US2089175A - Electroplated cooking utensil - Google Patents
Electroplated cooking utensil Download PDFInfo
- Publication number
- US2089175A US2089175A US2089175DA US2089175A US 2089175 A US2089175 A US 2089175A US 2089175D A US2089175D A US 2089175DA US 2089175 A US2089175 A US 2089175A
- Authority
- US
- United States
- Prior art keywords
- electroplated
- nickel
- chromium
- cast iron
- bath
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000010411 cooking Methods 0.000 title description 26
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 40
- 229910001018 Cast iron Inorganic materials 0.000 description 30
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 26
- 229910052804 chromium Inorganic materials 0.000 description 26
- 239000011651 chromium Substances 0.000 description 26
- 229910052751 metal Inorganic materials 0.000 description 24
- 239000002184 metal Substances 0.000 description 24
- 229910052759 nickel Inorganic materials 0.000 description 20
- 235000013305 food Nutrition 0.000 description 18
- KRVSOGSZCMJSLX-UHFFFAOYSA-L Chromic acid Chemical compound O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 16
- 238000007747 plating Methods 0.000 description 16
- 239000011148 porous material Substances 0.000 description 8
- CWYNVVGOOAEACU-UHFFFAOYSA-N fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 6
- 230000001105 regulatory Effects 0.000 description 6
- KGBXLFKZBHKPEV-UHFFFAOYSA-N Boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 4
- QMMRZOWCJAIUJA-UHFFFAOYSA-L Nickel(II) chloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 4
- LGQLOGILCSXPEA-UHFFFAOYSA-L Nickel(II) sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 4
- 239000004327 boric acid Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000004519 grease Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000011253 protective coating Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- ZEFWRWWINDLIIV-UHFFFAOYSA-N tetrafluorosilane;dihydrofluoride Chemical compound F.F.F[Si](F)(F)F ZEFWRWWINDLIIV-UHFFFAOYSA-N 0.000 description 4
- 229910001208 Crucible steel Inorganic materials 0.000 description 2
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 2
- 229910001296 Malleable iron Inorganic materials 0.000 description 2
- 240000003768 Solanum lycopersicum Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- REDXJYDRNCIFBQ-UHFFFAOYSA-N aluminium(3+) Chemical class [Al+3] REDXJYDRNCIFBQ-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000004070 electrodeposition Methods 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- OHORFAFFMDIQRR-UHFFFAOYSA-N hexafluorosilicate(2-) Chemical compound F[Si-2](F)(F)(F)(F)F OHORFAFFMDIQRR-UHFFFAOYSA-N 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- -1 nickel chromium Chemical compound 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 230000001681 protective Effects 0.000 description 2
- 230000001225 therapeutic Effects 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
Classifications
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J36/00—Parts, details or accessories of cooking-vessels
- A47J36/02—Selection of specific materials, e.g. heavy bottoms with copper inlay or with insulating inlay
Definitions
- the invention relates .to hollow ware, and the principal object of the invention is to obtain an improved type of hollow ware useful primarily for cooking purposes.
- the old fashioned skillet or frying pan made of cast iron is ideally suited for cooking certain foods, but it has on the other hand certain disadvantages, one of which is that being a ferrous metal, it is quite susceptible to rusting, and another is that the general appearance of cast iron is not as pleasing asthe appearance of certain other metals, such asaluminum, which are susceptible to a high degree of finish or polish.
- the principal object of our invention is to provide an improved type of frying pan or other hollow ware article, utilizing cast iron but modifying the same so as to improve both its properties as a cooking utensil and also its appearance.
- a cast iron frying pan is provided with an electro-plated protective coating on certain surfaces thereof. More particularly, the bottom and the outside surfaces including the handle, are provided with a protective coating while the inside surface which comes in contact with the food is unplated, and has the surface characteristics of un-treated cast iron.
- the hollow ware of our invention has the advantage that the outer surface of the device which comes in contact with the flame or other source of heat, is of a different composition than the inner surface which comes in contact with the food being cooked.
