US2021927A - Sodium nitrate - Google Patents
Sodium nitrate Download PDFInfo
- Publication number
- US2021927A US2021927A US625662A US62566232A US2021927A US 2021927 A US2021927 A US 2021927A US 625662 A US625662 A US 625662A US 62566232 A US62566232 A US 62566232A US 2021927 A US2021927 A US 2021927A
- Authority
- US
- United States
- Prior art keywords
- sodium nitrate
- nitrate
- sprayed
- per cent
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 title description 58
- 235000010344 sodium nitrate Nutrition 0.000 title description 29
- 239000004317 sodium nitrate Substances 0.000 title description 29
- YIXJRHPUWRPCBB-UHFFFAOYSA-N magnesium nitrate Chemical compound [Mg+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O YIXJRHPUWRPCBB-UHFFFAOYSA-N 0.000 description 12
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 239000000126 substance Substances 0.000 description 6
- 239000008187 granular material Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 150000003863 ammonium salts Chemical class 0.000 description 4
- 150000002823 nitrates Chemical class 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 235000010333 potassium nitrate Nutrition 0.000 description 4
- 239000004323 potassium nitrate Substances 0.000 description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 3
- 239000001166 ammonium sulphate Substances 0.000 description 3
- 235000011130 ammonium sulphate Nutrition 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- -1 before the spraying Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C1/00—Ammonium nitrate fertilisers
- C05C1/02—Granulation; Pelletisation; Stabilisation; Colouring
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D9/00—Nitrates of sodium, potassium or alkali metals in general
- C01D9/18—Preparation in the form of shaped products, e.g. granules
Definitions
- the present invention relates to sodium nitrate which is improved in its capacity for being stored and scattered and to a process for making such product.
- the object of this invention is a process for producing sodium nitrate in globular granules having improved mechanical strength and the product of that process.
- sodium nitrate has often been marketed in a form containing a substantial proportion of other salts, as for example potassium nitrate. It has also been proposed to prepare mixed fertilizers from sodium nitrate'by mixing the same with other fertilizing salts, such as potassium chloride or potassium nitrate.
- other fertilizing salts such as potassium chloride or potassium nitrate.
- products of the said kind which contain sodium nitrate and in addition thereto more or less substantial amounts of one or more other salts have never been marketed in the form of more or less globular granules.
- tween 1.5 and 12 per cent, and preferably between 3 and 5 per cent, are suicient to increase the pressure requiredA to destroy the granules of 2o the sprayed product by from two to seven times. In most cases amounts of less than 10 per cent will be employed.
- Example 1 instead of the magnesium nitrate in Example 1, the destroying pressure under the same conditions amounts to 1080 grams.
- Example 3 By employing 3 parts of potassium nitrate instead of the magnesium nitrate in Example 1,
- Example 4 the following pour weights i. e. the weight of the product which occupies a given volume after pouring:-
- the pour weight with sodium nitrate without any additional substances is 1150 grams per liter.
- the pour weights of sodium nitrate each with 3 per cent of additional substances are given in the following tablez- Additional substance Pour weight Grams per liter
- Example 5 95 parts of sodium nitrate are fused with an addition of 5 parts of magnesium nitrate and sprayed as already described.
- the average destying pressure of 10 globules having a diameter of 2.2 millimeters is 1400 grams.
- Ewmple '6' parts of sodium nitrate are fused with an addition of 10 parts of magnesium nitrate and sprayed as already described. vThe average destroying pressure of 10 globules having a diameter of 2.2 millimeters is 1800 grams.
- Sodium nitrate in the form of substantially globular rounded grains substantially free from voids and containing between 3 and 5 per cent .
- globular rounded grains Ysubstantially free from voidsand containing between 3 and 5 per cent of ammonium sulphate.
- the process of producing sodium nitrate of improved storage properties from practically pure sodium nitrate which comprises spray-solidifying the sodium nitrate from the fused state after having incorporated therewith between 1.5 and 12 per cent of an inorganic nitrogenous fertilizing salt selected from the group consisting of ammoniumsalts and those nitrates which are different from sodium nitrate.
- the process of producing sodium nitrate of improved storage properties from practically pure sodium nitrate which comprises spraysolidifying the sodium'nitrate from the fused state after having incorporated therewith between 3 and 5 per cent of an inorganic nitrogenous fertilizing salt selected from the group consisting of ammonium salts and those nitrates which are different from sodium nitrate.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Fertilizers (AREA)
Description
Nov. 26, 1935. w. STRATHMEYER 2,021,927
l' l soDIUM NITRATE Filed July 29, 1932 Patented Nov. 26, 1935 PATENT OFFICE soDIUM NITRATE Walter Strathmeyer, Oppau, Germany, assignor to I. G. Farbenindustrie Aktiengesellschaft, Frankfort-on-the-Main, Germany Application July 29, 1932, Serial No. 625,662' In Germany August 5, 1931 7 Claims. (Cl. 23--239) The present invention relates to sodium nitrate which is improved in its capacity for being stored and scattered and to a process for making such product.
The object of this invention is a process for producing sodium nitrate in globular granules having improved mechanical strength and the product of that process.
It has already been proposed, in order to improve the capacity of sodium nitrate for being stored and scattered, to melt it and spray it, for example according to the British Patent No. 315,262. In this manner globular granules are obtained which, however, have hollow spaces in the interior and the mechanical strength of which is consequently but slight, so that when stored in large amounts and when transported the globules collapse and thus lose their globular character. The advantages with regard to the desired properties in storing and scattering, which are produced by giving the salt the said form are thereby lost. In particular, the dust fraction, which has a very unfavorable eiect both on the capacity for storage and the capacity for being scattered, is considerably increased by the destruction of the globular shape of the granules.
