US2102214A - Art of preventing seizure of contacting surfaces of soft alloys and like materials - Google Patents

Art of preventing seizure of contacting surfaces of soft alloys and like materials Download PDF

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Publication number
US2102214A
US2102214A US751750A US75175034A US2102214A US 2102214 A US2102214 A US 2102214A US 751750 A US751750 A US 751750A US 75175034 A US75175034 A US 75175034A US 2102214 A US2102214 A US 2102214A
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Prior art keywords
lacquer
stearic acid
coating
materials
art
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US751750A
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Arthur L Parker
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16BDEVICES FOR FASTENING OR SECURING CONSTRUCTIONAL ELEMENTS OR MACHINE PARTS TOGETHER, e.g. NAILS, BOLTS, CIRCLIPS, CLAMPS, CLIPS OR WEDGES; JOINTS OR JOINTING
    • F16B33/00Features common to bolt and nut
    • F16B33/06Surface treatment of parts furnished with screw-thread, e.g. for preventing seizure or fretting
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S411/00Expanded, threaded, driven, headed, tool-deformed, or locked-threaded fastener
    • Y10S411/90Fastener or fastener element composed of plural different materials
    • Y10S411/901Core and exterior of different materials
    • Y10S411/902Metal core
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S411/00Expanded, threaded, driven, headed, tool-deformed, or locked-threaded fastener
    • Y10S411/914Coated bolt
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31678Of metal
    • Y10T428/31714Next to natural gum, natural oil, rosin, lac or wax

Definitions

  • the contacting surfaces are treated with an anti-seizing material of a character which adheres to the surfaces, so that the articles to be engaged may be previously prepared with the material in position, and then the articles are brought together and the material operates to permit the articles to be tightly engaged by sliding movement without danger of seizing either during the engagement or disengagement thereof.
  • such a de posit is made locally by the use of a composition which at a normal temperature for employment without difllculty gives a thin uniform film by reason of the employment of a solvent in the composition used.
  • a solvent is volatile and evaporates to deposit a film which is thinner than the applied coating and is of substantially uni form nature throughout the surface to which the application is made.
  • a preferred manner of operating is to employ a lacquer base dissolved in a normal lacquer solvent as a protective coating material and as the base for holding the anti-seize material.
  • a lacquer base should be insoluble in the gasoline when the composition is to be employed for a gasoline fuel line, and it has been found that a nitrocellulose of the normal character employed for making lacquer solutions provides an excellent base material.
  • the anti-seize material itself operates as an extending or plasti-' cizing agent for the lacquer base of the lacquer solution. It is customary also to include a dye stufl so that the proper application of the coating may be revealed in the finished article.
  • composition of this nature may be made by employing a normal lacquer solution comprising the lacquer base in a solvent therefor, in conjunction with a substance containing the stearic acid radicle.
  • Such a substance may be a metal stearate, such 3 as aluminum, zinc or lead stearate, or stearic acid. It has been found that excellent results are attained when a mixture is employed such, for example, as from 50 to 95 percent of aluminum, zinc or lead stearate' or mixtures thereof, along with 5 to 50 percent of stearic acid.
  • stearate compounds and stearic acid are soluble in the normal lacquer solvents and also in turpentine, carbon tetrachloride, other carbonmeans customarily employed for distributing paint onto surfaces to be coated.
  • the composition may be employed at normal room temperature or a slightly elevatedtemperature may be used, as in the case of applying lacquers.
  • the article is allowed to stand for the evaporation of the volatile solvent, which occurs rapidly, and may be accelerated by heating.
  • the operation is preferably completed by a baking operation at a temperature of, say, 200 to 300 degrees F. This produces a very firm coating in the form of a thin and continuous film which will stand handling without marring or chipping, and which will not be attacked by solvents such as gasolines and motor oils.
  • a composition of this nature by dissolving the single or mixed stearic acid compound in a volatile solvent, and applying this as a paint to the article to be safeguarded, and then effecting the evaporation and deposit of the thin film therefrom, this film then being protected by a further application of a thin lacquer solution which likewise is permitted to dry out.
  • the solvent for the lacquer usually operates to cause a fusion or blending of the films, at least at their meeting surfaces, so that the lacquer film is definitely held in position and operates as a protection against bruising or decomposition of the stearic acid compound or beeswax.
  • the application of the mixed lacquer solution and anti-seizing agent appears to result in the deposit of a definite solid colloidal film in which the lacquer provides a surface coating of sufllcient continuity to protect the stearic acid compound or beeswax which is incorporated within the film.
  • the method of preventing contact seizure of soft metal parts such as aluminum and aluminum alloy having threaded portions which consists in coating the threaded portions with a solution including an anti-seizing material composed of stearic acid and a compound selected from the group consisting of zinc, aluminum and lead stearates combined with alacquer base in the presence of a volatile solvent for said material and said ingredient, and vaporizing the solvent for forming on the threaded portions a thin hard adherent coating of substantially uniform thickness.
  • An article of manufacture comprising a soft metal part such as aluminum and aluminum alloy, having threaded portions which are coated with a thin adherent film of an anti-seizing material composed of 5 to 50% of stearic acid and from 50 to of a compound selected from the group consisting of aluminum, zinc and lead stearates, combined with a lacquer base in such an amount as to form a coating which will stand handling without marring or chipping, said lacquer base being insoluble in gasoline or motor oil.
  • a coating composition for'application to soft metal parts such as aluminum and aluminum alloy, for preventing contact seizure thereof comprising 5 to 50% of stearic acid, 50 to 95% of a compound selected from the group consisting of aluminum, zinc and lead stearates, a lacquer base in such amount as to form with said stearic acid and stearates a coating which will stand handling without marring or chipping, said lacquer base being insoluble in gasoline or motor oil, and a volatile solvent for said stearic acid, stearates and lacquer base.

