US2148680A - Catalyst for use in the oxidation of ammonia - Google Patents
Catalyst for use in the oxidation of ammonia Download PDFInfo
- Publication number
- US2148680A US2148680A US72661A US7266136A US2148680A US 2148680 A US2148680 A US 2148680A US 72661 A US72661 A US 72661A US 7266136 A US7266136 A US 7266136A US 2148680 A US2148680 A US 2148680A
- Authority
- US
- United States
- Prior art keywords
- platinum
- wires
- rhodium
- alloys
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title description 15
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title description 12
- 229910021529 ammonia Inorganic materials 0.000 title description 6
- 230000003647 oxidation Effects 0.000 title description 4
- 238000007254 oxidation reaction Methods 0.000 title description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 36
- 229910052697 platinum Inorganic materials 0.000 description 17
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 description 11
- HWLDNSXPUQTBOD-UHFFFAOYSA-N platinum-iridium alloy Chemical class [Ir].[Pt] HWLDNSXPUQTBOD-UHFFFAOYSA-N 0.000 description 10
- 229910045601 alloy Inorganic materials 0.000 description 8
- 239000000956 alloy Substances 0.000 description 8
- 229910052703 rhodium Inorganic materials 0.000 description 7
- 239000010948 rhodium Substances 0.000 description 7
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 7
- 229910000629 Rh alloy Inorganic materials 0.000 description 6
- 229910001260 Pt alloy Inorganic materials 0.000 description 5
- 229910052741 iridium Inorganic materials 0.000 description 5
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 5
- 229910000566 Platinum-iridium alloy Inorganic materials 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000009958 sewing Methods 0.000 description 2
- 229910000575 Ir alloy Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/20—Nitrogen oxides; Oxyacids of nitrogen; Salts thereof
- C01B21/24—Nitric oxide (NO)
- C01B21/26—Preparation by catalytic or non-catalytic oxidation of ammonia
- C01B21/265—Preparation by catalytic or non-catalytic oxidation of ammonia characterised by the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/42—Platinum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/468—Iridium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12444—Embodying fibers interengaged or between layers [e.g., paper, etc.]
Definitions
- a further disadvantage of the platinumrhodium catalyst is that the rhodium contained therein tends to oxidise at high temperatures, causing a reduction in the efiiciency of the catalyst.
- platinum-iridium alloys which have been employed react more vigorously than the p1atinum-rhodium alloys and at a relatively low temperature.
- these alloys are disadvantageous in that they may cause the reaction to go too far, thereby forming elemental nitrogen with a reduction in yields.
- platinum-iridium alloys when platinum-iridium alloys are employed the loss of platinum is greater than when other platinum alloys are employed.
- catalysts consisting of a combination of different contact bodies are employed.
- the catalyst may be composed, for example, of two or more difierent alloys, for example platinum-rhodium and platinum-iridium and pure platinum.
- Wire networks, wire gauze or wire fabrics, such as are employed as-catalysts in the synthesis of ammonia may be made, for example, of wires consisting of platinum alloys and of pureplatinum.
- the procedure may advantageously be such that the various wires are brought into intimate contact by interweaving or intertwisting them or by similar measures.
- a plurality of wire networks can be united, forv example by sewing them together, to form a contact body.
- the wire networks which are united in this way can be of the same kind or of different kinds and may be composed of the same or of different materials.
- a sluggish alloy which only reacts at an elevated temperature for example a platinum-rhodium alloy containing about -50% of rhodium
- a more active alloy which reacts at a lower tem- 10 perature for example a platinum-iridium alloy containing about 1-10% of iridium and substantially pure platinum.
- the substantially pure platinum for example platinum in which the content of rhodium amounts to not more than about 0.1% considerably improves the mechanical properties of the 35 catalyst and also considerably prolongs the life of the catalyst.
- net-like structures which contain a skeleton of pure platinum wire can be made.
- the wires of pure platinum are interwoven or interlaced with platinum alloys.