- a cast iron frying pan is placed in a special type of plating bath which is so regulated and controlled that the electro-deposited metal forms only upon the outer surfaces and not upon the inner surfaces.
- the first step in the process is to electro-plate the article with a suitable nickel bath containing for example nickel sulphate up to fifty ounces per gallon; nickel chloride up to six ounces per gallon, and boric acid up to six ounces per gallon.
- the formula for the bath is such that the nickel sulphate ranges between twenty and forty ounces per gallon, preferably thirty, while the nickel chloride ranges from two to seven ounces per gallon, preferably five.
- the boric acid is preferably five ounces per gallon.
- the bath is preferably so regulated that the acidity is of the order of pH 1.0, or a range say from .5 to 1.5.
- Such an acid bath has been found to provide a nickel coating on the outer surfaces of the frying pan without plating the inside surfaces.
- the plating is carried out at an elevated temperature from to 180 F., the preferred temperature being F.
- the article After plating with. nickel and washing in the usual manner, the article is placed in a special chromium bath so regulated as to cause electrodeposition of chromium on the outer surfaces and not on the inner surfaces.
- a suitable bath it is preferable to use chromic acid, together with a sulphate catalyst in the ratio of approximately sixty parts of chromic acid to one part of sulphate.
- the chromium is deposited on the outer surfaces to form a good coating, but no deposit is obtained on the inner surfaces.
- Another chromium bath which may be used to plate the outside surfaces without depositing chromium on the inside surfaces is a modified fiuo-silicate bath.
- a fluo-silicate bath it is usual to use a ratio of forty ounces per gallon of chromic acid to two ounces per gallon of hydrofluo-silicic acid.
- a bath having a ratio of chromic acid to hydro-fluo-silicic acid of fifty-eight ounces per gallon to eight ounces per gallon We have found that this bath inhibits the deposition of chromium on the inside surfaces and at the same time causes a bright deposit on the outside surfaces.
- hollow ware such as a frying pan
- outer surfaces coated with a combination nickel chromium layer while the inner surfaces are unplated cast iron.
- the article has a pleasing appearance because the chromium finish can be highly lustrous;
- the outer surface is prevented to a large degree from tendency to rust
- the inner surface with which the food contacts has'no metallic constituents which are ob- 45 jectionable from a therapeutic standpoint;
- the inner surface is non-destructible. If
- the inside surface retains the porosity of 55 which means that the heat will be delivered to the food more rapidly or for a longer period ofv time because of this difference in radiation surfaces. This is of particular advantagewhen our-p.
- a skillet or frying pan having the body and inner cooking surface of cast iron and having covered with electroplated chromium.
- ZuAskillet or frying pan having the body and the outer surface covered with consecutive layers of electroplated. nickel and electroplated chro- 3.
- a cast iron hollow ware article adapted for cooking purposes having the inner cooking surface of cast ironand having,v the outer surface covered with 'conse'cutiveflayers of electro-deposited'nickel andchromium, the handle, top
- edge and, side, surfaces being buffed to give a high lustre andfthebottom outside surface being relatively rough and .unpolished.
- a fo'od'c'ooking utensil having the body and inner cooking ⁇ surface ,of cast iron and having the'outer' surface covered with an electroplated metal of theclass consisting of nickel and chromium.'.
- a food cooking utensil having the body and inner cooking surfaceof cast iron and having the outersurface coated with electroplated nickel.
Landscapes
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Frying-Pans Or Fryers (AREA)
- Cookers (AREA)
Description
Patented Aug. 10, 1937 ELECTROPLATED COOKING UTENSIL Henry E. Adelsperger, Jr'., and Anthony F. Cassin, Detroit, Mich., assignors to Auto City Plating Company, Inc., Detroit, Mich., a corporation of Michigan No Drawing. Application January 29, 1936,
Serial No. 61,336
'7 Claims.
The invention relates .to hollow ware, and the principal object of the invention is to obtain an improved type of hollow ware useful primarily for cooking purposes. 'It is well known that the old fashioned skillet or frying pan made of cast iron is ideally suited for cooking certain foods, but it has on the other hand certain disadvantages, one of which is that being a ferrous metal, it is quite susceptible to rusting, and another is that the general appearance of cast iron is not as pleasing asthe appearance of certain other metals, such asaluminum, which are susceptible to a high degree of finish or polish.
