and a product of satisfactory storage stability can be obtained.

It is desirable that the amino group of the amino pyridine should be in the 2 position. .The compound can be further substituted by various groups such as, for example, alkyl groups or another amino group. 2-amino pyridine is a good activator. Z-methyl-B-amino pyridine is a repre'sentative of an alkyl'substituted amino pyridine. 2,6 di-arnino pyridine is an example of the diamino substituted compounds. It is understood that any of these compounds can b substituted in other positions although it should be stated that not all of the possible compounds obtainable are necessarily equivalent in their actions. The following examples are given to illustrate the. usefulness of the process:

Example, I

A Pennsylvania gasoline was used for this test. The induction period was obtained by the wellknown oxygen bomb method. The following results were obtained:

- Induction per., min.

'llie gum inhibitorwas a solution of N-bufyl p-anlinophenol.

, It will be oted that the 2,6 diamino pyridine gave no improvement in the induction period unless the inhibitor was present but when added together with the gum inhibitor produced a marked increase in the induction period.

Example II Another Pennsylvania gasoline was used in the following test:

v Induction per., min.

Uninhibited cracked gasoline 215 Uninhibited cracked gasoline+0.01% gum inhibitor 1 475 Uninhibited cracked gasoline+0.01%g1m1 Tb? gum inhibitor was a solution of i\'bulyl IHllllillU' 1on0 It will be noted that as little as 0.005% of.

2-amino pyridine produces a marked increase in the induction period of the inhibited cracked gasoline. When adding 2-amino pyridine to the gasoline without the gum inhibitor being present no improvement was shown in the induction period of the cracked gasoline over that of the uninhibited gasoline, even though quantities of 2-amino pyridine in excess of 0.01% were used.

Example III The same Pennsylvania gasoline used in Example II was employed in the following tests:

Induction per., min. Cracked gasoline+gum inhibitor +0.0005% 2-methyl-6-aminopyridine 505 Cracked gasoline+gum inhibitor +0.005%

2-methyl-6-aminopyridine 535 Cracked gasoline-i-gum inhibitor +0.010%.

2-metlryl-6-aminopyridine 590 T-he gum inhibitor was a solution of N-buiyl p-amino-' phenol.

The addition of as little as 0.005% of 2-methyl- G-amino pyridine improved the induction period substantially when the gum inhibitor was also present. In the same gasoline the addition of more than 0.01% of 2-methyl-6-amino-pyridlne in the absence of gum inhibitor produced no improvement in the storage stability of the cracked gasoline.

I claim as my invention:

1. A method for stabilizing hydrocarbon distillates normally tending to form gum which tillates normally tending to form gum which comprises adding thereto a gum inhibitor and a small but sufiicient amount of a substituted 2-amino-pyridine to increase the potency'of said inhibitor.

6. A method for stabilizing olefinic gasoline which comprises adding thereto a gum inhibitor and a small but sufficient amount of a substituted Z-amino-pyridine to increase the potency of said inhibitor.

'7. A method forstabilizing olefinic gasoline which comprises adding thereto a gum inhibitor and a small but suflicient amount of 2-aminopyridine to increase the potency of said inhibitor.

8. A method for stabilizing olefinic gasoline which comprises adding thereto a gum inhibitor and a small but suflicient amount of 2-methyl-6- amino-pyridine to increase the potency of said inhibitor.

9. A method for stabilizing olefinic gasoline which comprises adding thereto a gum inhibitor and a small but sufficient amount of -2,6-diamino-pyridine to increase the potency of said inhibitor.

10. Motor fuel comprising oleflnic gasoline, a gum inhibitor and a small but sufiicient amount of an amino-pyridine to increase the potency of said, inhibitor.

11. Motor fuel comprising oleflmc gasoline, at

- potency of said inhibitor.

which comprises adding thereto a gum inhibitor 12. Motor fuel comprising olefinicgasoline, gum inhibitor and a small but sumcient amount of a substituted Z-amino-pyridine to increase the potency of said inhibitor.

13. Motor fuel comprising oleflnic gasoline, a gum inhibitor and a small but sufiicient amount of 2-methyl-6-amino pyridine to increase the potency of said inhibitor.

14. Motor fuel comprising olefinic gasoline, a gum inhibitor and a small but suflicient amount of 2,6-di-amino-pyridine to increase the potency of said inhibitor. V

15. Motor fuel comprising olefinic gasoline, a

gum inhibitor and a small but suflicient amountof z-amino-pyridine to increase the potency of said inhibitor.

JOSEPH A. CHENICEK.