On the other hand, it is known that sodium nitrate has often been marketed in a form containing a substantial proportion of other salts, as for example potassium nitrate. It has also been proposed to prepare mixed fertilizers from sodium nitrate'by mixing the same with other fertilizing salts, such as potassium chloride or potassium nitrate. However, products of the said kind which contain sodium nitrate and in addition thereto more or less substantial amounts of one or more other salts have never been marketed in the form of more or less globular granules.
I have now found that the mechanical strength of sprayed sodium nitrate is considerably increased and the disadvantages inherent in the sprayed products referred to above are therefore avoided by adding to the sodium nitrate, before the spraying, substances which increase the strength of the sprayed particles and which do not, or not appreciably, alter and in particular, not reduce, the nitrogen content of the sodium nitrate. Thus in accordancewith the present invention, there are used as addition substances materials containing nitrogen, namely nitrates or ammonium salts, especially those which have approximately the same nitrogen content as sodium nitrate. Of these, ammonium sulphate and potassium nitrate are especially suitable. Other salts containing nitrogen, such as magnesium nitrate, ammonium nitrate and iron nitrate, also 'increase the strength of the sprayed sodium nitrate.
The annexed drawingshows by way of illustration, on an enlarged scale, single grains of ex- V5'- amples of the type of product of this invention,
tween 1.5 and 12 per cent, and preferably between 3 and 5 per cent, are suicient to increase the pressure requiredA to destroy the granules of 2o the sprayed product by from two to seven times. In most cases amounts of less than 10 per cent will be employed.
i For the purpose of comparison with the products obtained according to the following examples, 25 sodium nitrate was melted without any additional substances and sprayed through a nozzle having an internal diameter of l millimeter. From the sprayed product, 10 globules were picked out having a diameter of 2.2 millimeters and the 30 pressure required to destroy them was determined. The average destroying pressure amounts to 350 grams. 'Ihe products described in the examples were tested in the same manner. The proportions given in the examples are given 35 in parts by weight.
Example 1 instead of the magnesium nitrate in Example 1, the destroying pressure under the same conditions amounts to 1080 grams.
Example 3 By employing 3 parts of potassium nitrate instead of the magnesium nitrate in Example 1,
a destroying pressure of 1800 grams is attained and a product of the type illustrated in Fig. 1 is obtained.
Example 4 the following pour weights i. e. the weight of the product which occupies a given volume after pouring:-
The pour weight with sodium nitrate without any additional substances is 1150 grams per liter. The pour weights of sodium nitrate each with 3 per cent of additional substances are given in the following tablez- Additional substance Pour weight Grams per liter Magnesium nitrate 1180 Ammonium nitrate 1190 Potassium nitrate--. 1200 Ammonium sulphate. 1220 Example 5 95 parts of sodium nitrate are fused with an addition of 5 parts of magnesium nitrate and sprayed as already described. The average destying pressure of 10 globules having a diameter of 2.2 millimeters is 1400 grams.
Ewmple '6' parts of sodium nitrate are fused with an addition of 10 parts of magnesium nitrate and sprayed as already described. vThe average destroying pressure of 10 globules having a diameter of 2.2 millimeters is 1800 grams.
What I claim is:
1. Sodium nitrate in the form o-f substantially globular rounded grains substantially free from voids and containing between 1.5 and 12 per cent of an inorganic nitrogenous fertilizing salt selected from the group consisting of ammonium salts and those nitrates which are different from sodium nitrate.
2. Sodium nitrate in the form of substantially globular rounded grains substantially free from voids and containing between 3 and 5 per cent .globular rounded grains Ysubstantially free from voidsand containing between 3 and 5 per cent of ammonium sulphate.
6. The process of producing sodium nitrate of improved storage properties from practically pure sodium nitrate which comprises spray-solidifying the sodium nitrate from the fused state after having incorporated therewith between 1.5 and 12 per cent of an inorganic nitrogenous fertilizing salt selected from the group consisting of ammoniumsalts and those nitrates which are different from sodium nitrate.
'7. The process of producing sodium nitrate of improved storage properties from practically pure sodium nitrate which comprises spraysolidifying the sodium'nitrate from the fused state after having incorporated therewith between 3 and 5 per cent of an inorganic nitrogenous fertilizing salt selected from the group consisting of ammonium salts and those nitrates which are different from sodium nitrate.
WALTER STRATHMEYER.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2021927X | 1931-08-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2021927A true US2021927A (en) | 1935-11-26 |
Family
ID=7977909
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US625662A Expired - Lifetime US2021927A (en) | 1931-08-05 | 1932-07-29 | Sodium nitrate |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2021927A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3897237A (en) * | 1974-08-02 | 1975-07-29 | Us Navy | Process for disposing of pyrotechnic flares |
| US20180327678A1 (en) * | 2015-11-20 | 2018-11-15 | Hindustan Petroleum Corporation Ltd | Descaling and anti fouling composition |
-
1932
- 1932-07-29 US US625662A patent/US2021927A/en not_active Expired - Lifetime
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3897237A (en) * | 1974-08-02 | 1975-07-29 | Us Navy | Process for disposing of pyrotechnic flares |
| US20180327678A1 (en) * | 2015-11-20 | 2018-11-15 | Hindustan Petroleum Corporation Ltd | Descaling and anti fouling composition |
| US10851318B2 (en) * | 2015-11-20 | 2020-12-01 | Hindustan Petroleum Corporation Ltd | Descaling and anti fouling composition |
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