Description

Patented Dec. 14, 1931 UNITED STATES ART OF PREVENTING SEIZURE F CON= TACTING SURFACES OF SOFT ALLOYS AND MATERIALS I Arthur L. Parker, Cleveland, Ohio No Drawing. Application November 6, 1934, Serial No. 751,750
Claims.
My copending application Serial No. 740,029, filed August 15, 1934, describes certain manners of preventing contact seizure of metal parts, and the present invention likewise relates to the art of preventing suchseizure.
In making close fitting contacts between metal parts, especially those of soft metals such as aluminum and aluminum alloy (including duralumin), the parts sometimes seize and become "welded so that it is impossible to move the parts one with respect to the other. This is particularly the case when threads in such parts are caused to engage, and occurs both in tightening the threads together for establishing a coupling and in attempting to release them. Many such alloys have the property of yielding plastically rather than resiliently and hence imperfections in one surface result in a corresponding and mating imperfection in the other surface.
According to the present invention, the contacting surfaces are treated with an anti-seizing material of a character which adheres to the surfaces, so that the articles to be engaged may be previously prepared with the material in position, and then the articles are brought together and the material operates to permit the articles to be tightly engaged by sliding movement without danger of seizing either during the engagement or disengagement thereof.
When such articles are employed for making couplings in-pipe lines which are to convey gasoline and like fuels, it is especially necessary that the material should not be soluble in the gasoline, for example, and should not be present in such quantity and at such points that it may become disengaged in the course of service and either operate to obstruct the conduit locally or be carried along with the flow of gasoline and operate to obstruct the conduit at some other and re striated point.
It has heretofore been proposed to coat the articles as a whole by dipping them in hot liquid substances which form a deposit thereon and which become solid upon cooling. Such a procedure does not permit obtaining a thin film as the necessary high temperature for proper liquidity is dimcult to obtain by reason of t e possibility of decomposing the material employed. Hence it is customary to subject the dipped articles to a centrifugal operation to discharge excess material, but this operation is usually incomplete as the material tends to collect at' various points of the system and is not properly discharged to form the thin even coating which is so desirable. Similarly, such hot materials could not be adequately applied by brushing or spraying operations of a local nature, as the high temperature required gives difliculty in the proper application of the substance.
According to the present invention, such a de posit is made locally by the use of a composition which at a normal temperature for employment without difllculty gives a thin uniform film by reason of the employment of a solvent in the composition used. -This solvent is volatile and evaporates to deposit a film which is thinner than the applied coating and is of substantially uni form nature throughout the surface to which the application is made.
A preferred manner of operating is to employ a lacquer base dissolved in a normal lacquer solvent as a protective coating material and as the base for holding the anti-seize material. Such a lacquer base should be insoluble in the gasoline when the composition is to be employed for a gasoline fuel line, and it has been found that a nitrocellulose of the normal character employed for making lacquer solutions provides an excellent base material. The anti-seize material itself operates as an extending or plasti-' cizing agent for the lacquer base of the lacquer solution. It is customary also to include a dye stufl so that the proper application of the coating may be revealed in the finished article.
