US20210165461A1 - Articles with textured surfaces and methods of making same - Google Patents
Articles with textured surfaces and methods of making same Download PDFInfo
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- US20210165461A1 US20210165461A1 US17/174,918 US202117174918A US2021165461A1 US 20210165461 A1 US20210165461 A1 US 20210165461A1 US 202117174918 A US202117174918 A US 202117174918A US 2021165461 A1 US2021165461 A1 US 2021165461A1
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Images
Classifications
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- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F1/00—Details not covered by groups G06F3/00 - G06F13/00 and G06F21/00
- G06F1/16—Constructional details or arrangements
- G06F1/1613—Constructional details or arrangements for portable computers
- G06F1/1633—Constructional details or arrangements of portable computers not specific to the type of enclosures covered by groups G06F1/1615 - G06F1/1626
- G06F1/1656—Details related to functional adaptations of the enclosure, e.g. to provide protection against EMI, shock, water, or to host detachable peripherals like a mouse or removable expansions units like PCMCIA cards, or to provide access to internal components for maintenance or to removable storage supports like CDs or DVDs, or to mechanically mount accessories
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
- B41M3/008—Sequential or multiple printing, e.g. on previously printed background; Mirror printing; Recto-verso printing; using a combination of different printing techniques; Printing of patterns visible in reflection and by transparency; by superposing printed artifacts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
- B44C3/02—Superimposing layers
- B44C3/025—Superimposing layers to produce ornamental relief structures
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
- B05D5/02—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a matt or rough surface
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/06—Substrate layer characterised by chemical composition
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/06—Substrate layer characterised by chemical composition
- C09K2323/061—Inorganic, e.g. ceramic, metallic or glass
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F2200/00—Indexing scheme relating to G06F1/04 - G06F1/32
- G06F2200/16—Indexing scheme relating to G06F1/16 - G06F1/18
- G06F2200/163—Indexing scheme relating to constructional details of the computer
- G06F2200/1634—Integrated protective display lid, e.g. for touch-sensitive display in handheld computer
-
- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04B—TRANSMISSION
- H04B1/00—Details of transmission systems, not covered by a single one of groups H04B3/00 - H04B13/00; Details of transmission systems not characterised by the medium used for transmission
- H04B1/38—Transceivers, i.e. devices in which transmitter and receiver form a structural unit and in which at least one part is used for functions of transmitting and receiving
- H04B1/3827—Portable transceivers
- H04B1/3888—Arrangements for carrying or protecting transceivers
Definitions
- the present disclosure relates to articles having, and methods for providing, an improved textured surface on a substrate to provide a tactile feature, such as on a substrate used on a consumer article.
- an article in a first aspect includes a substrate comprising a first major surface and a second major surface opposite the first major surface; a first layer disposed on the first major surface, wherein the first layer has an adherence to the substrate of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17; and at least one ink layer disposed on the first layer, wherein the at least one ink layer has a surface roughness Ra greater than or equal 50 nm to provide a textured surface.
- an article in a second aspect, includes a substrate comprising a first major surface and a second major surface opposite the first major surface; a coating disposed on the first major surface, wherein the coating has an adherence to the substrate of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17, a gauge hardness greater than or equal to 4H according to a pencil test set forth in ASTM D3363-05(2011)e2, and a scratch hardness greater than or equal to 3H according to a pencil test set forth in ASTM D3363-05(2011)e2.
- a consumer electronic product in a third aspect includes a housing having a front surface, a back surface and side surfaces; electrical components provided at least partially within the housing, the electrical components including at least a controller, a memory, and a display, the display being provided at or adjacent the front surface of the housing; and a cover substrate disposed over the display, wherein at least one of a portion of the housing or the cover substrate comprises any of the article described herein.
- a method for creating a textured surface includes applying a first layer to a first surface of a substrate such that the first layer has an adherence to the substrate of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17; and applying at least one ink layer to the first layer, wherein the at least one ink layer has a surface roughness Ra greater than or equal 50 nm to provide a textured surface.
- a method includes applying a coating to a first surface of a substrate such that the coating has an adherence to the substrate of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17, wherein the coating has a gauge hardness greater than or equal to 4H according to a pencil test set forth in ASTM D3363-05(2011)e2 and a scratch hardness greater than or equal to 3H according to a pencil test set forth in ASTM D3363-05(2011)e2.
- FIG. 1 is a side view of an exemplary article according to embodiments described herein;
- FIG. 2 is a top view of the exemplary article of FIG. 1 ;
- FIG. 3 is a side view of another exemplary article according to embodiments described herein;
- FIG. 4 is a side view of the exemplary article of FIG. 1 having an extra layer 126 ;
- FIG. 5 is a side view of the exemplary article of FIG. 3 having an extra layer 126 ′;
- FIG. 6A is a plan view of an exemplary electronic device incorporating any of the strengthened articles disclosed herein.
- FIG. 6B is a perspective view of the exemplary electronic device of FIG. 6A .
- the present disclosure relates to an article having a textured surface and a method for making such a textured article.
- the article may be incorporated into a consumer electronic device (e.g., a mobile electronic device, a mobile phone, a smartphone, a tablet, a phablet, a notebook computer, a laptop, etc.) as part of the housing, for example the back side of the housing.
- the textured surface of the article provides tactile feedback when touched.
- a coating in the form of a first layer and at least one ink layer is applied to the surface of a substrate to form the textured surface. Forming the textured surface from a coating provides some benefits over other methods of forming a textured surface such as etching the surface.
- the benefits include (1) increased mechanical strength of the substrate because etching the substrate typically reduces the surface strength of the substrate; (2) an increase in cost and time efficiency because applying the coating is typically cheaper and faster than etching; and (3) increased safety and environmental friendliness because etching typically involves the use of acidic solutions which pose safety risks to workers and concerns with proper disposal of the acidic solutions.
- the present disclosure also relates to an article having a coating with suitable gauge hardness (for example a value of 4H or greater, 5H or greater, or 6H as determined by a pencil test) and suitable scratch hardness (for example a value of 3H or greater, 4H or greater, 5H or greater, or 6H as determined by a pencil test) and a method for making such a coated article.
- the article may be incorporated into a consumer electronic device (e.g., a mobile electronic device, a mobile phone, a smartphone, a tablet, a phablet, a notebook computer, a laptop, etc.) as part of the housing, for example the back side of the housing.
- the coating is textured and provides tactile feedback when touched.
- FIG. 1 shows a side view of an exemplary article 100 with exemplary substrate 102 having a first major surface 104 and a second major surface 106 opposite first major surface 104 connected by at least one edge surface 108 .
- a coating 110 is disposed on first major surface 104 of substrate 102 .
- coating 110 includes a first layer 112 having a first surface 114 and a second surface 116 and ink layer 118 having a first surface 120 and a second surface 122 .
- Second surface 116 of first layer 112 is disposed on first major surface 104 of substrate 102 and second surface 122 of ink layer 118 is disposed on first surface 114 of first layer 112 .
- First surface 120 of ink layer 118 functions as the textured surface of article 100 .
- disposed means directly or indirectly (e.g., having one or more layers inbetween) contacting.
- Substrate 102 may be glass-based or a polymer material.
- a “glass-based” used to include any object made wholly or partly of glass, including glass-ceramics (including an amorphous phase and a crystalline phase).
- a glass-based substrate may be a glass substrate or a glass-ceramic substrate.
