US2162273A - Insulation of magnetic powder for mass cores, in particular for high frequency purposes - Google Patents

Insulation of magnetic powder for mass cores, in particular for high frequency purposes Download PDF

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US2162273A
US2162273A US70219A US7021936A US2162273A US 2162273 A US2162273 A US 2162273A US 70219 A US70219 A US 70219A US 7021936 A US7021936 A US 7021936A US 2162273 A US2162273 A US 2162273A
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high frequency
insulation
cores
insulating
magnetic powder
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US70219A
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Schulze Walter
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ALLG ELEK CITATZ GES
ALLGEMEINE ELEKTRICITATZ GESELLSCHAFT
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ALLG ELEK CITATZ GES
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01FMAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
    • H01F1/00Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
    • H01F1/01Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
    • H01F1/03Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
    • H01F1/12Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
    • H01F1/14Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
    • H01F1/20Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder
    • H01F1/22Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together
    • H01F1/24Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together the particles being insulated
    • H01F1/26Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together the particles being insulated by macromolecular organic substances

Definitions

  • the present invention relates to magnetic cores especially those utilized in connection with high frequency work which cores are composed of finely divided magnetic materiah In particu- 6 lar the invention is concerned with the substance utilized for insulating the individual particles of the magnetic material.
  • the invention is fully described in connection with the drawing wherein Figs. 1, 2 and 3 show various forms which the cores take and Fig. 4 is an enlarged view of two of the magnetic particles showing the coating applied in accordance withthe invention.
  • Mass cores in particular those for high frequency purposes, require asXine a subdivision as possible of the magnetic powder and such an insulation of the individual magnetic particles from each other that the pressed magnet core possesses in particular those properties,which are the most important for loading coil cores,
  • Such an insulating substance must, furthermore, be so composed that it shows, in particular in the field of high frequency waves, only slight dielectric losses, since as is known, the dielectric losses increase with the third power of the frequency. It has already been proposed to use high quality insulating substances such as the known ceramic ones; these have, however, the disadvantage that in consequence of their brittleness, they easily break when subjected to pressure stresses, so that in this way the envelopes of the magnetic particles are destroyedbn the pressing of the cores 'and thus the insulation is partially counteracted.
  • mass cores in particular for high frequency purposes, that the layer round the individual magnetic particles is thin and uniform, to that the density of the magnetic particles and thus the permeability, is kept high.
  • the mass cores which, as suggested, are insulated from each other by a film of oxide; oxide films are, however, bad dielectrics and consequently cause a sharp increase of the losses.
  • the in sulating substance must be capable of hardenln that is, be converted by subsequent heat treat ments into a practically insoluble form so that 10 the insulating process can be frequently repeated.
  • the object of the invention is to provide an insulating substance which, without any addi- 25 tion which is to assist one or the other effect, has all the above-mentioned favorable properties and is consequently adapted in particular as an insulating substancefor mass cores for high frequency purposes.
  • Such an insulating substance for magnetic powder of mass cores for high frequency purposes is, according to the invention, amber varnish.
  • amber varnishes 35 which give very thin elastic but nevertheless pressure resisting films which adhere very firmly on iron.
  • amber belongs to the insulating substances having very good dielectric properties.
  • a further favorable property of 40 amber varnishes is that they satisfactorily comply with the thermal conditions to which cores are subjected.
  • the thin varnish films obtained, which coat the magnetic particles are made practically insoluble.
  • Amber solutions have, as compared with the use of finely powdered amber combined with a liquid medium, the advantage that they are extremely thinly 50 liquid and ensure in addition to an extremely thin and tough film, a perfectly unifonn 111;. sulating layer.
  • the iron powder insulated with 55 an amber varnish and cured can for example be mixed before pressing, with a substance of higher mastic strength; such a substance is for example polystyrol, since it also shows extremely small losses with high frequency.
  • a substance of higher mastic strength such a substance is for example polystyrol, since it also shows extremely small losses with high frequency.
  • Core material for inductance devices and the like said core material being formed of particles of magnetic material, each of said particles being provided with two distinct relatively thin coatings of insulation material, the first coating comprising an amber varnish, the second coating comprising polystyrol,

