US2189017A - Treatment of textile and other materials - Google Patents
Treatment of textile and other materials Download PDFInfo
- Publication number
- US2189017A US2189017A US126383A US12638337A US2189017A US 2189017 A US2189017 A US 2189017A US 126383 A US126383 A US 126383A US 12638337 A US12638337 A US 12638337A US 2189017 A US2189017 A US 2189017A
- Authority
- US
- United States
- Prior art keywords
- resist
- materials
- resists
- local
- textile
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/12—Reserving parts of the material before dyeing or printing ; Locally decreasing dye affinity by chemical means
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S524/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S524/925—Natural rubber compositions having nonreactive materials, i.e. NRM, other than: carbon, silicon dioxide, glass titanium dioxide, water, hydrocarbon or halohydrocarbon
Definitions
- these bodies are polymerisation products of aliphatic compounds containing one or more vinyl linkages, for example chlorinated vinyl acetylenes and polyvinyl chloride, poly-styrene and similar polymerised aromatic hydrocarbons containing one or more vinyl groups, highly chlorinated diphenyls or other diaryls, chlorinated naphthalenes or the like.
- I may employ tetrachlornaphthalene or the substances known commercially as chlorinated rubber, electrog'um (chlorinated rubber with a chlorine content of 64 to 66% suppliedby Soeit dElectrochimie dUgine) and polymerized chloroprene.
- these substances are highly water-resistant, preferably have a high melting point, and in particular a melting point above- 90 C. and preferably above 100 0., are
- benzene, toluene or xylene and/or in the relatively non-polar chlorinated hydrocarbon type of solvent, such as carbon tetrachloride, pentaand hexa-chlorethanes and perchlorethylene, and have, either alone or when mixed with suitable plasticisers, film-forming properties.
- solvent such as carbon tetrachloride, pentaand hexa-chlorethanes and perchlorethylene
- those which'are soluble in the non-polar or relatively non-polar type of solvents may be considered as universal resists for application to all types of textile material in processes wherein aqueous liquors are employed in the application of the colour, dis- 55 charge, etc. Thus, they may be applied, the local effect obtained, and the resist or reserve removed without detriment to the textile material, with all the commercial types of textile material, in-- eluding cotton or oher natural cellulosie fibres,
- the resists or reserves of the present invention may be employed to obtain local effects in a wide variety of processes including colouring with 8 basic, acid, direct, vat or anthraquinone colours, according to the colour desired and according to the nature of the fibre or fibres, in the production of discharge effects with reduction or oxidation discharges, for example hydrosulphites, formaldehyde hydrosulphites, formaldehyde sulphoxylates, stannous chloride, chlorates and the like, and the production of local lustre effects upon cellulose acetate artificial silk and other materials capable of being delustred.
- a cellulose acetate artificial silk reserved with the aid of the reserves of the present invention may be treated in a boiling or nearly boiling dilute solution of soap to obtain delustring on theunreserved portions while the reserved portions retain their original lustre.
- manyof the above processes notably in the dyeing of cotton or other natural or regenerated cellulosic materials with substantive and vat colours, in the dyeing of wool and silk, and in the dyeing of cellulose acetate artificial silk, it has hitherto been impossible to obtain local effects by bath treatments owing to the necessity of carrying out the bath treatments at relatively high temperatures, and accordingly the local effects in these operations have usually been effected by printing methods.
- Colourations ob tained by the present invention may in general be faster than those obtainable by printing methods and may, in fact, have the characteristic fastness of the dyeing methods while giving the variety of efiects obtainable by printing methods. Similarly, by printing methods it is often difficult to obtain good white discharges. The present method likewise gives improved effects in this respect. Again in the local delustring of cellulose acetate artificial silk, the local eflect had previously either to be obtained by using steam as the delustring agent, which is not so effective or uniform as hot aqueous liquors, or else the fabric had to be delustred uniformly and relustred locally.
- the reserves or resists of the present invention may be applied in solution in organic solvents, for example benzene, toluene, monochlorbenzene, dichlorbenzene, monochlornaphthalene, perchlorethylene, carbon tetrachloride or the like, and may be applied by any suitable metliiid of local application, for instance by printing rollers, engraved plates, by means of stencils or by screen printing, e. g. with a silk screen, and by aerographic methods.
- organic solvents for example benzene, toluene, monochlorbenzene, dichlorbenzene, monochlornaphthalene, perchlorethylene, carbon tetrachloride or the like.