- the glass-based substrate may be strengthened or non-strengthened.
- the term “strengthened substrate” refers to a glass substrate or a glass-ceramic substrate that has been chemically strengthened, for example through ion-exchange of larger ions for smaller ions in the surface of the glass or glass ceramic substrate, through thermal tempering, or through other strengthening methods known in the art.
- a glass substrate may be selected from soda-lime silicate glass, alkali-alumino silicate glass, alkali-containing borosilicate glass, alkali-containing aluminoborosilicate glass, and alkali-containing phosphosilicate.
- suitable polymeric materials include, but are not limited to: thermoplastics including polystyrene (PS) (including styrene copolymers and blends), polycarbonate (PC) (including copolymers and blends), polyesters (including copolymers and blends, including polyethyleneterephthalate and polyethyleneterephthalate copolymers), polyolefins (PO) and cyclicpolyolefins (cyclic-PO), polyvinylchloride (PVC), acrylic polymers including polymethyl methacrylate (PMMA) (including copolymers and blends), thermoplastic urethanes (TPU), polyetherimide (PEI) and blends of these polymers with each other.
- Other exemplary polymers include epoxy, styrenic, phenolic, melamine, and silicone resins.
- Substrate 102 may be substantially planar, although other embodiments may utilize a curved or otherwise shaped or sculpted substrate (e.g., having a 2.5-dimensional or 3-dimensional shape).
- the thickness of the substrate may vary along one or more of its dimensions for aesthetic and/or functional reasons. For example, the edges of the substrate may be thicker as compared to more central regions of the substrate. The length, width and thickness dimensions of the substrate may also vary according to the enclosure application or use.
- first layer 112 may be any suitable material that maintains a sufficient adherence of ink layer 118 to substrate 102 , for example, first layer 112 has an adherence to substrate 102 and ink layer 118 of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17.
- first layer 112 may act as a primer.
- first layer 112 may be a polymer based material and may be thermally cured, for example in an oven, or cured by exposure to radiation, such as ultraviolet light (i.e., uv curable).
- first layer 112 may contain a silicone resin component and in some embodiments, the silicon resin component may include a silsesquioxane component. In some embodiments, first layer 112 may be an ink, for example an inkjet ink. In some embodiments, the first layer may have a thickness of 3 ⁇ m or less, 2 ⁇ m or less, or 1 ⁇ m or less. In some embodiments, first layer 112 has a lesser thickness than ink layer 118 .
- ink layer 118 may be any suitable ink that maintains a sufficient adherence to first layer 112 , for example, ink layer 118 has an adherence to first layer 112 of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17.
- ink layer 118 is a solvent-based ink.
- ink layer 118 may be thermally cured, for example in an oven, or cured by exposure to radiation, such as ultraviolet light (i.e., uv curable).
- Ink layer 118 may be made up of at least one ink layer.
- ink layer 118 may be a single ink layer and in other embodiments, ink layer 118 may be multiple ink layers (e.g., two ink layers, three ink layers, four ink layers, etc.).
- First surface 120 of ink layer 118 provides a textured surface to article 100 .
- the textured surface also functions as a tactile feature that provides tactile feedback when touched.
- first surface 120 of ink layer 118 provides a textured surface that functions as a tactile feature based on a surface roughness Ra of first surface 120 of ink layer 118 being at least 50 nm.
- first surface 120 of ink layer 118 has a surface roughness Ra as a result of a plurality of features 124 .
- ink layer 118 may have a thickness in a range from 5 ⁇ m to 25 ⁇ m, from 5 ⁇ m to 20 ⁇ m, from 5 ⁇ m to 15 ⁇ m, from 10 ⁇ m to 25 ⁇ m, from 10 ⁇ m to 20 ⁇ m, from 15 ⁇ m to 25 ⁇ m, or any ranges and subranges therebetween. In some embodiments, ink layer 118 may have a thickness of at least 5 ⁇ m, at least 10 ⁇ m, at least 15 ⁇ m, or at least 20 ⁇ m. The thickness is measured using an optical surface profiler, such as the 3 D Optical Surface Profiler available from Zygo Corporation. In some embodiments, the above specified thicknesses facilitate tactile feedback based on surface roughness Ra.
- ink layer 118 are damage resistant and scratch resistant.
- ink layer 118 may have a gauge hardness value of 4H or greater, 5H or greater, or 6H according to a pencil test set forth in ASTM D3363-05(2011)e2 and/or a scratch value of 3H or greater, 4H or greater, 5H or greater, or 6H according to a pencil test set forth in ASTM D3363-05(2011)e2.
- first layer 112 covers only a portion first major surface 104 of substrate 102
- first layer 112 may be applied to first major surface 104 of substrate 102 in a first pattern.
- first pattern may be applied as a single contiguous body or in other embodiments, may be applied as multiple noncontiguous bodies.
- the first pattern is shown as a series of triangle shapes. However, this is merely exemplary and the first pattern may include, but is not limited to, lines, shapes, and designs.
- first layer 112 covers first major surface 104 of substrate 102 in its entirety.
- ink layer 118 may be applied to first layer 112 in a second pattern wherein the second pattern is the same as the first pattern. In other embodiments, the second pattern may be different than the first pattern such that there are portions of first layer 112 not covered with ink layer 118 .
- ink layer 118 may include a first ink layer 118 ′ applied to a first portion of the first pattern formed by first layer 112 and a second ink layer 120 ′ applied to a second portion of the first pattern formed by first layer 112 .
- First ink layer 118 ′ and second ink layer 120 ′ may differ by one or more of the following: pattern, color, thickness, surface roughness Ra, reflectance haze, transparency, average feature cross-section dimension, average feature height.
- FIG. 2 is merely exemplary and ink layer 118 may include may also include a third ink layer, a fourth ink layer, etc.
- an exemplary method for making the articles disclosed herein includes steps of applying first layer 112 , curing first layer 112 , applying ink layer 118 , and curing ink layer 118 .
- First layer 112 may be applied to first surface 104 of substrate 102 using conventional methods suitable for applying first layer 112 in the desired pattern.
- first layer 112 may be inkjet printed, screen printed, roll coated, or spray coated.
- First layer 112 may be cured prior to applying ink layer 118 .
- conventional heat sources can be used to cure first layer 112 including, but not limited to, an oven.
- conventional radiation source can be used to cure first layer 112 including, but not limited to, an ultraviolet (uv) light source.
- First layer 112 may be applied as a single layer or in multiple sublayers.
- Ink layer 118 may be applied to first surface 114 of first layer 112 using conventional methods suitable for applying ink layer in the desired pattern.
- ink layer 118 may be inkjet printed or screen printed.
- desired attributes e.g., thickness, surface roughness Ra, average feature cross-sectional dimension size, average feature height, etc.
- the ink may be applied in multiple sublayers to achieve the desired attributes.
- ink layer 118 may include portions (e.g., first ink layer 118 ′ and second ink layer 118 ′′) having different properties.
- achieving different thicknesses for different portions of ink layer 118 can be accomplished at least by one of more of utilizing different inks, using different application methods, and/or applying a different number of sublayers.
- achieving different color, reflectance haze, and transparency for different portions of ink layer 118 can be accomplished at least by utilizing different inks.
- achieving different surface roughness Ra, average feature cross-section dimension, and average feature height can be accomplished at least by one or more of using different inks, using different application methods, and/or applying a different number of sublayers.