Description

i June 13, .1939. V w. SCHULZE 2,162,273 OF MAGNET FOR INS T POWDER MASS CORBS. IN
A CULAR FOR H F UENCY PURPOSES Filed March 1936 Fi .1 i
INVENTOR W. SCH U 25 ATTORNEY Patented June 13, 1939 UNITED STATES PATENT OFFICE Walter Schulze, Berlin, Germany, assignor to Allgemelne Elektrlcltatz Gesellschaft, Berlin, Germany, a corporation of Germany Application March 23, was, Serial No. 120,219 In Germany March 27, 1935 r 1 Claim.
The present invention relates to magnetic cores especially those utilized in connection with high frequency work which cores are composed of finely divided magnetic materiah In particu- 6 lar the invention is concerned with the substance utilized for insulating the individual particles of the magnetic material. The invention is fully described in connection with the drawing wherein Figs. 1, 2 and 3 show various forms which the cores take and Fig. 4 is an enlarged view of two of the magnetic particles showing the coating applied in accordance withthe invention.
Mass cores, in particular those for high frequency purposes, require asXine a subdivision as possible of the magnetic powder and such an insulation of the individual magnetic particles from each other that the pressed magnet core possesses in particular those properties,which are the most important for loading coil cores,
namely, a high capacity of electrical insulation, great mechanical strength, and a high capacity of resistance with temperature variations. These properties are, in the main, dependent upon the insulating material with which each individual magnetic particlqis surrounded. A whole series of such insulating substances has already been proposed, which substances fulfill certain of these required conditions.
Such an insulating substance must, furthermore, be so composed that it shows, in particular in the field of high frequency waves, only slight dielectric losses, since as is known, the dielectric losses increase with the third power of the frequency. It has already been proposed to use high quality insulating substances such as the known ceramic ones; these have, however, the disadvantage that in consequence of their brittleness, they easily break when subjected to pressure stresses, so that in this way the envelopes of the magnetic particles are destroyedbn the pressing of the cores 'and thus the insulation is partially counteracted.
It must, furthermore, be required of an insulating substance for mass cores, in particular for high frequency purposes, that the layer round the individual magnetic particles is thin and uniform, to that the density of the magnetic particles and thus the permeability, is kept high. This condition is fulfilled by the mass cores which, as suggested, are insulated from each other by a film of oxide; oxide films are, however, bad dielectrics and consequently cause a sharp increase of the losses. Furthermore, it must be required of such insulating substances that their insulating layer has good adhesive properties with respect to the magnetic particles, and furthermore that the insulating layer besides hav ing great elasticity is as hard and resistant possible to mechanical stresses, that is, it must be resistant to pressure and be tough, since the 5 individual particles mustin the pressing withstand a shearing effect. In addition, the in sulating substance must be capable of hardenln that is, be converted by subsequent heat treat ments into a practically insoluble form so that 10 the insulating process can be frequently repeated.
Hitherto, no insulating agents have been known by the use of which all these properties M can be simultaneously attained. The majorityf of insulating substances have, in the case of high frequency, a considerable phase diiference, so that the dielectric losses alone form an appre ciable proportion of the total loss. The adhesiveness on iron is, with most insulating substances, not very high; it has sometimes been 20 proposed to add certain products to particular insulating substances in order to increase the adhesive eflfect.
The object of the invention is to provide an insulating substance which, without any addi- 25 tion which is to assist one or the other effect, has all the above-mentioned favorable properties and is consequently adapted in particular as an insulating substancefor mass cores for high frequency purposes. Such an insulating substance for magnetic powder of mass cores for high frequency purposes is, according to the invention, amber varnish.
It has been found possible to dissolve amber unmelted, and to thereby obtain amber varnishes 35 which give very thin elastic but nevertheless pressure resisting films which adhere very firmly on iron. As is known, amber belongs to the insulating substances having very good dielectric properties. A further favorable property of 40 amber varnishes is that they satisfactorily comply with the thermal conditions to which cores are subjected. By means of a curing process at high temperatures, the thin varnish films obtained, which coat the magnetic particles, are made practically insoluble. Amber solutions have, as compared with the use of finely powdered amber combined with a liquid medium, the advantage that they are extremely thinly 50 liquid and ensure in addition to an extremely thin and tough film, a perfectly unifonn 111;. sulating layer.
In order to improve the amber varnish in its mastic strength, the iron powder insulated with 55 an amber varnish and cured can for example be mixed before pressing, with a substance of higher mastic strength; such a substance is for example polystyrol, since it also shows extremely small losses with high frequency. This is shown by Fig. 4 of the drawing, wherein the outer coating 2 may comprise polystyrol and the inner coating 3 the amber varnish.
I claim:
Core material for inductance devices and the like, said core material being formed of particles of magnetic material, each of said particles being provided with two distinct relatively thin coatings of insulation material, the first coating comprising an amber varnish, the second coating comprising polystyrol,
WALTER SCHULZE.
US70219A 1935-03-27 1936-03-23 Insulation of magnetic powder for mass cores, in particular for high frequency purposes Expired - Lifetime US2162273A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2451444A (en) * 1946-04-05 1948-10-12 Jefferson Standard Broadcastin Adjustable wave coupling system
DE966314C (en) * 1949-08-26 1957-07-25 Standard Elek K Ag Process for the production of mass cores from magnetizable powder particles raised with an insulating material of high softening temperature
US2890968A (en) * 1955-06-02 1959-06-16 Rca Corp Electrostatic printing process and developer composition therefor
US5069972A (en) * 1988-09-12 1991-12-03 Versic Ronald J Moldable microcapsule that contains a high percentage of solid core material, and method of manufacture thereof
US5211896A (en) * 1991-06-07 1993-05-18 General Motors Corporation Composite iron material
US5271891A (en) * 1992-07-20 1993-12-21 General Motors Corporation Method of sintering using polyphenylene oxide coated powdered metal
US5982073A (en) * 1997-12-16 1999-11-09 Materials Innovation, Inc. Low core loss, well-bonded soft magnetic parts