- wires or the like of difierent thicknesses are made thicker in accordance with the greater extent to which they are used up than those of the less volatile alloys, for example platinum-rhodium alloys.
- the alloys to the present invention may in some cases contain, in addition to platinum, more than one vantages which were associated with the various 55 which contain 30-50% and have proved parthe wires of the easily volatile platinumbe employed in accordance with centimetre.
- Five layers of such Example A wire consisting of at least 99.9% of platinum and having'a diameter of 0.08 mm. is woven alternately with 5 to wires of alternately woven platinum-rhodium wires containing 10% of rhodium and platinum-iridium wires containing 1% of iridium. respectively having a diameter of 0.06 mm. and a diameter of 0.075 mm. so as to form a network having 1020 meshes per square network are intimately combined to form a contact body by sewing them together.
- a contact body of this nature has a life two to three times longer than that of an ordinary platinum contact body.
- a process for the oxidation of ammonia comprising passing a reaction mixture containing ammonia through a catalyst comprising a network which consists of wires of platinum-rhodium alloy, platinum-iridium alloy and pure platinum, respectively, which wires are interwoven with each other so as to be in intimate contact with each other, without supplying external heat.
- a catalyst for the oxidation of ammonia comprising a network which consists of wires'Ff' platinum-rhodium alloy, platinum-iridium alloy and pure platinum, respectively, which wires are interwoven with each other so as to be in intimate contact with each other.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
Description
Patented Feb. 28, 1939 UNITED STATES PATENT OFFICE 1 2,148,680 F CATALYST FOR USE IN THE OXIDATION or I AMMONIA I Oskar Brack, Visp, Wallis, Switzerland, assignor to Lonza Elektrizitatswerke und Chemische Fabriken Aktiengesellschaft (Garnpel), Basel, Switzerland, a. Swiss company No Drawing. "Application April a, 1936, No. 72,661. In Switzerland'April 6,
Serial 1935 6 Claims.
' employed give good yields of nitrogen oxides with but small'losseslof platin but as such alloys react only at high temperatures it is necessary to heat the contact bodies or'to preheat the contact gases.
A further disadvantage of the platinumrhodium catalyst is that the rhodium contained therein tends to oxidise at high temperatures, causing a reduction in the efiiciency of the catalyst. I
The platinum-iridium alloys which have been employed react more vigorously than the p1atinum-rhodium alloys and at a relatively low temperature. However, these alloys are disadvantageous in that they may cause the reaction to go too far, thereby forming elemental nitrogen with a reduction in yields. Furthermore, when platinum-iridium alloys are employed the loss of platinum is greater than when other platinum alloys are employed.
Contact bodies of pure platinum have been employed only to a small extent, as their catalytic action is comparatively low.
In accordance with the present invention, catalysts consisting of a combination of different contact bodies are employed. The catalyst may be composed, for example, of two or more difierent alloys, for example platinum-rhodium and platinum-iridium and pure platinum. In general it has been found to be advantageous for the individual components of the contact bodies to be in intimate contact with one another. Wire networks, wire gauze or wire fabrics, such as are employed as-catalysts in the synthesis of ammonia, may be made, for example, of wires consisting of platinum alloys and of pureplatinum. In this case the procedure may advantageously be such that the various wires are brought into intimate contact by interweaving or intertwisting them or by similar measures. A plurality of wire networks can be united, forv example by sewing them together, to form a contact body. The wire networks which are united in this way can be of the same kind or of different kinds and may be composed of the same or of different materials.
It has been found that,because of the action .upon one another of the bodies united in this way, it is possible to influence the properties of the individual components and to harmonize them in such a way that the disadvantages of one or the other of the components are eliminated or are reduced to a greater or less extent and advantageous combination efiects are produced.
