US2238862A - Desizing agent - Google Patents
Desizing agent Download PDFInfo
- Publication number
- US2238862A US2238862A US240861A US24086138A US2238862A US 2238862 A US2238862 A US 2238862A US 240861 A US240861 A US 240861A US 24086138 A US24086138 A US 24086138A US 2238862 A US2238862 A US 2238862A
- Authority
- US
- United States
- Prior art keywords
- parts
- salts
- acid
- amylase
- desizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
- C12N9/14—Hydrolases (3)
- C12N9/24—Hydrolases (3) acting on glycosyl compounds (3.2)
- C12N9/2402—Hydrolases (3) acting on glycosyl compounds (3.2) hydrolysing O- and S- glycosyl compounds (3.2.1)
- C12N9/2405—Glucanases
- C12N9/2408—Glucanases acting on alpha -1,4-glucosidic bonds
- C12N9/2411—Amylases
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12N—MICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
- C12N9/00—Enzymes; Proenzymes; Compositions thereof; Processes for preparing, activating, inhibiting, separating or purifying enzymes
- C12N9/96—Stabilising an enzyme by forming an adduct or a composition; Forming enzyme conjugates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
- D06L1/14—De-sizing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
Definitions
- This invention relates to improvements in amylase preparations.
- amylases It is known practice to use for technical purposes. especially ior desizing, amylases. These enzymes are very sensitive towards salts of heavy metals, particularly those of copper and zinc. Even the traces of such metal salts which frequently occur in town water supplies may considerably aflect the action of an enzyme liquor prepared with the water. In the technical application of the amylases there arise considerable disturbances through heavy metals. Such disturbances are especially noteworthy when the amylases are used for removing sizes which contain copper or zinc salts, which is frequently the case since. such metallic salts are often added to the sizing solution to avoid fermentation and.
- salts of the imino-diacetic acid or its substitution products of which the cation does not itself have an injurious action on the amylase must be used, but obviously only such salts of the imino-diacetic acid or its substitution products of which the cation does not itself have an injurious action on the amylase.
- the salts used must be soluble in water. Itis generally sufllcient, however, if the salts are only slightly soluble in water, since the heavy metal compounds which are to be rendered harmless'by the salts are present in the desizing liquor for the most part only in small proportions. There follows a list of compounds which may be used in the invention:
- CHI-COOR- (trimothylaniino-a:a':a-trimrboxylic acid) C H1.
- C O O H CHaC O OH 7 iminodiacetic acid C III.
- C O O H N-methyl-iminodiacetic acid 'HOOCJIIC CHLCOOH V N- CHz-CHrN H nooclnc CHaCOOH ethylenediamine-tetrsacetic acid V I I cracoon N-CHi.
- C O OH JtHu C-hexyl-trime thylamino-a, a, a"-tricarboxylic acid CH.
- C-plienyl-trimothyhmim a, a"-tricarboxylic acid
- ethylenetriaminoacetic acids which are obtained by the reaction of diethylenetriamine with chloracetic acid.
- the aforesaid compounds surpass to a considerable degree the protective agents hitherto added to enzyme preparations; They afford a practically complete protection also, which even remains when the temperature is raised.
- the compounds do not yield with lime salts any disturbing precipitation and are also efiective in very hard Water. They form, for example when used as their salts, mixtures with enzyme preparations that are good durable commercial products; unlike other protective agents they are equal in their effect towards different metals, for example zinc and copper.
- the protective action of the substances in question is available for amylases of any origin, for example in the case of pancreas amylases or bacterial amylases.
- a protective agent is preferably added, for example in the form of its alkali salt, to the amylase preparation during the manufacture of the latter.
- the enzyme preparation may also receive otherwise usualadditions such as hufler substances, stabilising agents and the like.
- a desizing agent of very good effect which is insensitive to the traces of-copper and zinc presentinthe usual'town water supply, is obtained by mixing 5 parts by weight of dry pancreas (Willstfitter and; Waldschmidt-Ieitz, Hoppe-Seyler Zs. r. physiol. Chemie, Bd. 125,150), 92 parts by weight of'sodium cbloride,'2 parts by weight of sodium' salt of .trimethylamine- :':"-tricarboxylic acid and .8- part by weight of primary sodium phosphate.
- dry pancreas Willstfitter and; Waldschmidt-Ieitz, Hoppe-Seyler Zs. r. physiol. Chemie, Bd. 125,150
- 92 parts by weight of'sodium cbloride 92 parts by weight of'sodium cbloride
- a desizing gent which retains its activity metal salts consists 014.5 parts of dry amylase preparation made from Bacillus mesentericus,
- a desizing agent is made by mixing 4 parts of dry pig pancreas, ,2 parts of calcium iormate, 86 parts of sodium chloride, 5 parts of anhydrous sodium sulphate and 3 parts of potassium salt of acid.
- a desizing agent consists of 6 parts of dry pig pancreas, 2 parts of primary sodium phosphate, 90 parts or sodium chloride and'4 parts of sodium iminodiacetate.