- the fabric or other material may be dried at about 50 0., then subjected to the dyew g odichlorbenzene ing', discharging, delustring or other process, again dried, say at 40-50 0., and finally treated to remove the resist or reserve, for example by means of solution in one of the organic solvents mentioned above.
- a highly chlorinated naphthalene or similar substance may serve as a plasticiser for another resist according to the inventiomior example chlorinated rubber.
- the process of the present invention is of particular value in the treatment of fabrics, but it is of course also, applicable to the production of local effects on other materials, e. 'g. yarns, foils, films and the like.
- a resist may be intermittently applied to yarns during their travel from one point to another by intermittently bringing them into contact with a roller supplied with. the resist, and the yarns so treated may then be immersed in adye bathjsothat the portions free from resist are dyed. On removal of the resist intermittently coloured yarns are thus obtained.
- Example 4 A cellulose acetate fabric is printed in a pattern with the resist specified in Example 2, and is then treated for about an hour in a 25% aqueous soap solution ata temperature of about 90 C. The fabric is then removed from the :bath, washed, dried and treated with a suitable solventto remove the resist. A locally delustred fabric is thus obtained.
- Example 5v A cellulose acetate fabric is printed in a pattern with the resist specified 'in Example 1, and
Description
Patented Feb. 6, 1940 TREATMENT OF TEXTILE AND OTHER. MATERIALS Georges Bivat, Lyon, France,assignor to Henry Dreyfus, London, England No Drawing. Application February 18, 1937, Serial No. 126,383. In- France February 19,
1 Claim.
available by this method. In particular, these bodies are polymerisation products of aliphatic compounds containing one or more vinyl linkages, for example chlorinated vinyl acetylenes and polyvinyl chloride, poly-styrene and similar polymerised aromatic hydrocarbons containing one or more vinyl groups, highly chlorinated diphenyls or other diaryls, chlorinated naphthalenes or the like. Thus, for example, I may employ tetrachlornaphthalene or the substances known commercially as chlorinated rubber, electrog'um (chlorinated rubber with a chlorine content of 64 to 66% suppliedby Soeit dElectrochimie dUgine) and polymerized chloroprene. Considered generically, these substances are highly water-resistant, preferably have a high melting point, and in particular a melting point above- 90 C. and preferably above 100 0., are
soluble in organic solvents and are preferably soluble in the hydrocarbon type of solvent, for
example benzene, toluene or xylene, and/or in the relatively non-polar chlorinated hydrocarbon type of solvent, such as carbon tetrachloride, pentaand hexa-chlorethanes and perchlorethylene, and have, either alone or when mixed with suitable plasticisers, film-forming properties.
These new resists or reserves present substantial advantages over the starch or gum type of resists hitherto known, in that they are much 4 more resistant to the action of water, and particularly hot aqueous liquors, and have the advantage over the known wax resists such as stearin or other animal or vegetable waxes that they have a higher melting point and therefore a e capable of being employed to obtain-resist or r serve eflects in the application of colours, discharges, etc. which necessitate the use of hot aqueous liquors. Furthermore, those which'are soluble in the non-polar or relatively non-polar type of solvents may be considered as universal resists for application to all types of textile material in processes wherein aqueous liquors are employed in the application of the colour, dis- 55 charge, etc. Thus, they may be applied, the local effect obtained, and the resist or reserve removed without detriment to the textile material, with all the commercial types of textile material, in-- eluding cotton or oher natural cellulosie fibres,
viscose artificial silk or other regenerated cellu- 1056s,, wool, silk, or other animal or vegetable fibres, as well as cellulose acetate artificial silk. The resists or reserves of the present invention may be employed to obtain local effects in a wide variety of processes including colouring with 8 basic, acid, direct, vat or anthraquinone colours, according to the colour desired and according to the nature of the fibre or fibres, in the production of discharge effects with reduction or oxidation discharges, for example hydrosulphites, formaldehyde hydrosulphites, formaldehyde sulphoxylates, stannous chloride, chlorates and the like, and the production of local lustre effects upon cellulose acetate artificial silk and other materials capable of being delustred. Thus, for example, in the last process a cellulose acetate artificial silk reserved with the aid of the reserves of the present invention may be treated in a boiling or nearly boiling dilute solution of soap to obtain delustring on theunreserved portions while the reserved portions retain their original lustre. In manyof the above processes, notably in the dyeing of cotton or other natural or regenerated cellulosic materials with substantive and vat colours, in the dyeing of wool and silk, and in the dyeing of cellulose acetate artificial silk, it has hitherto been impossible to obtain local effects by bath treatments owing to the necessity of carrying out the bath treatments at relatively high temperatures, and accordingly the local effects in these operations have usually been effected by printing methods. Colourations ob tained by the present invention may in general be faster than those obtainable by printing methods and may, in fact, have the characteristic fastness of the dyeing methods while giving the variety of efiects obtainable by printing methods. Similarly, by printing methods it is often difficult to obtain good white discharges. The present method likewise gives improved effects in this respect. Again in the local delustring of cellulose acetate artificial silk, the local eflect had previously either to be obtained by using steam as the delustring agent, which is not so effective or uniform as hot aqueous liquors, or else the fabric had to be delustred uniformly and relustred locally.