Thus, for example, a sluggish alloy which only reacts at an elevated temperature, for example a platinum-rhodium alloy containing about -50% of rhodium, can be combined with a more active alloy which reacts at a lower tem- 10 perature, for example a platinum-iridium alloy containing about 1-10% of iridium and substantially pure platinum. It is possible in this Way to make contact bodies which, as distinguished from platinum-rhodium contact bodies, work at relatively low temperatures, so that on the one hand preheating of the gases may be dispensed with or less preheating may be employed, while on the other hand the disadvantages of platinumiridium contact bodies such as their vigorous reaction power and their considerable loss of platinum are obviated to a large extent and which have substantially better mechanical properties. Combinations of platinum alloys rich in rhodium, for example alloys preferably about 40% of rhodium, with platinum alloys which contain only a small percentage of iridium, for example those which contain about 1-5% and preferably about 2% of iridium and substantially pure platinum, ticularly suitable.
The substantially pure platinum, for example platinum in which the content of rhodium amounts to not more than about 0.1% considerably improves the mechanical properties of the 35 catalyst and also considerably prolongs the life of the catalyst. Thus net-like structures which contain a skeleton of pure platinum wire can be made. Preferably, the wires of pure platinum are interwoven or interlaced with platinum alloys.
When building-up the contact bodies, it is advantageous to combine wires or the like of difierent thicknesses with one another. Thus, for example, wires of the more iridium alloys are made thicker in accordance with the greater extent to which they are used up than those of the less volatile alloys, for example platinum-rhodium alloys.
The alloys to the present invention may in some cases contain, in addition to platinum, more than one vantages which were associated with the various 55 which contain 30-50% and have proved parthe wires of the easily volatile platinumbe employed in accordance with centimetre. Five layers of such Example A wire consisting of at least 99.9% of platinum and having'a diameter of 0.08 mm. is woven alternately with 5 to wires of alternately woven platinum-rhodium wires containing 10% of rhodium and platinum-iridium wires containing 1% of iridium. respectively having a diameter of 0.06 mm. and a diameter of 0.075 mm. so as to form a network having 1020 meshes per square network are intimately combined to form a contact body by sewing them together.
A contact body of this nature has a life two to three times longer than that of an ordinary platinum contact body.
I claim:
1. In a process for the oxidation of ammonia, the step comprising passing a reaction mixture containing ammonia through a catalyst comprising a network which consists of wires of platinum-rhodium alloy, platinum-iridium alloy and pure platinum, respectively, which wires are interwoven with each other so as to be in intimate contact with each other, without supplying external heat.
2. A catalyst for the oxidation of ammonia, comprising a network which consists of wires'Ff' platinum-rhodium alloy, platinum-iridium alloy and pure platinum, respectively, which wires are interwoven with each other so as to be in intimate contact with each other.
3. A catalyst according to claim 2 in which the wires of pure platinum contain at least 99.9% platinum.
4. A catalyst according to claim 2 in which said platinum-iridium alloy wires are thicker than the platinum-rhodium alloy wires.
5. A catalyst according to claim 2 in which the network contains a skeleton of pure platinum wires which carries the platinum-rhodium wires and the platinum-iridium wires which are interwoven therewith so as to be in intimate contact with each other.
6. A catalyst according to claim 2 in which the platinum-rhodium wires contain 10% to 50% of rhodium and the platinum-iridium wires contain 1% to 10% of iridium.
OSKAR BRACK.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH2148680X | 1935-04-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2148680A true US2148680A (en) | 1939-02-28 |
Family
ID=4567700
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US72661A Expired - Lifetime US2148680A (en) | 1935-04-06 | 1936-04-03 | Catalyst for use in the oxidation of ammonia |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2148680A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3873675A (en) * | 1971-09-14 | 1975-03-25 | Degussa | Catalyst and catalyst arrangement for the production of nitric acid |
| US12128392B2 (en) | 2019-05-22 | 2024-10-29 | Johnson Matthey Public Limited Company | Catalyst gauze |
-
1936
- 1936-04-03 US US72661A patent/US2148680A/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3873675A (en) * | 1971-09-14 | 1975-03-25 | Degussa | Catalyst and catalyst arrangement for the production of nitric acid |
| US12128392B2 (en) | 2019-05-22 | 2024-10-29 | Johnson Matthey Public Limited Company | Catalyst gauze |
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