- sodium imino-diacetate there may be used, for example, an alkali salt of the N-methyl- -or N-ethyliminodiacetic acid or of the N-(ortho-carboxyphenyl) imino-diacetic acid or of the C,C'-dimethyl-trimethylamine-e:'2m"- tricarboxylic acid and the like compounds.
- alkali salts other watersoluble salts may be used, for example ammonium salts or salts of organic bases; also mixtures of several such substances may be used.
- a d'esizing bath is made by dissolving 5 parts of malt amylase and .5 part of ethylenediaminetet'racetic acid in 1000 parts of water at about '50v C.
- the pH-value is adjusted to about 5.
- the enzyme preparations used may 35.
- a desizing agent which comprises amylase and'a water-soluble compound of the formula:
- R1 to Rs stand for hydrogen, an aliphatic, 'cycloaliphatic or aromatic residue and K for a cation which does not disturb the action of the amylase.
- Adesizing agent comprising amylase and a water soluble alkali metal salt of trimethyl trimethylaminea a '-tricarb oxylic I comprises amylase
Description
w Patented Apr. 15,1941
' Wilhelm Nengebauer, mam-Bum, Germany, assignmto Kalle It 00. Aktiengea'ellsells-It, Wieabaden-Biebrleh, cm,
s. Drawing. Application November 1c, 1933, Se-
rlal No. 240,861. In Germany December 1,
This invention relates to improvements in amylase preparations.
It is known practice to use for technical purposes. especially ior desizing, amylases. These enzymes are very sensitive towards salts of heavy metals, particularly those of copper and zinc. Even the traces of such metal salts which frequently occur in town water supplies may considerably aflect the action of an enzyme liquor prepared with the water. In the technical application of the amylases there arise considerable disturbances through heavy metals. Such disturbances are especially noteworthy when the amylases are used for removing sizes which contain copper or zinc salts, which is frequently the case since. such metallic salts are often added to the sizing solution to avoid fermentation and.
putrefaction phenomena.
It has been proposed to add to the amylase preparations protective agents of various kinds. However, these agents do not afford complete protection for the amylases against poisoning by heavy metals. In some cases the activity of the "protective agent is diminished by heat or the agent produces troublesome precipitations by 'the action of lime salts; in other cases good durable mixtures of the enzyme preparation with the protective agent cannot be attained. 1
According to the invention protection of amylases is attained in an especially advanacid groups. Such compounds correspond with the general formula:
ccoon o-coon in which R1 in Rs stand for hydrogen, an ch- 5 Claims. (c1. its-s4) phatic or a cycloaliphatic residue or an aromaticresidue. It is advantageous to use compounds in which merely theihydrogen atom attached to the nitrogen atom of the imino-diacetic acid is exchanged for a substituent.
Instead of the said acids themselves salts thereof may be used, but obviously only such salts of the imino-diacetic acid or its substitution products of which the cation does not itself have an injurious action on the amylase. Moreover, the salts used must be soluble in water. Itis generally sufllcient, however, if the salts are only slightly soluble in water, since the heavy metal compounds which are to be rendered harmless'by the salts are present in the desizing liquor for the most part only in small proportions. There follows a list of compounds which may be used in the invention:
' CHLCOOH Ncn,.coon
CHI-COOR- (trimothylaniino-a:a':a-trimrboxylic acid) C H1. C O O H CHaC O OH 7 iminodiacetic acid C III. C O O H HzCN 7 CH1. C O O H N-methyl-iminodiacetic acid 'HOOCJIIC CHLCOOH V N- CHz-CHrN H nooclnc CHaCOOH ethylenediamine-tetrsacetic acid V I I cracoon N-CHi. C O OH CH. C O OH JtHu C-hexyl-trime thylamino-a, a, a"-tricarboxylic acid CH. C 0 OH N-CHaC 0 OH CR0 0 OH C-plienyl-trimothyhmim, a, a"-tricarboxylic acid CHpCOOH N-C :.COOH
ethylenetriaminoacetic acids which are obtained by the reaction of diethylenetriamine with chloracetic acid. The aforesaid compounds surpass to a considerable degree the protective agents hitherto added to enzyme preparations; They afford a practically complete protection also, which even remains when the temperature is raised. The compounds do not yield with lime salts any disturbing precipitation and are also efiective in very hard Water. They form, for example when used as their salts, mixtures with enzyme preparations that are good durable commercial products; unlike other protective agents they are equal in their effect towards different metals, for example zinc and copper. The protective action of the substances in question is available for amylases of any origin, for example in the case of pancreas amylases or bacterial amylases. A protective agent is preferably added, for example in the form of its alkali salt, to the amylase preparation during the manufacture of the latter. The enzyme preparation may also receive otherwise usualadditions such as hufler substances, stabilising agents and the like.