The reserves or resists of the present invention may be applied in solution in organic solvents, for example benzene, toluene, monochlorbenzene, dichlorbenzene, monochlornaphthalene, perchlorethylene, carbon tetrachloride or the like, and may be applied by any suitable metliiid of local application, for instance by printing rollers, engraved plates, by means of stencils or by screen printing, e. g. with a silk screen, and by aerographic methods. After application of the resist or reserve the fabric or other material may be dried at about 50 0., then subjected to the dyew g odichlorbenzene ing', discharging, delustring or other process, again dried, say at 40-50 0., and finally treated to remove the resist or reserve, for example by means of solution in one of the organic solvents mentioned above.
I As already indicated, it is sometimes desirable for the purpose of obtaining resists which are less brittle or form better films than the parent substance of the resist toadd plasticisers, for exam-- ple tricresyl phosphate or other triarylv phosphates, animal or vegetable oils and terebihthine. v
In some cases a highly chlorinated naphthalene or similar substance may serve as a plasticiser for another resist according to the inventiomior example chlorinated rubber.
The process of the present invention is of particular value in the treatment of fabrics, but it is of course also, applicable to the production of local effects on other materials, e. 'g. yarns, foils, films and the like. Thus a resist may be intermittently applied to yarns during their travel from one point to another by intermittently bringing them into contact with a roller supplied with. the resist, and the yarns so treated may then be immersed in adye bathjsothat the portions free from resist are dyed. On removal of the resist intermittently coloured yarns are thus obtained.
The following examples illustrate the resists to be used in accordance with the invention:
' Examples 1 1,
Parts by weisht Chlorinated rubber 100' Tetrachlornaphthalene 250-300 'Orthodichlorbenzene 300 a-monochlornaphthalene 300 The following are examples of processes for the production of local effects using the resists of the present invention,
Example 4 A cellulose acetate fabric is printed in a pattern with the resist specified in Example 2, and is then treated for about an hour in a 25% aqueous soap solution ata temperature of about 90 C. The fabric is then removed from the :bath, washed, dried and treated with a suitable solventto remove the resist. A locally delustred fabric is thus obtained.
' Example 5v A cellulose acetate fabric is printed in a pattern with the resist specified 'in Example 1, and
is thendyed in an aqueous bath containing a suitable cellulose acetate dyestu'fi, for example 4-nitro-2-methoxy-benzene=l azo 4 -diniethylamino benzene. It is then removed from the bath, washed, dried and treated to remove theresist.
