US2129089A

US2129089A - Electrolytic condenser

Info

Publication number: US2129089A
Application number: US60755A
Authority: US
Inventors: Joseph T Hood
Original assignee: PR Mallory and Co Inc
Current assignee: Duracell Inc USA
Priority date: 1936-01-25
Filing date: 1936-01-25
Publication date: 1938-09-06
Anticipated expiration: 1955-09-06

Description

Sept. 6, 1938. J. T. HOOD ELECTROLYTIC CONDENSER Filed Jan. 25, 1936 1 z 1 1 6 7 J flJ M J z E m m U I i w flm ATTO R N EY Patented Sept. 6, 1938 PATENT OFFICE.

ELECTROLYTIC CONDENSER Joseph TrHood, Indianapolis, Ind., assignor to P. R. Mallory & Co. Inc., Indianapolis, Ind., a

corporation of Delaw Application January 25', 1936, Serial No. 60,755

8 Claims.

This invention relates to electrolytic condensers and more particularly tothe structures thereof.

An object of the invention is to provide an electrolytic condenser of improved construction.

Other objects of the invention will be apparent from the following description and accompanying drawing taken in connection with the appended claims.

The invention comprises the features of construction, combination of elements, arrangement of parts, and methods of manufacture and operation referred to above or which will be brought out and exemplified in the disclosure hereinafter set forth, including the illustrations in the drawing, the scope of the invention being indicated in the appended claims.

For a fuller understanding of the nature and objects of the invention as well as for specific fulfillment thereof, reference should be had to the following detailed description taken in connection with the accompanying drawing, in which:

Figure 1 is a longitudinal section of a dry electrolytic condenser embodying the. invention;

Figure 2 is a longitudinal section of a modified form;

Figure 3 is a section on the line 33 of Fi gure 2; and

Figure 4 is a perspective view, with parts siderable variation may be made in the method,

of procedure and the construction of parts without departing from the spirit of the invention.

In the following description and in the claims,

parts will be identified by specific names for convenience, but they are intended to be as generic in their application to similar parts as the art will permit.

In operation of electrolytic condensers under certain conditions, some gas may be evolved within the unit. If the condenser elements were confined in a hermetically sealed container an excessive pressure might develop over a period of time, in some cases reaching dangerous proportions. In order to prevent such an occurrence some form of vent is necessary which will re lieve excess pressures and still prevent evaporation of the electrolyte and exclude foreign matter which might contain corrosive impurities or excess moisture.

According to one aspect of the present invention a novel vent construction is provided, one form of which is shown inFigure 1. The dry electrolytic condenser here illustrated comprises a metal can or container l0, preferably of alumi- 5 num, having therein a condenser section or roll ll, comprising a pair of foils of film-formin metal, such as aluminum, rolled together with a pair of porous sheet spacers therebetween, said spacers being saturated with an electrolyte. At least one of the foils is film-formed.

The condenser section Ii is held at its base in a mass of pitch or other insulating material l2 and a pair of terminal conductors i 3 and I4, preferably of the same metal as the electrodes, are connected, respectively, to the two electrodes. These are covered with sheaths l5 and I6 which prevent direct metallic contact between the terminal conductors and the container wall.

An annular groove or head ll previously rolled into the container I 0 near its open upper end supports a circular cover disc i8. Disc l8, of insulating material, such as sheet Bakelite or other resin, is fitted into the open end of container l8 and rests on internal bead H. The free edge iii of container I!) is spun over the top edge of disc l8 thereby securely holding disc l8 in place and sealing the top of container iii.

A pair of terminals 20 and 2| are riveted to the outer face of disc l8 for providing external circuit connections, rivets 22 and 23 passing through disc l8 and being connected to terminal conductors l3 and M respectively within the container.