It has been found that an excellent composition of this nature may be made by employing a normal lacquer solution comprising the lacquer base in a solvent therefor, in conjunction with a substance containing the stearic acid radicle.
Such a substance may be a metal stearate, such 3 as aluminum, zinc or lead stearate, or stearic acid. It has been found that excellent results are attained when a mixture is employed such, for example, as from 50 to 95 percent of aluminum, zinc or lead stearate' or mixtures thereof, along with 5 to 50 percent of stearic acid. These stearate compounds and stearic acid are soluble in the normal lacquer solvents and also in turpentine, carbon tetrachloride, other carbonmeans customarily employed for distributing paint onto surfaces to be coated.
The composition may be employed at normal room temperature or a slightly elevatedtemperature may be used, as in the case of applying lacquers. The article is allowed to stand for the evaporation of the volatile solvent, which occurs rapidly, and may be accelerated by heating. The operation is preferably completed by a baking operation at a temperature of, say, 200 to 300 degrees F. This produces a very firm coating in the form of a thin and continuous film which will stand handling without marring or chipping, and which will not be attacked by solvents such as gasolines and motor oils.
It is also possible to carry out the procedure by employing beeswax in lieu of the compound containing the stearic acid radicle, as set out above, as a substitution in whole or in part therefor.
It is also possible to prepare a composition of this nature by dissolving the single or mixed stearic acid compound in a volatile solvent, and applying this as a paint to the article to be safeguarded, and then effecting the evaporation and deposit of the thin film therefrom, this film then being protected by a further application of a thin lacquer solution which likewise is permitted to dry out. In this case, the solvent for the lacquer usually operates to cause a fusion or blending of the films, at least at their meeting surfaces, so that the lacquer film is definitely held in position and operates as a protection against bruising or decomposition of the stearic acid compound or beeswax. In this connection, it may also be pointed out that the application of the mixed lacquer solution and anti-seizing agent appears to result in the deposit of a definite solid colloidal film in which the lacquer provides a surface coating of sufllcient continuity to protect the stearic acid compound or beeswax which is incorporated within the film.
It is obvious that the invention is not limited to the specific embodiment set out but that it may be modified in many ways. without departing from the scope of the appended claims.
2. The method of preventing contact seizure of soft metal parts such as aluminum and aluminum alloy having threaded portions, which consists in coating the threaded portions with a solution including an anti-seizing material composed of stearic acid and a compound selected from the group consisting of zinc, aluminum and lead stearates combined with alacquer base in the presence of a volatile solvent for said material and said ingredient, and vaporizing the solvent for forming on the threaded portions a thin hard adherent coating of substantially uniform thickness.