- ink layer 118 When ink layer 118 is thermally curable, conventional heat sources can be used to cure ink layer 118 including, but not limited to, an oven. When ink layer 118 is curable by exposure to radiation, conventional radiation source can be used to cure ink layer 118 including, but not limited to, an ultraviolet (uv) light source. When ink layer 118 is applied in multiple sublayers, the ink may be cured after application of each sublayer or once all the sublayers have been applied. When ink layer 118 has different portions, for example first layer 118 ′ and second layer 118 ′′ and the different portions are applied at different times, the different portions can be cured at the same time or at different times.
- FIG. 3 shows a side view of an exemplary article 100 ′.
- Article 100 ′ is similar to article 100 in that the same type of substrate 102 may be used but an alternative coating 110 ′ is disposed on first major surface 104 of substrate 102 .
- coating 110 ′ has one or more of the following characteristics: (i) an adherence to substrate 102 of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17; (ii) a gauge hardness value of 4H or greater, 5H or greater, or 6H according to a pencil test set forth in ASTM D3363-05(2011)e2; (iii) a scratch value of 3H or greater, 4H or greater, 5H or greater, or 6H according to a pencil test set forth in ASTM D3363-05(2011)e2.
- coating 110 ′ may exhibit suitable adherence to substrate, damage resistance, and/or scratch resistance.
- coating 110 ′ may be a polymer based material and may be thermally cured, for example in an oven, or cured by exposure to radiation, such as ultraviolet light (i.e., uv curable).
- coating 110 ′ may contain a silicone resin component and in some embodiments, the silicon resin component may include a silsesquioxane component.
- coating 110 ′ may be an ink, for example an inkjet ink.
- a first surface 120 ′ of coating 110 ′ provides a textured surface to article 100 ′.
- the textured surface also functions as a tactile feature that provides tactile feedback when touched.
- first surface 120 ′ of coating 110 ′ provides a textured surface that functions as a tactile feature based on a surface roughness Ra of first surface 120 ′ of coating 110 ′ being at least 50 nm.
- first surface 120 ′ of coating 110 ′ has a surface roughness Ra as a result of a plurality of features 124 ′.
- coating 110 ′ may have a thickness in a range from 5 ⁇ m to 25 ⁇ m, from 5 ⁇ m to 20 ⁇ m, from 5 ⁇ m to 15 ⁇ m, from 10 ⁇ m to 25 ⁇ m, from 10 ⁇ m to 20 ⁇ m, from 15 ⁇ m to 25 ⁇ m, or any ranges and subranges therebetween.
- ink layer 118 may have a thickness of at least 5 ⁇ m, at least 10 ⁇ m, at least 15 ⁇ m, or at least 20 ⁇ m. The thickness is measured using an optical surface profiler, such as the 3 D Optical Surface Profiler available from Zygo Corporation. In some embodiments, the above specified thicknesses facilitate tactile feedback based on surface roughness Ra.
- coating 110 ′ may be made up of at least one layer.
- coating 110 ′ may be a single layer and in other embodiments, coating 110 ′ may be multiple layers (e.g., two layers, three layers, four layers, etc.) to achieve the desired thickness.
- coating 110 ′ covers only a portion first major surface 104 of substrate 102
- coating 110 ′ may be applied to first major surface 104 of substrate 102 in a pattern.
- the pattern may be applied as a single contiguous body or in other embodiments, may be applied as multiple noncontiguous bodies.
- the pattern may include, but is not limited to, lines, shapes, and designs.
- coating 110 ′ covers first major surface 104 of substrate 102 in its entirety.
- Coating 110 ′ may be applied to first surface 104 of substrate 102 using conventional methods suitable for applying coating 110 ′ in the desired pattern.
- coating 110 ′ may be inkjet printed, screen printed, roll coated, or spray coated.
- conventional heat sources can be used to cure first coating 110 ′ including, but not limited to, an oven.
- conventional radiation source can be used to cure coating 110 ′ including, but not limited to, an ultraviolet (uv) light source.
- Coating 110 ′ may be applied as a single layer or in multiple sublayers.
- first surface 120 of ink layer 118 or first surface 120 ′ of coating 110 ′ may have a surface roughness Ra in a range from 50 nm to 1,000 nm, from 50 nm to 900 nm, from 50 nm to 800 nm, from 50 nm to 700 nm, from 50 nm to 600 nm, from 50 nm to 500 nm, from 100 nm to 1,000 nm, from 100 nm to 900 nm, from 100 nm to 800 nm, from 100 nm to 700 nm, from 100 nm to 600 nm, from 100 nm to 500 nm, from 200 nm to 1,000 nm, from 200 nm to 900 nm, from 200 nm to 800 nm, from 200 nm to 700 nm, from 200 nm to 600 nm, from 200 nm to 500 nm, from 300 nm to 1,000 nm, from 300 nm to
- first surface 120 of ink layer 118 and first surface 120 ′ of coating 110 ′ may have a surface roughness Ra of at least 50 nm, at least 100 nm, at least 150 nm, at least 200 nm, at least 250 nm, at least 300 nm, at least 400 nm, or at least 500 nm.
- Surface roughness Ra measurements may be made over a sample surface section having dimensions of about 0.5 mm by 0.5 mm using an optical surface profiler, such as the 3 D Optical Surface Profiler available from Zygo Corporation.
- first surface 120 of ink layer 118 and first surface 120 ′ of coating 110 ′ has a surface roughness Ra as a result of a plurality of features 124 , 124 ′ respectively.
- features 124 , 124 ′ have an average cross-sectional dimension in a range from 20 ⁇ m to 200 ⁇ m, from 20 ⁇ m to 150 ⁇ m, from 20 ⁇ m to 100 ⁇ m, from 20 ⁇ m to 50 ⁇ m, from 30 ⁇ m to 200 ⁇ m, from 30 ⁇ m to 150 ⁇ m, from 30 ⁇ m to 100 ⁇ m, from 30 ⁇ m to 50 ⁇ m, from 40 ⁇ m to 200 ⁇ m, from 40 ⁇ m to 150 ⁇ m, from 40 ⁇ m to 100 ⁇ m, from 50 ⁇ m to 200 ⁇ m, from 50 ⁇ m to 150 ⁇ m, from 50 ⁇ m to 100 ⁇ m, or all ranges and subranges therebetween.
- the average cross-section dimension of the features may be measured by selecting a 0.5 mm by 0.5 mm section of the first surface 120 of ink layer 118 or first surface 120 ′ of coating 110 ′, viewing the section with an optical microscope under 200 ⁇ magnification, measuring the longest cross-sectional dimension in the x-y plane for each feature, and calculating the average.