. The vent construction is provided by piercing a small hole 24 in the side of container ill at the bottom of annular groove IT. A rubber band 25 of suitable tension is then stretched around container ill in groove l'l so as to cover hole 24. The tension of the rubber band causes it to be de- 40 formed within the hole, effecting a perfect seal against external pressures. The seal thus provided will also resist a certain amount of internal pressure but before such internal pressure hecomes excessive the rubber will yield sufliciently to let out the gas developed inside the unit thereby reducing the pressure to anormal value. The seal will then again be closed by the rubber band tension. The amount of internal pressure required to cause venting can be predetermined by selecting a rubber band of the required tension.

The band is prevented from dislodgement by being placed in groove ll below the general surface of the container l0.

Figures 2 and 3 illustrate a modification generally similar to that of Figure 1 except that a special groove 26 is provided for holding the rubber band. Additional protection against dislodgement is also provided in this instance by a paper label 21 which is pasted around the container Iltl and over groove 26, the depth of the groove preferably allowing a slight spacing between the rubber band and the label.

The present vent construction, while described in connection with a dry electrolytic condenser may also be applied to other condensers of the prior art, such as wet electrolytic condensers.

A further feature of my invention lies in the method of preventing metallic contact between terminal conductors I3 and I and the container H) or between each other.

Heretofore, it has been the general practice to attempt to insulate these connecting tabs from themselves, and from the conductive container, which in some instances forms the negative side of the circuit, by means of non-conductive insulators, that is, paper or gauze or fabric, sheet or tubing, either laid between, around or inserted over the tabs, these absorbent non-conductive materials being impregnated with wax or varnish, or some such material, in an attempt to prevent the absorption of electrolyte or condensation of electrolyte vapors that occur within the condenser. This type construction has the following disadvantages Some impregnated materials are non-flexible and thus must be handled hot in order to assemble within the unit. Other materials crack when bent, allowing a path of low resistance in case this crack falls opposite another tab or comes in contact with the container. In case such a weakness exists in a condenser, as quite common where a number of tabs are forced down into a narrow space so as to be pressed against the container sides, it is likely that a spark may occur through the weakened insulator. In the case of materials impregnated with insulating compounds or non-impregnated materials, the tendency is for the separator to carbonize, eventually causing a permanent short circuit.

Another fault lies in the fact that it is almost impossible to obtain an impregnating compound )hat is absolutely impervious to the absorption of moisture, or electrolyte. Consequently, it is quite common for condenser using the construction generally used in the past, to have the tab insulators absorb sufficient electrolyte or moisture caused by condensation, to become partially conductive. In such cases, the impurities in the separator and the impregnating compound, and the incomplete impregnation with a good electrolyte, tends to cause corrosion, resulting in a severance of the tab, which causes an open circuit, rendering the condenser inoperative.

It has also been found that the insulation of these terminal conductors or tabs in the ways heretofore employed has been a very sizable item of expense. According to the present invention a more economical sheathing has been provided which is free from the above mentioned disadvantages.

The sheaths l5 and I6 of Figures 1, 2 and 3, according to this invention, are made of strips or sleeves of highly purified absorbent sheet material such as very fine gauze muslin or absorbent paper. Other materials such as are used as spacers in dry electrolytic condensers may also be suitable.

These sheaths are impregnated with a filmforming electrolyte preferably of the same composition as the electrolyte used to impregnate the porous spacer between the electrodes in condenser section H.

With this arrangement if the sheathed tabs Iii and 14 come into contact with each other or with the wall of container ill the metal surfaces are separated by the electrolyte-impregnated absorbent sheet layer or layers and will, in effect, act as small electrolytic condensers. The tabs l3 and I4 may be film-formed before assembly. The electrolyte in the sheaths has all the self-healing characteristics of the condenser itself.

It may be desirable to provide a small excess of electrolyte within the container ill to keep the sheaths saturated with electrolyte at all times. This excess electrolyte may be the same as that used for impregnation of the condenser section or may be more fluid, if desired. Due to the freedom from impurities made possible by this invention no corrosion will take place.

Figure 4 shows a modification in which a single strip of electrolyte impregnated porous material 28 is interposed between the tabs l3 and I4 and the container l0 instead of the individual sheaths illustrated in the other figures. The result is the same.