3. The method of preventing contact seizure of threaded aluminum and like soft metal parts employed for conducting gasoline and motor oils, consisting in coating the threaded portions of the parts with a solution including an anti-seizing material composed of stearic acid and a com.- pound selected from the group consisting of zinc, aluminum and lead stearates, and also including a lacquer base and a volatile solvent for the said material and said lacquer base, said lacquer base being insoluble in gasoline or motor oil and being present in such an amount as to provide with said material a coating which will stand handling without marring or chipping, vaporizing the solvent for forming a substantially uniform film of said material and said ingredient on the threaded portion, and baking at a temperature of. substantially 200 to 300 F. for producing a hard thin adherent localized coating on said threaded portion.
4. An article of manufacture comprising a soft metal part such as aluminum and aluminum alloy, having threaded portions which are coated with a thin adherent film of an anti-seizing material composed of 5 to 50% of stearic acid and from 50 to of a compound selected from the group consisting of aluminum, zinc and lead stearates, combined with a lacquer base in such an amount as to form a coating which will stand handling without marring or chipping, said lacquer base being insoluble in gasoline or motor oil.
5. A coating composition for'application to soft metal parts such as aluminum and aluminum alloy, for preventing contact seizure thereof, comprising 5 to 50% of stearic acid, 50 to 95% of a compound selected from the group consisting of aluminum, zinc and lead stearates, a lacquer base in such amount as to form with said stearic acid and stearates a coating which will stand handling without marring or chipping, said lacquer base being insoluble in gasoline or motor oil, and a volatile solvent for said stearic acid, stearates and lacquer base.
ARTHUR L. PARKER.
US751750A 1934-11-06 1934-11-06 Art of preventing seizure of contacting surfaces of soft alloys and like materials Expired - Lifetime US2102214A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2419144A (en) * 1944-12-18 1947-04-15 Champion Spark Plug Co Antiseize and sealing compound
US2419252A (en) * 1943-09-27 1947-04-22 Gen Motors Corp Prevention of seizure of metal parts
US2437220A (en) * 1943-06-26 1948-03-02 Burndy Engineering Co Inc Aluminum connection parts treated with concentrated nitric acid
US2671644A (en) * 1949-11-30 1954-03-09 Union Carbide & Carbon Corp Heat regenerator containing metal packing material coated with a lubricant
US3405594A (en) * 1964-12-11 1968-10-15 Boeing Co Rivet joining method, pin therefor and pin manufacturing method
US3468701A (en) * 1966-02-09 1969-09-23 Atlas Chem Ind Method of preventing blocking of aluminum sheet material
EP0246564A1 (en) * 1986-05-15 1987-11-25 Union Carbide Corporation Strengthened graphite-metal threaded connection
EP1455101A1 (en) * 2003-03-06 2004-09-08 Siemens Aktiengesellschaft Screw and process for making a screw with a protective coating

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2437220A (en) * 1943-06-26 1948-03-02 Burndy Engineering Co Inc Aluminum connection parts treated with concentrated nitric acid
US2419252A (en) * 1943-09-27 1947-04-22 Gen Motors Corp Prevention of seizure of metal parts
US2419144A (en) * 1944-12-18 1947-04-15 Champion Spark Plug Co Antiseize and sealing compound
US2671644A (en) * 1949-11-30 1954-03-09 Union Carbide & Carbon Corp Heat regenerator containing metal packing material coated with a lubricant
US3405594A (en) * 1964-12-11 1968-10-15 Boeing Co Rivet joining method, pin therefor and pin manufacturing method
US3468701A (en) * 1966-02-09 1969-09-23 Atlas Chem Ind Method of preventing blocking of aluminum sheet material
EP0246564A1 (en) * 1986-05-15 1987-11-25 Union Carbide Corporation Strengthened graphite-metal threaded connection
EP1455101A1 (en) * 2003-03-06 2004-09-08 Siemens Aktiengesellschaft Screw and process for making a screw with a protective coating
US20040208726A1 (en) * 2003-03-06 2004-10-21 Christian Bohme Bolt and process for producing a protective layer on a bolt

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