- features 124 , 124 ′ have an average height in the z direction in a range from 0.5 ⁇ m to 100 ⁇ m, from 0.5 ⁇ m to 75 ⁇ m, from 0.5 ⁇ m to 50 ⁇ m, from 0.5 ⁇ m to 25 ⁇ m, from 1 ⁇ m to 100 ⁇ m, from 1 ⁇ m to 75 ⁇ m, from 1 ⁇ m to 50 ⁇ m, from 1 ⁇ m to 25 ⁇ m, from 3 ⁇ m to 100 ⁇ m, from 3 ⁇ m to 75 ⁇ m, from 3 ⁇ m to 50 ⁇ m, from 3 ⁇ m to 25 ⁇ m, from 5 ⁇ m to 100 ⁇ m, from 5 ⁇ m to 75 ⁇ m, from 5 ⁇ m to 50 ⁇ m, from 5 ⁇ m to 25 ⁇ m, from 10 ⁇ m to 100 ⁇ m, from 10 ⁇ m to 75 ⁇ m, from 10 ⁇ m to 50 ⁇ m, from 10 ⁇ m to 25 ⁇ m, or all ranges
- article 100 , 100 ′ may exhibit a reflectance haze (as measured at surface 120 of ink layer 118 or surface 120 ′ of coating 110 ′) in a range from 1% to 100%, from 1% to 90%, from 1% to 80%, from 1% to 70%, from 1% to 60%, from 1% to 50%, from 1% to 40%, from 1% to 30%, from 1% to 20%, from 5% to 100%, from 5% to 90%, from 5% to 80%, from 5% to 70%, from 5% to 60%, from 5% to 50%, from 5% to 40%, from 5% to 30%, from 5% to 20%, from 10% to 100%, from 10% to 90%, from 10% to 80%, from 10% to 70%, from 10% to 60%, from 10% to 50%, from 10% to 40%, from 10% to 30%, from 10% to 20%, from 20% to 100%, from 20% to 90%, from 20% to 80%, from 20% to 70%, from 20% to 60%, from 20% to 50%, from 20% to 40%, from 20% to 30%, from 30% to 100%, from 30% to 90%
- article 100 , 100 ′ may exhibit a gloss (as measured at surface 120 of ink layer 118 or surface 120 ′ of coating 110 ′) at 60° in a range from 1% to 80%, from 1% to 70%, from 1% to 60%, from 1% to 50%, from 1% to 40%, from 1% to 30%, from 1% to 20%, from 5% to 80%, from 5% to 70%, from 5% to 60%, from 5% to 50%, from 5% to 40%, from 5% to 30%, from 5% to 20%, from 10% to 80%, from 10% to 70%, from 10% to 60%, from 10% to 50%, from 10% to 40%, from 10% to 30%, from 10% to 20%, from 20% to 80%, from 20% to 70%, from 20% to 60%, from 20% to 50%, from 20% to 40%, from 20% to 30%, from 30% to 80%, from 30% to 70%, from 30% to 60%, from 30% to 50%, from 30% to 40%, from 40% to 80%, from 40%, from 40% to 60%, from 40% to 50%, from 50% to 80%, from
- ink layer 118 and coating 110 ′ have suitable gauge hardness (for example a value of 4H or greater, 5H or greater, or 6H as determined by a pencil test) and/or suitable scratch hardness (for example a value of 3H or greater, 4H or greater, 5H or greater, or 6H as determined by a pencil test) such that an additional protective coating is not needed for improving the damage resistance and/or scratch resistance of ink layer 118 and coating 110 ′.
- an additional protective coating such as a powder coating, is not disposed on ink layer 118 or coating 110 ′.
- a layer 126 may be applied to second major surface 106 of substrate 102 .
- substrate 102 may be sufficiently transparent so that layer 126 may be seen when looking at first major surface 104 of substrate 102 .
- layer 126 may correspond to and be aligned with the pattern of first layer 112 or coating 110 ′. In other embodiments, layer 126 may correspond to and be aligned with only a portion of first layer 112 or coating 110 ′. In some embodiments, layer 126 may have higher resolution than ink layer 118 or coating 110 ′ so that it creates depth to substrate 102 .
- the articles disclosed herein may be incorporated into another article such as an article with a display (or display articles) (e.g., consumer electronics, including mobile phones, tablets, computers, navigation systems, and the like), architectural articles, transportation articles (e.g., automotive, trains, aircraft, sea craft, etc.), or appliance articles.
- a display or display articles
- FIGS. 6A and 6B An exemplary article incorporating any of the substrates disclosed herein is shown in FIGS. 6A and 6B . Specifically, FIGS.
- FIGS. 6A and 6B show a consumer electronic device 600 including a housing 602 having front 604 , back 606 , and side surfaces 608 ; electrical components (not shown) that are at least partially inside or entirely within the housing and including at least a controller, a memory, and a display 610 at or adjacent to the front surface of the housing; and a cover substrate 612 at or over the front surface of the housing such that it is over the display.
- at least one of a portion of the housing or the cover substrate comprises the articles/substrates disclosed herein.
- article 100 , 100 ′ is incorporated into consumer electronic device 600 such that first major surface 102 of substrate 100 faces the user of consumer electronic device 600 .
- coating 110 , 110 ′ may be applied before or after article 100 , 100 ′ is incorporated into the other article.
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Abstract
An article includes a substrate; a first layer disposed on the first major surface of the substrate, wherein the first layer has an adherence to the substrate of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17; and at least one ink layer disposed on the first layer having a surface roughness Ra greater than or equal 50 nm to provide a textured surface. Also disclosed is an article a substrate a coating disposed on the first major surface, wherein the coating has an adherence to the substrate of greater than or equal to 4B according to a cross hatch adhesion test set, a gauge hardness greater than or equal to 4H according to a pencil test, and a scratch hardness greater than or equal to 3H according to a pencil test set.
Description
- This application is a divisional application and claims the benefit of priority under 35 U.S.C. § 120 of U.S. application Ser. No. 16/190,930 filed on Nov. 14, 2018, which in turn, claims the benefit of priority under 35 U.S.C. § 119 of U.S. Provisional Application Ser. No. 62/589,119 filed on Nov. 21, 2017, the contents of each of which are relied upon and incorporated herein by reference in their entireties.
- The present disclosure relates to articles having, and methods for providing, an improved textured surface on a substrate to provide a tactile feature, such as on a substrate used on a consumer article.
- As the sophistication of consumers continues to evolve and increase, the importance of aesthetic features (such as tactile features and visual features), especially the integration of form and function, also increases. Nowhere is this more evident than in the field of consumer electronics, such as in the design of mobile electronic devices (such as, mobile phones, smartphones, tablets, phablets, notebook computers, laptops, etc.). There have been many instances in which a consumer electronic device that exhibits some enhanced aesthetic feature over competing devices will enjoy significantly higher acceptance in the marketplace despite relatively comparable functional characteristics.
- For example, there have been efforts in the marketplace to texture the surface(s) of a mobile electronic device to provide a tactile feature, such as to the back side of a mobile phone. Previous efforts to provide a textured surface having proven to be costly and time consuming. Accordingly, there are needs in the art for new articles having, and methods for providing, a textured surface on an article having a tactile feature.
- In a first aspect an article includes a substrate comprising a first major surface and a second major surface opposite the first major surface; a first layer disposed on the first major surface, wherein the first layer has an adherence to the substrate of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17; and at least one ink layer disposed on the first layer, wherein the at least one ink layer has a surface roughness Ra greater than or equal 50 nm to provide a textured surface.
- In a second aspect, an article includes a substrate comprising a first major surface and a second major surface opposite the first major surface; a coating disposed on the first major surface, wherein the coating has an adherence to the substrate of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17, a gauge hardness greater than or equal to 4H according to a pencil test set forth in ASTM D3363-05(2011)e2, and a scratch hardness greater than or equal to 3H according to a pencil test set forth in ASTM D3363-05(2011)e2.