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2451444A (en) * 1946-04-05 1948-10-12 Jefferson Standard Broadcastin Adjustable wave coupling system
DE966314C (en) * 1949-08-26 1957-07-25 Standard Elek K Ag Process for the production of mass cores from magnetizable powder particles raised with an insulating material of high softening temperature
US2890968A (en) * 1955-06-02 1959-06-16 Rca Corp Electrostatic printing process and developer composition therefor
US5069972A (en) * 1988-09-12 1991-12-03 Versic Ronald J Moldable microcapsule that contains a high percentage of solid core material, and method of manufacture thereof
US5591373A (en) * 1991-06-07 1997-01-07 General Motors Corporation Composite iron material
US5211896A (en) * 1991-06-07 1993-05-18 General Motors Corporation Composite iron material
US5271891A (en) * 1992-07-20 1993-12-21 General Motors Corporation Method of sintering using polyphenylene oxide coated powdered metal
US5982073A (en) * 1997-12-16 1999-11-09 Materials Innovation, Inc. Low core loss, well-bonded soft magnetic parts
US6129790A (en) * 1997-12-16 2000-10-10 Materials Innovation, Inc. Low core loss, well-bonded soft magnetic
US6251514B1 (en) 1997-12-16 2001-06-26 Materials Innovation, Inc. Ferromagnetic powder for low core loss, well-bonded parts, parts made therefrom and methods for producing same
US6309748B1 (en) 1997-12-16 2001-10-30 David S. Lashmore Ferromagnetic powder for low core loss parts
US6340397B1 (en) 1997-12-16 2002-01-22 Materials Innovation, Inc. Method for making low core loss, well-bonded, soft magnetic parts
US6342108B1 (en) 1997-12-16 2002-01-29 Materials Innovation, Inc. Low core loss, well-bonded soft magnetic stator, rotor, and armature

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