A fabric exhibiting a coloured pattern is thus obtained. Having described my invention whatI desire to secure by Letters Patent is: f 'i {f Process for the productionof local colored ei-' fects on fabrics of cellulose acetate, which comprises locally printing'the materials with'a resist consisting substantially of 250-400f pa'rts of tricresyl phosphate, immersing the material for chlorinated rubber, 325-250 parts of toluene,.325-
250 parts of o-dichlorbenzene and 100 parts of;
a substantial period of time in'a hot aqueous dye liquid to dye the portions free "from the resist and then removing the resist'by means of an organic solvent. I
. GEORGES RIVAT.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR2189017X | 1936-02-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
US2189017A true US2189017A (en) | 1940-02-06 |
Family
ID=9684418
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US126383A Expired - Lifetime US2189017A (en) | 1936-02-19 | 1937-02-18 | Treatment of textile and other materials |
Country Status (1)
Country | Link |
---|---|
US (1) | US2189017A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5118322A (en) * | 1990-07-31 | 1992-06-02 | Eric Wasinger | Ozone decolorization of garments |
US5554195A (en) * | 1994-06-03 | 1996-09-10 | Sandoz Ltd. | Process for the production of resist prints |
US5625915A (en) * | 1993-05-14 | 1997-05-06 | Cyclo3Pss Textile Systems, Inc. | Laundry ozone injection system |
US5645608A (en) * | 1996-01-03 | 1997-07-08 | Cooper; Theodore R. | Cold water wash method |
US6006387A (en) * | 1995-11-30 | 1999-12-28 | Cyclo3Pss Textile Systems, Inc. | Cold water ozone disinfection |
US6458398B1 (en) | 1999-10-18 | 2002-10-01 | Eco Pure Food Safety Systems, Inc. | Cold water disinfection of foods |
US6685749B1 (en) | 2000-07-20 | 2004-02-03 | Malden Mills Industries, Inc. | Fabrics with surfaces of contrasting colors and/or different contour |
-
1937
- 1937-02-18 US US126383A patent/US2189017A/en not_active Expired - Lifetime
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5118322A (en) * | 1990-07-31 | 1992-06-02 | Eric Wasinger | Ozone decolorization of garments |
US5625915A (en) * | 1993-05-14 | 1997-05-06 | Cyclo3Pss Textile Systems, Inc. | Laundry ozone injection system |
US5554195A (en) * | 1994-06-03 | 1996-09-10 | Sandoz Ltd. | Process for the production of resist prints |
ES2101647A1 (en) * | 1994-06-03 | 1997-07-01 | Sandoz Ag | Process for the production of resist prints |
US6006387A (en) * | 1995-11-30 | 1999-12-28 | Cyclo3Pss Textile Systems, Inc. | Cold water ozone disinfection |
US6115862A (en) * | 1995-11-30 | 2000-09-12 | Cyclo3Pss Textile Systems, Inc. | Cold water ozone disinfection |
US5645608A (en) * | 1996-01-03 | 1997-07-08 | Cooper; Theodore R. | Cold water wash method |
US5763382A (en) * | 1996-01-03 | 1998-06-09 | Cyclo3Pss Textile Systems, Inc. | Cold water wash formula |
US6458398B1 (en) | 1999-10-18 | 2002-10-01 | Eco Pure Food Safety Systems, Inc. | Cold water disinfection of foods |
US6685749B1 (en) | 2000-07-20 | 2004-02-03 | Malden Mills Industries, Inc. | Fabrics with surfaces of contrasting colors and/or different contour |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US2189017A (en) | Treatment of textile and other materials | |
US2031929A (en) | Impregnation of materials | |
US3467484A (en) | Patterned application of benzyl alcohol with or without a resist on nylon fabrics and dyeing the patterned fabric | |
US2923593A (en) | Diethylene glycol diacetate as an assistant in the dyeing of cellulose triacetate | |
US2033976A (en) | Treatment op textile or other | |
US2221232A (en) | Production of crepelike textile webs | |
US2428836A (en) | Printing of cellulose acetate | |
US2619403A (en) | Emulsified volatile hydrocarbon liquids as printing paste thickeners | |
US1825342A (en) | Printed fabric and process of making the same | |
US2200389A (en) | Production and treatment of textile fabrics | |
US1839819A (en) | Extraction of dyestuffs | |
US1984788A (en) | Treatment of textile materials made of or containing organic derivatives of cellulose | |
US1610786A (en) | Fabric with a design and process for making the same | |
US1694466A (en) | Process of obtaining metallic effects on fabrics containing organic derivatives of cellulose | |
US1913410A (en) | Treatment of material containing derivatives of cellulose and product thereof | |
GB490532A (en) | Improvements in or relating to the colouration of textile fabrics | |
US1889045A (en) | Process of embossing fabrics and articles containing organic derivatives of cellulose | |
US2079604A (en) | Treatment of materials | |
US2245123A (en) | Fabric printing | |
US2296379A (en) | Textile material | |
GB340324A (en) | Improvements in the production of artificial materials by wet spinning processes from solutions of organic derivatives of cellulose | |
US1844204A (en) | Treatment of products or goods of or containing cellulose derivatives | |
US1981027A (en) | Textile printing process and composition | |
US1770114A (en) | Composition for and process of delustering artificial silk | |
US1822453A (en) | Printing of fabrics containing organic derivatives of cellulose |