- In a third aspect a consumer electronic product includes a housing having a front surface, a back surface and side surfaces; electrical components provided at least partially within the housing, the electrical components including at least a controller, a memory, and a display, the display being provided at or adjacent the front surface of the housing; and a cover substrate disposed over the display, wherein at least one of a portion of the housing or the cover substrate comprises any of the article described herein.
- In a fourth aspect, a method for creating a textured surface includes applying a first layer to a first surface of a substrate such that the first layer has an adherence to the substrate of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17; and applying at least one ink layer to the first layer, wherein the at least one ink layer has a surface roughness Ra greater than or equal 50 nm to provide a textured surface.
- In a fifth aspect, a method includes applying a coating to a first surface of a substrate such that the coating has an adherence to the substrate of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17, wherein the coating has a gauge hardness greater than or equal to 4H according to a pencil test set forth in ASTM D3363-05(2011)e2 and a scratch hardness greater than or equal to 3H according to a pencil test set forth in ASTM D3363-05(2011)e2.
- Additional features and advantages will be set forth in the detailed description which follows, and in part will be readily apparent to those skilled in the art from that description or recognized by practicing the embodiments as described herein, including the detailed description which follows, the claims, as well as the appended drawings.
- It is to be understood that both the foregoing general description and the following detailed description are merely exemplary, and are intended to provide an overview or framework to understanding the nature and character of the claims. The accompanying drawings are included to provide a further understanding, and are incorporated in and constitute a part of this specification. The drawings illustrate one or more embodiment(s), and together with the description serve to explain principles and operation of the various embodiments.
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FIG. 1 is a side view of an exemplary article according to embodiments described herein; -
FIG. 2 is a top view of the exemplary article ofFIG. 1 ; -
FIG. 3 is a side view of another exemplary article according to embodiments described herein; -
FIG. 4 is a side view of the exemplary article ofFIG. 1 having anextra layer 126; -
FIG. 5 is a side view of the exemplary article ofFIG. 3 having anextra layer 126′; -
FIG. 6A is a plan view of an exemplary electronic device incorporating any of the strengthened articles disclosed herein; and -
FIG. 6B is a perspective view of the exemplary electronic device ofFIG. 6A . - Reference will now be made in detail to the present preferred embodiment(s), examples of which is/are illustrated in the accompanying drawings. Whenever possible, the same reference numerals will be used throughout the drawings to refer to the same or like parts.
- The present disclosure relates to an article having a textured surface and a method for making such a textured article. In some embodiments, the article may be incorporated into a consumer electronic device (e.g., a mobile electronic device, a mobile phone, a smartphone, a tablet, a phablet, a notebook computer, a laptop, etc.) as part of the housing, for example the back side of the housing. In some embodiments, the textured surface of the article provides tactile feedback when touched. In some embodiments, a coating in the form of a first layer and at least one ink layer is applied to the surface of a substrate to form the textured surface. Forming the textured surface from a coating provides some benefits over other methods of forming a textured surface such as etching the surface. The benefits include (1) increased mechanical strength of the substrate because etching the substrate typically reduces the surface strength of the substrate; (2) an increase in cost and time efficiency because applying the coating is typically cheaper and faster than etching; and (3) increased safety and environmental friendliness because etching typically involves the use of acidic solutions which pose safety risks to workers and concerns with proper disposal of the acidic solutions.
- The present disclosure also relates to an article having a coating with suitable gauge hardness (for example a value of 4H or greater, 5H or greater, or 6H as determined by a pencil test) and suitable scratch hardness (for example a value of 3H or greater, 4H or greater, 5H or greater, or 6H as determined by a pencil test) and a method for making such a coated article. In some embodiments, the article may be incorporated into a consumer electronic device (e.g., a mobile electronic device, a mobile phone, a smartphone, a tablet, a phablet, a notebook computer, a laptop, etc.) as part of the housing, for example the back side of the housing. In some embodiments, the coating is textured and provides tactile feedback when touched.
- The articles and methods for making the articles will now be described with reference to the FIGs.
FIG. 1 shows a side view of anexemplary article 100 withexemplary substrate 102 having a firstmajor surface 104 and a secondmajor surface 106 opposite firstmajor surface 104 connected by at least oneedge surface 108. Acoating 110 is disposed on firstmajor surface 104 ofsubstrate 102. In some embodiments,coating 110 includes afirst layer 112 having afirst surface 114 and asecond surface 116 andink layer 118 having afirst surface 120 and asecond surface 122.Second surface 116 offirst layer 112 is disposed on firstmajor surface 104 ofsubstrate 102 andsecond surface 122 ofink layer 118 is disposed onfirst surface 114 offirst layer 112.First surface 120 ofink layer 118 functions as the textured surface ofarticle 100. As used herein disposed means directly or indirectly (e.g., having one or more layers inbetween) contacting. -
Substrate 102 may be glass-based or a polymer material. As used herein a “glass-based” used to include any object made wholly or partly of glass, including glass-ceramics (including an amorphous phase and a crystalline phase). Thus a glass-based substrate may be a glass substrate or a glass-ceramic substrate. In some embodiments, the glass-based substrate may be strengthened or non-strengthened. As used herein, the term “strengthened substrate” refers to a glass substrate or a glass-ceramic substrate that has been chemically strengthened, for example through ion-exchange of larger ions for smaller ions in the surface of the glass or glass ceramic substrate, through thermal tempering, or through other strengthening methods known in the art. In some embodiments, a glass substrate may be selected from soda-lime silicate glass, alkali-alumino silicate glass, alkali-containing borosilicate glass, alkali-containing aluminoborosilicate glass, and alkali-containing phosphosilicate. - In some embodiments, when the substrate is a polymeric material, suitable polymeric materials include, but are not limited to: thermoplastics including polystyrene (PS) (including styrene copolymers and blends), polycarbonate (PC) (including copolymers and blends), polyesters (including copolymers and blends, including polyethyleneterephthalate and polyethyleneterephthalate copolymers), polyolefins (PO) and cyclicpolyolefins (cyclic-PO), polyvinylchloride (PVC), acrylic polymers including polymethyl methacrylate (PMMA) (including copolymers and blends), thermoplastic urethanes (TPU), polyetherimide (PEI) and blends of these polymers with each other. Other exemplary polymers include epoxy, styrenic, phenolic, melamine, and silicone resins.