The principal object of our invention is to provide an improved type of frying pan or other hollow ware article, utilizing cast iron but modifying the same so as to improve both its properties as a cooking utensil and also its appearance. In accordance with our invention, a cast iron frying pan is provided with an electro-plated protective coating on certain surfaces thereof. More particularly, the bottom and the outside surfaces including the handle, are provided with a protective coating while the inside surface which comes in contact with the food is unplated, and has the surface characteristics of un-treated cast iron. Thus the hollow ware of our invention has the advantage that the outer surface of the device which comes in contact with the flame or other source of heat, is of a different composition than the inner surface which comes in contact with the food being cooked.
In carrying out our invention, a cast iron frying pan is placed in a special type of plating bath which is so regulated and controlled that the electro-deposited metal forms only upon the outer surfaces and not upon the inner surfaces. The first step in the process is to electro-plate the article with a suitable nickel bath containing for example nickel sulphate up to fifty ounces per gallon; nickel chloride up to six ounces per gallon, and boric acid up to six ounces per gallon. Desirably the formula for the bath is such that the nickel sulphate ranges between twenty and forty ounces per gallon, preferably thirty, while the nickel chloride ranges from two to seven ounces per gallon, preferably five. The boric acid is preferably five ounces per gallon. The bath is preferably so regulated that the acidity is of the order of pH 1.0, or a range say from .5 to 1.5. Such an acid bath has been found to provide a nickel coating on the outer surfaces of the frying pan without plating the inside surfaces. Usually the plating is carried out at an elevated temperature from to 180 F., the preferred temperature being F.
After plating with. nickel and washing in the usual manner, the article is placed in a special chromium bath so regulated as to cause electrodeposition of chromium on the outer surfaces and not on the inner surfaces. As an example of a suitable bath, it is preferable to use chromic acid, together with a sulphate catalyst in the ratio of approximately sixty parts of chromic acid to one part of sulphate. When such a bath is used, the chromium is deposited on the outer surfaces to form a good coating, but no deposit is obtained on the inner surfaces.
Another chromium bath which may be used to plate the outside surfaces without depositing chromium on the inside surfaces is a modified fiuo-silicate bath. For normal chromium plating operations with a fluo-silicate bath it is usual to use a ratio of forty ounces per gallon of chromic acid to two ounces per gallon of hydrofluo-silicic acid. In carrying out our invention we use a bath having a ratio of chromic acid to hydro-fluo-silicic acid of fifty-eight ounces per gallon to eight ounces per gallon. We have found that this bath inhibits the deposition of chromium on the inside surfaces and at the same time causes a bright deposit on the outside surfaces.
From the above it will appear that in accordance with our invention we have provided hollow ware such as a frying pan, with the outer surfaces coated with a combination nickel chromium layer while the inner surfaces are unplated cast iron. Among the advantages of this construction are the following:
1. The article has a pleasing appearance because the chromium finish can be highly lustrous;
2. The outer surface is prevented to a large degree from tendency to rust;
3. The surface of the skillet coming in contact with the heat or flame is protected therefrom by the electro-plated metals;
4. The inner surface with which the food contacts has'no metallic constituents which are ob- 45 jectionable from a therapeutic standpoint;
5. The inner surface is non-destructible. If
the inner surface were plated, there would be danger that the plate might chip, peel or scratch during service, thus contaminating the food and presenting an unsightly appearance;
6. The pores on the outer or fiame surfaces are closed by the electro-deposited metal, while the pores on the inner or food surface remain open;
7. The inside surface retains the porosity of 55 which means that the heat will be delivered to the food more rapidly or for a longer period ofv time because of this difference in radiation surfaces. This is of particular advantagewhen our-p.
