US2081449A - Solution for treating the surface of steel or iron for the application of paint - Google Patents

Solution for treating the surface of steel or iron for the application of paint Download PDF

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Publication number
US2081449A
US2081449A US21913A US2191335A US2081449A US 2081449 A US2081449 A US 2081449A US 21913 A US21913 A US 21913A US 2191335 A US2191335 A US 2191335A US 2081449 A US2081449 A US 2081449A
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Prior art keywords
solution
iron
steel
nitric acid
oxalic acid
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US21913A
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Jr Charles B Cook
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Individual
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/46Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing oxalates

Description

Patented May 25;, .1937
Lauren sTATes SOLUTION FOR TREATING THE SURFAGE OF STEEL OR IRON FOR THE APPLICfli- TION (3F PAINT- Charles a. Cook, Jan, West nardordpconn.
No Drawing: Application May 16, 1935, Serial No. 21,913
6 Claims. (Cl. 148-65) This invention relates to a rust-proofing process and formula whichwill'efiectively produce or cause to be produced on iron or steel or their alloys a protective rust-resisting coating which is a satisfactory finish coat in itself when oiled, or provides an adherent base for paint, enamel, or lacquer.
In the use of my improved solution herein set out I have demonstrated to my entire satisfaction 10 that a treatment of a surface of steel or iron with my improved solution will enable paint, lacquer, japan, or other coloring or coating matter to be applied in an effective manner and that such coating will be retained until it is worn away as the result of natural effects. In other words, the coating will adhere so tenaciously as to prevent its being peeled or flaked off.
I am disclosing herein the ingredients comprising formulas for my improved solution and the 21 proportions of such ingredients and the method of their application, these ingredients, the proportionsthereof and method of application, having produced results entirely to my satisfaction It will be understood, however, that the propor- 25 tions may be deviated from to some slight extent and yetproduce effective results, but as above noted, the formulas set out have-been most satisfactory.
My improved solution comprises oxalic acid combined with nitric acid and a nitrate, either or both of the latter. In the treatment of a surface of steel or iron such surface is first thoroughly cleaned in any desired manner, gasolene or other similar substance having been found to work sat- 3ii isfactorily. After such surface has been cleaned and dried it is treated with an application of my improved solution. This may be applied by dipping the article into the solution and then allowing the solution to drain from the article. The 40 article is then rinsed in water to remove any surplus portions of the ingredients and such article may then be subjected to any desired degree of heat, as in an oven, for the purpose of drying it.
As above intimated I contemplate a combination of various ingredients hereinbefore mentioned. As an example, oxalic acid and nitric acid may be employed tocomprise the solution, or oxalic acid and a nitrate may be employed, or the three ingredients oxalic acid, nitric acid and a nitrate may l e/combined in the solution. The
ingredients and the proportions thereof which I have found to effect most satisfactory results are as follows:
room temperature of about the treatment To 1 gal. water Oxalic acid "oz-.. 2
Nitric acid (36 Baum) c.c 20
To 1 gal. water ()xalic acid "oz-.. 2 Nickel nitrate oz.. 3 4 To 1 gal. water Oxalic acid oz v 2 Nitric acid (36 Baum) c. c... 10 f Nickel nitrate oz Va 20 has been completed in about three minutes and with ahigher temperature the treatment may be. completed in less time, I
I claim:
1. The process of producing a rust-resisting coating on iron or steel articles by subjecting them to the action of oxalic acid and nitric acid in solution and in the proportions of 4 to 12 parts of oxalic acid to 1 to 3 parts of nitric acid.
2. The process of producing a rust-resisting coating on iron or steel articles by subjecting their surfaces to the action of oxalic acid, nitric acid, and a nitrate in solution and in the proportions of 4 to 12 parts of oxalic acid to 1 to 3 parts of nitric acid.
3. A solution comprising oxalic acid and nitric acid and in the proportions of 4 to 12 parts of oxalic acid to 1 to 3 parts of nitric acid.
4;. A solution comprising oxalic acid, a nitrate, and nitric acid and in the proportions of ito 12 parts of oxalic acidto 1 to 3 parts of nitric acid.
5. A solution consisting of oxalic acid dihydrate and nitric acid (36 Baum) in the proportion by weight of 4 parts oxalic acid dihydrate to 1 part nitric acid (36 Baum) in 1 gallon of Water. 45
6. A solution consisting of oxalic acid dihydrate, a nitrate, and nitric acid (36 Baum) in the proportion by weight of 8 parts oxalic acid dihydrate, 1 part nitrate and 1 part nitric acid (36 Baum) in 1 gallon of water.
CHARLES B. coo'x, JR.
US21913A 1935-05-16 1935-05-16 Solution for treating the surface of steel or iron for the application of paint Expired - Lifetime US2081449A (en)

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US21913A US2081449A (en) 1935-05-16 1935-05-16 Solution for treating the surface of steel or iron for the application of paint

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US21913A US2081449A (en) 1935-05-16 1935-05-16 Solution for treating the surface of steel or iron for the application of paint

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2791525A (en) * 1952-11-11 1957-05-07 Parker Rust Proof Co Composition for and method of forming oxalate coatings on ferrous metal surfaces
US5795661A (en) * 1996-07-10 1998-08-18 Bethlehem Steel Corporation Zinc coated steel sheet and strip having improved formability and surface quality and method thereof
WO2001051682A1 (en) * 2000-01-13 2001-07-19 Usinor Method for oxalating the galvanized surface of sheet metal

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2791525A (en) * 1952-11-11 1957-05-07 Parker Rust Proof Co Composition for and method of forming oxalate coatings on ferrous metal surfaces
US5795661A (en) * 1996-07-10 1998-08-18 Bethlehem Steel Corporation Zinc coated steel sheet and strip having improved formability and surface quality and method thereof
WO2001051682A1 (en) * 2000-01-13 2001-07-19 Usinor Method for oxalating the galvanized surface of sheet metal
FR2803855A1 (en) * 2000-01-13 2001-07-20 Usinor PROCESS FOR OXALATION OF THE ZINC PLATED SURFACE OF A SHEET
US20030070731A1 (en) * 2000-01-13 2003-04-17 Jacques Petitjean Method for oxalating the galvanized surface of sheet metal
US6991688B2 (en) 2000-01-13 2006-01-31 Usinor Method for oxalating the galvanized surface of sheet metal

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