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Substrate 102 may be substantially planar, although other embodiments may utilize a curved or otherwise shaped or sculpted substrate (e.g., having a 2.5-dimensional or 3-dimensional shape). In some embodiments, the thickness of the substrate may vary along one or more of its dimensions for aesthetic and/or functional reasons. For example, the edges of the substrate may be thicker as compared to more central regions of the substrate. The length, width and thickness dimensions of the substrate may also vary according to the enclosure application or use. - In some embodiments,
first layer 112 may be any suitable material that maintains a sufficient adherence ofink layer 118 tosubstrate 102, for example,first layer 112 has an adherence tosubstrate 102 andink layer 118 of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17. In some embodiments,first layer 112 may act as a primer. In some embodiments,first layer 112 may be a polymer based material and may be thermally cured, for example in an oven, or cured by exposure to radiation, such as ultraviolet light (i.e., uv curable). In some embodiments,first layer 112 may contain a silicone resin component and in some embodiments, the silicon resin component may include a silsesquioxane component. In some embodiments,first layer 112 may be an ink, for example an inkjet ink. In some embodiments, the first layer may have a thickness of 3 μm or less, 2 μm or less, or 1 μm or less. In some embodiments,first layer 112 has a lesser thickness thanink layer 118. - In some embodiments,
ink layer 118 may be any suitable ink that maintains a sufficient adherence tofirst layer 112, for example,ink layer 118 has an adherence tofirst layer 112 of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17. In some embodiments,ink layer 118 is a solvent-based ink. In some embodiments,ink layer 118 may be thermally cured, for example in an oven, or cured by exposure to radiation, such as ultraviolet light (i.e., uv curable).Ink layer 118 may be made up of at least one ink layer. Thus in some embodiments,ink layer 118 may be a single ink layer and in other embodiments,ink layer 118 may be multiple ink layers (e.g., two ink layers, three ink layers, four ink layers, etc.). -
First surface 120 ofink layer 118 provides a textured surface toarticle 100. In some embodiments, the textured surface also functions as a tactile feature that provides tactile feedback when touched. In some embodiments,first surface 120 ofink layer 118 provides a textured surface that functions as a tactile feature based on a surface roughness Ra offirst surface 120 ofink layer 118 being at least 50 nm. In some embodiments,first surface 120 ofink layer 118 has a surface roughness Ra as a result of a plurality offeatures 124. - In some embodiments,
ink layer 118 may have a thickness in a range from 5 μm to 25 μm, from 5 μm to 20 μm, from 5 μm to 15 μm, from 10 μm to 25 μm, from 10 μm to 20 μm, from 15 μm to 25 μm, or any ranges and subranges therebetween. In some embodiments,ink layer 118 may have a thickness of at least 5 μm, at least 10 μm, at least 15 μm, or at least 20 μm. The thickness is measured using an optical surface profiler, such as the 3D Optical Surface Profiler available from Zygo Corporation. In some embodiments, the above specified thicknesses facilitate tactile feedback based on surface roughness Ra. - In some embodiments,
ink layer 118 are damage resistant and scratch resistant. For example,ink layer 118 may have a gauge hardness value of 4H or greater, 5H or greater, or 6H according to a pencil test set forth in ASTM D3363-05(2011)e2 and/or a scratch value of 3H or greater, 4H or greater, 5H or greater, or 6H according to a pencil test set forth in ASTM D3363-05(2011)e2. - As shown in
FIG. 1 andFIG. 2 , in some embodiments,first layer 112 covers only a portion firstmajor surface 104 ofsubstrate 102 For examplefirst layer 112 may be applied to firstmajor surface 104 ofsubstrate 102 in a first pattern. In some embodiments, first pattern may be applied as a single contiguous body or in other embodiments, may be applied as multiple noncontiguous bodies. InFIG. 2 the first pattern is shown as a series of triangle shapes. However, this is merely exemplary and the first pattern may include, but is not limited to, lines, shapes, and designs. In some embodiments (not shown),first layer 112 covers firstmajor surface 104 ofsubstrate 102 in its entirety. - In some embodiments,
ink layer 118 may be applied tofirst layer 112 in a second pattern wherein the second pattern is the same as the first pattern. In other embodiments, the second pattern may be different than the first pattern such that there are portions offirst layer 112 not covered withink layer 118. In some embodiments, as shown for example inFIG. 2 ,ink layer 118 may include afirst ink layer 118′ applied to a first portion of the first pattern formed byfirst layer 112 and asecond ink layer 120′ applied to a second portion of the first pattern formed byfirst layer 112.First ink layer 118′ andsecond ink layer 120′ may differ by one or more of the following: pattern, color, thickness, surface roughness Ra, reflectance haze, transparency, average feature cross-section dimension, average feature height.FIG. 2 is merely exemplary andink layer 118 may include may also include a third ink layer, a fourth ink layer, etc. - In some embodiments, an exemplary method for making the articles disclosed herein includes steps of applying
first layer 112, curingfirst layer 112, applyingink layer 118, and curingink layer 118. -
First layer 112 may be applied tofirst surface 104 ofsubstrate 102 using conventional methods suitable for applyingfirst layer 112 in the desired pattern. For example,first layer 112 may be inkjet printed, screen printed, roll coated, or spray coated. -
First layer 112 may be cured prior to applyingink layer 118. Whenfirst layer 112 is thermally curable, conventional heat sources can be used to curefirst layer 112 including, but not limited to, an oven. Whenfirst layer 112 is curable by exposure to radiation, conventional radiation source can be used to curefirst layer 112 including, but not limited to, an ultraviolet (uv) light source.First layer 112 may be applied as a single layer or in multiple sublayers. -
Ink layer 118 may be applied tofirst surface 114 offirst layer 112 using conventional methods suitable for applying ink layer in the desired pattern. For example,ink layer 118 may be inkjet printed or screen printed. Depending on the application method and desired attributes (e.g., thickness, surface roughness Ra, average feature cross-sectional dimension size, average feature height, etc.) offirst surface 120 ofink layer 118, the ink may be applied in multiple sublayers to achieve the desired attributes. In some embodiments, as discussed above in connection withFIG. 2 ,ink layer 118 may include portions (e.g.,first ink layer 118′ andsecond ink layer 118″) having different properties. In some embodiments, achieving different thicknesses for different portions ofink layer 118 can be accomplished at least by one of more of utilizing different inks, using different application methods, and/or applying a different number of sublayers. In some embodiments, achieving different color, reflectance haze, and transparency for different portions ofink layer 118 can be accomplished at least by utilizing different inks. In some embodiments, achieving different surface roughness Ra, average feature cross-section dimension, and average feature height can be accomplished at least by one or more of using different inks, using different application methods, and/or applying a different number of sublayers. - When
ink layer 118 is thermally curable, conventional heat sources can be used to cureink layer 118 including, but not limited to, an oven. Whenink layer 118 is curable by exposure to radiation, conventional radiation source can be used to cureink layer 118 including, but not limited to, an ultraviolet (uv) light source. Whenink layer 118 is applied in multiple sublayers, the ink may be cured after application of each sublayer or once all the sublayers have been applied. Whenink layer 118 has different portions, for examplefirst layer 118′ andsecond layer 118″ and the different portions are applied at different times, the different portions can be cured at the same time or at different times. -
FIG. 3 shows a side view of anexemplary article 100′.Article 100′ is similar toarticle 100 in that the same type ofsubstrate 102 may be used but analternative coating 110′ is disposed on firstmajor surface 104 ofsubstrate 102. In some embodiments, coating 110′ has one or more of the following characteristics: (i) an adherence tosubstrate 102 of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17; (ii) a gauge hardness value of 4H or greater, 5H or greater, or 6H according to a pencil test set forth in ASTM D3363-05(2011)e2; (iii) a scratch value of 3H or greater, 4H or greater, 5H or greater, or 6H according to a pencil test set forth in ASTM D3363-05(2011)e2. Thus, in some embodiments, coating 110′ may exhibit suitable adherence to substrate, damage resistance, and/or scratch resistance. - In some embodiments, coating 110′ may be a polymer based material and may be thermally cured, for example in an oven, or cured by exposure to radiation, such as ultraviolet light (i.e., uv curable). In some embodiments, coating 110′ may contain a silicone resin component and in some embodiments, the silicon resin component may include a silsesquioxane component. In some embodiments, coating 110′ may be an ink, for example an inkjet ink.