invention is used in connection with Dutch oven-1- "jinner cookmg surface of cast iron and having utensils or utensils used as roasters, sincethe outside surface will tend to insulate or improve the radiation of the inside surface. to still further bring out this advantage, it is sometimes desirable to coat the bottom surface only of the skillet with black or other colored paint or otherwise to treat the bottom of the utensil so as to improve the heat absorption qualities. This treatment is however provided at the flame surface only, since the other exposed surfaces are preferably maintained bright to reduce radiation. Inthe preceding description we have referred particularly to a cast iron frying pan having the outer surfaces coated first with a layer of nickel and then a layer of chromium. It is preferable to have the side surfaces highly polished'prior ,to electroplating so that a bright, shiny appearance is given after the chromium deposit. The
same is. true of the handle and the top edge of preferably left rough prior to plating, thus giving arelatively dull bottom surface after plating, al-
though one having, nevertheless, the protective properties of the plated metal.
While castiron is the preferred metal for an article made in accordance with our invention, nevertheless in the broader aspects the invention is not limited to this particular material.[ In
some instances it may be found desirable to replace the cast iron with malleable iron or cast steel, or any other suitable metal or alloy. ,It is also to be understood that in certain broader aspects the invention is not limited to electro electro-plated materials may be used in lieu thereof, providing they give to the finished artithe outer surface of tomatoes and certain other vegetables.
What we claim as our invention is:
1. A skillet or frying pan having the body and inner cooking surface of cast iron and having covered with electroplated chromium. t
ZuAskillet or frying pan, having the body and the outer surface covered with consecutive layers of electroplated. nickel and electroplated chro- 3. A cast iron hollow ware article adapted for cooking purposes having the inner cooking surface of cast ironand having,v the outer surface covered with 'conse'cutiveflayers of electro-deposited'nickel andchromium, the handle, top
edge and, side, surfacesbeing buffed to give a high lustre andfthebottom outside surface being relatively rough and .unpolished.
v 4. A fo'od'c'ooking utensil having the body and inner cooking} surface ,of cast iron and having the'outer' surface covered with an electroplated metal of theclass consisting of nickel and chromium.'. U
5. A food cooking utensil having the body and inner cooking surfaceof cast iron and having the outersurface coated with electroplated nickel.
'6. A. food cookingf utensil of a cast ferrous metal having unclosed pores on the inner cooking surface adapted to admit grease thereinto, said utensil having' anouter surface ooated with electroplated metal of the class consisting of chromum and nickel,
V An 'electrop I 7 ing the food-Contactirfginner surface of cast ferjrous'metal with unclosed pores to admit grease thereinto; said utensil having a. rough .and dark outside bottom surface 'fo r. rapidly absorbing heat and havingla lustrous iout'er'side surface of electropla'ted r'netalof the class consisting of chr0- n i 1- plated layers of nickel and chromium, but other f v ADELSPERGER, JR.
ated food-cooking utensillhav-
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2089175A true US2089175A (en) | 1937-08-10 |
Family
ID=3428839
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US2089175D Expired - Lifetime US2089175A (en) | Electroplated cooking utensil |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2089175A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2424583A (en) * | 1941-11-03 | 1947-07-29 | Gunnar Edward Ferdinand Palm | Plated article and method of manufacturing same |
| US2637686A (en) * | 1949-04-02 | 1953-05-05 | Int Nickel Co | Process of producing drawn articles |
| US2889069A (en) * | 1954-01-26 | 1959-06-02 | Fuchs George Hugo Von | Pressure vessels |
| US2985567A (en) * | 1959-03-16 | 1961-05-23 | Allied Chem | Electrodeposition of black chromium coatings |
-
0
- US US2089175D patent/US2089175A/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2424583A (en) * | 1941-11-03 | 1947-07-29 | Gunnar Edward Ferdinand Palm | Plated article and method of manufacturing same |
| US2637686A (en) * | 1949-04-02 | 1953-05-05 | Int Nickel Co | Process of producing drawn articles |
| US2889069A (en) * | 1954-01-26 | 1959-06-02 | Fuchs George Hugo Von | Pressure vessels |
| US2985567A (en) * | 1959-03-16 | 1961-05-23 | Allied Chem | Electrodeposition of black chromium coatings |
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