While the present invention, as to its objects and advantages, has been described herein as carried out in specific embodiments thereof, it is not desired to be limited thereby but it is intended to cover the invention broadly within the spirit and scope of the appended claims.

What is claimed is:

1. A dry electrolytic condenser comprising a condenser section comprising a pair of electrodes of film-forming metal, spacing means and a filmmaintaining electrolyte between said electrodes, a pair of terminal conductors connected respectively to said electrodes and extending outwardly from said condenser section, a protective sheath of porous material between said terminal conductors in the region outside said condenser section and a film-maintaining electrolyte held within the pores of said sheath.

2. A dry electrolytic condenser comprising a condenser section comprising a pair of electrodes of film-forming metal, a porous sheet spacer therebetween, a film-maintaining electrolyte held in said spacer, a pair of terminal conductors connected respectively to said electrodes and extending outwardly from said condenser section, a protective sheath of porous material between said terminal conductors where said conductors extend beyond said condenser section and a filmmaintaining electrolyte held within the pores of said sheath, said sheath being substantially free of corrosive agents.

3. A dry electrolytic condenser comprising a pair of sheet electrodes of film-forming metal, porous sheet spacers therebetween and a filmmaintaining electrolyte held in said spacers, terminal conductors of film-forming metal connect ed to said electrodes and extending beyond the edges 01 said spacers and a porous electrolyteholding protecting layer between at least one of said terminal conductors and surrounding parts protecting said terminal conductor beyond the edge of said spacer.

4. A dry electrolytic condenser comprising a pair of sheet electrodes of film-forming metal, porous sheet spacers therebetween and a filmmaintalning electrolyte held in said spacers, terminal conductors of film-forming metal connected to said electrodes and extending beyond the edges of said spacers and a porous electrolytepervious sheath over at least one of said terminal conductors and extending beyond the edges of said spacers.

5. A dry electrolytic condenser comprising a pair of sheet electrodes of film-forming metal,

porous sheet spacers therebetween and a filmmaintaining electrolyte held in said spacer, said electrodes and spacers being rolled into a compact substantially cylindrical roll, terminal conductors of film-forming metal connected to said electrodes and extending out from an end of said roll and a porous electrolyte-pervious protecting layer surrounding at least one of said terminal conductors beyond the end of said roll.

6. A dry electrolytic condenser comprising a pair of sheet electrodes of film-forming metal, porous sheet spacers therebetween and a filmmaintaining electrolyte held in said spacer, said electrodes and spacers being rolled into a compact substantially cylindrical roll, integral terminal tabs of film-forming metal connected to said electrodes and extending out from an end of said roll and a porous electrolyte-pervious protecting layer surrounding at least one of said integral terminal tabs beyond the end of said roll.

7. A dry electrolytic condenser comprising a pair of sheet electrodes of film-forming metal, porous sheet spacers therebetween and a filmmaintaining electrolyte held in said spacer, said electrodes and spacers being rolled into a com-- pact substantially cylindrical roll, terminal conductors of film-forming metal connected to said electrodes and extending out from an end of said roll, a container surrounding said roll and terminal conductors and having securing terminals extending through a wall thereof, said terminal conductors being secured to said securing terminals, and a porous electrolyte-pervious protecting layer surrounding at least one of said terminal conductors between the end of said roll and said securing terminals.

8. A dry electrolytic condenser comprising a pair of sheet electrodes of film-forming metal,

porous sheet spacers therebetween and a filmmaintaining electrolyte held in said spacers, said electrodes and spacers being rolled into a compact substantially cylindrical roll, elongate terminal conductors of film-forming metal connected at one end to said electrodes and extending out from an end of said roll, a container surrounding said roll and terminal conductors, securing terminal lugs extending through a wall of said container said terminal conductors being secured at their outer ends to said securing terminal lugs, and a porous electrolyte-pervious sleeve surrounding each of said terminal conductors within said container between the end of said roll and said securing terminal lugs.

JOSEPH T. HOOD. 3