- In some embodiments, a
first surface 120′ ofcoating 110′ provides a textured surface toarticle 100′. In some embodiments, the textured surface also functions as a tactile feature that provides tactile feedback when touched. In some embodiments,first surface 120′ ofcoating 110′ provides a textured surface that functions as a tactile feature based on a surface roughness Ra offirst surface 120′ ofcoating 110′ being at least 50 nm. In some embodiments,first surface 120′ ofcoating 110′ has a surface roughness Ra as a result of a plurality offeatures 124′. In some embodiments, coating 110′ may have a thickness in a range from 5 μm to 25 μm, from 5 μm to 20 μm, from 5 μm to 15 μm, from 10 μm to 25 μm, from 10 μm to 20 μm, from 15 μm to 25 μm, or any ranges and subranges therebetween. In some embodiments,ink layer 118 may have a thickness of at least 5 μm, at least 10 μm, at least 15 μm, or at least 20 μm. The thickness is measured using an optical surface profiler, such as the 3D Optical Surface Profiler available from Zygo Corporation. In some embodiments, the above specified thicknesses facilitate tactile feedback based on surface roughness Ra. In some embodiments, coating 110′ may be made up of at least one layer. Thus in some embodiments, coating 110′ may be a single layer and in other embodiments, coating 110′ may be multiple layers (e.g., two layers, three layers, four layers, etc.) to achieve the desired thickness. - As shown in
FIG. 3 , in some embodiments, coating 110′ covers only a portion firstmajor surface 104 ofsubstrate 102 For example, coating 110′ may be applied to firstmajor surface 104 ofsubstrate 102 in a pattern. In some embodiments, the pattern may be applied as a single contiguous body or in other embodiments, may be applied as multiple noncontiguous bodies. The pattern may include, but is not limited to, lines, shapes, and designs. In some embodiments (not shown), coating 110′ covers firstmajor surface 104 ofsubstrate 102 in its entirety. - Coating 110′ may be applied to
first surface 104 ofsubstrate 102 using conventional methods suitable for applyingcoating 110′ in the desired pattern. For example, coating 110′ may be inkjet printed, screen printed, roll coated, or spray coated. When coating 110′ is thermally curable, conventional heat sources can be used to curefirst coating 110′ including, but not limited to, an oven. When coating 110′ is curable by exposure to radiation, conventional radiation source can be used to curecoating 110′ including, but not limited to, an ultraviolet (uv) light source. Coating 110′ may be applied as a single layer or in multiple sublayers. - In some embodiments, first surface 120 of ink layer 118 or first surface 120′ of coating 110′ may have a surface roughness Ra in a range from 50 nm to 1,000 nm, from 50 nm to 900 nm, from 50 nm to 800 nm, from 50 nm to 700 nm, from 50 nm to 600 nm, from 50 nm to 500 nm, from 100 nm to 1,000 nm, from 100 nm to 900 nm, from 100 nm to 800 nm, from 100 nm to 700 nm, from 100 nm to 600 nm, from 100 nm to 500 nm, from 200 nm to 1,000 nm, from 200 nm to 900 nm, from 200 nm to 800 nm, from 200 nm to 700 nm, from 200 nm to 600 nm, from 200 nm to 500 nm, from 300 nm to 1,000 nm, from 300 nm to 900 nm, from 300 nm to 800 nm, from 300 nm to 700 nm, from 300 nm to 600 nm, from 300 nm to 500 nm, from 400 nm to 1,000 nm, from 400 nm to 900 nm, from 400 nm to 800 nm, from 400 nm to 700 nm, from 500 nm to 1,000 nm, from 500 nm to 900 nm, from 500 nm to 800 nm, from 500 nm to 700 nm or all ranges and subranges therebetween. In some embodiments,
first surface 120 ofink layer 118 andfirst surface 120′ ofcoating 110′ may have a surface roughness Ra of at least 50 nm, at least 100 nm, at least 150 nm, at least 200 nm, at least 250 nm, at least 300 nm, at least 400 nm, or at least 500 nm. Surface roughness Ra measurements may be made over a sample surface section having dimensions of about 0.5 mm by 0.5 mm using an optical surface profiler, such as the 3D Optical Surface Profiler available from Zygo Corporation. - In some embodiments,
first surface 120 ofink layer 118 andfirst surface 120′ ofcoating 110′ has a surface roughness Ra as a result of a plurality offeatures first surface 120 ofink layer 118 orfirst surface 120′ ofcoating 110′, viewing the section with an optical microscope under 200× magnification, measuring the longest cross-sectional dimension in the x-y plane for each feature, and calculating the average. - In some embodiments, features 124, 124′ have an average height in the z direction in a range from 0.5 μm to 100 μm, from 0.5 μm to 75 μm, from 0.5 μm to 50 μm, from 0.5 μm to 25 μm, from 1 μm to 100 μm, from 1 μm to 75 μm, from 1 μm to 50 μm, from 1 μm to 25 μm, from 3 μm to 100 μm, from 3 μm to 75 μm, from 3 μm to 50 μm, from 3 μm to 25 μm, from 5 μm to 100 μm, from 5 μm to 75 μm, from 5 μm to 50 μm, from 5 μm to 25 μm, from 10 μm to 100 μm, from 10 μm to 75 μm, from 10 μm to 50 μm, from 10 μm to 25 μm, or all ranges and subranges therebetween. The average height of the features may be measured over a sample surface section having dimensions of about 0.5 mm by 0.5 mm using an optical surface profile, such as the 3D Optical Surface Profiler available from Zygo Corporation.
- In some embodiments, article 100, 100′ may exhibit a reflectance haze (as measured at surface 120 of ink layer 118 or surface 120′ of coating 110′) in a range from 1% to 100%, from 1% to 90%, from 1% to 80%, from 1% to 70%, from 1% to 60%, from 1% to 50%, from 1% to 40%, from 1% to 30%, from 1% to 20%, from 5% to 100%, from 5% to 90%, from 5% to 80%, from 5% to 70%, from 5% to 60%, from 5% to 50%, from 5% to 40%, from 5% to 30%, from 5% to 20%, from 10% to 100%, from 10% to 90%, from 10% to 80%, from 10% to 70%, from 10% to 60%, from 10% to 50%, from 10% to 40%, from 10% to 30%, from 10% to 20%, from 20% to 100%, from 20% to 90%, from 20% to 80%, from 20% to 70%, from 20% to 60%, from 20% to 50%, from 20% to 40%, from 20% to 30%, from 30% to 100%, from 30% to 90%, from 30% to 80%, from 30% to 70%, from 30% to 60%, from 30% to 50%, from 30% to 40%, from 40% to 100%, from 40% to 90%, from 40% to 80%, from 40% to 70%, from 40% to 60%, from 40% to 50%, from 50% to 100%, from 50% to 90%, from 50% to 80%, from 50% to 70%, from 50% to 60%, or all ranges and subranges therebetween. The reflectance haze is measured according to ASTM E430-11 using a Rhopoint IQ available from Rhopoint Instruments Ltd.