. The following examples illustrate the invention, the parts being' by weight:
1. A desizing agent of very good effect, which is insensitive to the traces of-copper and zinc presentinthe usual'town water supply, is obtained by mixing 5 parts by weight of dry pancreas (Willstfitter and; Waldschmidt-Ieitz, Hoppe-Seyler Zs. r. physiol. Chemie, Bd. 125,150), 92 parts by weight of'sodium cbloride,'2 parts by weight of sodium' salt of .trimethylamine- :':"-tricarboxylic acid and .8- part by weight of primary sodium phosphate. v
2. 100 parts of cotton fabric carrying a starch size which contains zinc chloride are desized at 45 C. with 500 parts of a solution adjusted to pH=7 and containing per liter .1 gram of dry pancreas, 2 grams of sodium chloride and .2 grams of sodium salt of t1'imethy1amine-:'::a"- tricarboxylic acid. After one.hour complete desizing has generally occurred.
3. A desizing gent which retains its activity metal salts consists 014.5 parts of dry amylase preparation made from Bacillus mesentericus,
7 46 parts of sodium chloride, 45.5 parts 0! anhydrous sodium sulphate, 1.5 parts or primary sodium phosphate and 2.5 parts of sodium ethylene dlamine tetracetate.
4. A desizing agent is made by mixing 4 parts of dry pig pancreas, ,2 parts of calcium iormate, 86 parts of sodium chloride, 5 parts of anhydrous sodium sulphate and 3 parts of potassium salt of acid.
5. A desizing agent consists of 6 parts of dry pig pancreas, 2 parts of primary sodium phosphate, 90 parts or sodium chloride and'4 parts of sodium iminodiacetate.
Instead of the sodium imino-diacetate there may be used, for example, an alkali salt of the N-methyl- -or N-ethyliminodiacetic acid or of the N-(ortho-carboxyphenyl) imino-diacetic acid or of the C,C'-dimethyl-trimethylamine-e:'2m"- tricarboxylic acid and the like compounds. Moreover, instead of the alkali salts other watersoluble salts may be used, for example ammonium salts or salts of organic bases; also mixtures of several such substances may be used.
6. A d'esizing bath is made by dissolving 5 parts of malt amylase and .5 part of ethylenediaminetet'racetic acid in 1000 parts of water at about '50v C. The pH-value is adjusted to about 5. Where in the examples special instructions are not found, the enzyme preparations used may 35.
be of the usual commercial composition. Highly concentrated preparations are especially suitable.
I claim:
1. A desizing agent which comprises amylase and'a water-soluble compound of the formula:
wherein R1 to Rs stand for hydrogen, an aliphatic, 'cycloaliphatic or aromatic residue and K for a cation which does not disturb the action of the amylase. 2. A desizing agent which and a water-soluble compound of the formula:
' "crncoox 77 wherein R stands for hydrogen, an aliphatic,
cycloaliphatic or aromatic residue and X for a cationwhich does not disturb the action of the' amylase.
water soluble alkali 3. Adesizing agent comprising amylase and a water soluble alkali metal salt of trimethyl trimethylaminea a '-tricarb oxylic I comprises amylase
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEK0148713 | 1937-12-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
US2238862A true US2238862A (en) | 1941-04-15 |
Family
ID=7251754
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US240861A Expired - Lifetime US2238862A (en) | 1937-12-01 | 1938-11-16 | Desizing agent |
Country Status (5)
Country | Link |
---|---|
US (1) | US2238862A (en) |
CH (1) | CH208732A (en) |
FR (1) | FR845587A (en) |
GB (1) | GB521468A (en) |
NL (1) | NL49910C (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2974001A (en) * | 1957-07-20 | 1961-03-07 | Kalle Ag | Process and compositions for enzymatic desizing and bleaching of textiles |
US3071517A (en) * | 1954-08-20 | 1963-01-01 | Keimdiaet G M B H | Process of producing ferment preparations and products obtained thereby |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE742617C (en) * | 1941-03-28 | 1943-12-14 | Chem Fab Joh A Benckiser G M B | Process for preventing resin precipitations in paper manufacture |
-
0
- NL NL49910D patent/NL49910C/xx active
-
1938
- 1938-10-17 CH CH208732D patent/CH208732A/en unknown
- 1938-11-04 FR FR845587D patent/FR845587A/en not_active Expired
- 1938-11-16 US US240861A patent/US2238862A/en not_active Expired - Lifetime
- 1938-11-21 GB GB33786/38A patent/GB521468A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3071517A (en) * | 1954-08-20 | 1963-01-01 | Keimdiaet G M B H | Process of producing ferment preparations and products obtained thereby |
US2974001A (en) * | 1957-07-20 | 1961-03-07 | Kalle Ag | Process and compositions for enzymatic desizing and bleaching of textiles |
Also Published As
Publication number | Publication date |
---|---|
CH208732A (en) | 1940-02-29 |
FR845587A (en) | 1939-08-28 |
NL49910C (en) | |
GB521468A (en) | 1940-05-22 |
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