- In some embodiments, article 100, 100′ may exhibit a gloss (as measured at surface 120 of ink layer 118 or surface 120′ of coating 110′) at 60° in a range from 1% to 80%, from 1% to 70%, from 1% to 60%, from 1% to 50%, from 1% to 40%, from 1% to 30%, from 1% to 20%, from 5% to 80%, from 5% to 70%, from 5% to 60%, from 5% to 50%, from 5% to 40%, from 5% to 30%, from 5% to 20%, from 10% to 80%, from 10% to 70%, from 10% to 60%, from 10% to 50%, from 10% to 40%, from 10% to 30%, from 10% to 20%, from 20% to 80%, from 20% to 70%, from 20% to 60%, from 20% to 50%, from 20% to 40%, from 20% to 30%, from 30% to 80%, from 30% to 70%, from 30% to 60%, from 30% to 50%, from 30% to 40%, from 40% to 80%, from 40% to 70%, from 40% to 60%, from 40% to 50%, from 50% to 80%, from 50% to 70%, from 50% to 60%, or all ranges and subranges therebetween. The gloss is measured at 60° according to ASTM D523-14 using a Rhopoint IQ available from Rhopoint Instruments Ltd.
- In some embodiments, as noted above
ink layer 118 andcoating 110′ have suitable gauge hardness (for example a value of 4H or greater, 5H or greater, or 6H as determined by a pencil test) and/or suitable scratch hardness (for example a value of 3H or greater, 4H or greater, 5H or greater, or 6H as determined by a pencil test) such that an additional protective coating is not needed for improving the damage resistance and/or scratch resistance ofink layer 118 andcoating 110′. Thus, in some embodiments, an additional protective coating, such as a powder coating, is not disposed onink layer 118 or coating 110′. - In some embodiments, as shown in
FIGS. 4 and 5 , alayer 126 may be applied to secondmajor surface 106 ofsubstrate 102. In such embodiments,substrate 102 may be sufficiently transparent so thatlayer 126 may be seen when looking at firstmajor surface 104 ofsubstrate 102. In some embodiments,layer 126 may correspond to and be aligned with the pattern offirst layer 112 or coating 110′. In other embodiments,layer 126 may correspond to and be aligned with only a portion offirst layer 112 or coating 110′. In some embodiments,layer 126 may have higher resolution thanink layer 118 or coating 110′ so that it creates depth tosubstrate 102. - The articles disclosed herein may be incorporated into another article such as an article with a display (or display articles) (e.g., consumer electronics, including mobile phones, tablets, computers, navigation systems, and the like), architectural articles, transportation articles (e.g., automotive, trains, aircraft, sea craft, etc.), or appliance articles. An exemplary article incorporating any of the substrates disclosed herein is shown in
FIGS. 6A and 6B . Specifically,FIGS. 6A and 6B show a consumerelectronic device 600 including ahousing 602 havingfront 604, back 606, andside surfaces 608; electrical components (not shown) that are at least partially inside or entirely within the housing and including at least a controller, a memory, and adisplay 610 at or adjacent to the front surface of the housing; and acover substrate 612 at or over the front surface of the housing such that it is over the display. In some embodiments, at least one of a portion of the housing or the cover substrate comprises the articles/substrates disclosed herein. In some embodiments,article electronic device 600 such that firstmajor surface 102 ofsubstrate 100 faces the user of consumerelectronic device 600. In some embodiments, coating 110, 110′ may be applied before or afterarticle - It will be apparent to those skilled in the art that various modifications and variations can be made without departing from the spirit or scope of the invention.
Claims (12)
1. An article comprising:
a substrate comprising a first major surface and a second major surface opposite the first major surface;
a coating disposed on the first major surface, wherein the coating has an adherence to the substrate of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17, a gauge hardness greater than or equal to 4H according to a pencil test set forth in ASTM D3363-05(2011)e2, and a scratch hardness greater than or equal to 3H according to a pencil test set forth in ASTM D3363-05(2011)e2.
2. The article of claim 1 , wherein the coating has a thickness of at least 5 μm and a surface roughness Ra greater than or equal 50 nm to provide a textured surface.
3. The article of claim 1 , wherein a powder coating is not disposed on the coating.
4. The article of claim 1 , wherein the coating is a first pattern that does not completely cover the first surface.
5. The article of claim 1 , wherein the coating is a first pattern that completely covers the first surface.
6. The article of claim 1 , wherein the silicone resin component comprises a silsesquioxane component.
7. The article of claim 1 , wherein the coating is an ink.
8. The article of claim 1 , wherein the substrate comprises one of glass, glass ceramic, and polymer material.
9. A consumer electronic product, comprising:
a housing having a front surface, a back surface and side surfaces;
electrical components provided at least partially within the housing, the electrical components including at least a controller, a memory, and a display, the display being provided at or adjacent the front surface of the housing; and
a cover substrate disposed over the display,
wherein at least one of a portion of the housing or the cover substrate comprises the article of claim 1 .
10. The consumer electronic product of claim 9 , wherein the first major surface of the article faces a user of the consumer electronic product.
11. A method comprising:
applying a coating to a first surface of a substrate such that the coating has an adherence to the substrate of greater than or equal to 4B according to a cross hatch adhesion test set forth in ASTM D3359-17,
wherein the coating has a gauge hardness greater than or equal to 4H according to a pencil test set forth in ASTM D3363-05(2011)e2 and a scratch hardness greater than or equal to 3H according to a pencil test set forth in ASTM D3363-05(2011)e2.
12. The method of claim 11 , wherein the coating has a thickness of at least 5 μm and a surface roughness Ra greater than or equal 50 nm to provide a textured surface.
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US17/174,918 US20210165461A1 (en) | 2017-11-21 | 2021-02-12 | Articles with textured surfaces and methods of making same |
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US17/174,918 US20210165461A1 (en) | 2017-11-21 | 2021-02-12 | Articles with textured surfaces and methods of making same |
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DE102018109102A1 (en) * | 2018-04-17 | 2019-10-17 | Schott Ag | Printed device component |
US11402669B2 (en) | 2018-04-27 | 2022-08-02 | Apple Inc. | Housing surface with tactile friction features |
US11112827B2 (en) | 2018-07-20 | 2021-09-07 | Apple Inc. | Electronic device with glass housing member |
US11691912B2 (en) | 2018-12-18 | 2023-07-04 | Apple Inc. | Chemically strengthened and textured glass housing member |
US11199929B2 (en) | 2019-03-21 | 2021-12-14 | Apple Inc. | Antireflective treatment for textured enclosure components |
US11372137B2 (en) | 2019-05-29 | 2022-06-28 | Apple Inc. | Textured cover assemblies for display applications |
US11109500B2 (en) | 2019-06-05 | 2021-08-31 | Apple Inc. | Textured glass component for an electronic device enclosure |
US11192823B2 (en) | 2019-06-05 | 2021-12-07 | Apple Inc. | Electronic devices including laser-textured glass cover members |
US10827635B1 (en) | 2019-06-05 | 2020-11-03 | Apple Inc. | Electronic device enclosure having a textured glass component |
CN111587000B (en) * | 2020-05-15 | 2022-03-22 | Oppo广东移动通信有限公司 | Ceramic-like electronic equipment shell, preparation method thereof and electronic equipment |
US11897809B2 (en) | 2020-09-02 | 2024-02-13 | Apple Inc. | Electronic devices with textured glass and glass ceramic components |
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- 2018-11-19 CN CN201880086024.XA patent/CN111565937A/en active Pending
- 2018-11-19 WO PCT/US2018/061881 patent/WO2019103980A1/en active Application Filing
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US20190155339A1 (en) | 2019-05-23 |
CN111565937A (en) | 2020-08-21 |
US10921860B2 (en) | 2021-02-16 |
WO2019103980A1 (en) | 2019-05-31 |
TW201936418A (en) | 2019-09-16 |
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